Frescon Academy

Subject : Chemistry Paper Set : 1

Standard : 11 Structure of Atom Date : 12-11-2024
Total Mark : 180 Time : 0H:45M

(10) The frequency of a wave of light is 12 × 1014 s−1 . The wave

............ Chemistry - Section A (MCQ) ............
number associated with this light is
(A) 5 × 10−7 m (B) 4 × 10−8 cm−1
(1) Anode rays were discovered by
(A) Goldstein (B) J. Stoney (C) 2 × 10−7 m−1 (D) 4 × 104 cm−1
(11) Calculate the energy in joule corresponding to light of
(C) Rutherford (D) J.J. Thomson
wavelength 45 nm. (Planck’s constant, h = 6.63 × 10−34 J s,
(2) The minimum real charge on any particle which can exist is speed of light, c = 3 × 108 m s−1 )

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(A) 1.6 × 10−19 Coulomb (B) 1.6 × 10−10 Coulomb (A) 6.67 × 1015 (B) 6.67 × 1011
(C) 4.8 × 10−10 Coulomb (D) Zero

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(C) 4.42 × 10−15 (D) 4.42 × 10−18
(3) The nature of anode rays depends upon (12) The size of nucleus is of the order of
(A) Nature of electrode (A) 10−12 m (B) 10−8 m
(B) Nature of residual gas (C) 10−15 m (D) 10−10 m
(C) Nature of discharge tube (13) Magnitude of K.E. in an orbit is equal to
(D) All the above ad
(4) The total number of neutrons in dipositive zinc ions with
mass number 70 is
(A) Half of the potential energy
(B) Twice of the potential energy
(C) One fourth of the potential energy
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(A) 34 (B) 40
(D) None of these
(C) 36 (D) 38
(14) The most probable radius (in pm) for finding the electron in
(5) Which of the following are isoelectronic with one another He+ is
(A) N a+ and N e (B) K + and O (A) 0.0 (B) 52.9
(C) N e and O (D) N a+ and K +
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(C) 26.5 (D) 105.8

(6) The frequency of an electromagnetic radiation is 2 × 10 Hz. 6
(15) When α-particles are sent through a thin metal foil, most of
What is its wavelength in metres (Velocity of light
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them go straight through the foil because (one or more are

= 3 × 108 ms−1 ) correct)
(A) 6.0 × 1014 (B) 1.5 × 104 (A) Alpha particles are much heavier than electrons
(C) 1.5 × 102
(D) 0.66 × 10 −2
(B) Alpha particles are positively charged
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(7) The energy of a radiation of wavelength 8000 A is E1 and (C) Most part of the atom is empty space
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energy of a radiation of wavelength 16000 A is E2 . What is (D) Alpha particles move with high velocity
the relation between these two
(A) E1 = 6E2 (B) E1 = 2E2 (16) When an electron jumps from L to K shell
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(C) E1 = 4E2 (D) E1 = 1/2E2 (A) Energy is absorbed

(8) The frequency of yellow light having wavelength 600 nm is (B) Energy is released
(A) 5.0 × 1014 Hz (B) 2.5 × 107 Hz (C) Energy is sometimes absorbed and sometimes released
(C) 5.0 × 107 Hz (D) 2.5 × 1014 Hz (D) Energy is neither absorbed nor released
(9) A metal surface is exposed to solar radiations (17) The number of unpaired electrons in the F e2+ ion is
(A) The emitted electrons have energy less than a maximum (A) 0 (B) 4
value of energy depending upon frequency of incident
radiations (C) 6 (D) 3

(B) The emitted electrons have energy less than maximum (18) Electron occupies the available orbital singly before pairing
value of energy depending upon intensity of incident in any one orbital occurs, it is
radiation (A) Pauli’s exclusion principle (B) Hund’s Rule

(C) The emitted electrons have zero energy (C) Heisenberg’s principle (D) Prout’s hypothesis

(D) The emitted electrons have energy equal to energy of (19) The maximum probability of finding an electron in the dxy
photos of incident light orbital is

1
 (A) Along the x− axis (30) The radius of which of following orbits is same as that of
first orbit of H− atom ?
(B) Along the y− axis (A) He+ (n = 2) (B) Li+2 (n = 2)
(C) At an angle of 45o from the x and y− axes (C) Li+2 (n = 3) (D) Be+3 (n = 2)
(D) At an angle of 90o from the x and y− axes (31) Angular momentum of electron in second shell of Li+2 ion is
(20) Which quantum number is not related with Schrodinger (A) 6.62 × 10−34 J sec (B) 3.31 × 10−27 erg. sec.
equation
(C) 1.054 × 10−27 erg. sec. (D) 2.108 × 10−27 erg. sec.
(A) Principal (B) Azimuthal
(32) The potential energy of electron in third excited state of
(C) Magnetic (D) Spin He+ ion is ............. eV
(21) Be′ s 4th electron will have four quantum numbers (A) −12.08 (B) −3.4
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(C) −6.8 (D) −1.7
(A) 1 0 0 +1/2 (B) 1 1 +1 +1/2
(33) The frequency of first line of paschen series in spectrum of
(C) 2 0 0 −1/2 (D) 2 1 0 +1/2 Be+3 ion is
(22) The uncertainty in momentum of an electron is (A) 7RC
9 (B) 7RC
144
1 × 10−5 kg − m/s. The uncertainty in its position will be
(h = 6.62 × 10−34 kg − m2 /s) (C) 9RC
25 (D) 20RC
9

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(A) 1.05 × 10−28 m (B) 1.05 × 10−26 m (34) What will be the ratio of wavelength of third line of Balmer
series in He⊕ ion spectrum to the first line of balmer series
(C) 5.27 × 10−30 m (D) 5.25 × 10−28 m

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in Li+2 ion spectrum
(23) The uncertainty in the position of a moving bullet of mass 10 (A) 5 : 3 (B) 125 : 189
gm is 10−5 m. Calculate the uncertainty in its velocity
(C) 27 : 20 (D) 125 : 84
(A) 5.2 × 10−28 m/sec
(35) The shortest wavelength of He+ ion in Balmer series is x,
(B) 3.0 × 10−28 m/sec then longest wavelength in the paschen series of Li2+ is
(C) 5.2 × 10−22 m/sec
(D) 3 × 10−22 m/sec
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(24) If wavelength of photon is 2.2 × 10−11 m, h = 6.6 × 10−34
(A) 36x
(C)
5
9x
5
(B) 16x
(D)
7
5x
9
(36) If ratio of Area of two orbits of H atom is 4 : 1 then the ratio
J − sec, then momentum of photon is of frequency of e− in these two orbits is
Ac
√

(A) 3 × 10−23 kg ms−1 (A) 81 (B) 2 1 2

(B) 3.33 × 1022 kg ms−1 (C) 1

√
2 2
(D) 1
8
(37) The volume occupied by the nucleus is about______times
(C) 1.452 × 10−44 kg ms−1
of the volume of an atom.
(D) 6.89 × 1043 kg ms−1 (A) 10−15 (B) 1015
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(25) An electron has kinetic energy 2.8 × 10−23 J. de-Broglie (C) 10−12 (D) 10−10
wavelength will be nearly(me = 9.1 × 10−31 kg)
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(38) Choose the correct statement

(A) 9.28 × 10−4 m (B) 9.28 × 10−7 m
(A) Electronic energy is positive
(C) 9.28 × 10−8 m (D) 9.28 × 10−10 m
(B) ψ 2 represents the probability of finding an electron per
(26) What will be de-Broglie wavelength of an electron moving unit volume
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with a velocity of 1.2 × 105 ms−1

(C) ψ represents the probability of finding an electron
(A) 6.068 × 10−9 (B) 3.133 × 10−37
(D) none of the above is correct
(C) 6.626 × 10−9 (D) 6.018 × 10−7
(39) The set of quantum numbers not applicable for an electron
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(27) The frequency of radiation emitted when the electron falls

from n = 4 to n = 1 in a hydrogen atom will be in an atom is
(Given h = 6.625 × 10−34 Js) :- (A) n = 1, l = 1, ml = 1, ms = +1/2
(A) 3.08 × 1015 s−1 (B) 2.00 × 1015 s−1 (B) n = 1, l = 0, ml = 0, ms = +1/2
(C) 1.54 × 10 15 −1
s (D) 1.03 × 10 15 −1
s (C) n = 1, l = 0, ml = 0, ms = −1/2
(28) The energies E1 and E2 of two radiations are 25 eV and
(D) n = 2, l = 0, ml = 0, ms = +1/2
50 eV respectively. The relation between their wavelengths
i.e., λ1 and λ2 will be (40) A 3p orbital has
(A) λ1 = λ2 (B) λ1 = 2λ2 (A) Two spherical nodes
(C) λ1 = 4λ2 (D) λ1 = 1/2λ2 (B) Two non-spherical nodes
(29) If λ0 and λ be threshold wavelength and wavelength of
(C) One spherical and one non-spherical nodes
incident light, the velocity of photoelectron ejected from
the √metal surface is √ (D) One spherical and two non-spherical nodes
(A) 2h
m (λ 0 − λ) (B) m (λ0 − λ)
2hc
(41) When the value of the principal quantum number n is 3, the
√ ( ) √ ( ) permitted values of the azimuthal quantum numbers l and
(C) 2hc λ0 −λ
m λλ0 (D) 2h
m
1
λ0 − 1
λ
the magnetic quantum numbers m , are lm

2
 lm
0 0
(A) +1, 0, −1 +1, 0, −1
+2,+1,0,−1,−2 +2,+1,0,−1,−2

1 0
(B) 2 +1, 0, −1
3 +3, +2, 0, −1, −2

1 0
(C) 2 1, 2, 3
1 +3, +2, +1, −2, −3

1 0
(D) 2 0, 1, 2

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1 0, 1, 2, 3

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(42) The number of subshells associated with n = 4 and m = −2
quantum numbers is :
(A) 4 (B) 8
(C) 16 (D) 2
(43) The number of angular nodes and radial nodes in 3s orbital
are
(A) 0 and 1, respectively
(C) 1 and 0, respectively
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(B) 0 and 2, respectively
(D) 3 and 0, respectively
(44) The order of filling of electrons in the orbitals of an atom will
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be
(A) 3d, 4s, 4p, 4d, 5s (B) 4s, 3d, 4p, 5s, 4d
(C) 5s, 4p, 3d, 4d, 5s (D) 3d, 4p, 4s, 4d, 5s
(45) The quantum number which may be designated by s, p, d
and f instead of number is
n

(A) n (B) l
(C) ml (D) ms
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