APEX & STAR MODEL-A MOCK TEST-16

Time:3HRS Max. Marks: 300M

KEYSHEET
PHYSICS
1-10 A D C D A B A B C D
11-20 A A C D A B A A A B
21-25 7 1 3 8 2

CHEMISTRY
26-35 D C D B D D D C B D
36-40 B B A A B A B A B C
41-50 6 2 4 4 3

MATHEMATICS

51-60 C A B A D D B D B A
61-70 A B A A A B B C B A
71-75 1 2 3 8 7
 PHYSICS
1. All reversible engines working for the same temperature of source and sink have
same efficiencies. If the temperatures are different, the efficiency is different.

8 RT
2. vrms 
M
TH 2 TO2
For vrms to be equal 
M H2 M O2
Here M H 2  2; M O2  32;
TO2  47  273  320 K
TH 2320
   TH 2  20 K
2 32
3. If n1 moles of adiabatic exponent  1 is mixed with n2 moles of adiabatic exponent
 2 then the adiabatic component of the resulting mixture is given by
n1  n2 n n
 1  2
 1 1 1  2 1
11 1 1 2 5 3
     4
 1 7 1 5 1  1 2 2
5 3
6 3
 2  4  4    
4 2
3 3
4. P  T  PT = constant …(i)
But for an adiabatic process, the pressure temperature
Relationship is given by

1  1
P T  constant  PT = constant … (ii)
 3
From (i) and (ii)  3    3  3   
1  2

nRT 1000  8.3  7

5. W  146000 
1  1 
58.1 58.1
or 1       1  1.4
146 146

Hence the gas is diatomic.

6. According to Mayer’s relationship C P  CV  R

 CP CV R
   here M  28
M M M

mass 1
7. Volume =  m3
density 4
5 5 1
K .E  PV   8  104   5  104 J
2 2 4
 1  1  1
8. TV
1  T2  32V   T1   32  .T2
 2
For diatomic gas,     1 
5 5
2
T1   32  5 .T2  T1  4T2
T2 T 1 3
No, efficiency  1   1  2  1    0.75
T1 4T2 4 4

9. Here, work done is zero.

So, loss in kinetic energy = change in internal energy of gas
1 2 R
mv  nCv T  n T
2  1
1 2 m R Mv 2    1
mv  T T  K
2 M  1 2R

10. Efficiency of engine

1 T T  62 1
 1  2 and  2  1  2 
6 T1 T1 3
5
 T1  372 K and T2   372  310 K
6

11. Heat given to system   nCV T  AB   nC p T 

B C

3  5 
   nRT      nRT  
2  A B  2  B C
3  5 
   V0 P     2 P0  V0 
2  A B  2 
13
 PV 0 0
2
and W0  PV
0 0
 Work PV
  0 0  100  15.4%
heat given 13 PV
2 0 0

stress
12. Young’s modulus Y 
strain
Stress  Y  strain
Stress in steel wire = Applied pressure
Pressure = stress = Y  strain
L
Strain   T (As length is constant)
L
 2  1011 1.1  105  100
 2.2  108 Pa

13. Rate of heat flow is given by,

KA 1   2 
Q
l
Where, K  coefficient of thermal conductivity
l  length of rod and A  Area of cross-section of rod

If the junction temperature is T , then

QCopper  QBrass  QSteel
0.92  4 100  T  0.26  4  T  0  0.12  4  T  0 
 
46 13 12
 200  2T  2T  T
 T  40C
0.92  4  60
 QCopper   4.8cal / s
46

14. In cyclic process, change in total internal energy is zero.

 U cyclic  0
5R
U BC  nCv T  1  T
2
Where, Cv  molar specific heat at constant volume.
For BC , T  200 K
 U BC  500 R
1
15. 
 N  3RT
2 d 2  
V  M
V

T
As, TV  1  K
So,   V  1/ 2
 1
Therefore, q 
2

1
16. Time lost/ gained per day     86400 second
2
1
12    40     86400
2
1
4     20   86400
2
40  
On dividing we get, 3 
  20
3  60  40  
4  100    25C

18. We are given that 1kg of sweat requires 580  103 cal for evaporation. So, we will
follow unitary method to find the amount of sweat evaporated per minute from the
body.
1
So, 1 cal will produce sweat  kg
580  102
3 14.5  103
Now, 14.5  10 cal will produce sweat  kg
580  103
1
 kg  0.025 kg
40
So, amount of sweat evaporated per minute is 0.025kg
19. In the processes taking place in containers A and B, gas is being compressed from
same initial stage through two different paths.

Now, for isothermal process in container A, we have, PV 2 2.

1 1  PV

So, we get, P0  2V0   PV

2 0

 P2  2 P0
r r
Now, for adiabatic process, PV 2 2 .
1 1  PV

Now, substituting the known values, we get,

r r
P0  2V0   P2 V0 
r
 2V 
 P2   0  P0  2 r P0
 V0 
 P2 B 2r P0 r 1
So,   2 P0
 P2  A 2 P0
Hence, option A is the correct answer.
20. Let the equilibrium temperature to be found be T . Now, we consider T to be
greater than T1 and T2 but smaller than T3 .
Since there is no loss of heat energy. Hence, we get,
Heat lost by M 3  Heat regained by M 2  Heat regained by M 2
So, we get,
 M 2 s T3  T   M 1S T  T1   M 2 S T  T2 
Dividing both sides by s , we get,
 M 2  T2  T   M 1 T  T1   M 2 T  T2 
Opening the brackets and solving for T , we get,
 M 2T3  M 3T  M 1T  M 1T1  M 2T  M 2T2
 M 3T3  M 1T1  M 2T2  M 1T  M 2T  M 3T
M 1T1  M 2T2  M 3T3
T 
M1  M 2  M 3
 Hence, b is the correct option.

21. E  e AT 4
4
E2  T2 
 
E1  T1 
4
E2  400 
 
E1  300 
256
E2  E1
81
243 1
22.   4004  3004 
70 2r
1
R   6004  3004 
r
On solving, R  1

 T1   T2 
23.   
 A1   A2 
y11t  y2 2 t
y1  2 3
    1.5
y2 1 2
24. The rods are in series
2l l l
    ke  8
ke A 6 A 12 A

25. If T0 is the temperature of the middle plate,

1
 97  4
 4
 
 A  3T   T04   A T04   2T 
4
  T0   
 2 

CHEMISTRY
26.
%s H H H
%s C %s C C
H F H F F F
%s H F F

 %s character in C  F bonds will be less hence %s character will be more

in other bonds of molecule.
If %s character more, bond length will be smaller. Hence order will be
 CH 3 F  CH 2 F2  CHF3
27. Conceptual
qq
28. LE  1 2
r
MP  LE
Polarizing power of cation  charge on cation
Covalent character  polarizing power of cation
29. Conceptual
30. Conceptual
31. Hint:
1
e
N 2   N 2
B .O  3 B .O  2.5
 e 1
 O2
O2 
B .O  2 B.O  2.5

32.

HOMO LUMO
2 *
O2  2 px 6 2 pz
N 2  * 2 px  * 2 py
C2  2 px /  2 p y 6 zp z
N2  * 2 px /  * 2 p y 6 zp z
e 1 jump from ABMO to BMO  more energy gap.
So, more energy will be required.

33. Conceptual

34. Conceptual

35. Hint:
Extent of overlapping is more in d  d than p  p & p  d 

36. Conceptual

37.
 Number of sp 2 hybrid
Orbitals  6  x
Number of sp hybrid
Orbitals  2  y

38.

a  12, b  4, c  4
a  b 12  4 8
  2
c 4 4
39. Conceptual

40.  OH 2  Polar
 SCN 2  Polar
ClF3  Polar
SeF4  Polar
41. Conceptual

42.
43. Hint:
O O
N C Cl
O O O O O O
O
NO3- CO3-2 ClO3-
O
S
O O
SO3
44. Conceptual
45.
Partial XeF6 + H2O XeOF4 + 2HF
hydrolysis XeF + 2H O XeO2F4 + 4HF
6 2

XeF6 + 3H2O XeO3 + 6HF

Complete hydrolysis

46. No. of L.P in Malamine = 6

47. Orbitals which are perpendicular to z  axis and have proper lateral overlap can
form  - bond.
48.
 S
P
S
S S
P S
S P S
S S
P
S
No. of p  d  bonds = 4

49. Hint:

F
F F
I
F F square
prymidal

50. Conceptual
MATHEMATICS

51. (C)
Solution:
 P  P I  P
3

 PI  P 2  PI   I  P 
 P  I  P  2P  I
 Now, P 4  P.P 3
 P 4  P 2 P  I 
 P4  2P2  P
 P 4  2I  2P  P
 P4  2I  3P
and P 5  P 2 I  3P 
 P 5  2 P  3 I  P 
 P5  5P  3I
Also, P 6  P 5 P  3I 
 P6  5P2  3P
 P 6  5  I  P   3P
 P6  5I 8P
So, n  6
52. (A)
Given n  20; S 20  ?
Series (1)  3,7,11,15,19,23,27,31,35,39,43,47,51,55,59 ….
Series (2)  1,6,11,16,21,26,31,36,41,46,51,56,61,66,71
The common terms between both the series are 11, 31,51,71 ….
Above series forms an Arithmetic progression (A.P).
Therefore, first term (a) =11 and common difference (d) =20
(d= LCM (d of series (1), d of series (2)) so LCM (4,5) = 20)
n
Now, Sn   2a   n  1 d 
2
20
S20   2  11   20  1 20 
2
S20  10 22  19  20
S 20  10  402  4020
 S 20  4020  10k  k  402

2
n2 n  n  1
53. Sn  
1  n  2
1 2
 n  1
n  n 2  2n  1 n  n  n  2   1
Sn  ;S n  
 n  2 n  2
 1  n22
Sn  n  n   ; Sn  n2 
 n  2  n  2
 2
Sn  n2  1 
 n  2
27 50 2 2 2
Now,  n 1   n 1
26 n 1 n  2 n 1
27 50  2  1 1 
   n  n   2   
26 n1   n  2 n  1 
27  50  51 101 50  51  1 1  
    2      41652
26  6 2  52 2  
54. (A)
1 
1
  
log 5 5 x  125  log 5 6   1  
 2x 
 5 1 x  125   1 
 log 5    1  
 6   2 x 
1
 5 x  125  51.5  1 x
2
.6
 51/ x  125  5.6.51/2 x
1
Let 5 2 x  y
 y 2  30 y  125  0
  y  25  y  5   0
 y  5 or 25
1
5 2x
 51 or 52
1 1
x  or
2 4
So sum of all the possible value of x is 3/4
55. (D)
 1  1 
tn   n  1  n   n  2 
    
 1 1   1 1
 n3  n 2  2   1  n 1  2    1
     
 n 3  n 2    2  1  n    2  1  1
 n3  1
2
n n
n 2  n  1
 sn   t r    r  1  3
n
r 1 r 1 4
S10  3025  10  3035
 S 20  44100  20  44120
56. (D)
z 2  az  a 2  0
 z  a , a 2 (where ‘  ’ is non-real roots of unity)
 locus of z is a pair of straight lines and arg  z   arg  a   arg   or
arg  a   arg  2 
2
 arg  z   
3
Also, z  a  or a  2  z  a
All the three statements are correct.

57. (B)
Let the two numbers be a and b, then G  ab or G 2  ab

3120 3119 4 n  3 3
58.   n
12 4 4 4
59. x  1  x  x  1  6, gives four cases
Case I. when x  1 … (i)
  x  1  x   x  1  6
 x 1  x  x  1  6
 3 x  6 …(ii)
From eqs. (i) and (ii), x  2
Case II. When 1  x  0 …(iii)
 x  1  x   x  1  6
 1  x  1  6  x  4 … (iv)
 no value of x [From (iii) and (iv)]
Case III, When 0  x  1 …(v)
 x  1  x   x  1  6
x4 …(vi)
No solution, using Eqs. (v) and (vi)
Case IV. When x  1 … (vii)
x 1  x  x 1  6
 3x  6 or x  2 … (viii)
From eqs. (vii) and (viii), x  2
Thus, from above four cases,
x  2 or x  2
 x  (, 2]  [2, )
60. c 2  4ab
D
Minimum value is   c 2
4a
61. The roots are 2 , 2 2

62. (B)
2
x 1
 x 1 
 x  1
x x
Since, a  b  a  b iff ab  0
2
 x  1 .  x  1
  x  1  0 or 0
x x
 x  0 or 1
63. (A)
Here, x1  x2  4  x2  4  x1 and x1 x2  x32  4  x42
 x1  4  x1   x32  4  x42
 x12  4 x1  4  x32  x42  0
2
  x1  2   x32  x42  0 , which is possible
Only when x1  2, x3  0, x4  0 and x2  2.
So, there exist only one solution.
64. (A)
Equating the rational and irrational part, we get
x  y  3 x  y,
x  2 y  0, x  y  1  0
 x  2 and y  1
65. (A)
Factorise the given expression
1 1
6 x 2  xy  y 2  6 x  8 y  12  6  x   y  2  x   y  1    ,  
3 2
66. (B)
2 2
2  e x  1   e x   2e x  1  e x  1

e x  1  e x  1  2  0 or e x  1  2, 1
67. (B)
Since, two common roots must satisfy
x 3
 5 x 2  px  q    x 3  7 x 2  px  r   0
i.e., 2 x 2  q  r  0 sum of its roots is zero
So sum of common roots  0
 Let x 3  5 x 2  px  q  0 and x3  7 x 2  px  r  0 has roots  ,  ,  1 and  ,  ,  2
respectively.
      1  5 and      2  7 where     0
  1  5 or  2  7 so  1   2  12
68. (C)
To get maximum value of determinant diagonal elements are  min  0,1,2,3,4    0
non-diagonal elements are  max  0,1,2,3,4    4
0 4 4
So, A max  4 0 4,
4 4 0
 A max  0  4  16   4 16   128
Minimum value can be achieved just by
69. (B)
In order to get term independent of x we put x  0
0 1 3
Putting x  0  1 2 3  0  1 9   310   21
3 4 0
So constant term is 21
70. (A)
The given system has a non-trivial solution, if
 sin  cos
1 cos  sin   0
1 sin   cos
By expanding the determinant, we get 
 sin 2  cos 2
For   1,sin 2  cos 2  1
1 1 1  
 sin 2  cos   cos  2  
2 2 2  4
1    
 cos  2n    2  2n   , n being an integer.
2  4 4 4
So tan 2  1
71. (1)
Let
1  47 3
50  j
5
56  k

E 57  4 
C  C3   C53k 
C4  j 0 k 0 
 5
1  47  47 
 57  C4   C3  C3  C3  C3   56 k C53k  
48 49 50

C4   k 0 
1  7
 57  C4   47 C3  48 C3  49 C3  50 C3    51 C3  52 C3  53 C3  54 C3 55 C3  56 C3  
C4
57
C4
 57
1
C4
72. (2)
Since,
n
1  x  x  2
 a0  a1 x  a2 x 2  ...  a2 n x 2 n …(i)
Substituting x   ,  2 and 1 and then, adding them together a0  a2  a6  ...  3n1
Multiplying Eq. (i) by x 2 and then repeating the same process again
a1  a4  a7  ...  3n 1
 a0  a3  a6  ...  a1  a4  a7  ...
 a2  a5  a8  ...
2.3n1
Since the required ratio is n1  2
3
73. (3)
Let Ai  i  1,2,3,4  be the event that the urn contains 2,4,5 or 4 white balls and B
the event that two white balls are drawn.
We have to find P  A4 / B  .
Since the four events A1 , A2 , A3 , A4 are equally likely, we have
1
P  A1   P  A2   P  A3   P  A4   .
4
P  B / A1  is the probability of event that the urn contains 2 white balls and both
have been drawn.
2
C2 1
Hence P  B / A1   5
 .
C2 10
3
C2 3
Similarly P  B / A2   5
 .
C2 10
4 5
C2 6 3 C2
P  B / A3   5
  and P  B / A4   5
 1.
C2 10 5 C2
 by Baye’s theorem
P  A4  P  B / A4 
P  A4 / B   4
 P  A1  P  B / Ai 
i 1
  by Baye’s theorem
1
P  A4  P  B / A4  .1 1
P  A4 / B   4  4 
1 1 3 3  2
 P  A1  P  B / Ai      1
i 1 4  10 10 5 
74. (8)
Let A denote the event that he candidate A is selected and B the event that B is
selected. It is given that P  A  .5
75. (7)
Here total number of ways n  63  216 . To find favourable number of ways, we
have to find the sum of coefficients of powers of x less than 9 in the expansion
3
 x  x  x  x  x  x  and subtract this sum from 216.
2 3 4 5 6

3
Now  x  x  x  x  x  x 
2 3 4 5 6

3
 x 1  x  x  x  x  x 
3 2 3 4 5

3 3
x 1  x  x  x  x  x  1  x 
3 2 3 4 5
6 3 3
 x 1  x  1  x 
3
3

1 x  

 x 3 1  3 x 6  3 x12  x18   1  3 x  6 x 2  ... 
 r  1 r  2  x r  ...

 2 

  x 3  3 x 9  3 x15  x 21   1  3 x  6 x 2  ... 
 r  1 r  2  x r  ... …(1)
2 
 
So,

Coeff. of x8  1 
 5  1 5  2   21
2

Coeff. of x 7  1 
 4  1 4  2   15
2

Coeff. of x 5  1 
 2  1 2  2   6
2

Coeff. of x 4  1 
1  11  2   3
2
3
and Coeff. of x  1.
[Note that to obtain the coefficient of x 3 , we put r  5 in the second bracket an
multiply this Coeff. of x 5 (i.e.1) in the first bracket etc.]
Sum of these coefficients  56
Hence the favourable number of ways.
m  216  56  160