SAFETY DATA SHEET

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Annex II
Falcon
Revision Date 16-Apr-2020 Version 3 Product No HRB00865-44
Publish Date 16-Apr-2020 AG-P6-100 EC_ADM.06350.H.1.A***

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier

Falcon
Synonyms Propaquizafop 100 EC
Pure substance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Herbicide

Uses advised against No information available

1.3. Details of the supplier of the safety data sheet

Supplier Address ADAMA Agricultural Solutions UK Ltd

Third Floor East
1410 Arlington Business Park
Theale
READING
RG7 4SA
Tel: 01635 860555
Fax: 01635 861555

For further information, please contact

Email address [email protected]

1.4. Emergency telephone number

Emergency Telephone National Chemical Emergency Centre (UK):

Tel: 01865 407333 (24 hours)
National Poisons Information Centre (Republic of Ireland)
Tel: 01 809 2166 (8am – 10pm 7 days a week)***

Section 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Aspiration hazard Category 1*** - (H304)***

Serious eye damage/eye irritation Category 2*** - (H319)***

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Hazardous to the Aquatic Category 2*** - (H411)***
Environment - Chronic Hazard

2.2. Label elements

Labeling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms

Signal word Danger***

Hazard Statements H304 - May be fatal if swallowed and enters airways

H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects***

Precautionary Statements P102 - Keep out of reach of children

P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P331 - Do NOT induce vomiting
P501 - Dispose of contents/ container to an approved waste disposal plant***

EU Specific Hazard Statements EUH066 - Repeated exposure may cause skin dryness or cracking
EUH401 - To avoid risks to human health and the environment, comply with the instructions
for use***
EUH208 - Contains Propaquizafop. May produce an allergic reaction.***
Additional phrases for PPP SP1 - Do not contaminate water with the product or its container (Do not clean application
equipment near surface water/Avoid contamination via drains from farmyards and roads).

2.3. Other hazards

No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixture***

Chemical Name Weight-% CAS No EC No Index No Classification according to M-Factor REACH

Regulation (EC) No. Registration
1272/2008 [CLP] Number
Propaquizafop*** 7-12 111479-05-1 - - Skin Sens. 1 (H317) -
Aquatic Acute 1 (H400) M=1
Aquatic Chronic 1 (H410) M=1***

Hydrocarbons, 40-45 N/A 922-153-0 - Asp. Tox. 1 (H304) 01-2119451097

C10-C13, aromatics, Aquatic Chronic 2 (H411) -39-0001
<1% naphthalene*** (EUH066)

Alcohols, C11-14-iso-, 34-38 78330-21-9 500-027-2 - Acute Tox. 4 (H302) -

C13-rich, ethoxylated Eye Dam. 1 (H318)
(7-15 EO)*** Aquatic Chronic 3 (H412) ***
Propylene 7-12 108-32-7 203-572-1 607-194-00-1 Eye Irrit. 2 (H319) 01-2119537232
carbonate*** -48-0001

Full text of H- and EUH-phrases: see section 16

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Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

General advice In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible). First aider: Pay attention to self-protection!.***

Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Call
a physician.***

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Consult a physician if necessary.***

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing. Call a physician
immediately.***

Ingestion Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center
immediately.***

Self-protection of the first aider Use personal protective equipment as required.***

4.2. Most important symptoms and effects, both acute and delayed

Symptoms None known.

4.3. Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.***

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media

No information available.

5.2. Special hazards arising from the substance or mixture

No specific hazard known.

5.3. Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary***

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions
Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Evacuate personnel to safe
areas.***

For emergency responders

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Use personal protection recommended in Section 8.

6.2. Environmental precautions

Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary
sewer system.***

6.3. Methods and material for containment and cleaning up

Take up mechanically, placing in appropriate containers for disposal.

6.4. Reference to other sections

Other Information
See also section 8,13

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling

Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with skin, eyes or
clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Use with local exhaust
ventilation.***

General Hygiene Considerations

When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact
with skin, eyes or clothing. Wash hands thoroughly after handling. Keep away from food, drink and animal feeding stuffs. Wash
contaminated clothing before reuse.***

7.2. Conditions for safe storage, including any incompatibilities

Keep out of the reach of children. Keep container tightly closed in a dry and well-ventilated place. Keep containers tightly closed in
a cool, well-ventilated place. Keep in properly labeled containers.***

7.3. Specific end use(s)

Risk Management Methods (RMM)

The information required is contained in this Material Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

8.2. Exposure controls

Engineering Controls Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Eye/face protection Tight sealing safety goggles.

Hand Protection Suitable chemical resistant gloves (EN 374) also with prolonged, direct contact
(recommendation: protection index 6, corresponding > 480 minutes Permeability time
(permeation) according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5
mm), butyl rubber (0.7 mm).

Body Protection Use suitable protective clothing and equipment if required, such as safety goggles certified
to EN 166, gloves certified to EN 374, protective boots certified to EN 13832, and/or a water
repellent woven coverall with 65% polyester and 35 % cotton.

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Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and
clothing is recommended. Avoid contact with skin, eyes or clothing. Wash hands thoroughly
after handling. Keep away from food, drink and animal feeding stuffs. Wash contaminated
clothing before reuse.***

Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water. Local authorities
should be advised if significant spillages cannot be contained. Prevent product from
entering drains.***

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Property Values Method Remarks

Appearance
Physical state : Liquid
Color : amber
Odor : Aromatic
Odor threshold : *** *** No data available***
pH : 4 - 7*** CIPAC MT 75.3 ***
Melting point/freezing point °C : .*** *** Not Applicable
Boiling point/boiling range °C : .*** *** No data available***
Flash point °C : 102.6 CIPAC MT 12
Evaporation rate : .*** *** Not Applicable***
Flammability (solid, gas) : *** *** Not Applicable***
Upper/lower flammability or : .*** *** No data available***
explosive limits
Vapor pressure kPa : .*** *** Not Applicable
Vapor density : .*** *** No data available***
Relative density : 0.99 - 1.09 CIPAC MT 3.3 20 °C
Solubility(ies) mg/l : .*** *** Not Applicable
Partition Coefficient : See Section 12 for more
(n-octanol/water) Log Pow information
Autoignition temperature °C : 410 EEC A.15
Decomposition temperature °C : .*** *** No data available***
Kinematic viscosity mm2/s 40 °C : 16.2 OECD 114
Explosive properties : Not an explosive EEC A.14
Oxidizing properties : Not oxidizing EEC A.21***

9.2. Other information

Bulk density g/ml : .*** *** Not Applicable
Surface tension mN/m : 26.9 EEC A.5 25°C

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

No data available.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

None under normal processing.

10.4. Conditions to avoid

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Heat, flames and sparks.

10.5. Incompatible materials

No information available

10.6. Hazardous decomposition products

None under normal use conditions.

Section 11: TOXICOLOGY INFORMATION

11.1. Information on toxicological effects

Acute toxicity
Values Species Method Remarks
Oral LD50 mg/kg : > 2000 Rat OECD 423
Dermal LD50 mg/kg : > 2000 Rat OECD 402
Inhalation LC50 mg/l/4h : > 5.15 Rat OECD 403
Skin corrosion/irritation : Non-irritating to the skin Rabbit OECD 404
Serious eye damage/eye irritation : Irritating to eyes Rabbit OECD 405
Respiratory/skin sensitization : Not a skin sensitizer Guinea pig OECD 406

Chronic toxicity

Germ cell mutagenicity

Chemical Name
Propaquizafop*** : Not classified

Carcinogenicity .
Chemical Name
Propaquizafop*** : Not Carcinogenic

Reproductive toxicity .
Chemical Name
Propaquizafop*** : Not toxic for the reproductive system

STOT - single exposure

Chemical Name
Propaquizafop*** : No data available

STOT - repeated exposure

Chemical Name
Propaquizafop*** : No data available

Aspiration hazard
Chemical Name
Propaquizafop*** : No data available***

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Aquatic toxicity

Acute toxicity Values Species Method Remarks

Fish 96-hour LC50 mg/l : 6.53 Rainbow trout*** OECD 203
Crustacea 48-hour EC50 mg/l : 12.9 Daphnia magna OECD 202
Algae 72-hour EC50 mg/l : 2.99 D. Subspicatus OECD 201

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Other plants EC50 mg/l : No data available***

Chronic aquatic toxicity Values Species Method Remarks

Fish NOEC mg/l : No data available
Crustacea NOEC mg/l : No data available
Algae NOEC mg/l : 1.25*** green Algae*** OECD 201***
Other plants NOEC mg/l : No data available

Terrestrial Toxicity
Birds Oral LD50 mg/kg
Chemical Name
Propaquizafop*** : > 2000 Bobwhite quail*** EPA 71-1******

Bees Oral LD50 μg/bee

Chemical Name
Propaquizafop*** : >20*** Apis mellifera*** Acute oral toxicity*** Not toxic to bees;
Maximum attainable
concentration******

12.2. Persistence and degradability

Abiotic Degradation Values Method Remarks

Water DT50 days
Chemical Name
Propaquizafop*** : 32 EPA-FIFRA 161-2/3 pH 7, 25 ° C

Soil DT50 days

Chemical Name
Propaquizafop*** : < 3 days*** 20*** °C***

Biodegradation
Chemical Name
Propaquizafop*** : Not readily biodegradable OECD 301 B

12.3. Bioaccumulative potential

Partition Coefficient Values Method Remarks

(n-octanol/water) Log Pow
Chemical Name
Propaquizafop*** : 4.78 OECD 117 25° C

Bioconcentration factor (BCF)

Chemical Name
Propaquizafop*** : 583*** (Whole fish***)*** Low potential for
bioaccumulation in
aquatic
organisms******

12.4. Mobility in soil

Adsorption/Desorption Values Method Remarks

Chemical Name
Propaquizafop*** : 1028.60*** OECD 106****** KOC

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB

12.6. Other adverse effects

No information available.

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Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues/unused Disposal should be in accordance with applicable regional, national and local laws and
products regulations.

Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal.

Other Information Waste codes should be assigned by the user based on the application for which the product
was used.***

Section 14: TRANSPORTATION INFORMATION

IMDG/IMO
14.1 UN/ID No * 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Propaquizafop
Hydrocarbons, C10-13, aromatics, <1% naphthalene, )
14.3 Hazard Class 9
14.4 Packing Group III
14.5 Marine pollutant Yes
14.6 Special precautions for user

RID/ADR
14.1 UN/ID No * 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Propaquizafop
Hydrocarbons, C10-13, aromatics, <1% naphthalene, )
14.3 Hazard Class 9
14.4 Packing Group III
14.5 Environmental hazard Yes
14.6 Special precautions for user
14.7 Tunnel restriction code -

ICAO/IATA
14.1 UN/ID No * 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Propaquizafop
Hydrocarbons, C10-13, aromatics, <1% naphthalene, )
14.3 Hazard Class 9
14.4 Packing Group III
14.5 Environmental hazard Yes
14.6 Special precautions for user
14.7 Transport in bulk according to Not Applicable
Annex II of MARPOL 73/78 and the
IBC Code

* Note: UN3077 & UN3082 – These products may be transported as non-dangerous goods under the special provisions of IMDG
Code 2.10.2.7; ADR SP375 and ICAO/IATA A197 when packed in single or inner packaging of up to 5L for liquids or 5 kg or less
for solids.

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Section 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Trade name Registration number Registration date

Not Applicable Not Applicable Not Applicable

15.2. Chemical safety assessment

A chemical safety assessment according to regulation (EC) No. 1907/2006 is not required. A risk assessment was performed
according to directive (EC) No. 91/414 or according to regulation (EC) No. 1107/2009.

Section 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3
H302 - Harmful if swallowed
H304 - May be fatal if swallowed and enters airways
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
H411 - Toxic to aquatic life with long lasting effects
H412 - Harmful to aquatic life with long lasting effects
EUH066 - Repeated exposure may cause skin dryness or cracking***

List of Acronyms
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CAS Number - Chemical Abstracts Service number
EC Number - EINECS and ELINCS Number
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
OECD - Organization for Economic Co-operation and Development
PBT - Persistent, Bioaccumulative and Toxic substance
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
STOT - Specific Target Organ Toxicity
vPvB - Very Persistent and Very Bioaccumulative

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

Revision Note Changes made to the last version are labeled with this sign ***.

Process of classification evaluation in accordance with CLP regulation.

Classification of the mixture Classification procedure

H304 - May be fatal if swallowed and enters airways Classification based on test data
H319 - Causes serious eye irritation Classification based on test data
H411 - Toxic to aquatic life with long lasting effects*** Classification based on Calculation method***

Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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