NEET MCQ Chemistry Class 12
NEET MCQ Chemistry Class 12
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• Choose correct answer from the given options. [Each carries 1 Mark] [100]
1. ) Which one of the following do not have intermolecular hydrogen bond.
(A) Ether – Water (B) Alcohol – Water (C) Ether – Ether (D) Ketone – Water
2.
252)
C=C + H2O ® C–C
H OH
From the following which one is not the suitable type for this reaction ?
(A) Acidic hydrolysis of Alkene (B) Electrophilic addition reaction of alkene
(C) Elimination reaction of Alkene (D) These reaction has three steps
3. ) Order of boiling point for isomeric primary, secondary and tertiary alcohol is .......
(A) 1° > 2° > 3° (B) 3° > 2° > 1° (C) 3° > 1° > 2° (D) 1° > 3° > 2°
4. ) Methoxy and ethanol are of which type isometers ?
(A) Functional group isomerism (B) Optical isomerism
(C) Position isomerism (D) Chain isomerism
5. ) Common formula of alcohol ........
(A) R – OH (B) Ar – OH (C) R – O – R' (D) Ar – O – R
6. ) Reduction of ethyl benzoate by LiAlH4 gives ....
(A) Phenyl ethanol + Methanol (B) Phenyl/Ethanol + Ethanol
(C) Phenyl Methanol + Ethanol (D) Phenyl Methanol + Methanol
7. ) What is the laboratory test of the phenol ?
(A) Acidic FeCl3 (B) Neutral FeCl3
(C) with Br2 water (D) Reaction with NaOH
8. ) What is the type of hybridization for carbon and oxygen in R3C – OH respectively ?
(A) sp3 – sp2 (B) sp3 – sp3 (C) sp2 – sp3 (D) sp2 – sp2
9. ) Which of the following has highest reactivity towards nucleophilic addition reaction ?
(A) Butanone (B) Propanal (C) Ethanal (D) Propanone
(i) O3
244) “X”
10. ® ethanal + propanone. What is “X” in the reaction ?
(ii) Zn dust / H 2O
(A) 2-methylpropene (B) but-2-ene (C) 3-methylbut-1-ene (D) 2-methylbut-2-ene
11. ) By which reagent, ethanal and propanal are distinguished ?
(A) Ag(NH3)+2/OH– (B) NaHSO3 (C) NaOI (D) 2, 4-DNP
12. ) Which reagent is suitable for preparation of ethanol from ethane nitrile ?
(A) anhy. (B) DIBAL-H (C) PCC (D) KMnO4/H+
13. ) .......... reagent does not react with acetone.
(A) Grignard (B) Fehling (C) Phenyl hydrazine (D) NaHSO 3
14. ) What is the correct order of the reactivity of reaction of hydrogen halide(HX) with CH3OCH3 ?
(A) HCl > HBr > HI (B) HI > HBr > HCl (C) HBr > HI > HCl (D) HCl > HI > HBr
15. ) How many isomers of phenol having formula C7H8O are possible ?
(A) 3 (B) 4 (C) 5 (D) 2
16. ) What is the correct order of acidic strength of the following compounds ?
(i) m-cresol (ii) m-nitrophenol (iii) phenol
(A) (iii) > (i) > (ii) (B) (ii) > (iii) > (i) (C) (iii) > (ii) > (i) (D) (i) > (iii) > (ii)
17. ) Which compound gives dialkyl ether as a product when heated with trace amount of H2SO4 ?
(A) propan-2-ol (B) propan-1-ol (C) 2-methylpropan-2-ol (D) 2-methylbutan-2-ol
18. ) Assertion : The bond angle in ether is lesser than tetrahedral bond angle.
Reason : There is a repulsion between two alkyl (–R) groups of ether.
(A) Both assertion and reason are correct. (B) Both assertion and reason are incorrect.
(C) Assertion is correct but reason is incorrect. (D) Reason is correct but assertion is incorrect.
19. ) Which one of the following gives only ether as a product with CH3CH2ONa ?
(A) (CH3)2CHCl (B) C6H5Cl (C) CH3CH2Cl (D) (CH3)3CCl
234) On acid catalysed hydrolysis of 2-phenylpropene, the product obtained is....
20.
(A) 3-phenylpropan-2-ol (B) 2-phenylpropan-1-ol
(C) 1-phenylpropan-3-ol (D) 2-phenylpropan-2-ol
21. ) The solubility of alcohol with low molecular mass is due to....
(A) Hydrophobic nature of carbon chain.
(B) Ionic nature of C – C bond.
(C) H-bond between alcohol and water.
(D) H-bond between hydrocarbon part of alcohol and water.
22. ) Which substance is added to alcohol used industrially to make it denatured ?
(A) FeCl3 (B) KMnO4 (C) CuSO4 (D) K2Cr2O7
23. ) Which of the following reagents cannot be used for oxidation of 1o-alcohol to aldehyde ?
(A) In anhydrous CrO3. (B) Pyridinium Chlorochromate.
(C) KMnO4 in Acidic medium. (D) Heating in presence of Cu at 573 K temp.
24. ) Which of the following component acts as a strongest base ?
(A) Bromo butane (B) Bromo ethane (C) Bromo ethene (D) Ethanol
43. ) Who discovered the nucleophilic substitution reaction for synthesis of unsymmetrical ethens ?
(A) Williamson’s (B) Grignard (C) Hofmann (D) Nernst
44. ) Ethoxy ethane is obtained by the reaction between 2 mole of ethanol with conc. H2SO4 at 413 K
temp. This reaction is known as ........
(A) Williamson’s synthesis (B) Continuous etherification
(C) Grignand reaction (D) None of these
Conc. H SO
209) 2CH3 CH2 OH ¾¾¾¾¾¾¾®
45. 2 4 X, what is X ?
413° K
(A) Ethene (B) Ethoxy ethane (C) Dimethyl ether (D) Butane
Excess conc. H SO
208) CH3CH2OH ¾¾¾¾¾¾¾¾¾¾
46. 2 4 ® X, What is X ?
443K
(A) Ethene (B) Ethane (C) Dimithyl ether (D) Butene
47. ) The solubility of ether in water is similar to that of –
(A) Alcohol having same molecular weight (B) Phenol having same molecular weight
(C) Ester having same molecular weight (D) Ketone having same molecular weight
48. ) The Boiling point of ether is very low compared to that of same molecular weight of alcohol,
because –
(A) Ether having intermolecular Vanderwall’s bond.
(B) Ether is a weak polar solvent.
) The Boiling point of ether is very low compared to that of same molecular weight of alcohol,
because –
(A) Ether having intermolecular Vanderwall’s bond.
(B) Ether is a weak polar solvent.
(C) Ether can not form intermolecular hydrogen bond.
(D) All of these
49. ) State the value of C – O – C bond angle in ether.
(A) 108o (B) 109o (C) 111.7o (D) 111o
50. ) What type of hybridisation of ‘C’ and ‘O’ in ether ?
(A) sp (B) sp2 (C) sp3 (D) dsp2
(A) CH3 – O – CH3 (B) C2H5O – C2H5 (C) (D) All of these
197) Which is the product when phenol is oxidised with chromic acid (Na2Cr2O7 + Conc. H2SO4) ?
57.
(A) 1, 4 benzoquinon (B) Resorcinol (C) Benzoyl chloride (D) Hydro qunine
196) The addition of aldehyde group to aromic molecules of phenol when it react with sodium hydroxide
58.
and chloroform is known as ......... reaction.
(A) Kolbe-Schmitt (B) Reimer-Tiemann (C) Williamson’s (D)Fries rearrangment
59. ) Which is the correct structural formula of 2 hydroxy benzoic acid (salysilic acid) ?
67.
187) , What is X ?
(A) Methoxy benzene (B) Phenoxy benzene (C) Ethoxy benzene (D) Toluene benzene
NaOH + R-X Ar–O–Ar + NaX This reaction represent which of the following ?
68. ¾¾¾¾
186) Ar OH ® ArO– Na¾¾¾®
–H O 2 –NaX
(A) Lucas test (B) Cumene test (C) Dow process (D) None of these
69. ) Reaction between solution of phenol in aq.sodium hydroxide and halo alkane will give ether, what is
the name of this process of ether preparation ?
(A) Williamson’s synthesis (B) Dow process
(C) Cumene process (D) None of these
OH + NaOH
184)
70. COCl X What is X ?
–NaCl
71.
183) X. What is X ?
(A) Phenyl acetate (B) Phenyl benzoate (C) Phenoxy benzene (D) Toluene
OH
182)
72. + CHO3COCl NaOH X + NaCl + H2O What is X ?
[H3PO4]
176)
78. + CH3 – CH = CH2 Z ; What is Z ?
523 K
(A) Cumene (B) Phenol (C) Ethyl Benzene (D) None of these
79. ) Which catalyst is used in cumene process ?
(A) H3PO4 (B) H3PO3 (C) H3PO2 (D) H2CrO4
Cl
+ 2NaOH 633 K
80.
174) X + NaCl + H2O ; what is X ?
300 bar
Na OH ONa CH3
88. ) Boiling point and solubility of phenol is more than that of other arenes and haloarene with same
molecular weight; because –
(A) Phenol can form intermolecular H - bond (B) Phenol can form weak Vander valls bond
(C) Phenol is very reactive (D) All of these are correct
89. ) What is the C – O – H bond angle in phenol ?
(A) 108.5o (B) 109o (C) 108o (D) 111.7o
90. ) In phenol, the hybrid state of C and O are respectively ..........
(A) sp3, sp2 (B) sp2, sp3 (C) sp, sp2 (D) sp2, sp
OH
CH3
91. ) What is the IUPAC name of ?
Cl
(A) 5 – chloro – 2 – methyl phenol (B) 3 – methylchloro phenol
(C) 4 – chlorohydroxy Toluene (D) 3 – chloro 1 hydroxy Toluene
OH
O2 N NO2
92. ) What is the IUPAC name of ?
NO2
(A) Picric acid (B) 2, 4, 6 Triamino phenol
(C) 2, 4, 6 Trinitro phenol (D) 2, 4, 6 Trinitro benzene
(A) Benzene phenol (B) p – cresol (C) 4 – methyl phenol (D) o – cresol
OH
CH3
96. ) State the IUPAC name of .
(A) o – cresol (B) 2 – methyl phenol (C) 3 – methyl phenol (D) m – cresol
Red P
157) CH3CH2OH + 2HI ¾¾ ¾ ¾® X + I2 + H2O What is X ?
97.
D
(A) Methane (B) Ethane (C) Ethene (D) Butane
98. ) Which of the following will reduce alcohol ?
(A) Red P (B) Black P (C) White P (D) None of these
99. ) Which reagent mixture is used in Lucas test ?
(A) Anhydrous AlCl3 (B) Anhydrous ZnCl2 + Conc. HCl
(C) Anhydrous ZnCl2 + Conc. (D) Anhydrous ZnCl2 + H2SO4
100. ) Which compound will react rapidaly with anhydrous ZnCl2 and Conc. HCl ?
(A) Propan 1-ol (B) Ethanol (C) 2-methyl Propan 2-ol (D) None of these
Section [ A ] : 1 Mark MCQ