Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 28-12-2024
Time: 09:00AM to 12:00PM WTM-23 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point
Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on
the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.#
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:

Candidate’s Signature:________________ Invigilator’s Signature: ________________

 Sri Chaitanya IIT Academy, India 28-12-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-23_Q.P
28-12-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-23_Test Syllabus

MATHEMATICS : Application of Derivative : Angle between the two curves, Orthogonal

Curves , Rate Measure,Error & Approximation ,,, Interval of Monotonocity ,
Application of Monotonicity, Concavity of the curve, Jensen's Inequality ,
Stationary Points, Critical Points , Local Maxima and Local minima using
first order derivative,Maxima and minima using second order derivative ,,,
Global maxima and global minima, Maxima and minima using AM-GM
relation , Applications of maxima and minima in solving equations ,
Physical problems on maxima and minima (applications) ,,, miscellaneous
problems.
PHYSICS : Wave Motion: Introduction, Waves on Water Surface, Waves on Strings,
Transverse Wave Motion,Longitudinal Wave Motion(Definition only),
Terms Connected With Wave Motion, Relation Between Wave Speed,
Frequency and Wave Length, Characteristics of Wave Motion, Equation of
Plane Progressive Wave: Displacement Relation in a Progressive Wave,
Phase & Phase Difference, The Speed of Travelling Wave, Speed of
Transverse Waves on a Stretched String, Miscellaneous Problems
CHEMISTRY : General mechanism of EAS, directive influence of functional group in
mono substituted benzene , Eletrophilic aromatic substitution, mechanism of
halogenations,nitration, sulphonation, nitrosation, alkylation and acylation

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 Sri Chaitanya IIT Academy, India 28-12-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-23_Q.P
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The function f  x   x  log  x  is increasing when x belongs to the interval
1 x 
1) 1,   2)  2,   3)  3,   4)  , 1   0,  

2. The function g : R     ,   be given by g  x    2cot 1  5 x  may be :

2 2  2
1) even function and strictly increasing in  2, 5 
2) even function and strictly decreasing in  2, 5 
3) odd function and strictly decreasing in  2,5 
4) odd function and strictly increasing in  2,5
3. The function defined by f  x    x  2  e  x is
1) decreasing for all x 2) decreasing in  , 1 and increasing in  1,  
3) increasing for all x 4) decreasing in  1,   and increasing in  , 1
x x
4. If f  x   and g  x   , where 0  x  1. then in this interval
sin x tan x
1) both f  x  and g  x  are increasing functions
2) both f  x  and g  x  are decreasing functions
3) f  x  is an increasing function
4) g  x  is an increasing function
5. The volume of the greatest cylinder which can be inscribed in a cone height 30 cm and
semi vertical angle 30 0 is
4000 3 400 4000 3 400 3
1) cm 2) cm3 3) cm 4) cm
3 3 3 3
6. Let f  x   x4  14 x2  24 x  k
statement-I: the number of integral values of k for which the equation f  x   0 has four
real and unequal roots 2
statement-II: the least negative integral value of k for which the equation f  x   0 has 2
distinct real roots 116
1) Both statement-I and statement-II are true
2) Both statement-I and statement-II are false
3) Statement-I is true but Statement-II is false
4) Statement-I is false but Statement-II is true
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7.  
If f " x   0 and f ' 1  0 such that g  x   f cot 2 x  2cot x  2 , where 0  x  
then the interval in which g  x  is decreasing is
   3   3 
1)  0,  2)  ,   3)  ,   4)  0, 
2   4   4 
2
8 Let f :  0,1  R be the function defined as f  x    4 x   x  1   x  1  ([.]=g.i.f) then
 4  2
the minimum value of f  x  is
1 1 1
1)  2)  3) 0 4)
512 432 432
f  x 
1/ x

9 The polynomial function f  x  of degree 6 which satisfy lim 1  3   e2 and has
x0
 x 

maxima at x  1 and minima at x  0 and 2. if a, b, c be the coefficients for the

polynomial function of three highest power of ‘ x ’ in the f  x  b  a  c 
statement-I: the value of 3a  5b  8c  6
statement-II: the value of 15 f 1  4
1) Both statement-I and statement-II are false
2) Statement-I is false but Statement-II is true
3) Statement-I is true but Statement-II is false
4) Both statement-I and statement-II are true
10. Match the following :
COLUMN-I COLUMN-II
I) The function f ( x)  ( x  1) 2  ( x  2) 2  ( x  3) 2 P) 0
has a minimum for x 
II) The least value of the function Q) 2
f ( x )  2(3)3 x  32 x.4  2.3x in [ 1,1] is
III) 4 R) 8
Let f ( x )  x3  4 x, 0  x  2, then the global
3 27
minimum value of the function is
IV) Let f ( x)  6  12 x  9 x 2  2 x 3 , x  [1,4] then S) 8

Absolute maximum value of f ( x) is 3
A) I-Q, II-P, III-S, IV-Q B) I-R, II-S, III-Q, IV-P
C) I-S, II-R, III-Q, IV-P D) I-R, II-Q, III-S, IV-P

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11.
 
 
f :  0,   A, f  x   log e  sin x   1 , then the minimum value of f  x  is
 2
sin x

  1 1/ e   1
1) log e 2 2) log e     1 3) log e  ee   4) 2
 e    2
 
12. The point on the curve y  x 2  4 x  3 which is closest to the line y  3x  2 is

1 5  1 5  5  5
1)  ,  2)   ,  3)  2,   4)  2, 
2 4  2 4  3  3
13 A rectangle with one side lying along the x-axis is to be inscribed in the closed region of
the xy-plane bounded by lines y  0, y  3 x and y  30  2 x . if ‘ m ’ is the largest area of
2m
such a rectangle then value of is
27
1) 4 2) 2 3) 3 4) 5
 p2  1  3
14. If f  x    2  x  3 x  log 2 is decreasing function of x in r. then set of possible
 p 1
values of p (independent of x ) is
1)  1,1 2) 1,  3)  , 1 4)  0, 
15. Let f , g and h be real-valued functions defined on the interval  0,1 by

f  x   e x  e x , g  x   xe x  e x and h  x   x 2e x  e x . if a, b and c denote

2 2 2 2 2 2

respectively, the absolute maximum of f , g and h on  0,1 , then

1) a  b and c  b 2) a  c and a  b
3) a  b and c  b 4) a  b  c
 1
16. Let Q  x   f  x   f 1  x  and f " x   0 for 0  x  1 . then, on  0, 
 2
1) Q  x  is increasing 2) Q  x  is decreasing
3) Q  x  is constant 4) Q  x  is not increasing
17. The function f  x   x3  4 x2  4 x  3 defined on [-1,3] has
1) minimum value -6 at x=-1 2) minimum value 6 at x=3
3) minimum value 3 at x=2 4) maximum value 9 at x=3
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18. An approximate value of 18 is 4

1) 2.0512 2) 2.0425 3) 2.0625 4) 2.0834

19.  
If the function f  x   x3  3  a  7  x 2  3 a 2  9 x  1 has a positive point of

maximum then
 11 
1) a   ,3  1,4  2) a   , 3   2, 
 2
 28   29 
3) a   ,3   7,  4) a   , 3    3, 
 3   7 
20. The maximum possible area that can be enclosed by a wire of length 20 cm by bending it
into the form of a sector of a circle, is
1) 10 2) 25 3) 30 4) none

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
n n
 x  y 
21. The slope of the tangent of the curve       2 at (31,1209) is K then K 
 31   1209 
22. A water tank has the shape of a right circular cone with axis vertical and vertex
3
downwards. it semi-vertical angle is tan 1 . water is poured in it at a constant rate of 6
4
cubic meter per hour. the cube of the rate (in square meter per hour), at which the wet
curved surface area of the tank is increasing, when the depth of water in the tank is 4
meters, is ___.
23 The radius of the base of a cone is increasing at the rate of 3 cm/minute and the altitude is
decreasing at the rate of 4cm/minute. the rate of change of lateral surface area when the
radius = 7 cm and altitude 24 cm is 6k , then the value of ‘ k ’ = ___
24. The greatest value of x3 y 4 if 2 x  3 y  7 and x  0, y  0 , is g, then the value of 3g =
25. The volume of a spherical balloon is increasing at the rate of 2cm 3 / sec. when its radius is
4cm,the rate of change of its surface area  in cm2 / sec is

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 Sri Chaitanya IIT Academy, India 28-12-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-23_Q.P
PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. Transverse waves are generated in two uniform wires a and b of the same material by
attaching their free ends to a vibrating source of frequency 200 hz. the cross-section of a
is half that of b while the tension on a is twice that on b. the ratio of wavelengths of the
transverse waves in a and b is
1) 1 : 2 2) 2 : 1 3) 1 : 2 4) 2 : 1
2
27. The equation y = a sin (vt – x) is expression for

1) stationary wave of single frequency along x-axis
2) a simple harmonic motion
3) a progressive wave of single frequency along x-axis
4) the resultant of two shm’s of slightly different frequencies.
A simple harmonic wave is represented by the equation y ( x, t )  a 0 sin 2 vt   .
x
28.
 

if the maximum particle velocity is three times the wave velocity, the wavelength
 of the wave is
a 0 2a 0 a0
1) 2) 3) a 0 4)
3 3 2
29. A transverse wave is travelling along a string from left to right. the figure below
represents the shape of string at a given instant. A, B, C, D, E, F, G and H are points on
the string at this instant. which of the above points have upward velocity?
C
B D
A H
E
F
G
1) D,E, F 2) A, B, H 3) C and G 4) A, E and H
30. A simple harmonic wave has the equation y = 0.3 sin (314 t – 1.57 x), where t, x and y are
in seconds, metres and cm respectively. find the frequency and wavelength of the wave.
1) 100 Hz, 4m 2) 50 Hz, 8m 3) 50 Hz, 4m 4) 100 Hz, 8m
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31. Given below are some functions of x and t to represent the displacement of an elatic wave
Column – I Column - II
a) y  5cos(4 x)sin(20t ) p) a travelling wave long +x direction
b) y  4sin(5x  t / 2)  3cos(5x  t / 2) q) not a travelling wave
c) y  cos[250 t ] r) S.H.M
d) y  100cos(100 t  0.5 x) s) a travelling wave along -x direction
given reasons for your answers
1) a-p, b-q, c-r, d-s 2) a-q, b-p, c-s, d-r 3) a-p, b-q, c-s, d-r 4) a-q, b-p, c-r, d-s
32. A uniform rope having mass m hangs vertically from a rigid support. A transverse wave
pulse is produced at the lower end. The speed (v) of wave pulse varies with height (h)
from the lower end as

1) 2) 3) 4)
1
33. The amplitude of wave disturbance propagating in positive x-axis is given by y 
1  x2
1
at t = 0 and y  at t  2s. Where x and y are in metres. The shape of the
1  ( x  1) 2
disturbance does not change during the propagation. The velocity of the wave is
1) 1ms 1 2) 0.5ms 1 3) 2ms 1 4) 4ms 1
34. In a plane progressive harmonic wave particle max speed is always less than the wave
speed if (  is wavelength)
 
1) amplitude of wave is less than 2) amplitude of wave is greater than
2 2

3) amplitude of wave is less than  4) amplitude of wave is greater than

35. A transverse wave is travelling along a string from left to right. the figure below
represents the shape of string at a given instant. A, B, C, D, E, F, G and H are points on
the string at this instant. Which points have the maximum magnitude of velocity ?
C
B D
A H
E
F
G
1) D,E, F 2) A, B, H 3) C and G 4) A, E and H
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36. Transverse waves of wavelength  travelling in a medium with a speed of v m/s enter
into another medium where its speed is 2v m/s. wavelength of sound waves in the second
medium is

1)  2) 3) 2 4) v
2
37. Statement –I : Mechanical waves does not require medium for propagation
Statement – II : Wave is a carrier of energy and momentum
1) statement-I & statement-II both are correct
2) statement-I is true & statement-II is false
3) statement-I is false & statement-II is true
4) statement-I & statement-II both are false
38. With propagation of longitudinal waves through a medium, the quantity transmitted is
1) matter 2) energy
3) energy and matter 4) energy, matter and momentum
39. Which of the following statements are true for wave motion?
1) mechanical transverse waves can propagate through all mediums.
2) longitudinal waves can propagate through solids only.
3) mechanical transverse waves can propagate through solids only.
4) longitudinal waves can propagate through vacuum.
40. A string of mass 2.5 kg is under a tension of 200 N. the length of the stretched string is
20.0 m. if the transverse jerk is struck at one end of the string, the disturbance will reach
the other end in
1) one second 2) 0.5 second 3) 2 seconds 4) data given is insufficient.
41. A transverse harmonic wave on a string is described by y( x, t )  3.0sin (36t  0.018x   / 4)
where x and y are in cm and t is in s. the positive direction of x is from left to right then
find correct alternative
1) the wave is travelling from right to left 2) the speed of the wave is 20 m/s
3) frequency of the wave is 5.7 hz 4) all the above are true
42. Assertion : Wave velocity in a stretched string does not depend on frequency of source
particle
Reason : Propagation of mechanical wave is due to elastic property of the medium
1) both A and R are correct and R is the correct explanation of A
2) both A and R are correct but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is not correct
43. During propagation of a plane progressive mechanical wave
1) amplitude of all the particles is equal.
2) particles of the medium executes s.h.m.
3) wave velocity depends upon the nature of the medium
4) all above are correct
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 Sri Chaitanya IIT Academy, India 28-12-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-23_Q.P
44. A simple harmonic wave has the equation y = 0.3 sin (314 t – 1.57 x), where t, x and y are
in seconds, metres and cm respectively. Find phase difference between the two particles
5
situated at x1  2 and x2  ?
2
1) 45°C 2) 90°C 3)30°C 4) 60°C
45. A simple harmonic progressive wave has equation y  0.10sin(314t  1.57 x  1.57) . If y, x, t
1
are in cm, m, s respectively. Then find velocity of the particle at x  and at t  1 ?
2
31.4 31.4 31.4 1.57
1) m/s 2) m/s 3) cm / s 4) cm / s
2 2 2 2
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
46 The displacement of an elastic wave is given by the function y  3sin t  4cos t where y
is in cm and t is in second. calculate the resultant amplitude in cm.
47. A sitar wire is replaced by another wire of same length and material but of three times the
1
earlier radius. if the tension in the wire remains the same, then new wave velocity is
x
times the initial wave velocity. Then find x ?
48. A steel wire has a length of 12 m and a mass of 2.10 kg. what will be the speed of a
transverse wave on this wire when a tension of 2.06 104 N is applied? (round off to
nearest integer)
49. For the harmonic travelling wave y  2cos 2 (10t  0.0080 x  3.5) where x and y are in cm
and t is in seconds. What is the acceleration amplitude (in m / s 2 ) of the particle at x  1m ?
( 2  10)
50. In the given progressive wave y  5sin(100 t  0.4 x) where y and x are in m, t is in s. what
is the ratio of maximum acceleration to maximum velocity of particle situated at x  3 ?
(take   3.14 )

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 Sri Chaitanya IIT Academy, India 28-12-2024_Jr.Super60_STERLING BT_Jee-Main_WTM-23_Q.P
CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

51.

1) 2) 3) 4)
52. Write the product of the following reaction

1) 2) 3) 4)

53.
The predominant product is

1) 2) 3) 4)
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54. Ring nitration of dimethyl benzene results in the formation of only one nitro dimethyl
benzene. The dimethyl benzene is

1) 2) 3) 4)

55.

1) 2) 3) 4)

56.
The decreasing order of electrophillic aromatic substitution is
1) X > Z > Y 2) Y > Z > X 3) Z > Y > X 4) Z > X > Y
57. The major product of the following reaction is

1) 2) 3) 4)
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58. Incorrect statement regarding Friedel-Crafts alkyation reaction is
1) when CH 3 Br / AlBr3 is used for alkylation of benzene, the electrophile involved is free
methyl carbocation
2) As alkyl groups are activating in nature. Friedel-Crafts reaction leads to poly
alkylation
3) when Me3CCH 2Cl / FeCl3 is used for alkylation of benzene, unrearranged product is
formed almost exclusively
4) low temperature facilitate unrearranged product
59. The decreasing order of reactivity towards electrophillic substitution reaction of
following compounds
A) Benzene B) bromobenzene C) nitrobenzene D) toluene is
1) A> C >D >B 2) D >A > C >B 3) D >A >B >C 4) D >B >A >C
60. In chlorobenzene, the Cl group :
1) Activates the benzene ring more, via resonance effect than deactivating it via inductive
effect
2) Deactivates the benzene ring more, via inductive effect than activating it via resonance
effect
3) Activates the benzene ring via resonance effect and deactivates it via inductive effect
both these effect are evenly matched
4) it is net deactivating group with director characteristics
61. Benzene can be obtained by
CuO
1) C6 H 5OH  NaOH 

 2) C6 H 5OH  Zn 



3) C6 H 5  N  N  Cl  H 2O  4) All of these
62. Which one of the following aromatic compounds fails to undergo Fridel-crafts reactions?
1) C6 H 5  CH 3 2) C6 D6 3) C6 H 5  NO2 4) C6 H 5Cl

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63.

1) 2)

3) 4)

64. Compound C will be

1) 2)

3) 4)
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65.

1) 2)

3) 4)

66. Assertion : Nitration of benzene with nitric acid is required, concentrated sulphuric acid
Reason : The mixture of Conc. H 2 SO4 produces the nitronium [ NO2 ] electrophile
1) both A and R are correct and R is the correct explanation of A
2) both A and R are correct but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is not correct
67. Assertion : Toulene on friedel crafts methylation gives ortho and para xylene.
Reason : CH 3 group bonded to benzene ring increases electron density at ortho and para
postion.
1) both A and R are correct and R is the correct explanation of A
2) both A and R are correct but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is not correct
68. Assertion : NO2 group is benzene ring deactivating and meta directing group.
Reason : NO2 group withdraws electron density from benzene ring and makes ortho and
para positions more electron deficient than meta position.
1) both A and R are correct and R is the correct explanation of A
2) both A and R are correct but R is not the correct explanation of A
3) A is correct but R is not correct
4) A is not correct but R is not correct
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69. Number of coplanar atoms present in the structure of toluene
1) 10 2) 14 3) 12 4) 13
Re d hot
70. But  2  yne  x ( aromatic )
Fe  tube

Number of methyl groups present on the structure of x is

1) 4 2) 2 3) 6 4) 3
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. The number of compounds which do not undergo Friedel-Crafts acylation is

72. From which position does NO2 replace a hydrogen from the following compound
predominantly ?

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73. What is the number of compounds having a benzene nucleus which can have the
molecular formula C7 H 8O ?
74. Identify number of substituents those are deactivating but Ortho and para directing

75. Examine the structural formulas shown below and find out how many compounds
undergo electrophillic nitration more rapidly than flouro benzene.

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