HOBART GmbH

Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
Revision date: 06.03.2020 Product code: Page 1 of 14

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

HYLINE HLU-31
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Professional: Cleaner
Uses advised against
Any non-intended use.
1.3. Details of the supplier of the safety data sheet
Company name: HOBART GmbH
Street: Robert-Bosch-Strasse 17
Place: D-77656 Offenburg
Telephone: +49 (0) 781.600-0 Telefax: +49 (0) 781.600-23 19
e-mail: [email protected]
Internet: www.hobart.de
Responsible Department: Dr. Gans-Eichler e-mail: [email protected]
Chemieberatung GmbH Tel.: +49(0)2534 6441185
Otto-Hahn-Str. 36 www.tge-consult.de
D-48161 Muenster
1.4. Emergency telephone Giftnotruf (Poison Center) Berlin: +49 (0) 30 30686700
number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008
Hazard categories:
Substance or mixture corrosive to metals: Met. Corr. 1
Skin corrosion/irritation: Skin Corr. 1
Serious eye damage/eye irritation: Eye Dam. 1
Hazardous to the aquatic environment: Aquatic Acute 1
Hazardous to the aquatic environment: Aquatic Chronic 2
Hazard Statements:
May be corrosive to metals.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Very toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labelling
potassium hydroxide; caustic potash
Sodium Hypochlorite
Signal word: Danger

Pictograms:

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 HOBART GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
Revision date: 06.03.2020 Product code: Page 2 of 14

Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P260 Do not breathe vapour/aerosol.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
2.3. Other hazards
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
GHS Classification
1310-58-3 potassium hydroxide; caustic potash 5 -15 %
215-181-3 019-002-00-8 01-2119487136-33
Met. Corr. 1, Acute Tox. 4, Skin Corr. 1A; H290 H302 H314
1312-76-1 Silicic acid, potassium salt MR >3,2 1-5%
215-199-1 01-2119456888-17
Skin Irrit. 2, Eye Irrit. 2; H315 H319
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid 3-<5%
253-733-5 01-2119436643-39
Met. Corr. 1, Eye Irrit. 2; H290 H319
7681-52-9 Sodium Hypochlorite 1-5%
231-668-3 017-011-00-1 01-2119488154-34
Met. Corr. 1, Skin Corr. 1B, Eye Dam. 1, STOT SE 3, Aquatic Acute 1, Aquatic Chronic 1; H290
H314 H318 H335 H400 H410 EUH031
%

Full text of H and EUH statements: see section 16.

Further Information
Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article
59 (REACH)

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
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sheet if possible).
After inhalation
In case of accident by inhalation: remove casualty to fresh air and keep at rest. In case of respiratory tract
irritation, consult a physician. In the case of lung irritation: Primary treatment using corticoide spray, eg.
Auxiloson spray, Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks).
After contact with skin
After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated
clothing. In case of skin irritation, seek medical treatment.
After contact with eyes
In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. Subsequently consult an ophthalmologist.
After ingestion
Do NOT induce vomiting. Rinse mouth thoroughly with water. Let water be drunken in little sips ( dilution effect).
Observe risk of aspiration if vomiting occurs. Never give anything by mouth to an unconscious person or a
person with cramps. When in doubt or if symptoms are observed, get medical advice.
4.2. Most important symptoms and effects, both acute and delayed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects).
4.3. Indication of any immediate medical attention and special treatment needed
First Aid, decontamination, treatment of symptoms.
In the case of lung irritation: Primary treatment using corticoide spray, eg. Auxiloson spray,
Pulmicort-dosage-spray. (Auxiloson and Pulmicort are registered trademarks).

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Sand. Foam. Carbon dioxide (CO2). Extinguishing powder. In case of major fire and large quantities: Water
spray jet. Water mist.
Unsuitable extinguishing media
High power water jet
5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Phosphorus oxides. Chlorine (Cl2).
Hydrogen chloride (HCl).
5.3. Advice for firefighters
In case of fire and/or explosion do not breathe fumes. In case of fire: Wear self-contained breathing apparatus.
Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Co-ordinate fire-fighting measures to the fire surroundings.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment (refer to section 8).
Do not breathe vapour/aerosol. Avoid contact with skin, eyes and clothes.
High slip hazard because of leaking or spilled product.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. Eliminate leaks immediately. Prevent spread over a wide
area (e.g. by containment or oil barriers). Do not allow to enter into soil/subsoil. If required, notify relevant
authorities according to all applicable regulations.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .

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 HOBART GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
Revision date: 06.03.2020 Product code: Page 4 of 14

Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections
No information available.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Wear suitable protective clothing. ( See section 8. )
Do not mix with acids.
Advice on protection against fire and explosion
Usual measures for fire prevention.
Further information on handling
Advices on general occupational hygiene: See section 8.
Shelf Life (months): 12
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Unsuitable materials for Container: Aluminium. Zinc.
Keep only in the original container in a cool, well-ventilated place away from acids. Keep container tightly
closed. Handle and open container with care.
Make sure spills can be contained (e.g. sump pallets or kerbed areas).
Suitable floor material: Leachate-proof.
Hints on joint storage
Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Organic peroxides. Self-reactive
substances and mixtures. Radioactive substances. Infectious substances.
Further information on storage conditions
Protect against: frost. UV-radiation/sunlight. heat. Humidity frost.
storage temperature: (-)10 - 20°C
7.3. Specific end use(s)
See section 1.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

7782-50-5 Chlorine 0.5 1.5 STEL (15 min) WEL

1310-58-3 Potassium hydroxide - 2 STEL (15 min) WEL

DNEL/DMEL values

CAS No Substance
DNEL type Exposure route Effect Value
1310-58-3 potassium hydroxide; caustic potash
Worker DNEL, long-term inhalation local 1 mg/m³
Consumer DNEL, long-term inhalation local 1 mg/m³
1312-76-1 Silicic acid, potassium salt MR >3,2
Worker DNEL, long-term inhalation systemic 5,61 mg/m³

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 HOBART GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
Revision date: 06.03.2020 Product code: Page 5 of 14

Worker DNEL, long-term dermal systemic 1,49 mg/kg

bw/day
Consumer DNEL, long-term inhalation systemic 1,38 mg/m³
Consumer DNEL, long-term dermal systemic 0,74 mg/kg
bw/day
Consumer DNEL, long-term oral systemic 0,74 mg/kg
bw/day
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid
Worker DNEL, long-term inhalation systemic 15 mg/m³
Worker DNEL, long-term dermal systemic 4,2 mg/kg bw/day
7681-52-9 Sodium Hypochlorite
Worker DNEL, long-term inhalation systemic 1,55 mg/m³
Worker DNEL, acute inhalation systemic 3,1 mg/m³
Worker DNEL, acute inhalation local 3,1 mg/m³
Worker DNEL, long-term inhalation local 1,55 mg/m³
Consumer DNEL, long-term oral systemic 0,26 mg/kg
bw/day
Consumer DNEL, long-term inhalation systemic 1,55 mg/m³
Consumer DNEL, long-term inhalation local 1,55 mg/m³
PNEC values
CAS No Substance
Environmental compartment Value
1312-76-1 Silicic acid, potassium salt MR >3,2
Freshwater 7,5 mg/l
Freshwater (intermittent releases) 7,5 mg/l
Marine water 1 mg/l
Micro-organisms in sewage treatment plants (STP) 348 mg/l
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid
Soil 0,491 mg/kg
Freshwater sediment 1,47 mg/kg
Freshwater (intermittent releases) 10,42 mg/l
Marine water 0,33 mg/l
Freshwater 3,33 mg/l
7681-52-9 Sodium Hypochlorite
Freshwater 0,00021 mg/l
Freshwater (intermittent releases) 0,00026
Marine water 0,000042 mg/l
Secondary poisoning 11,1 mg/kg
Micro-organisms in sewage treatment plants (STP) 4,69 mg/l

8.2. Exposure controls

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
Revision date: 06.03.2020 Product code: Page 6 of 14

Appropriate engineering controls

Provide adequate ventilation.
Protective and hygiene measures
When using do not eat, drink or smoke.
Eye/face protection
Wear eye/face protection. BS/EN 166
Hand protection
Wear suitable gloves.
Suitable material:
FKM (fluororubber). - Thickness of glove material: 0,4 mm
Breakthrough time >= 8 h
Butyl rubber. - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
CR (polychloroprenes, Chloroprene rubber). - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
NBR (Nitrile rubber). - Thickness of glove material: 0,35 mm
Breakthrough time >= 8 h
PVC (Polyvinyl chloride). - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
The selected protective gloves have to satisfy the specifications of EU Directive EC/2016/425 and the standard
EN 374 derived from it.
Before using check leak tightness / impermeability. In the case of wanting to use the gloves again, clean them
before taking off and air them well.
Skin protection
Protective clothing: Protective apron.
Standard: Protective clothing: EN 136, EN 137, EN 140, EN 143, EN 149,EN 405, EN 12941, EN 12942, EN
14387
Respiratory protection
With correct and proper use, and under normal conditions, breathing protection is not required.
Respiratory protection necessary at:
-Exceeding exposure limit values
-Insufficient ventilation and aerosol or mist formation .
Suitable respiratory protective equipment: Combination filtering device (EN 14387) Type : B- P2/P3
The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates)
that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus
must be used.
Environmental exposure controls
The product needs to apply neutralizing agents before draining to wastewater treatment plants.
This material and its container must be disposed of in a safe way.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: liquid
Colour: yellow
Odour: characteristic (Chlorine.)
pH-Value: >13 (conc.); 12 (1 %in aqueous
solution)
Changes in the physical state
Melting point: not determined
Boiling point or initial boiling point and not determined
boiling range:

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Safety Data Sheet

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HYLINE HLU-31
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Sublimation point: No information available.

Softening point: No information available.
Pour point: No information available.
Flash point: not determined
Sustaining combustion: No data available
Flammability
Solid: No information available.
Gas: No information available.
Explosive properties
none
Lower explosion limits: not determined
Upper explosion limits: not determined
Auto-ignition temperature: not determined
Self-ignition temperature
Solid: No information available.
Gas: No information available.
Decomposition temperature: No information available.
Oxidizing properties
none
Vapour pressure: No information available.
(at 20 °C)
Vapour pressure: No information available.
(at 50 °C)
Density (at 20 °C): 1,35 g/cm³
Bulk density: No information available.
Water solubility: miscible.
Solubility in other solvents
miscible.
Partition coefficient n-octanol/water: No information available.
Viscosity / dynamic: < 30 mPa·s
Viscosity / kinematic: No information available.
Flow time: No information available.
Relative vapour density: No information available.
Evaporation rate: No information available.
Solvent separation test: No information available.
Solvent content: No information available.
9.2. Other information
Solid content: No information available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No information available.
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
May cause decomposition by long-term light influence.
Decompostion takes place from temperatures above: 40°C
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HYLINE HLU-31
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Decomposition under formation of: Chlorine (Cl2). Oxygen. (Danger of bursting container.)
10.3. Possibility of hazardous reactions
The product develops hydrogen in an aqueous solution in contact with metals. (Explosion hazard)
Contact with acids liberates toxic gas. (Chlorine.)
10.4. Conditions to avoid
heat. frost. UV-radiation/sunlight.
10.5. Incompatible materials
Materials to avoid: Strong acid. Base metals and alloys. Aluminium. Zinc. Lead. Oxidizing agents. Reducing
agents. Amines. Ammonia.
10.6. Hazardous decomposition products
Can be released in case of fire: Carbon monoxide Carbon dioxide (CO2). Phosphorus oxides. Chlorine (Cl2).
Hydrogen chloride (HCl).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution
No information available.
Acute toxicity
Based on available data, the classification criteria are not met.
CAS No Chemical name
Exposure route Dose Species Source Method
1310-58-3 potassium hydroxide; caustic potash
oral LD50 333 Rat ECHA
mg/kg
1312-76-1 Silicic acid, potassium salt MR >3,2
oral LD50 > 5000 Rat ECHA dossier EPA OPPTS 870.1100
mg/kg
dermal LD50 > 5000 Rat ECHA dossier EPA OPPTS 870.1200
mg/kg
inhalation (4 h) vapour LC50 > 2,06 Rat ECHA dossier EPA OPPTS 870.1300
mg/l
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid
oral LD50 > 6500 Rat. Echa dossier
mg/kg
dermal LD50 >4000 Rat. Echa dossier
mg/kg
inhalation (4 h) aerosol LC50 > 1,98 Rat. Echa dossier
mg/l
7681-52-9 Sodium Hypochlorite
oral LD50 1100 Rat ECHA Dossier OECD Guideline 401
mg/kg
dermal LD50 20000 Rat ECHA Dossier OECD Guideline 402
mg/kg
inhalation (1 h) vapour LC50 >10,5 Rat ECHA Dossier OECD Guideline 403
mg/l

Irritation and corrosivity

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HYLINE HLU-31
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Causes severe skin burns and eye damage.

Causes serious eye damage.
Irritant effect on the eye: highly caustic.
Irritant effect on the skin: highly caustic.
Irritant effect on the respiratory tract: Irritant.
Sensitising effects
Based on available data, the classification criteria are not met.
Potassium Silicate: no danger of sensitization.
Sodium Hypochlorite : no danger of sensitization.
literature infomation: ECHA dossier
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
Sodium Hypochlorite :
No experimental indications of mutagenicity in-vivo exist.
Literature information: ECHA dossier
2-phosphonobutane-1,2,4-tricarboxylic acid:
In vitro mutagenicity/genotoxicity: Method: OECD 471 (Ames test). Result: negative.; Developmental
toxicity/teratogenicity: Method: OECD 414. Species: Rat. Exposure duration: 20d. Result: NOEL 1000 mg/kg
bw/day. Literature information: ECHA Dossier.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Sodium Hypochlorite :
Subchronic oral toxicity (90d) NOAEL = 34,4 mg/kg (Mouse.)
Literature information: ECHA dossier
2-phosphonobutane-1,2,4-tricarboxylic acid:
Subchronic oral toxicity : Method: OECD 408. Species: Rat. Exposure duration: 90d. Test results: NOAEL >=
424 Mg/kg bw male Rat. >= 632Mg/kg bw female ,Rat. Literature information: ECHA Dossier.
2-phosphonobutane-1,2,4-tricarboxylic acid:
Subchronic oral toxicity:
Result: NOAEL = 424 mg/kg
Exposure time: 90 d
Species: Rat.
Aspiration hazard
Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1. Toxicity
The product has not been tested.
CAS No Chemical name
Aquatic toxicity Dose [h] | [d] Species Source Method
1312-76-1 Silicic acid, potassium salt MR >3,2
Acute fish toxicity LC50 > 146 96 h Leuciscus idus ECHA dossier
mg/l
Acute algae toxicity ErC50 207 mg/l 72 h Desmodesmus ECHA dossier other guideline:
subspicatus DIN 38412
Acute crustacea toxicity EC50 > 146 48 h daphnia magna ECHA dossier
mg/l
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid
Acute fish toxicity LC50 > 1042 96 h Danio rerio Echa dossier
mg/l

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Safety Data Sheet

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HYLINE HLU-31
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Acute algae toxicity ErC50 >140 72 h Desmodesmus Echa dossier

mg/l subspicatus)
Acute crustacea toxicity EC50 > 1071 48 h Daphnia magna Echa dossier
mg/l
Fish toxicity NOEC >1042 14 d Danio rerio Echa dossier
mg/l
Crustacea toxicity NOEC 104 mg/l 21 d Daphnia magna Echa dossier
7681-52-9 Sodium Hypochlorite
Acute fish toxicity LC50 0,032 96 h Fish ,various ECHA Dossier
(TRO) mg/l
Acute algae toxicity ErC50 0,036 72 h Pseudokirchneriella ECHA Dossier OECD Guideline
mg/l subcapitata 201
Acute crustacea toxicity EC50 0,035 48 h Ceriodaphnia dubia ECHA Dossier OECD Guideline
mg/l 202
Fish toxicity NOEC 0,04 28 d Menidia peninsulae ECHA Dossier
mg/l
Crustacea toxicity NOEC 0,015 21 d V. iris (Ambloplites ECHA Dossier READ ACROSS
mg/l rupestris)
Acute bacteria toxicity (563 mg/l) 3 h Activated sludge ECHA Dossier OECD Guideline
209

12.2. Persistence and degradability

The product has not been tested.
CAS No Chemical name
Method Value d Source
Evaluation
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid
OECD 302A / ISO 9887 / EEC 88/302 annex V, C.12 30-40% 90 Echa dossier
Not easily bio-degradable (according to OECD-criteria).

12.3. Bioaccumulative potential

No indication of bioaccumulation potential.
The statement is derived form the properties of the components.
Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
37971-36-1 2-phosphonobutane-1,2,4-tricarboxylic acid -1,36

12.4. Mobility in soil

No information available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
No information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations
Dispose of waste according to applicable legislation. Consult the local waste disposal expert about waste
disposal. Non-contaminated packages may be recycled. The allocation of waste identity numbers/waste
descriptions must be carried out according to the EEC, specific to the industry and process.
Control report for waste code/ waste marking according to (EWC) European Waste Catalogue:

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HYLINE HLU-31
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List of Wastes Code - residues/unused products

200129 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately
collected fractions (except 15 01); detergents containing hazardous substances; hazardous waste
List of Wastes Code - used product
200129 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately
collected fractions (except 15 01); detergents containing hazardous substances; hazardous waste
List of Wastes Code - contaminated packaging
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); packaging containing residues of or contaminated by
hazardous substances; hazardous waste
Contaminated packaging
Handle contaminated packages in the same way as the substance itself.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (Contains: potassium hydroxide,
sodium hypochlorite, solution ... % Cl active )
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Classification code: C5
Special Provisions: 274
Limited quantity: 1L
Excepted quantity: E2
Transport category: 2
Hazard No: 80
Tunnel restriction code: E
Inland waterways transport (ADN)
14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (Contains: potassium hydroxide,
sodium hypochlorite, solution ... % Cl active )
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Classification code: C5
Special Provisions: 274
Limited quantity: 1L
Excepted quantity: E2
Marine transport (IMDG)

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14.1. UN number: UN 1719

14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S .(contains: Potassiumhydroxide,
Sodium Hypochlorite solution)
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Marine pollutant: YES

Special Provisions: 274
Limited quantity: 1L
Excepted quantity: E2
EmS: F-A, S-B
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1719
14.2. UN proper shipping name: CAUSTIC ALKALI LIQUID, N.O.S. (contains: Potassiumhydroxide,
Sodium Hypochlorite solution)
14.3. Transport hazard class(es): 8
14.4. Packing group: II
Hazard label: 8

Special Provisions: A3 A803

Limited quantity Passenger: 0.5 L
Passenger LQ: Y840
Excepted quantity: E2
IATA-packing instructions - Passenger: 851
IATA-max. quantity - Passenger: 1L
IATA-packing instructions - Cargo: 855
IATA-max. quantity - Cargo: 30 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: Yes

Danger releasing substance: Sodium Hypochlorite

14.6. Special precautions for user
Refer to section 6-8
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
No information available.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 3

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HYLINE HLU-31
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2010/75/EU (VOC): No information available.

2004/42/EC (VOC): No information available.
Information according to 2012/18/EU E1 Hazardous to the Aquatic Environment
(SEVESO III):
Additional information
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (amended by Regulation (EU) No 2020/878)
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
REACH 1907/2006 Appendix XVII, No (mixture): 3
National regulatory information
Employment restrictions: Observe restrictions to employment for juveniles according to the 'juvenile
work protection guideline' (94/33/EC).
Water hazard class (D): 2 - obviously hazardous to water
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:
potassium hydroxide; caustic potash
Silicic acid, potassium salt MR >3,2
2-phosphonobutane-1,2,4-tricarboxylic acid
Sodium Hypochlorite

SECTION 16: Other information

Changes
Rev. 1,0: 29.02.2012
Rev. 1,01: 02.05.2012
Rev. 1,02: 08.05.2102
Rev. 1,03: 14.08.2012
Rev. 1,10: 16.06.2016 ; Changes in chapter: 1-16
Rev. 2,00; 04.10.2018; ; Changes in chapter: 1-16
Rev. 2,10; 06.03.2020; ; Changes in chapter: 14.5
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route ( European Agreement
concerning the International Carriage of Dangerous Goods by Road)
CAS Chemical Abstracts Service
CLP: Classification, Labelling and Packaging of substances and mixtures
DNEL: Derived No Effect Level
d: day(s)
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European LIst of Notified Chemical Substances
ECHA: European Chemicals Agency
EWC: European Waste Catalogue
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
h: hour
LOAEL: Lowest observed adverse effect level
LOAEC: Lowest observed adverse effect concentration
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent

Revision No: 2,1 GB - EN Print date: 03.03.2021

 HOBART GmbH
Safety Data Sheet

according to Regulation (EC) No 1907/2006

HYLINE HLU-31
Revision date: 06.03.2020 Product code: Page 14 of 14

NOAEL: No observed adverse effect level

NOAEC: No observed adverse effect concentration
NLP: No-Longer Polymers
N/A: not applicable
OECD: Organisation for Economic Co-operation and Development
PNEC: predicted no effect concentration
PBT: Persistent bioaccumulative toxic
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de
fer (Regulations Concerning the International Transport of Dangerous Goods by Rail )
REACH: Registration, Evaluation, Authorisation of Chemicals
SVHC: substance of very high concern
TRGS: Technische Regeln für Gefahrstoffe
UN: United Nations
VOC: Volatile Organic Compounds
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification Classification procedure
Met. Corr. 1; H290 On basis of test data and / or calculated and / or estimated.
Skin Corr. 1; H314 Calculation method
Eye Dam. 1; H318 Calculation method
Aquatic Acute 1; H400 Calculation method
Aquatic Chronic 2; H411 Calculation method

Relevant H and EUH statements (number and full text)

H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
EUH031 Contact with acids liberates toxic gas.
Further Information
Classification according to Regulation (EC) No 1272/2008 [CLP] - Classification procedure:
Health hazards: Calculation method.
Environmental hazards: Calculation method.
Physical hazards: On basis of test data and / or calculated and / or estimated.

The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 2,1 GB - EN Print date: 03.03.2021