SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.

Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S

Sri ChaitanyaIIT Academy.,India.

A.PT.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_Elite, Target & LIIT-BTs JEE-MAIN Date: 25-01-2024
Time: 09.00Am to 12.00Pm GTM-18 Max. Marks: 300
KEY SHEET
PHYSICS
1) 1 2) 3 3) 2 4) 2 5) 2
6) 1 7) 2 8) 1 9) 2 10) 2
11) 1 12) 4 13) 4 14) 2 15) 1
16) 3 17) 4 18) 1 19) 1 20) 3
21) 2 22) 5 23) 1 24) 5 25) 100
26) 20 27) 2 28) 2 29) 11 30) 36

CHEMISTRY
31) 1 32) 2 33) 2 34) 2 35) 3
36) 4 37) 1 38) 3 39) 3 40) 1
41) 3 42) 2 43) 3 44) 3 45) 1
46) 1 47) 4 48) 3 49) 4 50) 1
51) 4 52) 2 53) 16 54) 429 55) 16
56) 5 57) 6 58) 2 59) 9 60) 6

MATHEMATICS
61) 2 62) 1 63) 2 64) 2 65) 4
66) 3 67) 1 68) 2 69) 4 70) 3
71) 3 72) 1 73) 1 74) 2 75) 1
76) 1 77) 4 78) 3 79) 4 80) 4
81) 19 82) 8 83) 8 84) 16 85) 1
86) 5 87) 9 88) 0 89) 3 90) 4

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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S

SOLUTIONS
PHYSICS
1. In refracting telescope lens as objectiveand in reflecting telescope mirror as objective.
2. From Electromagnetic spectrum & Production, detection of the waves.
3. Ionisation energy will be least forGe, followed by Si and highest for C.
N  500 
4. B  0 ni  0 i  4  10 7  3
10  12.56  10 T
  0.5 
ˆi ˆj kˆ
  
5.   r  F  1 1 1
7 3 5
 iˆ  5  3  ˆj  5  7   kˆ  3  7   2iˆ  12 ˆj  10kˆ
1 1 1 -1
6. Bt=1  B= =T -1 Dx=1  D= = =L
T x L
F=A  MLT -2 =A
F=C  MLT -2 =C  ABCD=MLT -2  MLT-2  T -1L-1 =M2 LT-5
7. d=Rθ
 3π  90×4 120
90 =R   R= =
 4  3π π
Displacement  R 2  R 2  2 R 2 cos1350
2
 120 
= 3.4R 2 = 3.4    70.46m
 π 
 ucosθ  +  usinθ-gt 
2 2
8. V= Vx2 +Vy2 =
2 2
 1   1 
  40    40  10 1 
 2  2 
 28.29    28.29  10 
2 2

 800.32  334.52 = 1134.84=33.68m/s
 mg  +  ma  = 10  + 10  =10 2N
2 2 2 2
9. T=

Ma

Mg
 1 
10.   tanθ 1- 2 
 n 
 1   1 
= tan600 1- 2  = 3 1- 2 
 n   n 
30 130
11. P1 =P+ P= P=1.3P
100 100

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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
%increase in K.E
K1 -K
= ×100
K
2

=
P1 -P 2
P 2 
×100 = 1.3  12 100
2
 = 69%
L L

12. Position of com is at X cm =

 xdm =  x  x  dx
0 0
L L
 dm    x  dx
0 0

 X  L bx 2   L2 b L3 
0  L 
L
0 x  a+b L  dx ax+ dx a  . 
2 L 3
= = 
L X L bx  b L2
0  a+b L  dx 0  L 
a+ dx aL+ .
L 2
aL2 bL2 aL bL 2  3aL+2bL 
+ = +  
2 3 =  6 
= 2 3
aL+
bL
a+
b  2a+b 
2 2
2
 L L ML2
13. I=MR 2
L=2πR =M   R= =
 2π  2π 4π 2
14. Planet’s follow law of conservation of angular momentum.
F Mg M Vol
15. Stream   =     l  2  7 1
A A A A
d 1
1 10 2 
e dt BAcosθ 2  2.02 102 A
16. I= = = =
R R tR 0.7  0.5 
μ 0 Ni 4 107 100  2 
17. B= B =1.26×10-3 Wb/m2
2r 
2 10 102 
 
18. F  ma
 d 2r
a 2  30 ˆj
dt

 F is along +ve y-axis
R 5
19. R AC =R CB = CD = =2.5k/w
2 2
TC -TD TC -25
H1 = =
R CD 5
T -T T -0 T -T 100-TC
H2 = C B = C H= A C = H=H1 +H 2
R CB 2.5 R AC 2.5
100 -TC TC - 25 TC
= + TC =450 C
2.5 5 2.5
45-25 20
H1 = = =4W
5 5
-P
20. Equation of line is P= 0 V+3P0
V0
nRT
PV0 =P0 V=3P0 V0 +P0 V=3P0 V0
V
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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
2
nRT V0 +P0 V =3P0 V0 V
dT 3V 9P V
For temp max =0  V= 0  Tmax = 0 0
dV 2 4nR
dv
21. F=Eq ma=Eq m =E 0 qsin  t
dt
π/
Eq E q  -cos t 
dv= 0 sin tdt Vmax = 0   =2m/s
m m   0
V ΔR ΔV ΔI
22. R= ×100= ×100+ ×100
I R V I
2 0.2
  100   100 = 5%
50 20
23.

24. N  mg cos 300

 mg sin 300   N  ma
a  9.8m / s 2 down the incline
Using v 2  u 2  2as
0  102  2  9.8  s  s  5.1m

q 2 100×10 
-3 2

25. E= = =100J
2C 2×50×10-6
V 3  1 2
26. I    20mA
R 100 100
27. Slope gives resistance
 R  tan 600  3  1.732
 10
28. t2 2  2 sec
g 10
1 1
29. For point B;  0.1,  0
u v
 u=-10cm
v =α
 f=10cm
1 2
= 1.55-1  
10 R
R=11cm

30. r0  i  2 j  4kˆ
  
r  4i  2 j r  r  3i  4kˆ
0

1 q
V  
4 0 1r  r0
9 109  2 108
V =36V
5
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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S

CHEMISTRY
31. SRP values order indicates that  Al  Alaq3   is easy when compared with Tl  Tlaq3  
Telugu Academy  315
32. EA, order =O<S<F<Cl
33. SnO, SnO2 are amphotric
34. 1 O2  4 H   4e1  2 H 2O; E10  1.23V
 2  Fe  Fe 2  2e  ; E20  0.44V
1
 31Fe  O2  2 H   1Fe 2  1H 2O; E30  Ecell
0
]
2
 3    2  1   1  
1
 2
 Ecell  2    0.44  2   1.23  2 
0

0
Ecell  1.67V
But, G 0  nF Ecell
0
 2.303 RT log K c
2  96500  1.67 
Log K e     56.4876
 2.303  8.314  298 
K C  1056  2.85
35. C2 , N 2 , F2  Diamagnetic (According to MOT)
 2 px22  
C2 12    1s  *1s  2 s  * 2 s 
2 2 2 2
  2 p 2  Dia
 2 py2 
2

 2 px12  
B2 10    1s  *1s  2 s  * 2 s 
2 2 2 2
  2 p 2  Para
 2 py2 
1

36. CO  x   C2 H 6  y   Hc  z   50mL
1
CO  O2  CO2
2
x
x x
2
7
C2 H 6  O2  2CO2  3H 2O
2
7y
y 2y
2
x  y  z  50  1
x 7y
x y   x  2 y  170  142 
2 2
x  5 y  56   2 
x  2 y  26   3
From (1) (2) (3)  x=6ml, y=10ml, z=34ml
V  unreacted O2   VO2  V  reacted O2 

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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
 x 7y 
 120      82ml
2 2 
x  ny 1.3  a  0.8  a  0.5
Initial 1.3 0 na  1.0
37.
Equilibrium 1.3  a  na n  0.5  1.0
0.8M 1.0 M n2
 y   1.0   1  10  1.25
n 2

Kc 
 x   0  8 0.8 8
1 1

Kf
Kc   Kf   K c  K b   1.25  10  12.5, Kf  12.5
Kb
rf  Kf   X   12.5  1.3
1

rf=16.25M/ minute
38.
M
NH 4 NO3 
 N 2O; E 
4
3 5 1
4
4

1
39. NN  O  O   N  N  O; Hf  cal   ?
2
H    BDE  R   BDE  P  

 498 
Hf  cal    946     418  607 
 2 
Hf  cal   170 KJ / mole
Hf  Expt   82 KJ / mole
Resonance Energy = Hf  cal   Hf  Expt 
R E  170  82
R E  88 KJ / mole
40.
1
A2 g  
 B g   C g 
2
I .Pr ess 
100 0 0
t1  0 

 x  100  x  x  x  120
100  x  x 2
t2  5 min)  2
100  40   60 100  x  120
 2
x
 20
2
x  40

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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
 Co 
 y K  t  2.305log  
100  y  y  Ct 
t3  10 min   2
100  64   36  100 
 K  5  2.303log  
 60 
 100 
K 10  2.303log   K  0.1022
 100  y 
 100 
2.303log  
 2   K 10 
2
 100  y 
1 K  5 2.303log 
 100 

 60 
2
5  100  25 100
log    log     y  64
 3  100  y  9 100  y
 
r  k PA2 / r  0.1022   36  / r  3.679 mm of Hg/ min
41. Reactivity  Magnitude of +ve charge on diazoinium salt
42. Anti Aromatic compounds are unstable at room temp.
43.
Br

A B O C  Aldol
O O

 
F  CH 2 Cl  CH 2
44. is less stable than due to d-orbital resonance
O
C  OH

CHCl3

X 
45. Haloform reaction gives
O
O
C  OH O
C  C NH 2
NH  C 
SOCl2

N 2O5 / 
Nitration

O
O2 N NH  C  Ph

Major

46. Strength of ligands are  en  NH 3  H 2O  F 

But CFSE  charge on metal ion
A, C , D  Co 3 , B  CO 2
Cl

47. The major product is

1.4  200 1.4  NV
48. %N   46.67% %N 
6 wt. of org . com
49. At low temperature elimination (dehydration) doesnot takes place.
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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
50. Reducing property of H 3 PO2  H 3 PO3  H 3 PO4
a 
m  f  of  A  x A 
P0 A 1 P0
  PA0  1P 0 & PB0  2 P0 a  b  x A a
51.  
P0 B 2 P0 b  xB b
m  f  of  B  xB 
a  b 
PA  PA0 .x A  y A. P PB  PB0 .xB  y B P
PA PA0 .x A y A 1P0 a 2 a 4
   0   
PB PB0 .xB yB 2P b 1 b 1
52. All except CH 4
1Mn3O4 
 3MnO2
53. 0.4 Mn3O4 
1.2 MnO2
8
 4
3
 8 4
Q   4    3  0.4 F Q   3  0.4  1.6 F  1.6mole e 
 3 3
W 1  1 1
54. M    Msaturated   S
M V  233 V
2 2
BaSO4  Be  SO4
So ln  s s s
1
K sp   Ba 2  SO42   s.s.  s 2 S  K sp 
233V
1  105 
1.11010  V     430 L
233V  233 
1 M 2 T2 n 64  1200
55.     16
2 T1 M 1 SO 2
300  1
56.
Br CH 2  Br
I

, , NH Br
O
CH 3 OCH 3

57.
NH 2
NH 2
* , *
*
NH 2
d,l  d,l 
d,l 
2
2 2 6
58. 
BrF , ICl
4

4
2 2 2
 Pt  NCS 2  en 2  ,  Pt  SCN 2  en 2  &  P   SCN  NCS  en 2 

59. GI  cis, trans 3 3  Total  9

Optical active  cis
3
60. 1) Valine 2) Tryptophon 3) Leucine 4) Lysine 5) Anginine 6) Histidine
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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S

MATHEMATICS
2  28 1 i 3
61.  ,  are  2   
2 2 2 

 2
16
 16   16   256
102
d
62.  dx   x  1 x  2        x  100  
0

63. L.H .L  R.H .L

K .2  3m  2
L.H .D  R.H .D
1
K m
2.2
K  4m
8m  3m  2
2
m
5
8
k  km2
5
64. f  2  0
f  2   4   2   0  0  0
2

f  2   4   2    1  1  0
2

Hence, f  x  is continuous at x=2

f  2   0
f  2   4   2    1  0  0  f  2  
2

Hence, f  x  is discontinuous at x=-2

65. 10  4  1C4  7C4  35
N
7
5
66. A= Car met with an accident
1
B1 : Driver was alcoholic P  B1  
5
4
B2 : Driver was sobed P  B2  
5
P  A  B1    0.001, P  A  B2    0.0001
1 1
.
5 1000 5
Re q.  
1 1 4 1 7
.  .
5 1000 5 10000
67. 2700 1  2  3  4  ......  9   810 1  4  9   27 1  2  3  .....  9 
 2700  45  810  14  27  45  134055
22C11
1  2  3      22 
253
.22C11
(or) 2 2

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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
68. y  x........  i 
2

2 y  2 x 2  5 x  1.......  ii 
Solving (i) & (ii)  y  1  2 y 2  4 y  1  0
2

y  1 is the repeated root which is the y-(o-ordinate of point of contact. So point of

contact =(1,-1)
Common tangent at point of contact
x 1
y  1   x  2 y 1  0
2
 b2 
69. Normal at  ae,  passes through (0,b)
 a
5 1
e4  e2  1  0  e2 
2

 b2 
 ae, 
 a

 0, b 

 5 1 
b 2  a 2 1  e 2   4 1 
2 

  2 3 5  6 2 5 


Length of L.R 
2b 2 4 3  5
  62 5
 
a 2
2 2
70. S.d between y=x and hyperbola x  y  1 is the distance between line y=x and tangent
9 4
y  x  c, C   a 2 m 2  b 2
1 2100
71. 101C1  101C3      101C101  
101! 101!
72. a2 1  2  a  1
73. f  x    x  1 x  2  x  3
1
f ' x  0  x  2 
3
 1   1 
 2 , 2   2  ,3 
 3   3 

1 2 3

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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
1 1
74.  dx   dx 1  e4 x  t
1  e 
4 x 3/4
3x

1  e 
3 4x
e5 x e 2 4 x 4 e
n 1
75. AdjA  A , KA  K n A
L.H .S   24  A
6 2 4
R.H .S  36.212 A
 
76.  x   1, 0 cos 1    x    ,  
2 
77. y  2sin x, y  x  a
dy    3 3 
 2 cos x  1  x    a  2.sin a
dx 3 3 3 3
3
 a  c b d  5  2 7
78.      1
b d 14 2 2
ax1  by1  c 6
79. 
a cos a  b sin  3

80. x i  300,  xi 2  4680

 x  
2
i
 178  4680  600  20 2  3560    2,  28
20
 Square of maximum value =4
32003  32.32001  9  28  1
667
81.
 9  28k   9 Req is 9  28  19
82. Radius given circle is 3. Centre of 3 circles are A  0, 2  , B  6, 2  , C  3, 6 
Let P  ,   be the centre of the circle passing through A, B, C
 31 23  1 5
Radius r   2     2  
2
P ,  23725  549
 18 12  36 36
5
Required radius  3  549
36
  4 x 2    2 x 2 
1        a 1       b
 2!   2! 
83. Lt    
x0 x4
32 2
1  a  b  0,  8  2a  0  a  4, b  3 L  a 8
3 3

 
4
84. y  x  x2  1
y
y1  , y2 1  x 2   xy1  16 y
1 x 2

a   b  c   a b  c sin 2  a , b  c 
2 2 2
85.
a
2
b 2
 c  2  b .c   1
2

86. Given the point  p, p  1 lie inside the region E   x, y  : 3  x  y  9  x 2 , 0  x  3  
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SRI CHAITANYA IIT ACADEMY, INDIA 25‐01‐24_Sr.Super60_Elite, Target & LIIT-BTs_Jee‐Main_GTM‐18_KEY &SOL’S
And the set of all values of p is the interval  a, b 
Now by observation  p, p  1 lies on x 2  y 2  9
So, solving y  x  1 and x 2  y 2  9 , we get
x2  x  4  0
1  1  4.4  17  1
x 
2 2
 17  1 
Hence, P  1, 
 2 
Now on comparing with p   a, b  we get
 a  1, b 2  b  4
Hence the values of b2  b  a 2  4  1  5
Given equation  2a    bc 
ln a ln b
87.
ln a  ln  2a   ln  b  .ln  bc 
 ln a  ln 2  ln a   ln b.  ln b  ln c 
ln a  x, ln b  y, ln c  z, x  y  z
x  ln 2  x   y  y  z 
x ln 2  y 2  x 2  yz
Similarly from second equation
ln 2.ln b  ln c.ln a
xz
ln 2 
y
Substitute eq(ii) and eq(i)
We get,
 y 3  yx 2  y 2 z  x 2 z
y2  y  2  x2  y  z   0
 x  y  x  y  y  z   0
x  y   x  y  y  z   0  y  z
xz
But ln 2  xz  ln 2 
y z 
ln 2   x   ln a a 1  y  z
2
ln b   ln c ln b  ln c  0 bc  1
1
6a  6bc  6    6 1  9
2
88. x  5  y in 1st one, 3 x  2  t in 2nd one I1  I 2  0
 25r 2  15r  21  1 1
89. cot 1    Tan
 25  3 21
r2  r 
5 25
 1  4  25m  1
 Tan 1  r    Tan 1  r   S n  Tan 1    Tan 5
 5  5  5m  26 
90.    x   y   z  0   1,   3

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