Paper No 13
Paper No 13
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-2
Q1. Given below are two statements : One is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A : For measuring the potential difference across a resistance of 600 , the voltmeter
with resistance 1000 will be preferred over voltmeter with resistance 4000 .
Reason R : Voltmeter with higher resistance will draw smaller current than voltmeter with lower
resistance.
In the light of the above statements, choose the most appropriate answer from the options given
below.
(A) Both A and R are correct and R is the correct explanation of A
(B) A is not correct but R is correct
(C) Both A and R are correct but R is not the correct explanation of A
(D) A is correct but R is not correct
Q2. Two objects A and B are placed at 15cm and 25cm from the pole in front of a concave mirror
having radius of curvature 40cm. The distance between images formed by the mirror is
_________.
(A) 60cm (B) 40cm
(C) 160cm (D) 100cm
Q3. A coil is placed in magnetic field such that plane of coil is perpendicular to the direction of
magnetic field. The magnetic flux through a coil can be changed :
A. By changing the magnitude of the magnetic field within the coil.
B. By changing the area of coil within the magnetic field.
C. By changing the angle between the direction of magnetic field and the plane of the coil.
D. By reversing the magnetic field direction abruptly without changing its magnitude.
Choose the most appropriate answer from the options given below :
(A) A, B and D only (B) A and B only
(C) A, B and C only (D) A and C only
Q4. The escape velocities of two planets A and B are in the ratio 1 : 2. If the ratio of their radii
respectively is 1 : 3, then the ratio of acceleration due to gravity of planet A to the acceleration of
gravity of planet B will be :
2 4
(A) (B)
3 3
3 3
(C) (D)
4 2
Q5. If the velocity of light c, universal gravitational constant G and Planck’s constant h are chosen as
fundamental quantities. The dimensions of mass in the new system is :
1 1 1 1 1 1
(A) h 2 c 2 G 2
(B) h 2
c 2
G 2
1 1
(C) h1 c1 G 1
(D) h 2 c 2
G1
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-3
2 11
Q6. The Young’s modulus of a steel wire of length 6m and cross-sectional area 3 mm , is 2 × 10
2
N/m . The wire is suspended from its support on a given planet. A block of mass 4kg is attached
1
to the free end of the wire. The acceleration due to gravity on the planet is of its value on the
4
2
earth. The elongation of wire is (Take g on the earth = 10m/s ) :
(A) 1 cm (B) 0.1 cm
(C) 1 mm (D) 0.1 mm
Q8. Given below are statements : One is labelled as Assertion A and the other is labelled as Reason
R.
Assertion A : Two metallic spheres are charged to the same potential. One of them is hollow and
another is solid, and both have the same radii. Solid sphere will have charge than the hollow one.
In the light of the above statements, choose the correct answer from the options given below.
(A) A is false but R is true
(B) A is true but R is false
(C) Both A and R are true but R is not the correct explanation of A
(D) Both A and R are true and R is the correct explanation of A
Q10. Equivalent resistance between the adjacent corners of a regular n-sided polygon of uniform wire
of resistance R would be :
n 1R n 1R
(A) (B)
n2 n
2
n R n 1R
(C) (D)
n 1 2n 1
th nd
Q11. An electron of a hydrogen like atom, having Z = 4, jumps from 4 energy state to 2 energy
state. The energy released in this process, will be :
(Given Rch = 13.6 eV)
Where R = Rydberg constant
c = Speed of light on vacuum
h = Planck’s constant
(A) 3.4 eV (B) 40.8 eV
(C) 10.5 eV (D) 13.6 eV
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-4
Q13. The ratio of average electric energy density and total average energy density of electromagnetic
wave is :
1
(A) 3 (B)
2
(C) 2 (D) 1
Q15. The threshold frequency of a metal of f 0. When the light of frequency 2f 0 is incident on the metal
plate, the maximum velocity of photoelectrons is 1. When the frequency of incident radiation is
increased to 5f 0, the maximum velocity of photoelectrons emitted is 2 . The ratio of 1 to 2 is :
1 1 1 1
(A) (B)
2 2 2 4
1 1 1 1
(C) (D)
2 16 2 8
Q16. Figures (a), (b), (c) and (d) show variation of force with time.
F(N) F(N)
0.5 0.5
(a) (b)
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-5
F(N) F(N)
0.5
0.5
(c) (d)
T2 T2
(A) (B)
O L O L
T2 T2
(C) (D)
O L O L
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-6
I1 I3 10V 20V
Q1. In the given circuit, the value of is ________
I2
10
I1
10
I2
I3 10
MR2
Q2. Moment of inertia of a disc of mass M and radius ‘R’ about any of its diameter is . The
4
moment of inertia of this disc about an axis normal to the disc and passing through a point on its
x
edge will be, MR 2 . The value of x is _________.
2
2 -2
Q3. A square shaped coil of area 70 cm having 600 turns rotates in a magnetic field of 0.4 wbm ,
about an axis which is parallel to one of the side of the coil and perpendicular to the direction of
field. If the coil completes 500revolution in a minute, the instantaneous emf when the plane of the
22
coil is inclined at 60 with the field, will be _______V. (Take )
7
2
Q4. The surface of water in a water tank of cross section area 750cm on the top of a house is h m
above the tap level. The speed of water coming out through the tap of cross section area 500
2 dh
mm is 30cm/s. At that instant, is x 10 3 m / s. The value of x will be _______.
dt
Q5. A block is fastened to a horizontal spring. The block is pulled to a distance x = 10 cm from its
equilibrium position (at x = 0) on a frictionless surface from rest. The energy of the block at x =
-1
5cm is 0.25 J. The spring constant of the spring is ________Nm .
Q6. Nucleus A having Z = 17 and equal number of protons and neutrons has 1.2 MeV binding energy
per nucleon.
Another nucleus B of Z = 12 has total 26 nucleons and 1.8 MeV binding energy per nucleons.
The difference of binding energy of B and A will be _______ MeV.
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-7
Q9. A force F (5 3y 2 ) acts on a particle in the y-direction, where F is in newton and y is in meter.
The work done by the force during a displacement form y = 2m to y = 5m is ______J.
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-8
Q1. Given below are two statements: one is labelled as Assertion (A) and the other is labelled as
Reason (R)
2+ +
Assertion (A): Cu in water is more stable than Cu
2+ +
Reason (R): Enthalpy of hydration for Cu is much less than that of Cu
In the light of the above statements, choose the correct answer from the options given below:
(A) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(B) (A) is correct but (R) is not correct
(C) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(D) (A) is not correct but (R) is correct
Q2. Given below are two statements: one is labelled as Assertion (A) and other is labelled as
Reason (R)
Assertion (A): -halocarboxylic acid on reaction with dil NH3 gives good yield of -amino
carboxylic acid whereas the yield of amine is very low when prepared from alkyl halides.
Reason (R): Amino acids exist in zwitter ion form in aqueous medium.
In the light of the above statements, choose the correct answer from the options given below:
(A) (A) is not correct but (R) is correct
(B) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(C) (A) is correct but (R) is not correct
(D) Both (A) and (R) are correct and (R) is the correct explanation of (A)
1
Q3. The correct order of bond enthalpy (kJ mol ) is:
(A) Si –Si > C – C > Ge – Ge > Sn – Sn
(B) C – C > Si – Si > Ge – Ge > Sn – Sn
(C) C – C > Si – Si> Sn – Sn > Ge – Ge
(D) Si – Si > C – C > Sn – Sn > Ge – Ge
Q4. The structure of major products A, B and C in the following reaction sequence are.
O
NaHSO3, dil. HCl LiAlH4
H [A] [B]
NaCN, H2O
HCl / H2O
[C]
HO CN HO CHO HO CO 2H
(A) A = B=
H , H , C= H
HO CN HO NH2 HO CO2H
(B) A = B=
H , H , C= H
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-9
OSO 3 Na HO Cl
(C) A = B=
H , H , C =. H
HO SO3H HO SO2Cl
(D) A = B=
H , OH , C = H
Q5. Given below are two statements: one is labelled as Assertion (A) and other is labelled as
Reason (R)
Assertion (A): Gypsum is used for making fireproof wall boards
Reason (R): Gypsum is unstable at high temperature
In the light of the above statements, choose the correct answer from the options given below:
(A) (A) is not correct but (R) is correct
(B) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(C) (A) is correct but (R) is not correct
(D) Both (A) and (R) are correct and (R) is the correct explanation of (A)
Q6.
HF
'X' is X
Major product
(A) (B)
(C) (D)
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-10
Q8. In a reaction
OH OH OCOCH3
Q9. Which one of the following sets of ions represents a collection of isoelectronic species?
(Given: Atomic Number: F: 9, Cl: 17, Na = 11, Mg = 12, Al = 13, K = 19, Ca = 20, Sc= 21)
2+ 2+ + 2+ + + 2+ 2+
(A) Ba , Sr , K , Ca (B) Li , Na , Mg , Ca
+ 2+ 3+ 3 2 2
(C) K , Cl ,Ca , Sc (D) N ,O ,F ,S
Q11. For electron gain enthalpies of the elements denoted as egH, the incorrect option is:
(A) egH(I) < egH(At) (B) egH(Te) < egH(Po)
(C) egH(Cl) < egH(F) (D) egH(Se)< egH(S)
rate rate
(A) (B)
[OH ] [(C6H5)3C-Cl]
rate rate
(C) (D)
[Pyridine] [(C6H5)3C-Cl]
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-11
Q13. All structure given below are of vitamin C. Most stable of them is:
OH HO
HO O HO O O
O
(A) (B)
H H
O OH HO O
HO HO
HO O HO O
O OH
(C) (D)
H H
HO OH O OH
Q14. The Industrial activity held least responsible for global warming is:
(A) Electricity generation in thermal power plants
(B) Steel manufacturing
(C) Industrial production of urea
(D) manufacturing of cement
1
(y = 3x +2.505). The vale of and log K are respectively.
n x
log
(A) 0.3 and 0.7033 m
log K
(B) 3 and 2.505
(C) 0.3 and log 2.505
x
(D) 3 and 0.7033 log P
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-12
Q20. O-O bond length in H2O2 is X than the O-O bond length in F2O2. The O-H bond length in H2O2 is
Y than that of the O-F bond in F2O2.
Choose the correct option for X and Y from those given below:
(A) X – shorter, Y = longer (B) X- longer, Y – shorter
(C) X- shorter, Y- shorter (D) X- longer, Y- longer
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-13
Q1. The molality of a 10%(v/v) solution of di-bromine solution in CCl4 (Carbon tetrachloride) is ‘x’
2
x= ______________ 10 m. (Nearest integer)
1
[Given: molar mass of Br2 = 160 g mol
1
Atomic mass of C = 12 g mol , Atomic mass of Cl 35.5 g mol 1
3
Density of dibromine = 3.2g cm
3
Density of CCl4 = 1.6 g cm ]
o
Q2. 0.3 g of ethane undergoes combustion at 27 C in a bomb calorimeter. The temperature of
o
calorimeter system (including the water) is found to rise by 0.5 C. The heat evolved during
1
combustion of ethane at constant pressure is_______ kJ mol .(Nearest integer)
1 1 1
[Given: The heat capacity of the calorimeter system is 20 kJ K , R = 8.3 JK mol .
Assume ideal gas behaviour.
1
Atomic mass of C and H are 12 and 1g mol respectively]
Q3. A B
The above reaction is of zero order. Half life of this reaction is 50 min. the time taken for the
concentration of A to reduced to one- fourth of its initial value is___________ min.
(Nearest integer)
Q4. 20% of acetic acid is dissociated when its 5 g is added to 500mL of water.
3o
The depression in freezing point of such water is___________ 10 C.
Atomic mass of C, H and O are 12,1 and 16 a.m.u respectively.
1 3
[Given: Molal depression constant and density of water are 1.86 K kg mol and 1g cm
respectively].
Q5. Among following compounds, the number of those present in copper matte is______.
(A) CuCO3 (B) Cu2S
(C) Cu2O (D) FeO
CH3
O
Testosterone
The total number of asymmetric carbon atom/s in testosterone is___________.
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-14
5
Q8. 1 10 M AgNO3 is added to 1 L of saturated solution of AgBr. The conductivity of this solution at
298 K is__________ 10 8 Sm 1.
13
[Given : Ksp(AgBr) = 4.9 10 at 298 K
0
Ag
6 10 3 Sm2 mol 1
0
Br
8 10 3 Sm2 mol 1
0
NO3
7 10 3 Sm2 mol 1 ]
2+
Q9. The spin only magnetic moment of [Mn(H2O)6] complexes is_______B.M
(Nearest integer)
(Given: Atomic no. of Mn is 25)
Q10. A metal M crystallizes into two lattices:- face centred cubic (fcc) and body centred cubic (bcc) with
o
unit cell edge length of 2.0 and 2.5 A respectively. The ratio of densities of lattices fcc to bcc for
the metal M is___________.
(Nearest integer)
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-15
Q1. The sum of the absolute maximum and minimum values of the function
f x x 2 5x 6 3x 2 in the interval 1, 3 is equal to :
(A) 10 (B) 12
(C) 13 (D) 24
1
Q3. Let f : R 0,1 R be a function such that f x f 1 x .Then f 2 is equal to
1 x
7 7
(A) (B)
4 3
9 9
(C) (D)
4 2
Q4. The number of integral values of k, for which one root of the equation 2x 2 8x k 0 lies in the
interval 1, 2 and its other root lies in the interval 2, 3 , is :
(A) 0 (B) 1
(C) 2 (D) 3
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-16
1 1 x 1 1 x2
Q7. Let S x R:0 x 1and 2 tan cos .
1 x 1 x2
If n S denotes the number of elements in S then :
1
(A) n S 1 and the element in S is less than .
2
1
(B) n S 1 and the elements in S is more than .
2
(C) n S 0
1
(D) n S 2 and only one element in S is less than .
2
Q8. Let P S denote the power set of S 1, 2, 3,....,10 . Define the relations R1 and R2 on P S as
C C
AR1B if A B B A and AR 2B if A BC B AC, A, B P S . Then :
(A) both R1 and R2 are not equivalence relations
(B) only R1 is an equivalence relation
(C) both R1 and R2 are equivalence relations
(D) only R2 is an equivalence relation
Q9. Let 9 x1 x2 .... x7 be in an A.P. with common difference d. If the standard deviation of
x1, x 2 ,....,x 7 is 4 and the mean is x , then x x 6 is equal to :
8 1
(A) 2 9 (B) 18 1
7 3
(C) 25 (D) 34
Q10. Let P x0 ,y 0 be the point on the hyperbola 3x 2 4y 2 36 , which is nearest to the line
3x 2y 1. Then 2 y0 x0 is equal to :
(A) 9 (B) 3
(C) 3 (D) 9
1 1 3
Q11. If A , then :
2 3 1
(A) A 30 A 25 A I (B) A 30 A 25 2I
(C) A 30 A 25 (D) A 30 A 25 A I
2n2 3n 4
Q12. The sum is equal to :
n 1 2n !
11e 7 11e 7
(A) (B) 4
2 2e 2 2e
13e 5 13e 5
(C) (D) 4
4 4e 4 4e
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-17
st
Q14. Two dice are thrown independently. Let A be the event that the number appeared on the 1 die is
nd st
less than the number appeared on the 2 die, B be the even that the number appeared on the 1
die is even and that on the second die is odd, and C be the event that the number appeared on
the 1st die is odd and that on the 2nd is even. Then :
(A) the number of favourable cases of the events A, B and C are 15, 6 and 6 respectively
(B) the number of favourable cases of the event A B C is 6
(C) A and B are mutually exclusive
(D) B and C are independent
1 ai
Q15. Let a, b, be two real numbers such that ab 0 . If the complex number is of unit modulus
b i
1 a
and a ib lies on the circle z 1 2z , then a possible value of , where t is greatest
4b
integer function, is :
1
(A) (B) 1
2
1
(C) (D) 1
2
4 x
Q16. The value of the integral 4 dx is :
2 cos 2x
4
2 2
(A) (B)
6 3 3 3
2 2
(C) (D)
6 12 3
Q19. Let a 5iˆ ˆj 3kˆ and b ˆi 3ˆj 5kˆ be two vectors. Then which one of the following statements
is TRUE?
17
(A) Projection of a on b is and the direction of the projection vector is opposite to the
35
direction of b .
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-18
17
(B) Projection of a on b is and the direction of the projection vector is same as of b .
35
17
(C) Projection of a on b is and the direction of the projection vector is opposite to the
35
direction of b .
17
(D) Projection of a on b is and the direction of the projection vector is same as of b .
35
Q20. Let the plane P pass through the intersection of the planes 2x 3y z 2 and x 2y 3z 6,
and be perpendicular to the plane 2x y z 1 0 . If d is the distance of P from the point
2
7, 1, 1 , then d is equal to :
250 15
(A) (B)
83 53
25 250
(C) (D)
83 82
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JEE-MAIN-2023 (1st February-Second Shift)-PCM-19
Q2. Let x y yz 1 be the equation of a plane passing through the point 3, 2, 5 and
perpendicular to the line joining the points 1, 2, 3 and 2, 3, 5 . Then the value of is equal
to………..
Q4. The total number of six digit numbers, formed using the digits 4, 5, 9 only and divisible by 6,
is…………
Q5. The point of intersection C of the plane 8x y 2z 0 and the line joining the points A 3, 6, 1
and B 2, 4, 3 divides the line segment AB internally in the ratio k : 1. If
a,b,c, a , b , c are coprime are the directions ratios of the perpendicular from the point C on the
1 x y 4 z 2
line , then a b c is equal to………
1 2 3
Q6. The sum of the common terms of the following three arithmetic progressions
3,7,11,15,.......,399 ,
2,5,8,11,.....,359 and
2,7,12,17,.....,197 , is equal to…………
Q7. If the x-intercept of a focal chord of the parabola y 2 8x 4y 4 is 3, then the length of this chord
is equal to…….
m
log2 10 3x 5 x 2 log2 3
Q8. Let the sixth term in the binomial expansion of 2 2 , in the increasing
x 2 log 3
powers of 2 2
, be 21. If the binomial coefficients of the second, third and fourth terms in the
expansion are respectively the first, third and fifth terms of A.P., then the sum of the squares of all
possible values of x is………..
x2 y2
Q9. The line x = 8 is the directrix of the ellipse is E : 1 with the corresponding focus 2,0 . If
a2 b2
the tangent to E at the point P in the first quadrant passes through the point 0, 4 3 and
2
intersects the x-axis at Q, then 3PQ is equal to………..
22
2
Q10. If the term without x in the expansion of x 3
is 7315, then is equal to……….
x3
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