Physical Sciences ( Chemistry) P2
September 2024 Marking guideline
Question 1
1.1 B√√
1.2 C√√
1.3 C√√ [6]
Question 2
2.1 Temperature of 273K√ (0°c) and Pressure of 1,013×105Pa/ 101,3 KPa /1atm√ (2)
23
2.2.1 Percentage composition of Na in NaOH= × 100 √
23+16+1
= 57.59%√ (2)
𝑚
2.2.2 n= √
𝑀
10
= √
23
=0.43 mol
2moles of Na produces 1mol of H2
0.43
n (H2 )= √
2
=0.215 mol
𝑚
n=
𝑀
𝑚
0.215= √
(1+1)
m=0.43g√ (5)
𝑉
2. 2.3. n= √
𝑉𝑚
𝑉
0.2175= √
22.4
V=4.87dm3√ (3)
𝑚
2.3 n=
𝑀
5
= √
(12×3+8×1)
=0.11 mol
1 mole of C3H8 produces 3 moles of CO2
3
n (CO2) = 0.11× √
1
=0.33 mol
𝑚
n=
𝑀
𝑚
0.33= √
44
m=14.52g
𝑎𝑐𝑡𝑢𝑎𝑙 𝑚𝑎𝑠𝑠
Percentage yield= ×100
𝑡ℎ𝑒𝑜𝑟𝑒𝑡𝑖𝑐𝑎𝑙 𝑚𝑎𝑠𝑠
𝑎𝑐𝑡𝑢𝑎𝑙 𝑚𝑎𝑠𝑠
75= ×100√
14.52
Actual mass=10.89g√ (5)
[17]
QUESTION 3
3.1.1 Concentration is the number of moles of solute per lcubic decimeter of solution√√ (2)
3.1.2
M(NH4NO₃)=14)+(4×1)+(14)+(3×16)=80g·mol-1
250 cm³=0,25dm³
m
n=
M
32
= √
80
=0.4 mol
𝑛
c=
𝑣
0.4
= √
0.25
=1.6 mol.dm-3√ (3)
3.2 3.2.1 2 KCIO₃ → 2KCl + 3O₂
2 mol KClO₃produces 2 mol KCl
1 mol KCIO₃produces 1mol KCl
MKCl= 39+35.5= 74,5g.mol-1
M(𝐾𝐶𝑙𝑂3)= 39+35.3+16× 3 = 122,5 g.mol-1
𝑚
n= √
𝑀
160
= √
74,5
=2.15 mol
n (KClO3)=n (KCl)= 2.15mol
𝑚
n=
𝑀
𝑚
2.15= √
122.5
m=263.38g√ (4)
3.2.2 Mole ratio of n KCl: n O2= 2: 3
𝑚
n= √
𝑀
200
= √
74,5
=2.68 mol
3
nO2= 2.68×
2
=4.02 mol
𝑉
n=
𝑉𝑚
𝑉
4.02= √
22.4
V=90.05dm3√ (4)
QUESTION 4
4.1.1 Empirical formula is the simplest whole number ratio of atoms in a compound√ √ (2)
4.1.2
C H O
48.7 8.1 43.2
𝑚 48.7 8.1 43.2
n= (mol)√ = 405 =8,1 =2.7√
𝑀 12 1 16
4.05 8.1 2.7
=1.5 =3 =1√
2,7 2,7 2,7
1,5×2=3 3 ×2=6 1 ×2=2√
Ratio C: H: 0 is 3:6:2
Empirical formula C3H6O2√
4.2.1Water changes into gas √and leaves the (system)√ (2)
4.2.2
CuSO4 H2O
Mass (g) 4 2.257
M(g.mol-1) 159.5 18
𝑚
n= 0,0251 0,125
𝑀
(mol)
Ratio 1 5
CuSO4.5H2O
[14]
TOTAL: 50
