Section-I: (Maximum Marks: 80) 20 Questions Only One Option Is Correct
Section-I: (Maximum Marks: 80) 20 Questions Only One Option Is Correct
PHYSICS
SECTION-I : (Maximum Marks: 80) 3. Five equal resistances are connected in a network
This section contains 20 questions. Each question has as shown in figure. The net resistance between the
points A and B is :
4 options for correct answer. Multiple-Choice
Questions (MCQs) Only one option is correct. For
each question, marks will be awarded as follows:
Full Marks : +4 If correct answer is selected.
Zero Marks : 0 If none of the option is selected.
Negative Marks : –1 If wrong option is selected.
1. A current through a wire depends on time as i = α 0t
+ β t2 where α 0 = 20 A/s and β = 8 As – 2. Find the
charge crossed through a section of the wire in 15
s.
(A) 2R (B) R
(A) 2250 C 2
(B) 11250 C (C) 3R (D) R
2
(C) 2100 C 4. A wire of 1 Ω has a length of 1m. It is stetched till
(D) 260 C
its length increases by 25%. The percentage change
2. A cell E1 of emf 6V and internal resistance 2 Ω is in resistance to the neartest integer is :-
connected with another cell E2 of emf 4V and
internal resistance 8 Ω (as shown in the figure). The (A) 56% (B) 25%
potential difference across points X and Y is : (C) 12.5% (D) 76%
5. A resistor develops 500 J of thermal energy in 20s
when a current of 1.5 A is passed through it. If the
current is increased from 1.5 A to 3A, what will be
the energy developed in 20 s.
(A) 10.0 V (B) 3.6 V (A) 1500 J (B) 1000 J
(C) 5.6 V (D) 2.0 V (C) 500 J (D) 2000 J
Enthusiast Course - I(A) & I(B) 1801CJA101821230146
of 15 Ω resistance is connected across BD. per unit length is 0.1 Ω per cm. Across AB, a
battery of emf E and internal resistance 'r' is
Calculate the current through the galvanometer
connected. The maximum value of emf measured
when a potential difference of 10V is maintained
by this potentiometer is :
across AC.
(A) 2.44 μ A
(A) 5 V (B) 2.25 V
(B) 2.44 mA
(C) 6 V (D) 2.75 V
(C) 4.87 mA
9. The given potentiometer has its wire of resistance
(D) 4.87 μ A
7. 10 Ω . When the sliding contact is in the middle of
the potentiometer wire, the potential drop across
2 Ω resistor is :
(A) 4A
(B) 8A
(A) 10 V (B) 5 V
(C) 10A
40 40
(D) 6A (C) V (D) V
9 11
(A) +1V
(B) – 1V
(C) – 2V
(D) +2V
SECTION-II : (Maximum Marks: 20)
This section contains 05 questions. 3. In an electrical circuit, a battery is connected to
The answer to each question is a Numerical Value. pass 20 C of charge through it in a certain given
time. The potential difference between two plates
For each question, enter the correct integer value (In
of the battery is maintained at 15 V. The work done
case of non-integer value, the answer should be by the battery is ______J.
rounded off to the nearest Integer). 4. In the figure given, the electric current flowing
Answer to each question will be evaluated according to through the 5 k Ω resistor is 'x' mA.
the following marking scheme:
Full Marks : +4 If correct answer is entered.
Zero Marks : 0 If the question is unanswered.
Negative Marks : –1 If wrong answer is entered.
1. A cylindrical wire of radius 0.5 mm and The value of x to the nearest integer is _______.
conductivity 5 × 107 S/m is subjected to an electric 5. The energy dissipated by a resistor is 10 mJ in 1s
when an electric current of 2 mA flows through it.
field of 10 mV/m. The expected value of current in The resistance is _______ Ω .
the wire will be x3 π mA. The value of x is ____. (Round off to the Nearest Integer)
HINT – SHEET
PHYSICS 4. Ans ( A )
SECTION-I R0 = 1 Ω R1 = ?
1. Ans ( B )
i = 20t + 8t2 ℓ 0 = 1m ℓ 1 = 1.25m
dq
i= ⇒ ∫ dq = ∫ idt A0 = A
dt
15
2. Ans ( C ) R0 ℓ0 /A0
=
R1 ρℓ1 /A1
6−4
I= = 1A 1
=
ℓ0 ℓ 0 A0
) R1 =
ℓ21
= 1.5625W
10 5 (
R1 A0 ℓ 1 × ℓ 1 ℓ20
Vx + 4 + 8 × 1 – Vy = 0
5 So % change in resistance
Vx – Vy = – 5.6 ⇒ |Vx – Vy| = 5.6 V
3. Ans ( D ) = R1 − R0
R0
× 100%
This diagram can be drawn like 1.5625 − 1
= × 100%
1
= 56.25%
5. Ans ( D )
It is a wheat stone bridge 500 = (1.5)2 × R × 20
2R × 2R E = (3)2 × R × 20
∴ Req = ⇒R
2R + 2R E = 2000 J
1801CJA101821230146 HS-1/5
Target:JEE(MAIN & ADVANCED)-2025/07-11-2024
6. Ans ( C ) 9. Ans ( C )
20 − V0 0 − V0 20 − V0
+ + =0
5 5 2
2V0 V0
4 + 10 = +
5 2
4V0 + 5V0
14 =
x − 10 x−y x−0 10
+ + =0 140
100 15 10 V0 = V olt
53x – 20y = 30 .....(1) 9
y − 10 y−x y−0 Potential difference across 2 Ω resistor is 20 –
+ + =0 V0
60 15 5
17 y – 4x = 10 ......(2) That is (
140
20 −
) V olt
HS-2/5 1801CJA101821230146
Enthusiast Course/Phase-I(A) & I(B)/07-11-2024
12. Ans ( A ) 15. Ans ( B )
P = Vi
500 = Vi
i = 5 Amp
V=i×R
R = 20
Ans. 1
13. Ans ( D ) ⇒ I=
20
2
= 10A
Now,
16. Ans ( D )
Maximum power in external resistance is
generated when it is equal to internal resistance
of battery.
2
∈
PR = ( ) R
r+R
PR is max. when r = R
3 × 3/2 9/2
Req = = = 1Ω
3 + 3/2 9/2
14. Ans ( D )
220 I = P = 15 × 45 + 15 × 100 + 15 × 10 + 2 ×
103
b
4325 ρdr ρ b
I= = 19.66 ∫ dr = ∫ ⇒r= ln
220 2πrl 2πl a
I ≃ 20 A a
1801CJA101821230146 HS-3/5
Target:JEE(MAIN & ADVANCED)-2025/07-11-2024
17. Ans ( B ) 20. Ans ( A )
⇒ 1 = ig (G + R1) .....(1)
2. Ans ( 2.00 )
For parallel combination current devides in the
20
− 10
inverse ratio of resistance.
17 2
∴I= 70
= 0.21 A iPQ = ×6A
4+ 6
3. Ans ( 300.00 )
17
from +ve to – ve terminal
Work done by battery = Q ( Δ V)
⇒ 20 × 15 = 300 J
HS-4/5 1801CJA101821230146
Enthusiast Course/Phase-I(A) & I(B)/07-11-2024
4. Ans ( 3.00 )
21
I= = 3 mA
5+1+1
5. Ans ( 2500.00 )
Q = i2 RT
Q 10 × 10−3
R= = = 2500 Ω
i2 t 4 × 10−6 × 1
1801CJA101821230146 HS-5/5
Topic : Carboxylic Acid and Amines
CHEMISTRY
SECTION-I : (Maximum Marks: 80) 3. Which of the following reaction DOES NOT
This section contains 20 questions. Each question has involve Hoffmann Bromamide degradation ?
4 options for correct answer. Multiple-Choice
Questions (MCQs) Only one option is correct. For (A)
each question, marks will be awarded as follows:
Full Marks : +4 If correct answer is selected.
Zero Marks : 0 If none of the option is selected.
Negative Marks : –1 If wrong option is selected. (B)
1. Carbylamine test is used to detect the presence of
primary amino group in an organic compound.
Which of the following compound is formed when (C)
this test is performed with aniline?
(A) (B)
(D)
(C) (D)
C6H5CH2CN −−
→ C6H5CH2CH2NH2 product "A"
(C) HCl +
(A) (B)
C6H5NH2 −−→C6 H5 N H3 Cl−
(D) C6H5CH2Cl + NH3 → C6H5CH2NH2
6. (C) (D)
(C)
10. Primary, secondary and tertiary amines can be
separated using :-
(A) Para-Toluene sulphonyl chloride
(D)
(B) Chloroform and KOH
(C) Benzene sulphonic acid
(D) Acetyl amide
(D)
(A)
16.
(B)
Maleic anhydride
Maleic anhydride can be prepared by : (C)
(A) Heating trans-but-2-enedioic acid
(B) Heating cis-but-2-enedioic acid
(C) Treating cis-but-2-enedioic acid with alcohol (D)
and acid
(D) Treating trans-but-2-enedioic acid with
alcohol and acid
(CH3 CO)2 O
−−−−−−−→ P
(Major product)
(A)
The major product in the above reaction is :
(A)
(B)
(C)
(B)
(D)
(1)
(2)
(3) R – C ≡ N
(4) 4. When
(5)
are added to a round bottom flask
and reacted with Br2/KOH then how many organic
(6)
products are obtained?
5. The number of moles of given reactants in the
given reactions are x,y & z respectively.
(7)
Find (100x + 10y – z)
(8)
HINT – SHEET
CHEMISTRY 3. Ans ( C )
SECTION-I
1. Ans ( D )
CARBYL amine given by 1° amine
5. Ans ( D )
The process of cleavage of the C – X bond by
Ammonia molecule is known as ammonolysis.
Ex :
1801CJA101821230182 HS-1/5
Target:JEE(MAIN & ADVANCED)-2025/07-11-2024
6. Ans ( B ) 9. Ans ( D )
Hinsberg reagent (Benzene sulphonyl chloride)
gives reaction product with 1° amine and it is
soluble in dil. NaOH.
7. Ans ( C )
10. Ans ( A )
Primary amines react with Para Toluene sulfonyl
chloride to form a precipitate that is soluble in
NaOH.
Secondary amines reacts with para toluene
8. Ans ( A ) sulfonyl chloride to give a precipitate that is
insoluble in NaOH.
Tertiary amines do not react with para toluen.
11. Ans ( A )
Mechanism
12. Ans ( C )
HS-2/5 1801CJA101821230182
Enthusiast Course/Phase-I(A) & I(B)/07-11-2024
13. Ans ( A ) 18. Ans ( C )
14. Ans ( B )
19. Ans ( D )
15. Ans ( B )
20. Ans ( C )
16. Ans ( B )
Cis but 2-enoic acid
17. Ans ( C )
1801CJA101821230182 HS-3/5
Target:JEE(MAIN & ADVANCED)-2025/07-11-2024
CHEMISTRY 2. Ans ( 5 )
SECTION-II
Ans. 1, 3, 4, 6, 8
1. Ans ( 5 ) 3. Ans ( 5 )
Ans. a, b, d, e, g
4. Ans ( 3 )
It is Hoffman's Bromamide reaction and in this
Now since the molecular mass increases by 42 reaction cross over products are not obtained.
unit as a result of the reaction of the reaction of 5. Ans ( 422 )
one mole of CH3COCl with one-NH, group and
the given increase in mass is (390 – 180) 210.
Hence the number of – NH2 groups = 210/42 =
5.
HS-4/5 1801CJA101821230182
Enthusiast Course/Phase-I(A) & I(B)/07-11-2024
1801CJA101821230182 HS-5/5
Topic : Statistics, Determinant
MATHEMATICS
(A) 92
5 (A) ƒ( – 50) = 501
(B) 134 (B) ƒ( – 50) = – 1
5
536 (C) ƒ(50) = 1
(C)
25 (D) ƒ(50) = – 501
112
(D)
5 18. Let xi (1 ≤ i ≤ 10) be ten observations of a random
15. The system of linear equations variable X. If
10
∑ (xi − p) = 3 and ∑
10
2
(xi − p) = 9
i=1 i=1
λ x + 2y + 2z = 5
where 0 ≠ p ∈ R , then the standard deviation of
2 λ x + 3y + 5z = 8 these observations is :
4x + λ y + 6z = 10 has (A) √
3
5
(A) infinitely many solutions when λ = 2 7
(B)
10
(B) a unique solution when λ = – 8
(C) 9
(C) no solution when λ = 8 10
(D) 4
(D) no solution when λ = 2 5
20. Let m and M be respectively the minimum and 3. Consider the statistics of two sets of observations
maximum values of as follows :
∣ cos2 x 1 + sin2 x sin 2x ∣
Size Mean Variance
∣ ∣
∣ ∣
∣ 1 + cos2 x sin2 x sin 2x ∣ . Then the Observation I 10 2 2
∣ ∣
∣ ∣
∣ cos2 x sin2 x 1 + sin 2x ∣ Observation II n 3 1
ordered pair (m, M) is equal to
If the variance of the combined set of these two
(A) ( – 3, – 1) (B) ( – 4, – 1) 17
observations is , then the value of n is equal to
(C) (1,3) (D) ( – 3,3) 9
__________.
SECTION-II : (Maximum Marks: 20) 4.
This section contains 05 questions. Consider the following frequency distribution :
HINT – SHEET
MATHEMATICS 2. Ans ( D )
∣ 1 −2 0∣
SECTION-I ∣ ∣
1. Ans ( D ) D = ∣1
∣
∣
−1 k ∣∣ = 4 − k2
∣
∣ 3 −2 −k ∣ ∣ 0 k 4∣
∣ ∣
Δ = ∣2
∣
−4 −2 ∣∣ = 0
so, A is correct and B, C, E are incorrect. If k =
∣ ∣
2
∣ 1 2 −1 ∣ ∣ 1 −2 0∣
⇒ 24 – 2(0) – k(8) = 0 ⇒ k = 3 ∣
∣
∣
∣
∣ 10 −2 −3 ∣ D1 = ∣ −2 −1 2 ∣ = −48 ≠ 0
∣ ∣ ∣ ∣
Δx = ∣ 6 ∣
−4 −2 ∣
∣ ∣ 6 2 4∣
∣ ∣
So no solution
∣ 5m 2 −1 ∣ D is correct.
= 10(8) – 2( – 10m + 6) – 3(12 + 20m)
= 8(4 – 5m)
3. Ans ( D )
∣ 3 10 −3 ∣
2x + 3y + 2z = 9 ...(1)
∣ ∣ 3x + 2y + 2z = 9 ...(2)
Δy = ∣∣ 2 6 −2 ∣∣ x – y + 4z = 8 ...(3)
∣
∣ 1 5m −1 ∣
∣
(1) – (2) ⇒ – x + y = 0 ⇒ x – y = 0
= 3( – 6 + 10m) + 10(0) – 3(10m – 6) from (3) 4z = 8 ⇒ z = 2
=0 from (1) 2x + 3y = 5
∣ 3 −2 10 ∣ ⇒x=y=1
∣ ∣
∴ system has unique solution
Δz = ∣ 2 ∣
−4 6 ∣
∣
∣ ∣
∣ 1 2 5m ∣
= 3( – 20m – 12) – 2(6 – 10m) + 10(8)
= 40m – 32 = 8(5m – 4)
for inconsistent
4
k=3&m≠
5
1801CJA101821230175 HS-1/5
Target:JEE(MAIN & ADVANCED)-2025/07-11-2024
4. Ans ( B ) 8. Ans ( C )
R2 → R2 − R1 and R3 → R3 − R1 n1 = 100 m = 250
¯ ¯
X 1 = 15 X = 15.6
V1(x) = 9 Var(x) = 13.44
100 × 9 + 150 × σ22 100 × 150
13.44 = + ×1
250 (250)2
n2 = 150, x¯2 = 16, V2(x) = σ 2
100 × 9 + 150 × σ22 100 × 150
13.44 = + ×1
250 2
(250)
⇒ σ 22 = 16 ⇒ σ 2 = 4
9. Ans ( D )
= 4(a + 2) – 4a – 10 Mean = 6 + 10 + 7 + 13 + a + 12 + b + 12 =9
8
= 4a + 8 – 4a – 10 = – 2 60 + a + b = 72
5. Ans ( D ) a + b = 12 … (1)
2
For a, b, c ∑ x2i ∑ xi
37
variance = −( ) =
mean = a + b + c ¯
(= x) n n 4
3 Σx2i = 62 + 102 + 72 + 132 + a2 + b2 + 122 + 122
b=a+c
2b = a2 + b2 + 642
⇒ x¯ = ......(1)
3 a2 + b2 + 642 2 37
S.D. (a + 2, b + 2, c + 2) = S.D. (a, b, c) = d − (9) =
8 4
a2 + b 2 + c2 a2 + b 2 321 37
⇒ d2 = ¯ 2
− (x) + − 81 =
3 8 4 4
2
a2 + b 2 + c2 4b a2 + b 2 37 321
⇒ d2 = − = 81 + −
3 9 8 4 4
⇒ 9d2 = 3(a2 + b2 + c2) – 4b2 a2 + b 2
= 81 − 71
⇒ b2 = 3(a2 + c2) – 9d2 8
6. Ans ( A ) ∴ a2 + b2 = 80 … (2)
From (1) a2 + b2 + 2ab = 144
For non-trivial solution
∣ 4 λ 2∣
80 + 2ab = 144 ∴ 2ab = 64
∣ ∣ (a – b)2 = a2 + b2 – 2ab = 80 – 64 = 16
1 ∣∣ = 0
10. Ans ( C )
∣
∣
2 −1
∣ ∣
∣ μ 2 3∣ Given 32 + 8 α + 9 β = (8 + α + β ) × 6
⇒ 2m – 6 λ + λ m = 12 ⇒ 2a + 3 β = 16 … (i)
when µ = 6, 12 – 6 λ + 6 λ = 12 Also, 4 × 16 + 4 × α + 9 β = (8 + α + β ) × 6.8
which is satisfied by all λ ⇒ 640 + 40 α + 90 β = 544 + 68 α + 68 β
7. Ans ( D ) ⇒ 28 α – 22 β = 96
10 =
7 + 10 + 11 + 15 + a + b ⇒ 14 α – 11 β = 48 … (ii)
6 from (i) & (ii)
⇒ a + b = 17 .....(i)
2 2 2 2 α=5&β=2
20 7 + 10 + 11 + 15 + a2 + b2
= − 102 32 + 35 + 18 85 17
3 6 so, new mean = = =
a2 + b2 = 145 ......(ii) 15 15 3
Solve (i) and (ii) a = 9, b = 8 or a = 8, b = 9
|a – b| = 1
HS-2/5 1801CJA101821230175
Enthusiast Course/Phase-I(A) & I(B)/07-11-2024
11. Ans ( D ) 13. Ans ( D )
Given : ∣ 2 1 1∣
∣ ∣
= 2 (−a − 1) − 1 (a − 1) + 1 + 1
¯ =
Σxi Here D = ∣∣ 1 −1 1∣
∣
Mean (x) = 10
∣ = 1 − 3a
20 ∣
1 1 a∣
or Σ xi = 200 (incorrect) ∣ 2
∣
1 5∣
or 200 – 25 + 35 = 210 = Σ xi (Correct) ∣ ∣
= 2 (−b − 3) − 1 (b − 3) + 5 (1 + 1)
D3 = ∣∣ 1 ∣
−1 3 ∣
Now correct x¯ = 210 = 10.5 ∣ ∣ = 7 − 3b
20 ∣ 1 1 b∣
again given S.D = 2.5 ( σ ) for a = 1 , b ≠ 7 , system has no solutions
Σxi 2 3 3
σ2 =
20
– (10)2 = (2.5)2 14. Ans ( C )
or Σ xi2 = 2125 (incorrect) Let 8, 16, x1, x2, x3, x4, x5 be the observations.
or Σ xi2 = 2125 – 252 + 352 x1 + x2 +. . . +x5 + 14
Now =8
= 2725 (Correct) 7
5
2725 ⇒ xi = 42 … (1)
2
∴ correct σ = − (10.5)2 ∑
20 i=1
2
––σ– = 26 x21 + x22 +. . . x25 + 82 + 62
Also − 64 = 16
or σ = 26 7
5
∴ α = 10.5, β = 26 ⇒ ∑ x2i = 560 – 100 = 460 … (2)
12. Ans ( B ) i=1
1801CJA101821230175 HS-3/5
Target:JEE(MAIN & ADVANCED)-2025/07-11-2024
17. Ans ( C ) MATHEMATICS
R1 → R1 + R3 – 2R2 SECTION-II
= (a + c – 2b) ((x + 3)2 – (x + 2)(x + 4))
= x2 + 6x + 9 – x2 – 6x – 8 = 1
1. Ans ( 11.00 )
2
Σx2 Σx
⇒ ƒ(x) = 1 ⇒ ƒ(50) = 1 σ2 = −( )
n n
18. Ans ( C ) =
9+k 2
−(
9+k
2
) < 10
2 2
Σ(xi − p) Σ(xi − p) 10 10
Variance = −( )
90 + 10k – 81 – k2 – 18 k < 1000
2
n n
9 3 81
2
9k2 – 18k – 991 < 0
= −( ) =
10 10 100 991
k2 – 2k <
9 9
S.D. = 1000
10 (k – 1)2 <
19. Ans ( A ) −10√10
9
10√10
∣ 2 −4 λ∣ <k−1<
∣ ∣
3 3
k < 10 10 + 1
√
D= ∣
1 −6 1 ∣∣
∣
3
∣ ∣
∣ λ −10 4∣ k ≤ 11
= 2(3 λ + 2) ( λ – 3) Maximum value of k is 11.
D1 = – 2( λ – 3) 2. Ans ( 21.00 )
D2 = – 2( λ + 1)( λ – 3) We observe 5P2 – P1 = 3P3
D3 = – 2( λ – 3) So, 15 – K = – 6
When λ = 3 , then ⇒ K = 21
D = D1 = D2 = D3 = 0
⇒ Infinite many solution
3. Ans ( 5.00 )
n1 σ12 + n2 σ22 n1 n2
2 σ2 = + (x¯1 − x¯2 )2
when λ=− then D1, D2, D3 none of them is n1 + n2 (n1 + n2 )
3
n1 = 10, n2 = n, σ12 = 2, σ22 = 1
zero so equations are inconsistant
17
2 x¯1 = 2, x¯2 = 3, σ 2 =
∴ λ=− 9
3 17 10 × 2 + n 10n
= + (3 − 2)2
20. Ans ( A ) 9 n + 10 (n + 10)
2
HS-4/5 1801CJA101821230175
Enthusiast Course/Phase-I(A) & I(B)/07-11-2024
4. Ans ( 164.00 ) 5. Ans ( 5.00 )
∵ Sum of frequencies = 584 For infinite solutions
⇒ α + β = 390 Δ = Δ1 = Δ2 = Δ3 = 0
∣1 1 −1 ∣
Now, Median is at 584 = 292th ∣ ∣
2
∵ Median = 45 (lies in class 40 – 50) Δ = ∣1
∣
2 α ∣
∣
=0
∣ ∣
⇒ α + 110 + 54 + 15 = 292 ∣2 −1 1 ∣
⇒ α = 113, β = 277 ∣3 0 0∣
∣ ∣
⇒ | α – β | = 164
Δ = ∣1
∣
2 α ∣∣ = 0
∣ ∣
∣2 −1 1 ∣
Δ = 3 (2 + α) = 0
⇒ α = −2
∣1 2 −1 ∣
∣ ∣
Δ2 = ∣ 1∣
1 −2 ∣∣ = 0
∣ ∣
2 β 1 ∣
∣
1 (1 + 2β) − 2 (1 + 4) − (β − 2) = 0
β−7=0
β=7
∴ α + β = 5 Ans.
1801CJA101821230175 HS-5/5