GTM-J

SR MPC(CIO&CAO) DT:29-01-23
Time: 3 Hrs GTM-25-AN Max. Marks: 300

29.01.23_SR MPC(CIO& CAO) _JEE MAIN MODEL _GTM-25_AN QP_FINAL

PHYSICS

01-10 1 2 3 4 4 3 1 1 2 3

11-20 2 4 4 4 1 1 3 4 1 3

21-30 50 4 5 1 4 2 30 20 8 4

CHEMISTRY

31-40 4 4 4 1 1 4 2 1 4 3

41-50 2 4 4 4 1 2 2 2 1 4

51-60 9 10 4 8 2 7 2 4 4 416

MATHEMATICS

61-70 2 2 1 3 1 1 3 3 2 1
71-80 2 1 3 2 1 2 4 1 2 2
81-90 4 11 0 16 5 4 9 1 12 14
Narayana IIT Academy

SOLUTIONS
PHYSICS
aR 2R  R Tr2 R R
1.  2   
ar r  r TR2 r r
As Tr  TR
2. When work done by non-conservative forces is zero, the total mechanical energy of a
system remains constant.
3. ( m1v1'  m2 v2' )  ( m1v1  m2 v2 )
= change in momentum of the two particles
= External force on the system  time interval
=  m1  m2  g  2t0   2  m1  m2  gt0
4. If M is mass of the square plate before cutting the holes, then mass of portion of each
hole, m  M 2   R 2  M 
16 R 16
 Moment of inertia of remaining portion about Z axis, I  I square  4 I hole
M  m R2 
 (16 R 2  16 R 2 )  4   m( 2 R ) 2 
12  2 
M 8 10
  32 R 2  10m R 2  MR 2  MR 2
12 3 16
 8 10  2
I    MR
 3 16 
5. m  2kg b2  a 2 1  e2 
a  5m 16  25 1  e2 
3
v1 1  e 1
3 v1 5  4m / s
b  4m e  
5 v2 1  e v2 1  3
5
6.

P0  1gh r2  F  B  1 2 r 3g

3
2
 F  P0 r 2  1ghr 2  r 3 1g
3

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Narayana IIT Academy
 2 
 F  P0 r2  r 21g  h  r 
 3 
T
7. From   1  2
T1
1 T 2
 1  2  T2  T1 ……………(1)
3 T1 3
2 T  58
And  1  2
3 T1
T2  58 1
  3  T2  58   T1 ……….(2)
T1 3
Solving (1) and (2) T2  116 K
8. 00

9. It will form a stationary wave

  2l  2  10 9 m

h
 
2 mE
h2
E  2
 6  10 20 J
2 m
10. ultra high frequency band
1  K2 
mv  
Rotational KE 2  R2  K2
11.  
Total KE 1 2  K2  K 2  R2
mv 1  2 
2  R 
12. Electric force between electrons is given as
kq1q 2 9  109  (1.6  10 19 ) 2
Fe  2 
r r2
9  1.6 1.6  10 29
Fe 
r2
Fe
 is of the order of 1042
Fg

13. V 
6 0
12 R 2  r 2 

For a uniformly charged sphere, potential at the centre of sphere is given as

2R 2
VC 
0
Thus potential difference is given as

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Narayana IIT Academy

11R 2 2R 2 R 2
VR  VC   
6 0 0 6 0
14 Right hand rule to find magnetic field
15. Number of atomic dipoles, n  2.0  10 24
Dipole moment of each atomic dipole, M  1.5  10 23 JT 1

When the magnetic field, B1  0.64T

o
The sample is cooled to a temperature, T1  4.2 K

Total dipole moment of the atomic dipole, M tot  n  M

 2  10 24  1.5  10 23  30JT 1

Magnetic saturation is achieved at 15%
15
Hence, effective dipole moment, M1   30  4.5J T 1
100
When the magnetic field, B2  0.98T
o
Temperature, T2  2.8 K

Its total dipole moment  M 2

According to Curie’s law, we have the ratio of two magnetic dipoles as:
M 2 B2 T1
 
M 1 B1 T2
B2T1M 1 0.98  4.2  4.5
M2    10.336 J T 1
B1T2 2.8  0.64
Therefore, 10.336JT 1 is the total dipole moment of the sample for a magnetic field of
0.98T and a temperature of 2.8K.
16. The induced emf is given by
d
e ……(i)
dt
And the magnetic flux is given as
  BA cos 

(Here,  is the angle between the magnetic field B and area vector of ring A)

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Narayana IIT Academy

So,   0    BA cos 0    BA …….(ii)

From Eqs. (i) and (ii), we get
d
e  BA 
dt
d
So, e    B0   t  A   given; B  B0   t 
dt 
d
 A  B0   t    A  0      A
dt
But A   r 2 is the area of ring, here r is the radius of ring.
So, e   r 2  e   r 2
100 100 103 
17. P  Vr .m. s I r .m.s cos     cos
2 2 3

10 4  10 3 1 10
    2.5 watt
2 2 4

18. I  I1  I 2  2 I1I 2 cos 

2  y 
and   .d  
 D
x 1
19. For balanced Wheatstone bridge 
R 100  l
x 20 3
  x   1.5
6 80 2
No current flows through galvanometer G.
The resistances of AJ and JB are 40  and 160  then
1 1 1
 
R 7.5 200
1 10 1
   R  7.23
R 75 200
V 10
i   1.38 A.
R 7.23
20. Under the influence of one force F1  m12 y and under the action of another force,

F 2  m  22 y .
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Narayana IIT Academy
Under the action of both the forces F  F1  F2

 m 2 y  m12 y  m 2 y
2 2 2
2  2   2   2 
2
    
1  
2   
 T   T1   T2 
2 2
 4  3
T12T22    
5 5
 T   2   2  0.48sec
T12  T22  4  3
 5 5
   

21. 2 N cos 300  w  mg  10 3 10

3
N  50 3
2
N  100, F  N cos 60 0

1
 F  100   50 N
2

22. For a sector

2R sin  / 2 
rcm 
3  / 2 

  900
For quadrant disc

2 R sin 450 4 2 R
rcm  . 
3  /2 3
2
23. Q  U  W
 V
 U  Q  W  540 
J
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Narayana IIT Academy

1.013 103 1671  1 106

 U  540   540  39.7  500cal
4.2
2T
24.  h g
R
1 1   1 1 
25. E  240  13.6 z 2  2  2  40.8  13.6 z 2  2  2  z  4, n  2
 1 4n   n 4n 
26. Applying Kirchhoff’s law to mesh ADCEFA
VCC  10  I C 103  VCE 10  I C 103  5 or I C  5 103 A ---------------(1)

Appling Kirchhoff’s law to loop AGBEFA

D A
G
lb lc

RB 1 K

10 V VCC
C
B

E VCE

Ib  Rb  VBE  Vcc  10V Ib  Rb  0  10 ------------------(2)

Ic I 5 103
Since   100  ; Ib  c   5 105 A
Ib 100 100

Putting value in (2)

5 105  Rb  10 Rb  2 105   200 103 

 12V
27. I max    30 A
r 0.4 
 f   f 
28. m1     & m2    .
 25  f   40  f 
m1 40  f 40  f
  or 4  or f  20 cm
m2 25  f 25  f

l l 
29. r  R 1 2 
 l2 
30. For observer note of B will not change due to zero relative motion.

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Narayana IIT Academy

CHEMISTRY
31.
O O O O
S P
O O O O

O O
O O
S S P P

O O O O O O

32. n  3: Z  3
n2
r3  r1
Z
r x
So, r1  3  cm
3 3
2 x
De-Broglie’s wavelength  cm
3
2 r
de Broglie wavelength =  
n
32
r3  r1 X
3
33.
OCH 3
Cl F
OCH 3
S
Cl S
OCH 3
OCH 3 F
34. Werner theory.
4.305
n AgCl   0.03moles
143.5
0.01 moles of compound gives 0.03 moles of precepitate
35. AS OXIDATION STATE OF THE METAL INCREASES, ACIDIC NATURE OF ITS
OXIDE INCREASES

36. Molar conductance of NO3 = molar conductance of Cl 

 
As long as reaction takes place Cl is replaced by NO3 . Hence conductance remains
unchanged .

After completion of reaction Ag also present in solution
Hence conductance increases
V1 V2 V 3V
37.     T2  900 K
T1 T2 300 T2
38. Heavy water has more boiling point. So deuterates have less vapour pressure the
remaining are correct
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Narayana IIT Academy
39. AS PER SUITABLE REDUCING AGENTS
40. The Ionization energies difference is more between 6th and 7th energies so it contains 6
electrons in the outer most shell
41. (a) Density of solid remains unaffected by Frenkel defect and hence, the density of
sample  2.4 g / cm 3
(b) Density of solid decreases by Schottky defect and hence, the density of sample
95
  2.4  2.28 g / cm3
100
42. cyanides gives ketones with Grignard reagent
43. CHARATERISTICS OF ENZYME CATALYSIS
44. Water gives bule colour with anhy. CuSO4
45. Ortho substituted anilines are less basic due to stearic effects in protonated products.
46. Phenolic –OH is more nucleophilic than -COOH
47.
Ethanolic NaCN
CH3  CH2  CH2  Cl  
Na  Hg
CH3  CH2  CH2  CN 
Et  OH
 CH3  CH2  CH2  CH2  NH2
48.
H

CH 3CHO
 i  CH 3MgBr H 2 SO4
CH 2  CH  CH 3
CH 3  C  OH
 ii  H 2O 
Ethanal
CH 3
 B  Propene
 A
Propan-2-ol

CH 2CH 2CH 2OH

Hydroboration
CH 3  CH  CH 2 Oxidation  C  Propan-1-o1
49. B-complex and vitamin C are water soluble.
50. 1% phenol is disinfectant and 0.2% Phenol is antiseptic
51.

39gm=1.5 mole
1mole acetylene – 6 moles silver iodide
1.5 moles of acetylene - 9 moles of silver iodide
52. C 6 H 5C H  O C r O C H C l 2 2
53. B, C , E, H  4 only
54. x = 5, y = 3
55. Mn 7  5e 
 Mn 2 ; X n 
 X 5  (5  n)e
Meq of X n  = Meq of KMnO4

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2.68 X 103 x (5-n) x 10-3 = 1.61 x 10-3 x 5 x103 ; n=2
56. 
Zn  OH 2  2
 Zn  2OH


2 2
K sp   Zn 2  OH    2  1013  0.2 OH    2  1013 OH    106 M
3
K sp  Al  OH 3    Al 3  OH    16  10 25
3
 Al 3  106   16  10 25 16  10 x  1018  16  1025 x  7

57 t1/2  20 years number of half lines  100  5

20
6400 6400
Activity remaining= 5
  200  x2
 2 32
58.

59. ZnS , CdS , Sb2S3 , MnS

60.
C s   2H 2 g  
 CH 4 g 

C g  Hg
 H f  { Sublimation energy + 2 X (dissociation energy)} – {4(C-H bond energy)

75  720  2  435   4x ;  75  1590  4x ; x  416 KJmol 1

MATHMATICS
61. (2)
Substituting 1, 2  in 2 x  y  6  0  2  2  6  0 and substituting 1, 2  in
2 x  4 y  7  0  2  8  7  0 both have opposite sign
2 x  y  6  2 x  4 y  7
Bisector of angle which contain 1, 2  is 
5 2 5
 4 x  2 y  12  2 x  4 y  7  6x  2 y  5  0
62. (2)
 a  6  x 2  2ax  3  0 ; D  0  4a 2  4  a  6  3  0
2
a  3a  18  0   a  6  a  3  0 a   6,3

63. (1)
PS1  PS2  S1 S2  15

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3
 2ae  2a  15 2a 1  e   15 1 e 
2
64. (3)
BA. BC  c2  a2  b2 
| BA | cos B  C  
| BC |  2ca 
65. (1)
5x  x 2
1
4
66. (10)
Clearly f  x  is continuous at x  0

1 1 1
h2  2
e 0 1 h
Now, f '  0   lim  lim h1  lim h
1
 lim 1  0
h0 h h 0
2
h0
2 2 2 h 0 h2
eh  3 eh e
h
Also f '  0   0
 f  x  is differentiable at x  0
67. (3)
a y  2 x3  4 x  2 nd y  x 3  2 x  1  2 y  2 x3  4 x  2
2 y  2 x3  4 x  2
  y  8x  4
y  2 x3  4 x  2 
 Slope of the line =8

68. (3)
We have f  x   tan 1  sin x  cos x  , x  0,
1 cos x  sin x
Therefore f '  x   2  cos x  sin x   ( on simplification)
1   sin x  cos x  2  sin 2 x
Note that 2  sin 2 x  0 for all x
Therefore f '  x   0 if cos x  sin x  0 or f '  x   0 if cos x  sin x or cot x  1

Now, cot x  1 if tan x  1, i.e., if 0  x 
4

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
Thus f '  x   0 in  0, 
4
 

Hence f is increasing function in  0,  .
 4
69. (2)
use parametric points
70. (1)
using integration by parts
71. (2)
convert into exact differential
72. (1)

Let AO = 2x, BO = 3x
Now, AO. BO = OE. OF
X= 2
Now, D is mid-point of chord AB
5
AD = DB =
2
Equation of AB is y = mx
3m  2 5
   m  1, 17 / 7
2 2
1 m
17
Equation of AB is y  x and y   x
7

73. (3)

300
B 600 m
10
6

x x
PAM  Tan60o  AM 
AM 3
x
PMB  Tan30o  BM  x 3
BM
BM2  AM2  AB2
x2 8x 2 x
3x 2   600 ;  600 ;  75  5 3
3 3 3
74. (2)

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α  3α  4 a ; α  a  a 2  4a 2  a  f  a   0 ; f  a   3a 2  a
4ac  b2 1
Min value of f  a   
4a 12
75. (1)

|z  1|  |z  1|  Re  z   0 and |z| 3

9
Required Area 
2
76. (2)
1 2 3
A  2 6 11  0
1 2 7
A1  4  5a  2b  c  A2  5  5a  2b  c  A3  2  5a  2b  c 
For infinitely many solutions
5a  2b  c  0 5a  2b  c

77. (4)
6!
6C .4C .2C  3
 90
2 2 2
 2!
78. (1)
Principal amount = P, Interest = r
r  r 
Amount after 1 year = P  p
 P 1  
100 100 
Amount after 2 years = Amount after 1 year + Interest for the amount
2
 r   r  r  r 
 P 1    P 1    P 1  
 100   100  100  100 
n
 r 
Amount after n years  P  1  
 100 
n  no. of years ; r  rate of interest ; n6; r  50%
6
 1 36
A  32000 1    32000   500  729  364500
 2 64
79. (2)
From the given table prime numbers are 2, 3, 5, 7 ' E ' denote prime
' F ' denotes the number  4

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 P  E   P  2 or 3 or 5 or 7  (Events 2, 3, 5, 7 are m.E )
 P  2   P  3  P  5   P  7   0.62
P  F   P 1 or 2 or 3 (events 1, 2, 3 are m.E )  P 1  P  2   P  3  0.5
P  E  F   P  2 or 3   P  2   P  3  0.35
P  E  F   P  E   P  F   P  E  F   0.77
80. (2)
Given that   p  q   (q  r )  ( r )   ( p  q) is false.
   p  q   ( q  r )  (  r )  is true and p  q is false,
  p  q  ,and ( r ) all are true.  r is false
Now, (q  r ) is true and r is false.  q is false
Also, p  q is true and q is false  p is true.

81. (4)
BD and BE are intersect at B
1
Coordinates of B are   3, 2  mAB 
5
3 1 3
 m
tan   2 5  2 3  2m 3  2m 1
3 3m 1 or  1   m   rejected  or  5
1 1 2  3m 2  3m 5
10 2
Equation of BC  y  2   x  3   5x  y  17  0

82. (11)
1 1 1 1
f  x  is undefined when sin 0 x x ,.....
x n 2011 2001
83. (0)
comparing coefficients
84. use Leibnitz’s rule
85. Conceptual
86. (4)
y  xy y2 
cos 1 x  cos 1     ; cos 1   1  x2 1  
2  2 4 

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Narayana IIT Academy

2 y2 xy 2 y2 x2y 2 2 x2 y2
1 x 1  cos   ; 1 x    cos    xy cos 
4 2 4 4 4
 4x 2  4xy cos   y 2  4sin2 
87. (9)
 2i  j  1 1
An   2 n   2 n  2i  j   3n An  n  2i  j 
 3  3 3
1  1 18
tr  3n An   tr  n  2i  j    n  3  6  9   n
3  3 3
 2 18  6
l  lim  6  2   .....  n   9
n 
 3 3  1 1
3
88. (1)
2
1
5C3   .x3 .tan 3 x
T4  x 2 4 2 4 4

   ; 4 2
2 x tan x    2

T2 1
4
27 27
; 4 2
x tan x   
3
 3 ; x  3
5C1   x tan x
 x

 x    1
 3 
89. E  first boys can be arranged in 4 ways, then there are 5-gaps between boys in 5-gaps,
5-girls can be arranged in 5 ways
54 5 4 3 2 1
PE   
9 5  6  7  8  9 126
90. (14)
0  y  x  2y  y  x  2y  y y  x y  y
0 x y  y  x  y  y  x  2 x  y  Even 
yx
Median   10  x  y  20 _______ 1
2
Range  28   2 x  y    x  y   28  x  2 y  28 ______  2 
 x  12; y  8
By sol (1) and (2)
x  12, y  8, 2 x  y  32, x  y  4
12  8  32  4 56
 Mean    14
4 4

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