CHEMISTRY Max.

Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.

19 For the given complexes the correct statement is/are

[Mo(CO)3 (PF)3], [Mo(CO)3(PCl3) 3], [Mo(CO)3(PMe3) ],
(A) [Mo(CO)3 (PFe3) 3] has max bond length of CO bond
(B) [Mo(CO)3 (PMe3)3] has max bond length of CO bond
(C) [Mo(CO)3 (PMe3)3] has minimum  -character in M-C bond
(D) [Mo(CO) 3 (PF3) 3] has max bond order of CO bond

20. Which of the following is/are CORRECT statements?

(A) Ore bauxite is purified by alkaline treatment in the Baeyer process and then dissolved in
molten cryolite and reduced electrolytically in the fused salt system to get metal
(B) Sulphide ore of some of the less electropositive metals like Hg, Cu, Pb etc. are heated in air, a
part of these is changed into oxide or sulphate then that reacts with the remaining part of the
sulphide ore to give its metal and SO
Metallic gold is dissolved from its ore in dilute NaCN solution in presence of air and the
solution so obtained is treated with scrap zinc when gold metal is precipitated
(D) Magnesium is precipitated as Mg(OH)2 from sea water by treatment with lime and then it
dissolved in dilute HCl and reduced electrolytically in aqueous medium to get magnesium metal
21. Which of the following will give negative Kjeldahl and Lassaigne test for Nitrogen.
(A) Aniline (B) Hydrazine
(C) Benzenediazonium chloride (D) Dimethyl ethanamine
22. Incorrect option among the following is/are
(A) Nucleophilicity order ⇒ PhSΘ > CH3Θ > IΘ > EtOΘ
O O
|| ||
(B) Acidic strength order ⇒ CH3CO2H>H2CO3> CH 3  C  CH 2  C  CH 3  CMe3OH

(C) Basic strength order ⇒

  
(D) Stability order : C Cl3  C F3  C H 3  CMe3
23. d H 2O  1 g / ml; d C2 H5OH  0.92 g / ml
540 ml of H 2O is mixed with 500 ml of C2 H 5OH to form an ideal solution. Consider solute present
to be non-volatile and non-electrolyte ( K b  H 2O   0.54 K kg mole 1 ;
K b  C2 H 5OH   1.2 K kg mole 1 )

Page. No. 10
 Boiling point of water = 373 K;
Vapour pressure of H 2O = 35 mm Hg
Vapour pressure of C2 H 5OH = 40 mm Hg

(A) Boiling point of above solution is = 383 K

(B) If 500 ml C2 H 5OH is further added to above solution then the boiling point elevation of new
solution is 36 K
(C) Initial vapour pressure of solution 26.25 mm Hg
(D) Initial vapour pressure of solution 8.75 mm Hg

24. Which of the following statement is/are CORRECT ?

(A) Higher is the gold number of a lyophilic sol. more is its coagulating power
(B) An electrolyte can coagulate both positive sol and negative sol
(C) Impurities present in a colloid makes it more stable
(D) Dialysis is a process to remove impurities of ions and smaller molecules from a colloid
25. The nucleus of an atom is located at x = y = z = 0. If the probability of finding an 's' orbital electron in
a tiny volume around x = a, y = z = 0 is 1.0 × 10-5. Choose the correct statement(s) regarding the
probability of finding electron.
(A) The probability of finding the electron in the same-sized volume around x = z = 0, y = a is the
same i.e., 1 × 10-5
(B) The probability of finding the electron in the same-sized volume around x = y = 0, z = a is zero
(C) The probability of finding the electron at x = y = z = 0 is zero.
(D) The probability of finding the electron at x = 2a, y = z = 0 must be greater than 1.0 × 10-5.
26. Ca3 P2  H 2O  A   B

Which of the following statements is/are correct regarding A and B?

(A) Gas 'A' is passed into CuSO4 solution and black ppt. is obtained

(B) CO2 is passed into excess of 'B' and clear solution is obtained
(C) When "A" is pure burns in air spontaneously
(D) 'A' is slightly soluble in water

Page. No. 11
 SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
27 Aqueous urea solution is hydrolysed according to the reaction
 NH 2 2 CO( aq )  H 2O(l )  2 NH 3( aq.)  CO2( aq.)
the standard enthalpy of formation and entropies at 300 K for reactants and products are

CO2(aq .) H 2O( l ) NH 3(aq .)  NH 2 2 CO(aq.)

H 0  kJ / mole   412.9  285.8  80.8  317.7

S o  JK –1mole –1  121.0 69.9 110.0 176.0

Find value of lnK of above reaction at 300 K.

28. 2.24 g of a mixture having impure Fe2  SO4 3 sample and pure FeC2O4 was dissolved in dil. H 2 SO4 .

N
the complete oxidation of reaction mixture requires 100 ml 20 KMnO4 solution. After the oxidation

the reaction mixture was reduced completely into Fe +2 by Zn and dil. H 2 SO4 . This reduced solution

requires 200 ml of same KMnO4 solution. Then find percentage purity of Fe2  SO4 3 sample. [Fe =

56]

The decomposition of A B follows the rate equation r  K  A2 B2  .

2
29.

A2B2 → A2 + B2. The kinetic data of the reaction is given below.

If the initial concentration of A2B2 were 56 m mol/lit, Calculate the time (in sec) taken for the
t
conversion of A2B2 to reach 60% of initial value. (Report your answer as )
1000
30. Reagents which can convert CH3–CHO into carboxylic acid/salt :
(i) [Ag(NH3)2]OH (ii) CH3–CO3H (iii) NaOI (iv) DIBAL – H

(v) Cu/300°C (vi) K2Cr2O7/H+ (vii)

Page. No. 12
  
31. Calculate the isoelectric point (pI) of lysine. Give the pKa of   N H3 is 8.95, pKa side chain N H 3 is
10.53 and pK a of   COOH is 2.18
32. Find sum of the number of B–O–B bonds in
2– –
(i)  B4O5  OH 4  (ii)  B5O6  OH 4 

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.33 and Q.34 by appropriately matching the lists based on the information
given in the paragraph.
Answer the following by appropriately matching the lists based on the information given in the paragraph.

List – I List – II
(I) (P)
3
(II)
(R) R – CH = CHR

(III) (S)

(T)

(U)

33. Incorrect Match:

(A) (I)  (T) (B) (II)  (R) (C) (III)  (S) (D) (IV)  (P)
34. Correct Match:
(A) (I)  (R) (B) (II)  (Q) (C) (III)  (S) (D) (IV) → (P)

Answer Q.35 and Q.36 by appropriately matching the lists based on the information
given in the paragraph.
Answer the following by appropriately matching the lists based on the information given in the paragraph.
List – I List -II
(I) K 4  Fe  CN 6  (P) Produces deep blue solution with CuSO4 solution

(II)  NH 4  S (Q) Produces deep blue PPT with FeSO4 solution

2

Page. No. 13
 (III) NH 4 OH  excess  (R) Produces deep blue PPT with FeCl3 solution
(IV) NaOH  excess  (S) Produces colourless solution or white PPT with ZnSO4
solution
(T) Produces chocolate brown PPT with CuSO4 solution
(U) Produces reddish brown precipitate with FeCl3

35. Which of the following is incorrect match?

(A) I  R (B) I  S (C) I  Q (D) I  T
36. Which of the following is correct match?
(A) IV  S,U (B) III  P,S,U (C) II  S (D) All of the above

MATHEMATICS Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
37. There are three distinct points A(2,0) ; B and C such that OB = OC = 2. Consider the triangle T
formed by the point A,B and C. Let there are exactly m such triangles T that are equilateral and there
are exactly n such triangles T that are right angled isosceles. Then 2m + n is
A) divisible by 2 B) Composite number C) prime number D) divisible by 5
1
 x
f f  x   3 ; x  R and h  t    f  t  dx; t  0 then which of the following is/are true
x
38.
1

h t  2 h  t  2
A) lim  B) lim 
t 0 t ln 3 t 0 t ln 3

h t  h t  2
C) lim does not exist D) lim 
t 0 t t 0 t ln 3
1
39. Let g : R  R be a continuous function such that g  x  1  g  x  for all x  R and let
3
n
 n   g  x dx for all integer n  1. Then lim  n
n 
0

1 1
3 3
A) Exist B) Does not exist C) is equal to  g  x  dx D) not equal to  g  x  dx
20 20

t1   sin 1 x  ; t2   sin 1 x  ; t3   cos 1 x  ; t4   cos 1 x 

sin 1 x cos1 x sin 1 x cos 1 x
40. . Where sgn(x) represents

signum function. Then which of the following statement is/are correct.

A)If x   0, cos1 then sgn  t4  t2  t3  t1   1

Page. No. 14
 5500 + 4500 = 104 N
17&18.

σ1 A1 + σ2 A2 = – (σ3 A1 + σ4 A2)
σ1 A1 + σ2 A2 = (σ5 A1 + σ6 A2)
__________________________
2(σ1A1+ σ2A2) = (σ5 – σ3)A1 + (σ6 – σ4)A2
1     3     4 
 E1 , 2  E 2 , 5  E, 6 E
0 0 2 0 2 0
2A1E1 ∈0 + 2A2E2∈2 = 2∈0EA1 + 2∈0EA2
A1E1 + A2E2 = E(A1 + A2) ....(1)
E1d1 = E2d2 ....(2)

E1  Ed
 A1  A  
100  2 1  2 

200  3
 150
A1d 2  A 2 d1 

E 2  Ed1
 A1  A 2   75
 A1d 2  A 2d1 
E1 + E2 = 225
E1 – E2 = 75
CHEMISTRY
PART-2 : CHEMISTRY SECTION-I (i)
19. Ans (B,D)
The electron pair back donated by metal goes into antibonding MO of carbon monoxide,
thus decreases the bond order and increases the bond length. The π-acceptor tendency of
ligands are in order PF3 > PCl3 > PMe3.
20. Ans (A,B,C)
Magnesium metal can't be extracted from aqueous solution.
23 Ans (A,C)
10
Tb  0.54   1000  10
540
30
PS  Po X H2O  35   26.25
40
27. Ans (-0.18 to -0.19)
H 0reaction = 29.0kJ
S0reaction = 95.1JK 1
G 0reaction = H o  T So
= 29000 – 300 × 95.1
= 470 J
G o
In K =  0.188
RT
28 Ans (83.33)
1
No. of m mol. of FeC2O4  100   5m mol.
20
5
The solution now has  2 y mol of Fe+3 Which will convert to Fe+2
3
5
  2 y  10
3
Mass of Fe2(SO4)3
25 5000 5
= × 400 = mg = g
6 3 3
Mass of FeC2O4 = 0.24 g
5/3
  100 
2
29. Ans (120.00)
For rate to reach 36%
A t = 0.6 Å

1 1 1
t=  o
 o 
k  0.6 A A 
1 2 
t=  o
k  3A 
1
k=
1440  7
2 1 
 t = 1440×7   3 
 3 56  10 
t = 120×103 sec
32. Ans (11.00)
33. Ans (B)

(I)

(II) 
PPh 3
reduction
 R – CH = CH – R + Ph3P = O

(III)

(IV)

36. Ans (D)

Fe +3 
K 4 [Fe(CN)6 ]
 Fe4 [Fe (CN) ] 
Blue 6

Zn 
+2
 K 2 Zn 3[Fe (CN)6 ] 
K 4 [Fe(CN)6 ]

White

Cu 2 
K 4 [Fe(CN)6 ]
 Cu2 [Fe(CN)6 ] 
Choclate brown

FeSO 4 
 K 2 Fe[Fe(CN) ] 
K 4 [Fe(CN)6 ]

White ppt 6

MATHS