SRI CHAITANYA IIT ACADEMY, INDIA 01-01-25_ Sr.

S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-12/07_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_Elite, Target & LIIT-BTs JEE-MAIN Date: 01-01-2025
Time: 09.00Am to 12.00Pm GTM-12/07 Max. Marks: 300^
KEY SHEET
MATHEMATICS
1 3 2 1 3 1 4 3 5 4
6 2 7 3 8 1 9 4 10 1
11 1 12 2 13 2 14 1 15 2
16 1 17 2 18 3 19 4 20 4
21 42 22 75 23 34 24 75 25 8

PHYSICS
26 2 27 1 28 1 29 2 30 2
31 4 32 3 33 2 34 2 35 2
36 1 37 4 38 4 39 3 40 1
41 3 42 2 43 3 44 4 45 2
46 5 47 1 48 1 49 2 50 2

CHEMISTRY
51 3 52 3 53 1 54 3 55 3
56 4 57 2 58 3 59 4 60 2
61 2 62 1 63 4 64 2 65 3
66 1 67 1 68 2 69 4 70 4
71 4 72 4 73 4 74 4 75 4

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SOLUTION
MATHEMATICS
1. Given that PQ = kI
P . Q  k3  P  2k  0  P is an invertible matrix
 PQ  kI  Q  kP 1 I  P 1 P  I 
adj.P k
Q   q23  
2 8
 3  4   k  12  16..... i
 
2 8
 P  2k  k  10  6
From (i) and (ii) we get  = -1, k = 4   2  k 2  17
2.  is 7th root of unity  1    a 2  ...  a 6  0, p  q  1
pq   4  a 6   5   7   8   7   9   10  3     2   3  ....   6   3  1  2
 x2  x  2  0
Both I and II are true and II is the correct explanation.
3.
M A N K I N D
 4  6!   4! 3 
    5! 0       3! 2    2! 1  1!1   0! 0    1492
 2!   2! 
 1440  36  12  4  1492
4. (A) No. of such triangles = 10 6Cl + = 60
(B) No. of such triangles = 10
(C) No. of such quadrilaterals = 10 5Cl + = 75
(D) No. of such quadrilaterals = 10 (when four consecutive points are taken)
5. Let p  E1   x. p  E2   y and p  E3   z
 
  p E1  E2  E3  p  E1  . p E2 . p E3    
   x 1  y 1  z  …..(i)
Similary,
  1  x  . y 1  z  ……(ii)
  1  x 1  y  .z …..(iii)
p  1  x 1  y 1  z  …..(iv) and solve equation.
6.

slope of AC  
Slope of PD  0
 a a b3  b3
D ,   D  a, 
 2 2   2 

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b3
 1  0, b  3  2  0  b  1
2
b  1
 b  a 5  b   a 1 
E ,  ,2
 2 2   2 
slope of BC  slope of EP  1
 
 5  b   2 1   6   2 
    a  1   1      1  12  1  a  a  3
ba  1   1  a   a  3 
 2 
 12  a  3a  a  3  a 2  2a  15  0
2

a  3 accept
Equation of AP A  3,3 , P 1,1
 3 1 
y 1     x  1  x  2 y  3
 3  1 
Equation of BC B  1,5 , C   3, 1
 5 1 
Y 1     x  3  3x  9 3x  y  8  0
 1  3 
 13 17 
Q , 
 7 7 
7. Given equation is
e 4 x  4e3 x  58e 2 x  4e x  1  0
 1  1  
Take, f  x    e2 x   4  e x    58 
 e2 x  ex  
1
Let e x   p   0 …..(i)
ex
p 2  4 p  60  0 p  6 or  10
1
Only p = is allowed e x  6
ex
Two real and distinct value od x
d
8. Since, given  1   2  20  2  1
d 1
2
   
Now, A1   1  and A2  π  2 
 4  2π 
 2 3 2
Let S  2 A1  3 A2  1  2
8 4π
For max or min
ds 2 6 d   6 π
0 1  2 . 2 0 1  2  1 6
d 1 8 4π d  1 4 4π 2
9. Let f  x   4 x 3  11x 2  8 x  5x  R
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 f '  x   12 x 2  22 x  8 and f '  x  0

10. Since, we know AB  BC  CA  0  α  2, β  4 ,γ  δ  3
1
Now, AB  AC  5 6
2
 δ  9 2   2δ  12 12  100  600  δ  5,γ  8
Hence, CB.CA  60
11. Given points and direction ratios are shown below.
   
a1  1,2 ,3 ,a2   2 ,4 ,5  ,b1  2 i  3 j  λ k
   
b2  i  4 j  5 k
Apply shortest distance formula,

 
2
12. 15 sin4 α  10 1  sin2 α  6 ,25 sin 4 α  20 sin 2 α  4  0

 25 sin 4 α  10 sin2 α  10 sin 2 a  4  0

 
 5 sin2 a  2  0  sin 2 a 
2
5
 x  1  x2  3x  5
13. For, Sl we have  0
x 2  3x  2
 x    ,2   1,2 
For S2, we have
  
3 x 3x  3  32 3 x  3  0 
For S2, x  1,2    ,2   1,2
x2 d
14.   x sin x  cos x  dx   sin x  cos x   x cos x
dx
 
x cos x  x dx  x  1 
 x sin x  cos x 2  cos x  cos x  x sin x  cos x 
   
Use by parts method
4
15. Area: 2 2 x  2 x dx 
1
16.  
Given, 1  x 2 dy  y  x  y  dx


Where, y  0   1, y 2 2  β 
 yx  y 2 
dy    dx
 1  x2 
 
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dy   x   1  2
 y  y ,divide by y2 both sides and proceed
dx 2  2
1 x  1 x 
17. First common term of both the series is 23 and common difference is 7 x 4 = 28
 Last term  407  23   n  1  28  407   n  1  28  384
384
n  1  n  14.71
28
Hence, number of terms common are 14
18. N = (26 + a + b), fixi = (504 + 3a + 9b)
50 50
19. U X i  U Yi  T ;  n  X i   10 ,n Yi   5
i 1 i 1
50 50 500 5n
So, U X i  500 ,U Yi  5n    n  30
i 1 i 1 20 6
20. Given function is
lim
 5 x  ...  ln 1   x   0
x 0 x
 ln 1  5 x   ln 1   x 
 : x0
f ( x)   x
 10 : x0

Applying expansion of ln 1  x  .
lim  5     10 5    10    5
x 0

    

21. Given matrix is A    2  2
 2 
        

R3  R3  R1
  
 A       2
  2 2

1 1 1
 A                    adjA  A
n 1

 n 1 2
adj  adjA   A


adj adj  adj  adjA   A   n 1 4
 A
24
 A         2 .3
16 32 16

1 d
22. 0  1  3  d  1 .....(i )
4
1  2d 1 3
0 1    d  .....(ii )
4 2 2
1  4d 3 1
0 1    d  .....(iii )
4 4 4
1  3d 1
0  1    d  1 .....(iv )
4 3
From (i ), (ii ), (iii ) and (iv )
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1 1 1
  d  minimum value of d  
3 4 3
1  2 d 2 1  4d  3 1  3d 
Mean  0   
4 4 4
6  3d 1  1 5 5
X   6  3     60 X  60   75
4 4 3 4 4
23. It has infinitely many solutions.
24. we have x 2  4 y 2  2 x  8 y    0
 x  1  y  1
2 2
2b 2
  1  4
 5  5 a
4
2    5
4
4   5 
On solving    59
  5
1  2a  2   5  2 65  16
   l  59  16  75
25.
(a, 4, 2)

2 6

2, 3, -1

 2  1,3  3,   1
X 1 Y  3 Z 1
Given line   
2 3 1
X  2  1, Y  3  3, Z    1
 2 1  a  2   3 1 3     1 1  0
 4  2  2a  9  3    1  0
14  4  2a  0  7  2  a  0
  5  1   3  1     1  24
2 2 2

35 2  14  21  0     1 35  21  0

For,   1  a  5
Let 1 , 2 , 3  be reflection point P
1  5  2  4  12 3  2  0
1  3  2  8  3  2
a  1   2   3  8

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PHYSICS
26. 
M 1L3T 0  M L T 1 1 2 a
  LT  T 1 b c
a  1, b  4, c  2

27. Rate of change of speed is minimum at highest point. Since at highest position.

 vcos 
2

R
g
28. Inside a closed Guassian surface Qenc  0
m m 2m2   
29. In 1D collisions formula for v1  1 2 v1  v2 , when m1  m2 , v1  u1  2u2 .
m1  m2 m1  m2
  
30. E  B gives direction of V
R
31. Time period becomes 2 in statement 1. We can’t neglect roundness of earth for
g
pendulum of infinite length.
2 r g   B  l 
2  
32. VT  , Power  F .V
9 
33. T = 4sec, Body starts at extreme position and ends at mean position as shown

t=2 t=1 t=0

t =3

1 x
34. For dropped body L  x  gt 2 , for pulse t  2 .x is the distance from bottom free end of
2 g
row.
0 I 0
35. For infinitely long wire B  , r  a 2, BRe s  2B
2 r
BA

900

BB

36. Above curie temperature ferro becomes para.

37. Distance between any two points when only increase.
38. Vavg, Vrms , Vmp will all exist at a particular temperature.

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VRms
39. IN resonance VL  VC ,Vres  VR , Z  R iRms 
Z
dB 
40. emf  A ,i  .
dt R
Z2 n2 0 z 2 rn
41. En  13.6 ev , rn  0.529 A , Vn  2.2  10 6 m / s , T  .
n 2
z n vn
1/3
RGe  X 
42.   X = 72, Number of neutron = 72  32 = 40
RBe  9 
43. Zener current will be maximum, when V = 15V ,15  (i  2.5k) = 5, i = 4 mA ,iz = 3 mA
44. In uniform pure rolling, the linear velocity is constant. If no external force or torque is
applied, the body will remain in a state of uniform pure rolling. In this case, the friction
force is always zero, so there will not be any effect of the frictional force on the body.
I coherent 4I
45.  2
I Incoherent 2 I
1 2 1 2 mv 2
46. mv0  mv  mgl 1  cos   T  mg cos   .
2 2 R
KQx dE R
47. E ,  0 is maximum x  .
 R2  x  2 3/2 dx 2

E
48.  E  ir , 2E  i  3  r  ,r = 1.
2
49. 1 sin 900   sin 300
ML2 2
50. I sin  ,angle is with vertical
3

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CHEMISTRY
51. Stability of complex  chelation
52.

F F H3N NH3
2+
Cu
Xe
F F H3N NH3

53. Statement 2 is the reason for statement 1

54. Oxidation power order : F2 > Cl2 > Br2 > I2
55. Energy   n  l 
e3  e2  e4  e1 
 n  l  3  2 4  0 3  1 3  0
 5 4 4 3 

56. S R  O 2 
 SO2 H ,  70960Cal ____(i )
S M  O 2   SO2H ,  71030Cal ____(ii )
Subtracting eqn (II) from (i) we get ,
H  H1  H 2   70960    71030   70Cal
57.

N I
S
O n I I
O n n I
Bent Pyramidal Bent
58. The correct statement for B is 5f electrons have much lower shielding effect as compared
to 4f electrons because 5f- orbitals more diffused than 4f-orbitals
59. Correct assertion The bond enthalpies of the two O-H bonds in H-O-H are not equal.
Correct reason This is because electronic environment around O is not same after
breakage of one O-H bond.
60.  2 NH 3  g  ; K c
N 2  g   3H 2  g  
 N 2  g   3H 2  g  ; 1
2 NH 3  g  
Kc
1
Multiplying by , reaction becomes
2
 1 N 2  g   3 H 2  g 
NH 3  g  
2 2

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1 1
 1 2  1 2
1
 New K c      
 Kc   64  8
61. Both assertion and reason are true but reason is not correct explanation of assertion.
Ammonium acetate is a salt of weak acid (CH3COOH) and weak base (NH4OH).
62. C6 H12O6 (GLUCOSE) monosaccharide.
63. Ethanol and hexane forms positively deviated non-ideal solution.
64. MnO4  e  
 MnO42 

5e- Mn+2

+3e- MnO2
k  1000
65. nm 
m
=  
1 1 1 1000
Specific conductance = nm  
specific resis tan ce  x x y
66.
O

C C C C C
O

C  C  C  C  C H3

gives +ve Iodoform test

67.
Br
SN1 
+

[Carbocation isstablized by resonance & Br is good leaving group]

SN2

Br

Negative Inductive group favours

incoming nucleophile to attack readily

68. Compound (Y) is 10-amine.

1
69. Basic strength 
stability of Anion

Sec: Sr.S60_Elite, Target & LIIT-BTs Page 10

 SRI CHAITANYA IIT ACADEMY, INDIA 01-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-12/07_KEY &SOL’S
70.
Cl NH2

NaNH2/lig NH3

71.
4mL  %  w / w   d  10 
 
 29.2   1.25  10  10M

M  molar mass  36.5
According to dilution, eqn, MiVi = MfVf
0.4  100
Vf   4mL
10
16 / 3
72. 4
4/3
73. (i),(ii),(iv),(vi)
74. C4H10O
CH 3
H 3C  CH 2  CH 2  CH 2  OH H 3C  C  C  CH 3

OH
CH 3
H 3C  CH 2  CH  CH 3
H 3C  C  CH 2  OH
H
75. (i),(iii),(iv),(v)

Sec: Sr.S60_Elite, Target & LIIT-BTs Page 11