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RACE # 01 PHYSICA L CHEMISTRY
M.M. : 30 TIME : 35 Min.

Single correct :
1. Which of the following is not a crystalline solid ? [3]
(A) Common salt (B) Sugar (C) Iron (D) Rubber
2. a ¹ b ¹ c, a = g = 900, b ¹ 900 represents [3]
(A) tetragonal system (B) orthorhombic system
(C) monoclinic system (D) triclinic system
3. The most unsymmetrical crystal system is : [3]
(A) Cubic (B) Hexagonal (C) Triclinic (D) Orthorhombic
4. In a face centred cubic cell, an atom at the face contributes to the unit cell,
(A) 1 part (B) 1/2 part (C) 1/4 part (D) 1/8 part
5. A compund having bcc geometry has atomic mass 54. Calculate the density of the unit cell, if its edge
length is 300 pm. (NA = 6 × 1023)
(A) 6.67 g cm–3 (B) 3.33 g cm–3 (C) 13.33 g cm–3 (D) 4.67 g cm–3
6. Volume of dil. HNO3 (d = 1.1 gm/ml, 20% w/w) that can be prepared by diluting, 50 ml of concentrated
HNO3 (d = 1.4 gm/ml, 70% w/w) with water is nearest to - [3]
(A) 150 ml *(B) 223 ml (C) 178 ml (D) 333 ml

7. If a pure compound is composed of X2Y3 molecules and consists of 60 % X by weight what is the
atomic weight of Y in term of atomic weight of X (Atomic mass of X = Mx) ? [3]

9 4 2 3
(A) M (B) M (C) M (D) M
4 x 9 x 3 x 2 x

8. Calculate the volume of Cl2 gas (in ml) liberated at 1 atm & 273 K when 1.74gm MnO2 reacts with
2.19gm HCl according to the following reaction with % yield 40. (Mn = 55) [3]

MnO2 + HCl ¾¾
® MnCl2 + Cl2 + H2O

(A) 336 ml (B) 112 ml (C) 134.4 ml (D) 44.8 ml

9. The volume (in ml) of 0.5 M NaOH required for the complete reaction with 150 ml of 1.5M H3PO3
solutions is - [3]
(A) 1350 (B) 900 (C) 1250 (D) 1150
10. Find molality of 0.1M glucose (aq.) solution (dsol = 1.218 gm/ml) (M.W.. of glucose = 180)
(A) 0.1 (B) 0.12 (C) 0.08 (D) 0.095

PHYSICAL /R # 01 E - 1/16
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RACE # 02 PHYSICA L CHEMISTRY
M.M. : 32 TIME : 35 Min.

More than one may be correct :

1. Which of the following is not a characteristic of crystalline solids ? [3]
(A) They have a regular geometry (B) They have sharp melting points
(C) They are isotropic (D) They undergo a clean cleavage
2. Bravais lattices are of [3]
(A) 10 types (B) 8 types (C) 7 types (D) 14 types
3. An element crystallizes in both fcc & bcc lattices. Then ratio of edge length of fcc unit cell to bcc unit
cell will be -

(1) 1 : 2 2 (2) 3: 2 (3) 2: 3 (4) 6 :1 [3]

4. The number of atoms per unit cell in a simple cubic, face-centred cubic and body-centered cubic structure
respectively are - [3]
(A) 1, 4, 2 (B) 1, 2, 4 (C) 8, 14, 9 (D) 8, 4, 2
5. If the coordination number of an element in its crystal lattice is 8, then packing is : [3]
(A) fcc (B) hcp (C) bcc (D) sc
6. Sodium metal crystallises in bcc lattice with the cell edge, a = 42.29 Å. What is the radius of sodium
atom ? [3]
(A) 1.86 Å (B) 16.2 Å (C) 18.3 Å (D) 1.12 Å

7. 500 mL of a gaseous hydrocarbon when burnt in excess of O2 gave 2.5 L of CO2 and 3 L of water
vapour under the same conditions. The formula of the hydrocarbon is [3]

(A) C4H8 (B) C4H10 (C) C5H6 (D) C5H12

8. Fraction of edge length covered by atoms in BCC structure is - [3]

3p 1 3
(A) 1 (B) (C) (D)
8 2 2

9. Find moles of NO(g) formed when 112 litre NH3(g) is at 1 atm & 273 K is reacted with
192 gm O2(g) according to the reaction -
4NH3(g) + 5O2(g) ® 4NO(g) + 6H2O(g)
(A) 4.8 (B) 5 (C) 6 (D) 7.2 [3]
INTEGER TYPE Subjective :
10. 500 ml of 2M CH3COOH solution is mixed with 600 ml 12% w/v CH3COOH solution, then calculate
the final molarity of solution. [3]

PHYSICAL /R # 02 E - 2/16
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RACE # 03 PHYSICA L CHEMISTRY
M.M. : 30
More than one may be correct :
1. Which of the following is a non-crystalline solid ? [3]
(A) CsCl (B) NaCl (C) CaF2 (D) Glass
2. A solid has structure in which W atoms are located at the corners of a cubic lattice, O atoms at the centre
of edges and Na atom at centre of the cube. The formula of the compound is, [3]
(A) NaWO2 (B) NaWO3 (C) Na2WO3 (D) NaWO4
3. The coordination number of a cation occupying a tetrahedral hole is : [3]
(A) 4(B) 6 (C) 8 (D) 12
4. A metallic crystal crystallizes into a lattice containing a sequence of layers AB AB AB....Any packing
of spheres leaves out voids in the lattice. What percentage of volume of this lattice is empty space,
(A) 74% (B) 26% (C) 32% (D) 48 % [3]
5. If the radius of an atom of an element is 75 pm and the lattice is body-centred cubic, the edge of the unit
cell will be ,
(A) 32.475 pm (B) 173.2 pm (C) 37.5 pm (D) 212.1 pm [3]
6. A compound formed by elements A and B has cubic structure in which A atoms are at the corners of the
cube and B atoms are at the face centres. The formula of the compound will be ,
(A) A4B3 (B) A2B (C) AB3 (D) A2B3 [3]
7. On heating 60 ml mixture containing equal volume of chlorine gas and it's gaseous oxide, volume
becomes 75 ml due to complete decomposition of oxide. On treatment with KOH volume becomes
15 ml. What is the formula of oxide of chlorine
(A) ClO2 (B) Cl2O3 (C) Cl2O (D) Cl2O7 [3]
8. 10 mole of A2B3 contains 100gm of A atom & 60 gm of B atoms. Choose the correct statements -

(A) Molecular weight of A2B3 is equal to 16 [3]

(B) Atomic weight of A is equal to 5
(C) Weight of one atom of B is equal to 2
(D) Atomic weight of B is equal to 6
9. Select the incorrect statement(s) [3]
(A) During a reaction, moles and mass of atoms remain constant
(B) For reaction 2A + 3B ¾¾
® C + 3D, for maximum product formation per gram of reactant mixture,
mass ratio of A & B must be 2 : 3
(C) Both molarity and mole fraction are temperature dependent
(D) 22.7 litre of water at S.T.P. conditions contains 6 × 1024 protons.
10. Which of the following atoms touch each other in a fcc unit cell (diagram given) - [3]

Atom 4 is at the centre of side face

5 4 Atom 5 is at the centre of back face
Atom 3 is at the centre of bottom face
1 2
3

(A) 1 & 2 (B) 1 & 3 (C) 3 & 5 (D) 3 & 4

PHYSICAL /R # 03 E-3 /16

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RACE # 04 PHYSICA L CHEMISTRY
M.M. : 30

More than one may be correct :

1. The co-ordination number of sodium oxide (Na2O) type structure is - [3]
(A) 1 : 2 (B) 4 : 4 (C) 4 : 8 (D) 8 : 4
2. An element has bcc structure having unit cells 12.08 × 1023. The number of atoms in these cells is -
(A) 12.08 × 1023 (B) 24.16 × 1023 (C) 48.38 × 1023 (D) 6.09 × 1023 [3]
3. A metal has bcc structure and the edge length of its unit cell is 3.04 Å. The volume of the unit cell in cm3
will be -
(A) 1.6 × 10–21 cm3 (B) 2.81 × 10–23 cm3 (C) 6.02 × 10—23 cm3 (D) 6.6 × 10–24 cm3 [3]
4. The compound CuCl has ZnS (ccp) structure. Its density is 3.4 g cm–3. What is the length of the edge of
the unit cell ? [Cu = 63.5, Cl = 35.5, NA = 6 × 1023 , (2.924)3 = 25] [3]
(A) 5.84 cm (B) 584.8 pm (C) 292.4 m (D) 193.3 × 10–24 cm

5. Number of electrons in 36mg of 18

8 O -2 ions are (Take NA = 6 × 1023)
(A) 1.2 × 1021 (B) 9.6 × 1021 (C) 1.2 × 1022 (D) 1.9 × 1022

6. 4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the
resultant solution is _____________. [3]

(A) 0.004 (B) 0.008 (C) 0.012 (D) 0.016

7. How many grams of sucrose (mol. wt. = 342) should be dissolved in 100 gm water in order to produce
a solution with 105° C difference between the freezing point & boiling point temperatures ?
(Unit : kf = 2 K.kg mol-1;kb = 0.56 K.kg mol-1)
(A) 34 gm (B) 46 gm (C) 72 gm (D) 342 gm [3]
8. The solubility of common salt is 36.0 gm in 100 gm of water at 20°C. If systems I, II and III contain
20.0, 18.0 and 15.0 g of the salt added to 50.0 gm of water in each case, the vapour pressures would
be in the order.
(A) I < II < III (B) I > II > III (C) I = II > III (D) I = II < III [3]
9. For a liquid normal boiling points is -173°C then at 2 atm pressure it's boiling point should be
nearly
(DHvap. = 200 cal/mole, R=2 cal/mol-KI, ln 2 = 0.7)
(A) -73°C (B) 333°C (C) 60°C (D) 103°C
10. A 2% (w/v) solution of glucose has the same elevation in B.P. as that of 5% (w/v) solution of a
non-volatile solute the molar mass of the solute is - [3]
(A) 180 (B) 450 (C) 72 (D) 18

PHYSICAL /R # 04 E-4 /16

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RACE # 05 PHYSICA L CHEMISTRY
M.M. : 30

More than one may be correct :

1. The density of KBr is 3.33 g cm–3. The length of the unit cell is 619.7 pm. Then the solid is [3]
(K = 39, Br = 80, , (6.197) = 238, NA = 6 × 10 )
3 23

(A) Face centred cubic (B) Simple cubic system

(C) Body centred cubic system (D) None of these
2. An atomic solid crystallizes in bcc lattice if circumference (surface) of atoms at the adjacent corners are
seperated by 54 pm then edge length of bcc unit cell is ( 3 = 1.7) [3]
(A) 450 pm (B) 108 pm (C) 216 pm (D) 360 pm
3. Packing fraction in fcc lattice is - [3]

p 2p p 3p
(A) (B) (C) (D)
6 6 2 3 8
4. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because
_____________.
(A) it gains water due to osmosis. (B) it loses water due to reverse osmosis. [3]
(C) it gains water due to reverse osmosis. (D) it loses water due to osmosis.

5. Value of Henry’s constant KH ____________. [3]

(A) increases with increase in temperature. (B) decreases with increase in temperature.

(C) remains constant. (D) first increases then decreases.

6. We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M, 0.01M
and 0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the order______.
(A) iA < iB < iC (B) iA > iB > iC (C) iA = iB = iC (D) iA < iB > iC [3]
7. On the basis of information given below mark the correct option. [3]
Information : On adding acetone to methanol some of the hydrogen bonds between methanol molecules
break.
(A) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will
show positive deviation from Raoult's law.
(B)At specific composition methanol-acetone mixture forms maximum boiling azeotrope and will show
positive deviation from Raoult's law.
(C) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will
show negative deviation from Raoult's law.
(D) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will
show negative deviation from Raoult's law.

PHYSICAL / R # 05 E-5 /16

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8. Which represents correct difference for an ideal solution containing non-volatile solute. [3]

Vapour
Vapour
(DS)solution
(I) (DS)Solvent
Solution
(II) (DH) Solution = (DH)solvent

Solvent or Solution
Solvent

Solution

(III) B.P.

Solvent

(A) I, II, III (B) I, III (C) II, III (D) I, II

9. Equal volumes of 1.0 M KCl and 1.0 M AgNO3 are mixed. The depression of freezing point of the
resulting solution will be (Kf(H2O) = 1.86 K kg mol–1, 1 M = 1m) [3]
(A) 3.72 K (B) 1.86 K (C) 0.93 K (D) None of these
10. In the following questions a statement of assertion followed by a statement of reason is given. Choose
the correct answer out of the following choices. [3]
(A) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(B) Assertion and reason both are correct statements but reason is not correct explanation for assertion.
(C) Assertion is correct statement but reason is wrong statement.
(D) Assertion and reason both are incorrect statements.
(E) Assertion is wrong statement but reason is correct statement.
Assertion : When methyl alcohol is added to water, boiling point of water increases.
Reason : When a volatile solute is added to a volatile solvent elevation in boiling point is observed.

PHYSICAL / R # 05 E-6 /16

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RACE # 06 PHYSICA L CHEMISTRY
M.M. : 30

More than one may be correct :

1. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent
does not depend upon ____________. [3]
(A) Temperature (B) Nature of solute (C) Pressure (D) Nature of solvent
2. Which of the following statements is false?
(A) Units of atmospheric pressure and osmotic pressure are the same. [3]
(B) In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of
lower concentration of solute to a region of higher concentration.
(C) The value of molal depression constant depends on nature of solvent.
(D) Relative lowering of vapour pressure, is a dimensionless quantity.
3. On the basis of information given below mark the correct option. Information: [3]
(i) In bromoethane and chloroethane mixture intermolecular interactions of A.A and B.B type are nearly
same as A.B type interactions.
(ii) In ethanol and acetone mixture A.A or B.B type intermolecular interactions are stronger than A.B
type interactions.
(iii) In chloroform and acetone mixture A.A or B.B type intermolecular interactions are weaker than
A.B type interactions.
(A) Solution (ii) and (iii) will follow Raoult's law.
(B) Solution (i) will follow Raoult's law.
(C) Solution (ii) will show negative deviation from Raoult's law.
(D) Solution (iii) will show positive deviation from Raoult's law.
4. KH value for Ar(g), CO2(g), HCHO (g) and CH4(g) are 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively.
Arrange these gases in the order of their increasing solubility. [3]
(A) HCHO < CH4 < CO2 < Ar (B) HCHO < CO2 < CH4 < Ar
(C) Ar < CO2 < CH4 < HCHO (D) Ar < CH4 < CO2 < HCHO
5. On dissolving sugar in water at room temperature solution feels cool to touch. Under which of the following
cases dissolution of sugar will be most rapid? [3]
(A) Sugar crystals in cold water. (B) Sugar crystals in hot water.
(C) Powdered sugar in cold water. (D) Powdered sugar in hot water.
6. For a binary ideal liquid solution, the variation in total vapour pressure versus composition of solution
is given by which of the curves? [3]

P P P P
(A) (B) (C) (D)
x1 x1 x1 x1
x2 x2 x2 x2
PHYSICAL /R # 06 E-7 /16
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7. Find type of crystallization of Ag(At. wt. = 108 amu) atom with cubical side length 5Å, if density of
crystall lattice is 2.88 gram/cm3. (NA = 6 × 1023) [3]
(A) SC (B) FCC (C) BCC (D) HCP
8. If r+ = 200 pm & r– = 500 pm in ionic crystal then cation will be present in - [3]
(A) triangular void (B) tetrahedral void (C) octahedral void (D) cubical void
Multiple correct :
9. Which of the following are correct - [3]
(A) In NaCl type crystal coordination number of cation and anion are 6
(B) In CaF2 type crystal the coordination number of cation is 4 and anion is 8
(C) In zinc blende type crystal (ZnS) the coordination number of cation and anion is 6
(D) In CsCl type crystal the coordination number of cation is 8
10. Select the correct statement for antifluorite structure (a = edge length of unit cell)
(A) 4 : 8 co-ordination (cation : anion)
a
(B) Nearest neighbour distance is 3 [3]
4

a
(C) Shortest cation -cation distance is
2

a
(D) Distance of cation to next nearest cation
2

PHYSICAL /R # 06 E-8 /16

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RACE # 07 PHYSICA L CHEMISTRY
M.M. : 30
More than one may be correct :
1. A quantity of hydrogen gas occupies a volume of 30.0 mL at a certain temperature and pressure. What
volume would half this mass of hydrogen occupy at triple the absolute temperature if the pressure
were one-ninth that of the original gas? [3]
(A) 270 mL (B) 90 mL (C) 405 mL (D) 135 mL
2. The correct statement regarding F-centre is :
(A) Electrons are held in the voids of crystals
(B) F-centre imparts colour to the crystal
(C) Conductivity of the crystal increases due to F-centre
(D) All the three above
3. A metal carbonate decomposes according to following reaction [3]
M2CO3(s) ¾¾
® M2O(s) + CO2(g)
Percentage loss in mass on complete decomposition of M2CO3(s)
(Atomic mass of M = 102)
100 50 25
(A) % (B) % (C) % (D) 15%
3 3 3
Assertion & Reason :
4. Statement-1: In diamond carbon atoms occupy alternate tetrahedral voids in the FCC lattice formed
by the carbon atoms. [3]
Statement-2: In diamond, packing fraction is more than 74%.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
5. Which of the following statements is not correct about order of a reaction. [3]
(A) The order of a reaction can be a fractional number.
(B) Order of a reaction is experimentally determined quantity.
(C) The order of a reaction is always equal to the sum of the stoichiometric coefficients of reactants in the
balanced chemical equation for a reaction.
(D) The order of a reaction is the sum of the powers of molar concentration of the reactants in the rate law
expression.
6. Which of the following expressions is correct for the rate of reaction given below? [3]
– – +
5Br (aq) + BrO3(aq) + 6H (aq) ® 3Br2(aq) + 3H2O(l)

D[Br - ] D[H + ] D[Br - ] 6 D[H + ]

(A) =5 (B) =
Dt Dt Dt 5 Dt

D[Br - ] 5 D[H + ] D[Br - ] D[H + ]

(C) = (D) = 6
Dt 6 Dt Dt Dt

PHYSICAL /R # 07 E-9 /16

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Comprehension (7 to 9)
Concentrations measured as a function of time when gaseous N2O5 as initial concentration of 0.02M
decomposes to gasesous NO2 and O2 at 50°C. The change in concentration with time is given by
the following graph.

0.03 NO2
D[NO 2]
=0.003M

Concentration(M) 0.02 D[NO2] =0.004M

0.01
O2

N2O5
q =tan–1 (2.5 × 10–5)

0.00
0 100 200 300 400 500 600 700 800
Time (s)

7. The instantaneous rate of disappearance of N2O5 at the begining of the reaction is :- [3]
(A) 2 × 10–5 M/s (B) 1 × 10–5 M/s (C) 5 × 10–5 M/s (D) Zero
8. The rate of formation of O2 during the period 600 – 700 s is [3]
(A) 4 × 10–5 M/s (B) 3 × 10–5 M/s (C) 5 × 10–5 M/s (D) 7.5 × 10–6 M/s
9. The rate of decomposition of N2O5 during the period 300 – 400 s is :- [3]
(A) 4 × 10–4 M/s (B) 3 × 10–5 M/s (C) 2 × 10–5 M/s (D) 4 × 10–8 M/s
Subjective
10. A compound formed by elements X & Y, Crystallizes in a cubic structure, where X is at the corners of
the cube and Y is at six face centers. What is the formula of the compound? If side length is 5Å,
estimate the density of the solid in gm /cm3 assuming atomic weight of X and Y as 60 amu and 90 amu
respectively. [3]

PHYSICAL /R # 07 E-10 /16

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RACE # 08 PHYSICA L CHEMISTRY
M.M. : 30
More than one may be correct :
1. How many litres of oxygen at 1atm & 273K will be required to burn completely 2.2 g of propane (C3H8)
(A) 11.2 L (B) 22.4 L (C) 5.6 L (D) 44.8 L [3]
2. A 150 ml mixutre of CO and CO2 is passed through a tube containing excess of red hot charcoal. The
volume become 200 ml due to reaction. [3]
CO2(g) + C(s) ¾¾
® 2CO(g)
Select the correct statement(s).
(A) mole percent of CO2 in the original mixture is 50
(B) mole fraction of CO in the original mixture is 0.66
(C) the original mixture contains 50 ml of CO2
(D) the orginal mixture contain 50 ml of CO.
3. The dissociation of HI molecules as shown below, occurs at a temperature of 629 K. The rate constant,
k = 3.02 × 10–5 M–1s–1
1 1
HI(g) ¾® H2(g) + I2(g)
2 2
What is order of reaction. [3]
(A) 0 (B) 1 (C) 2 (D) Can not be predicted
4. In a reaction involving the synthesis of ammonia by Haber’s process,
N2 + 3H2 2NH3, the rate of reaction was measured as = 2.5 ×10–4 mol L–1 s–1. The rate of change
of conc. of H2 will be [3]
–4
(A) 1.25 × 10 mol L s –1 –1 –4
(B) 2.50 × 10 mol L s –1 –1
–4
(C) 7.5 × 10 mol L s –1 –1 (D) 5.0 × 10–4 mol L–1 s–1
5. The density of a pure substance 'A' whose atoms pack in cubic close pack arrangement is 1 gm/cc. If B
atoms can occupy tetrahedral void and if all the tetrahedral voids are occupied by 'B' atom. What is the
density of resulting solid in gm/cc. [Atomic mass (A) = 30 gm/mol & Atomic mass (B) = 50 gm/mol]
(A) 3.33 (B) 4.33 (C) 2.33 (D) 5.33 [3]
6. Diamond structure can be considered as ZnS (Zinc blend) structure in which each Zn2+ in alternate
tetrahedral void and S2- in cubic close pack arrangement is replaced by one carbon atom. If C–C covalent
bond length in diamond is 1.5Å , what is the edge length of diamond unit cell (z = 8).
(A) 3.46 Å (B) 6.92 Å (C) 1.73 Å (D) 3 Å [3]
7. A solid is formed and it has three types of atoms X, Y, Z. X forms a FCC lattice with Y atoms occupy-
ing all the tetrahedral voids and Z atoms occupying half the octrahedral voids. The formula of the solid
is :-
(A) X2Y4Z (B) XY2Z4 (C) X4Y2Z (D) X4YZ2 [3]

PHYSICAL /R # 08 E-11 /16

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Multiple correct :
8. Select the correct statement about FCC (ABCAB...) structure. [3]
3a
(A) Distance between nearest octahedral void and tetrahedral void is
4
a
(B) Distance between two nearest octahedral void is
2
3a
(C) Distance between two nearest tetrahedral void is
2
2
(D) Distance between layer A and B is 2r
3
9. The co-ordination number of FCC structure for metals is 12, since [3]
(A) each atom touches 4 others in same plane, 3 in plane above and 3 in plane below.
(B) each atom touches 4 others in same plane, 4 in plane above and 4 in plane below.
(C) each atom touches 6 others in same layer, 3 in layer above and 3 in layer below.
(D) each atom touches 3 others in same layer, 6 in layer above and 6 in layer below.
10. In a solid AB having NaCl type structure A atoms occupy the corner of the cubic unit cell and the face
centered positions. If all the face-centered atom along one of the axes are removed, choose the correct
options: [3]
(Atomic weight of A = 40),
Atomic weight of B = 60, rA = 1.4 Å, rB = 2.8 Å
(A) the packing fraction is 0.579
(B) The density of the resultant solid is 1.008 g/cc
(C) The packing faction is 0.679
(D) The density of the resultant solid is 2.008 g/cc

PHYSICAL /R # 08 E-12 /16

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RACE # 09 PHYSICA L CHEMISTRY
M.M. : 30
More than one may be correct :
1. Consider the following reaction [3]
2Na + 2NH3 ¾¾ ® 2NaNH2 + H2(g)

2NaNH2 + C ¾¾
® Na2CN2 + 2H2 (g)

Na2CN2 + C ¾¾
® 2NaCN
51gm dry ammonia gas is passed over excess heated sodium to form sodamide (NaNH2) which is further
reacted with carbon (excess) to finally form NaCN. Find the total volume of H2(g) evolved at 0.5 atm,
273K [3]
(A) 201.6 L (B) 100.8 L (C) 403.2 L (D) 50.4 L
2. The order of reaction A ¾® product can be given by the expression (s) [3]
[where r = rate of reaction ; [A]1 = concentration at time t1 ; [A]2 = concentration at time t2]
ln r2 - ln r1 ln[A 0 ]2 - ln[A0 ]1 æ -d(A) ö ln(r / k)
(A) (B) ln[t ] - ln[t ] (C) ln ç ÷ / ln[A] (D)
ln[A]2 - ln[A]1 1/ 2 2 1/ 2 1 è k.dt ø ln[A]
3. If decomposition of H2O2 in aqueous medium follows first order kinetics then which of the following
are correct [3]
(A) It is an example of single step reaction (B) It is an example of complex reaction
(C) Half life of reaction varies with time (D) Half life of reaction varies with temperature
4. An ionic solid has some point defect but its experimental density is equal to its theoretical density.
The type of defect is [3]
(A) Schottky defect (B) Frenkel defect
(C) Metal excess defect (D) Metal deficient defect
5. If the concentration of the reactants in the reaction 2A + B ® C + D is increased by three folds, the rate
of the reaction will be increased by-
(A) 27 times (B) 9 times (C) 64 times (D) 01 times
6. Substance A reacts according to a first order rate law with
k = 5.0 × 10–5 s–1. If the initial conc. of A is 1.0 M, the initial rate is
(A) 1 × 10–5 Ms–1 (B) 5.0 × 10–5 Ms–1 (C) 1 × 10–4 Ms–1 (D) 5.0 × 10–4 Ms–1
7. Following data are obtained for the reaction A + B ® product
[A] [B] Rate
(mole L–1) (mole L–1) (mole L–1 s–1)
4 × 10–2 4 × 10–2 2 × 10–2
4 × 10–2 8 × 10–2 4 × 10–2
2 × 10–2 8 × 10–2 2 × 10–2
The reaction confirms the rate law
d[B] d[B] d[B] d[A]
(A) – = k [A] (B) – = k [A] [B]2 (C) – = k [A] [B] (D) – = k [B]
dt dt dt dt

PHYSICAL /R # 09 E-13 /16

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8. If a graph is plotted between log (a – x) and t, the slope of the straight line is equal to – 0.03. The specific
reaction rate will be :
(A) 6.9 × 10–2 (B) 6.9 (C) 0.69 (D) 6.9 × 10–4
9. The half life period of a first order reaction is 100 seconds. Its rate constant is :
(A) 0.693 sec–1 (B) 6.93 × 10–3 sec–1 (C) 6.93 × 10–2 sec–1 (D) None of these
Integer :
10. 280 g of a mixture containing CH4 and C2H6 in 5 : 2 molar ratio is burnt in presence of excess of oxygen.
Calculate total moles of CO2 produced. [3]

PHYSICAL /R # 09 E-14 /16

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RACE # 10 PHYSICA L CHEMISTRY
M.M. : 30
More than one may be correct
1. Aspartame, an artificial sweetener contains 9.52 wt.% nitrogen. There are two nitrogen atoms per mol-
ecule. What is the molecular weight of aspartame ?
(A) 147 (B) 294 (C) 588 (D) 266
2. The following kinetic data are provided for a reaction between A and B : [3]
Concentration Concentration Rate of reaction
of A(M) of B(M) (M min–1)
0.50 0.02 1.15 × 10–4
0.50 0.04 2.30 × 10–4
0.01 1.00 2.30 × 10–6
0.02 1.00 0.92 × 10–5
Then value of the rate constant for the above reaction is equal to :
(A) 1.15 × 10–4 dm3/mol min (B) 2.30 × 10–4 dm6/mol2 min
(C) 2.30 × 10–2 dm6/mol2 min (D) 1.15 × 10–2 dm3/mol min
d[D]
3. The rate law for the reaction : 2 C + D ® A + E is – = k[C]2 [D] [3]
dt
If C is present in large excess, the order of the reaction will be -
(A) Zero (B) First (C) Second (D) Third
1
4. The half life period of a chemical reaction is given by : t 1 µ [3]
2
a n-1
The order of the reaction is :
(A) n (B) n – 1 (C) n + 1 (D) None of these
5. In the equation of a first order reaction Ct = C0e–kt if the initial concentration C0 is increased m times then
[3]
(A) The value of k will increase m times (B) The value of k will decrease m times
(C) The value of k will remains unchanged (D) None of these
6. In a second order reaction 20% of a substance is dissociated in 40 minutes. The time taken by the 80%
of its dissociation is
(A) 160 minutes (B) 640 minutes (C) 200 minute (D) 320 minute [3]
7. 75% of a first order reaction was completed in 32 minutes. When was 50% of the reaction completed.
(A) 24 minutes (B) 8 minutes (C) 16 minutes (D) 4 minutes [3]
8. Select the correct statement regarding truncated tetrahedron [3]
(A) having 12 vertices (B) having 8 faces
(C) having 18 edges (D) having 3 hexagonal faces

PHYSICAL /R # 10 E-15 /16

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MATCH THE COLUMN :

9. Column (Order) Column II [5]

1
(A) Zero (P) (a – x) 2

(B) First (Q) log(t1/2) 45°

log a

(C) Second (R)

(a–x)

(D) Third (S) log(t1/2)

log a

(T) (a-x)

t
Integer :
10. 5.00 moles of hydrogen gas, 3 moles of white phosphorus {P4(s)} and 12 moles of oxygen gas are taken
in a sealed flask and allowed to react as follows : [3]
H2(g) + P4(s) + O2(g) ¾® H3PO4
Determine the moles of ortho-phosphoric acid that can be produced, considering that the reaction occurs
in 90% yield.

PHYSICAL /R # 10 E-16 /16

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RACE # 11 PHYSICA L CHEMISTRY
M.M. : 30

More than one may be correct

1. Consider a first order gas phase decomposition reaction given below : [3]
A(g) ¾¾
® B(g) + C(g)
The initial pressure of the system before decomposition of A was pi. After lapse of time ‘t’, total pressure
of the system increased by x units and became ‘pt’ The rate constant k for the reaction is given as
_________.
2.303 pi 2.303 pi
(A) k = t log p - x (B) k = t log 2p - p
i i t

2.303 pi 2.303 p
(C) k = t
log
2p i + p t (D) k = t
log i
pi + x
2. A graph of volume of hydrogen released vs time for the reaction between zinc and dil.HCl is given
in Figure-I On the basis of this mark the correct option. [3]
V3 - V2 V5
(A) Average rate upto 40s is V4
40
V3 - V2 V3
(B) Average rate upto 40 seconds is
40 - 30 Figure-I
V2
V3 V1
(C) Average rate upto 40 seconds is
40
V - V1
(D) Average rate upto 40 seconds is 3
40 - 20 O 20 30 40 50
3. Consider the graph given in Figure-I. Which of the following options does not show instantaneous
rate of reaction at 40th second?

V5 - V2 V4 - V2 V3 - V2 V3 - V1
(A) (B) (C) (D)
50 - 30 50 - 30 40 - 30 40 - 20
4. For the gase phase reaction : R – H + X2 ® R – X + HX [3]
Following mechanism has been proposed :
ˆˆˆ
k
(i) X2 ‡ˆˆ †
ˆ 2X•
1

k 2

(ii) X• + R –H ¾¾®
k
R•+ H–X (slowest)3

(iii) R•+ X2 ¾¾® R –X + X•

k4

Based on this select the correst option (s)

k1
(A) Effective rate constant for the formation of RX is k3k 4
k2

d[RX]
(B) µ [X2 ]
dt
(C) Overall order of the reaction is 3/2
d[RX]
(D) µ [RH]1
dt
PHYSICAL /R # 11 E-1 /E
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5. A compound containing 5 gm sulphur and 5gm oxygen atom. Then empirical formula of
compound is :

(A) SO (B) SO2 (C) S2O (D) SO3 [3]

6. 60 gm of an organic compound containing C,H & O atoms on complete combustion gave 88gm
CO2 & 36gm H2O. The empirical formula of the organic compound is :

(A) C2HO (B) CHO (C) CH2O (D) CHO 2 [3]

7. For a reaction of order n, what is the relationship between t3/4 and t1/2, where t3/4 is the time required
for concentration (C) to become 1/4. C0 and C are the values of the reactant concentration at the start
and after time t, respectively. [3]
n–1 n–1 n+1 n+1
(A) t3/4 = t1/2 [2 + 1] (B) t3/4 = t1/2[2 – 1] (C) t3/4 = t1/2 [2 – 1] (D) t3/4 = t1/2 [2 + 1]
Paragraph for Question 9 to 11
In the case of crystalline solids, the lattice points are occupied by molecules, atoms or ions. In addition
to the corners, face centres and body centres, the species can occupy interstitial sites also. The re-
lationship between the length of edge of unit cell and the radius of atom or ion forming the crystal
depends on the type of unit cell. The coordination number of cation and that of anion in the ionic
crystal depends on the radius ratio (r+/r– ).
8. A solid AB has a rock salt type structure. If the radius of the cation (A+) is 100 pm, what is the maximum
possible radius of the anion (B–) :- [3]
(A) 241 pm (B) 137 pm (C) 200 pm (D) 150 pm
9. What is the effective number of AB ionic pair per unit cell ? [3]
(A) 6 (B) 4 (C) 2 (D) 1
+
10. The number of octahedral voids occupied by Na per unit cell in rock salt type structure is :-[3]
(A) 6 (B) 4 (C) 2 (D) 1

PHYSICAL /R # 11 E-2 /E
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RACE # 12 PHYSICA L CHEMISTRY
M.M. : 30
One or more than may be correct :
1. In the presence of a catalyst, the heat evolved or absorbed during the reaction ___________. [3]
(A) increases. (B) decreases.
(C) remains unchanged. (D) may increase or decrease.
2. For a complex reaction ______________. [3]
(A) order of overall reaction is same as molecularity of the slowest step (provided slowest step having no
reaction intermediate)
(B) order of overall reaction is less than the molecularity of the slowest step.
(C) order of overall reaction is greater than molecularity of the slowest step.
(D) molecularity of the slowest step is never zero or non interger.
3. Mark the incorrect statements. [3]
(A) Catalyst provides an alternative pathway to reaction mechanism.
(B) Catalyst raises the activation energy.
(C) Catalyst lowers the activation energy.
(D) Catalyst alters enthalpy change of the reaction.
4. In fcc unit cell number of tetrahedral voids present along one of its body diagonal
(A) one (B) two (C) four (D) eight [3]
5. At 912ºC and 105 Pa, a-Iron (bcc form) may be transformed into g-iron (fcc form). If density of
a-iron is r then what is density of g-iron (assume no change in radius of iron atom )- [3]

r´ 0.68 4r 3 ´r 1.5
(A) r/0.74 (B) (C) (D)
0.74 3 1.5 4
6. Consider Figure and mark the correct option. [3]
Activated complex

E1
Energy®

Products
E2
Reactants

(A) Activation energy of forward reaction is E1 + E2 and product is less stable than reactant.
(B) Activation energy of forward reaction is E1+E2 and product is more stable than reactant.
(C) Activation energy of both forward and backward reaction is E1 + E2 and reactant is more stable
than product.
(D) Activation energy of backward reaction is E1 and product is more stable than reactant.

PHYSICAL /R # 12 E-3 /E
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7. For a gas reaction A ® P at T (K) the rate is given by [3]

rate = k1 pA2 atm/hr
rate = k2CA2 mol/litre/hr
the relation between k1 and k2 is
(A) k2 = k1 (B) k2 = k1 RT (C) k2 = k1/RT (D) k2 = k1(RT)2
8. For the reactions (i) A ¾¾
KI
® P. [3]

& (ii) B ¾¾®

K II Q, following observation is made.

1M
Concentration

1M
Concentration

0.5
[A] 0.5
0.25
[B]
0 30 60
Time (min) 60 Time (min)

KI
Calculate K , where K1 and KII are rate constants for the respective reaction.
II

(A) 2.772 (B) 1 (C) 0.36 (D) None of these

9. Consider the Arrhenius equation given below and mark the correct option. k = A e–Ea / RT [3]
(A) Rate constant increases exponentially with increasing activation energy and decreasing temperature.
(B) Rate constant decreases exponentially with increasing activation energy and decreasing temperature.
(C) Rate constant increases exponentially with decreasing activation energy and decreasing temperature.
(D) Rate constant increases exponentially with decreasing activation energy and increasing temperature.
10. tx/y= time in which x/y fraction of reactant converts into product. [3]
ColumnI Column II
(A) t5/9 (P) Equal to 54 sec. if t1/3 is 18 sec. in case of first order reaction.
(B) t19/27 (Q) Equal to 32 sec. if t1/4 is 16 sec. in case of first order reaction.
(C) t7/8 (R) Equal to 56 sec. if t1/3 is 4 sec. in case of second order reaction.
(D) t7/16 (S) Equal to 30 sec. if t1/3 is 18 sec. in case of zero order reaction.
(T) Equal to 28 sec. if t1/2 is 16 sec. in case of zero order reaction.

PHYSICAL /R # 12 E-4 /E
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RACE # 13 PHYSICA L CHEMISTRY
M.M. : 30
One or more than one may be correct :
1. Which of the following (s) influence the rate of chemical reactions. [3]
(A) Catalyst (B) Nature of reactants
(C) Concentration of reactant (D) Temperature
2. In which of the following process involving ideal gas in a closed container internal energy does not remains
constant during the entire process - [3]

PV
PV PV

P
(A) (B) (C) (D)
P
1/V V V
2 3
3. Select the correct statements considering given fcc unit cell 9
4
1
(A) sphere 11 & 14 touch each other 14
10 12
(B) sphere 10 & 14 touch each other
8 13 5
(C) sphere 10 & 12 are at a distance of 2 2 r 11
7 6
(D) There are six planes in the fcc unit cell having such arrangement of atoms [3]

4. For any reaction A(g) ® P(s) following observation is made : [3]

Time (min) Partial pressure of A ( in bar)
0 20
20 10
60 5
Order of the reaction may be -
(A) –1 (B) 0 (C) 1 (D) 2
5. Half lives for a zero order (A ® B) & Ist order reaction (A ® P) are same. Then starting with
same intial concentratiion of 'A' the ratio of intial rate of first order & zero order will be -

0.693 1
(A) 0.693 (B) (C) 0.693 × 2 (D) [3]
2 0.693
6. For any fist order reaction following observation is made [3]
log K
16

0
1 (S.I Units)
T

PHYSICAL /R # 13 E-5 /E
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If at temperature (T) half life of the reaction is 6930 sec. & at temperature (T') half life of the reaction
T'
is 0.693 msec. Then calculate .
T
(A) 2 (B) 4 (C) 6 (D) 8
7. In a chemical reaction A(g) is converted to B(g), following observation is made. Identify the correct
statement(s) [3]
PB

Pressure (atm)
8
6
4
PA
2

10 20 30 time(min.)
1
(A) Chemical reaction should be A(g) ¾® B(g)
2
(B) t1/2 of the reaction in independent of initial partial pressure of A.
(C) Reaction must be complex reaction.
(D) Time of completion for the reaction is 40 minutes.
1 1
8. The slope of the line for the graph of log k versus for the reaction, N2O5 ® 2NO2 + O2 is – 5000.
T 2
Calculate the energy of activation of the reaction - (kJ K–1 mol—1)
(A) 95.7 (B) 9.57 (C) 957 (D) None [3]

9. For a reaction, the rate constant is expressed as, k = A.e–40000/T . The energy of the activation is :
(A) 40000 cal (B) 88000 cal (C) 80000 cal (D) 8000 cal [3]

10. A reaction takes place in three steps. The rate constants are k1, k2 and k3. The over all rate constant

k = k1k 3 . If (energy of activation) E1, E2 and E3 are 60, 30 and 10 kJ. The overall energy of activation is
k2

(A) 40 (B) 30 (C) 400 (D) 60 [3]

PHYSICAL /R # 13 E-6 /E
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RACE # 14 PHYSICA L CHEMISTRY
M.M. : 30

More than one may be correct :

1. The half life for a reaction is .... of temperature : [3]
(A) independent (B) increased with increase
(C) decreased with increase (D) dependent
2. A substance undergoes first order decomposition. The decomposition follows two parallel first order reactions
as :
K1 B
K1=1.26 × 10–4sec–1
A and K2=3.8 × 10 –5sec–1
K2
C
The percentage distribution of B and C are :
(A) 80% B and 20% C (B) 76.83% B and 23.17% C [3]
(C) 90% B and 10% C (D) 60% B and 40% C
d[B]
3. For a reaction A ¾¾
k1
® B ¾¾¾
¾ k2
® C. If the reaction are of I st order then is equal to :
dt
(A) – k2[B] (B) + k1 [A] (C) k1 [A] – k2 [B] (D) k1 [A] + k2 [B]
4. In a certain reaction 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours
and so on. Dimension of the velocity constant (rate constant) are- [3]
(A) Hour –1 –1
(B) Mol litre hour –1

–1
(C) Litre mol sec –1 (D) Mol sec–1
5. Which of the following statements is correct? [3]
(A) The presence of reacting species in a covered beaker is an example of open system.
(B) There is an exchange of energy as well as matter between the system and the surroundings in a closed
system.
(C) The presence of reactants in a closed vessel made up of copper is an example of a closed system.
(D) The presence of reactants in a thermos flask or any other closed insulated vessel is an example of
a closed system.

æ r 2+ ö
6. The radius ratio of P2+ and Q– ions ç P ÷ is 0.8. The unit cell of this ionic solid is [3]
çr - ÷
è Q ø

(A) Simple cubic for Q– ions and P2+ ions are in cubic voids
(B) Face centered cubic for Q– ions and P2+ ions occupy all the tetrahedral voids.
(C) Face centered cubic for P2+ ions and Q– ions occupy all the tetrahedral voids.
(D) Face centered cubic for Q– ions and P2+ ions occupy 50% of octahedral voids.
7. The gaseous decomposition reaction, A(g) ¾® 2B(g) + C(g) is observed to first order over the excess
of liquid water at 25°C. It is found that after 10 minute the total pressure of system is 188 torr and
after very long time it is 388 torr. The rate constant of the reaction (in hr–1) is : [3]
[Given : vapour pressure of H2O at 25° is 28 torr (In 2 = 0.7, 3 = 1.1, In 10 = 2.3)]
(A) 0.02 (B) 1.2 (C) 0.2 (D) None of these
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8. 2 mol of He gas is undergoing through following process - [3]

work during the process ABCD is -
C
(A) +100 R B
V(litre)
(B) + 200 R
A
(C) 300 R 1
(D) 400 R D
9. The incorrect statement is- 500 600
T(K)
400
(A) All the collisions between reactant molecules do not lead to a chemical change [3]
(B) A zero order reaction proceeds at a constant rate independent of concentration or time
(C) Fast reactions have low activation energies
(D) In a first order reaction, the reaction ideally takes finite time to be completed
10. A state function is that :
(A) Which is used in thermochemistry [3]
(B) Quantity whose value depends on path of process.
(C) Quantity whose value depends only upon the state of the system
(D) Quantity which is used in measuring thermal change

PHYSICAL /R # 14 E-8 /E
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RACE # 15 PHYSICA L CHEMISTRY
M.M. : 47
1. Mark as true or false with appropriate reason - [2 × 10 = 20]
Assertion T/F Reason

1. DH is a state function
2. CV is independent of T for a perfect (ideal) gas.
3. DU = q + w for every thermodynamic system
at rest in the absence of external field.
4. A process in which final temperature equals
initial temperature must be an isothermal process

5. U remain constant in every isothermal process

in a closed system
6. q = 0 for every cyclic process.
7. DU = 0 for every cyclic process.
8. A thermodynamic process is specified by
specifying only initial and final state of system.

9. P-V work is usually negligible for solid and liquid.

10. If neither heat nor matter can enter or leave a
system, that system must be isolated.

2. For a reaction A ® P [3]

1
[A]t2

time
Find order of reaction based on the graph
(A) 0 (B) 1 (C) 2 (D) 3
3. Which amongst the following is an extensive property of the system - [3]
(A) Temperature (B) Volume
(C) Specific heat capacity (D) Refractive index
4. Which of the following is not a state function of thermodynamic system -
(A) Internal energy(E) (B) Free energy(G)
(C) Enthalpy(H) (D) Work(W)

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5. What is true for a cyclic process

(A) W= 0 (B) DU = 0 (C) D H = 0 (D) B & C both [3]
6. Thermodynamics mainly deals with [3]
(A) interrelation of various forms of energy and their transformation from one form to another.
(B) energy changes in the processes which depend only on initial and final states of the microscopic
systems containing a few molecules.
(C) how and at what rate these energy transformations are carried out.
(D) the system in equilibrium state or moving from one equilibrium state to another equilibrium state.
7. In an exothermic reaction, heat is evolved, and system loses heat to the surrounding. For such system
(A) qp will be negative (B) DrH will be negative [3]
(C) qp will be positive (D) DrH will be positive
8. A system is provided 50 J of heat and work done on the system is 10 J. The change in internal energy during
the process is :- [3]
(A) 40 J (B) 60 J (C) 80 J (D) 50 J
Subjective
9. The volume, V, of a right circular cylinder is given by V = pr2h, where r is the radius and h is the height of
cylinder. Show that [3]
(a) dV = pr2dh + 2prh dr
(b) V is state function
10. In the PV-diagram shown if figure, [3]
Find the work done in the process ABC (in l-atm)

3 C
P B .
(atm)
1 A

1 2
V (lit.)

PHYSICAL /R # 15 E-10 /E
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RACE # 16 PHYSICA L CHEMISTRY
M.M. : 30 TIME : 35 Min.

MORE THAN ONE MAY BE CORRECT :

1. Which of the following statement is/are true for one mole of an ideal gas ? [3]
æ ¶H ö æ ¶U ö æ ¶H ö æ ¶U ö
(A) ç ÷ -ç ÷ =R (B) ç ÷ >ç ÷
è ¶T ø P è ¶T ø V è ¶T ø P è ¶T ø V
æ ¶H ö æ ¶H ö
(C) ç ÷ =0 (D) ç ÷ =0
è ¶V ø T è ¶P øT
2. The spontaneity means, having the potential to proceed without the assistance of external agency. The
processes which occur spontaneously are [3]
(A) flow of heat from colder to warmer body.
(B) gas in a container contracting into one corner.
(C) gas expanding to fill the available volume.
(D) burning carbon in oxygen to give carbon dioxide.
3. Following graph for the reaction is given. What is enthalpy of reaction (DrH°) ? [3]

tan–1(1000)
log KP

1/T(K–1)
(A) –4.606 cal (B) +4.606 cal (C) –4.606 kcal (D) –2 kcal
4. During an adiabatic process, the pressure of a gas is found to be proportional to cube of its absolute
temperature. The poisson‘s ratio of gas is :- [3]
(A) 3/2 (B) 7/2 (C) 5/3 (D) 9/7
q rev
5. The entropy change can be calculated by using the expression DS = . When water freezes in a glass
T
beaker, choose the correct statement amongst the following : [3]
(A) DS (system) decreases but DS (surroundings) remains the same.
(B) DS (system) increases but DS (surroundings) decreases.
(C) DS (system) decreases but DS (surroundings) increases.
(D) DS (system) decreases and DS (surroundings) also decreases.
6. For the following reaction :
CDiamond + O2 ¾® CO2(g) ; DH = –94.3 kcal
CGraphite + O2 ¾® CO2(g); DH = –97.6 kcal
The heat required to change 1 g of Cdiamond ¾® Cgraphite is :-
(A) 1.59 kcal (B) 0.1375 kcal (C) 0.55 kcal (D) 0.275 kcal

PHYSICAL /R # 16 E-11 /E
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7. Which of the following are correct for allotropes - [3]

(A) It is used for elements not for compound
(B) Two allotropes must have same chemical formula
(C) Two allotropes may or may not have same chemical formula
(D) Allotropes have same state of matter and different crystalline structure in solid state.

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8. A gas expands slowly against a variable pressure given by p = bar, where V is volume of gas at each
V

stage of expansion. During expansion from volume 10 L to 100 L the gas undergoes an increase in internal
energy of 400 J. How much heat is absorbed by gas during expansion. [3]
(A) 1900 J (B) 2300 J (C) 2700 J (D) 423 J
9. An ideal gas initially at Po, Vo & To is expanded isothermally to twice it’s volume & then compressed at
constant pressure to have the original volume Vo. Finally the gas is heated at constant volume to get original
temperature, what is correct. [3]
(A) P–V diagram for the process is
(B) Total heat exchange is 0.193 Po Vo
(C) Net work is done by the gas
(D) Interal energy remain same during the whole process
INTEGER :
10. An ideal gas sample (g = 1.5) is expanded adiabatically from 2 atm, 300 K against a constant external
x
pressure of 1 atm. If decrease in temperature is 'x' kelvin then calculate . [3]
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PHYSICAL /R # 16 E-12 /E