Dr.G.

Venkatachalam/ Polytech-TRB/ Chemistry/UNIT-IX

1. Which of the following method yields a mass average molar mass of a polymer?
a) light scattering b) Osmometry c) Sedimentation velocity d) Viscometry
2. Mark-Houwink equation is used to determine
a) Heat capacity of solids b) molecular weight of polymers c) kraft temperature
d) enthalpy vapourization of liquids
3. The degree to which the molecules of a polymer are arranged in orderly pattern with respect to each
Other is a measure of
a) Viscosity b) mechanical strength c) elasticity d) crystallinity
4. Which of the following method is used for the calculation of ground state energy and wave
functions of many electron atoms or ions?
a) Variation method b) perturbation method c) HF (or) SCF method d) all of these
5. The heterogeneity of the polymer sample is called as
a) poly dispersity b) mono disperisity c) mass average molar mass d) none of these
6. Mark-Houwink-sakurada equation is
a) [η] = KMa b) [η] = Km×sample wt c) [η] = K d) none of these
7. End-group analysis is used to measure
a) number average mol.wt b) weight average mol.wt c) both (a) and (b) d) none of these
8. Number average molecular weight is measured by
a) Osmometry b) mass spectrometry c) end group analysis d) all of these
9. Weight average molecular weight is measured by
a) Sedimentation b) end- group analysis c) cryoscopy d) osmometry
10. Polymers having regular alternation of d- and l- configurations in the molecular chains are called
a. syndiotactic b. atactic c. isotactic d. none of these
11. Nylon 6,10 is made from hexamethylene diamine and
a. adipic acid b. sebacic acid c. succinic acid d. squaric acid
12. Vinyl compounds usually undergo ............polymerisation
a) chain b) step c) condensation d) cross-linked
13. Which one of the following is not an example for condensation polymerisation?
a. styrene b. polyester c. Dacron d. nylon 66
14. The most common epoxy-prepolymer present as end groups is an epoxy resin is
a) Amide linkage b) ester linkage c) glycidyl ether d) none
15. Peroxides are the initiator for ................polymerisation reactions
a. radical b. cationic c. anionic d. condensation
16. Magnetic recording tapes are made from
a) PVC b) nylon c) polyester d) polystyrene
17. Inorganic polymer from the following is
a. PVC b. Bakelite c. Nylon d. silicones
18. Bakelite is a
a) Amino acid resin b) epoxy resin c) phenol resin d) none
19. Which one of the following polymer is called Dacron?
a) Terylene b) actrilonitrile c) poly vinyl acetate d) methylmethacrylate
20. The polymerisation of two or more different monomers is called
a) Copolymerisation b) Addition polymerisation c) stepwise polymerisation d) Homo polymer
21. Polymerisation of stryrene initiated by aqueous solution of BF3 is an example of
a) Cationic polymerisation b) anionic polymerisation c) free radical polymerisation
d) Coordination polymerisation
22. Polymerisation of caprolactum yields?
a) Terylene b) Nylon-6 c) Nylon-66 d) Bakelite
23. Which of the following polymer has amide linkages?
a) Nylon b) Bakelite c) Terylene d) PVC
24. Which of the following polymer has ester linkages?
a) Nylon b) Bakelite c) Terylene d) PVC
25. The correct statement from the following is/are
I. Teflon is used as insulation for electrical items and in the manufacture of gaskets and valves
II. Teflon has low chemical reactivity, excellent toughness, electrical and heat resistance
a. I only b. II only c. I & II d. none of these
26. Terylene is synthesized by polymerizing
a. ethylene glycol and dimethyl terephthalate
b. ethylene glycol and acetylene
c. glycerol and HCHO
d. glycerol and dimethyl terephthalate
27. Which among the following is eigen function of d/dx?
a) sinkx b) coskx c) kx2 d) eikx
28. The de-broglie wave length of tennis ball of mass 60g moving with a velocity of 10m/s is
approximately
a) 10-33 b) 10-31 c) 10-16 d) 10-25
29. The orbital angular momentum of an electron in 2p orbital is-
a) ½(h/2π) b) 0 c) h/2π d) √2h/2π
30. The orbital angular momentum of an e- in 3d-orbital is-
a) √6/h/2π b) √8h/2π c) 0 d) h/2π
31. The normalized wave function for the particle in a one dimensional box of with ‘a’ is-
a) √a/2 sin(nπx/a) b) sin[nπx/a] c) √a/2 sin(nπx/a) d) √2/a sin(nπx/a)
32. A diatomic molecule can act as
a) Simple harmonic oscillator b) rigid rotor c) both(a) and (b) d) none these
33. What is the wavelength of e- wave determined by Davisson and Germer experiment?
a. 165A0 b. 0.165A0 c. 1.65A0 d. 16.5A0
34. Compton wavelength from the following is
a. 2.42A0 b. 24.2A0 c. 0.242A0 d. 0.0242A0
35. How many degenerate energy state present in E = 9h2/8mL2?
a. 9 b. 8 c. 6 d. 3
36. Choose the delocalisation energy for 1,3-butadiene using Huckel MO theory?
a. 0.472β b. 4.472β c. 4α+4β d. 4α+4.472β
37. For a particle in cubic box of side ‘a’ if E = 11h2/8ma2, then the degeneracy is
a. 1 b. 3 c. 5 d. 7
38. The zero point energy of a simple harmonic oscillator is equal to
a) hυ b) 1/2 hυ c) 3/2 hυ d) 0
39. The particle of mass ‘m’ moving in a cubic box of side ‘a’ has energy 14h2/8ma2. How many
degenerate levels are possible?
a. 2 b. 3 c. 6 d. 4
40. The eigen functions of rigid rotor are
a) Hermit polynomials b) Legendre polynomials c) spherical harmonics
d) Bessel functions
41. The eigen value of d2/dx2 sin3x is
a. 3 b. -3 c. 9 d. -9
42. The degeneracy of the energy level for nx=1, ny=2 and nz=3 of a particle in three dimensional box
is
a. 14 b. 1 c. 3 d. 6
43. If two operators commute, then
a) They are linear b) they are hermitian c) they have the same eigen values
d) They have same eigen functions
44. The ratio of the energy of the second energy level to the first energy level of a particle in a one-
dimensional box of infinite highest is
a) 1 b) 2 c) 1/4 d) 4
45. The value of commutator [x, d/dx] is
a) 1 b) -1 c) 0 d) 2
46. Which is not a linear operator from the following?
a. d/dx b. √ c. Δ2 d. a(b+c) = ab + ac
47. Fɸi = Eiɸi, which is pseudo Schrodinger equation, in which orbital is an eigen function of F. This
operator is introduced to include
a. Orthogonality of α and β spins b. electron exchange c. Average potential energy
d. none
48. In the lowest energy level of n=1, the particle is most likely to be in the middle of the box, while in
the next higher state of n = 2, the particle is
a. is never to be found there b. is in the middle of box c. near the wall
d. none
49. Sin 2x is not an eigen function of the operator d/dx, but of d2/dx2. If so, what is its eigen value?
a. 2 b. 3 c. -4 d. 1
50. Which cannot be energy of a particle in a one-dimensional box?
a. 25h2/8mL2 b. 9h2/8mL2 c. 17h2/8mL2 d. 16h2/8mL2
51. The valence bond wave function of HF molecule, if ψionic = 0.2, ψcovalent = 0.8, with λ as iconicity
parameter, is
a. ψVB = 1.6 λ b. ψVB = 4 λ c. ψVB = 0.8 +0.2 λ d. ψVB = 0.8-0.2 λ
52. A particle is confined in a one dimensional box of length ‘L’. The probability of finding the
particle in the region 0<x<L/2 is
a. 2 b. 0.25 c. 1 d. 0.5
53. A vector product of position vector and linear momentum vector is equal to
a. Laplacian operator b. angular momentum vector c. Hermitian operator
d. Hamiltonian operator
54. The energy of third permitted energy level of an electron in a box of 1A0 width is
a. 37.69 eV b. 150.76eV c. 339.21eV d. 75.38eV
55. A particle of mass ‘m’ is in a one dimensional box of length ‘l’. The frequency the photon emitted
when this particle goes from the n = 3 to the n=2 level is
a. 5h2/8ml2 b. h2/8ml2 c. 5h/8ml2 d. h/8ml2
56. In Compton effect, the Compton wavelength of the electron is 2.43 pm. The maximum Compton
wavelength shift occurs at (cos 1800 = -1) is
a. 1.22 pm b. 3.65pm c. 7.29 pm d. 4.86 pm