MARKING SCHEME FOR CLASS 12 CHEMISTRY – PRE BOARD I
SECTION A
1. b) PbSO4 anode is reduced to Pb (1)
2. c) triethylamine (1)
3. b) ii and iii (1)
4. a) Vitamin B12 (1)
5. d) P, R, and S (1)
6. d) Neopentane (1)
7. b)Free radical halogenation of alkanes (1)
8. c) Glucose (1)
9. b )B (1)
10. d) 2, 6 (1)
11. a) zero order reaction (1)
12. d)Variable oxidation states (1)
13. B) Both A and R are true but R is not the correct explanation of A. (1)
Explanation: halogens withdraw electrons through an inductive effect -I and
release electrons through resonance +R . Through I effect destabilize the
intermediate carbocation forme during the electropohilic substitution. So
reactivity is controlled by I effect and orientation is controlled by R effect.
14. D) A is false but R is true. (1)
15. B) Both A and R are true but R is not the correct explanation of A. (1)
16. A)Both A and R are true and R is the correct explanation of A (1)
SECTION B
17. a)Reimer Tiemann reaction, (1/2) ortho hydroxyl benzaldehyde (1/2)
b) Williamson syntheses, (1/2) 2-ethoxy-3-methylpentane (1/2)
18. π = iCRT (1/2)
π=¿ 3x0.025 x 0.0821 /174 x 2 (1)
π=¿ 5.27 x 10 atm
-3
(1/2 + ½)
(OR)
PoA-PA/ PoA = wB xMA / MB x wA (1/2)
MB = 2x18x1.013 /98 x (1.013 -1.004) (1)
MB = 41.35 g mol-1 (1/2 + ½)
19. .a) Glycine (1/2) H2NCH2COOH (1/2)
b) Glucose or any other example (1/2) sucrose or any other example (1/2)
20. a) Both show +3 oxidation state , strong reducing agent (1/2 + ½)
b) This is due to the increasing stability of the species of lower oxidation state to
which they are reduced. (1)
21. a) The geometry is pyramidal (1/2) Hybridisation is SP3 (1/2)
b) IUPAC is ethanamine (1)
SECTION C
22. X is 2-chloro-2,3-dimetylbutane (CH3)2C(Cl)CH(CH3)2 (1)
Y is 2,3-dimethylbut-2-en (CH3)2C=C(CH3)2 (1)
Z is 2,3-dimethylbut-1-ene CH2=CH(CH3)CH(CH3)2 (1)
23. ʌm = k x 1000/C (1/2)
-5
ʌm = 7.896 x 10 x 1000/0.00241
=32.76 Scm2mol-1 (1/2)
o
α = ʌm/ ʌ m (1/2)
α = 32.76 /390.5
= 8.4 x 10-2 (1/2)
Ka = c α2/1- α ( 1/2)
= 0.00241 x 8.4 x 10 x 8.4 x 10-2 /1-0.084
-2
= 1.86 x 10-5 (1/2)
24. a)dissolved oxygen is high in cold water (1)
b) solution which obeys Raoult’s law. A-A, B-B = A-B or Any example (1/2 + ½)
c) common salt is added in pure water to get elevation in boiling point. (1)
25. a) nitrous acid test : Aniline gives diazonium salt and produces colour dye but
benzylamine gives benzylalcohol which is confirmed by esterification reaction.(1)
b)A= C6H5CN, B= C6H5COOH, C= C6H5CONH2, D= C6H5NH2 (1/2 mark each)
(OR)
a)i) due to formation of anilinium ion which is meta directing group. (1)
ii)Aryl halide will not favour for SN reaction.(1)
b) CH3COOH + NH3 ----CH3CONH2 +NaOBr---- CH3NH2 (1)
26. a)Cu2[Fe(CN)6] (1)
b) explanation based on VBT : [Co(NH3)6]3+ - d2sp3 (1)
[Ni(NH3)6]2+-sp3d2 (1)
27. a) 2Na2CrO4 + 2H+ --Na2Cr2O7 + 2 Na+ + H2O (1/2)
Na2Cr2O7 + 2KCl --- K2Cr2O7 + 2 NaCl (1/2)
b) due to lanthanoid contraction(1)
c) 2MnO4- + 10I- +16 H+----- 2Mn2+ + 5I2 +8 H2O (1)
28. a)4 different products structure ( half mark each =2 marks)
b)(CH3)2CHCOOH <CH3CH2CH2COOH <CH3CH(Br)CH2COOH
<CH3CH2CH(Br)COOH. (1)
SECTION D
29. a) it indicate the absnce of free –CHO group (1)
b) it is water soluble . hard to be stored in our body. Excreted via urine. (1)
c) i)it is an amide formed between two amino acid (–CO-NH- ) (1)
ii) cyclic structure (1)
(OR)
c)i)the two monosaccharide joined together by a linkage called glycosidic
linkage (-O-)(1)
ii)cyclic structure(1)
30. a) Rate = k[NH3]x[ O2]y (1)
b)Molecularity of the reaction is the number of molecules taking part in an elementary
step For this we require at least a single molecule leading to the value of minimum
molecularity of one (1)
c) i) zero , -d[R]/dt = K (1/2 + ½)
ii)mol L-1S-1 , mol L-1S-1 (1/2 + ½)
(OR)
c)i) it is complex reaction because in elementary reaction the order and molecularity will
be same. The order of the reaction is 1.5 but molecularity cannot be a fraction. (1)
ii) rate increases to 8 times (need calculation steps) (1)
SECTION E
31. a)i) The electronic configuration of Ni is [Ar] 3d84s2 which shows that it can only
formtwo types of complexes i.e. square planar (dsp2) in presence of strong ligand
and tetrahedral (sp3) in presence of weak ligand. There are four empty orbitals in
Ni while octahedral complexes require six empty orbitals. (1)
(ii) Due to presence of empty d-orbitals in transition metals, they can accept
electronpairs from ligands containing π electrons and hence can form π -bonding
complexes.Example : ligands like CO (1)
iii) Due to greater magnitude of Δ0 , CO produces strong fields which cause more
splitting of d-orbitals and moreover it is also able to form π bond due to back
bonding. (1)
-2
b) [Ni(C2O4)2(H2O)2] : diaquadioxalatonickelate (II), (1)
c) Pure Ni can be obtained from Ni(CO)4 , Gold and Ag are extracted by the use
of complex formation like Na[Ag(CN) 2]. (1/2 + ½)
(OR)
3-
i) [CoF 6] is paramagnetic due to the presence of 4 unpaired electrons. (1)
ii) [Co(en)3] 3+ is more stable because of chelation. (1)
3+ 2 3
iii) [Co(en)3] forms an inner orbital complex involving d sp hybridisation (1).
iv) [CoF 6] 3- forms a high spin complex (sp3d2 hybridisation). (1)
3 3+
v) Cationic complex exhibits optical isomerism [Co(en) ] (1)
32. (1+2+1)
c) molar conductivity at inifinte dilution is called limiting molar
conductivity (1)
(OR)
a) In corrosion, a metal is oxidised by loss of electrons to oxygen and formation of
oxides in presence of water, air and H+. It is basically an electrochemical
phenomenon.
c)Anode – oxygen ; cathode - Ag
33. i) Unstability of carboxylate anion due to conjugation in benzoic acid.(1)
ii) Among carboxylic acid methanoic acid alone will answer for Tollens test and
produces silver mirror (1)
iii) C=O group is sterically hindered in carboxylic acid. Example: carboxylic
acid will not undergo addition reaction with HCN,.. (1)
iv) Due to more extensive association of carboxylic acid molecules through
intermolecular hydrogen bonding. The hydrogen bonding are not broken
even in vapour phase. (1)
v) The lone pair electron present on Nitrogen near to carbonyl group take part
in resonance which makes less available of hydrogen to the reaction. (1)
vi) HCHO +HCHO +conc. NaOH→ + HCOONa +CH3OH (1)
vii) Structure. (1)
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