. « “S b
e
TART TAM, tt
227 WI TelD ay os ficzs Batra era a aan epoca Hise Bea ATS |
(n= 1)d°ns! [n= 4]
ot, Saieced Seraie eapilt afearedt—aprest oa | [puctaa]
u, Gatered d Bomeie ara Sem Beriverns way RTo aeIR wey are wNTAe
Conroe Fea fey Efe farses ea | [o.cr-ag]
a ___—_—
© 2 (4 DANS! A, oceeenren dds!
wate Cr(24) —> 15° 2s? 2p*3s° 3p° 3d 4s!
saat 2eTaas feo ar Berar aece fe fer wafebrer oR aca Sar Os “fear wafeorer
at wea | Raa Car walabrey pf Vou ak Haare wrowAy MS acer |
ait range fafeg wafebiera “fea Swarr feat
Is <2s < 2p <3s <3p<4s < 3d < 4p
0) Sar ee ay asia “fe wr ace) ai A Bafeors CREM (n + C) Ot TA AMA BE, Se
Gl SARGTATES n? oz WR SH, SOTA GFE Salar OIE erat wea! BAT fe for waheor | foe Sw
tara Saran fear aafews wbAT EC
Cr aa Reever far Feat:
Cr(24)—> 1 2p®3s? 3p" 3d° 4s!
mente Poy wale Bara wat yeh aT dal OE oe TTC FefoMersr aehT Ste 1 OE Se
as Gere frie pferer ees sat a) Bags aT of d-waiete aa ara Peer eres feet
CALS 4s CoC GaN Rea 3d CH EMTBTS BH |
Cras Crm 3d wafabree Berea ART 4 Ut ofort oom Mate Berea ow | yea Pefettrer wets eT
eatery wdeet Rom AMET | a MATT OE Seg! weiera Say 4s safer care eel Boras 3d
‘wafabrn grarefaw art eee Cr éyef wegnr feloArTer ASA eA |
© a8 wages cx cae OB Berd oT comb Aes TA TG OST WS AAT SUR ST GTS
SERA gD Berend fond corte HATH HI aE eam ad Con HR eA SA
Cr(24) —> Is" 2s’ 2p°3s” 3p? 30°
GUO i
aaefg: seog Seq Gatton Berebrecd ares Way Sart GM Wel ates He PY aT faceny
WAS UTS I aR © facory Berabaacera Poa are Gea | d-Borsfeera fears ereiaena Bay
CORTES ART
eo n=3e—>n=3, s=+
e—>n=3, (=2, m=0, so
e—on=3, C=2, m=-l, 4
es—>n=3, C=2, m=-2, S24
Sete Berar SHAT GTI (n), SPE (() @ Pom (s) ase ere AIS WEA (m) fy
D ett os Feast Chtralh eras oa cer orators Hide Beat wns |
«:
8. Galrcen Reraatha gerecas wo AB ahi afBonos aa fara? Aes fecereet we |
fou: H smarga Srafers wey
1, Datorces dehy crea Ailes Reval vial FET / em aa TA faefayde fers SA 1 [oaT-23)
[uctt-23]
© Brrrces where afew oe eee rete CORNET HeIT n = 4
Sem COROT | Rea CHRO TPTCARS COTAT OTT Ret (m) wateort | Gio Sry
FCT (n) Feat (0) ATT FT
0 1
1 3
‘ 2 5 2
3 7
© oa af,
=e J4_4) eae,
A wil om ny = 2 (frag @FTR)
mi
a, 4 = 4.8627 x 10 em
am,
2. = 486.27 nm
Lo
109678 [= -3] = 20564.625
= (4.8627 x 10°) x 107 nm
ny = 4 (Sw wR)
Upriat (Indigo) wa wrens Tar Caef 450-500 nmi wee ffs af wf wpanfs aa) wwue AB
acho aftorpa wc |D ote os Hera Batoralh ary sa eR SepereTa APT GEA ATS |
Tsomk3.0~10°M] [ 60mL
| poze
ae
MQ; Gitevra graven acter 4.5 x 10%
91, OMe) ea BRAD AHP BOT MyN; a TST OT POAT FH |
SL, 9Ae OT PRATT ART AAT SLOT SS AOS GR AL TMT TTT awe FART FATT MQ;
(o.cr-83]
SEITEN OGTR? [nca-23]
© «ff, MN; 64 B84 = S
2M* +3N™
Wo
GRITS OFM, K,
SM TNE,
grave, S=3.0x 10°M
08 x (3.0 x 10°)
2 x 10°! mol*/L*
frerera qe M** a,
rmem, V, = 50mL
waa, S, =2 x (3.0 x 10°)M
‘Firereers 1c,
0 x 2x (3.0 x 10°’) areH, (50+60)mL = 110 mL
11g wana, $=?
S)= 2.727 x 107M
AMI-2,
PQ: P+ 2Q" freee ac Q" aH,
‘sal an, SHB, V; = 60mL
ViSi = V2S2 ware, $) = (2 x X) M («f)
a, s,-%% matax fRecera 1c,
= (60+50)mL = 110 mL
. S)= 1.091 X
MQ; M* +3Q"
Ky=(M*}(Q)°
ARE, SETA APCS, Ky > Ky
i, (M}IQT > Ky
1, (2.727 x 10°) (1.091 x)'> 4.5 x 10%
3.34 10 S'> 4.5 x 10°
5x 10"
3.54 x 10
mxa, x>V127x 10"
x> 2.334 x 10°M
welte, PO, A WANN FUT 2.334 x 107 M at AT RET WT MQ, a BTR GCA |
D ony o8s Fea Bars aay aa ose Heres Ase Bae Ars |
are
FS iPar
Tere
IN corr career Reereags corres HH fathers afte ceiBeaa MAS 1.45 x 107'KI]
ot, Sajorcea wrens one wwe waar Fea fetuses Acdtoy TAPS TTA HAT CHT
Fees RIT FETS Fa [rucar-2a]
&. Batters Berediers eoracas Ue fafefaw aya wamtacets odes feta oat | [auetag]
© BHore Bats areata aeeiey erty THR Be HTT |
[eer WET fam | Sawa ae |
| corntm corerort aooraibe cormrBe att (m) at | Conroy | Bera ata
ART (n) OF | Fea (C) at meat (s) | Fe Bea
um | stewa | ae | boas a Saab AAT ae
| 0} 4s 0 1 2
| 1 4p +1, 0,-1 3 6
4 | N-orr | 2
2 | 4d +2, 71,0, 5 10
3) af [43.42 41.0, 7 4 i
ON cr core erates wer fafefire «fea era,
ama ais, fates a, at,
piu = i= AE = 1.45 x 107k) = 1.45 x 10 J
AES hu= hy h = 6.626 x 10" Js
_ 6.626 * 10° x3 «10° arena Cat, c = 3 10° m/s
, © 145 «10° waa tf 2. = 2
a, 4 = 1.37089 = 107m
4 = 137.089 nm
(i m= 10" nm)Oram, wnat ors,
F |
=Ry| 73-7
Ny Ny,
= 109678 [+-#] cm!
A
wan traf, A=?
I= >I
4
7 = 15233.05556 em"
A
>
|. A = 6.565 x 10cm
A = (6.565 « 10°) x 107 nm
“= 656.5 am
«. fafefe wen Creufa afar = (656.5 — 137.089) nm = 519.411 nm
> oF oes Firza Oahraly ary sa aaR ermperera Hise Bar ANS |
A
25°C 25°C
AIC 384 NaOH 84
Ls x 10%gL" 2.5 x 10°M
A-mTa Be"
AN(OH); 4% Ky, = 1.2 x 10"
91, Galore A omoae area BTaTET were fafa aa | [#129]
a. Balter A 8 B ora Beran fife sac fie Baca erpfe Fa wa—mffSerora fore a |
[x.ctt-2a]
® AICI, 63 are,
Ls x 107 f = 13
_ — = 1.124 10% mol L" AICI a3 Srefae ea = 133.5
AP’ +3CP
38
= S x (38)' = 278" = 27(1.124 x 10°%)*
= 431 x 10 mol'L~*
© A 6 Boma CRON, BerNa SIT OTTEA = VL
fafeeur: AICI, + 3NaOH —> Al(OH); + 3NaCl
arma fe,
ViS) = V2S> ae, AL as ona,
VS é \
=, s,-48 fiers qt4, STIe, V\ = VL («ff
“ 3 “AUR, S) = 1.124 x 10° mol L!
Vx 1.124 x 10 ' oun
MI, S)= Rreiort otce, STE, V>=(V +V)=2VL
5.62 x 10°M eitexit, OH” 6% OFT,
2 , 10°M
. NV x25 x 107
~ 2V
25 10°M
Ga SERS GARETT:
AI(OH); === Al” + 30H
K, = [Al] [OH |’
= (5.62 x 10°) x (1.25 x 10°)
= 1.098 x 10'!
CREE Koy > Kip TR ATE BAS GHOST APTA |
> ot os fires Barras wee AEE ecxa Baa ATs:
0)
NaOH
ae at
A2 > [Ar]3d9
x Y
11, Galea A gatiiow Bhiced fame X Bea Sea cat sare S oifsesa rw Sara OT AM eTAy
ot
%, ft foq Gs-Bere SHteces Bg Aca Aha fae X GY COM sae FH eb? TA eaPrE fre
TH _§
@ Barca A” —> [Ar]3d”, A —> [Ar]3d'°4s! aig A Ts (Cu) cw fot wa
Bors (IL) AS, CURA. THT ATTA HAC OTC TATETHTSS HT CAM SATA BHATT HOT TACT
4 Bae ae aac G SENT aeS See ar) Benq Aad Sra fee ofa NH,OH ae
capt Sacer GGT emir fesiers mrerced a sy Aer acta wet oem aT | O% fefers atTCN Sera SE
MATH HAT SAT ATT |
2CuSO, + 2NH;OH —» CuSO,.Cu(OH)¥ + (NH4):8Os
Reve Aer Wes
CuSO,.Cu(OH); + (NH,):SO, + 6NH,OH —> 2[Cu(NH;).]SO. + 8H;0
ab Aleta© Shorea B apefiirracs (Al) For wea | ae oeseT 1-2 mL FT BAH PTT AT |-2 HBT NaOH
BAT MMT ATT | AAT CS ATTN SST BET OE o BAEOROT ate VSATe NaOH BAT CIMT
Sa TAT SST CAT BAIS RCH UAT) WAAR geet feR SA NHAC] CM Fea See Fe) ERAT AAT
oraTon Cot Farce SIT |
RTT AI(OH); 24 AMT MOTT COPA AIR BEET TG |
AI" (aq)+ 3NH,OH(()—> — Al(Geryd + 3Na"“(aq)
ar OTST CHA)
‘ASE NaOH Het ca Fae 4 BATT NaAl(OH), Sey WI
Al(OH); + NaOH —>:NaAKOH),
‘35% NH.Cl Cit wa See Fata 4A Al(OH), 8 AT CORA ATE Bees oar fect TCT |
NaAL )y+NHCI—— "> AON) gb + NaCl + NH: + H,0
(arm covet)
gat AP ort S#fyw | NaOH Bata oftars ome NH,OH Bete Bea sates HAT atKAT coh
TOT SesCRCA HB ee fee Geacw BISIEe NH,OH Bare Feef wire BATT cate wT |
> ae 098 com Bar afeSe ARE ecria Seq ATs :
Bal >) TRE
[PY2 9% Ky = 1.85 x 107%)
1. 316 an strona Fars Bare p> oa warmer faefy sa | [Fcraa]
W. O9 6 2m orcas Rect PY, washes aa feat snfifeesrce fecee oA | [f.ct-23]
® PQ == P*+Q? ours, feera a4,
ar) 30 * 0.5 PP aa ere, V, = 50 mL
(P'] = 2
50+ 50 Po a4 SAT, S; = 0.5 M
=0.25M fas geet Gnd wnTEA, V, = (50 +50) mL = 100 mL
fafers gece Pas yaaa, ’
© frerera ota Hefty fee: PQ + 2XY = PY) +QX) 1
PQ P* +?
erat of, eae,
ViSi = V2S) Freneit 4,
a, 5-48
50 + 50) mL = 100 mL
Fafere qact P?* oq wear, ?ater, fires 94,
Y a4 oTrer, V; =50 mL
Y a WRT, S| =0.1M
fate warts ond wre, V, = (50 +50) mL = 100 mlo
fatere get Yaa WaT, S, +?
PY2.4% Kyp = [P"] « [Y ]? = 0.25 « (0.05)' = 6.25 x 10%
CRRE, Ky = 1.85 « 10°
Kip Kop 1 PY) G4 SETH NYT |
D ay ove Fiera Dire eras ea aaR eoerera Aids Bee ATS |
Ose EM A 6 Baa fear afb Berea fear free:
A(19) = 1s?2s?2p'3s?3p°3d! (STSeaTe Frac)
B7) eB (1) (UL 4] _| ceces free)
e
G
A, e, TRe, a corn fra aS I | [zeraa]
a, Baocea gone fret Serdar gia afsewr Sorqe erarre facet 74 | [ect-as]
© Barres B Gilera Bera FAT
8) > fi} A) GAT)
1 3 5 6
2 4 7
ett OATS OF OR BE Vera VAG oMTGM eT WA BATS USE ATS TAT SER ASR TALS
SEAS AD Revere feat corarber Meee AH eR RreTG HE CHT FAT INTE FAA |
eReader | n-1 | c-0 | m=0 | s=4
e; Rares we | n= 2 t=1 | m=0
Baocea Here Poe Ge CGA ONS COTTON AAT HIN SHE ae ATS fon coTUTON Head NE
foq foq | Teak areca aire zee Aife CTE |
@ wiSeans AS epics OTN Reeve ears PHM
joK —> Is? 2s? 2p? 3s? 3p" 3d 4s!
an + Creme Prey eee A Pos a THT TL (1 + C) ea IA SE CH STRFADTCMT ROMER TEN MT
Sata | Ral fry afer wrafeiTeT |
cua 3d SAMBA BAT n = 3 AR C= 2 AWAR (n+ C) = (3 + 2)=5
45 ORAS HAT n= 4 Gee C= 0 FWAR (n+ CF) =(4+0)=4
SAM 3d GOVT 4s GATATTCHT (n + C) A AIA SH AL
Bi oDIPTENA ye OA Ree 3d Goraca a1 fitew 4s Seraca A
rain aeory FAfog ARAB ROTAGTOTA OTH STR STR ALA CH Ta AR MST TH AT FACTS
eA STATS MCA Mae FACTS Ree ToceTA Pers Rea aL |N at Reeraia fae fezwer- AHR: Noy = Is? 2s? 2p! 2p! 2p!
OU Ot) TTT
rfs4 2p, 2p, 2p, wafebrreceme gaat ot Pers eeit at Beret acre ara ee eifee
FROSTg STEN SIEM BE |
> oF ops Reqs Bara aay sa ee orepereta Hide BET Ate |
ir
PAR
E
TM TCE
1, Gateres fatetaw afiya wantruf fora ea | [Rer-aa]
BE carer 32 {Ba cat Recreate eres orca ar" _corerore ear WIceTICs Facet ea | [cra]
© sma of, ater,
tig w [4s] n= 1 GRE)
Un m. ny = 3 (OF FRra)
Ru = 109678 cm!
109678 [4 3]- 97491.56 ear ta, =?
A= 1.026 x 10% em
®
Eri FR Sota | aa
err corre ameaBe cormrsry Aeagt (m) a Rereat| aa
ARM (n) at | ART ({) oF ae | Beret
4m | “eee | a | See | a ea ART ae
0 | 4s 0 1 2
: 1 | 4p +1.0,-1 3 6
4 | N-crer a“
2 | 4d +2, +1,0,-1,-2 5 10
3 | caf | +3, 42,41, 0,-1,-2,3 7 14
sik ex fea Jaf Gi Renan ace Tart) reg dn? AS qui ex ibe Wael Wea
wer 508 | foe en afeas of oma 948 Sera Ub fGaca acet we |R08 | are we ROTH § OF J
> eS Saatae eee
100mL | 80 mL
6x 10°M caPocareris
CuSO, NaOH
wat at
A B
Cu(OH); €% Ky = 1.0 x 10"
[ears]
% ACB ea yet ytcw aan Fife Farr Sears fea mUTareT mifewerd Reet FA [zcT-Ra]
of, Balerces BITE Cu(OH), AF Braet feats Fa
rr
© wer &, Cu(OH), 44 BITS = S mol L
Cu(OH); == oe +20H
28
: 3 fox 10"
es Aja
© BAorces ay aR TR aa Ba OCR Fate ace Facer fafiteaT SCE |
CuSO, + 2NaQH —> Cu(OH)2 + NarSOx
fetes ofa, A TER CC,
: CuSO, == Cu” + SO
= 2.924 x 10° mol L
amma er, area, Fiercta 904,
ViS1 = V2S> Cu?" a ere, V; = 100 mL
ay $2 Manx IO) Cu ae era, S) = 6 * 10M
3 va uy Fifire gacta cad GRE, V2 = (100+ 80) mL = 180 mL,
=3.33 «104M fafaw BACT Cur wa TATA, S> =?
B atone crc,
NaOH === Na’ + OH canine, Freres 4,
conran sat, OH aa SHER, V, = 80 mL.
ViSi = VaS2 OH «a wawtat, S, = 0.01 M
a, g.- oot faire BACT CHIE STTEA, V2 = (100 + 80) mL = 180 mL.
2 ee
Aaa tooM fafate gett OH 4 WAN, S, =?
Cu(OH), aa facarers fafiear fest
Cu(OH), === Cu” +2 OHKy= (Zn" [OH F
TW, Ky = (3.33 * 10) x (4.444 x 107
ZH, Ky = 6.576 x 10”
Cu(OH)> 8% Ky = 1 «10-7
FIR Ky, > K,, | BAS Cu(OH)» GF BETA HLT
Som yos fea Batralh ores aa ae erecta aise Beat Ans |
waa ae-B
Kgp[Mz(SOq)3] = 1.75 « 10-1!
o, Balerea A-BAT OH OF WARE g/L aero fend + [B.cat-2a]
u, weran fire ware wesc ete fre mfemwIe fcwEt oA | [p.cr-aa]
® MOH); M’ + 30H
0.03M_—(3x0.03)M
OW) SIRtAS BraTET = (3 x 0.03)M.
= (3 x 0.03) mol L! = (3 x 0.03 x I7)g LL"! = 1.53 gL!
© We4-A, M(OH); M* +30H faerera 904 M** 7,
nist sf, ‘ORTea, V, = 60mL
VS = V2S2 ANT, S| = 0.03 M
at, 5) =MiSig, = 800.03 fiers oa,
2 RV PF 10 ‘SRTER, V2 = (60+50)mL = 110 mL
2 = 0.0163 M AANM, S.= 7?
-B, MSO, 2M" + SOe
amar or, frrerra 94 SO; 43,
ViSi = V2 ‘SrA, V, = S0mL
at, s,- 48 ama, $; = 0.04 M
° Frercta cH,
50 x 0.04
a, = SRTEA, V2 = (50+60)mL = 110 mL
S) = 0.0182 M Toa, S27
MxSO,)s 2M" +380;
K,=[M"P [sor]
Ky = (0.0163)? x (0.0182)°
Ki, = 1.6 = 10°M [orem are, K,, = 1.75 x 10°")
CHE Kip > Key, Mx(SOq)s S:FRE BA |D ate one eas Bala oray se ee enters HPSS Bea ANS |
Coo 3
py
n=1
= 109678 cm-!
9, Dalorcoe arence Shore Cle “ANS SAT UAT? GIT FA [B.car-aa])
4, Biles teralaia 5 3 eR QaIeTeT CRUE ene shit aca SUE oye eneTbAT
ea | [b.car-aa]
I ____
© tears wares wet eB a cece Gils MTS Sar aT orcas caer . SPAR MATOS | OIA: GA SPT |
3. Became caret freee |
2°. Gare fofeern |
8. fefmecwafine (acer OM, area HET @ fee fret Be) |
ec. eae eiesry fierce face AATATe FAT |
BR HTT He ATS |a. BG comma Caterer aeomw cart Fea
bv. Weare afee (Ears icfow
d, SOSA TDP AM ARTS
30, RIGSTAT G CONGT ICA Sets TAT |
>>. Cafeern cremate srafere cafsert IR etfevelace Thermal IR Tt!
D ote y08 Rees Baral wey sa ee ermperrrts Hise Beat ANS |
=
5, A aa are fof a1 [Fucat-aa]
u, Shore Binttw afta wae Cres frefayse aaa WTO TA | [Fucar-aa]
$$
GTC,
ny = 1 (RR Pte)
I < ny = 4 (So FFA)
= 102823.125 Ry= 109678 en”!
9.72 «10° em ‘arena sfcet, C= 3 x 10'° cm/s
(9.72 x 10°) x 10” nm a=?
4=97.2.nm
© ama af,
ny =2
ny = 00 (SAD TY)
Ry = 109678 cm!
war Ore, A=?
1
A= 374195
3.647 x 10% em
@, 4=(3.647x 10%) x 10’ nm (= Lem = 10" nm)
2. = 364.7 nm (Ans)
UV af: 200-375 nm Gam Cres fates afece wfecaert afy a UV I CT |
IFS TRS Cs Cofecw Frater {ST (Security thread) M1, 7M (Image) VS | ak Farrer yer
TEN PACH ATS Ue Haas SH Bag By | AF WATTS Fe (UV-fluorescent ink) tefacw fafeq
wifa Mex SaNRS 9 eHTEMTRS GrICAA fie eAw BWUR SaM Orcas Gee 230-375 nm SAF CATAHT UV SKN OHTA SL eR FRR Ga CATAa PTET APY
fafeact sca adie 380-780 nm a7 tacala fafeararat arate orf 230-375 nm Gam reels UV af
weber ATS aL BST MATERA APT aTRS OT |
‘SIRS FahH GAD Security device a7 Saibaret ori TOK ae se Aas Saas VT A ST
rer TAPS Tea VAT! IES CTS aT POM eral GS MATES GeTATETT ComrECOTATTA
cafrafta (JACOFP6200) FRET UV af atefow sare AME aes wre TST OTe ATT | SET BT
ATG ACT OF SITET CANT ATTA |
AETEAHA 100, 500 6 1000 Brat crBecems UV afin aaa Serer erer, caval @ ze tet fefeaet sea |
rea GTS CHAR. 5 Wentes ater sf, 10 Genes eTrer af, 20 wentca HEH af, 50 wera Reva aH Af, 100
wena wae ae we |
ean Safes whet UV wesc |
D or oes Rea Baral ery sa ee eters Ae Gas ats |
A
@)
is
He* O wim
Ry = 109678 cm-!
ot, Sales BWA C SHR Te B FRM eee etre mie vfs tA eA) [u.caT-g9]
§, Giemsa Sly aay cere Berea B OTT Gate Spr feet «fe pas es fear? nose
Facet 4 | [a.ca1-33]
© ana afr,
1 rT
RuxZ [ _ ] SATA,
1M ny =2
fh cn! m=
TRIS 8 | Se Ry = 109678 cm!
60932,22 em! oem toe = 2
Z=2
. A= 1.6412 « 10% em
fates “fe,
° = «102
AG=ho=h? MNT, h = 6.626 ie ergs
= os o HIER CAM, c= 3 x 10! cm sec
26 x 10.77 x3 x 2
wag - S26 Ste warm ref, A = 1.6412 « 10° em
AE=?
AE = 1.211 «10! erg |i
4
lio, (2 ‘) ny=2
x Ru 2 armas ny = 00 (SARE RP)
1 tod Ry = 109678 cm
™ z= 109678 x 3(3r~ a) aT CHE, A=?
1 Z=2
a5 wnumex (4 -0) cm’ = 109678
TH, A=9.12 x 10% em
= (9.12 x 10%) x 10’ nm {Lem = 10’ nm]
A=91.18 nm
Caray Cartref 91.18 nm Bt UV AP (10 — 380)nm at BETS | Bete fase fs opty Kc |
F eet ses rea Baa ores Sa eR ereecera Aide Gea ATs |
AY OE TT OH Ky = 4.8% 10-7
1, Dae Ty eR TMQ a RES BACT BY AACA VATA TAT | [acral
W, Da ST M-> Oe MQ at Tee fie sae AY, GF SeseRT nye for nffSewre facet
wal [R.t-aa]
EE
@® — AsB) + 6XY —> 3AY2 + 2X:B
BY 43 3, aa, fiers 9d,
AsB) 3A” + 2B" BY az STH, V) = 40 mL
oraaT aT, B> at WAN, S) =2 <6 «107M
ViSi = V2S2 i FRfew wacra cad STA, V2 = (40 + 80) mL
ai 5, atti f022x(6%.10) = 120 mL
manny 120 fiftre qa BY aa WATE, S2
S)=0.04M
© fiers 3,
AB + 6XY —> 3AY2 + 2X;B
AY 63 3, oer, firerts 94,
AB 3A” + 2B* AY ax STTeR, V; = 40 mL
AY aa EMM, S) = 3 x 6 «107M
fafers gata CHS SETTER, V2 = (40 + 80) mL
120 mL.
fafers qact A? oa ENTE, S) =?axe, Frere 4,
Yo aa ome, V, = 80 mL.
Y> aa wratan, $= 6 « 10°M
free geet ard OTT, V) = (40 + 80) mL
120 mL.
2
I, Ky = (0.06) * (4 x 10°)
Ki =9.6 x 107
FGM AMR, Ky = 4.8 « 10
Ky > Ky UR AY: oF Sere Iga | Sei Beet BFSTS 1
D op ous Fez Varah eres wat cae erstecerta Hise Baa MS |
erat
ery
ities SRT
Wwwa-A
WoA-B
st, Batcea B-xowerlo Haars xe Beeralicas fafetre atts wore frchar a [zct-2a]
T AGRB TOO Teg Mle afeaea Sorcat acer wea a_fareret SHY [2.423]
OAT,
ny = 1 O® eee)
ny = 3 (oF FFA)
Ry, = 109678 cm
werera stata, c= 3 x 10'° cm/sec
worn, v= 2
ORT,
eam teh, 4 = 1.026 x 10° em
ay 2oOx 08
»Y = "7026 * 10
= 2.923 x 10'* Hz (Ans)
© Sécea SAY AIARICOTS HOGA OAR SB? ATA CSTR CHT Hea | THAT TAAL ATS @ CATE TATE
TOUTES TUT, CATH TET AoE write Borceni erat —
>. TRRORTS oN AEST wpe fefey wee ReratiTece BATA eNCe | TiseTATETS Give PST
we prea eter wigs vege Reais afta wie fafoar ware) eer Bera Gare «ie
RAS AALS PRACT APTS AAT CMTS TAT eR ATCA Sera PSHM afew Ae
a8 SET FATA BBY AIF ATTee I ANY, NOT PINS Aeraga fee fea ewe STTAeT Ce eer ME CE aT
fafeast wea aT) RTE Bera Slee ye Reet acpe BHM afew MT AT we ATTA
‘wfeR TeTT aCe |
2, SARTRE TOSS FTO aT ara HE CEM Trot rea wai few cals AEC AAT
rete efits ret OTSA ATT |
©, TARTS TE WMT ero Perc le @ eTpies were GIA Meet AB; fee CT
Tos ART STR SHCA TAS fTa Fa UT |
8, aMraceré acer wpiis rele fears fe fafeat earn oemrys frafetiag whey moms ser, foe
area fie art eit orem wa) weRince aM Hea Sp Bera oe “feet cae GT
wafer Gree eer aE amtMTETT os oat fate cre afifeT MSA TT
¢. aRRTETE woEe crfee aT fafefas «fea cor ara fice AT mace Cala AMT AST one eT
fatofaw “fea ares free ca |
&, aIRTaRTE WEEE Rerera ihre waracrs CHT TAT GAR | fee ca TSC ReraCTA cae
SAAC MTA CHGA SEACH |
Bocas MATT CRITE RAT ATT, AVATARS TS OST ICHMT CAT TANTS CERT fe Sorc |
D ot ye ficza Batre erey Fa aa erecta ASH BeR ATs |
Kgxaycn = 17x10”
st, Deora ele ereera mere Star are CT [a.cr2a]
¥. ‘SRL ATT O.1M HCL Cat acer TATST weTeCeTA CHTCAT saa BOTA fT fecaret FA [zara]
SE
© Beorea Ge OAD Ch ORT) GS eae Fat Beret ARGS wet cam eae PreteTs
GRRE TT BEET oC TAREE afroe CERT few oremfia eRETHEE BAA |
NaCl + AgNO; —> AgCll + NaNO;
TAT BTR
AgCl + 2NH,OH —> [Ag(NH))2]CI + 220
(oR wont Pets GAR)
(NH,OH 4 344)
© (i) AgCl === Ag (aq) + Cl (aq)
(ii) HCKag) —> H(aq) + CI(aq)
AgC] & HCL See Racers wen CY wr Beery wea 1 ote aeRE Cl TEA ROR ARS | NTE
sgh oer ya Se aT Cor eto carey tare Fer ATH A eS ATATOT CN TH |
O SDACS ATA ASS TA |
FARE wren Core eB Aa erat FEO Tac Gorhgw SoA ANAL APTA NT GARSTCS
ararora eoerey We CYS HATO em et oT fy TAT wet eT -eTOAATA AS erga (JR
FRRRMTS TUTTE OTe, CRE AL | AOS Ag” SACRA VAST RMN aT | FRE ATSIC STAT CI OA TTS
sare fersree CC TAT | Bee CU TT MeeTRT CT ERP AH, FBR MAR ATER Ag’ AACA SATA AMTA | UCT PYTBSICA Ag” ST @ Cl GRAS CUTS KAT CFR SAT GATS STI GTS ees |
OTe THT UH, ATSC eteted AITO Gra ASA TT |
ff, AgCl 4 grayer *S*
HCI—> H" + CI
Agcl = Ag’ +Cl
S $+0.1
Ky = [Ag] [CF] =Sx($+0.1)=018
Ky 17x10" 4
Ko_l7x10"_ > mmol/l
a, “O17 01 =1.7= 10" mol/L
vwelle [Ag’] = 1.7 x 10” mol/L, [CF] = (1.7 x 107) + 0.1 = 0.100 mol/L
SAR HCI az GefePECw AgCl MA K,, = (1.7 x 10°) x 0.10= 1.7 x 10"
PRGA FT AT AgC] OF AISA CHET TOIT SOs am woreTeT ae |
S ay oes vaaTyPa aCweT RT BAT :
> OFT
Lor
K cet
CEE
1, Salored SereaAtT etree wee Be Pefearta waatees fete wa [x.cr-aa]
B/S m Os TH aR ora Taare Cre MSUCAS CHE BeevaaA Hee fete wear | [z.cat-33]
© sna or,
_ [-2 aa,
Ln ny =2
\ m=3
Ry = 109678 cm!
‘Gar tref, =?
2 = 6.565 x 10° cm = 656.5 nm
®
[an owsw | sent Pa | Seer SF OH
Ae (n) ee | MTOM AMT | opsAtbe cearon Ret (m) ae | come | Seria] Berea
Ct) a 1 Feet | ROT
am | steer [wm | See a [saat acoT 7 (8)
0 | 3s 0 1
gh
2
| 1
3 jMorm | 1 | 3p +1,0,-1 3 (33) 6 18
29)
2
nv
&
aN
+2, +1,0,-1,-2 | 5D ate ong faces Bara aay FT a SOTA VF Ger ANS |
150 mL
103 moll -!
AICI; FT
wee
Atta
ss § TT Bracers BAST weer frrehet wee | [Rct-23]
AKOH); + 3NaCl
Asan 88, AIC === Al’ +3Cr
‘ona sift, eaten, Rea 4,
q AD’ 63 Tae, V, = 150 mL
aI, AD! ax ararat, S; = 107 mol L™ .
faterw qacta cad errs, V) = (150 + 100) mL = 250 mL
x 10 mol L! fafirs acy Al’ as wamTaT, S) = 7
B *iuma CREM, ~=NaOH == Na’ + OH
sre ori, aac, Freres 94,
ViSi , OH «a ere, V; = 100 mL
a, S- 100-10" OH «a erm, S;= 107 mol L™
een Safire aacra cad BITTER, V. = (150 + 100) mL
410° moll fafire geet OH ea WANT,
AKOH), AP + 30H
AKON), 94
kK, =[AI][OH |?
A Kip = (6 * 10) « (4 x 10°)
K, = 3.8410"!
RP Kiy > Ky SE AN OH); 4 SALTY GTS |DM 208 eTafbal eray eat:
&
> KCl at
BS 250 g ye OTS He
: i
1 Aaa
— erat (°C) —>
1. A AGRE BAICH 50°C STMT ces 25°C rr Heer Say FS aT KCI eas cers Re?
[crag]
S.A MGT AEICH B MNT BACT CU FATT AGC] PACT BATS SPH WD fer Sacas ace afer
[ae-33]
50°C Brera
oe, $= 60
Basa , M = 250 g
A (AAC) SA, m=?
i, 100m = 15000 ~ 60m
=, 160m = 15000
3.75 g
latent 4 = (M — m) = (250 ~ 93.75) = 156.25 g
‘STs ATeTST,
= mxto0 25°C orate
M-m arersi, $= 40
SAUTE ©, M - m= 156.25 g
4 (724) ©,
m=62.5g
coofaw ret = (93.75 - 62.5)g = 31.25 2
@ A gat BAAR AgC] Bett *B? TIT TES KCI BAT CAPT ALA AgC] OF ATOR MCT KCl @ AgCl
Ber a Ace act wa Tat STE (Commonion) C1Bsy BW) AgCl Ter wise face LeRE af
TMT oft STE eT eae ae efseMid sree Rare ere | KCI Se wise fey eeas Be
ate gars etary ori ey wee afer eeqa Se Fy BT
(i) AgCl = Ag’ +Cl (ii) KCL > K°+Cl
A BRO ARR AAT Bo AM FAT Cl SRY AWA KoA BATT Cl OF WANA CCH AT) SO, AT
mercer AS SPAT (ire Fafa APHITA PST MCS MS BA aR AgCl aa OTAAS Rou FAT Se
SRTSTRP A | AT STC rerea YS wfgs facsCRTa WHT MT URE fecNCMTA Sree ROMEPT TE) @
AAS CTE AH A ASIA ALA | OF GAYA AgC] OA FAT Kip > Kp BW SIR AgC] Aa ALOK ATH |D ae aos Fees Bara eas sa ae orerena Hise Bas AN |
fom: aed TaMIys Ww; Ry = 109678/cem
91, Biocon defy siteaes GUT Reree oat FET CHAT OTE FRAT / om ee ATA aTTCH flere
at [3.ca1-23]
a. Oars tralia eoraca fofe arcere afty cain wea aa? sTfefeeeres ACT HAT | [ce Ra]
© Serres TOT ee-08 [A.AT-Ra] MF Oecyrsa GT
© wegeTs yer efy-08 [F1.CaT-2a] oF Oaerarar WT
D ate ga3 eee Barat eras aa ae erecta fsa Best APs |
Mg(OH); €% Ky = 1 x 1077
91, Peoeas ONE BIATST were feehR sca | [aL.ceaa]
YR eae feeds seecer af8e Aart vifoeers fecwat FAT | [aera]
® A anaes At MgSO, a fecaree fafeeat Pres
MgSO, > Mg” + SO; ef, MgSO; S2 5RTST = S
sos os
Ky, = [Me” ][SO; } eam, S=6 «10 ‘M
a K,=S*S
a, Ky=S
*
K,,= (6 « 10 4) = 3.6 « 107 mol” L*
® MgSO, + KOH —>+ Mg(OH)> + K»SO,
frets 4,
P Tra ce, MgSO, ——+ Me” + SO;site ois, : Te,
ViSi = V2S2 Recs 4,
a, 5th Mg seaisiney, Vi > SOL,
2 i Mg” aa WaT, S, = 6 x 10M
a, 5, eee fae wacea GHD BITE, V2 = (60 + 50) mL = 110 mL
fae aect Mg” ais erat, S) =?
$= 3.27x 104M
Quam cron, KOH == K’+OH
oma wif, eer,
VS: = V2S2 frecra 4, :
a, 5)-US OH a winem, V, = 50 mL
» Saye &
onenes OH a TATE, S, = 0.05M
1, = Tg faferw qacea cab eIATER, V2 = (60 + 50) mL = 110 mL
*. $;=0.0227M fafeaecrOH ax WANT, S.=?2
Mg(OH); === Mg” + 20H”
') (0.0227)
Kip = 1.685 * 107
Mg(OH); 3% Ky = 1 «1077
BAR Kip > Koy | WER Mg(OH)2 4 BAO HA |
D ay gos Ree Baa eres Fa eR neces MiSs Ber ATS |
aia
25°C A AgNOs 6% Kup = 2.86 x 10°*
A MR Baa STATON AT Fehr eT [stata]
B.C oro Riaest i A ee cea BIRTeTA Creat oie a Fate sTPReSIE cata PAT | [a.T-88]
® «ff, AgNO; “4 @RTST = S mol L"
AgNO; === Ag’ + NO;
Sat 8)
Ky = [Ag"] [NO3]
a, Ky=SxS
a, Ky=S?
sore sx one (came) 3e(~)
$= VK =V2.86 x 10 = 1.69 x 10 mol L*"© «8 C ot AgNO, “4 AIaTST S,
NaNO; —> Na’ + NO}
AgNO; === Ag + NO};
S S,+0.1
Ky = [Ag"][ NOs] = $; « (S)+0.1)
a, Ky = 018;
s ao AgNOs 94 ARTS WHAT aH, $40.1 = 0.1
= 2.86 x 10°” mol/L
acumen 69 x 10°) - (2.86 x 107
ROR CeC moc Cou Erno
> ent age fcea Barat eras wer oe fcom efepererra BaR ANE |
.687 x 107 mol/L
mat XY
| asc 32°C
130 gm H,0 | Seer.) xy XZ
OTe rae ae
eee
REST , RR RET
XZ 64 Ky =4 x 10" mol?
[28°C eae 32°C Brera XY Aactioe HrayST WIECH 35 aR 45]
HS ATE APPS ATS FH oefsrarer HH HaS Ba CAM SATS ACA AAT VCAT | [pLcat-a9]
B. 0.01M XY Bat Ome BAC CUT SaT BT XZ Ga ATS CoAT afta aca fe? snes gfe ae |
[rara3]
100 m
© 28°C wea, S =
M-m
a 8, M-m= 130g
at SH, m=
a, 100 m= 35 x 130
m=
5 100m
CRE, S94
an 45 - 100m ae (1) eres, M— m= 130g
130 Fa SH, m=?
m=
FOE SATS ANAT HA CHM PaCS VA = (58.5 — 45.5) = 13.0© off, one 1am XZ ee aayeI = S
2X'+Z
ss
CHEM BIE,
Ky =4% 10"! mo? L?
a, S=V4x 107
» $= 6324 10 mol L
XY gett XZ. 0a wrayer = S,
XY xX +Y-
XZ—=— Xt ORT, X” RR A-SI |
(Si +001) S
Ky =[X] [Z]
I, Ka = (Si + 0.01) x Sy
7, Ky= 0.01 S) XZ oF BTS BS AT AHS, + 0.01 = 0.01
a, s= fe SA, Koy = 4 x 10"! mol? L?
4xio"
Si= —t =4* 10" mol Lt
ads, XY At XZ Oe ARTSAP MH = (S — S,) = {(6.324 « 10) - (4 * 107)} mol L™
= 632% 10° mol L!
()XY—+xX°+Y" (ii) XZ X+Z
OF AA X! STAT ANON | MSR X” oa MATTEL PH oT aR.(ii) ae ATTTSET OATS BAP TA |
ode XZ OF BSE an | AT waa Safefon arace cara aatd ArTeA ERTS ones frente
ARS STE SCT
D ort acs ficgs Cire ervey sa cee eos eterna Bae ATS |
Zn AgyCO3
AB OS
wate wat
3a tt ae oT
Zn(OH),, AMOH); 648 AgsCO, 44 Ky TART 3.0 * 1077, 3.0 « 10 wae 8.5 « 10 |
51, AR TE Ag” STA SRT fT aT | [p.ce-33]
MOF TCE BAT NHCI wt Sefefees NHOH GM sar ZA ae SEATS oe sehr ea?
ferrgreet Seat | [picar-as]
© «ff, Ag.CO; a3 ao
Ag:CO 2Ag + CO}
s