SET-2
Series HFG1E/1 àíZ-nÌ H$moS>
Q.P. Code 56/1/2
amob Z§.
narjmWu àíZ-nÌ H$moS> >H$mo CÎma-nwpñVH$m Ho$
Roll No. _wI-n¥ð >na Adí` {bIo§ &
Candidates must write the Q.P. Code
on the title page of the answer-book.
agm`Z {dkmZ (g¡ÕmpÝVH$)
CHEMISTRY (Theory)
:3 : 70
Time allowed : 3 hours Maximum Marks : 70
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àíZ-nÌ _| Xm{hZo hmW H$s Amoa {XE JE àíZ-nÌ H$moS> H$mo narjmWu CÎma-nwpñVH$m Ho$ _wI-n¥ð>
na {bI| &
H¥$n`m Om±M H$a b| {H$ Bg àíZ-nÌ _| >35 àíZ h¢ &
H¥$n`m àíZ H$m CÎma {bIZm ewê$ H$aZo go nhbo, CÎma-nwpñVH$m _| àíZ H$m H«$_m§H$
Adí` {bI| &
Bg àíZ-nÌ 15 {_ZQ >H$m g_` {X`m J`m h¡ & àíZ-nÌ H$m {dVaU
10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db àíZ-nÌ H$mo
-nwpñVH$m na H$moB© CÎma Zht {bI|Jo &
Please check that this question paper contains 19 printed pages.
Q.P. Code given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 35 questions.
Please write down the serial number of the question in the
answer-book before attempting it.
15 minute time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m.,
the students will read the question paper only and will not write any
answer on the answer-book during this period.
*
56/1/2 1 P.T.O.
General Instructions :
Read the following instructions carefully and strictly follow them :
(i) This question paper contains 35 questions. All questions are compulsory.
(ii) This question paper is divided into five Sections A, B, C, D and E.
(iii) In Section A Questions no. 1 to 18 are multiple choice (MCQ) type questions,
carrying 1 mark each.
(iv) In Section B Questions no. 19 to 25 very short answer (VSA) type questions,
carrying 2 marks each.
(v) In Section C Questions no. 26 to 30 are short answer (SA) type questions,
carrying 3 marks each.
(vi) In Section D Questions no. 31 and 32 are case-based questions carrying
4 marks each.
(vii) In Section E Questions no. 33 to 35 are long answer (LA) type questions
carrying 5 marks each.
(viii) There is no overall choice. However, an internal choice has been provided in
2 questions in Section B, 2 questions in Section C, 2 questions in Section D and
2 questions in Section E.
(ix) Use of calculators is not allowed.
SECTION A
Questions no. 1 to 18 are Multiple Choice (MCQ) type Questions, carrying
1 mark each. 18 1=18
1. An -helix is a structural feature of :
(a) Sucrose (b) Starch
(c) Polypeptides (d) Nucleotides
2. The glycosidic linkage involved in linking the glucose units in amylase
part of starch is :
(a) C1 C6 linkage (b) C1 C6 linkage
(c) C1 C4 linkage (d) C1 C4 linkage
3. Ag+ (aq) + e Ag (s) E = + 0 80 V
Fe2+ (aq) + 2e Fe (s) E = 0 44 V
Find the Ecell for :
Fe (s) + 2Ag+ (aq) Fe2+ (aq) + 2Ag (s)
(a) 16V (b) 1 16 V
(c) 2 04 V (d) 1 24 V
56/1/2 3 P.T.O.
4. A first order reaction takes 30 minutes for 50% completion. The value of
rate constant k would be :
3 4
(a) 25 10 min 1 (b) 2 75 10 min 1
(c) 1 25 10 3 min 1 (d) 2 31 10 3 min 1
5. Which of the following is least basic ?
(a) (CH3)2NH (b) NH3
(c) NH2 (d) (CH3)3N
6. CH3CONH2 on reaction with NaOH and Br2 in alcoholic medium gives :
(a) CH3COONa (b) CH3NH2
(c) CH3CH2Br (d) CH3CH2NH2
ZnCl2
7. In the reaction R OH + HCl RCl + H2O, what is the correct
order of reactivity of alcohol ?
(a) 1 <2 <3 (b) 1 >3 >2
(c) 1 >2 >3 (d) 3 >1 >2
8. The colligative property used for the determination of molar mass of
polymers and proteins is :
(a) Osmotic pressure
(b) Depression in freezing point
(c) Relative lowering in vapour pressure
(d) Elevation is boiling point
9. Low concentration of oxygen in the blood and tissues of people living at
high altitude is due to :
(a) high atmospheric pressure
(b) low temperature
(c) low atmospheric pressure
(d) both low temperature and high atmospheric pressure
56/1/2 5 P.T.O.
10. Which of the following is affected by catalyst ?
(a) H (b) G
(c) Ea (d) S
11. The compounds [Co(SO4) (NH3)5] Br and [Co(Br) (NH3)5] SO4 represent :
(a) optical isomerism (b) linkage isomerism
(c) ionisation isomerism (d) coordination isomerism
12. The synthesis of alkyl fluoride is best obtained from :
(a) Free radicals (b) Swartz reaction
(c) Sandmeyer reaction (d) Finkelstein reaction
13. The most common and stable oxidation state of a Lanthanoid is :
(a) +2 (b) +3
(c) +4 (d) +6
14. The order of the reaction
h
H2 (g) + Cl2 (g) 2HCl (g) is :
(a) 2 (b) 1
(c) 0 (d) 3
For Questions number 15 to 18, two statements are given one labelled as
Assertion (A) and the other labelled as Reason (R). Select the correct
answer to these questions from the codes (a), (b), (c) and (d) as given below.
(a) Both Assertion (A) and Reason (R) are true and Reason (R) is the
correct explanation of the Assertion (A).
(b) Both Assertion (A) and Reason (R) are true, but Reason (R) is not
the correct explanation of the Assertion (A).
(c) Assertion (A) is true, but Reason (R) is false.
(d) Assertion (A) is false, but Reason (R) is true.
15. Assertion (A) : (C2H5)2NH is more basic than (C2H5)3N in aqueous
solution.
Reason (R) : In (C2H5)2NH, there is more steric hindrance and +I
effect than (C2H5)3N.
56/1/2 7 P.T.O.
16. Assertion (A) : The molecularity of the reaction H2 + Br2 2HBr
appears to be 2.
Reason (R) : Two molecules of the reactants are involved in the given
elementary reaction.
17. Assertion (A) : Acetylation of aniline gives a monosubstituted product.
Reason (R) : Activating effect of NHCOCH3 group is more than that
of amino group.
18. Assertion (A) : EDTA is used to determine hardness of water.
Reason (R) : EDTA is a bidentate ligand.
SECTION B
19. A solution is prepared by dissolving 10 g of non-volatile solute in 200 g of
water. It has a vapour pressure of 31 84 mm Hg at 308 K. Calculate the
molar mass of the solute.
(Vapour pressure of pure water at 308 K = 32 mm Hg) 2
20. Explain briefly : 1+1=2
(a) Carbylamine reaction
(b) Gabriel phthalimide synthesis
21. How would you account for : 2 1=2
(a) The E value for the Mn3+/ Mn2+ couple is much more positive than
that for Cr3+/ Cr2+ couple or Fe3+/ Fe2+ couple.
(b) Complete the following equation :
+ 2
2MnO4 + 16H + 5C O4
2
22. (a) On diluting two m
5 times. Which of the two
electrolytes is strong ? Justify your answer graphically. 2
OR
(b) The electrical resistance of a column of 0 05 mol L 1 NaOH solution
of diameter 1 cm and length 50 cm is 5 55 103 ohm. Calculate the
conductivity. 2
56/1/2 9 P.T.O.
23. (a) Predict the products of the following reactions : 2 1=2
Cu 273 K
(i) CH3CH2OH
Br2 aq
(ii) C6H5OH
OR
(b) Give reasons for the following : 2 1=2
(i) p-nitrophenol is more acidic than p-methylphenol.
(ii) (CH3)3C Br on reaction with NaOCH3 gives alkene as the
main product and not an ether.
PCl 5 AgCN
24. (a) CH3 CH CH3
|
OH
ethanol HBr
(b) CH3CH2CH2Cl + KOH
1+1=2
25. Define denaturation of protein. What is the effect of denaturation on the
structure of protein ? 2
SECTION C
26. Give reason : 3 1=3
(a) Measurement of osmotic pressure method is preferred for the
determination of molar masses of macromolecules such as proteins
and polymers.
(b) Aquatic animals are more comfortable in cold water than in warm
water.
(c) Elevation of boiling point of 1 M KCl solution is nearly double than
that of 1 M sugar solution.
56/1/2 11 P.T.O.
1 1
27. Complete the following reactions : 1 +1 =3
2 2
28. How do you convert the following : (Any three) 3 1=3
(a) Phenol to 2-Hydroxybenzaldehyde
(b) Anisole to 2-Methoxyacetophenone
(c) Propene to Propan-2-ol
(d) Ethanol to Ethanal
29. (a) What are the hydrolysis products of (i) Lactose, (ii) Maltose ?
(b) Give the basic structural difference between starch and cellulose. 3
30. (a) Explain why : 3 1=3
(i) Carboxyl group in benzoic acid is meta directing.
(ii) Sodium bisulphite is used for the purification of aldehydes and
ketones.
(iii) Carboxylic acids do not give characteristic reactions of
carbonyl group.
OR
(b) 3H8O on
I2 / NaOH. Deduce the structures of A, B and C. 3
56/1/2 13 P.T.O.
SECTION D
The following questions are case-based questions. Read the case carefully and
answer the questions that follow.
31. In coordination compounds, metals show two types of linkages, primary
and secondary. Primary valencies are ionisable and are satisfied by
negatively charged ions. Secondary valencies are
non-ionisable and are satisfied by neutral or negative ions having lone
pair of electrons. Primary valencies are non-directional while secondary
valencies decide the shape of the complexes.
(i) If PtCl2 . 2NH3 does not react with AgNO3, what will be its
formula ? 1
3+
(ii) What is the secondary valency of [Co(en)3] ? 1
(iii) (1) Write the formula of Iron(III)hexacyanidoferrate(II).
(2) Write the IUPAC name of [Co(NH3)5Cl] Cl2. 2 1=2
OR
(iii) Write the hybridization and magnetic behaviour of [Ni(CN)4]2 . 2
[Atomic number : Ni = 28]
32. The rate of reaction is concerned with decrease in concentration of
reactants or increase in the concentration of products per unit time. It
can be expressed as instantaneous rate at a particular instant of time
and average rate over a large interval of time. Mathematical
representation of rate of reaction is given by rate law. Rate constant and
order of a reaction can be determined from rate law or its integrated rate
equation.
56/1/2 15 P.T.O.
(i) What is average rate of reaction ? 1
(ii) Write two factors that affect the rate of reaction. 1
(iii) (1) What happens to rate of reaction for zero order reaction ?
(2) What is the unit of k for zero order reaction ? 2 1=2
OR
(iii) (1) For a reaction P + 2Q Products
Rate = k[P]1/2 [Q]1. What is the order of the reaction ?
(2) Define pseudo first order reaction with an example. 2 1=2
SECTION E
33. Assign reason for each of the following : 5 1=5
(i) Manganese exhibits the highest oxidation state of +7 among the 3d
series of transition elements.
(ii) Transition metals and their compounds are generally found to be
good catalysts in chemical reactions.
(iii) Cr2+ is reducing in nature while with the same d-orbital
configuration (d4) Mn3+ is an oxidising agent.
(iv) Zn has lowest enthalpy of atomization.
(v) Cu+ is unstable in an aqueous solution.
34. (a) (i) Carry out the following conversions :
(1) Ethanal to But-2-en-1-al
(2) Propanoic acid to 2-chloropropanoic acid
(ii) An alkene with molecular formula C5H10 on ozonolysis gives
a mixture of two compound
positive Fehling test and also reacts with iodine and NaOH
2+3=5
OR
56/1/2 17 P.T.O.
(b) (i) Distinguish with a suitable chemical test :
(1) CH3COCH2CH3 and CH3CH2CH2CHO
(2) Ethanal and Ethanoic acid
(ii) Write the structure of oxime of acetone.
(iii) Identify A to D. 2+1+2=5
PCl5 H2 / Pd BaSO4 (i) CH3 / MgBr
CH3COOH A B C
(ii) H3O+
LiAlH4
35. (a) (i)
Write an expression for the molar conductivity of acetic acid
at infinite dilutio
(ii) Calculate the maximum work and log Kc for the given
reaction at 298 K :
2+
Ni (s) + 2Ag+ (aq) Ni (aq) + 2Ag (s)
Given : E = 0·25 V, E = + 0·80 V
Ni 2 / Ni Ag / Ag
1
1 F = 96500 C mol 2+3=5
OR
(b) (i)
terms of Faraday, is required for the reduction of 1 mol Cu 2+
to Cu ?
(ii) Calculate emf of the following cell at 298 K for
Mg (s) Mg2+ (0 1 M) Cu2+ (0 1 M) Cu (s)
1
[ E cell = + 2 71 V, 1 F = 96500 C mol , log 10 = 1] 2+3=5
56/1/2 19 P.T.O.
