01 AJAS SourcesofVariabilityFull-Paper COALS-2018
01 AJAS SourcesofVariabilityFull-Paper COALS-2018
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Abstract
Albania is a country rich in freshwater resources, both surface and ground waters, but the water quality has
deteriorated significantly over the last several decades. The objective of this paper is to present a general
overview of the issues related to the surface and ground water quality in Albania and discuss about sources and
controlling processes. The sources of metal and organic contaminants are: i.) Many oil industry severely
contaminated, abandoned or operating sites; ii.) Cr, Ni and Cu mines, mainly in the north; and iii.) Old
processing factories. The sources that contribute to the high concentrations of N and P are: i.) A growing
number of fertilizer and pesticide storage facilities (ten of them are considered “hot spots” and significant
sources of N and P); ii.) Other identified point sources, industrial or urban; and iii.) Urban liquid and solid
waste; the vast majority of residential areas with more than 5,000 inhabitants have no wastewater treatment
plants, and the waste waters are directly discharged into rivers or the Adriatic and Ionian Seas. It is estimated
that these sources supply up to 20% of the N and P transported to water collection basins. Another important
contributing factor to pollution of waters in Albania is erosion. The erosion rate, varying from 1 to 30 t ha-1 yr-1,
is the highest in the southeast Europe. The high erosion rates are mainly due to the lack of soil vegetative cover
and poor natural resources management practices. Especially over the last two decades, the soil vegetative cover
has been removed due to massive uncontrolled deforestation, mainly the result of lack of enforcing forest
protection laws and policies. In addition, abandoned agricultural lands and overgrazed pastures at higher
elevations have rare vegetation and the agricultural land-use management practices are outdated. In conclusion,
we propose that systematic research efforts should be conducted to: i.) Document all sources of water
contamination and types of organic and inorganic contaminants; ii.) Quantify amounts and fluxes of
contaminants from sources to surface and ground waters; and, iii.) Determine the best research based remedial
strategies to remove contaminants from waters and decrease risks to humans and wild life. In addition, adequate
rigorous and continuous monitoring to determine potential risks to aquatic ecosystems should be established and
implemented throughout the Albanian territory. Monitoring plans for integrated transboundary waters should be
regularly updated and a comprehensive database on water pollution should be created and maintained.
Keywords: Water quality; water pollution; surface water; groundwater; Albania; erosion; erosion rate.
1. Introduction
Albania is a rich country in freshwater resources, but the quality of this water has deteriorated significantly
especially over the last several decades. The factors that have caused this deterioration are numerous and of
different nature. Probably, the most important one is that there have been significant social changes in Albania in
recent years, such as the change of the political regime from a one party communist system to a democratic
system, and the severe downturn in economy prior to the fall of communism. Other important natural and
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anthropogenic factors are climate, hydrology, vegetation coverage, land use, geology, and topographical
characteristics, which have contributed in different ways to the deterioration of the water quality in Albania.
In Albania, there are approximately 150 streams and rivers flowing from east to west, including relatively big
rivers such as Drini, Shkumbini, Devolli, Osumi, Semani, Vjosa, and Bistrica (Kabo, 1990) (Figure 1). The water
of the rivers is used in urban areas, agriculture, aquaculture, recreation, hydropower, and industry. The upper
reaches of major rivers flow through steep terrain contributing significantly to erosion in the eastern highland
areas and alluvium deposits in the western flat areas.
There are a number of deltas, lagoons and wetlands in western Albania, which are critical because of both their
tremendous biodiversity and their function as wildlife habitats. For this reason, the wetlands have both national
and international protection status. However, the transport of contaminants and colloids from the eastern part of
the country has deleteriously affected these transitional bodies of water at the interface of rivers and seas.
Pollution from mobile aqueous species of nitrogen (N) and phosphorus (P) is one of the most pressing
environmental issues associated with degrading of the water quality because it often results in eutrophication
(Viličić et al., 2010). Nitrogen and P are mostly associated with agricultural activities and are considered
nonpoint source pollutants. However, they can have impacts similar to those of other soluble substances
transported with colloid and sediment particles from point source pollutions, which are monitored in specific
areas and are relatively easy to manage.
Ammonium (NH4+), nitrite (NO2-), and nitrate (NO3-) are the main inorganic ionic species of N in aquatic systems
(Wetzel, 2001; Kopáèek et al., 2004; Rabalais, 2010). These inorganic N aqueous species are transported via
surface runoff and subsurface groundwater. In addition, dissolution of N-rich geological deposits, soil erosion,
and biological mineralization of organic matter contribute to increasing concentration of N aqueous species in
surface waters and groundwater.
Anthropogenic N and P can enter in ecosystems via point and nonpoint sources. Phosphorus is found in all soils
in different forms: soluble, adsorbed, precipitated, and organic (Frossard et al., 2000). The mechanisms involved
in soluble P transport include initial desorption or dissolution of P bound to soil particles, followed by transport
to streams or rivers (Haygarthand Jarvis, 1999). The inorganic P in surface waters is in the form of PO43-, HPO42-
and H2PO4- (Pierzinski et al., 2000).
Figure 1. Hydrologic map of Albania showing major rivers and permanent water monitoring stations
(represented by red squares and rectangles) (from Institute of Hydrometeorology, modified by Albanian
National Agency of Environment).
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Water quality in Albania: An overview of sources of contamination and controlling factors
Total concentrations of N > 50 mg NO3- N L-1 and P > 100 mg P L-1 may cause eutrophication. The main
anthropogenic sources of N and P are listed in Table 1 (Carpenter et al.,1998; Pierzinski et al., 2000; Howarth et
al., 2000; Smith, 2003;Galloway and Cowling, 2002).
As a candidate for the European Union (EU), Albania has redesigned the environmental protection laws. The
2011 environmental law and, especially, the standards for fresh waters are very similar to those of other EU
countries (Water Framework Directive 2000/60/EEC). The major goal is to attain the same water quality
indicators as EU by 2020 (Inter Sectorial Strategy for Environmental Protection, 2015-2020). However, major
challenges related to implementation and enforcement of the law still remain, and, unfortunately, water quality
issues do not currently constitute an emergency for the Albanian government.
Point sources
Liquid waste from cities near water flow (mainly rivers)
Waste water from livestock and farming (cattle, pigs, and chickens)
Industrial wastewater effluents
Runoff and infiltration from waste disposal sites
Runoff from operational mines, oilfields, and unsewered industrial sites
Overflow from combined storm and sanitary sewers
Nonpoint sources
Use of animal manure and inorganic N fertilizers and the subsequent runoff from agriculture
Runoff from burned forests and grasslands
Runoff from N-rich forests and grasslands
Urban runoff from unsewered and sewered areas
Septic leachate and runoff from failed septic systems
Runoff from construction sites and abandoned mines
N loadings to ground water and subsequently to receiving surface waters (rivers, lakes, estuaries, and coastal
zones)
Emissions into the atmosphere of reduced (from volatilization of manure and fertilizers) and oxidized (from
combustion of fossil fuels) N compounds and the subsequent atmospheric (wet and dry) deposition over
surface waters
Other activities that can mobilize nitrogen and phosphorus, such as wetland drainage
The objective of this paper is to present a general overview of surface and ground water quality in Albania and
analyze sources and related controlling processes. Specific objectives are to: (i) identify and assess contributions
of point and non-point sources to water pollution; (ii) determine the role of the transport of soluble and/or colloid
bound forms of contaminants (mainly macronutrients, such as N and P) in water pollution and quality; (iii) assess
the influence of macronutrients transported via streams and rivers on lagoon and coastal wetland ecosystems of
Albania; and (iv) identify adequate measures for the protection of these ecosystems.
2. General overview
2.1. Geology
Geology and parent material control to a considerable degree the physical and chemical properties of soils. The
adsorption and release of contaminants depend on the mineralogical composition of the parent material or rocks
from which the soil is formed. The geology of Albania is composed mainly of three rock formations: (i)
sedimentary rock in the south and western plains; (ii) conglomerates in central part of the country, and (iii)
magmatic rock in the east and north-east.
The major rock formations influencing the soil properties in the most important watersheds include: (i)
calcareous rock; (ii) ultra-basic and basic ophiolitic rocks (diabasic composition); (iii) flysch (including sand and
limestone); (iv) the Virgla Formation (limestone); and (v) sediment (“alluvions”).
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There are no geological formations rich in N in Albania. However, in the south, phosphate minerals originating
from sedimentary rocks have a relatively high P concentration (up to 11% P in the apatite mineral). In the north-
central part of Albania, which is dominated by magmatic rocks, there are large areas with geochemically high
levels of potential contaminants such as Cu (>2000 mg/kg soils), Cr (>5000 mg kg-1 soil), and Ni (>8000 mg kg-1
soil), which serve as sources for these contaminants.
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Water quality in Albania: An overview of sources of contamination and controlling factors
According to the National Soil Classification System (NSCS), which is based on soil-forming factors (climate,
vegetation, geology, topography/relief) and physical and chemical soil properties, soils are divided into four
broad vertical regions (Veshi and Spaho, 1988). According to the FAO classification, there are six major soils
types/orders: (i) Cambisols (30.6%); (ii) Luvisols (25.3%);(iii) Regosols (13.2%); (iv) Phaeozems (10.5%);(v)
Leptosols (8.8%), and in the western coastal areas, (vi) Fluvisols (5.5%) (SSI, 2002, Figure 3).
Figure 3. Major soil types of Albania (from Soil Science Institute, 2002).
The Soil Science Institute of Albania conducted an assessment in 1988 of the potential capability and suitability
classes of soils (based on soil fertility indicators such as macronutrients and soil organic carbon) and grouped
soils into 10 major classes. The presence of macronutrients in arable lands (Table 2) indicates that soils are
moderately rich in N (63% of the total surface layer) and P (67%) and rich in potassium (K). The arable lands are
dominated by loamy soils (50%), followed by clayey soils (30%) and sandy soils (20%).
Table 2. Concentration of humus, N, P, and K in arable soil (Soils Science Institute, 1988).
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Water quality in Albania: An overview of sources of contamination and controlling factors
m3 capita-1 year-1 (Stanners and Bourdeau, 1995). There are approximately 247 natural lakes throughout the
country, and most of them are karstic or glacial in origin andvery small (~1 ha).
2.6. Erosion
Soil colloids with substantial amounts of sorbed N, P, trace metals, and organic matter of different types, may be
transported to rivers, lakes and seas. Usually, the surface soil A and AB horizons, which are rich in
macronutrients and organic matter, are eroded the most. Erosion is influenced by several factors, such as climate,
rainfall intensity and distribution, geology, morphology, land cover, and slope characteristics (Wischmeier and
Smith, 1978; Nearing et al., 1999). The calculated slope length and LS factor derived from the NASA Shuttle
Radar Topographic Mission (SRTM) elevation data (Jarvis et al., 2008) is as high as 160, especially for the hills
and foothills, mountains foothills, and mountains physiographic regions (Figure 4).This indicates a high potential
for soil loss through erosion. The long-term evidence on erosion rates during the last two decades in Albania is
based on limited surveys and is sporadic and fragmented (MOEF, 2012-2014). Erosion data from other sources
for the Mediterranean regions are often incomplete and contradictory. The lack of vegetative cover is identified
as one of the major drivers for the higher erosion rates (Kosmas et al., 1997).
Figure 4. Universal Soil Loss Equation (USLE) LS factor for Albania calculated based on SRTM elevation
data (Grazhdani and Shumka 2007).
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The erosion rates in Albania are expected to be much higher than in other European countries due to the higher
degree of deforestation, overgrazing, high-intensity use of biomass, and cultivation of steeply sloping areas. The
reported erosion rates in different studies conducted in Albania are inconsistent. On one hand, according to the
study by Grazhdani and Shumka (2007), the average erosion rate is greater than 10 t ha-1 y-1; in some areas in
south, the rate can reach 100 t ha-1y-1. On the other hand, as stated in the monitoring reports of the Albanian
Ministry of the Environment (MOEF, 2010-2012), the erosion rate in Albania varies from 3.6 t ha-1 y-1in pastures
to 18.3 t ha-1y-1in corn cultivated areas (AKM report, 2012). These rates are similar to those reported by Cerdan et
al.(2010), which were determined in experiments conducted in 81 sites (a total of 2741 plots) located in 19
European countries. It should be emphasized, however, that in areas prone to high erosion, as described by
Grazhdani and Shumka (2007), there was no vegetative cover for10 to 20% of the time during the year and the
intensity of rainfall was twice as high as that in the central part of the country.
Earlier studies have estimated the nutrient losses due to erosion in Albania to 100,000 t y-1 for N, 60,000 t y-1 for
P and 16,000 ty-1 for K (Kovaci et al., 1996). Other authors (Gjoka and Cara,1996) estimated that annual losses
are approximately 70,000 ty-1, 40,000 ty-1, and 6,400 ty-1 for N, P, and K, respectively. In a more recent study,
Binaj et al., (2014), found that the N and P losses were respectively around 40 000 and 24 000 tons. Although the
data provided by Binaj et al. (2014) were significantly smaller than those presented in previous studies, they also
stated that erosion is the main factor of soil degradation which contributes to the removal of substantial amounts
of plant macronutrients. Practically, 90% of the N added into arable lands with fertilizers is used to replace N
losses from erosion, whereas the amounts of P added with fertilizers are much lower than the losses through
erosion.
amount of P leached from irrigated soils, mainly sandy soils, is reported to be approximately 2-3 kg ha-1
(Erickson et al., 2005; Sinaj et al., 2002), whereas it does not exceed 1 kg ha-1in soils with lower sand content
(Aronsson et al.,2011; Sinaj et al.,2002). Recent ongoing lysimeter studies in two Albanian soils with different
sand contents under irrigation showed P leaching of less than 0.1 kg ha-1year-1 (Rroço, 2016, personal
communication), demonstrating again low P mobility.
The release of P from soils to surface waters is controlled by a variety of factors, such as soil properties, crop
type, management practices, surface runoff, erosion, and preferential flow in the subsurface (McDowell et al.,
2001). In areas with soils that have been degraded as a result of significant erosion and/or poor management
practices, P removal via runoff is significant. Studies in Albania have shown that the <2m size fraction
separated from soils was the main sink of water-soluble P (as phosphate), and the P released and transported into
surrounding rivers and lakes increased significantly when soil aggregates became unstable (Sinaj et al., 1997).
The most common method of calculating the losses of nutrients via erosion is based on the amount of the soil
particles transported with surface waters and the average contents of nutrients in these particles; however, this
method provides only estimates of nutrient losses, which may or may not be accurate (Joneset al., 2003).
According to the World Bank estimates (WB, 2007) approximately 350,000 ha, or close to 60% of the
agricultural land in Albania are subject to significant erosion, with a loss of soil estimated at approximately 25
million t y-1. Studies conducted in recent years, have demonstrated that the annual amount of soil and nutrient
loss from the most important watersheds in Albania are considerable and highly variable (Table 3). Pano (2008)
reported that the rivers of Albania deposit, on average, approximately 53.2 × 106 t y-1into the sea.
Table 3.Hydrographic data (Kabo, 1990–91), average solids and nutrient values of the principal Albanian
rivers (AKM, 2010-2011; Abazi [Ishmi River], 2014 Malltezi and Sulce [Mati River], 2013-2014; Pano, 2008;
Cullaj et al., 2005).
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downstream flows are cleaner. Meanwhile, the Devolli, Erzeni, and Ishmi Rivers flow, in large part, through
sandy soils that are easily erodible contributing to the poor water quality of these rivers.
Figure 5. The watershed most impacted by direct wastewater discharge (from Abazi, 2003).
In general, streams in agricultural areas are polluted predominantly by nonpoint sources of nutrients (Carpenter et
al., 1998). In urban areas, in particular, point sources of pollution, such as municipal and industrial wastewaters,
contribute significant nutrient loads (Haggard et al., 2005).
Table 4 provides estimates of N and P concentrations in the main rivers in Albania, based on the average N and P
concentrations in wastewaters, (Tchobanoglous et al., 2003). In the central part of the country, the Ishmi River
watershed includes the City of Tirana and its suburbs wiith a population of approximately 1 million inhabitants,
which is the major contributor to N and P pollution, with 876 and 153 tons per year, respectively. These data are
also suggested by previous surveys. According to Abazi (2003), for example, the point sources generally account
for 80% of nutrient inputs to the Ishmi River in central Albania, where population density is higher. The point
sources account for 10%, 15%, and 23% of N and P inputs in other rivers such as Buna, Semani, and Shkumbini.
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The contribution of nonpoint and point sources varies according to the size of the watershed, population, and
agricultural activities. Not well documented point source pollution areas are also very important in Albania due to
the fact that housing units have been illegally built in agricultural lands. Official municipality data indicate that
approximately 480,000 private housing units have been built outside urban or rural areas. Because these units
have no or failing septic systems, they all serve as important sources of N and P. Their contributions, however,
remain unquantified or unaccounted for. In a study conducted in Devolli River, samples were taken before and
after the irrigation season at three different points of the river to assess the impact of a population of almost
22,000 and that of the agricultural activities conducted at the area (Beqaj et al., 2015). The results indicated a
clear increase in the N and P concentrations in the river water as it flowed through the populated area clearly
demonstrating the deteriorating impact of human activity although the concentrations of both N and P were still
low enough that the water could be used for irrigation (Beqaj et al., 2015).
Table 4. The average total concentrations of N and P of the typical composition of untreated domestic waste
water and respective inhabitants for each watershed that discharges waste water directly into a river.
* The values are the typical composition of untreated wastewater in Wastewater Engineering: Treatment and Reuse,
Metcalf & Eddy, Inc., 4th ed., revised by George Tchobanoglous et al., 2003)
PA
Figure 6. The most important lagoons and lakes of Albania (from Shallari, 2013)
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Figure 7. Topographic wetness index showing high values for the wet areas to the west, where the majority of
wetlands and lagoons are located.
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Water quality in Albania: An overview of sources of contamination and controlling factors
The data included in Table 5 shows that the four lagoons that were subject of recent studies have soluble N and P
at levels that are moderate and comparable with other Mediterranean lagoons. The status of the Butrint and Narta
Lagoons is mainly oligotrophic most of the year, and that of the Patok and Narta Lagoons is transitory.
Lagoons, together with wetlands, are part of coastal areas and important for the economy and tourism industry.
They serve as a buffer zone between the sea and the agricultural areas. One of the most important, although
“invisible,” functions of lagoons and wetlands is the biological filtering of nutrients and heavy metal overloads
through the vegetation.
Table 5. Data on nutrients, chlorophyll and trophic states for transitional waters.
Transitional Protection Surface Dissolved N Dissolved P Chlorophyll Status based References
waters (km2) (mol l-1) (mol l-1) (gram dm-3) on N and P
concentration
Sulce and
3.51±2.7 0.055±0.04 1.8±0.47 Mostly
Butrinti a 16.0 Bani (2011)
(n=14) oligotrophic
Bino et al.
3.3±4.5 0.06±0.084 2.38±5.62 Mesotrophic-
Narta c 29.90 (2004),
oligotrophic
(n=7) Cako et al.
(2014)
Oligotrophic Babani et
4.8±6.6 0,079±0.03 0.33±0.35
Karavasta a 43.3 – mesotrophic al. (2012)
(n=9)
Avdolli
Mostly (2012),
Patok b, c 7.10 2.4 ± 7.7 0.043±0.09 2.1 -9.6
mesotrophic KociKalfa
(n=18)
et al.
(2014)
Koci Kalfa
Kune Vain b, c 11.45 6.4±2.2 0.088±0.06 4.3±3.6 Mostly et al.
Lagoons (n=12) 2 mesotrophic- (2014),
Kokali
(2014)
The protection actions are classified as a = Ramsar site; b = Nature 2000 site; c = Local protection plans
(classification by Barbone et al., 2012).
The protection status of the lagoons is based on their international, national, or local importance. For example,
the Butrinti and Karavasta Lagoons have the highest status (category “a” or Ramsar site), while the Patok and
Narta Lagoons have a lower status. The status is also related to the pressure exercised on the lagoons and their
surroundings by different natural and anthropogenic factors. The overall pressure varies according to the different
functions and activities of a lagoon (Table 6).
Table 6. The pressure evaluation on the list of the transitional water ecosystems considered. The intensity of
every pressure type was evaluated using a scale of values ranging from 0 to 4 (0 = absent; 1 = very low; 2 =
low; 3 = moderate; and 4 = high) according to an expert evaluation based on existing knowledge as reported in
a TW Reference Net report. A = organic load; B = nutrient load; C = hazard substances; D = fishing; E = alien
species; F = navigation; G = physical modification; H = average pressure; Ia = net pressure. The data and
evaluation in this table are from Barbone et al. (2012), except for the data and evaluation of the Butrinti and
Kune Vain Lagoons.
Lagoons Pressures References
A B C D E F G H Ia
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4. Conclusions
Surface waters in Albania are heavily influenced by N and P through nonpoint and point source pollution.
Rivers transport considerable amounts of macronutrients that impact water quality. The Semani, Shkumbini,
and Ishem Rivers are the most polluted with macronutrients and are classified as category IV or V. These
rivers flow through the central regions of Albania, where agricultural activities and untreated waste water
from urban areas increase considerably the concentration of macronutrients and the microbial activity.
Similar patterns of deterioration of the chemical, physical, and biological properties of the waters lagoons and
on the seashore are also observed. Their waters show a clear tendency toward degradation, and their
functions are restricted due to direct human pressure. The lagoons considered in this study are characterized
as having:(i) oligotrophic water quality and low human pressure (Butrinti Lagoon); (ii) oligotrophic-
mesotrophic water quality and medium human pressure (Karavasta Lagoon);(iii) mesotrophic-oligotrophic
water quality and high human pressure (Narta Lagoon); and (iv) mostly mesotrophic water quality and very
high human pressure (Patok and Kune-Vain Lagoons). The lagoons with high human pressure risk the
deterioration of their trophic status. In addition, the quality of coastal waters is deteriorated, especially in
estuaries and in the waters connected with lagoons.
In Albania, the amount of N and P transported through rivers to the sea is very high. Apart from serious
economic loss, erosion causes pollution of surface and transitional waters and, in particular, affects the
quality of surface water and drinking water by leading to reduced filtration or purification.
The soil erosion rates in Albania are much higher than other countries in the region. There are two main
causes for these high rates: (i) lack of a vegetative cover and (ii) inappropriate natural resource management
practices. In the last two decades, vegetation in Albania has decreased drastically because of massive
deforestation, the result of lack of targeted policies and protection from illegal logging.
Vegetation is highly degraded on abandoned land, while most pastures are overgrazed. Agricultural practices
are outdated and associated with the misuse of natural resources, particularlywater and soil. They have
resulted in groundwater pollution, especially with N.
Pollution from identified sources, industrial or urban, contributes to the degradation of water quality in rivers
and lagoons. These pollution sources comprise up to 20% of the contribution of N and P to water collection
basins. For the vast majority of residential areas with more than 5,000 inhabitants, there are no wastewater
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treatment plants and wastewater is disposed directly into rivers or the sea. A lack of investment and
inappropriate policies have resulted in serious pollution problems and increased threats to all water bodies,
transitional waters, and coastal waters, including those with protective status.
Short - and mid-term investments need to be focused on building wastewater treatment plants in urban
centers with populations greater than 10,000, especially those near coastal areas and major rivers. In addition,
watershed management plans and best management agricultural practices are some short-term measurements
that could reduce the negative impacts on water quality.
A national monitoring network should be established, and adequate monitoring plans that identify pollutant
sources and quantitative transport of contaminants in aquatic ecosystems should be enacted. Monitoring plans
for integrated transboundary water, which are compiled pursuant to bilateral or multilateral agreements,
should be funded to establish a solid database for water pollution.
5. Acknowledgements
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