CanadaColorsandChemicalsLimited


152KennedyRoadSouth
Brampton,Ontario
Canada
L6W3G4

GeneralInquiryNumber:(905)459Ͳ1232


MaterialSafetyDataSheet
Attached
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SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

EPON™ Resin 862

Section 1. Product and company identification

GHS product identifier : EPON™ Resin 862 Thisproductisdistributedby
MSDS Number : K8124 CanadaColorsandChemicalsLimited
(905) 459-1232
Product type : Epoxy Resin GeneralInquiry:(416)449Ͳ7750
24HourEmergency:(416)444Ͳ2112
Material uses : Industrial use.
409008

CCC:ProductCode:______________________

Manufacturer/Supplier/Impor : Hexion Inc. EPON 862
CCC:ProductName:______________________________________

ter 180 East Broad Street

Columbus, Ohio
43215 USA

Contact person : [email protected]

Telephone : For additional health and safety or regulatory information, call

1 888 443 9466.

Emergency telephone number : For Emergency Medical Assistance

Call Health & Safety Information Services
1-866-303-6949

For Emergency Transportation Information

CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887
CANUTEC CA Domestic (613) 996-6666

Section 2. Hazards identification

Classification of the substance or : SKIN CORROSION/IRRITATION - Category 2
mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
[Respiratory tract irritation] - Category 3

GHS label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.

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Precautionary statements

General : Not applicable.

Prevention : Wear protective gloves.

Wear eye or face protection.
Use only outdoors or in a well-ventilated area.
Avoid breathing vapor.
Wash hands thoroughly after handling.
Contaminated work clothing should not be allowed out of the
workplace.

Response : IF INHALED:
Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN:
Wash with plenty of soap and water.
Take off contaminated clothing.
Wash contaminated clothing before reuse.
If skin irritation or rash occurs:
Get medical attention.
IF IN EYES:
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists:
Get medical attention.

Storage : Store locked up.

Disposal : Dispose of contents and container in accordance with all local,

regional, national and international regulations.

Other hazards which do not result : None known.

in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % by weight CAS

number
Phenol-Formaldehyde Polymer Glycidyl Ether 100 28064-14-4

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

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Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing
apparatus. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Get medical attention. If necessary, call
a poison center or physician. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing
and shoes. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves. Continue to rinse for at least 10 minutes.
Get medical attention. In the event of any complaints or symptoms,
avoid further exposure. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim
to fresh air and keep at rest in a position comfortable for breathing. If
material has been swallowed and the exposed person is conscious, give
small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Do not induce vomiting unless directed
to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention
if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist

immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first aid personnel : No action shall be taken involving any personal risk or without
suitable training. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media : None known.

Specific hazards arising from the : In a fire or if heated, a pressure increase will occur and the container
chemical may burst.

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Hazardous thermal : Decomposition products may include the following materials:

decomposition products Fumes and vapors from the thermal and chemical decompositions vary
widely in composition and toxicity.
carbon monoxide
aldehydes
other organic compounds

Special protective actions for fire- : Promptly isolate the scene by removing all persons from the vicinity
fighters of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-
fire-fighters contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through
spilled material. Avoid breathing vapor or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of
any information in Section 8 on suitable and unsuitable materials. See
also the information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).

Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with
water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach
release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to
local regulations (see section 13 of SDS). Dispose of via a licensed
waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see section 1 of SDS for
emergency contact information and section 13 of SDS for waste
disposal.

Section 7. Handling and storage

Precautions for safe handling

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Protective measures : Put on appropriate personal protective equipment (see section 8 of

SDS). Persons with a history of skin sensitization problems should not
be employed in any process in which this product is used. Do not get
in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or
mist. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Keep in the original container or an
approved alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where this
hygiene material is handled, stored and processed. Workers should wash hands
and face before eating, drinking and smoking. Remove contaminated
clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container
including any incompatibilities protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials (see section 10 of SDS) and food
and drink. Store locked up. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid
environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits

None.

Recommended monitoring : If this product contains ingredients with exposure limits, personal,
procedures workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures
and/or the necessity to use respiratory protective equipment. Reference
should be made to appropriate monitoring standards. Reference to
national guidance documents for methods for the determination of
hazardous substances will also be required.
Appropriate engineering controls : Use only with adequate ventilation. If user operations generate dust,
fumes, gas, vapor or mist, use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Environmental exposure controls : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to

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remove potentially contaminated clothing. Contaminated work

clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used
when a risk assessment indicates this is necessary to avoid exposure to
liquid splashes, mists, gases or dusts. If contact is possible, the
following protection should be worn, unless the assessment indicates a
higher degree of protection: chemical splash goggles.

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved

standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary. Considering the
parameters specified by the glove manufacturer, check during use that
the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures,
consisting of several substances, the protection time of the gloves
cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with
an approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the
selected respirator.

Section 9. Physical and chemical properties

Appearance

Physical state : Liquid

Color : Light yellow

Odor : slight
Odor threshold : Not available

pH : 7

Melting point/ Freezing point : Not available

Boiling point : 200 °C (392.00 °F)

Flash point : 150 °C (302.00 °F)

Burning time : Not available

Burning rate : Not available
Evaporation rate : Not available
Flammability (solid, gas) : Not available

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Lower and upper explosive : Lower: Not available

(flammable) limits Upper: Not available

Vapor pressure : 82 Pa @ 20 °C (68.00 °F)

Vapor density : Not available

Relative density : Not available
Density : 1,170 kg/m3 (ASTM D 4052)

Solubility : Not available

Solubility in water : Negligible

Partition coefficient: n- : 3
octanol/water
Auto-ignition temperature : > 300 °C (572.00 °F)

Decomposition temperature : Not available

SADT : Not available
Viscosity : Dynamic: 2.5 - 4.5 Pa·s @ 25 °C (77.00 °F)

Kinematic: Not available

Other information
No additional information.

Section 10. Stability and reactivity

Reactivity : Stable under normal conditions.

Chemical stability : The product is stable.

Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will
not occur.

Conditions to avoid : No specific data.

Incompatible materials : Reactive or incompatible with the following materials:

strong oxidizing agents,
strong acids,
aliphatic amines,

Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition
products should not be produced.

Other hazards Reacts with considerable heat release with some curing agents.
Run-a-way cure reactions may char and decompose the resin system,
generating unidentified fumes and vapors which may be toxic.
Heating this substance above 300 deg. F in the presence of air may
cause slow oxidative decomposition; above 500 deg. F polymerization
may occur.
Some combinations of resins and curing agents can produce
exothermic reactions which in large masses can cause runaway
polymerization and charring of the reactants

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Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Conclusion/Summary : Not available

Irritation/Corrosion

Conclusion/Summary
Skin : Not available
eyes : Not available
Respiratory : Not available

Sensitization

Conclusion/Summary
Skin : Not available
Respiratory : Not available

Mutagenicity

Conclusion/Summary : Not available

Carcinogenicity

Conclusion/Summary : Not available

Reproductive toxicity

Conclusion/Summary : Not available

Teratogenicity

Conclusion/Summary : Not available

Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
Phenol-Formaldehyde Polymer Category 3 Respiratory tract irritation
Glycidyl Ether

Specific target organ toxicity (repeated exposure)

Not available

Aspiration hazard
Not available

Information on the likely routes of : Not available

exposure

Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : May cause respiratory irritation.

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Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:

pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects : Not available

Potential delayed effects : Not available

Long term exposure

Potential immediate effects : Not available

Potential delayed effects : Not available

Potential chronic health effects

Conclusion/Summary : Not available

General : Once sensitized, a severe allergic reaction may occur when

subsequently exposed to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

Not available

Section 12. Ecological information

Toxicity

Conclusion/Summary : Not available

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Persistence/degradability

Conclusion/Summary : Not available

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential

EPON™ Resin 862 3 - low

Mobility in soil

Soil/water partition coefficient : Not available

(KOC)
Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever
possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be
disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal
of spilled material and runoff and contact with soil, waterways, drains
and sewers.

Section 14. Transport information

The data provided in this section is for information only and may not be specific to your package size or
mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for
transportation.

International transport regulations

Regulatory UN/NA Proper shipping name Classes/*PG Reportable
information number Quantity (RQ)
CFR Non-regulated

TDG Non-regulated

IMO/IMDG Non-regulated

IATA (Cargo) Non-regulated

*PG : Packing group

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Special precautions for user : Transport within user’s premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product know what to do in the event of an accident
or spillage.’

Section 15. Regulatory information

United States

U.S. Federal regulations : United States - TSCA 12(b) - Chemical export notification: None
required.
United States - TSCA 5(a)2 - Final significant new use rules: Not listed
United States - TSCA 5(a)2 - Proposed significant new use rules: Not
listed
United States - TSCA 5(e) - Substances consent order: Not listed

California Prop. 65: : WARNING: This product contains less than 0.1% of a chemical known to
the State of California to cause cancer., WARNING: This product contains
less than 1% of a chemical known to the State of California to cause birth
defects or other reproductive harm.

Ingredient name Cancer Reproductive No significant risk Maximum

level acceptable dosage
level
Oxirane, 2-(phenoxymethyl)- Yes. No. 5 μg/day No.
Oxirane, 2-(chloromethyl)- Yes. Yes. 9 μg/day No.

United States inventory (TSCA : All components are listed or exempted.

8b)

Canada

WHMIS (Canada) : Class D-2B: Material causing other toxic effects (Toxic).

Canadian lists

Canadian NPRI : None required.

CEPA Toxic substances : None required.

International regulations

International lists : Australia inventory (AICS): All components are listed or exempted.
Canada inventory: All components are listed or exempted.
Japan inventory: All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Korea inventory: All components are listed or exempted.
New Zealand Inventory (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
United States inventory (TSCA 8b): All components are listed or exempted.
Taiwan inventory (CSNN): All components are listed or exempted.

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Section 16. Other information

Hazardous Material Information System III (U.S.A.) :
Health * 2
Flammability 1
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented
HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).
HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

Full text of abbreviated H : Not applicable.

statements

History

Date of printing : 03/22/2016

Date of issue/Date of revision : 04/10/2015
Date of previous issue : 11/08/2012
Version : 9.0
Prepared by : Product Safety Stewardship
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous Goods by
Rail
UN = United Nations
References : Not available

Notice to reader

The information provided herein was believed by Hexion Inc. ("Hexion") to be accurate at the time of preparation or
prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand
other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and
use of the product and to determine the suitability of the product for its intended use. All products supplied by
Hexion are subject to Hexion's terms and conditions of sale. HEXION MAKES NO WARRANTY, EXPRESSED
OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR
ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY HEXION,
except that the product shall conform to Hexion's specifications. Nothing contained herein constitutes an offer for
the sale of any product.
® and (TM) Licensed trademarks of Hexion Inc.

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