Chemistry For NEET By Prince Sir

LEVEL-1
INTRODUCTION 8. When a gas is compressed
adiabatically and reversibly, the
1. Thermodynamics is concerned with :-
final temperature is-
(1) Total energy of a system
( 1) H ig h er t ha n t he in it ia l
(2) Energy changes in a system temperature
(3) Rate of a chemical change (2) Lower than the initial
(4) Mass changes in nuclear reactions temperature
2. A well stoppered thermos flask contains (3) The same as initial temperature
some ice cubes. This is an example of (4) Dependent upon the rate of
:– [AIIMS–92] compression
(1) Closed system 9. Which one is a state function :-
(2) Open system (1) Heat supplied at constant
pressure
(3) Isolated system
(4) Non-thermodynamic system (2) Heat supplied at constant volume

3. Identify the intensive quantity from (3) Enthalpy

the following - (4) All of the above

(1) Enthalpy and temperature[ I I T – 9 3 ] 10 . Out of boiling point (I), entropy

(II), pH (III) and emf of a cell
(2) Volume and temperature
(IV), intensive properties are :
(3) Enthalpy and volume
(4) Temperature and refractive index (1) I, III, IV (2) I, II
4. Which of the following is an extensive
(3) I, II, III (4) All of these
property
11 . The work done by a weightless piston
(1) Mass (2) Enthalpy in causing an expansion  V (at
(3) Energy (4) All of these constant temperature), when the
5. For an adiabatic process which of the opposing pressure P is variable, is
following relations is correct given by :
[CPMT–90]

(1) E = 0 (2) PV = 0

(1) W = – z PV (2) W = 0

(3) q = 0 (4) q = + W
(3) W = – PV (4) None
 dE  12 . The work done by 100 calorie of
6. For an ideal gas, the value of  
 dV  T heat in isothermal expansion of
is : ideal gas is :-
(1) 418.4 J (2) 4.184 J
(1) Positive (2) Zero
(3) Negative (4) Interchangeable
(3) 41.84 J (4) None
7. In which of the following process work
13 . Temperature and heat are not :-
behaves as state function :
(1) Isothermal (1) Extensive properties
(2) Intensive properties
(2) Isochoric
(3) Intensive and extensive
(3) Adiabatic
properties respectively
(4) Isobaric
(4) Extensive and intensive
properties respectively

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 Chemistry For NEET By Prince Sir
14 . One mole of a gas absorbs 200J of (1) – 200 Joul (2) 400 Joul
h e at a t co n s t an t v ol u m e . I t s (3) 720 Joul (4) 120 Joul
temperature rises from 298 K to 308
21 A system has internal energy equal to
K. The change in internal energy is
E1, 450 J of heat is taken out of it
:-
and 600 J of work is done on it. The
(1) 200 J (2) –200 J final energy of the system will be -
(1) (E1 + 150) (2) (E1 + 1050)
308 298
(3) 200 × (4) 200 × J (3) (E1 – 150) (4) None of these
298 308
22 . The work done by a system is 8J when
15 . q = –w is not true for :-
40J heat is supplied to it. The change
(1) Isothermal process in internal energy of the system during
(2) Adiabatic process the process :
(3) Cyclic process (4) 1 and 3 both (1) 32 J (2) 40 J
16 . The temperature of an ideal gas (3) 48 J (4) –32 J
increase in an -
23 . If a gas absorbs 100 J of heat and expands
(1) Adiabatic compression by 500cm3 against a constant pressure of
(2) Adiabatic expansion
2 × 10 5 Nm -2 , the change in internal
(3) Isothermal expansion energy is:-
(4) Isothermal compression
(1) - 300 J (2) - 100 J
17 . Enthalpy of 1 mole monoatomic ideal
gas is equals to :– (3) + 100 J (4) None of these
24 . Identify the 'State function' among the
3 5
(1) RT (2) RT following:-
2 2
(1) q (2) q × W
(3) RT (4) 2 RT (3) q/W (4) q + W
18 . Which statement is true for reversible
ENTHALPY [H = E + PV/H= E + ng
process :–
RT ]
(1) It takes place in single step
25 . Internal energy change during a
(2) Driving force is much greater reversible is othermal expansion of an
than opposing force ideal gas is :-

(3) Work obtain is minimum (1) Always negative

(2) Always positive
(4) None (3) Zero
FIRST LAW OF THERMODYNAMICS (4) May be positive or negative
(E = q + W) 26 . Under which of the following conditions
19 . Both q & w are_ _ _ _ _ function & is the relation, H = E + PV valid
q + w is a _ _ _ _ _ function :- for a system :–

(1) State, State (2) State, path (1) Constant pressure

(3) Path, state (4) Path, path (2) Constant temperature

20 . If work done by the system is 300 (3) Constant temperature and pressure
joule when 100 cal. heat is supplied
to it. The change in internal energy (4) Constant temperature, pressure and
during the process is :- composition

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Chemistry For NEET By Prince Sir
27 . The difference between heats of reaction 34 . For CaCO 3(s) CaO(s) + CO 2(g)
at constant pressure and constant volume at 977°C, H = 174 KJ/mol ; then
for the reaction 2C6H6(l) + 15O2(g)  E is :-
12CO2(g) + 6 H2O(l) at 250C in KJ is (1) 160 KJ (2) 163.6 KJ
[IIT-1991]

(1) + 7.43 (2) +3.72 (3) 186.4 KJ (4) 180 KJ

(3) – 7.43 (4) – 3.72 35 . Heat of reaction for , CO(g) + ½
O2(g) CO2(g) at constant V is –
28 . For a gaseous reaction,
67.71 K cal at 17°C. The heat of
A(g) + 3B(g) 3C(g) + 3D(g) reaction at constant P at 17°C is
E is 17 Kcal at 270C assuming R = 2 cal K– (1) –68.0 K cal
1
mol–1, the value of H for the above (2) + 68.0 K cal
reaction is:
(3) – 67.42 K cal
(1) 15.8 Kcal (2) 18.2 Kcal
(4) None
(3) 20.0 Kcal (4) 16.4 Kcal 36 . The reaction :-
29 . Which of the following statements is
correct for the reaction ;CO(g) + ½ O2(g) 3
NH 2CN(S) + O (g)  N 2(g) +
2 2
 CO2(g) at constant temperature and
pressure [AIIMS–83] CO2(g) + H2O()

(1) H = E (2) H < E wa s car ri ed ou t in a bo mb

caloriemeter. The heat released
(3) H > E (4) None of the above
was 743 KJ mol–1. The value of
30 . For the reaction Ag2O(s)  2Ag(s) + ½ H300k for this reaction would be
O2(g), which one of the following is true
(1) – 740.5 KJ mol–1
:
(2) – 741.75 KJ mol–1
(1) H = E (2) H = ½ E
(3) – 743.0 KJ mol–1
(3) H < E (4) H > E (4) – 744.25 KJ mol–1
31 . A mixture of 2 moles of carbon monoxide
37 . The enthalpy of vaporisation of
and one mole of oxygen in a closed vessel
water at 1000C is 40.63 KJ mol–1.
is ignited to get carbon dioxide. If H
The value E for this process
is the enthalpy change and E is the
would be:-
change in internal energy, then :–
(1) 37.53 KJ mol–1
[KCET–88]
(2) 39.08 KJ mol–1
(1) H > E (2) H < E
(3) 42.19 KJ mol–1
(3) H = E (4) Not definite
(4) 43.73 KJ mol–1
32 . For the gaseous reaction involving the
38 . The difference in H and E for
complete combustion of isobutane -
the combustion of methane at 250C
(1) E (2) E would be:-
(3) E = 0 (4) E (1) Zero
33 . For the reversible isothermal expansion (2) 2 × 298 × - 2 cals
of one mole of an ideal gas at 300 K,
(3) 2 × 298 × - 3 cals
from a volume of 10 dm3 to 20 dm3, H is
(4) 2 × 25 × - 3 cals
-
39 . For the system
(1) 1.73 KJ (2) –1.73 KJ
S(s) + O2(g) SO2(g) :–
(3) 3.46 KJ (4) Zero
(1) H = E (2) H > E

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 Chemistry For NEET By Prince Sir
(3) E > H (4) H = 0 46 . For a reaction 2X(s) + 2Y(s)  2Cl)
+ D(g)
1
40 . For the reaction CO (g) + O (g)  The qp at 27°C is – 28 K Cal. mol–1.
2 2
The qV is ----------- K. Cal. mol–1
CO2 (g) :–
Which one of the statement is correct (1) – 27.4 (2) + 27.4
at constant T and P ?
(1) H = E (2) H < E (3) – 28.6 (4) 28.6
(3) H > E
WORK DONE IN DIFFERENT PROCESS
(4) H is Independent of physical state
of reactants 47 . Th e w ork do ne in er gs for a
reversible expansion of one mole of
41 . Which is true for the combustion of
an ideal gas from a volume of
sucrose (C12H22O11) at 25°C :-
10 litres to 20 litres at 250C is :
(1) H > E (2) H < E
(1) –2.303 × 8.31 × 107 × 298 log2
(3) H = E (4) None
42 . For which change H E :- (2) –2.303 × 0.0821 × 298 log2
(1) H2(g) + I2(g) ‡ˆ ˆ†
ˆˆ 2HI(g (3) –2.303 × 0.0821 × 298 log 0.5
(2) HCl () + NaOH () NaCl (s) +
H2O () (4) –2.303 × 2 × 298 log2
(3) C(s) + O2(g) CO2(g) 48 . Two litre of N2 at 0°C and 5 atm are
(4) N2(g) + 3H2(g)  2NH3(g) expanded isothermally against a
constant external pressure of 1 atm
43 . The heat of combustion of ethanol
until the pressure of gas reaches 1
determined in a bomb calorimeter is –
atm. Assuming the gas to be ideal
670.48 K. Cals mole–1 at 25°C. What is
calculate work of expansion ?
H at 25°C for the reaction :–
(1) –504.2 joule (2) –405.2 joule
(1) – 335.24 K. Cals.
(2) – 671.08 K. Cals. (3) +810.4 joule (4) –810.4 joule
(3) – 670.48 K Cals. 49 . Two moles of an ideal gas expand
(4) + 670.48 K. Cals. spontaneouly into vacuum. The work
done is :–
44 . The difference in H and E for the
combustion of methane at 25°C would (1) Zero (2) 2 J
be :– (3) 4 J (4) 8 J
(1) Zero (2) 2  298  – 2 50 . One mole of a gas occupying 3dm3
Cals. expands against a constant external
(3) 2  298  – 3 Cals.(4) 2  25  – pressure of 1 atm to a volume of 13
3 Cals. lit. The workdone is :–
45 . For which of the following reactions (1) – 10 atm dm3 (2) – 20 atm dm3
H is less than E :–
(1) C12H22O11(s) + 6O2(g)  6CO2(g) (3) – 39 atm dm3 (4) – 48 atm dm3
+ 6H2O (l)
ENTROPY/SECOND LAW OF THERMODYNAMICS
(2) 2SO2(g) + O2(g)  2SO3(g)
51 . F o r w h i c h r e a c t i o n f r o m t h e
(3) N2O4(g)  2NO2(g)
following, S will be maximum ?
(1) Ca(s) + ½ O2(g)  CaO(s)
(4) N2(g) + O2(g)  2NO(g)
(2) CaCO3(s)  CaO(s) + CO2(g)
(3) C(s) + O2(g)  CO2 (g)
(4) N2(g) + O2(g)  2NO(g)

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Chemistry For NEET By Prince Sir
52 . An adiabatic reversible process is one 60 . When two gases are mixed the entropy
in which :- :–
(1) Temperature of the system does (1) Remains constant (2) Decreases
not change
(2) The system is not closed to heat (3) Increases (4) Becomes zero
transfer
61 . The enthalpy of vaporization for
(3) There is no entropy change
water is 186.5 KJ mol–1, the entropy
(4) None of these of its vaporization will be-
53 . Entropy means [AFMS–94] [CPMT–88]
(1) Disorderness (2) Randomness (1) 0.5KJK –1mol –1 (2) 1KJK –1mole –1
(3) Orderness (4) both 1 & 2 (3) 1.5KJK –1mole –1 (4) 2KJK –1mole –1
54 . S for the reaction; 62 . The enthalpy of vaporisation of per
MgCO3(s)  MgO(s) + CO2(g) will be mole of ethanol (b.p. = 79.50C and S
(1) 0 (2) –ve (3) +ve (4)  = 109.8 JK–1 mol–1) is :–
55 . Change in entropy is negative for (1) 27.35 KJ/mol
[AIIMS–89] (2) 32.19 KJ/mol
(1) Bromine ()  Bromine (g) (3) 38.70 KJ/mol
(2) C(s) + H2O(g)  CO(g) + H2(g) (4) 42.37 KJ/mol
(3) N2(g, 10 atm)  N2 (g, 1 atm) 63 . If 900J/g of heat is exchanged at boiling
point of water, then what is increase
(4) Fe(at 400 K)  Fe(at 300 K) in entropy? [BHU–98]

56 . In which reaction S is positive :- (1) 43.4 J/K-mole

(1) H2O () H2O (s) (2) 87.2 J/K mole

(2) 3O2 (g) 2O3 (g) (3) 900 J/K-mole

(3) H2O () H2O (g) (4) Zero

(4) N2(g) + 3H2(g) 2NH3 (g) 64 . Calculate enthalpy of vapourization

per mole of ethanol. Given S = 109.8
57 . When the egg is hard boiled, there JK–1 mol–1 and B.pt. of ethanol is
is- 78.5 0 C.
(1) Increase in disorder(2) Decrease
H vap
in disorder (1) S vap  (2) 38.594 KJ mol–
T
(3) No change in disorder (4) G is 1
negative
(3) 3.85 KJ mol–1
58 . If S 0 for H 2, Cl 2 and HCl are 0.13,
(4) Some more data is required
0.22 and 0.19 KJ K –1 m o l – 1
65 . 5 mole of an ideal gas expand reversibly
respectively. The total change in
from a volume of 8 dm3 to 80dm3 at a
standard entropy for the reaction
temperature of 270C. The change in
H2 + Cl2  2HCl is :
entropy is :–
(1) 30 JK–1 mol–1 (2) 40 JK–1 mol–1 (1) 41.57 JK–1 (2) – 95.73 JK–1
(3) 95.73 JK–1 (4) – 41.57 JK–1
(3) 60 JK–1 mol–1 (4) 20 JK–1 mol–1 66 . In a spontaneous irreversible process
59 . Which has the least entropy : the total entropy of the system and
(1) Graphite (2) Diamond surroundings
(3) N2(g) (4) N2O(g) (1) Remains constant (2) Increases
(3) Decreases (4) Zero

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 Chemistry For NEET By Prince Sir
67 . The total entropy change for a system & 74 . For a reaction at 25 0C enthalpy
its surroundings increases if the change (H) and entropy change (S)
process is : are –11.7 × 103 Jmol–1 and –105 J
[PET (MP)93] mol–1 K–1 respectively. The reaction
(1) Reversible (2) Irreversible is :
(3) Exothermic (4) Endothermic (1) Spontaneous
68 . Calculate the entropy of Br2(g) in the (2) Non spontaneous
reaction H2(g) + Br2(g)  2HBr(g), S° (3) At equilibrium
=20.1JK–1 given, entropy of H2 and HBr is (4) Can't say anything
130.6 and 198.5
75 . The spontaneous nature of a reaction
J mol –1 K –1 :-
is impossible if :
(1) 246.3 JK–1 (2) 123.15 JK–1
(1) H is +ve, S is also +ve
(3) 24.63 JK–1 (4) 20 KJK–1 [AIIMS–80]
69 . Ammonium chloride when dissolved in water (2) H is – ve; S is also – ve
leads to cooling sensation. The
(3) H is –ve ; S is +ve
dissolution of NH 4 Cl at constant
temperature is accompanied by :–
(4) H is +ve; S is –ve
(1) Increase in entropy
76 . At a certain temperature T, the
(2) Decrease in entropy
endothermic reaction A B proceeds
(3) No change in entropy almost to completion. The entropy
(4) No change in enthalpy change is :
70 . In which of the following case entropy (1) S = 0
decreases–
(2) S < 0
(1) Solid changing to liquid (2)
(3) S > 0
Expansion of a gas (3) Crystals dissolve
(4) Polymerisation (4) Cannot be predicted

71 . Which of the following state function 77 . If H > 0 and S > 0, the reaction
is not zero at standard state :– proceeds spontaneously when :-
(1) Enthalpy (2) Entropy (1) H > 0 (2) H < T S
(3) Free energy (4) None
72 . Entropy of an adiabatic reversible (3) H = TS (4) None
process is:-
78 . The temperature at which the reaction
(1) Positive (2) Zero
(3) Negative (4) Constant Ag2O(s)  2Ag(s) + ½ O2(g)

GIBBS FREE ENERGY is at equilibrium is ........;

73 . A gas is allowed to expand under Given H = 30.5 KJ mol–1

reversible adiabatic conditions what is and S = 0.066 KJK–1 mol–1 :
zero for such a process:-
(1) 462.12 K (2) 362.12 k
(1) G = 0 (2) T = 0
(3) S = 0 (4) None of these
(3) 262.12 k (4) 562.12k

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Chemistry For NEET By Prince Sir
79 . The enthalpy change for a given
reaction at 298 K is –x cal/mol. If (3) G < 0 (4) None of these
the reaction occurs spontaneously at
85 . What is the free energy change G, when
298 K, the entropy change at that
1.0 mole of water at 100ºC and 1 atm
temperature
pressure is converted into steam at
(1)Can be negative but numerically
100°C and 1 atm pressure :–
larger than x/298 cal K–1 mol–1
[MP PMT–1998]

(2)Can be negative but numerically (1) 540 Cal (2) –9800 Cal
smaller than x/298 cal K–1 mol–1 (3) 9800 Cal (4) 0 Cal
(3)Cannot be negative 86 . A reaction A + B C + D + q is found
to have a positive entropy change, the
(4) Cannot be positive
reaction will be -
80 . Which of the following is true for
(1) Possible at high temperature
the reaction H2O() H2O(g) at
(2) Possible only at low temperature
1000C and 1 atmosphere
(3) Not possible at any temperature
(1) S = 0 (2) H = 0
(3) H = E (4) H = TS (4) Possible at any temperature
87 . Equilibrium constant of a reaction is
81 . For the reaction Ag2O(s) 2Ag(s) + ½ related to :
O2(g) the value of H = 30.56 KJ mol –1
(1) Standard free energy change G0
and S=66 JK–1 mol–1. The temperature [AIIMS–91]
at which the free energy change for (2) Free energy change G
the reaction will be zero is :–
(3) Entropy change
(1) 373 K (2) 413 K (4) None
88 . The Vant Hoff equation is :
(3) 463 K (4) 493 K
(1) G° = RT loge KP
82 . For hypothetical reversible reaction
(2) –G° = RT logeKP
3
½ A2(g) + 2 B2 (g) AB3(g); H =
nKP
2
(3) G° = RT
–20 KJ if standard entropies of A2, (4) None
B2 and AB3 are 60, 40 and 50 JK–1
89 . If G0 > 0 for a reaction then :
mole –1 respectively. The above
(1) KP > 1
reaction will be in equilibrium at
(2) KP < 1
:–
(3) The products predominate in the
(1) 400 K (2) 500 K equilibrium mixture
(3) 250 K (4) 200 K (4) None
83 . For the precipitation of AgCl by Ag+ 90 . If the equilibrium constant for a
ions and HCl reaction is 10, then the value of G0
will be
(1) H = 0 (2) G = 0
(R = 8JK–1 mol–1, T = 300 K)
(3) G = –ve (4) H = G (1) + 5.527 KJ mol–1
84 . What is the sign of G for the process (2) – 5.527 KJ mol–1
of ice melting at 283 K ? (3) +55.27 KJ mol–1
(1) G > 0 (2) G = 0 (4) – 55.27 KJ mol–1

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 Chemistry For NEET By Prince Sir
91 . When the value of entropy is greater JOULE THOMSON EFFECT
then the ability for work is : 97 . The Joule-Thomson expansion of a gas
(1) Maximum is an
(2) Minimum
(1) Isothermal process
(3) Medium
(4) None of these (2) Isochoric process
92 . The process of evaporation of a liquid (3) Isoenthalpic process
is accompanied by : (4) Isobaric process
(1) Increase in enthalpy 98 . In case of an ideal gas, Joule Thomson
(2) Decrease in free energy coefficient is -
(3) Increase in entropy
(1) Zero (2) Positive
(4) All
(3) Negative (4) Infinite
93 . For the process, CO2(s) CO2(g) :
99 . Above the inversion temperature,(J.T.
(1) Both H and S are +ve
coefficient)
(2) H is negative and S is +ve
(3) H is +ve and S is –ve (1) Is positive (2) Is zero

(4) Both H and S are –ve (3) Is negative (4) Depends on the
gas
94 . Which of the following provide
e x c e p t i o n s t o t h i r d l a w o f 10 0. The inversion temperature for vander
thermodynamics Waal's gas is
(1) CO (2) ice (1) Ti= 2a/Rb
(2) Ti = a / Rb
(3) CO2 (4) All the above
(3) Ti = a/2Rb
95 . The Gibbs free energy change of a
(4) Ti = 0.5 T Boyle
reaction at 27°C is –26 Kcal. and its
entropy change is – 60 Cals/K. H for
the reaction is :–
(1) – 44 K. Cals. (2) – 18 K. Cals.

(3) 34 K. Cals. (4) – 24 K. Cals.

96 . Which of the following reaction is
expected never to be spontaneous :–
(1) 2O3  3O2
H = – Ve, S = + Ve

(2)Mg + H2  MgH2
H = – Ve, S = – Ve

(3)Br2(I)  Br2(g)
H = + Ve, S = + Ve

(4)2Ag + 3N2  2AgN3

H = + Ve, S = – Ve

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Chemistry For NEET By Prince Sir

LEVEL-1

Qu e. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
An s. 2 3 4 4 3 2 3 1 4 1 1 1 4 1 2
Qu e. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
An s. 1 2 4 3 4 1 1 4 4 3 1 3 2 2 4
Qu e. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
An s. 2 2 4 2 1 2 1 2 1 2 3 4 2 2 2
Qu e. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
An s. 3 1 4 1 1 2 3 4 3 4 3 1 1 2 3
Qu e. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
An s. 1 3 1 2 3 2 2 1 1 4 2 4 3 2 4
Qu e. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
An s. 3 2 1 2 4 3 2 3 3 4 4 1 2 2 2
Qu e. 91 92 93 94 95 96 97 98 99 100
An s. 2 4 1 4 1 4 3 1 3 1

30 E
 Chemistry For NEET By Prince Sir
LEVEL–2(A)
1. The absolute enthalpy of neutralisation of the 7. For the reaction of one mole of zinc dust with one
reaction for MgO(s) : [AIPMT–2005] mole of sulphuric acid in a bomb calorimeter, U
MgO(s) + 2HCl(aq) Mg Cl2 (aq) + H2O () and w correspond to :– [AIIMS–2005]

will be : (1) U < 0, w=0 (2) U < 0, w < 0

(3) U > 0, w=0 (4) U > 0, w > 0
(1) 57.33 kj mol–1
8. When you make ice cubes, the entropy of water
(2) – 57.33 kj mol–1
[AIIMS–2006]
(3) Greater than –57.33 kj mol–1 (1) Does not change
(4) Less than –57.33 kj mol–1 (2) Increases
2. Which of the following pairs of a chemical reaction (3) Decreases
is certain to result in a spontaneous reaction.? (4) May either increase or decrease depending on
[AIPMT–2005] the process used
(1) endothermic and decreasing disorder 9. For a phase change H2O() ‡ˆ ˆˆ0ˆˆCˆˆ1 bar
ˆˆ ˆ†
ˆˆ H2O(s)
(2) exothermic and increasing disorder
[AIIMS–2006]
(3) endothermic and increasing disorder
(1) G = 0 (2) S = 0
(4) exothermic and decreasing disorder
(3) H = 0 (4) U = 0
3. Identify the correct statement for change of Gibbs
10. For a spontaneous process the correct statement
energy for a system (Gsystem) at constant
is– [AIIMS–2006]
temperature and pressure. [AIPMT–2006]
(1) Entropy of the system always increase
(1) If Gsystem > 0, the process is spontaneous. (2) Free energy of the system always increases
(2) If Gsystem = 0, the system has attained equilibrium. (3) Total entropy change is always negative
(4) Total entropy change is always positive
(3) If Gsystem = 0, the system is still moving in a 11. The enthalpy change (H) for the reaction,
particular direction. N2(g) + 3H2(g) 2NH3(g) is –92·38 kJ at 298 K.
The internal energy change U at 298 K is
(4) If Gsystem < 0, the process is not spontaneous.
[AIIMS–2006]
4. Assume each reaction is carried out in an open (1) –92·38 kJ (2) –87·42 kJ
container. For which reaction will H = E ? (3) –97·34 kJ (4) –89·9 kJ
(1) H2 (g) + Br2 (g)2 HBr (g) [AIPMT–2006] 12. Consider the following reactions : [AIPMT–2007]
(2) C (s) + 2 H2O (g) 2 H2 (g) + CO2 (g) (a) H+(aq)+OH–(aq)=H2O(l), H=–X1kJ mol–1

(3) PCl5 (g)  PCl3 (g) + Cl2 (g) 1

(b) H2(g)+ O2(g)=H2O(l) , H=–X2kJ mol–1
(4) 2 CO (g) + O2 (g)  2 CO2 (g) 2
5. The enthalpy and entropy change for reaction (c) CO2(g) + H2(g) = CO(g)+H2O(l) – X3kJ mol–1
Br2 () + Cl2 (g) 2 BrCl (g) are 30 kJ mol–1 and
5
105 JK–1 mol–1 respectively. The temperature at (d) C2H2(g)+ O2(g)=2CO2(g)+H2O(l)+X4kJ mol–1
2
which the reaction will be in equilibrium is
Enthalpy of formation of H2O(l) is :
(1) 285.7 K (2) 273 K[AIPMT–2006]
(1) +X1 kJ mol–1 (2) –X2 kJ mol–1
(3) 450 K (4) 300 K (3) +X3 kJ mol –1
(4) –X4 kJ mol–1
6. The enthalpy of hydrogenation of cyclohexene is 13. Given that bond energies of H–H and Cl–Cl are 430
–119.5 kJ mol–1 . If resonance energy of benzene kJ mol–1 and 240 kJ mol–1 respectively and fH for
is –150.4 kJ mol–1 , its enthalpy of hydrogenation HCl is –90 kJ mol–1. Bond enthalpy of HCl is :
would be [AIPMT–2006] [AIPMT–2007]
–1
(1) – 508.9 kJ mol–1 (2) – 208.1 kJ mol–1 (1) 245 kJ mol (2) 290 kJ mol–1
(3) – 269.9 kJ mol–1 (4) – 358.5 kJ mol–1 (3) 380 kJ mol–1 (4) 425 kJ mol–1

E 31
Chemistry For NEET By Prince Sir
14. Bond dissociation enthalpy of H2,Cl2 and HCl are 21. The following two reactions are known :
434, 242 and 431 kJmol–1 respectively.Enthalpy Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g) ;
of formation of HCl is:- [AIPMT–2008]
(1) –93 kJmol–1 (2) 245 kJmol–1 H = –26.8 kJ
(3) 93 kJmol–1 (4) –245 kJmol–1 FeO(s) + CO(g) Fe(s) + CO2(g) ;
15. For the gas phase reaction, [AIPMT–2008]
H = –16.5 kJ
PCl5(g) ‡ˆ ˆˆ ˆ†
ˆˆ PCl (g)+Cl (g)
3 2 Correct target equation is [AIPMT–2010]
Which of the following conditions are correct ? Fe2O3(s) + CO(g) 2FeO(s) + CO2(g), H = ?
(1)H < 0 and S < 0 (2) H > 0 and S < 0
(1) –43.3 kJ (2) –10.3 kJ
(3) H = 0 and S < 0 (4) H > 0 and S > 0
16. Which of the following are not state functions ? (3) + 6.2 kJ (4) + 10.3 kJ
(I) q + w (II)q [AIPMT–2008] 22. Standard entropies of X2, Y2 and XY3 are 60, 40
(III)w (IV) H-Ts –1 –1
and 50 JK mol respectively. For the reaction
(1)(I),(II)and(III) (2)(II)and(III)
(3)(I)and(IV) (4)(II),(III)and(IV) 1 3
X + Y2 ‡ˆ ˆˆ ˆ†
ˆˆ XY3, H = –30 kJ to be at
17. From the following bond energies :-[AIPMT–2009] 2 2 2
–1
H – H bond energy : 431.37 kJ mol equilibrium, the temperature should be :-
–1
C = C bond energy : 606.10 kJ mol
–1
(1) 500 K (2) 750 K [AIPMT–2010]
C – C bond energy : 336.49 kJ mol
(3) 1000 K (4) 1250 K
C – H bond energy : 410.50 kJ mol–1
Enthalpy for the reaction, 23. Intensive property is :- [AIIMS–2010]
(1) Moles (2) Volume
H H H H (3) Enthalpy (4) Temperature
C=C+H–H H–C–C–H
24. In which of following there is decrease in
H H H H
entropy :- [AIIMS–2010]
willbe:- [AIPMT–2009]
(1) When temperature is raised from 30 K to 150 K.
(1) 553.0 kJ mol–1 (2) 1523.6 kJ mol–1
(3) –243.6 kJ mol–1 (4) –120.0 kJ mol–1 (2) When NaHCO3 changes into Na2CO3 (s) and
18. The values of H and S for the reaction, CO2(g)
C(graphite) + CO2(g) 2CO(g) are 170 kJ and (3) H2(g) 
 2H(g)
170JK–1, respectively. This reaction will be
spontaneous at :- [AIPMT–2009] (4) Liquid crystalises into a solid
(1) 510 K (2) 710 K 25. Which of the following is not a state function:-
(3) 910 K (4) 1110 K (1) Pressure (2) Volume[AIIMS–2010]

19. For vaporization of water at 1 atmospheric pressure, (3) Temperature (4) Heat
the values of H and S are 40.63 kJ mol–1 and 26. If the enthalpy change for the transition of liquid
–1 –1
108.8 Jk mol , respectively. The temperature water to steam is 30 kJ mol–1 at 27°C, the entropy
changes for the process would be:[AIPMT Pre.–2011]
when Gibbs energy change (G) for this
transformation will be zero, is :- [AIPMT–2010] (1) 10 J mol–1 K–1 (2) 1.0 J mol–1 K–1

(1) 393.4 K (2) 373.4 K (3) 0.1 J mol–1 K–1 (4) 100 J mol–1 K–1

(3) 293.4 K (4) 273.4 K 27. Enthalpy change for the reaction, [AIPMT Pre.–2011]

20. Three moles of an ideal gas expanded 4H(g)  2H2(g) is –869.6 kJ

spontaneously into vacuum. The work done will be :- The dissociation energy of H–H bond is :
(1) 3 Joule (2) 9 Joule[AIPMT–2010] (1) –434.8 kJ (2) 869.6 kJ
(3) Zero (4)Infinite (3) +434.8 kJ (4) +217.4 kJ

32 E
 Chemistry For NEET By Prince Sir
28. Which of the following correct option for free 34. In which of the following reactions, standard reaction
expansion of an ideal gas under adiabatic condition? entropy charge (S°) is positive and standard Gibb's
energy charge (G°) decreases sharply with
(1) q = 0, T  0, w = 0 [AIPMT Pre.–2011] increasing temperature? [AIPMT Pre.–2012]

(2) q  0, T = 0, w = 0 1
(1) Mg(s) + O (g)  MgO(s)
2 2
(3) q = 0, T = 0, w = 0
1 1 1
(4) q = 0, T < 0, w  0 (2) C graphite + O2(g)  CO2(g)
2 2 2
29. Consider the following processes :-
1
(3) C graphite + O (g)  CO (g)
[AIPMT Mains–2011] 2 2
H(kJ/mol) 1
(4) CO(g) + O (g)  CO2(g)
2 2
1
A B +150 35. Standard enthalpy of vapourisation vapH1 for
2
water at 100°C is 40.66 kJmol–1. The
3B  2C + D –125 internal energy of vaporisation of water at
E + A  2D +350 100°C (in kJmol–1) is [AIPMT Pre.–2012]

For B + D  E + 2C, H will be : (1) +43.76 (2) +40.66

(3) +37.56 (4) –43.76
(1) 325 kJ / mol (2) 525 kJ / mol
36. The enthalpy of fusion of water is 1.435 kcal/mol.
(3) –175 kJ / mol (4) –325 kJ / mol The molar entropy change for the melting of ice at
30. The enthalpy of formation of CO(g), CO2(g), N2O(g) 0°C is: [AIPMT Pre.–2012]

and N2O4(g) is –110, –393, +81 and 10 KJ/mol (1) 5.260 cal/(mol K) (2) 0.526 cal/(mol K)
(3) 10.52 cal/(mol K) (4) 21.04 cal/(mol K)
respectively. For the reaction N2O4(g) + 3CO(g)  37. The Gibbs' energy for the decomposition of Al2O3
N2O(g) + 3CO2(g). Hr is [AIIMS–2011] at 500°C is as follows : [AIPMT Mains–2012]

(1) –212 (2) +212 2 4

Al2O3  Al + O2 ;
(3) +778 (4) –778 3 3
31. For adiabatic process which is correct-[AIIMS–2011] rG = +960 kJ mol–1.
(1) T = 0 (2) S = 0 The potential difference needed for the electrolytic
reduction of aluminium oxide (Al2O3) at 500°C is at
(3) q = 0 (4) qp = 0 least:
32. Which of the following is not thermodynamic (1) 2.5 V (2) 5.0 V
function- [AIIMS–2011] (3) 4.5 V (4) 3.0 V
(1) Internal energy (2) work done 38. At equilibrium which is correct :- [AIIMS–2012]
(1) G = 0 (2) S = 0
(3) Enthalpy (4) Entropy
(3) H = 0 (4) G° = 0
33. Which of the following is intensive property- 39. Bond dissociation energy of CH4 is 360 kJ/mol and
[AIIMS–2011] C2H6 has 620 kJ/mol. Then bond dissociation
energy of C–C bond is :- [AIIMS–2012]
(1) Enthalpy (2) Entropy (1) 170 kJ/mol (2) 50 kJ/mol
(3) specific heat (4) volume (3) 80 kJ/mol (4) 220 kJ/mol

ANSWER KEY LEVEL 2(A)

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
A. 3 2 2 1 1 2 1 3 1 4 2 2 4 1 4
Q. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A. 2 4 4 2 3 3 2 4 4 4 4 3 3 3 4
Q. 31 32 33 34 35 36 37 38 39
A. 3 2 3 3 3 1 1 1 3

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Chemistry For NEET By Prince Sir
LEVEL–2(B)
1. Consider the reaction : N2 + 3H2 2NH3 carried 6. The enthalpy changes for the following processes
out at constant temperature and pressure. If H are listed below : [AIEEE-2006]
and U are the enthalpy and internal energy –1
Cl2(g) = 2Cl(g), 242.3 kJ mol
changes for the reaction, which of the following
I2(g)=2I(g), 151.0 kJ mol–1
expressions is true ? [AIEEE–2005]
ICl(g) = I(g) + Cl(g), 211.3 kJ mol–1
(1)  H <  U (2)  H >  U
I2(s)=I2(g), 62.76 kJ mol–1
(3)  H = 0 (4)  H = U
Given that the standard states for iodine and chlorine
2. For a reversible process at T = 300K, the volume
is increased from Vi = 1L to Vf = 10L. Calculate are I2(s) and Cl2(g), the standard enthalpy of
H if the process is isothermal - [IIT-2004] formation forICl(g) is :-
(1) 11.47 kJ (2) 4.98 kJ (1) –16.8 kJ mol–1 (2) +16.8 kJ mol–1
(3) 0 (4) –11.47 kJ (3) +244.8 kJ mol–1 (4) –14.6 kJ mol–1
3. If the bond dissociation energies of XY, X2 and Y2 7. For the process H2O() (1 bar , 373K) H2O(g)
(all diatomic molecules) are in the ratio of 1 : 1 : 0.5 (1 bar , 373K), the correct set of thermodynamic
and fH for the formation of XY is –200 kJ mol–1. parameters is : [IIT-2007]
The bond dissociation energy of X2 will be :- (1) G = 0, S =+ve (2) G = 0, S = –ve
[AIEEE-2005] (3) G = +ve, S=0 (4) G = –ve, S = +ve
(1) 200 kJ mol–1 8. In conversion of lime-stone to lime,
(2) 100 kJ mol–1 CaCO3(s)  CaO(s) + CO2(g)
–1
(3) 800 kJ mol the values of H° and S° are +179.1 kJ mol–1 and
(4) 300 kJ mol–1 160.2 J/K respectively at 298 K and 1 bar.
4. The conversion A to B is carried out by the following Assuming that H° and S° do not change with
temperature, temperature above which conversion
path : [IIT-2006]
of limestone to lime will be spontaneous is :-
C D [AIEEE-2007]
Given : S(A C) = 50 e.u. , (1) 1008 K (2) 1200 K
A B (3) 845 K (4) 1118 K
S(C D) = 30 e.u., S(B D) = 20 e.u.
9. Assuming that water vapour is an ideal gas, the
where e.u. is entropy unit then S(A B) is
internal energy change (U) when 1 mol of water
(1) + 100 e.u. (2) + 60 e.u.
is vapourised at 1 bar pressure and 100°C,
(3) – 100 e.u. (4) – 60 e.u.
(Given : Molar enthalpy of vapourisation of water
5. The standard enthlapy of formation (fH°) at 298K at 1 bar and 373 K = 41 kJ mol–1 and
–1
for methane, CH4(g), is –74.8 kJ mol . The R = 8.3 J mol–1 K–1 will be) :- [AIEEE-2007]
additional information required to determine the (1) 4.100 kJ mol–1 (2) 3.7904 kJ mol–1
average energy for C–H bond formation would be:- (3) 37.904 kJ mol–1 (4) 41.00 kJ mol–1
[AIEEE-2006] 10. Identify the correct statement regarding a
(1) Latent heat of vapourization of methane sponateous process :- [AIEEE-2007]
(2) The first four ionization energies of carbon and (1) For a spontaneous process in an isolated system,
electron gain enthalpy of hydrogen the change in entropy is positive
(3) The dissociation energy of hydrogen molecule (2) Endothermic processes are never spontaneous
H2 (3) Exothermic processes are always spontaneous
(4) The dissociation energy of H2 and enthalpy of (4) Lowering of energy in the reaction process is the
sublimation of carbon only criterion for spontaneity

34 E
 Chemistry For NEET By Prince Sir
11. Oxidising power of chlorine in aqueous solution can 15. The standard enthalphy of formation of NH3
be determined by the parameters indicated below: is –46.0 kJ mol–1. If the enthalpy of formation of
1 H2 from its atoms is –436 kJ mol–1 and that of N2
1  diss H Θ  eg H Θ
2
Cl2(g)   Cl(g)  
 Cl–(g) is –712kJ mol–1, the average bond enthalpy of
2 N–H bond in NH3 is :- [AIEEE-2010]
 HΘ (1) –1102 kJ mol–1 (2) –964 kJ mol–1

hyd
 Cl–(aq) [AIEEE-2008]
(3) + 352 kJ mol–1 (4) +1056 kJ mol–1
1 16. A system absorbs reversibly 600 J of heat and
The energy involved in the conversion of Cl (g) performs 250 J of work. The increase in the
2 2
to Cl–(aq) internal energy of system is :- [RPMT-2011]
(1) 850 J (2) 250 J (3) 600 J (4) 350 J
(using the data diss H ΘCl2 = 240 kJ mol–1, 17. For reversible melting of ice at 0°C and 1 atm.
pressure, the value of G will be :-[RPMT-2011]
eg H ΘCl = –349 kJ mol–1, hyd H ΘCl = –381 kJ mol–1) (1) < 0 (zero) (2) > 0 (zero)
willbe:- (3) 0 (zero) (4) (infinity)
(1) –610 kJ mol–1 (2) –850 kJ mol–1 18. The entropy change involved in the isothermal
(3) +120 kJ mol –1
(4) +152 kJ mol–1 reversible expansion of 2 moles of an ideal gas from
12. Standard entropy of X2, Y2 and XY3 are 60, 40 a volume of 10 dm3 to a volume of
and 50 JK–1 mol–1, respectively. For the reaction, 100 dm3 at 27°C is :- [AIEEE-2011]
(1) 32.3 J mol–1 K–1 (2) 42.3 J mol–1 K–1
1 3 (3) 38.3 J mol–1 K–1 (4) 35.8 J mol–1 K–1
X2 + Y2  XY3, H = – 30 kJ, to be at
2 2 19. The value of enthalpy change (H) for the reaction
equilibrium, the temperature will be[AIEEE-2008] C2H5OH() + 3O2(g)  2CO2(g) + 3H2O()
(1) 1250 K (2) 500 K (3) 750 K (4) 1000 K at 27°C is –1366.5 kJ mol–1. The value of internal
13. On the basis of the following thermochemical energy change for the above reaction at this
temperature will be :-
 0 
data : H f H  aq   0  (1) –1371.5 kJ
[AIEEE-2011]
(2) –1369.0 kJ
H2O() H+(aq) + OH–(aq) ; H = 57.32 kJ (3) –1364.0 kJ (4) –1361.5 kJ
20. Consider the reaction : [AIEEE-2011]
1
H2(g) + O2(g) H2O () ; H = –286.20 kJ 4NO2(g) + O2(g)  2N2O5(s), rH = –111kJ.
2
If N2O5(s) is formed instead of N2O5(g) in the above
The value of enthalpy of formation of OH– ion at reaction, the rH value will be :-
25°C is :- [AIEEE-2009]
(given, Hof sublimation for N2O5 is 54 kJ mol–1)
(1) +228.88 kJ (2) –343.52 kJ
(1) –165 kJ (2) +54 kJ
(3) –22.88 kJ (4) –228.88 kJ
(3) +219 kJ (4) –219 kJ
14. In a fuel cell methanol is used as fuel and oxygen 21. The incorrect expression among the following is :-
gas is used as an oxidizer. The reaction is (1) K = e–G°/RT [AIEEE-2012]
3
CH3OH() + O (g) CO2(g) + 2H2O() G system
2 2 (2) =–T
Stotal
At 298 K standard Gibb's energies of formation for
CH3OH(), H2O() and CO2(g) are –166.2, –237.2 Vf
and –394.4 kJ mol–1 respectively. If standard (3) In isothermal process, Wreversible = – nRT ln
Vi
enthalpy of combustion of methanol is
–726 kJ mol–1, efficiency of the fuel cell will be
H  TS
[AIEEE-2009] (4) lnK =
(1) 90% (2) 97% (3) 80% (4) 87% RT

ANSWER KEY LEVEL 2(B)

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
A. 1 3 3 2 4 2 1 4 3 1 1 3 4 2 3
Q. 16 17 18 19 20 21
A. 4 3 3 3 4 4

E 35