Revision date: 24/09/2020 Revision: 1.

SAFETY DATA SHEET BELZONA® 1511 SOLDIFIER

SECTION 1: Identification: Product identifier and chemical identity

Product identifier
Product name BELZONA® 1511 SOLDIFIER

Product No. SN2859

Relevant identified uses of the substance or mixture and uses advised against
Application High temperature repair metal for the rebuilding of pitting damage in equipment subject to
erosion-corrosion. For industrial use only.

Uses advised against The product should not be used for purposes other than those recommended in the
appropriate Instructions For Use (IFU) leaflet.

Details of the supplier of the safety data sheet

Supplier Rezitech Services Reptech Corporation Ltd
109 - 111 Wedgewood Road 503 Great South Road
Hallam, Victoria 3803 Penrose, Auckland 1061
AUSTRALIA NEW ZEALAND
+61 3 8720 8600 0800 (REPTECH) 737832

Manufacturer Belzona Polymerics Limited

Claro Road, Harrogate
HG1 4DS
United Kingdom
+44 1423 567641
[email protected]

Emergency telephone number

Emergency telephone Australia: Steven Hunt +61 404 843 835
New Zealand: National Poisons Centre 0800 764 766

SECTION 2: Hazard(s) identification

Classification of the substance or mixture
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2A - H319 Skin Sens. 1 - H317 Repr. 1B - H360F

Environmental hazards Aquatic Chronic 3 - H412

Reference The full text for all hazard statements is displayed in Section 16.

Label elements

Hazard pictograms

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Hazard statements H315 Causes skin irritation.

H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H360F May damage fertility.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P202 Do not handle until all safety precautions have been read and understood.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing and eye protection.
P308+P313 IF exposed or concerned: Get medical attention.
P501 Dispose of contents/ container in accordance with national regulations.

Contains EPOXY PHENOL NOVOLAC RESIN, TRIMETHYLOLPROPANE TRIGLYCIDYLETHER,

BISPHENOL F-EPOXY RESIN

Other hazards
HSNO classification: 6.3A 6.4A 6.5B 9.1C

SECTION 3: Composition and information on ingredients

Mixtures

EPOXY PHENOL NOVOLAC RESIN 10-30%

CAS number: 28064-14-4

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

TRIMETHYLOLPROPANE TRIGLYCIDYLETHER 5-10%

CAS number: 30499-70-8

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Skin Sens. 1B - H317
Repr. 1B - H360F
Aquatic Chronic 2 - H411

BISPHENOL F-EPOXY RESIN 1-5%

CAS number: 9003-36-5

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2A - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

Description of first aid measures

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General information In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.

Inhalation Remove to fresh air. Keep the patient warm and at rest. Give nothing by mouth.

Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with
plenty of water. Do NOT induce vomiting.

Skin Contact Remove contaminated clothing. Wash skin thoroughly with soap and water or use a
proprietary skin cleaner. Do NOT use solvents or thinners. If irritation or inflammation
persists, seek medical attention.

Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15
minutes, holding the eyelids apart, and seek medical advice.

Most important symptoms and effects, both acute and delayed

General information May damage fertility.

Skin contact Prolonged or repeated contact with the skin or mucous membrane may result in irritant
symptoms such as redness, blistering or dermatitis. Onset of symptoms may be delayed. May
cause an allergic skin reaction.

Eye contact Irritating to eyes.

Indication of any immediate medical attention and special treatment needed

Specific treatments None.

SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, or water fog for larger
fires.
Do NOT use water jet.

Special hazards arising from the substance or mixture

Hazardous combustion In a fire, hazardous decomposition products such as smoke, carbon monoxide and carbon
products dioxide may be produced.

Advice for firefighters

Protective actions during Fire will produce dense black smoke containing hazardous products of combustion. Exposure
firefighting to decomposition products may be a hazard to health. Appropriate self-contained breathing
apparatus may be required. Cool closed containers exposed to fire with water spray. Do not
allow run-off from fire fighting to enter drains or watercourses.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Exclude non-essential personnel. Keep up-wind of spill to avoid breathing vapours. Do not get
on skin or in eyes.

Environmental precautions
Environmental precautions Prevent spills from entering drains or sewers. If the product enters drains or sewers in large
quantities, the local Water Company should be contacted immediately; in the case of
contamination of streams, rivers or lakes, the appropriate National regulating agency.

Methods and material for containment and cleaning up

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Methods for cleaning up Scrape the majority of the product into a suitable labelled container. Cover the spill area with
sand or other suitable inert material and sweep up into the container. Do not allow spilled
product or the associated washings to enter surface water drains or watercourses.

Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13. .

SECTION 7: Handling and storage, including how the chemical may be safely used
Precautions for safe handling
Usage precautions GENERAL Keep the container tightly closed until ready for use. Vapours may collect in the
container headspace during transit or prolonged storage. Do not breathe vapour when
opening the container. Where possible open containers and mix components in a well
ventilated place away from the application area. Exclude non-essential personnel. Minimise
the number of employee exposed and the duration of their exposure. Do not get on skin or in
eyes. Smoking, eating and drinking should be prohibited in areas of storage and use. For
personal protection see Section 8. Always keep in containers made of the same material as
the supply container. Ensure emergency equipment (for fires, spills, leaks, etc.) is readily
available. Good housekeeping methods and regular safe removal of waste materials should
be observed. FIRE/EXPLOSION This product is combustible. Exclude sources of heat,
sparks and open flame. SPECIAL In cold conditions to ease mixing, product should be
allowed to reach room temperature in a warm ventilated store inside the work place.

Advice on general Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure
occupational hygiene eye wash facilities (fountain, bottle, vials, etc.) are readily available. Do not put contaminated
articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets. Where
necessary, contaminated work clothing and shoes should be removed to prevent cross
contamination of surfaces and the risk of inadvertent skin contact and ingestion.

Conditions for safe storage, including any incompatibilities

Storage precautions Observe the label precautions. Store between 5 °C and 30 °C unless otherwise stated in a
dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking.
Prevent unauthorised access. Store separately from oxidising agents and strongly alkaline
and strongly acidic materials. ENVIRONMENTAL STORAGE PRECAUTIONS Spillage,
incorrect storage of chemicals or waste materials or unsuitable disposal activities can result in
pollutants seeping through the soil, causing serious harm to groundwater- which is a vital
source of drinking water. All wastes, especially liquid wastes, must be securely stored on site
in designated areas that are isolated from surface drains and bunded to contain any spillages.

Specific end use(s)

Specific end use(s) Application by plastic applicator or spatula provided. Mix with Solidifier component before use.
Please refer to the relevant Belzona® Instructions For Use for further information.

SECTION 8: Exposure controls and personal protection

Ingredient comments No exposure limits known for ingredient(s).

Exposure controls
Appropriate engineering Use in well ventilated areas or provide adequate mechanical ventilation.
controls

Eye/face protection It is recommended that eye protection, for example safety spectacles or goggles are worn at
all times during the handling and use of this material. Eye protection should be selected in
accordance with EN 166 Personal eye protection. During subsequent machining, grinding,
abrasion or removal of this product appropriate eye protection should be selected according to
the type of tools or equipment used.

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Hand protection Hand protection should be selected in accordance with EN 374 Protective gloves against
chemicals. The breakthrough time of the gloves selected should exceed the expected use
period. Where this is not possible gloves should be changed in good time, and in any case
before the breakthrough time is exceeded. If any doubt exists, advice should be sought from
glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of
skin but are not substitutes for full physical protection. They should not be applied once
exposure has occurred. SPECIFIC RECOMMENDATIONS Use protective gloves made of:
Nitrile. STANDARD APPLICATIONS Medium-heavy weight gauntlet type gloves that provide
wrist protection are suitable.

Other skin and body Synthetic polyethylene coveralls such as the Tyvek PRO-TECH® or equivalent coveralls
protection manufactured to EN 13034 Type 6, Protective clothing against liquid chemicals. Grossly
contaminated clothing should be removed and the skin washed with soap and water or a
proprietary skin cleaner. APPLICATION OF SMALL QUANTITIES Cotton overalls are
normally suitable.

Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible. Respirator selection must be
based on exposure levels, the hazards of the product and the safe working limits of the
selected respirator. Respiratory protection is not normally required, but the hazards of the
Solidifier component should be considered for mixing and application purposes. Respiratory
protection is not normally required but it may be required when this product is used in
confined spaces or where adequate ventilation cannot be achieved. It is essential that the
concentration of the contaminant(s) in the application environment does not exceed the
applicable Occupational Exposure Limit(s) (OELs) multiplied by the Assigned Protection
Factor (APF) quoted for the respiratory protective equipment selected. Where necessary, it is
recommended that respiratory protective equipment that complies with EN 136 (full face
mask) or EN 140 (half face mask) should be worn in combination with an organic/inorganic
vapours, acid gases and ammonia cartridge (ABEK1). Where the application environment is
likely to be contaminated by significant concentrations of dust then the appropriate particulate
prefilter (N-, R- or, P-series) should be worn in combination with the above. It is essential that
the facepiece is correctly fitted and the filter is changed in accordance with the manufacturer's
instructions.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties
Appearance Paste.

Colour Dark grey.

Odour Epoxy.

Odour threshold Not applicable.

pH Not applicable.

Melting point Not available.

Initial boiling point and range >200°C/>392°F @ 100 kPa

Flash point >150°C/>302°F Closed cup.

Evaporation rate Not available.

Flammability (solid, gas) Not applicable.

Flammability Limit - Lower(%) Not applicable.

Vapour pressure Not available.

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Vapour density Not available.

Relative density 2.85 - 2.95 @ 20°C/68°F

Solubility(ies) Immiscible with water.

Partition coefficient Not available.

Auto-ignition temperature >300°C/>572°F

Decomposition Temperature >200°C/>392°F

Viscosity Not available.

Explosive properties Not applicable.

Oxidising properties Not applicable.

Other information This section contains typical values for Health, Safety and Environmental guidance only and is
not intended to represent a technical specification for the product.

SECTION 10: Stability and reactivity

Reactivity There are no known reactivity hazards associated with this product.

Stability Stable under recommended storage and handling conditions (see Section 7).

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

Materials to avoid Keep away from oxidising agents and strongly alkaline and strongly acidic materials to
prevent the possibility of exothermic reaction.

Hazardous decomposition None at ambient temperatures. In a fire, hazardous decomposition products such as smoke,
products carbon monoxide and carbon dioxide may be produced.

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation
Animal data Irritating to skin.

Serious eye damage/irritation

Serious eye damage/irritation Irritating to eyes.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation

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Skin sensitisation Based on the properties of the epoxy constituent(s) and considering toxicological data on
similar preparations, this preparation may be a skin sensitiser. Repeated skin contact may
lead to sensitisation with possibly cross-sensitisation to other epoxies.

Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.

Genotoxicity - in vivo Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity Not listed.

NTP carcinogenicity Not listed.

Reproductive toxicity
Reproductive toxicity - fertility May damage fertility.

Reproductive toxicity - Based on available data the classification criteria are not met.
development

Specific target organ toxicity - single exposure

STOT - single exposure Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazard
Aspiration hazard Not relevant.

Route of exposure Skin and/or eye contact

Medical considerations Skin contact constitutes a pronounced hazard. Persons with a history of skin sensitisation
problems should only be employed in processes in which this product is used under
appropriate medical supervision.

Toxicological information on ingredients.

EPOXY PHENOL NOVOLAC RESIN

Toxicological effects @@@Repeated skin contact may lead to sensitization with possibly cross-
sensitization to other epoxies.@@@

TRIMETHYLOLPROPANE TRIGLYCIDYLETHER

Reproductive toxicity

Reproductive toxicity - - NOAEL 100 mg/kg, Oral, Rat

fertility

SECTION 12: Ecological information

Ecotoxicity There is no data on the product itself. The following information is provided on the basis of the
individual component data available.

Toxicity Based on the individual component data, the product is expected to have experimental
EC50/IC50 values between 10 and 100 mg/l.

Ecological information on ingredients.

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EPOXY PHENOL NOVOLAC RESIN

Toxicity LC50/EC50 between 1 and 10 mg/l in most sensitive species.

Persistence and degradability

Persistence and degradability Based on the individual component data, the product is not expected to be rapidly
biodegradable according to OECD/EC guidelines.

Ecological information on ingredients.

EPOXY PHENOL NOVOLAC RESIN

Persistence and Not expected to be rapidly biodegradable according to OECD/EC guidelines.

degradability Biodegradation reached in Carbon Dioxide Evolution Test (Modified Sturm Test,
OECD Test No. 301B) after 28 days: 10 - 16%.

Bioaccumulative potential
Bioaccumulative Potential Based on the individual component data, the product is expected to bioaccumulate.

Partition coefficient Not available.

Ecological information on ingredients.

EPOXY PHENOL NOVOLAC RESIN

Bioaccumulative Potential ***US Only***

Mobility in soil
Mobility There is no data available on the product itself.

Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

Waste treatment methods
Disposal methods Do not allow into drains or watercourses or dispose of where ground or surface waters may
be affected. Controlled wastes include non-hazardous industrial and hazardous chemical
wastes. All controlled wastes should be disposed of in accordance with regulations made
under the Control of Pollution Act and the Environmental Protection Act. In addition,
hazardous chemical wastes should be disposed of in accordance with the Hazardous Waste
Regulations. When in doubt, using information provided in this safety data sheet, advice
should be obtained from the National regulating agency whether the Hazardous Waste
Regulations apply. Refer to information sources listed in Section 16. COMPONENT
DISPOSAL TRANSIT PACKAGING: shrink or stretch wrap, boxes and fittings that have not
been contaminated with product should be re-used or recycled. UNREACTED PRODUCT and
empty uncleaned containers should be disposed of as hazardous chemical waste. REACTED
PRODUCT, contaminated mixing boards, spatulas, applicators, brushes, nominally empty
containers and mixing bowls- once fully cured- should be disposed of as non-hazardous
waste.

Waste class . *Hazardous waste pursuant to Directive 91/689/EEC. The LoW code quoted in this section is
a general entry. LoW codes should be assigned based on the end use of the product. Where
a more specific code is available it should be used in preference to the code given above.
Where in doubt refer to the List of Wastes, your local licensed waste contractor or the National
regulating agency. Refer to information sources listed in Section 16.

SECTION 14: Transport information

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General Labelling and packaging requirements may vary with pack and load size. Please refer to the
current transport regulations. Transport within user's premises: always transport in closed
containers that are upright and secure. Ensure that persons transporting the product know
what to do in the event of accident or spillage.

UN number
Not applicable.

UN proper shipping name

Not applicable.

Transport hazard class(es)

Not applicable.

Packing group
Not applicable.

Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

Special precautions for user

Not applicable.

Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations GROUP STANDARD: Surface coatings and colourants (Subsidiary)
HSNO APPROVAL NUMBER: HSR002670

Inventories
Australia - AICS
All the ingredients are listed or exempt.

New Zealand - NZIOC

All the ingredients are listed or exempt.

SECTION 16: Any other relevant information

General information The information contained within this safety data sheet does not constitute the users own
assessment of workplace risks as required by other health and safety legislation. As the
specific conditions of use of the product are outside the supplier's control, the user is
responsible for ensuring that the requirements of relevant National legislation are complied
with. The information contained within this safety data sheet is based on the present state of
knowledge and current national legislation. It provides guidance on health, safety and
environmental aspects of the product and should not be construed as any guarantee of
technical performance or suitability for particular applications.

Key literature references and ......

sources for data

Training advice For further information please contact your supplier, Belzona consultant or Belzona direct.

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Revision comments REVISION. This safety data sheet has been revised in the following Section(s): 7, 8, Please
observe the REVISION DATE. Should you be reading a safety data sheet that is more than 24
months old or have concerns over its validity, please contact your local Belzona consultant or
Belzona direct ([email protected]) and the most current information will be sent to you.

Revision date 24/09/2020

Revision 1.4

SDS No. 40935

SDS status English. Approved.

Hazard statements in full H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H360F May damage fertility.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

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