MAGNETIC RESONANCE LOG
BASIC CONCEPT
             OF
     Magnetic Resonance Log
  HISTORY
MRI Introduced by Dr. Raymond Damadian July 3, 1977
with “Indomitable” now at the Smithsonian Institute
Color Enhanced MRI
MAGNETIC RESONANCE TOOLS
   From the center of the tool, a permanent
    magnet produces a magnetic field that
    magnetises the formation material (Known as
    B0).
 Additionally, precisely timed oscillating
    magnetic field is applied
MAGNETIC RESONANCE LOGGING
Introduced by NUMAR in 1991 based on medical MRI
MR Tool
                                  24 "
                        2.5 –            Depth of Investigation
 Borehole                 4.5 "
M R LOGGING SEQUENCES
 Before the tool is lowered in the well, protons in the
  formation fluids are randomly oriented
M R LOGGING SEQUENCES
 Before the tool is lowered in the well, protons in the
  formation fluids are randomly oriented
 These protons are activated when tool generates the
  magnetic fields while passing through the formation.
M R LOGGING SEQUENCES
 Before the tool is lowered in the well, protons in the
  formation fluids are randomly oriented
 These protons are activated when tool generates the
  magnetic fields while passing through the formation.
 First, the tool’s permanent magnetic field aligns or
  polarizes, the spin axes of the protons, in a particular
  direction.
M R LOGGING SEQUENCES
 Before the tool is lowered in the well, protons in the
    formation fluids are randomly oriented
 These protons are activated when tool generates the
    magnetic fields while passing through the formation.
 First, the tool’s permanent magnetic field aligns or
    polarizes, the spin axes of the protons, in a particular
    direction.
   Then the tool’s oscillating field is applied to tip these
    protons away from their new equilibrium position.
       M R LOGGING
       CONCEPTS
 When the oscillating field is subsequently removed,
  the protons begin tipping back, or relaxing, towards
  the original direction in which the static magnetic field
  aligned them.
       M R LOGGING
       CONCEPTS
 When the oscillating field is subsequently removed,
  the protons begin tipping back, or relaxing, towards
  the original direction in which the static magnetic field
  aligned them.
 Specified pulse sequences are used to generate a
  series of spin echos, measured by the tool and are
  displayed on logs as spin echo trains. These spin echo
  trains constitute the raw MR data.
       M R LOGGING
       CONCEPTS
 When the oscillating field is subsequently removed,
  the protons begin tipping back, or relaxing, towards
  the original direction in which the static magnetic field
  aligned them.
 Specified pulse sequences are used to generate a
  series of spin echos, measured by the tool and are
  displayed on logs as spin echo trains. These spin echo
  trains constitute the raw MR data.
 The tool measures the amplitude of the spin echo as a
  function of time and can be displayed as a function of
  depth.
IDEALIZED MR ECHO TRAIN
   Amplitude
                           Decay Curve
               TE   Time
        M R LOGGING
        CONCEPTS
   The initial amplitude of the spin echo is proportional to
    the hydrogen nuclei, associated with fluids in the pore
    and thus amplitude can be calibrated to porosity.
   The observed Echo-train can be linked to:
       1.   Data Acquisition Parameter
       2.   Properties of the pore fluids located in the
            measurement area.
 M R Logging
DATA ACQUISITION PARAMETER:
    1.    Inter echo spacing (Te) : the time between the
         individual echo
    2. Polarization time (TW) time between the
         cessation of measurement of one echo train
         and the begining of measurement of the next
         echo train.
    3. Both Te & TW can be adjusted to change the
         information content of the acquired data
         measurement area.
M R Logging
 PROPERTIES OF PORE FLUIDS:
     1.   Hydrogen Index (HI); measure of the density of hydrogen
          atoms
     2.   Longitudinal relaxation time T1; Indication of how fast the
          tipped protons relaxed longitudinally (relative to the axis
          of the static magnetic field)
     3.   Transverse relaxation time T2 Indication of how fast the
          tipped protons relaxed transversely (again relative to the
          axis of the static magnetic field)
     4.   Diffusivity (D): Measure of the extent to which molecules
          move at random in the field.
         M R LOGGING
         CONCEPTS
 Since only fluids are visible to MRI, the porosity
    measured by the tool is independent of matrix
    material: a significant different from other porosity
    devices.
   The main information from Magnetic Resonance:
    1.   Information about quantities of fluids in the rock
    2.   Information about the properties of these fluids
    3.   Information about the size of these pores that
     contain these fluids.
T2 DISTRIBUTION
 The amplitude of the spin -echo train
  decay forms the decay spectrum or
  transverse relaxation time (T2)
  distribution.
Echo Data Inversion
                   Decay Curve
Amplitude
                                                         T 2 Spectrum
            Time                              20
                                      Ø
                          Inversion           15
                                              10
                                      Part.
                                              5
                                              0
                                                   0.1   1     10      100   1000
                                                             T2 [ms]
T2 DISTRIBUTION
    1. Small pores will have small T2 value and large
       pore will have large T2 value.
T2 DISTRIBUTION
    1. Small pores will have small T2 value and large
       pore will have large T2 value.
    2. The estimate of free fluid index is based on the
       assumption that the producible fluids reside in
       the large pores whereas the bound fluids
       reside in the smaller pores.
T2 CUTOFF
  3.   Because T2 values can be related to pore sizes, a T2 value can
       be selected below which the corresponding fluids are
       expected to reside in the small pores and above which the
       corresponding fluids are expected to reside in larger pores.
  4.   This T2 value is called T2 cutoff.
T2 CUTOFF
  3.   Because T2 values can be related to pore sizes, a T2 value can
       be selected below which the corresponding fluids are
       expected to reside in the small pores and above which the
       corresponding fluids are expected to reside in larger pores.
  4.   This T2 value is called T2 cutoff.
  5.   This cutoffs then divide the total porosity into free fluid and
       bound fluid (bulk volume irreducible).
  6.   The area under the T2 curve is total porosity.
  7.   Usual value of T2 cutoff, (determined from core calibration)
       Gulf of mexico Sandstone: 33ms and Carbonates : 92ms.
Pore-Size Distribution from MR
                       Magnetic Resonance
                                           MR Porosity                                                                                              T2 Cutoff
                                                                                     Incremental Porosity pu)
              20
                                                                                                                4.00                                                  4.00
                                                                                                          (
              15                           T2 Decay                                                             3.00                                                  3.00
  Amplitude
   Echo
                                                                                                                2.00                                                  2.00
              10
                                                            Transform
                                                                                                                1.00                                                  1.00
               5
                                                                                                                               CBW       BVI      BVM
                                                                                                                0.00                                                  0.00
                   0   15   30   45   60   75    90   105   120   135   150
                                                                                                                       0.1      1        10       100     1000    10000
                                      Time (ms)                                                                                                T2 Decay (ms)
                                                                                                                 Clay-
                                                                                                                 Clay-       Capillary
                                                                              Dry                                                        Mobile
                                                Matrix                                                          Bound         Bound                 Hydrocarbon
                                                                              Clay                                                       Water
                                                                                                                Water         Water
    Bulk Volume Irreducible Water
    (“MBVI”)
 Bound Water occupies pore space and is not producible,
  but it affects resistivity measurements and must be
  accounted for !
 Bound Water is generally confined to small pores.
                                                 MBVI
                                                                  disconnected
                                                                        ?
                                                                poorly connected
                             Dry    Clay- Capillary
                    Matrix   Clay   Bound Bound Mobile Hydrocarbon       Vugs
                                    Water Water     Water
                                    MCBW               MBVM
                                                  MPHI  eff
                                                    total
Porosity – Different Points of View
                                  clay-   capillary
                          dry                         mobile
                 matrix          bound     bound                  hydrocarbon   Vugs
                          clay                        water
                                 water     water
 RESERVOIR ENGINEER’S                                                           ?
                                                                  eff
                                                            t
                                  clay-   capillary
                          dry                         mobile
                 matrix          bound     bound                  hydrocarbon   Vugs
                          clay                        water
                                 water     water
 LOG ANALYST’S                                                                  ?
                                                           eff
                                                      t
Conventional Simple NMR Interpretation
             CBW      Irred. water Mov. water       L.H.C.
                                                               T2
   Ideal Case:
        Cutoff can be established to separate bound vs. free water;
        hydrocarbon vs. aqueous phases
Pore Volumetric Partitioning of T2 Spectra
                                                                              GR   CBW   BVI   BVM
                                                      T2 Cutoffs
Incremental Porosity (pu)
                            4.00                                       4.00
                            3.00                                       3.00
                            2.00                                       2.00
                                      CBW   BVI    BVM
                            1.00                                       1.00
                            0.00                                       0.00
                                0.1     1    10     100     1000   10000
                                            T2 Decay (ms)
                             Default T2 Cutoff Values:
                             3 ms for CBW - Effective Porosity
                             33 ms for BVI - BVM (Clastics)
                             92 ms for BVI - BVM (Carbonates)
Petrophysical Integration of NMR & Conventional
Logs
Bulk   Analysis
 GR, SP &    Resistivity & T   Total Fluid
                               2
                                           Total Pore             Formation
  Caliper    Permeability             Saturation   Volumetrics   Volumetrics
                            Spectra
Sensitive Volume in the Invaded Zone
                           Mechanical Damage
                           from drilling            Sxo        Sw
     NMR (MREx, MRIL, CMR, …) measurements are primarily in the
     flushed zone where invasion alters the native fluid saturation.
      … Additives in the mud system may alter wetability.
NMR vs. Core Porosity
               Gulf of Mexico Sandstone                                                            Middle East Carbonate
                     20                                                                            0.3
                     18
                                                                                                  0.25
                     16
                                                                          MRIL Porosity (frac.)
MRIL Porosity ( %)
                     14
                                                                                                   0.2
                     12
                     10                                                                           0.15
                     8
                                                                                                   0.1
                     6
                     4                               1.2 TE                                       0.05
                                                     0.5 TE
                     2
                                                      = +/- 1 p.u.
                     0                                                                              0
                      0   2   4    6   8   10   12   14   16    18   20                                  0   0.05   0.1   0.15   0.2   0.25   0.3
                                  Core Porosity (%)                                                            Core Porosity (frac.)
                                            Mineralogy-Independent Porosity
Gas and Shale Effects
                 Gas
           ØD
                             Shale
                        ØN
                                MRIL-CN cross-plot
                                provides a gas-effect
                 Gas            free Vshale estimate
         ØMPHI
                             Shale
                        ØN
Vsh from CNC - MRIL Shale Triangle
                   Effect of light Hydrocarbons
                                    s
                                  Gas
                                 Ga
          MRIL 
                                              e
                                         h aal le
                                        SS h
                             Neutron 
BVM/BVI Concept :
We remember: empirical equations for k
 Pore properties empirically expressed in irreducible water
 saturation terms (Timur 1968, Coates & Dumanoir 1974):
                                            2
                                 2.25 
                   k  100            
                            S w, irr 
 --> permeability determination from NMR measurements:
         4          2
      
       MBVM              MBVM - bulk volume moveable fluids
 k   
  
     C   MBVI           MBVI     - bulk volume irreducible
                             fluids
NMR Logging User Perspectives
  Primary interests for NMR logging
       Bound water (clay and capillary bound)
       Effective and total porosity
       Permeability
  Advanced NMR applications
       Fluid typing, saturation, and viscosity
       Contacts: OWC, GOC, GWC
                                                  from S. Chen et al., 2003
NMR - Information
                                          Total porosity
                                  Irreduci
                                            b le w a t e
                              Cla                        r
                                  yb           volume
                                      oun
                              Po           dw
                                 re            ate
                                    siz            r
                    pe
                     Flu
                                        e
                      rm
                        id v
                         ea
                            bil
                             isc
                                ity
                                  os
                                     ity
T2 - An Overview
                                                      water
        CBW    BVI       BVM                          (free)
           water in rocks
        heavy                                       light
        cold                oil                      hot
                                      Gas no
                     gradient           gradient
    1           10              100          1000     T2 ms
MAGNETIC RESONANCE LOG
          Any Questions
               On
      Magnetic Resonance Log ? ?
Applications
  Low resistivity pay (high Swir)
  Shaly sands (effective)
  Improved reserves estimation (Net Pay and So)
  Reservoir Quality (e, k, Vsh, Qv, Grain Size, …)
  Producibility (Pore Size, k, SMoveable Fluid, …)
  Porosity (complex mineralogy, dolomitization, ...)
  Hydrocarbon Typing (PoroPerm + Oil, PoroPerm + Gas)
  Viscosity Estimation (Diffusion measurements)
Environmental Effects on NMR logs
Temperature                       Reduces S/N somewhat
Conductive mud                  Loading reduces S:N (low Q),
                 logging speed may      suffer.
                                Interference signal from sodium ?
Washout >                         MPHI too high, excess (mud) signal,
                 usually in
 DIO (MREx)       MBVI and CBW
Invasion                         Alters native fluid saturations;
                 primarily measures      the flushed zone
MAGNETIC RESONANCE LOGGING
Introduced by NUMAR in 1991 based on medical MRI
                                         Sensitive Volumes
                                         (1 mm thick sectors,
                                            10 mm spacing)
MR Tool
                                  24 "
                        2.5 –            Depth of Investigation
 Borehole                 4.5 "
MR Spin Echo Sequence
          90°          180°             180°
 RF
                TE/2
                         TE              TE
                         T2 Decay
                 T2 * Decay
 Signal
                1st Spin-Echo       2nd Spin-Echo
Data Acquisition Parameters: Te & TW
                          T1 Build up
             T2 Decay
                            TW
  TW =    wait time
  Te = interecho time
  T1 = Longitudinal magnetization build up
  T2 = Transverse magnetization decay         Te
                                             CPMG
NMR - Physics and Petrophysics
      - FUNDAMENTALS -
   Nuclear Magnetic Resonance
    is originated by interaction
    of nuclei magnetic moments
   with an external magnetic field
NMR Properties - Clay Minerals
 Clay mineral      Specif. Internal   Cation Exchange            T2
                      Surface         Capacity CEC               ms
                      m2/g            meq/100g
 Montmorillonite      760                   76                   0.3 … 1
 Illite               93                    15                   1…2
 Kaolinite            18                     4                   8 … 16
                                                  data after Prammer et al., 1996
Thomas-Stieber Porosity Model
                                    sd + (1 - sd ) • sh
              max
Sand
Total
                                                                            Shale
         sd • sh
                     sd = Vsh                               1- sd = Vsh
                                 Vshale
MRAX: Vshale and Vclay
    Vshale
           “catch-all” term, not well defined
            (analogous to “garbage”)
           includes both silt and clay
    Vclay
           mineralogy (illite, smectite, koalinite, …)
           size (< 1/256 mm, 0.00015”)
kaolinite                Chlorite            Illite
Idealized NMR Echo Train
                 Ø nmr
                BVM (“FFI”)
 BVI
   Amplitude
                                     T2 Decay Curve
               TE             Time
MRIL Echo Data
       MPHI
MBVI
               Coarse grained sand
MBVM
                                       Fine grained sand
              Time (ms)
                                     Time (ms)
Hydrocarbon Typing Methods
 Simple analysis of T
                       2
      Identify gas-oil, oil-water & gas –water contacts
      Viscosity estimates
 Differential Spectrum (DSM)
      Exploits T1 differences of fluids
 Shifted Spectrum (SSM)
      Exploits diffusion differences of fluids
 Enhanced Diffusion (EDM)
      Identify upper T2 limit of water
 Dual-TW, Dual / Multiple-TE
      DSM + SSM for thorough analysis
 Density Dual-Wait Time (DDTW)
      Technique for gas saturation analysis
       with NMR and density log data
Summary
Hydrocarbon Typing Methods
     Simple analysis of T2
           Identify gas-oil, oil-water & gas –water contacts
           Viscosity estimates
     Differential Spectrum (DSM)
           Exploits T1 differences of fluids – light hydrocarbons
     Shifted Spectrum (SSM)
           Exploits diffusion differences of fluids – oil viscosity & quantification
     Enhanced Diffusion (EDM)
           Fluid identification based on max T 2_max(diffusion)
     Density Dual-Wait Time (DDTW)
          Deterministic method for gas saturation analysis with NMR and density log data
     Objective Oriented Acquistions – comprehensive data package for hydrocarbon identification &
      analysis
          PoroPerm+Oil
          PoroPerm + Gas
          PoroPerm + Heavy Oil
     SIMET and 2D NMR Analysis
          Used for analyzing OOA data
          T1, T2, Diffusion
          Saturation analysis for oil, gas and water
          HI & ρg for gas
          T2 & diffusion maps for heavy oil