08-02-23 - Sr.S60 - NUCLEUS & ALL - BT - Jee-Main-GTM-23 - SECOND YEAR SYLLABUS - KEY & Sol'S
08-02-23 - Sr.S60 - NUCLEUS & ALL - BT - Jee-Main-GTM-23 - SECOND YEAR SYLLABUS - KEY & Sol'S
CHEMISTRY
31 4 32 3 33 3 34 2 35 4
36 2 37 3 38 2 39 2 40 1
41 1 42 2 43 2 44 3 45 2
46 2 47 4 48 4 49 1 50 3
51 5 52 2 53 2 54 3 55 6
56 4 57 4 58 6 59 4 60 3
MATHEMATICS
61 4 62 3 63 3 64 2 65 3
66 1 67 1 68 3 69 3 70 2
71 4 72 4 73 4 74 2 75 2
76 1 77 3 78 3 79 1 80 4
81 4 82 1 83 4 84 22 85 0
86 8 87 2 88 2 89 20 90 0
SOLUTIONS
PHYSICS
1.
600
O 600 S
v v0 11
v 10v0 v0 34m / s
v v0 g
2
R
2 17
t 3
v0 3 34 3
2. y sin i1
1
5
i1
i1 2 ˆj
1 2
5 i2 P iˆ
x
2
2
1 5
Applying Snell’s law, 1 sin i1 2 sin i2 2 2 sin i2
5
P
530
5 3
4 Q
sin i2 or i2 530 4
So, unit vector in the direction of PQ will be,
5
3 ˆj 4iˆ
5
3. 9
l1 4l0 , l2 l0 , lP l1 9l0 lP l1 l2 2 l1l2 cos 9l0 4l0 l0 4l0 cos cos 1
4
2
2n n 1, 2,.... x 2n Or x n Or x 2 d 2 x n
d 2 n2 2
x S1P Or x2 d 2 x2 n2 2 2 xn x
2n
4. kt 3 d 3t 2 k k 2
D R t R t2
6 d dt 6 d 2d
5. The given system is equivalent to a spherical capacitor of inner radius b and outer
radius c. Hence, the capacity of the system will be 4 0
bc
cb
6. y 2 2 1 tan 2 1
tan 2 Or cot tan cot
x 2 2 2 2 2
y E
P 2 2, 2, 0
y
x
E tan x
tan 900
p
Er 2
RAB 3
10. both true, R is not correct explanation of A
11. Current per unit area i
At C Magnetic field due to remaining portion
2 2
b a
=magnetic field due to whole portion – magnetic field due to cavity Or
1 ib 2 0ic
B 0 2 c 0 Here I b 2 2 B
2 b b a2
2 b 2 a 2
12. both true, R is not correct explanation of A
13. 100 2 1 1
I R 0 2A I R 2 sin100t X C 50
100 C 100 0.2 103
I C 0
100 2
50
2 2 A I C 2 2 sin 100t 900 X L L 100 1 100
X L 0
100 2
100
2 A I L 2 sin 100t 900 Now, I I R I C I L 2sin 100t 450 A
2A
900
100t
900 2 2A 450
100t
14. The charge on the capacitor at time t after the connections are made is
Q Q0 e t / RC
dQ
Or, i Q0 / RC et / RC .
dt
Heat dissipated during the time t1 to t2 is
t2
U i 2 Rdt
t1
t2
Q0 2t / RC
e dt
t1 RC 2
Q02 RC1
2t 2t
2
e e RC . ………… (i)
2C
The time constant RC is 5 5.0 F 25 s .
Putting t1 25 s , t2 50 s and other values in (i),
20C 2
U
2 5.0 F
e 2
e 4 4.7 J .
15. The light contains two different frequencies. The one with larger frequency will cause
8 1015 s 1
photoelectrons with largest kinetic energy. This larger frequency is v
2 2
The maximum kinetic energy of the photoelectrons is K max hv
8 1018 1
4.14 1015 eVs s 2.0eV 5.27eV 2.0eV 3.27eV .
2
16. h h 1 M
as m
mv 3RT MT NA
m
M
1 M 2T2 4 400 8
2 M1T1 2 300 3
17. 1 1
hf1 hf0 mv12 hf 2 hf 0 mv22
2 2
1
h f1 f 2 m v12 v22
2
v12 v22
2h
m
f1 f 2
18. If Q be the charge on the capacitor, the surface charge density is Q / A and the
Q
1
electric field is KA 0 . This should not exceed the dielectric strength 1.9 10 V m .
7
Q
1.9 107 V m 1 1
Thus, the maximum charge is given by KA 0 Or, Q KA 0 1.9 10 Vm
7
5.0 102 m2 8.85 1012 Fm1 1.9 107Vm1 8.4 106 C .
19. 3 2
The side of the square is l 2.5 10 m 0.05 m As it is uniformly out in 1.0 s, the
1
speed of the loop is 0.05 ms . The emf induced in the left arm of the loop is
E N Bl
100 0.05 m s 1 0.40T 0.05m
0.1V .
0.1V
i 1.0 103 A
The current in the loop is 100 .The force on the left arm due to the
magnetic field is F NilB 100 1.0 103 A 0.05m t 0.40T
2.0 103 N . This force is towards left in the figure. To pull the loop uniformly, an
3
external force of 2.0 10 N towards right must be applied. The work done by the
force is
W 2.0 103 N 0.05m 1.0 104 J
.
20. This is an LCR series circuit. The current will be maximum when the net reactance is
1 1
1 C 2
L 4 2 2.0 103 s 1
2
L 0.1H
zero. For this, C Or, 63 nF .
3 4 3 2 4 3 4 4 3
1 sin i 2 sin r sin c sin r sin r sin r At point E sin r 1 sin
2 3 2 3 3 4 3 3 4
sin 4
2
22.
Five fringes have be shifted. 5
1 1 t 2 1 t 1 2 t
5
t
1 2
23. q'
q
k q q ' kq q
Vc 0 0 q ' Now
3a 4a 4
kq kq / 4 kq kq
VA VC 0
2a 3a 4a 6a
24. Let resistance of 400 W is R. Then resistance of 200 W will be 2R.
V2 V2
From P R Total resistance of the shown circuit will be 2R
R 400
V2 V2 V2
Pnet 2 200W
Rnet 2R
V / 200
25. l 75
r R 1 1 24 1 6
l2 60
26. 4A current flows on upper side and 2A on lower side.
0
300 30 r 3m
r
1m
B 3 0
4 3 0 2 sin 300 sin 00
4
3 sin 300 sin 300
4
3
2 3 0
4
7
2 3 10 T
27. X L 2 fL 2 50 0.7 220 Z R 2 X L2 220 2
CHEMISTRY
31. 2
Cr 3
Ecell 0.3
0.6
log 0.3 0.01log
0.1
2
0.013
3
6 Fe2
32. 10 1 H
p H log H log C C0 p 2.3
200 20
33. A0
For a zero order reaction (1)For zero order reaction K (2)Since
2t 1
2
0.25
A0 2M , t 1 1h, K 1 from equation (1) t 0.25h
2
1
34. The fraction of molecules having energy equal to or greater than Ea is:
n n 0.001
x e Ea / RT x 0.001% 105
N N 100
Ea
log x
2.3 RT
R 2 cal mol 1K 1 , T 500 K
5 Ea
log10 Ea 11.5 103 cal mol 1 11.5 kcal mol 1
2.3 2 500
35. For fcc, number of X atoms = 4/unit cell
Number of TVs = 8ZNumber of OVs = 4YNumber of atoms removed along one body
diagonal 2 X (corner) and 2Z(TVs) and IY (OV at body centre) Number of X
atoms left 4 2 Number of Y atoms left 4 1 1 3 Number of Z atoms
1 15
8 4
left 8 2 1 6 The simplest formula X 15Y3 Z6 X15Y12 Z 24 X 5Y4 Z8
4
36. 1.2 g of NaCl is 100 ml of solution 1 litre 12 g 12 M
58.5
72
7.2 g of glucose is 100 ml of solution 1 litre 72 g
180
NaCl Glucose i1 1 i2 1
12 72 12 72 58.5
C1 C2 i1C1 i2C2 1 1 0.95
58.5 180 58.5 180 30
37. As we know Pr PA0 X A PB0 X B PT PA0 X A PB0 1 X A PT PB0 X A PA0 PB0
……………… (1) But from question, PT 180 X A 90 …………… (2)
PA0 270
Equation (1) and (2) PA0 PB0 180 PB0 90; PA0 180 90 270 3 :1
PB0 90
38. Mass of acetic acid adsorbed by 2g charcoal 100 103 0.6 0.5 60
x 0.6
0.6; 0.3
m 2
H I
H CH 3
CH 2 CH 3
40. O O Li O
C CH 3
COH C CH 3
OH
LiOH I 2 NaOH
C H3 L i
CO O N a
CHI 3
41. O OH
C N
OH
CH 2 NH 2
O
HCN
LiAlH 4
NaNO2
HCl
42. OH O
Hg / H 2
CH 3 C CH
H O
CH 3 CH CH 2 CH 3 C CH 3
2
A ketone (gives +ve
Iodoform test with NaOI)
3 1 BH .THF
CH 3 C CH CH 3 CH CH OH CH 3 CH 2 CH O
2 H 2O2 / OH
(An aldehdye)
ve Iodoform test because C CH3 group is absent
5
Average bond order between Cl and O atom in NaClO3 1.67
3
53. O
Cl
NH C CH
Cl
O2 N CH CH CH 2 OH
OH
54. Greater the oxidation state of the central metal ion, greater is the stability of the
complex
55. Molecular weight of decapeptide = 796 g/mol
Total bonds to be hydrolysed = (10 – 1) = 9 per molecule
Total weight of H 2O added 9 18 162 g / mol
Total weight of hydrolysis products 796 162 958g
Total weight % of glycine (given) = 47%
958 47
Total weight of glycine in product g 450 g
100
Molecular weight of glycine 75 g / mol
450
Number of glycine molecules 6.
75
Note: A dipeptide has one peptide bond. Thus, a decapeptide has 9 peptde bonds.
56. Formic acid, Fomaldehdye, fructose, glucose
57. Three in aldol, one in cannizzaro
58. In F.C.C cations at octahedral Void r r a 3 a6
2
59. x x 1 1 x
kp1/n log log k log p y c mx m 1 n 1 log 0.6020 1log1
m m n n m
x
4
m
60. 3 1
t2g eg
MATHEMATICS
61. 2 can be taken in 2 ways 20 or 22
3 can be taken in 3 ways 30 or 32 or 34
Similarly, 5 can be taken in 4 ways 50 or 52 or 54 or 56
And 7 can be taken in 5 ways 70 or 7 2 or 7 4 or 76 or 78
Hence, total divisors which are perfect squares = 2.3.4.5 = 120.
62. A x, y B a, b, c, d A B having 2 4 8 elements Total subsets of
A B 28 256 Total no. of subsets of A B having 3 or more elements.
256 (1 null set +8 singleton set 8 C2 subset having 2 elements)
256 1 8 28 219
63. x1 x2 x3 11 x1 x2 x3 7 st
It is possible only if or For 1 case number of
y1 y2 7 y1 y2 11
solution 10 C2 .6 C1 270 For 2nd case number of solution
Total ways 270 150 420
64. Let P 4 4 cos , 3 3sin be any point on the ellipse. Then image of P w.r.t line
x 4 4 cos y 3 3sin 2 4 1 cos 3 1 sin 2
x y 2 is
1 1 2
2 2
x 5 y 2
x 5 3sin & y 2 4 cos 0 K1 160 & K 2 292
3 4
65. 4 x3 dx 4 y 3 dy 12 xy 2 dx 12 x 2 ydy
x x 2 3 y 2 dx y y 2 3 x 2 dy 0
x4 y 4 6 x2 y 2
0
ln x 4 y 4 6 x 2 y 2 ln c x4 y 4 6 x2 y 2 c
66. Triangle ABC is equilateral z 2 z 1 z z z z 1 z z 1 z
2 2
2 12 1
3z 2 2 z 1 z 2 4z2 2z 1 0 z Re z
8 4
67. I x x ln ex dx x x 1 ln x dx Let t x x e x ln x
dt 1
x x x. ln x
dx x
dt x x 1 ln x dx I dt t C x x C
68. Equation of common chord is 6 x 14 y p 2 q 2 0. it must pass through the center of
first circle p 2 q 2 50 as p 2 q 2 2 pq pq 25
/2
69. Put x tan dx sec2 d l
1
n tan
1 2
sec d
0 1 tan
2
tan
/2 /2
1
l n d n 2 n sin 2 d Now apply f x f a x property.
0 sin .cos 0
70. 5 7
8
5 x8 7 x 6 6 1 1
f x 2
dx x x
2
dx Put, 2 7 5 t
1 1 1 1 x x
x14 2 7 5 2 7 5
x x x x
dt 1 x 7
f x
c 7 2 c f 0 0 c0
t2 t 2x x 1
x7 1
f x 7 2 f 1
2x x 1 4
71. /4 5 /4 3 /2
cos x sin x dx sin x cos x dx cos x sin x 4 2 2
0 /4 5 /4
72.
1
Required area = Shaded region x2 x1 dy (integrating along y-axis)
0
7
1
1 y 2 y 1 dy sq.units
0
6
73. Point P is nearest to the given line if the tangent at P is parallel to the given line.
Now, the slope of tangent at P x1 , y1 is
dy 18 y1 3 y1
which must be equal
dx x1, y1 24 x1 4 x1
3 3 y1 3
to . Therefore, Or y1 2 x1 (i) Also, x1 , y1 lies on the curve,
2 4 x1 2
x12 y12
Hence. 1 (ii) Solving (i) and (ii), we get two points 6, 3 and 6, 3
24 18
of which 6, 3 is the nearest.
Y
X' O X
P x1, y1
M
3x 2 y 1 0
Y'
Statement 1
75. In last five thrown can there be 0, 1, 2, 3, 4, or 5 heads and the same should be in
first ten throws. n E 10 C0 .5 C0 10 C1.5 C1 10 C2 .5 C2 10 C3 .5 C3 10 C4 .5 C4 10 C5 .5 C5
3003 n s 215 32768
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 08‐02‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐23_KEY &SOL’S
76. On substituting value of y from chord to parabola, we
2
2 x 4a 2 4ax x 2 100 x 16a 2 0 x 8a & 2a On putting these values in
chord, we get values of y y 4 2a & 2a 2 length of chord is
8a 2a 2 4
2
2a 2 2a 6 3a
77. Point of intersection of parabola with x axis are
Y
O X
A B
5 1 5 1 5 1 5 1
A , 0 & B , 0 OT 2 OA.OB OT 2 . OT 1
2 2 2 2
78. Order of matrix A can be 1 32, 2 16, 4 8,8 4,16 2 & 32 1 Order of matrix B can be
1 56, 2 284 14, 7 8,8 7,14 4, 28 2, 56 1 sample space 6 8 48
Now, AB is possible only in 4 8,8 7 8 4, 4 14 16 2, 2 28 32 1,1 56
79. y
f x 1 x 2 4 x 2
2
y x2 4 Required area
2 16 2
2 x 2 x 2 4 dx square units.
0 3
80.
1 100 1 100 1 100 1 100
l2 1 x50 1 x50 dx 1 x50 dx x50 1 x50 dx l1 x50 1 x50 dx
0 0 0 0
1
101 101
50 50
1 x 1 x 1 1 1 x
1
l1 x. 1 x 50 100 49
x dx l1
50 0
dx
0 50 101 101
0
1
1 1
1 l1 5051
101
50
l1 1 x dx l1 l2 l2 1 l1
5050 0 5050 5050 l2 5050
81. As 2005! , 2006!
2006! 2007!
& 2007!
2008!
are divisible by 2004.
So, the remainder is 4
82. z2 z1 z4 z1 z4 2 2 2 2 2 2
z3 1 z1 z4 z1 z4 1 z1 z4 z1 z4 1 0
z1 z4 1 z1 z4 1
z 1
2
1 z 4
2
1 0 z4 1
rmax 2/ 3 A
max 4
rmin 2 / 12 Amin
84. 2 2 2
Expression x 2 y 4 x 9 y 4 x
9 9 x 2 4 x 18 x 2 4 x 18 x 2 4
2
22 x 2
2
Maximum value 22
85. Let mid point of chord be t 2 , 2t
As mid point of chord lies inside the ellipse. So
t 4 8t 2 1 0 t 2 0, 17 4 Also equation of chord whose mid point is t 2 , 2t is
S1 S11 i.e. t 2 x 4ty t 4 8t 2 As it passes through , 0 t 2 t 4 8t 2
t 2 8 8, 4 17
86. Any number is divisible by 3, then sum of digits must be divisible by 3. i.e.
x y 27 is divisible by 3 x y is divisible by 3 As x, y 1,3, 5,9, 0
possible pairs are 5,1 , 1, 5 , 3, 0 , 0,3 9, 0 0,9 9,3 , 3,9
87. dx dy y2
According to the question Y y X x y x x 1 xc
dy dx 2
As curve passes through 0, 0 , so c 0 Equation of curve is y 2 2 x latus
rectum = 2
88.
sin 1 x sin 1 y sin 1 x sin 1 y So
2 2 2 2
for sin 1 x sin 1 y sin 1 x & sin 1 y x1 and y 1 Area
2 2
0 1 2
required 1 x 12 dx 1 sq.units .
1 3 3
89. r2 3 r r
10!
10
1 21/2 31/3 51/5 1r1 2 2 3 3 5 5
r1 !r2 !r3 !r4 !
For rational term r1 r2 r3 r4 10, r2 , r3 & r4 are multiple of 2, 3 & 5 respectively.
r1 , r2 , r3 , r4 0, 0, 0,10 , 5, 0, 0, 5 , 2, 0, 3, 5 , 0, 2, 3, 5
3, 2, 0, 5 1, 4, 0, 5 7, 0, 3, 0 5, 2, 3, 0
3, 4, 3, 0 1, 6, 3, 0 4, 0, 6, 0 2, 2, 6, 0