Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Jr.Super60_STERLING BT JEE-ADV-2024_P1 Date: 15-12-2024
Time: 09.00Am to 12.00Pm QAT-07 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 A 2 B 3 A 4 B 5 AC 6 BCD

7 AC 8 79 9 343 10 2003 11 8000 12 81

13 1 14 C 15 C 16 C 17 C

PHYSICS

18 A 19 C 20 C 21 C 22 ABCD 23 ACD

24 ABD 25 12 26 180 27 90 28 20 29 10

30 11 31 A 32 D 33 B 34 C

CHEMISTRY
35 D 36 B 37 C 38 B 39 AC 40 A

41 ABCD 42 6 43 12 44 17 45 8 46 2

47 3 48 B 49 D 50 B 51 B
 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s

SOLUTIONS
MATHEMATICS
1. ABC is equailateral  a  b  c
2. AC 2  AB 2  BC 2 -(1)
BD 2  BC 2  CD 2 -(2)
CA2  CD 2  DA2 -(3)
DB 2  DA2  AB 2 -(4)
(1)+ (3)
2AC 2  AB 2  BC 2  CD 2  DA2
(2)+ (4)
2BD 2  BC 2  CD 2  DA2  AB 2
From (5) and (6)
AC  BD
AB  CD
BC  AD
From (1) and (2) AB 2  BC 2  BC 2  CD 2
From (2) and (3) BC 2  CD 2  CD 2  DA2
CBD and ADB are congment.
 CBD  ADB  90  ABD
 CBD  ABD  CBA
DB lies on the plane of ABC
so points are coplanar
3. a,b,c,d are in AP
b  a  t; c  a  2t ; d  a  3t
a  d  3t  a  d  3t
bc   d  2t  d  t   d 2  3dt  2t 2
a t
Also  1  3
d d
 3t 
hk  d 2  1  
 d
hk  d 2  3td  d 2t3td t 2t 2
hk  bc
a, h, k , d
ha/r
k  a / r2
d  a / r3

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
a
 r 3  a  dr 3
d
a2
hk  3
r
d 2r 6 a  3t 
hk  3  d 2 r 3  d 2    d 2  1    d 2  3td  d 2  3td  2t 2
r d   d
hk  bc
4. sin x  sin y  cos  cos xx  

Let x    sin y  1  sin y  1
2
1  sin x  cos  cos x
cos  cos x  sin x  1
cos 2   1  1  cos   0
sin y  cos   1  0  1
   
5. 2sin 2  cos 2 x   2sin 2  sin 2 x 
2  2 
cos 2 x  sin 2 x  cos x  cos x  2sin x   0
1
1
1 4 3
cos x  0  tan x  ;cos 2 x 
2 1 5
1
4
6. f  x   ax  bx  c
2

f 1  a  b  c  0  f  x   0x  
f  2   4a  2b  c  0 f  2   4a  2b  c  0
f  3  9a  3b  c  0
f  2   f  3   0  13a  5b  2c  0
f  5   25a  5b  c  0  5b  25a  c  0
 x  x   x  x  0  0 x0
7. f  x    2
  x  x x x  0  2 x x0
f is continuous and differentiable
 0 x0
Again f '  x   
4 x x  0
f '  x  is continuous but not differentiable at x = 0
 3 
8. f  3 / 2   2 so f '   g '  2   1
 2 

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
4
f '  x   25  2 x  3  .2 
24
 sin x
3
 3  4 7
f '   0  1 
 2  3 3
3
g '  2   k1  3 k2  7
7
9  21  49  79
9. Given lines will be parallel to ax 2  6 xy  y 2  0
2b 6
m  m2   6
b 1
a
m.m 2  a
b
m3  a

   
2
m3  m3  3m3 m  m 2  63

a  a 2  3a  6   63
a 2  19a  216  0
a 2  27 a  8a  216  0
a  a  27   8  a  27   0
a  8a  27
Sum= 8  27  19  v
v 2  v  1  343
cot A  cot C sin  A  C  sin B sin 2 B
10.  
cot B sin A sin C cos B sin A sin C cos B
b2 2b 2 2b 2
  
ac cos b 2ac cos B a 2  c 2  b 2
2b 2 2 2
  
2002b 2  b 2 2001 
  2  2003
11.     
S  12  1  2  22  4  6  32  ....  192  380  202 
There are 20 brackets. Each bracket has 3 terms out of which the first and last turns are
perfect squares of consecutive integers and the middle term is their product.
General term = tr   r  1  r  r  1  r 2
2

n
  r  1   r  1 r  r 2 )
2
Sum of n terms 3n 
r 1

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s

 
n
  r 3   r  1
3

r 1

   
 1  03  23  13  .....  n3   x  1
3

 n3
S 20  203  8000
12. R  p1q8 p  A8

  
2
2  3 2 3  2 
A 
 0 1 
 

  
3
3 2  3   2 3  2 
A 
3
 0 1 
 
 3
8
r11   81

a  b  b  c  c  a  58  2  a .b  b .c  c .a 
2 2 2
13.

a  b  c   0  2  a .b  b .c  c .a   29
2

2 2 2
a  b  b  c  c  a   87
p  8 q  7 p  q 1
14. Conceptual
 k2  k2
P) Limit is easily reductible to cos ec 1  1
 2 
15. by L’Hospital’s rule which if
  2
Q) kx 2   3  2k  x  6   kx  3  x  2   0
3
x   ; x  2  4  3 / k  5
k
3 3
K
4 5
2
R) x3  x   a 2  a 
3 3
f  x   x3  x
1
f  x   3 x 2  150  x  
3
1 1 2
Minimum value of f  x    
3 3 3 3 3

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
2 2
a 2  a  
3 3 3 3
a 2  a  0  a  a  1  0 0  a  1
a   0,1
5  5 
S) x   ; 4  x  4 x   ,4
2  2 
 16  x 2  16  x 2
log5  1  51
 2 x  5  2x  5
 
x   , 9   [1, )
x   1, 4
ae x  b
16. A) lim  a b  0 ab
x 0 x
ae x  0
lim a2 b2
x 0 1
x
B) e lim  cos 2kx  1 cot 2  e 2
x 0 k
x
cos 2
1  cos 2kx 2 2 k  e2
 lim  4 k x .
x  4k 2 x 2 x
sin 2 2
kx
x2 k2
k2
1
 .4k 2 .k 2  2
2
4
k 1
k 1
ax  bx 2
C) lim  e2  a  2 b  
e x  x
D) RHL  lim  x  cos  2  x   0.cos 0  0
x 0 
LHL  lim  x  cos  2  x     1 cos  2   1
x 0 
17. P) f '  x   2 x  g ' 1 , f 11  x   2
g '  x   2 x  f '  2  ; g ''  x   2
at x  1  f ' 1  2  g ' 1 ; g ' 1  2  f '  2 
f ' 1  4  f '  2 

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
Q) 2 f  x  f  y   f  x  y   f  x  y   1
Replacing x by y and y by x
2 f  x . f  x   f  y  x   f  x  y    2
From (1) and (2) f  y  x   f  x  y 
Put y  0 f   x   f  x 
f '   x  .  1  f '  x  .1
x  2  1  f '  2   f  2 
f '  2   f '  2   0
R) f '  x   3x 2  2 xf ' 1  f ''  2 
f ' 1  3  2 f 1  f ''  2 
f ' 1  f '  2   3 f ' 1  5
f ''  x   6 x  2 f ' 1 f ' 2  2
f '  2   12  2 f ' 1 f  x   x3  5 x 2  2 x  6
f '  2   2 f ' 1  12 f  0  6
f '''  x   6 f  3   6
f  0   f  3  1  1
S) f  x   x n
f  x   nx n 1
n 1
f'a b   n  a  b 
n 1
n  a  b  na n 1  nb n 1
 a  b n1  a n1  bn 1
n2

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s

PHYSICS
4R
18. Centre of mass semi circular disc lie at
3
Centre of mass of rectangular plate lie at its centre
4R
 distance between centers of semi circular disc and the plate is R 
3
  R2
m1  and m2   4 R 2
2
 R2  4R 
 R 
2  3   R (3  4)
xcm   .
 R2 3(  8)
   4R2
2
19. O2  is diatomic hence it has 5 degrees of freedom total kinetic energy of a single
5
molecule is K BT . As 1 kg-mole of O2 has N molecules the total K.E of one kg – mole
2
5
O2 at room temperature is RT
2
5 5
 RT   8.31  103  300  6.23  106 J . kg 1  mole
2 2
x4 x2
20. u 
4 2
du du
Now 0   x3  x  x3  x  0, x  0 (or ) x  1
dx dx
2
d u 2 d 2u
 3x  1  Ve for x  1
2 2
dx dx
1
 u ( 1)    umin
4
Now K max  umin  T .E
1
K max   2
4
1 9
K max  2  
4 4
1 2 9 9 3
 mv   V 2   V
2 4 2 2
21. There will be only vertically downward force on curved surface of the cone (applied by
the liquid) as horizontal force is cancelled
Let this force be ‘F’

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s

Now Buyant force   P0   gH  R 2  F

Vin  g   P0   gH  R 2  F
1
 R 2 Hpg   P0  H  g  R 2  F
3
 R2
F (3P0  2  gh)
3
22. Work done in pushing the ball = F.S
 Vg ( d   ) s
4  3 3 103 
  R3  10 10    0.7
3  4 R3 
 0.077 J
When ball is released at bottom same work is done on the ball
1
Now mv 2  0.077
2
V  7 m sec1
V 2 77
Also H    2.45m
2g 20
Now Fnet on the ball is Fnet  Vg ( d   )
 0.11 N  11 10 2
3
( Fv ) max  6 rV  6    103   7  102
2
 18  11 105 N
Fnet 11 102 103 10 5 500
     102  .
( FV )max 18  11105 18 18 9 9
23. for rod to be in equilibrium    0 w.r.t ‘O’

1 T
10.  x (10)(1)  (1)
2 2

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
T
5  10 x 
2
T  (5 2  10 x 2) 1
For balancing the rod
T
N1   10  10 x  N1  5  10 x  10  10 x
2
N1  5 N
Hence option (1) is correct
For horizontal force equation
T  1
N2   10  x  
2  2
If x  0.5 then N 2  10 N  T  10 2 N
Option (4) is correct and option (2) is wrong
For option (3)
Maximum tension  20 2 N
T  20 2 N
 1
10 2  x    20 2
 2
So, if x  1.5 string will break
Hence option (3) is correct
24. Along horizontal direction
S x  u x .t
60  20.cos 45. t
60
t   3 2 sec
10 2
Along y – direction
1
Sy  uy t  gt 2
2
1
 (10 2)(3 2)  (10)(3 2)2
2
1
 60  (10)(9)(2)
2
 60  90  30m
Hence 1kg mass hit the rod at A but not at it’s center of mass
 time for collision is 3 2 sec.
According to law of conservation of angular momentum
30(1)(u x )  I total ( )

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s

 1 
30(10 2)  1.(30) 2  (5)(30) 2  
 3 
 5
300 2  (30)2 1   
 3
2 8
 .
3 3
1
 rad sec1 .
4 2
25.

Using principle of moments

 40 g  30    mg 10 
m  120 gm
 12  103 kg
 12 102 kg
 x  12
26 Total reading   M .S .R   L.C V .C     zero error 

 
 1.7   0.01 5     0.05 cm
 1.75  0.05  1.80 cm  180  10 2 cm
27 Let thermal resistance of rod having a length L is R then equivalent rod combination
in resistance is

3R
Req between PQ istemperature difference between PQ is
5
3R 3R
5 3
 240  5  240   240  90o
R 3R R 8R 8
 
2 5 2 5
28 On using conservation of energy
1  1
2  mv 2   kx 2
2  2

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
1
2  40 2  2.x 2
4
2
40 40
 x2  x   20cm
4 2
29.

dir
Along y 

` N  mg  F sin 60o
Along x  direction
For limiting condition
F f  F cos 60o
 N  F cos 60o
 
 mg  F sin 60o  F cos 60o
 mg
F
cos 60o   sin 60o
1 10
 3 10
3 3  3
1 1 3 1 1
 . 
2 3 3 2 2 6
10
  10 N
4
3 
12 
30.

Let mass of triangular lamina is m and length is l then I 0 ml 2

I 0  kml 2  k  cons tan t 
Now I1  moment of inertia of DEF about G so

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
2
 m  l  ml 2 I 0
I1      
 4  2  16 16
Let I ADE  I BDE  I EFC  I 2
 3I 2  I1  I 0
I 5I
 3I 2  0  I 0  I2  0
16 16
Now moment of inertia DECB after removal of ADE is  2I 2  I1
 5I  I 11I0
 2 0   0 
 16  16 16
 N  11
31. A  P0 ,V0 , T0 
B  P0 ,3V0 ,3T0 
 3V 
C  2 P0 , 0 ,3T0 
 2 
 V 
D  2 P0 , 0 , T0 
 2 
AB  Isobaric w1  P0  3V0  V0   P0  2V0   2nRT0  2 P0V0
f 5
u  nR.dT  nR  2T0   5nRT0
2 2
 3V0 
BC isothermal - w2  nR  3T0  ln 
 2  3V  
 0 
1
 3nRT0 ln  
2
u  0  Q  3nRT0 ln 2
V 3V 
CD - isobaric w3  2 P0  0  0   2 P0V0
 2 2 
 
 V0 
DA  isothermal w4  nRT0 ln   nRT0 . ln 2
V0 
 
 2 
Total work done  w  w1  w2  w3  w4  2 RT0 ln 2
32. Conceptual
33. Conceptual
34. Conceptual

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s

CHEMISTRY
35. Group Period
i), iv) Increases Decreases
ii), iii) Decreases Increases
36. i) and ii) are stronger acids than iii) and iv) because of ortho effect. Hence i) is more
stronger acid then ii) as it has two - OH groups at ortho position
37. C2  MO electronic configuration can be written as
2  2  2  2  2
1s  1s *  2s  2 s *  2 p   2 p1x   2 py1
z
Be2  4e , Diamagnetic
B2  10e , Diamagnetic
N 2  14e , Diamagnetic
38.
N 2O4  2 NO2
g g
Initial moles 1 0
At equilibrium l  2
Total no of moles of equilibrium  1  
1
PN O  P
2 4 1
2
PNO  P
2 1   
P 2 NO2 4 2
Hence K P   P
PN O
2 4 
1 2 
4 2
4.5   2    0.6
1 2
1
X N 2O4   0.25
1 
X NO2  0.75
 Average molar mass of mixture
 0.25  92  0.75  46  57.5
39. ClF3 , SP3d 3b. p  2l. p  '' T '' shape

I Cl4  : sp 3d 2 B. A : 90o

40. 4 LiNO3  2 Li2O  4 NO2  O2
41. For Boyle's law

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
1
v  cons tan t T 
p
pv  k  constant
42. H 2 SO4  H   HSO4
1 1
Na2 SO4  2 Na   SO42
O 0.036
0.018
H SO4  H   SO42
1 1 0.018
( Q  kc so the reaction will go in back ward direction)
1  a  1  a   0.018  a 
1 1
1  0.018  a 
Now, 0.012 
1
a  0.006
 SO 2   0.018  0.006  1.2  102 M
 4 
PbSO4  Pb 2 Aq   SO42
S   Aq 
S  0.012  S   0.012
1.6  108
S  1.33  106
0.012
 y6
43.  321  n  3; l  2; m  1
h 6h
Angular momentum  l  l  1 
2 2

No of spherical nodes  n  l  1
 3  2 1
0
No of angular nodes  l   2
6h 6h  4
Sum of all the above 02 
2 2
 x  6, y  4, z  2
44. Volume strength = Molarity 11.2
45. PV  nRT
P and V are same So,
n1T1  n2T2

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 Sri Chaitanya IIT Academy 15-12--2024_Jr.Super60_STERLING@ BT_Jee-Adv(2024-P1)_QAT-07 _Key & Sol’s
w1 w
T1  2 T2
M1 M2
3.7 0.184
 298   290
M1 2
 M1  41.33 g
46.
SO3H

S
(i), (iv) H2N C NH2 ,

NH2
Urea and sulphanilic acid contain nitrogen and sulphur gives, blood red colour
47. CH 3OH  CH 3 MgBr  CH 4   CH 3O  MgBr
32 gs  1mole
96 gs  ?
x  3mole
 High
48. A) Na2 B4O7 .10 H 2O  Na2 B4O7  NaBO2  B2O3
T
B ) B2 H 6  6 H 2O  2 H 3 BO3  6 H 2
High
C ) B2 H 6  2 NH 3   BN  x
T
Ether
D ) 4 BCl3  3LiAlH 4  2 B2 H 6  3Licl  3 AlCl3

3 5
49. NH 3  NO3
2 3 3 4
Fe C2O4  Fe CO2
6 o
H 2 SO5  S8

7
K mnO4  Mn 2
50. A) H  0, S  0  G  0 at low temperature
B ) H  0, S  0  always G  0
C ) H  0, S  0  G  0 at high temperature
D ) H  0, S  0  always G  0
51. HBO - Anti markonikor's addition, Anti markonikov's product with out rearrangement.
OMDM - Markonikov's addition, and makonikov's product with out rearrangement.
H 2O / H  (or) H 3O  : Markonikov's addition, and markonikov's product with
rearrangement.
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