Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_NUCLEUS & STERLING_BT Paper -1(Adv-2024-P1-Model Date: 08-12-2024
Time: 09.00Am to 12.00Pm RPTA-21 Max. Marks: 180^

KEY SHEET
MATHEMATICS
1 D 2 C 3 C 4 A 5 ABC 6 AB

7 CD 8 17 9 7 10 2 11 3 12 8

13 13 14 C 15 B 16 C 17 A

PHYSICS
18 B 19 A 20 D 21 A 22 ACD 23 ABCD

24 AD 25 200 26 2 27 3 28 9801 29 500

30 8 31 A 32 A 33 B 34 A

CHEMISTRY
35 A 36 B 37 D 38 D 39 ABCD 40 BC

41 AB 42 180 43 1 44 85 45 6 46 207

47 10 48 A 49 C 50 D 51 B
 Sri Chaitanya IIT Academy 08-12-24_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Key& Sol’s

SOLUTIONS
MATHEMATICS
1. We know that P  R  S  T  =
P  R   P  S   P T   P  R  S   P  S  T   P T  R   P  R  S  T 
By substituting the values, we get
P  R  S  T   0.69  P  R  S  T 
Now the value of P  R ' S ' T '  1   R  S  T 
 P  R ' S ' T '  1   0.69  P  R  S  T  
 The greatest value of P  R ' S ' T '   0.31.
2. Let the events A and B be the first man and second man speak truth respectively. Let R
be the event that the day is a rainy day  P  A   4 / 5; P  B   2 / 3; P  R   3 / 4
P  A  B P  R 24
Required probability  
P  A  B  P  R   P  A ' B  P  R ' 35
3. The possible events are (1) exactly 4 games played (2) exactly 5 games played (3) exactly
6 games played
 the required probability is 2  1  4  10   11
 16 32 64  16
11c  5c  7c 1
4. Clearly the required probability is 1 1 1 
25c5 138
5. P  A  : Probability that bus A will be late
P  B  : Probability that bus B will be late
P  A  :1/ 5; P  B   7 / 25; P  B / A   9 / 10

  
 P A  B  1  P  A   P  B   P  A)  B / A    7 /10 
P  A  B P  A  .P  B / A  9
P  A / B   
P  B P B 14
Probability that at least one bus is late  1  7 / 10  3 /10
probability that at least one bus is on time = P  A  B   41 / 50
rC2 r  r  1
6. The probability of drawing two red ball’s is P1  
 r  b  C2  r  b  r  b  1
bC2 b  b  1
The probability of drawing two blue ball’s P2  
 l  b  C2  r  b  r  b  1
rC1  bC1 2br
The probability of drawing one red ball and one blue ball is P3  
 r  b  C2  r  b  r  b 
Give that P1  5P2 and P3  6P2
b 1
 b  r  9; br  18;1b  r1  3 and 
r 2
7. P  E   P  E1  E2  E3   P  E1  E2  E2   P  E1  E2  E3   P  E1  E2  E3   1 / 4
1 / 32 1 5 / 32 5
A) P  E1C / E    B) P  E / E2   
1/ 4 8 1/ 4 8

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 Sri Chaitanya IIT Academy 08-12-24_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Key& Sol’s
7 / 32 7 7 / 32 7
C) P  E / E1    D) P  exactly two motors are fuctioning / E   
1/ 2 16 1/ 4 8
8. Let there exist 3 or more rational point 10n the circle x 2  y 2  2 gx  2 y  c  0
if  x1 , y1  ,  x2 , y2,  and  x3 , y3  be those 3 points then by substituting we get g,f,c as rational,
this the circle is a rational point h clearly the possible values q,k, are 1,2   h, k  can be
taken with at any restriction in 36 ways, hence the probability that at moist two ratio and
32
point exist on the circle is  8 / 9  p  q  17
36
m
1
9. clearly pk  mck   
 2
Since P4, P5, P6 are in A.P.  2.p5  p4  p6 m7
n 1

 n  1 cr 1  
1 1 1
10. P  E   1/ 2 P  Fr   ncr also P  E  Fr  
2n 2  2
n 1

Events E and Fr are independent   n  1 cr 1  

1 1 1 n
 ncr n  n  2r  2
2 2 2 r
11. For ranked 1 and 2 players to be winner and runner up respectively, they should not be
30 14 6 2 16
paired with each other in any r and  P     
31 15 7 3 31
12. Since exactly one bullet hits the animal, we need probability that exactly one of the
hunters hits the boar while the others miss.
The probability that only first hunter
hits  P  A  1  P  B   1  P  C    0.048
Similarly the chance that only second and third hunter hits are respectively
0.128 and 0.288 but the ratio of these probability is 3 : k :18  k  9
6

clearly the required probability is  

1
13.
7
14. P  E   1/ 2; P  F   1/ 5, P  E  F   1/ 10 P  E  F   3 / 5
PE 5
I) PE / E  F    II ) P  E  F / E C  F C   0
PE  F  6
1
III ) P  E / F   IV ) P  E C  F C   1  P  E  F   2 / 5
2
P  A  BC 
15. P  A   9 /10; P  B   P  A  B   8 /100 P  A / BC    9 /19
P  BC 
P  A  B   P  A  P  B   P  A  B   9 / 10
40C20 240  40C20
 A   3 / 4  ; B   3 / 4  C  
20 20
16. ; D 
4 20 241
17. Clearly P  M 2  N 2  =11/16, P  M 2  N 2  5/16, P  M 3  N 3  77/432, P  M 3  N 3  355/864

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 Sri Chaitanya IIT Academy 08-12-24_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Key& Sol’s

PHYSICS
18. Mass of the differential element is dm  0 ydy
Mass of he string up to the length y is
y 0 y 2
m   dm   0 y dy m
0 2
0 y 2
Tension at the position of element is T  mg  g
2

T
Speed of wave pulse at this location is V 

0 y 2 g g dy g 8L0
Or V   y  y or t 
2 0 y 2 dt 2 g
2
1  dy 
19. du  T   dx; v p  vw .slope
2  dx 
6v 3v V L
20. f       L  3
2L L f 3
 40
1  x     20cm
p0   p0 max sin kx  sin kx   kx   x   8 2
2 4 2 8
4

 L  160cm  L  3  4.8m
u
10u 
21. 1  wavelength of the incident sound  2  19u
f 2f
10u  u 18
f1  frequency of the incident sound =  f  f '  frequency of the
u 19
10u 
2
10u  u 11u 11 19 u
reflected sound 1  wavelength of the reflected sound   19  .
f' 18 f 18 f
1 19u 18 f 9
  
1 2 f 11 19u 11
T T 1 1 T 1 T
22. When node at O V V  v m n
 4 2 2  2  2l  4 
n 1 m 1
m     m  1, n  4
2 2 n 4
With antinode at O
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1 T 1 T m 1 1 m 1 1 T V0
m n       m  1 f min  1 
4  4  2l  4 n 2 2 n 4 4l  2
(B is wrong)
Also, when node at O.
Total nodes=6
(C is Correct)
A,C,D are Correct
[ l 2
 L  x ]
x
2
23. Tension = where x is the distance from the free end
2
L2  L  x 
2

Transverse velocity of pulse w.r.t to the string =  

2
Transverse velocity of pulse at the free end  1
3l 2 w2 l 2 2 5
Transverse velocity of pulse at the mid of string    l
8 4 8
dx  2dx
2

L2   L  x     dt
2
 t
dt 2  L2   L  x 
2
2 2
24. v p  vw .slope
25. For case 1: 
S 1 V
 
V
O
288 f app  240  240
 V V   VS  V 
f app  f  S   288  240   ...  i 
 VS  V   VS  V 
 V V   V V 
For case 2: f app  f  S   240  S  ..........  ii 
 VS  V   VS  V 
From (i) and (ii)
 V V   VS  V 
288  f app  240  S   240  
 VS  V   VS  V 
288 f app  240  240 f app  200 Hz
2 V F
26. amax   2 A  g  ,V 
 
4 2
F 4 F 2
2   amax  . Amin  g
 
2
 2
g   2
2
Amin  2 
4 F 4 F
 2
 g

 0.5   0.1
2

Amin   2 103 m  2mm

4  3.125 
27. Fundamental frequency of open organ pipe is
V 292
f0   or f 0  292 Hz
2 L 2  0.5 
Let L’ is the stressed length of the wire. The L '  L  L, where L=initial length
 L '  0.98  0.02  1m

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1 T
The fundamental frequency of stressed wire is f 0 '  ...  i 
2L '  r 2 
Where, r=radius of the wire and   density of wire. It is given that wire produces 8 beats
with open pipe. Thus,
f 0'  f 0  8 or f 0'  292  8
So, f 0'  300 Hz or f 0'  284 Hz
Increasing stress f 0' increases and it is given that beat frequency decreases. Thus,
f 0'  300 Hz
T
From Eq.  i   4 f 02  L'  
2

r 2

4 f 02  L '  4  300  1 104

2 2 2
T /r 2
Y  
L / L  L / L   0.02 / 0.98 
Or Y  1.764 1011 Nm 2   0.588  3  1011 Nm 2    3

28.

 C  V0   330  V0 
f 1  f0    f0  
 C   330 
 f  0.94 f 0
1
 0.06  330  V0  19.8m / s
19.8
2

V2  u 2
 2as  5   98m
2 2
1 1  A  2 
2

29.   A 
2 2
v    v   t  MS T
 2 2  2  
Where   0.1kg / m
1 40
A  m, M  kg ,   40rad / sec and S  4.2 kJ / kgK
5 21
30. y1  A sin 1t y2  A sin 2t yr  2 A cos
   1   2  1  
yr  2 A cos  2 t  sin t
 2  2 
cos    t
Resultant amplitude Ar  2 A0
2

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 Sri Chaitanya IIT Academy 08-12-24_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Key& Sol’s
t  1 t  1
     s   
 t s
2 2 4 2 3 6
In one cycle intensity of s, the detector remain idle for 2    s  sec
1 1 1 1
2 4 6 6
1 1 1 1
in sec cycle, active time is     sec
2 2 6 3
1
 
3
 In 12 sec interval, active time is 12     8sec
1
 
2
F F F V1 V
31. V  V1  and V2    1 3
  9 3 V2
 V V   V  3V2  Ai
A1  Ar   2 1  Ai   2  Ai  
 V1  V2   3V2  V2  2
 2V2  2V2 A A
A2  At    Ai  . Ai  i  1 1
V 
 1 2V 3V2  V2 2 A2
1 1 2 2
l  2 A2V   AV
2 2 s
We do not have the information about density (and cross-sectional s of two ropes).
SO, l1 / l2 cannot be calculated.
1
Power is P   2 A2 SV
2
2
1 P  V A  1 1 P
As    s, P   2 A2V  P  VA2  1  1 . 1  1   .3 1   2  3
2 P2  2 V2  A2  9 3 P1
32. In organ pipes, longitudinal waves exist. In strings, transverse waves exist. Open end is
an antinode, fixed (or closed) end is a node. The least distance between node and
 
antinode is and between the nodes is .
4 2
 v  v0 
33.
f ' f  
 v  vs 
34. f1  f 2
1 T 1 T

1 1 2 2
 
N1 1  l1 N 2 2  l2
2 2

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CHEMISTRY
35. L.R
3D  4 E 
80%
 5C  A
5
9mole 14mole  9  0.8  12 mole
3
3C  5G 
50%
 6B  F
12 mole 4 mole
L.R is G
6
Moles of B formed =  4  0.5  2.4
5
1 1
36. Eq. mass of KBrO3  of its mol. Mass   167
6 6
0.167 1
N Na2 S2O3  6  0.12 N
167 0.05
37. 3Cl2  6 NaOH  
 5 NaCl  NaClO3  3H 2O
n1  1 2  2
n2  5  2  10
nn 2 10 5 71
nf  1 2    Eq.wt of Cl2   42.6
n1  n2 2  10 3 5
 
3
38. Milli equivalents. Of HCl initially 10  0.5  5.
Now, milli equivalents. of NaOH consumed=Milliequivalents. Of HCl in excess=
 10  0.20  2
Therefore, milli equivalents. Of HCl consumed=milli equivalents. Of Ba(OH)2=5-2=3
Thus, equivalents of Ba(OH)2= 3  103 ,
Mass of Ba  OH 2 =Equivalents x equivalent weight
=  3 103 171/ 2   0.2565g
0.2565
Therefore, % Ba (OH)2 = 100  1.28%
20
39. H 2O2 KMnO4
N1V1  N 2V2
N  50  0.2 10
2 1 1 w 1 1
N   N H 2 O2   
50 25 25 Gmw  v  50
1 34
 strength (g/lit) =  Gmw   0.68 g / lit
50 50
 0.68 100  w
0.68 g of H 2O2  1000 ml ?  100 ml  0.068   %  0.068
1000 v
40. Let M presents the respective molecular mass
(a) If empirical formula of compound 3 is P3Q4
3M P 40
  9 M p  8M Q
3M P  4M Q 100
If empirical formula of compound 2 is P3Q5 ,

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3M p 8 / 3M Q
% of P   100   100  34.78
3M p  5 M Q 8 / 3M Q  5 M Q
Hence, option (a) is incorrect
(b) If empirical formula of compound 3 is P3Q2 ,
3M p 40 9
  4M Q  9M P  M Q   20  45
3M P  2 M Q 100 4
Hence, option (b) is correct.
(c) If empirical formula of compound 2 is PQ,
Mp 44.4
  5M P  4 M Q
M p  MQ 100
If empirical formula of compound 1 is P5Q4 then weight % of P:Q=1:1
Hence, option (c) is correct
(d) If empirical formula of compound 1 is P2Q,
2M p
%P   100  50  2 M p  M Q
M p  MQ
Hence, atomic weight of P and Q cannot be 70 and 35, respectively.
41. Let nCu2 s  a; nCus  a
Cu2 S  C u S  Ba  MnO4 2  H   Cu 2  SO2  Mn 2
6
n  factor 8 n  factor  6 n  factor 10

42. Molarity of stock solution

w 1000 5 1000
M   
Gmw V  ml  40 450
Acc. To dilution law
M 1V1  M 2V2
 5 1000 
   V1  0.1 500
 40 450 
V1  5  9  4  180ml
43. K 2Cr2O7  X n   X 5 O3  Cr 3
6 10 3  6   5  n   9 103  n  1
6
44. 14 mole HCI loses 6 mole e  ; 1mole HCI loses mole e 
14
M 36.5 14
eq. mass of HCI    85.1
 6 6
 
 14 
45. 4.44 mg CaCl2 is equivalent to 4 mg CaCO3
1.9 mg MgCl2 is equivalent to 2mg CaCO3
Total mass of CaCO3=6 mg
6  103
Hardness in ppm   106  6 ppm
103
46. 3 PbS  3O2  3Pb  3SO2

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 Sri Chaitanya IIT Academy 08-12-24_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Key& Sol’s
47. No of m. equivalents of Cl2 = No. of m. equivalents of Hypo = 10  0.11 =1
No. of m. equivalents of Cl2 in 50 ml of solution =1
No. of m. equivalents of Cl2 in 100 ml of solution=2
 w  w
 1000   2  1000  2
 G.E.W  35.5
35.5  2 71 weight of Cl2
w  g  0.071g % of available Cl2 =  100
1000 1000 weight of CaOCl2
48. I. H 2O  SO3  H 2 SO4 ;
18 g water combines with 80g of SO3
80% free SO3.
II. H 2O  SO3  H 2 SO4 ;
18 g water combines with 80g of SO3
 4.5 of H 2O combines with 20 g of SO3
100 g of oleum contains 20 g of SO3 Or 20% free SO3.
III. n-factor= (5-3)x2+8x3=28
4 2 4
IV. n-factor= 
4 2 3
49.
Sample of H2O2  w M N
(vol. strength)   % strength
v
10 Vol 3.036 0.893 1.786

20 Vol 6.072 1.786 3.572

30 Vol 9.108 2.679 5.358

50. (p) FeS2  Fe2O3  SO2
n1  1 1  1
n2  2   4   1   10  n f  n1  n2  1  10  11
(q) Cl2  OH  ClO 3  Cl
  

n1  2  5  10
n2  1 2  2
nn 10  2 10  2 5
nf  1 2   
n1  n2 10  2 12 3
(r) FeC2O4  Fe 3  CO2
nf  1 2  3
4
(s)  Fe  CN 6   Fe3  CO2  NO3
Fe : n1  1
C : n2  2  6  12
N : n3  6  8  48  n f  n1  n2  n3  1  12  48  61

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 Sri Chaitanya IIT Academy 08-12-24_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Key& Sol’s
51. 1 NaOH+Na 2CO3
1
Hph:- m. equivalents of HCl= m. equivalents of NaOH  m. equivalents of Na2CO3
2
1
w  1  m. equivalents of NaOH  m. equivalents of Na2CO3 ___ 1
2
MeOH:- m. equivalents of HCl=
m. equivalents of NaOH +m. equivalents of Na2CO3
x  m. equivalents of NaOH + m. equivalents of Na2CO3 ____  2 
1
 2   1 
m. equivalents of Na2CO3  x  w
2
equivalents of Na2CO3  2  x  w 
100  2  M Na2CO3  2  x  w 
 M Na2CO3   x  w   102
From (1), 2w =2m. equivalents of NaOH 
m. equivalents of Na2CO3   3
 3   2   2w  x  m. equivalents of NaOH
 100  1 M NaOH
 M NaOH   2 w  x   102
2) NaHCO3  Na2CO3
1
Hph: m. equivalents of Na2CO3  y
2
 m.equivalents of Na2CO3  2 y   4 
MeOH:- m. equivalents of NaHCO3  m.equivalents of Na2CO3  z   5 
From (4) &(5)
M. equivalents of NaHCO3 + 2y =z
m. equivalents of NaHCO3  z  2 y
100 1 M NaHCO3  z  2y
 M NaHCO3   z  2 y   102
From (4), m. equivalents of Na2CO3  2 y
M Na2CO3  2 100  2 y
M Na2CO3  y 102

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