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Jacam Wci1000

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83 views18 pages

Jacam Wci1000

Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 18

SAFETY DATA SHEET

WCI 1000

Section 1. Identification
GHS product identifier : WCI 1000

Other means of : Water Soluble Corrosion Inhibitor


identification

Product use : Not available.

Product type : Liquid.

Manufacturer : Jacam Manufacturing 2013, L.L.C.


P.O.Box 208, 1656 Ave. Q.
Sterling, Kansas 67579

Validation date : 2/21/2017.

For Chemical Emergency : Call CHEMTREC Day or Night


Spill, Leak Fire, Exposure or Within USA and Canada 800-424-9300 CCN# 11754
Accident: Or +1 703-527-3887 (Collect calls accepted)

Direct all other calls to:


Jacam Chemicals 2013, L.L.C. 620-278-3355
Mon – Fri 8 a.m. to 5 p.m. (Closed on major holidays)

Supplier's details : Jacam Chemicals 2013, L.L.C.


P.O. Box 96, 205 S. Broadway
Sterling, Kansas 67579

Section 2. Hazards identification

Classification of the : FLAMMABLE LIQUIDS - Category 2


substance or mixture ACUTE TOXICITY (oral) - Category 4
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 30.9%

GHS label elements

Date of issue/Date of revision 2/21/2017. Version : 1.01


WCI 1000 Page: 2/18

Section 2. Hazards identification


Hazard pictograms :

Signal word : Danger


Hazard statements : H225 - Highly flammable liquid and vapor.
H302 - Harmful if swallowed.
H319 - Causes serious eye irritation.
Precautionary statements
General : P103 - Read label before use.
P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Prevention : P280 - Wear protective gloves: > 8 hours (breakthrough time): nitrile rubber. Wear eye
or face protection: Recommended: chemical splash goggles.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P233 - Keep container tightly closed.
P270 - Do not eat, drink or smoke when using this product.
P264 - Wash hands thoroughly after handling.
Response : P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you
feel unwell. Rinse mouth.
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for 15 minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Obtain medical attention.
Storage : P403 - Store in a well-ventilated place.
P235 - Keep cool.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise : None known.
classified

Routes of entry : Dermal contact. Eye contact. Inhalation.


INGESTION: Although not a normal route of entry, ingestion is expected to be harmful.
DO NOT TAKE INTERNALLY. FOR INDUSTRIAL USE ONLY.
Target organs : Contains material which causes damage to the following organs: upper respiratory tract,
skin.
Contains material which may cause damage to the following organs: blood, kidneys,
liver, mucous membranes, spleen, gastrointestinal tract, cardiovascular system, central
nervous system (CNS), eye, lens or cornea.

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WCI 1000 Page: 3/18

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Chemical name : Not available.
Other means of : Water Soluble Corrosion Inhibitor
identification

CAS number/other identifiers


CAS number : Not applicable.

Ingredient name % CAS number


Isopropanol 30 - 60 67-63-0
Methanol 5 - 10 67-56-1
Oxyalkylated Resins 1-5 9016-45-9

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least
15 minutes. If irritation persists, obtain medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. If adverse health effects
persist or are severe, obtain medical attention. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. If irritation or symptoms persists, obtain medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. If irritation
persists, obtain medical attention. If necessary, call a poison center or physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.

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WCI 1000 Page: 4/18

Section 4. First aid measures


Inhalation : No known significant effects or critical hazards.
Skin contact : May cause skin dryness and irritation.
Ingestion : Harmful if swallowed. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Specific target organ toxicity (single exposure)


Name Category Route of Target organs
exposure
Not available.

Specific target organ toxicity (repeated exposure)


Not available.

Aspiration hazard
Name Result
Not available.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will
from the chemical occur and the container may burst, with the risk of a subsequent explosion. The
vapor/gas is heavier than air and will spread along the ground. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source
of ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Additional Vapor Statement : Not available.
Not available.

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WCI 1000 Page: 5/18

Section 5. Fire-fighting measures


Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident
for fire-fighters if there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Remark : Not available.
Remark : Not available.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools
and explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

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WCI 1000 Page: 6/18

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-
sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse
container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and
incompatibilities well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Isopropanol ACGIH TLV (United States, 4/2014).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Methanol ACGIH TLV (United States, 4/2014).
Absorbed through skin.
TWA: 200 ppm 8 hours.
TWA: 262 mg/m³ 8 hours.
STEL: 250 ppm 15 minutes.
STEL: 328 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
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WCI 1000 Page: 7/18

Section 8. Exposure controls/personal protection


Control parameters Absorbed through skin.
TWA: 200 ppm 8 hours.
TWA: 260 mg/m³ 8 hours.
STEL: 250 ppm 15 minutes.
STEL: 325 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
Absorbed through skin.
TWA: 200 ppm 10 hours.
TWA: 260 mg/m³ 10 hours.
STEL: 250 ppm 15 minutes.
STEL: 325 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 260 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles Recommended: chemical splash goggles
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated. > 8 hours (breakthrough time): nitrile rubber
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Recommended: overall safety apron
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product. Recommended: nitrile rubber

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WCI 1000 Page: 8/18

Section 8. Exposure controls/personal protection


Control parameters
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.
Personal protective :
equipment (Pictograms)

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid. [Clear.]
Color : Amber.
Odor : Unpleasant.
Odor threshold : Not available.
pH : 5 to 6
Melting point : Not available.
Boiling point : 82.222°C (180°F)
Flash point : Closed cup: 22.222°C (72°F) [Pensky-Martens.]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : >1 [Air = 1]
Relative density : 0.88 to 0.91
Density : 7.34 to 7.68 (lbs/gal)

Solubility : Easily soluble in the following materials: cold water.


Partition coefficient: n-octanol/ : Not available.
water

Auto-ignition temperature : Not available.


Decomposition temperature : Not available.
SADT : Not available.
Viscosity : Not available.
Type of aerosol : Not applicable.
Heat of combustion : Not available.
Ignition distance : Not applicable.
Enclosed space ignition - : Not applicable.
Time equivalent
Enclosed space ignition - : Not applicable.
Deflagration density
Flame height : Not applicable.

Date of issue/Date of revision 2/21/2017. Version : 1.01


WCI 1000 Page: 9/18

Section 9. Physical and chemical properties


Appearance
Flame duration : Not applicable.

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials:


oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Isopropanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours
LC50 Inhalation Gas. Rat 64000 ppm 4 hours
LD50 Dermal Rabbit 15800 mg/kg -
LD50 Oral Rat 5600 mg/kg -
Conclusion/Summary : Not available.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Isopropanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 10 milligrams -
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
Methanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 40 milligrams -
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Oxyalkylated Resins Eyes - Severe irritant Guinea pig - 20 milligrams -
Eyes - Severe irritant Mouse - 20 milligrams -
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Human - 72 hours 15 -
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WCI 1000 Page: 10/18

Section 11. Toxicological information


milligrams
Intermittent
Skin - Mild irritant Rabbit - 500 -
milligrams
Skin : Not available.
Eyes : Not available.
Respiratory : Not available.
Sensitization
Product/ingredient name Route of Species Result
exposure
Not available.
Skin : Not available.
Respiratory : Not available.
Mutagenicity
Product/ingredient name Test Experiment Result
Not available.

Conclusion/Summary : Not available.


Carcinogenicity
Product/ingredient name Result Species Dose Exposure
Not available.

Conclusion/Summary : Not available.


Classification
Product/ingredient name OSHA IARC NTP
Isopropanol - 3 -
Reproductive toxicity
Product/ingredient name Maternal Fertility Development Species Dose Exposure
toxicity toxin
Not available.
Conclusion/Summary : Not available.
Teratogenicity
Product/ingredient name Result Species Dose Exposure
Not available.

Conclusion/Summary : Not available.


Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard

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WCI 1000 Page: 11/18

Section 11. Toxicological information


Name Result
Not available.

Information on the likely : Routes of entry anticipated: Dermal, Inhalation.


ToxKinetics - routes of
exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause skin dryness and irritation.
Ingestion : Harmful if swallowed. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects

Not available.
Conclusion/Summary : Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates

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Section 11. Toxicological information


Route ATE value
Oral 717.6 mg/kg
Inhalation (vapors) 24.89 mg/l

Interactive effects : Not available.

Other information : Not available.

Section 12. Ecological information


Toxicity

Product/ingredient name Result Species Exposure

Isopropanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1400000 µg/l Fish - Gambusia affinis 96 hours
Methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute LC50 2500000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
- Adult
Acute LC50 3289 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC 9.96 mg/l Marine water Algae - Ulva pertusa 96 hours
Oxyalkylated Resins Acute EC50 12 mg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute LC50 1.23 mg/l Marine water Crustaceans - Americamysis 48 hours
bahia
Acute LC50 0.148 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 1300 µg/l Fresh water Fish - Lepomis macrochirus 96 hours
Chronic NOEC 8 mg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Chronic NOEC 35 µg/l Fresh water Fish - Oryzias latipes - Fry 100 days
Conclusion/Summary : Not available.

Persistence and degradability


Not available.

Product/ingredient name
Not available.
Conclusion/Summary : Not available.
Product/ingredient name
Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential

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Section 12. Ecological information


Isopropanol 0.05 - low
Methanol -0.77 <10 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapor from product residues
may create a highly flammable or explosive atmosphere inside the container. Do
not cut, weld or grind used containers unless they have been cleaned thoroughly
internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
Waste stream : Not available.
RCRA classification : Not available.
United States - RCRA Toxic hazardous waste "U" List
Ingredient CAS # Status Reference
number
Methanol (I); Methyl alcohol (I) 67-56-1 Listed U154

Section 14. Transport information

Regulatory UN/NA Proper shipping name Hazard PG*


information Number Class(es)

DOT Classification PG* : Packing group

UN1993 FLAMMABLE LIQUID, N.O.S. (Isopropanol, Methanol) 3 II

Additional information

Emergency Response Guide (ERG): 128

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Section 14. Transport information

Label

TDG
Classification
UN1993 FLAMMABLE LIQUID, N.O.S. (Isopropanol, Methanol) 3 II

Additional information

Label

IMDG Class
UN1993 FLAMMABLE LIQUID, N.O.S. (Isopropanol, Methanol) 3 II

Marine pollutant notes: : Not available.

Additional information

Label

IATA-DGR Class
UN1993 FLAMMABLE LIQUID, N.O.S. (Isopropanol, Methanol) 3 II

Additional information

Label

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WCI 1000 Page: 15/18

Section 15. Regulatory information


U.S. Federal regulations : TSCA 8(a) PAIR: Oxyalkylated Resins
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
All components are listed or exempted.

Clean Air Act Section 112 : Listed


(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients

No products were found.

SARA 304 RQ : Not applicable.


SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) health (chronic)
pressure hazard health hazard

Isopropanol 30 - 60 Yes. No. No. Yes. Yes.


Methanol 5 - 10 Yes. No. No. Yes. Yes.
Oxyalkylated Resins 1-5 No. No. No. Yes. No.

SARA 313
Product name CAS number %
Form R - Reporting Isopropanol 67-63-0 30 - 60
requirements Methanol 67-56-1 5 - 10
Supplier notification Isopropanol 67-63-0 30 - 60
Methanol 67-56-1 5 - 10
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall
include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: METHANOL; ISOPROPYL ALCOHOL
New York : The following components are listed: Methanol
New Jersey : The following components are listed: METHYL ALCOHOL; METHANOL;
ISOPROPYL ALCOHOL; 2-PROPANOL
Pennsylvania : The following components are listed: METHANOL; 2-PROPANOL
Date of issue/Date of revision 2/21/2017. Version : 1.01
WCI 1000 Page: 16/18

Section 15. Regulatory information


California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Ingredient name Cancer Reproductive No significant risk level Maximum acceptable
dosage level

Methanol No. Yes. No. 23000 µg/day


(ingestion)
47000 µg/day
(inhalation)
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Canada
WHMIS (Canada) : Class B-2: Flammable liquid
Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
Canadian lists
Canadian NPRI : The following components are listed: Methanol; Isopropyl alcohol;
(Pollution Release) Oxyalkylated Resins
CEPA Toxic substances : The following components are listed: Oxyalkylated Resins
Canada inventory-DSL / NDSL : All components are listed or exempted.
International lists
National inventory
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe : All components are listed or exempted.
Japan : Not determined.
Malaysia : Not determined.
New Zealand : All components are listed or exempted.
Philippines : Not determined.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.

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WCI 1000 Page: 17/18

Section 16. Other information

National Fire Protection Association (U.S.A.)

Flammability
3
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997,
National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National
Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied
only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited
number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the
chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Normal Package Size(s): Ball: 2" Ball 50/Cooler; 4" Ball 12/Cooler
Dry Product: 50 Lbs/Box
Liquid: 5 Gallon/55 Gallon/Bulk
Pellets: 30 Lbs/Cooler; 24 Lbs/Pail
Stix: 1 1/4": 50 Each/Cooler

History
Date of issue/Date of revision : 2/21/2017.
Version : 1.01
Date of previous issue : 6/10/2015.
Previous Validation Date : 6/10/2015.

Prepared by : Jacam Regulatory Department

SDS Requests: : [email protected]

Key to abbreviations : ATE = Acute Toxicity Estimate


BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader

Date of issue/Date of revision 2/21/2017. Version : 1.01


WCI 1000 Page: 18/18

Section 16. Other information


This Safety Data Sheet (“SDS”) is a mandatory disclosure pursuant to 29 CFR § 1910.1200 and related rules and
regulations. Therefore, it is not intended, nor shall it serve to create, any rights, obligations, liabilities, and remedies, of
any kind whatsoever, between Jacam Chemicals 2013, LLC and related entities (“Jacam”) and any users of this SDS
(“Users”).

To the extent that a court of competent jurisdiction determines that this SDS creates any rights, obligations, liabilities,
and remedies, of any kind whatsoever, notwithstanding the foregoing paragraph, Users accept the product AS IS and
WITH ALL FAULTS. Further, Jacam DISCLAIMS ANY EXPRESS OR IMPLIED WARRANTY OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Users’ sole and exclusive remedies shall be
(if any), in Jacam’s sole and absolute discretion, either: (1) return of the product and repayment of the purchase price;
or (2) repair/replacement of the product. In no event shall Jacam be liable for any damages of any kind whatsoever,
including but not limited to, actual, compensatory, reliance, expectancy, foreseeable, future, statutory, incidental,
consequential, and exemplary damages. Users assume any and all risks of any kind whatsoever that in any way relate to
the product.

*** END OF SDS ***

Date of issue/Date of revision 2/21/2017. Version : 1.01

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