To determine the concentration in terms of molarity of KMnO, by titrating it against (0.1 M) standard solution-of oxalic acid. To determine the concentration in terms of molarity of KMnO, by titrating it against | 09 ~ (0.1 M) standard solution of ferrous ‘ammonium sulphate. To study the effect of concentration on rate 3 of reaction between Na,S,0, and HCl. 4 To study the effet of temperature on rate of reaction between Na,S,0, and HCl. 5 To study the rate of reaction between KIO, and Na,$,0, using starch as an indicator. Study of variation of cell potential of cell Zn|Zn*"||Cu*|Cu with change in concentration of electrolyte CuSO, and ZnSO, at room temperature. To determine enthalpy of dissolution of 7 | CuS0,.5H,0 in water at room temperature. g__ To determine enthalpy of neutralization of HCI and NaOH. g To determine enthalpy change of displacement of Cu from CuSO, by Zn. 19 | To determine enthalpy change during the interaction between acetone and chloroform To prepare a pure sample of ferrous ammonium sulphate. 12 | To prepare a pure sample of potash alum. To prepare a pure sample of potassium trioxalatoferrate (III) complex.To prepare dibenzalacetone. To prepare 2-naphthol aniline dye. To prepare acetanilide from acetyl chloride. To prepare p-nitro acetanilide from group Test for functional group present in given yy organic compound. Characteristic tests of carbohydrates, proteins, fats and oil in pure samples and their detection in given food stuffs. (Any one of each) Characteristic tests of carbohydrate, tz proteins, fats and oils. Detection of two acidic radicals qualitatively from given inorganic salt mixture. ‘The given inorganic salt mixture no.1 contains following tw acidic radicals. 93 i 027.0 cllontde- ) 60g Sulphate ) The given inorganic salt mixture no.2 following two acidic radicals. x Carbonate ) iiMOg-( Auckrate _) The given inorganic salt mixture no.3 following two acidic radicals. 0.0): 20 Detection of two basic radicals qualitatively from given inorganie salt mixture my The given inorganic salt mixture no.1 cont s following two basic radicals. oC Ammon! um ) ii iad * Barturo ) The given inorganic salt mixture no.2 containg following {wo basic radicals. i PBT Lea ) Gath calelum _) | The given inorganic salt mixture no.3 Wt contajgs following two, basic radicals. 2s (ALB Cadumini uv ) mgt magnes tur) 23 114 24Preparation of phthalic anhydride from phthalic acid. 120 Preparation of succinic anhydride from |p. 9 9 succinic acid. Preparation of methy| salicylate. 124 Measurement of e.m.f. of commercial cells 9 6 by using voltmeter. (Any four cells) Identification of Resin identification code (RIC) on given different plastic materials. (Any two plastic material) Preparation of 100 mL 0.1 M standard solution of ferrous ammonium sulphate. (Mohr’s salt) 130 Read instructions of do's and dont's carefully. Record your observations and calculations on sapce provided in the notebook. Take signature of the batch incharge after completion of experiment on same day. Read carefully the begining of each section, a concise explanatory account of theoretical experiments has been given. Solve exercise of each experiment after completion of experiment on same day. Use given space provided after each experiment for notes, rough work and rough calculations and then fair it to main experiment ‘A Scheme of marking for practical examination is given on page no. 143 for accurate working. ‘A format of question paper for annual practical examination is given for your information on page no. 145. At the end, tables of logarithums is given for calculation. ‘At the end, tables for preparation of different concentration solutions ‘and reagents are given in appendix I to V.Aim: To determine the concentration in terms of molarity of KMnO, solution by titrating it aganist standard solution of oxalic acid. ‘Theory: The substances available in the staté of high purity are used to prepare standard solutions by dissolving a fixed/definite mass in definite volume of distilled water. Oxalic acid is a primary standard substance. Its molar mass is 126 g/mol. ‘A. Preparation of standard solution of oxalic acid ‘Molar mass of oxalic acid (H,C,0,.2H,0) is 126 g/mol For 1000 mL I M oxalic acid solution required mass is 126 g of oxalic acid Hence for 100 mL of 0.1 M oxalic acid the required mass is 126 x 100 = 0.1 1000 * 1 = 1.26 g of oxalic acid Apparatus: 100 mL standard flask, balance, watch glass, beaker, glass rod, etc. Chemicals: Oxalic acid, distilled water. Procedure: 1. Weigh accurately 1.26 g oxalic acid on watch glass. 2. Transfer the weighed oxalic acid to a beaker and wash the watch glass with distilled water and transfer washings to the beaker. Add little distilled water to dissolve it by stirring. 3. Transfer the solution of oxalic acid from beaker to 100 mL standard flask. Wash beaker twice with water and transfer washings to the 100 mL standard flask. Dilute the solution up to the mark on standard flask to make volume 100 mL. B. Determination of molarity of KMnO, solution using standard solution of oxalic acid. Apparatus: Burette, pipette, conical flask, burner, water bath, etc. Chemicals: KMnO, solution, 0.1 M oxalic acid, 2M H,SO,. Procedure: 1. Wash the burette, pipette and conical flask with water. 2. Rinse the burette with given KMnO, solution and then fill it. Remove air bubble from the nozzle and avoid leakage if any. 3. Adjust the level of KMnO, solution in burette up to zero mark with upper meniscus and fix it on a burette stand. Rinse the pipette with standard 0.1 M oxalic acid solution. Pipette out 10 mL of 0.1M oxalic acid solution and transfer into clean conical flask. Then add one test tube 2M sulphuric acid. (The solution remains colourless) 6. Heat the conical flask up to 60 to 70°C on wire gauze or water bath (as reaction at room temperature is very slow) 7. Place the conical flask with hot solution on a white porcelain tile below the burette. 8. Start adding KMnO, solution drop wise from burette in a conical flask with continuous stirring till light/faint pink colour is obtained in conical flask. Keep the flask constant shaking in a circular manner. This is called swirling of solution. See that the colour does not disappear even on vigorous shaking. This is end point of titration, 9.» Note this reading as ‘Pilot reading’ (pilot reading is always in whole number.) 10. Now fill the burette again with KMnO, solution up to the zero mark with upper meniscus. 11. Repeat the above procedure and take minimum three more correct burette readings. 12. Note down the constant burette reading ...........(x) mL (C.B.R.) 13. From C.B.R, calculate the molarity of given KMnO, solution. ®D a+Observations: 1. Solution ina burette :.KIM.OS. 2. Solution by apipette oaate..ccctol ; 3, Solution in conical flask Ozalic.ccecd., Itest tthe dil.tyso., 4, Indicator Keomogbksels , 5. End point Colorless. £0 Zant pink, 6. Chemical Equation: 2KMnO, + SH,C,O, + 3H,SO, —» K,SO, + 2MnSO, + 8H,O + 10C0,* Observation Table: I I i Final ol Led Lr) Lon) Tnitial 00 00 0.0 Difference mL rad | baa) | DLA. Calculation: From above chemical equation 2KMn0, + SH,C,O, + 3H,S0, —» K,SO, + 2MnSO, + 8H, + 10CO, 2moles 5 moles 2x 158 g (316 g) = 1000 mL 5 M (molar mass of KMnO, = 158 g/mol) ©. 1000 mL 5 M oxalic acid = 316 g of KMnO, 316 x 10x 0.1 -. 10 mL 0.1 M oxalic acid = 7999 x5 = 0.0632 g of KMnO, ~. Hence IL)..(x) C.B.R. mL of KMnO, solution contains = 0.0632 g of KMnO, i 0.0632 x 1000 | o-_, an - 1000 mL of KMnO, contains = “TFTA = SeLGS GEE. 0.0632 x 1000 Space for log calculation Number. log Hence molarity of KMnO, in the solution isSelect [V] the most appropriate answer from given alternatives of each sub question. 1. The molar mass of oxalic acid is a. 1260 Ue. 126 g/mol c.12.6u d. 12.6 g/mol 2. Toprepare 1 M solution of oxalic acid var 126 g of oxalic acid dissolve in distilled water and diluted to 1 L b. 12.6 g of oxalic acid dissolve in distilled water and diluted to 1 L c. 1.26 g of oxalic acid dissolve in distilled water and diluted to 1 L d..0.126 g of oxalic acid dissolve in distilled water and diluted to 1 L 3. Water of crystallization present in oxalic acid is/are. al vbr? 3 as 4. Oxalic acid is used to prepare standard solution because it is a... a, substance vb: primary standard substance c. secondary standard substance _d. tertiary standard substance 5. The quantity of oxalic acid required to prepare 0.1 M 100 mL standard solution of oxalic acid is a. 126g b. 12.69 ve: 1.26 d.0.126g L ia ant oe ena C=12,0= 16) Ans Modecelar..joamiula..o7.ecaticactd.£8..Hg6e04:.%H,0. om pecan mass. qaralie, acid. slcanot(eniao 4 lanieot (2x89) a F.QRALBALG ABE wae: 2.126... Gf D0b.: 2. Why heating ig required in oxalic acid and paaaiat permanganate titration? An@ikb avasd-canvers, 310: 0.9, pink COlaue. {NEO AROWD.60/D.... @ R.oneéd... raceelege omaliic atid, tt 1's heated at certain aie dmataenceeed i onal b on ab C.. ceva. Verses. TING ¥ 3. Why one test tube of 2M sulphuric acid is required in permanganate titration? Ans...CM@,.£0bE s6ttb€... Pie HyS 0g, 8... 204 ULERX€...k>.. PERIOD: Peuroongeate ETERONDON..bECOLSE EO. poencen es ged bioks -qymangneses to 502M... PIMA... 4 ‘What is the oxidation state: ofcarbon atom in oxalic acid after completion of redox titration? Ans.oretdahion..cbake..9,.carbhosp..ctoxn.. porate. cast. o| 2», oan g-neale Sieachon 8. ey 5. Why primary oe fais ‘are used to make standard solutions? i (eee eee ubstances..aré..Lised.comake atd..80/2 . eCOULSE. have. doww.22eachvi ence sed: 1809. pea acd 5 asthe ae Remark and sign of teacher:‘Aim: To determine the concentration in terms of molarity of KMnO, solution by titrating it against standard solution of ferrous ammonium sulphate.(Mohr’s salt). ‘Theory: The substances available in the state of high purity are used to prepare standard solution by dissolving a fixed/definite mass in definite volume of distilled water. The molar mass of ferrous ammonium sulphate is 392 g/mol. A. Preparation of standard solution of ferrous ammonium sulphate (F.A.S.) Molar mass of ferrous ammonium sulphate (Mohr’s salt) (FeSO,,(NH,),SO,,6H,0) is 392 g/mol For 1000 mL 1 M Mohr’s salt required mass is 392 g of Mohr’s salt. }92 x 100 x 0.1 Hence for 100 mL of 0.1 M Mohr’s salt the required mass is 1000 3.92 g of Mohr’s salt Apparatus: standard flask 100 mL, balance, watch glass, beaker, glass rod, et Chemicals: Ferrous ammonium sulphate, distilled water, sulphuric acid. Procedure : 1. Weigh accurately 3.92 g Ferrous ammonium sulphate on watch glass. 2. Transfer the weighed F.A.S. to a beaker and wash the watch glass with distilled water and transfer washings to the beaker. Add little distilled water to dissolve it by stirring. 3. Transfer the solution of F.A.S. from beaker to 100 mL standard flask. Wash the beaker twice with distilled water and transfer washings to the 100 mL standard flask. Add few drops of H,SO, to get clear solution. Dilute the solution up to the mark on standard flask to make volume 100 mL. B. Determination of molarity of KMnO, solution by using standard solution of BAS. Apparatus: Burette, pipette, conical flask, white porcelain tile, etc. Chemicals: KMnO, solution, 0.1 M F.A.S., 2M H,SO,, Procedure: 1. Wash the burette, pipette and conical flask with water. 2. Rinse the burette with given KMnO, solution and then fill it. Remove air bubble from the nozzle and avoid leakage if any. 3. Adjust the level of KMnO, solution in burette up to zero mark with upper meniscus and fix it on a burette stand. 4, Rinse the pipette with standard 0.1 M F.A.S. solution. 5. Pipette out 10 mL of 0.1M F.A.S. solution and transfer it into a clean conical flask. Then add one test tube 2M sulphuric acid. (The solution remains colourless) 6. Place the conical flask on a white porcelain tile below the burette. 7. Startadding KMn0, solution drop wise from burette in a conical flask with continuous stirring till light/faint pink colour is obtained in conical flask. Keep the flask constant shaking in a circular manner. This is called swirling of solution. See that the colour does not disappears even on vigorous shaking. This is end point of titration. 8. Note this reading as ‘Pilot reading’ (pilot reading is always in whole number.) 9. Now fill the burette again with KMnO, solution up to the zero mark with upper meniscus. 10. Repeat the above procedure and take minimum three more correct burette readings. 11. Note down the constant burette reading ..........(x) mL (C.B.R.) 12. From C.B.R. calculate the molarity of KMnO, solution.Observations: 1. Solution ina burette — :.AROMNA|Ng,. 2. Solution bya pipette: 10.2904... FAS. 3. Solution in conical flask :020041. (AS. + Mths. Hp$0,... 4. Indicator :Kmn.04 Lb8els 5. End point codouirless..£0 yeunt pin 6. Chemical Equation _ : 2KMnO,+ 10FeSO,(NH,),SO, + 8H,SO, 80 ;aNASO + 5Fe,(SO,),+ 10(NH,),SO, + 8 HO Observation Table: ir ” ier. ne I " Ml Final ow, |... 9..804. to ocoou (X) ML Initial 00 0.0 0.0 Difference nfl 9.mod.. | 9.nod..| Qn. Calculation: From above chemical equation 2KMnO,+ 10FeSO,(NH,),SO, + 8H,SO, —> K,SO, + 2MnSO, + 5Fe,(SO,),+ 10(NH,),SO, + 2moles 10 moles 8H,0 2 x 158 = 10 moles of mohr’s salt (molar mass of KMnO, = 158 g) 1000 mL 10M Mohr’s salt = 316 g of KMnO, 316 x 10x 0.1 ~T000* 10 — = 0.0316 g of KMnO, <. 10 mL 0.1M Mohr’s salt = -. Hence Iw CBR mL of KMn0, solution contains = 0.0316 g of KMnO, 0.0316 x 1000 _ 31-6 BYE = 0-022 "1000 mL. of KMnO, contains = 35 CCR «TSE = 1g09 Space for log calculation Hence molarity of KMnO, in the solution is = __0.0316 x 1000 __ | [Number "B..) CBR x 158 log] Result: The molarity of KMnO, solution is ... Remark and sign of teach_ Select [V] the most appropriate answer from given alternatives of each sub question. 1. The indicator used in Redox titration is----- a. phenolphthalein b. methyl orange c. methylene blue \- potassium permanganate 2. Select the titrant used in redox titration «a. oxalic acid b.FAS \verKMnO, d. H,SO, 3. The oxidation state of Mn in KMnO, in redox titration before titration is +7, the oxidation state of Mn after completion of titration is—- ye 42 b. +3 c. +4 di+7 4. The oxidation state of Iron in Mohr’s salt is +2, the oxidation state of Iron after completion of titration is----- a.+l b.42 ve43 a4 5. The role of Mn® ion during oxidation-reduction titration of KMnO, by oxalic acid is--——- a. catalyst br reductant c. oxidant d. reactant . What ane name is given to the permanganate titrations? Che. specie. mare. Us. géven.o, perma make titaabon 1's peamagnedie... dae: 02)... x a Why heating i not sagaites in FAS. and her areas ppireaaaganete titration? Ans feb U8. BOK: shag ubteet | tn. fiAs.vs..Kromneg dtnabon. b e. cca ig... verge aggbs.ak 200m Epnpanliine £0. dekerm ane... AAR... RETO gern 3. Why a dilute sulphuric acid one while io a standard solution of Mohr’s salt? eer De FOrpouts. 1020. Cfett Lom J... Prren.cine: Oath tA AOD. LTHEO. epic due Lo deh» Ho$04.08.added eile Pb pant prepe.atd 20/2. ite BALE....LB.. ORDO. ARQTOOMLUTS.. hake... 4. Calculate the molar mass of Mohr’s salt (Fe=56,S= 32,N= 14,H=1, O=16) Ans. Moleccrlar.feanola be FAS. LS... PS0¢ CN#H3 2359.06. molar mass. Speen aalerk 4 AG HDD. Perea exia]) Oe ssh 5. Calculate the mount of FA. lee to prepare Mn standard solution of FA S. ANS 2 BO or bee QE O42. O$..PD.8 392. dni 1e00. 104. 109 ool 3G.2-K-0-05" ne dg sor. Qs at = 1926 Ff Remark and sign of teacher:Ldentizicabion 3 funchenal ‘eur ‘Compound No.1 (aw aie | Observation "Inference 1. Test for Carboxylic acid group | | SK &2b+ Z Coz | Carboayt group gos eseart __| CG coow#> Substance + 10% NaHCO, solution. functional group. Result: The given organic compound no. ing Structure of functional group | [Name of the functional group ~ Bou ~ Compound No. (Een patna Observation | Inference IiTestTor Carboxylicacid group] N° 289K e3b- casbory! group | Substance + 10% NaHCO, solution. Cog ges wolet reel Dhenoblec CAr-oH) 2. Test for Phenolic group e Colourahon fa" present . Substance + little water + neutral FeCl, tains following functional group. solutior Structure of functional group CoH) phenolic + Compound No.3 [ 7 Test Observation Inference | ] | [TestforCarboxylicacid group) (No Brisk esb-% carboreyt grcup | | Substance + 10% NaHCO, solution. 60g | (2. Test for Phenolic group Mo wlolet /green/ phenoluc C- oH) | Substance + little water + neutral FeCl, Sétee/ ved Qroup absent. solution colournbion dull | Biiestfor Aldehyde group (liquid)| | PtK_ colour Aldehyde (-é-4)| oe 3 Tole’ reagent ond es empress casio Result: The given organic 1 no.3 contains fol unctional group. _ Name | of the functional group Structure of functional group _ a CH oe ~cHO Compound No.4 Inference pes: Test Observation rence i Test for Carboxylic acid group nto brlsk ORD - FB enor peur | | Substance + 10% NaHCO, solution. C0 gas Ti0 No wolet'/g2een/: Phenols C-on) Substance + little water + neutral FeCl, blue colourab'e group absent solution est for Aldehyde group diguid)) No pink colour. Aldehyde C-cHte) Substance + 2-3 mL Schiff’s reagent/ Group absent- Tollen’s reagent and heat Red Colour. Ketonic (>c=0) Substance + few drops of NaOH + present few drops of sodium nitroprusside soln Result: The given organic compound no.4 contains following functional group. Compound No.5 ALO b2esK CBB 7 Carbo: group Cog gas ateend Substance + 10% NaHCO, solution. Alo violet green) phenobilc C-0) blue/ Substance + litle water + neutral FeCl,soln | Cotguzabiony POP Absent . BtestforAldenyde group diquid)) = MO PINK —Afdeyce (e410) Substance + 2-3 mL Schiff’s reagent/| COLOLU. group absent Tollen’s reagent and heat [Westfor Ketone group (liquid) | MO rea] Ketone. Ge=o) Substance + few drops of NaOH+ few, COLO ULE group absent drops of sodium nitroprusside soln R RBLIGFAMIO RON) ane + OPANFE Hed Amino MK) cone. HC! and shake to dissolve. Cool ype SEU Is Prop 19 under tap water, add excess of NaNO,. + - B-naphthol in NaOH poammed presen Result: The given organic compound no.5 contains following functional group.Select |] the most appropriate answer from given alternatives of each sub question. 1. The functional group Preset in Methanal is ...... g 0 / ro ¢ cy b. - d.-N va - Ch, ‘c= ° © CQ MA 2. Identify the functional group or primary amine .-NH, b-N- o\N-H d. NH, Z 3. The distinguishing test between alcohol and phenol is - a. bicarbonate test br neutral FeCl, test c. sodium nitroprusside test d. tollen’s reagent test 4, Primary amines on treatment with excess of NaNO,, concentrated HCI and B-naphthol in, alkaline medium gives a. green colour \beorange colour c. violet colour d. red colour 5. Acetaldehyde when heated with ammonical silver nitrate solution gives ..... a.'red ppt \besilver mirror ¢. red colour 4. grey mirror answer qt i bee Functional group, Spock eds uvhach, olectoles..chernscal. .neachy.ii oe mapds..8..c.atled..as Sunchonal 2. Draw structure of an organic compound having ire fonction crap eran. Ans. an CHa= gta tig C40... @ ctle- - th 3, Give distinguishing test for carboxylic ocld and es Ans QQ)... COOH. +. NAH. COg,.—>.R= COON. + Hy0.cb.COg Gs Cote CHF Fecly. > Cee od, Fe. Cnet colour) 4. If alkaline KMnO, solution is added to an organic compound, it decolorises. Identify ' functional group present in the compound? Ans..D 9. Katine.Kinin.0g.d3.added...£0..0%7 ee are deeoteyie. Be ata fe ads PAO Lop. POSE A 1'90. ‘Soy Compa [email protected] x0 Ce 0Biim CEE Cusatirrabed..hyelrotar a Write a ene reaction for Tollen’s reagent test with ethanal, oes. + 21A8 Cate d9} of ——9 2. Choe COOH. +. 2AGT FEN Acetaldehy olf cn Seta ‘Acelse. acid aiken | mirror - Remark and sign of teacher:Solubility: Substance + Water : To detect the presence of carbohydrates or proteins or fats and oils in the given food stuff. Food stuff for carbohydrates (Perform any two tests) Soluble tm wok Heat gently. Pp. Fehling Test: Little substance +1 | Axéck sed colo carbolyolrate 2 | mL Fehling solution ‘A’ and ‘B’.| Qe2rrmabon 1S present Heat the test tube on a water bath Cconkt2menl Benedict's Test: Litle substance |O2amge weol | Carbo 3 | + add 2 mL Benedict’s reagent. | eg /o¢py oun col | 0S conystrmn sult : The given SAM Pe..9...GeLLLLO.SE,..f00d stuff contains carbohydrates Food stuff for protein (Perform any two tests) Solubility: a, Substance + Water Biuret Test: Substance + 10% | Reolalish vtolet-| protern 1's NaOH + few drops of 1% CuSO, color Comp 27> solution, shake well Xanthoprotic Test: Substance + gellow colour. protein is few drops of cone. HNO, Shake Tif, bruins haies 2 little and leave undisturbed for ond ch onal conpt some time mee en aa a Ninhydrin Test: Substance +) Deep blue proteins 3 | NaOH solution + few drop of eoloursilsom .|Conteuins <-amino Ninhyédrin reagent. Heat. acta - Result: The given. LQF..ahbUtnd70. ..food stuff contains protein. Food stuff for fats and oils (Perform any two tests) ‘b. Substance + chloroform Soluble i'n Hels fat ov oft ts congrmed 2° | Spot Test: Puta drop of substance PE oliggracks ight Fal or oct Us on filter paper & Conprmmed + Aerolein Test: Substance + few puny - worbtab! fak oy of 1% 3 | crystals of potassium bisulphate. | ng “odour Oe . 4g i ie mpiranedl Heat Results The given . 4220444NA..2ILLE..poUude2Food stuff contains fats or oils. Remark and sign of teacherSelect |] the most appropriate answer from given alternatives of each sub question. 1. Fats and oils are ------- a triesters of glycerol and fatty acids b. diesters of glycerol and fatty acids c. glycerol and fatty acids d. glycol and fatty acids 2 are insoluble in water but soluble in acidic or alkaline solutions a. fats er oils c. proteins d. carbohydrates 3. Proteins contain ------- linkage. 1 polypeptide b. polyester c.polypropylene _d. polystyrene 4. Glucose powder when heated with Fehling solution gives------- a. blue ppt Vor red ppt c. green ppt. 4. black ppt 1, What are rr 0. bs Ans carbohydrate ily el achive.....p! Maphagtnorgy Hyclrakes ae ls. cabled, oh carbohydrabes. 2. Write the name of chemical test, when protein in food stuff is treated with concentratet HNO,. Ans. Xanbhoparoter'e, best besk.!~ protetin.gample.+-..cone...t1MQg,..sh dwell, Ebea..Ck. ghves..yellaUo.COLOUA.. disc £2tDS...0.220 3. Write structure of peptide linkage present in proteins. pe adding ee dni —<« . e Soe . A. ¥ 4. Mention Biuret test for proteins in short. i A molicate. Ans POLLO Gample + loy,NabH —+ eh cake, + few drops 31% cusog, shake well” calatun..... -Conly diate P26bein - 5. Write an important difference between oils‘and fats. Ans@eel contains. unsaturated. Batty accel ty atule cole, Gi) ott ane. Ligutel ot.noom.£emp..sladte. jake 28.8 Weeks can be hydropemated wbthe jake cane: be hgdageoate [= ‘and sign of teacher: ~YSelect (“| the most appropriate answer from given alternatives of each sub question. 1. The anion does NOT gives positive test with dil. H.SO, and cone. H.SO, a.cr b. CO, c. CH,COO VSO, 2. When moisten oxalic acid is taken between the fingers, it smells like vinegar, indicates the presence of following anion a. sulphate b.nitrate —_ ceracetate d. nitrite 3. Canary yellow ppt. of ammonium phosphomolybdate indicates the presence of......... radical a. Cr b. SO, ver PO,” d.NO, 4. Smell of rotton eggs of a substance with dil. H,SO, indicates the presence of ........ radical a. SO,” b. $0," ve S* C0, 1. Write the formula of the compound formed in brown ring test. Ans. F&CN.OD. CHO] 904. r BROW. 2LF.COMYPRER 2.0.0. 2. Write the name of the complex formed, when sodium nicroeranets is ‘added to O.S. of mixture in the confirmatory test of sulphide ion. AMS oo MOG. CFEC MOT S Sedum shloneerd. nnnsaldes o. sodium, pentacyno. syemneed sulphake. 3. Write the nomen of anion detected with the help of dil. H,SO,. ans Dhe. anton. detected .tistlh the drelp.9,di't.t1a504.are, 6037 (carbanate) (Go Caubphide)., mébrake. (M03)... sStulphike. ($037), cucebake (cHf06 ) 4, Write the names of anion detected with the help of conc. H,SO,. Ans fhe.anion.detect.wtth bhe help eenc: Hy504..828.ch, DAA xi iin nr . 5. at is lime water _ what of ini on possing CO, gas iticeag i Ans. Coletzumo, bypolroantde (calor, 1's called os dime. wale ».tsher Cog t..passed bregh.lime.waker., Lhe becomes.04LK 4. 6. _ Describe the layer test for iodide ions? Ans.On6itde: HaSeapt chloryeare Chdo.20soam cod OM. = hl aber 190 020085. Re BDAKE oo MUON: presen. 7. How do you test the presence of sulphide ion in dry test. Ans.gamnell. poe nnoten.2gg.wrhich, truns. dead. acekate. paper.black ushich..lndtea.be.. presence. 4, = ($7 7D.ton0... Remark and sign of teacher:Quatitabive. ee Analyst's 4, two acidic. cabs ROD Geren mabe, Aim: Analyse two acidic (anion) radicals qualitatively from given inorganic mixture. Apparatus : Test tubes, test tube holder, test tube stand, filter paper etc. A. Preliminary tests: uslite (colorless) | Abt3, mgtt Batt Kt nuif| be preset i Soules. Nature Crystalline nearbons Ce oe hates, Nut, Alt? ray be’ p26s20) 1, Heating in a dry test tube:~ Take a small quantity of the mixture in a clean and dry test tube and heat it strongly B. Dry Tests for Acidic radicals (Test tube must be dry for following tests) wstuch onsateel Yoditle paper blue No evelublen 4 DS group 2. Action of dil. H,SO,: Take a small sbtic quantity of mixture + dilute H,SO, gs are absent. Bvolublon =r 7g oup ent 3. Action of cone. H,SO, : Take a small |g xeeniah yao $4 cr quantity of mixture + cone. H,SO, eg 4. Action of Cu foils and conc. H,SO, Mixture + Cu filings and cone. H,SO,, heat it strongly No evedlutsea % KL05, I's absew) ges 5. Action of MnO, and cone. H, jneenvsh yellow gas CL” may econ, peel ps Mixture + dil. HCl, boil the solution + BaCl, solution 1. Test for sulphate wobite ppl (nsolulle 605 “may be do cone Hel present . 2. Test for phosphate Mixture + conc. HNO, boil + excess of ammonium molybdate solution Sac! yellow poz? te absent. ppe. C. Preparation of original solution (O.S) : Mixture is dissolved in 20 mL quantity of distilled water in a beaker, stir with glass rod to dissolve the mixture. Clear solution is obtained. Use this O.S. for further tests of acidic radicals.D. Wet Tests for Anion (Acidic Radicals) 1. OS. +AgNO, cohrte ppe er imag be Comp! Soluble present. Wm) Ade If white ppt obtained in above test, perform following distinction test Distinction between CI, Br and’ : chlonozerm La yer a be OS. + dil. H,SO, (till acidic) + chloroform 46 J yyy bess + Cl, water (fresh) in excess, shake . vigorously and observe the colour of chloroform layer carefully. ‘ . Ushtte ppt tnseluble 367 ray be 2. 0S. + Ba(NO,), solution tn oll. #101 03 Doe 3.0.8. + dil. acetic acid + (Freshly prepared) FeSO, solution r ai 4. O.S. + diphenyl amine + cone. H,SO, - = 5.0. + FeCl, solution - = 6.0. + dil. acetic acid + CaCl, - - 7.0.8. + dil, H,SO, + 2-3 drops of KMnO, - oe E. Confirmatory tests for Acidic Radicals _ , 1. CT. for first detected acidic radical... (chLortale) 20-8. + Agnos 2. C.T. for second detected acidic radical 8.04 (Sulphate) + Bacly ) 2.0.8.+ Lead acelrate white ppt nso | ae to obit. HN 03 hat Result :> ‘The given inorganic mixture no. 1 contains following éwo anions (Acidie radicals) 1) GAZ. Oy ChLosetelen) Hi) 80S". Beal phate)Alm: Analyse two acidic (anion) radicals qualitatively from given inorganic mixture. re N (bac 7 7) Apparatus : Test tubes, test tube holder, test tube stand, filter paper ete. A. Preliminary tests: Col y ALT? Rn} 2, Bat? sot: ‘ley white une me roe ‘Nature 7 water Scluble Salhs Crgstatline C6, BS, P™ 50g ~ NCH DAY be PRESEDE B. Dry Tests for Acidic radicals (Test tube must be dry for following tests) 1. Heating in a dry test tube:- etnies ornas C05” 0% Sog- Take a small quantity of the mixture ina 44 ushich t thas be clean and dry test tube and heat it strongly Loe Waterrilky present. y Lees ts. nok. chkalned,. Jom. mekal - Remark and sign of teacher:tue basic aducats Aim: Analyse two basic (cation) radicals qualitatively from given inorganic mixture. Apparatus: Test tubes, test tube holder, test tube stand, filter paper ete. A. Preliminary tests: _= Us __ Observation 1. Heating in a dry test tube:- Take a small quantity of the mixture a clean and in dry test tube and heat it strongly. 2. Charcoal Cavity Test: Stebs tance oy cath Binture * No,CO, slid in 1:2 & tints in ee Nua, cot? rag proportion placed in fresh charcoal be preseat cavity, moisten with a drop of Cavite water, Heat it with blow pipe in a reducing (yellow) flame 3. NaOH Test: Dursvert N 4 Mixture + NaOH solution & heat. bare me ee | NAG roayg bee pres roe Hold moist turmeric paper near Euans the mouth of the test tube 4, Flame Test: Prepare a paste of the given mixture pale green on | Batt rong be pres with conc. HCI on a watch glass. See el loop artis end of| (Pee ee the platinum wire & dip it in the mixture or use glass rod. Heat it on oxidising flame (Blue) observe the colour change of the flame. . Preparation of original solution (O.S) “Take w small quantity of mixture in a beaker add 20 mL of distilled water, stir with glass rod to dissolve the mixture, If mixture does not dissolve completely then warm it to dissolve, Clear solution is obtained, which is used as a O-S for further tests. 1, Analysis of Group zero (NH,") (ite Tes ___ Observatioi "Inference 1.O.S. + NaOH solution + Evolution Nts 444 Group Kero present Heat, test with moist turmeric WHuleh Ecvins oh OP nA Nug snag be present. paper.2.0.8.+NoOH solution+ |Dease white Nila may be prése Heat, Bring a glass rod dipped ‘eum es % Hace in conc. HCl. near the mouth of | the test tube G.I. for NH, + 1, 0.8. + - Meat tte compe : Nessler’s reagent in excess Brown ppt al ts conpiraned ii, OS + Pieric Acid Gellow ppt & — Nad Ue conprmed » (2, 4, 6 trinitro phenol) ammonium picrate Detection of group (if group zero is absent, two groups must be detected following test) absent (pst, 1.08. + dil. HCI Group D 2. 0.S/Filtrate + dil HCl (heat) ALO black ot yellow Group 2 absent + HLS gas or water ppr Ceur?, Ag) OS iltrate (Remove H,S)+ Mo whtke OF yeddith Gaoup IT absent NH,CI (equal) + NH,OH (till hyoro9y eodoured — +3 +3 alkaline to litmus) ppt cau, fet? ) 4.0.8,Filtrate +NH,Cl(equal)|Alo vohtle oP (Groupie absent + NH,OH (till alkaline to black ppe Crosstt, gt? ot? Ni*? J litmus) + H,S gas or water es Sc 5.0.8.Filtrate (Remove HS) | pf pie ppt Gaoup Ww present + NH,Cl (equal) + NH,OH (till alkaline to litmus) Catt sath Bott may +ONH,),CO, be present - 6. OS. /Filtrate + NH,C! (equal) + NH,OH (till alkaline to _— me litmus) + Na,HPO, 2.Analysis of first detected group Bal cat? gxit* may be preseok while ppi Diesolve ppt tn hot CARLboH a Me this sof RS + Rotnog, fellow ppe - Bat? may be Present.3.C.T. for first detected radical OrS- del. 4,80, | Batt 1's conpinmmed 9, OnSs + NMG )y Co Bart's congirmed Result:- The, oe Inorganic mixtere no. I contains following two cations (Basic Radicals) ) sia ¢ AromontumAim: Analyse two basic (cation) radicals qualitatively from given inorgai Apparatus : Test tubes, test tube holder, test tube stand, filter paper etc. A ree tests: Observation Clos: [ete 2 ray be : abe b Se 4M ALS may Inference 1, Heating in a dry test tube:- Bat? .$st*, Batt Take a small quantity of the AN3. gatts be mixture a clean and in dry test present g tube and heat it strongly. “ 2. Charcoal Cavity Test: Subkonces Firses Nid may be Mixture + Na,CO, solid in 1:2 kaye ti conn ae proportion pldcedin fresh charcoal |S S40KS tp CaWtey | p. cavity, moisten with a drop of water. Heat it with blow pipe in a reducing (yellow) flame 3. NaOH Test: Motse turmmerte sunt is absent. Mixture + NaOH solution & heat. paper doesnot Hold moist turmeric paper near | burns ned oF the mouth of the test tube SLB 4, Flame Test: Prepare a paste of the given mixture with conc. HC] on a watch glass. Make a small loop at the end of. the platinum wire & dip it in the mixture or use glass rod. Heat it on oxidising flame (Blue) observe the colour change of the flame. C. Preparation of original solution (O.S) Take a small quantity of mixture in a beaker add 20 mL of distilled water, stir with glass rod to dissolve the mixture. If mixture does not dissolve completely then warm it to dissolve. Clear solution is obtained, which is used as a O.S for further tests. 1. Analysis of Group zero (NH,") yservation, 1.08,+NaOH solution + Mets Eivanerse Heat, test with moist turmeric Deed oloesnot paper. burns red oF Srenc aD iene eb absent Nud vg absent ,2.0.8.+NaOH solution+ |No ucute clemse MHZ 1's absead Heat, Bring a glass rod dipped | ¢-uapes aw thon: HCL wear the mouth of] ee > the test tube. CT. for NH; : i, OS.+ _ _ Nessler’s reagent in excess ii. O.S + Picric Acid (2, 4, 6 trinitro phenol) ‘Detection of group (if group zero is absent, two groups must be detected follo Observation Inference 1.0.S. + dil. HCL 2. O.S./Filtrate + dil HCI (heat) ie black ol olp D absext- +H,S gas or water Ctut?, Ast?) 3. O.S./Filtrate (Remove H,S) + a Fook or Group ML absent NH,Cl (equal) + NH,OH (till pecldash ppt Catt3, fet3 > alkaline to litmus) . 4. 0.S./Filtrate + NH,Cl (equal) Mo euhete oe Group Te absent +NH,OH (tillalkalineto black colorerecl * cot xen, nu litmus) + H,S gas or water epee Cat, al > OS,Filtrate (Remove HS) hike ppb Group™ present +NH,CI (equal) + NH,OH Ceatt, part sxttd > (till alkaline to litmus) +(NH,),CO, rong be present. O.S./Filtrate + NH,CI (equal) +NH,OH (till alkaline to = _ litmus) + Na,HPO, ” a 2. Analysis of first detected group os. +d Hel while ppt Group 2D present - 4 ushtke, Aoke ~ Bork the tse fe PPE ae 4, pott lon 3. C.T. for first detected radical C Pht? D 1, Ors. + RZ Yellow ppl 2, One t Kglr0g — yellow Rpt2. Analysis of second detected group (Catt, gat, Batt) 01S + FAH G CLA y + (AH4 Cog 2RsSe+Koln04 SEepxwabhon 3.ReS PHONHG), SOG {Rs HAN44),C20g + “+ AlHg 0H Result:- ‘The given inorganic mixture no. 2 contains following two cations (Basic Radicals) D RBS (Lead corinn ast. ¢caletum)Aim ; Analyse two basic (cation) radicals qualitatively from given inorganic mixture. Apparatus : A. Preliminary tests: Test tubes, test tube holder, test tube stand, filter paper etc. 1. Heating in a dry test tube: Take a small quantity of the mixture a clean and in dry test tube and heat it strongly. Att ealks may be Present, 2. Charcoal Cavity Test: Mixture + Na,CO, solid in 1:2 proportion placed in fresh charcoal cavity, moisten with a drop of water. Heat it with blow pipe in a reducing (yellow) flame Atts Bat? eatt mgt? Balls may be presen - 3. NaOH Test: molet terme Alig? I's aheens- Mixture + NaOH solution & heat paper cloesmee Hold moist turmerie papernearthe |4y15 1 seal OV mouth of the test tube Roe ee 4. Flame Test: Prepare a paste of the given mixture with cone. HCI on a watch glass. Make a small loop at the end of the platinum wire & dip it in the mixture or use glass rod. Heat it on oxidising flame (Blue) observe the colour change of the flame. . Preparation of original solution (0.S) Take a small quantity of mixture in a beaker add 20 mL of distilled water, stir with glass rod to dissolve the mixture. If mixture does not dissolve completely then warm it to dissolve. Clear solution is obtained, which is used as a O.S for further tests. 1. Analysis of Group zero (NH,’) 1.0.8. + NaOH solution + Heat, MCKIE test with moist turmeric paper. P re doesnot2. 0.S. + NaOH solution + Heat, Bring a glass rod dipped in cone. HCl. near the mouth of the test tube. umes 9, nee, No ushete lense Neg i's absear cf C.T. for NH: 1.0.8. + Nessler’s reagent in excess ii, O.S + Pierie Acid (2,4, 6 trinitro phenol) - 0S. + dil. HCL O.S.Filtrate + dil HCI (heat) + Nv Gaoupy. ane (pot lov Group absent NH,OH (till alkaline to litmus) + Na,HPO, H,S gas or water ppi- Ceect?, Asttt) 3.0.8/Filtrate (Remove H,8)+ whebe gelataneuw F2cup UL present ‘NH,Cl (equal) +NH,OH (till ppg oe alkaline to litmus) P CAE, Fett) 4. 0.S./Filtrate + NH,Cl (equal) + Alo Whete or black Group TW absent NH,OH (till alkaline to litmus) Coloured Pp 4 Cmat®, Rat? cat? NP +H,S gas or water is , > 5. 0.8/Filtrate (Remove H,S)* | Mo tohilke Ppd- Group absent NH,CI (equal) + NH,OH (till Ccatr axtt, Batt alkaline to litmus) +(NH,),CO, 2 ’ 6. 0.S/Filtrate +NH,Cl(equal)+ whike ppd Group UI present (get) [ La Test O+Se-NHGLd + NH coy Observations white pp 2. Analysis of first detected group JT. (Ag+3 Fert? Aloke. Dissolve he ppE tn dit-Hel & use RS- BOXC-T. 4 Alt33. C.T. for first detected radical R.s-+ Rew drops L NapH & warm” excess QALADH: Coke fesk Blue gloaking mass AL*? 1's conptrsved|, 2. RS 5. Blue Utrnns Un colourtess 80/9. 0-$-+NHG CL eihl ot Lalkaline)-+-Na2¢41 Poy -, mote — Dissolve the Ber eR 2 OUP VT In alt ete use thts RS. BOX C- B mgr (on « a 3. C.T. for second detected radical MQ++ gf Test RS.t 3. + Dito 1) Rose ned ppk = ATTY | , RS eet e PP: | 1g nae pieddbe Reddish bxown p mgr ts coms ene te Result:~ The given inorganic mixtureno3 contains following two cations (Basic Radicals) ) vALT Aluminium , ii) MET Magnesium - Remark and sign of teacher:‘Aim: To prepare phthalic anhydride. ‘Theory: Phthalic acid is a dicarboxylic acid which on heating loses a water molecule and undergo cyclisation reaction to form phthalic anhydride. : Chemical Reaction: 6 COOH é feat Ny COOH ov Phthalic acid 8 Phthalic anhydride Apparatus: Evaporating dish, funnel, cotton, tripod stand, wire gauze, pair of tongs, filter paper, etc. ‘Chemicals: Phthalic acid. Diagram: — Cotton plug +— Funnel hed Filter paper YS China dish gf Phihalic acid Wire guaze +— Tripod stand Bumer Procedure: 1. Take 2 g of phthalic acid in a dry evaporating dish. 2. Cover the dish with filter paper having number of small holes in the centre. 3. Keep an inverted funnel on the filter paper and close nozzle of the funnel with cotton plug. Place evaporating dish on the tripod stand with wire gauze as shown in above diagram, 4. Now heat the china dish slowly and carefully on low flame. 5. After sometime the acid sublimes and anhydride collects on the inner side of the funnel. 6. Stop heating and remove the funnel carefully with pair of tongs and cool. 7. Collect the crystals of phthalic anhydride on the paper and weigh it. Result: 1. Colour of the crystals = 2. Shape of the crystals 3. Yield of phthalic anhydrid Remark and sign of teacher:Select [|] the most appropriate answer from given alternatives of each sub question. 1. Phthalic acid is ---—- a. monocarboxylic acid Abr dicarboxylic acid ¢. tricarboxylic acid 4d. polycarboxylic acid 2. Phthalic anhydride is obtained by the process known as --—~ «a. decomposition dehydration c. sublimation 4. distillation 3. Phthalic acid undergo ---- during preparation of phthalic anhydride -vacdehydration b. decarboxylation . dehalogenation d. dehydrohalogenation 4. Shape of crystals of phthalic anhydride is verteedle b. hexagonal ¢. triclinic 4, monoclinic 5. Formation of phthalic anhydride takes place by -——- process/reaction. «. isolation Urrcyclisation c. decomposition 4, diazotization 1, Why cotton plug is Ans C2bLo2. Us. used, bhe. pce Sublamabon. t0.cover the paptiitacliae Ceahous. fhe oats eit WOrIy.gases ‘prevent .bhelr esCape..3.0thak. thes. Bee. er ine tae pel. condenses) 2. Write chemical equation for preparation. wt ‘anhydride from acetic acid, Ans nGllgeOOH --pyeans ae 7 ae ao 12. Sigcbont. a ascsae . 3. What is the colour and shape of phthalic a es crystals? Ans. fhe .codol..9, phralie .arhyelrtae...ts. choke cabot less Ae 1 ShAPR..B Cathal Us. needhe.. shaped... 4. Why slow heating is required to the contents during process of sublimation? Ans Whole sublimabon Can be.occure. at abroosprbernte P2essure , the. p2ocess.1s eather lou becarse. be Qa molec uiles. 5621.1 MU aiind thels way. kbrough, bne.abmasphente gases thak are, bombnrdiag the 's. Why filter paper is used with small holes in the centre during preparatioa ics I UCe. anhydride? ply us presentdy abtalned by catalylye oaticlabee, eae.om naphthalene ienecepna bie 4 phibelee ene 00) 7 — AGE2IES. Rees Remark and sign of teach‘Theory: Succinic acid is a dicarboxylic acid which on heating loses a water molecule and undergo cyclisation reaction to form succinic anhydride. Chemicals Reaction: H,C-COOH , cH Coy, A H,C-COx, H¢-CooH * Greg? —*—* H#E- co * 2CH,COOH Suecinic acid Acetic anhydride Suceinic Acetic acid anhydride Apparatus: Evaporating dish, funnel, cotton plug, tripod stand, wire gauze, pair of tongs, filter paper, ete. Chemicals: Suecinie acid. eae — Cotton plug Filter paper China dish Succinic acid Wire guaze +— Tripod stand Procedure: 1. Take 2 g of succinic acid in a dry evaporating dish, add 1 ml of acetic anhydride. 2. Cover the dish with filter paper having number of small holes in the centre. 3. Keep an inverted funnel on the filter paper close nozzle of the funnel with cotton plug, Place evaporating dish on the tripod stand with wire gauze as shown in above diagram. 4. Now heat the china dish slowly and carefully on low flame. 5. After sometime the acid sublimes and anhydride collects on the inner side of funnel. 6. Stop heating and remove the funnel carefully with pair of tongs and cool 7. Collect the niddle shape crystals of succinic anhydride on paper and weigh it. Result: i Fi Ph 1. Colour of the crystals =ashute CCrystolline Sobral ) 2. Shape of the crystals = Neeolle &hé 3. Yield of succinic anhydride = .1*.$°.gSelect |] the most appropriate answer from given alternatives of each sub question. 1. The molecular formula of succinic acid is x C,H,0, b. C,H,0, ©. CHO, d. CHO; 2. The by product is formed in the formation of succinic anhydride is a. water sbeticetic acid c. acetic anhydride 4, succinic acid 3. The process carried out to convert succinic acid to succinic anhydride is «a. oxidation b. reduction c. hydration sdctlehydration 4, The role of acetic anhydride is chemical reaction is as ar reducing agent b. oxidising agent c. dehydrating agent d. hydrating agent 5. IUPAC name of oxalic acid is «4. ethanedioic acid b. butanedioie acid ¢. propanoic acid d, propanedioic acid 1. What happen when succinic ac{d, undergoes dehydration? Ans whem. 6 Ucclmec. undergoes Nan, Lhe te gives sgucclni¢..anbydatde» the. delysnotsea suceinie.aced. rs. canwted auuk..dor.presence.q,ackd.andyelaicle...ax..phasphorgyt chlozdale.: 2. Write IUPAC name of cn acid, Ans. LUPAC.DGmNDé gysuecinie actl.l¢. Butane-1,4.dlole.acsol » 3. Write names and formulae of any two aca eld thier than phthalic acid and Succi oc . oxatle, etd). [email protected]¢. cel DPHB0G=CHy- C004 \Beuccente eRe ARO COOH, 4. = fa the term ma ot on sais abt cab Ans. fa gpa > MLL, atbiph C.TAONOG aarplee, nhs is. Known gatty acca acta 5. Write chemical equation for the tL propionic anhydride from propionic acid. Ans..694H g CO DM. Py Ogre Cae dager ergy ronen RES Oe ‘Cote COOH art a ; Remark and nd ign of teacher?Aim: To prepare methyl Salicylate (oil of winter green) qualitatively. Theory: Carboxylic acids are converted to ester by the Fischer esterification, an acid catalysed reaction with an alcohol. Reaction: ‘orn +CH,-OH —4_, C—OCH, + 4.0 ‘OH ,H Salicylic acid methyl alcohol methy! salileylate Procedure: 1. Take a small amount of salicylic acid in a hard glass test tube. 2. Add 2-3 mL of methyl alcohol. 3. Add I mL cocentrated H,SO, 4. Heat the test tube for 10 to 15 minutes at low flame. 5. Observe the colour and take odour of the formed compound. Observation and Result : . 1. Colour of the compound = Ugh pale colow2 ox colourless (methyl sabicy| 2. Odour of the compound =Disinct: characteresbe odatwr, Csweet oe Brulty olor)Select |v] the most appropriate answer from given alternatives of each sub question. 1. The molecular formula of methy! salicylate is. .C,H,0, Abr C,H,O, ©. CH,0, 4.C,H,,0, 2. The hybridisation of carbon atoms of methyl salicylate is. a. SP-SP? b. SP?-SP VC SP?-SP? d. SP3-SP 3. Another name of methyl salicylate is. a. oil of coconut b. oil of almonds agcvil of winter green d. oil of vitriol 4. The role of H,SO, in esterification reaction is, «a. oxidising agent b.reducing agent se“ dehydrating agent d. hydrating agent 5. The functional groups present in salicylic acid are ...... a. carboxylic acid and alcoholic «balcoholic and ester c. ester and amide d. carboxylic acid and amide 6. Formation of water molecule in esterification reaction is by elimination of a. -OH group from alcohol and ‘H’ from carboxylic acid \.bc-OH group from carboxylic acid and ‘H’ from alcohol c. -OH group from carboxylic acid and ‘-OH" from alcohol d. ‘H’ from alcohol and ‘-OH’ from carboxylic acid 1. What is Fischer esterification? 4 h et Ans..An2.29.. canhomybic. actid ts heat cogil alechol.wn Presence CONC: My ey AD..KORI. RELLL Kit a te Cakded as. plscher terieteabom. RxCOO+H + HOR). CEM. R— Boo Rl Hj0- 2. Write a general chemical equation showing formation of StE2= Ans... 2 f RrGa Ott. MO: OR! tthe actd..altohol. Sn QSCBDn n 3. Write the rote of conc. H,SO, in esterification process? Ans...-2a. esbertpicablon, reaction. came. HgS.04,.16.used.ars... catalysk.0s Wels.as,.oleh GAG again. Fb. increases. rake. grceaction.d eh ps.tar wremnoval. Wwaker. Remark and sign of teache