Little Flower Higher Secondary School
Chapters : 2 Std 11 : Chemistry Date : 08/08/24
Total Marks : 25 marks Unit Test-2 Time : 01 Hour
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [15]
1. Which of the following statement is incorrect regarding cathode rays ?
(A) Characteristics cathode rays do not depend upon the material of electrode.
(B) Characteristics cathode rays do not depend upon the nature of the gas.
(C) Cathode rays have no mass and charge.
(D) Cathode rays originate from the cathode.
2. State the species in which electron, proton and neutron are 10, 8, 8 respectively ?
(A) 128 O2– (B) 168 O (C) 168 O2– (D) 168 O–
3. State True (T) or False (F) for following statements.
(i) As the frequency is more wavelength is less.
(ii) As the frequency is more energy is less
(iii) As the frequency is more energy is more
(iv) As the frequency is more wavelength is more
(A) T F T F (B) F T F T (C) T T F T (D) F F F T
1
4. How many maximum number of electrons in 3p orbital have spin quantum number S = – ?
2
(A) 0 (B) 6 (C) 3 (D) 2
5. Which pair is true from the following ?
(a) Aufbau (i) mvr
(b) Angular momentum (ii) Orientation of electron in orbital momentum
(c) Hund’s Rule (iii) energy order of orbitals
(A) b – i (B) a – i (C) c – ii (D) c – i
6. How many orbitals upto n = 4 ?
(A) 8 (B) 30 (C) 16 (D) 4
7. Match the species of Column - X with the electron configuration of the elements in the Column -
Y and select correct answer.
Column – X Column – Y
(i) 22 Ti2+ (P) (n–1) d4ns2
(ii) 30 Zn (Q) (n – 1) d10 ns1
(iii) 24Cr (R) (n – 1) d2 ns0
(iv) 29Cu (S) (n – 1) d5 ns1
(M) (n – 1) d10 ns2
(N) (n – 1) d10 ns2
(A) (i) ® M; (ii) ® N; (iii) ® P; (iv) ® Q (B) (i) ® R; (ii) ® N; (iii) ® P; (iv) ® S
(C) (i) ® M; (ii) ® Q; (iii) ® S; (iv) ® R (D) (i) ® R; (ii) ® N; (iii) ® S; (iv) ® Q
8. Which of the following electronic configuration is not possible ?
(A) 3d2 (B) 2p2 (C) 3f2 (D) 4s2
9. Assertion (A) : An orbital cannot have more than two electrons.
Reason (R) : Two electrons in an orbital create opposite magnetic field. The correct choice is,
Wish
(A) Both (A) and (R) are true and (R) is You
the -correct
All The Best
explanation of (A)
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(C) (A) is true but (R) is not true
Assertion (A) : An orbital cannot have more than two electrons.
Reason (R) : Two electrons in an orbital create opposite magnetic field. The correct choice is,
(A) Both (A) and (R) are true and (R) is the correct explanation of (A)
(B) Both (A) and (R) are true but (R) is not the correct explanation of (A)
(C) (A) is true but (R) is not true
(D) (A) is not true but (R) is true
10. Give number of unpaired electrons in Ni+2 .
(A) 0 (B) 1 (C) 3 (D) 2
11. An electron from one Bohr stationary orbit can go to next higher orbit
(A) by emission of electromagnetic radiation.
(B) by absorption of electromagnetic radiation.
(C) by absorption of electromagnetic radiation of particular frequency.
(D) without emission or absorption of electro-magnetic radiation.
12. Three unpaired electron of nitrogen atom can be explained by.....
(A) Pauli’s rule (B) Aufbau principle
(C) Uncertainity principle (D) Hund’s rule
13. Which orbital is non directional ?
(A) 4p (B) 4d (C) 4f (D) 3s
14. Isotone of 76
32 Ge is : ..........
(A) 37
32
Ge (B) 77
33
As (C) 77
34
Se (D) 78
36
Sc
15. The nature of anode rays depends upon
(A) Nature of electrode (B) Nature of residual gas
(C) Nature of discharge tube (D) All the above
Section B
//X
• Write the answer of the following questions. [Each carries 5 Marks] [10]
16. 2) The work function for caesium atom is 1.9 eV. Calculate the threshold frequency of the radiation.
If the caesium element is irradiated with a wavelength 500 nm, calculate the kinetic energy and the
velocity of the ejected photoelectron. (1 eV = 1.602 ´ 10–19 J)
17. The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value
of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value
of n will have lower energy.
(I) Based upon the above information, arrange the following orbitals in the increasing order of energy.
(a) 1s, 2s, 3s, 2p (b) 4s, 3s, 3p, 4d
(c) 5p, 4d, 5d, 4f, 6s (d) 5f, 6d, 7s, 7p
(II) Based upon the above information, solve the questions given below :
(a) Which of the following orbitals has the lowest energy ? 4d, 4f, 5s, 5p
(b) Which of the following orbitals has the highest energy ? 5p, 5d, 5f, 6s, 6p
Wish You - All The Best
