2 Chem
2 Chem
o Where does hydrogen occur in the free state? (a) a monovalent metal (b) a divalent metal.
Gi) How did the name "hydrogen' originate ? Ans. (i) 2Na + H, A 2NaH
A() Hydrogen is found in minute traces in the (sodium hydride)
earth's crust and the earth's atmosphere. The
atmosphere around the sun and stars is found
(ii) Ca + H CaH,
(Calcium hydride)
to contain 1.1% hydrogen.
(ü) Henry Cavendish when prepared this gas 3. Which metal is preferred for collecting hydrogen
from :
from iron and dil. acids, he established its (a) cold water (b) hot water (c) steam
elementary nature and showed that when
the gas burns in air, water is formed. It was Write balanced equation for each.
on account of this property that Lavoisier in Ans. Collection of hydrogen from
1783 named it hydrogen (Greek word (a) Cold Water:Sodium metal wrapped in small
meaning water-former). piece of wire gauze or Sodium amalga
. Hydrogen can be prepared with the help of cold mated with mercury is used. This prevents
water. Give a reaction of hydrogen with : sodium from darting about.
2 Na + H, O 2 NaOH + H, T
(ii) The heat liberated ignites
(b) From hot water : Zn or Mg can be used the
Mg + H,0 ’ MgO +H, 1
(ii) Calcium is expensive.
(ii) Iron : Iron re acts slowly at hydrogr
hydrogen produced also containheatiorng.dinaThe
ry
(Boiling water) temperatures, hence requires
(c) Steam: Iron reacts with steam when it is
red hot as hydrogen is blown out of contact
with iron by the force of current of fhe
like sulphur dioxide and hydrogen
Hence it is not used in lab
imsumpurlphiidtie.e,
steam
Fe,0, + 4H, 1
hydrogen.
(iii) Aluminium : It is not used
preparation
of
preparation of hydroger becausein the lab
3Fe 4H,0
Triferric - Tetroxide
2 Na, Al O3 + 3H,
’ K, CO, + H,0 2Al + 6 NaOH
2 KOH + CO, Sodium Aluminate
:
From Natural Gas
Nickel CO+ 3H, 2Al + 2KOH + 2H ’ 2 KAIO, + 3H,
CH, + H,O 800°C Potassium meta
(Water gas) almuminate
Steam
through Ammonical
The mixture is passed dissolve CO Zinc and Aluminium have unique
nature. They
cuprous chloride solution to react with acids and can
even react with hot
(b)
similar Mg + H,O
Why does not copper show (c)
reactivity Zn + H,O
n Zinc and iron lie above hydrogen in acid (d)
from Fe + H,0
series and can displace hydrogen (e)
(a) Zn + H,SO4 ’ Zn SO, + H, T ()
Zn + HCI
() It is not easily liquefied (a) an oxidizing agent that does not contain
(d) It is strong oxidising agent. Oxygen.
(b) a substance that oxidizes concentrated HCI
a ld)It is strong Oxidising agent. to chlorine.
For the reaction PbO + H2 ’ Pb + H,0, which
5. af (c) asubstance that will reduce aqueous Iron
the following statements is wrong? (III) ions to Iron (I) ions.
la) H, is the reducing agent. (d) a liquid that is an oxidizing as well as a
) PbO is the oxidizing agent. reducing agent.
Pb
(c) PbO is oxidised to (e) a gas that is an oxidizing as well as a
(d) H, is oxidised to H,0 reducing agent.
() a solid that is an oxidizing agent.
Ans (c)
PbO is oxidised to Pb
Ans (a) Hydrochloric acid (HCI)
Which metal gives hydrogen with all the
(b) Manganese dioxide, oxidizes HClto chlorine
following water, acids and alkalis?
(b) Zn MnO, + 4HCI
(a) Fe ’ MnClh + 2H,0 + Clz
(d) Pb
(c) g MnO
Ans, (b) Zn (c) H,S (Hydrogen sulphide)
.Which of the following metals does not give (d) H,0, (Hydrogen per oxide)
hydrogen with acids? (e) SO2 gas
(a) Iron (b) Copper () MnO, (Manganese dioxide)
(c) Magnesium (d) Zinc 3. Correct the following statements
Ans, (b) Copper (a) Hydrogen is separated from CO by passing
the mixture through caustic potash solution.
B) VERY SHORT ANSWER TYPE (b) All metals react with acids to give hydrogen.
1. Choose terms from the options given in brackets () Hydrogen is dried by passing it through
to complete these sentences. conc. H2504.
(a) When CuO reacts with hydrogen, (d) Very dilute nitric acid reacts with iron to
is reduced and is oxidised to produce hydrogen.
(CuO, H2, Cu, H,O) (e) Conc. H,SO4 reacts with Zinc to liberate
b) Hydrogen is soluble in water. hydrogen.
Correct statements are
(sparingly, highly, moderately) Ans
(c) Metals like and (a) CO, is separated from impure hydrogen by
...give H, with steam. passing it through caustic potash solution.
(iron, magnesium, aluminium, sodium, (b) All metals above hydrogen in reactivity
calcium) series react with acids to give hydrogen.
(d) Sodium reacts smoothly with (c) Hydrogen is not dried by passing it through
cold water. conc. H,SO4 as it is a strong oxidiser and
(metal, amalgam, in the molten state) will produce sulphur dioxide.
reacts with
(e) A metal hydrogen in the activity (d) Very dilute nitric acid
Series gives hydrogen with...... acid magnesium to produce hydrogen.
with
Or......... acid. (e) Concentrated sulphuric acid reacts
(above, below, dilute hydrochloric, zinc to liberate sulphur dioxide.
Concentrated hydro choloric, dilute
(C) SHORT ANSWER TYPE
sulphuric) reactions into
1. Divide the following redoxreaction.
la) CuO, H, H;0 oxidation and reduction half
b) Sparingly i) Zn + Pb2+ ’ Zn2t + Pb
() Iron, magnesium, Aluminium
() Zn + Cu2* ’ Zn2+ + Cu is extinguishedI when pushed
(ii) Cl, +2Brr Br + 2CH (c) Apparatus for
laboratory linside the jar.
hydrogen should be air tight preparation
and. nof
Ans (i) Zn +Pb2* Zn + Pb a naked flame. away from
Oxidation Half Reaction Ans (a) Hydrogen iscollected by the
Zn ’ Znt + 2e
Reduction Half Reaction
displacement of water because
(i) Hydrogen is nearly insoluble in
downward
(ii) It forms an explosive water
Pb2+ + 2e- ’ Pb mixture with airo
inspite of being lighter, it is collecte
(ii) Zn + Cu2 Zn2+ + Cu by downward displacementnot of air.
Oxidation Half Reaction (b) Because hydrogen is a combustible gas but
non-supporter of combustion ie.
Zn ’ Zn2t + 2e itself but does not allow substances itto burns
b
Reduction Half Reaction in it.
Anß OXIDATION: "Loss of electron (s) by an atom (iv) Electronegative character : Both halogens
or an ion is called oxidation."
and hydrogen are non-metals. They show
electronegative character.
Zn ’ Znt + 2e H + e ’ H
F+e’F
Na -e’Nat
(v) Physical state : Like halogens (fluorine and
"Addition of electro-negative ion is called chlorine), hydrogen too is a gas.
Oxidation."
(vi) Atomicity : Hydrogen as well as halogens
Zn + 2HCI ’ZnClh + H, exist in the form of diatomic molecules (H,
Here zinc is oxidised to zinc chloride Fz Clz Br2 l4).
2FeCl) + Clh ’ 2FeCl3 4. Which is the most preferred metal for the
laboratory preparation of hydrogen ? Why is
Ferrous chloride to ferric chloride by the addition any other metal not used ?
of electronegative chloride ion.
Or
Ans. In the laboratory preparation of hydrogen, zinc
is the most preferred metal. Other metals are
Removal of electropositive ion (element) not used because of the following reasons :
2KI + H,O, ’ 2KOH + I2
Potassium jodide is oxidised to lodine by () Sodium and potassium react violently with
acid.
removal of electro positive K* ion.
(ii) Calcium and magnesium are expensive.
REDUCTION: "Gain of electron (s) by an atom (iii) Aluminium forms a protective coating of
or an ion" is called
REDUCTION. Al,O, due to its great affinity for oxygen.
Cu2t + 2 e ’ Cu Due to the coating of Al,O, aluminium
2C1 + 2 e ’ Cl2 does not give hydrogen with acid.
Or
"Addition of electro-positive ion is called (iv) Iron has to be heated, but then the
Reduction." hydrogen thus produced contains
impurities like hydrogen sulphide and
2HgClh + SnCl, HgCl, +SnCl_
Mercuric chloride is reduced to mercurous sulphur dioxide.
chloride by gain of electro positive ion Hg (v) Lead reacts with dilute sulphuric acid or
hydrochloric acid and forms an insoluble
"Removal of electro-negative ion is called coating of lead sulphate or lead chloride.
reductio." Therefore, further reaction is prevented.
FeClz + H,S’ 2FeCl, + 2HCI + S
(vi) Hydrogen cannot be prepared from metals Impurities can be removed from hydrogen
that are below it in the activity series of passing it through by
metals, such is copper and mercury, since 1. Silver nitrate solution (to remove
only metals that are more reactive than hydrogen and phosphine). arsine
can dispiace it from acids. AsH, +6AgNO, ’ AggAs +
e.g., Cu + HCl (dil.) ’ No reaction
PH, + 6AgNO, ’ Ag3P + 3AgNO, + 3HNO. 3AgNO,
+3HNO,
5. Describe the laboratory preparation of 2. Lead nitrate solution (to remove
hydrogen with a labelled diagram. How are
the impurities removed?
sulphide)
Pb (NO;), + H,S ’ PbS + 2HNO,
hydrogen
Reactants :Granulated zinc; dilute hydrochloric
Ans. 3. Caustic potash solution (to
acid or dilute sulphuric acid. dioxide, carbon dioxide and removeoxides
sulphur
Procedure : Place some pieces of granulated zinc nitrogen).
in a flat-bottom flask fitted with an air tight SO, + 2KOH ’ K,SO, + H,O
cork with two holes. Through one hole, pass a
thistle funnel with a long stem provided with CO, + 2KOH ’ K,CO, + H,O
astopper, and through the other, a long delivery 2NO, + 2KOH -’ KNO, + KNO, + H,0
tube. 6. How is hydrogen manufactured ? Describe with
Pour dilute hydrochloric acid (or dilute the equation(s) involved.
sulphuric acid) through the funnel.
Ans. Bosch process : Bosch process is used to prepare
Reaction:
Zn 2HC1 ZnCl, + H, hydrogen on large scale and it consists of the
following steps :
(dilute)
(1) Steam is passed over hot coke (1000°C) in
Or
furnaces of a special design, called
Zn H,SO4 ZnSO4 H,‘ converters, giving water gas.
1000°C
(dilute) + H,0 ’ (CO+ H,) - A
Dilute sulphuric acid/ hot coke steam water gas
-Dilute hydrochloric acid The reaction is endothermic.
Thistle funnel (or dropping funnel) (i) Water gas is mixed with excess steam and
passed over heated ferric oxide, which acts
as a catalyst, and chromic oxide Cr,0,
which acts as a promoter.
Hydrogen - Fez03
Water
(CO + H,) + H,0 450°C
CO, + 2H, +A
water gas steam