IKV-FILMSEC 1010 Spray

Safety Data Sheet

according to Regulation (EU) 2015/830
Date of issue: Revision date: 08/07/2015 : Version: 1.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : IKV-FILMSEC 1010 Spray
Product code : IFILMFZ10AA
Type of product : Lubricant
Vaporizer : Aerosol
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use
Industrial/Professional use spec : For professional use only
Function or use category : Lubricants and additives

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
IKV TRIBOLOGIE
ZI de la Gare BP31
F-26260 St Donat sur l'Herbasse - France
T +33 (0)4 75 45 06 45 - F +33 (0)4 75 45 28 09
[email protected] - www.ikvtribologie.com

1.4. Emergency telephone number

Emergency number : France_Tel ORFILA (INRS) : 33 (0)1 45.42.59.59
Country Organisation/Company Address Emergency number
UNITED KINGDOM Guy's & St Thomas' Poisons Unit Avonley Road 0870 243 2241
Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SE14 5ER London

Ελλάδα Poisons Information Centre 11527 Athens +30 10 779 3777

Children's Hospital "Aglaia. Kyriakou"
‫ﺇﺳﺮﺍﺋﻴﻞ‬ Israel Poison Information Center 6 Ha'Aliya Street +972 4 854 1900
Rambam Health Care Campus 31096 Haifa

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Aerosol 1 H222;H229
STOT SE 3 H336
Aquatic Chronic 2 H411
Full text of H-statements: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

F+; R12
N; R51/53
R66
R67
Full text of R-phrases: see section 16

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02 GHS07 GHS09

Signal word (CLP) : Danger
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IKV-FILMSEC 1010 Spray
Safety Data Sheet
according to Regulation (EU) 2015/830

Hazardous ingredients : Isopropyl alcohol, Hydrocarbons, C6, isoalkanes, (<5% n-hexane)

Hazard statements (CLP) : H222 - Extremely flammable aerosol
H229 - Pressurized container: May burst if heated
H336 - May cause drowsiness or dizziness
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P102 - Keep out of reach of children
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking
P211 - Do not spray on an open flame or other ignition source
P251 - Do not pierce or burn, even after use
P261 - Avoid breathing vapours, fume, spray
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P405 - Store locked up
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation
EUH-statements : EUH066 - Repeated exposure may cause skin dryness or cracking
Extra phrases : Not to be used for any purpose other than the one the product was designed for
Contains the following fluorinated greenhouse gas (chemical name): HFC-134a:0,297 kg;
0,425t.Eq.CO2; GWP=1430

2.3. Other hazards

Other hazards not contributing to the : Contains gas under pressure; may explode if heated.
classification
PBT: not relevant – no registration required
vPvB: not relevant – no registration required

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable

3.2. Mixture

Name Product identifier % Classification according to Classification according to

Directive 67/548/EEC Regulation (EC) No.
1272/2008 [CLP]
Hydrocarbons, C6, isoalkanes, (<5% n- (EC no) 931-254-9 50 - 75 F; R11 Flam. Liq. 2, H225
hexane) (REACH-no) 01- Xn; R65 STOT SE 3, H336
2119484651-34 N; R51/53 Asp. Tox. 1, H304
R66 Aquatic Chronic 2, H411
R67

1,1,1,2-Tetrafluoroethane (CAS No) 811-97-2 25 - 50 Not classified Liquefied gas, H280

(EC no) 212-377-0
(REACH-no) 01-
2119459374-33
Isopropyl alcohol (CAS No) 67-63-0 5 - 10 F; R11 Flam. Liq. 2, H225
(EC no) 200-661-7 Xi; R36 Eye Irrit. 2, H319
(EC index no) 603-117-00-0 R67 STOT SE 3, H336
(REACH-no) 01-
2119457558-25

Full text of R- and H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical
advice/attention if you feel unwell.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse.
First-aid measures after eye contact : In case of eye contact, immediately rinse with clean water for 10-15 minutes. Seek medical
attention if ill effect develops.
First-aid measures after ingestion : Do NOT induce vomiting. Allow the victim to rest. If swallowed, seek medical advice
immediately and show this container or label.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Overexposure to vapours may result in headache, nausea and reduced blood pressure. May
cause drowsiness or dizziness.

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IKV-FILMSEC 1010 Spray
Safety Data Sheet
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Symptoms/injuries after skin contact : Repeated or prolonged skin contact may cause dermatitis and defatting.
Symptoms/injuries after eye contact : Direct contact with the eyes is likely to be irritating. Redness, pain.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : carbon dioxide (CO2), powder, alcohol-resistant foam, hazy water.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Extremely flammable aerosol.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of
burns and injuries. May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : on exposure to temperature rise pressure rise and possible bursting of container.
Hazardous decomposition products in case of : Thermal decomposition generates : Carbon monoxide. fume. Toxic vapours.
fire
5.3. Advice for firefighters
Precautionary measures fire : Ventilate area. No flames. Eliminate all sources of ignition. Pressurized container. Protect from
sunlight and do not expose to temperatures exceeding 50°C. Do not spray on an open flame or
other ignition source.
Firefighting instructions : Fight fire remotely due to the risk of explosion. Prevent fire-fighting water from entering
environment. Use water spray or fog for cooling exposed containers. Exercise caution when
fighting any chemical fire.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Evacuate and limit access.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Do not get in eyes, on skin, or on clothing. No open flames. No
smoking. Pressurized container: Do not pierce or burn, even after use.

6.1.1. For non-emergency personnel

Protective equipment : Wear suitable protective clothing. Do not attempt to take action without suitable protective
equipment.
Emergency procedures : Keep public away from danger area. Do not breathe fumes from fires or vapours from
decomposition.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Do not allow to enter drains or water courses. Notify authorities if product enters sewers or
public waters.
6.2. Environmental precautions
Notify authorities if liquid enters sewers or public waters. Prevent entry to sewers and public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Small
quantities of liquid spill: take up in non-combustible absorbent material and shovel into
container for disposal. Dispose of at a licensed waste collection centre. This material and its
container must be disposed of in a safe way, and as per local legislation.
6.4. Reference to other sections
No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : In use, may form flammable vapour-air mixture. Handle empty containers with care because
residual vapours are flammable. Pressurized container: Do not pierce or burn, even after use.
Precautions for safe handling : Provide good ventilation in process area to prevent formation of vapour. Use personal
protective equipment as required. Keep away from sources of ignition - No smoking. Do not
spray on an open flame or other ignition source. Avoid contact with skin, eyes and clothing.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse.
Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work.

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Safety Data Sheet
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7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in dry protected location to prevent any moisture contact. Keep in fireproof place. Do not
expose to temperatures exceeding 50 °C/ 122 °F.
Storage temperature : 5 - 25 °C
Heat and ignition sources : Store in tightly closed, properly ventilated containers away from heat, sparks, open flame.
Storage area : Store in a well-ventilated place.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Isopropyl alcohol (67-63-0)
France VLE (mg/m³) 980 mg/m³
France VLE (ppm) 400 ppm
USA - ACGIH ACGIH TWA (mg/m³) 492
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (mg/m³) 984
USA - ACGIH ACGIH STEL (ppm) 400 ppm
Hydrocarbons, C6, isoalkanes, (<5% n-hexane)
France VME (mg/m³) 1000 mg/m³
France VLE (mg/m³) 1500 mg/m³
1,1,1,2-Tetrafluoroethane (811-97-2)
France VME (mg/m³) 4420 mg/m³
France VME (ppm) 1000 ppm

8.2. Exposure controls

Hand protection : In case of repeated or prolonged contact wear gloves. Nitrile-rubber protective gloves.
Chemical resistant gloves (according to European standard NF EN 374 or equivalent)
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is
recommended
Thermal hazard protection : Not applicable.
Environmental exposure controls : No data available.
Consumer exposure controls : No data available.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : white.
Odour : Alcohol.
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : < 0 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : ≈ 0.94
Solubility : Material insoluble in water.
Log Pow : No data available

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IKV-FILMSEC 1010 Spray
Safety Data Sheet
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Viscosity, kinematic : No data available

Viscosity, dynamic : No data available
Explosive properties : Pressurized container: May burst if heated.
Oxidising properties : No data available
Explosive limits : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Not expected to present a significant hazard under anticipated conditions of normal use.
10.2. Chemical stability
The product is stable at normal handling and storage conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
Overheating. Contains gas under pressure; may explode if heated.
10.5. Incompatible materials
Oxidizing agent.
10.6. Hazardous decomposition products
None under normal conditions. Thermal decomposition generates : Carbon dioxide. fume. Carbon monoxide. Toxic vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity : Not classified

Isopropyl alcohol (67-63-0)

LD50 oral rat > 5000 mg/kg
LD50 dermal rabbit > 5000 mg/kg
Hydrocarbons, C6, isoalkanes, (<5% n-hexane)
LD50 oral rat > 16750 mg/kg
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness.
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
IKV-FILMSEC 1010 Spray
Vaporizer Aerosol
Potential adverse human health effects and : Inhalation of mists or vapours at elevated temperatures may cause respiratory irritation.
symptoms Repeated or prolonged skin contact may cause dermatitis and defatting. Overexposure to
vapours may result in headache, nausea and reduced blood pressure.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Notify authorities if product enters sewers or public waters. Take all necessary measures to
avoid accidental discharge of products into drains and waterways due to the rupture of
containers or transfer systems.

Isopropyl alcohol (67-63-0)

LC50 fish 1 9640 - 10400

12.2. Persistence and degradability

IKV-FILMSEC 1010 Spray
Persistence and degradability Not established.
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IKV-FILMSEC 1010 Spray
Safety Data Sheet
according to Regulation (EU) 2015/830

12.3. Bioaccumulative potential

IKV-FILMSEC 1010 Spray
Bioaccumulative potential Not established.

12.4. Mobility in soil

IKV-FILMSEC 1010 Spray
Ecology - soil Not established.

12.5. Results of PBT and vPvB assessment

IKV-FILMSEC 1010 Spray
PBT: not relevant – no registration required
vPvB: not relevant – no registration required

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

ADR IMDG IATA ADN RID

14.1. UN number
1950 1950 1950 1950 1950
14.2. UN proper shipping name
AEROSOLS AEROSOLS Aerosols, flammable AEROSOLS AEROSOLS
Transport document description
UN 1950 AEROSOLS, 2.1, UN 1950 AEROSOLS,
(D), ENVIRONMENTALLY 2.1, MARINE
HAZARDOUS POLLUTANT/ENVIRO
NMENTALLY
HAZARDOUS
14.3. Transport hazard class(es)
2.1 2.1 2.1 2.1 2.1

14.4. Packing group

Not applicable Not applicable Not applicable Not applicable Not applicable

14.5. Environmental hazards

Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : Yes environment : Yes environment : Yes environment : Yes environment : Yes
Marine pollutant : Yes
No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : 5F
Special provisions (ADR) : 190, 327, 344, 625
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P207, LP02
Special packing provisions (ADR) : PP87, RR6, L2

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Mixed packing provisions (ADR) : MP9

Transport category (ADR) : 2
Special provisions for carriage - Packages : V14
(ADR)
Special provisions for carriage - Loading, : CV9, CV12
unloading and handling (ADR)
Special provisions for carriage - Operation : S2
(ADR)
Tunnel restriction code (ADR) : D

- Transport by sea
Special provisions (IMDG) : 63, 190, 277, 327, 344, 959
Limited quantities (IMDG) : SP277
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P207, LP02
Special packing provisions (IMDG) : PP87, L2
EmS-No. (Fire) : F-D
EmS-No. (Spillage) : S-U
Stowage category (IMDG) : None
Stowage and segregation (IMDG) : Protected from sources of heat For AEROSOLS with a maximum capacity of 1 litre: Category
A. Segregation as for class 9 but 'Separated from' class 1 except division 1.4. For AEROSOLS
with a capacity above 1 litre: Category B. Segregation as for the appropriate sub-division of
class 2. For WASTE AEROSOLS: Category C. Clear of living quarters. Segregation as for the
appropriate sub-division of class 2.

- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Y203
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 203
PCA max net quantity (IATA) : 75kg
CAO packing instructions (IATA) : 203
CAO max net quantity (IATA) : 150kg
Special provisions (IATA) : A145, A167, A802
ERG code (IATA) : 10L

- Inland waterway transport

Classification code (ADN) : 5F
Special provisions (ADN) : 19, 327, 344, 625
Limited quantities (ADN) : 1L
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01, VE04
Number of blue cones/lights (ADN) : 1
Not subject to ADN : No

- Rail transport
Classification code (RID) : 5F
Special provisions (RID) : 190, 327, 344, 625
Limited quantities (RID) : 1L
Excepted quantities (RID) : E0
Packing instructions (RID) : P207, LP02
Special packing provisions (RID) : PP87, RR6, L2
Mixed packing provisions (RID) : MP9
Transport category (RID) : 2
Special provisions for carriage – Packages : W14
(RID)
Special provisions for carriage - Loading, : CW9, CW12
unloading and handling (RID)
Colis express (express parcels) (RID) : CE2
Hazard identification number (RID) : 23
Carriage prohibited (RID) : No

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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no substances with Annex XVII restrictions

Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

Other information, restriction and prohibition : Council Directive 75/324/EEC of 20 May 1975 on the approximation of the laws of the Member
regulations States relating to aerosol dispensers. Fluorinated greenhouse gases - (EC) No 842/2006.

15.1.2. National regulations

France
Occupational diseases : RG 36 - Affections provoquées par les huiles et graisses d'origine minérale ou de synthèse
RG 84 - Affections engendrées par les solvants organiques liquides à usage professionnel

Germany
VwVwS Annex reference : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS,
Annex 4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Vruchtbaarheid
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Ontwikkeling

Denmark
Class for fire hazard : Add boilingpoint
Store unit : Add boilingpoint
Classification remarks : Add boilingpoint; Emergency management guidelines for the storage of flammable liquids must
be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Abbreviations and acronyms:
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
RID Regulations concerning the International Carriage of Dangerous Goods by Rai
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
LC50 Median lethal concentration
EC50 Median effective concentration
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Full text of R-, H- and EUH-statements:

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Aerosol 1 Aerosol, Category 1

Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2
Asp. Tox. 1 Aspiration hazard, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Liq. 2 Flammable liquids, Category 2
Liquefied gas Gases under pressure : Liquefied gas
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis
H222 Extremely flammable aerosol
H225 Highly flammable liquid and vapour
H229 Pressurized container: May burst if heated
H280 Contains gas under pressure; may explode if heated
H304 May be fatal if swallowed and enters airways
H319 Causes serious eye irritation
H336 May cause drowsiness or dizziness
H411 Toxic to aquatic life with long lasting effects
EUH066 Repeated exposure may cause skin dryness or cracking
R11 Highly flammable
R12 Extremely flammable
R36 Irritating to eyes
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R65 Harmful: may cause lung damage if swallowed
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
F Highly flammable
F+ Extremely flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

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