Clp + Cr+ dt ante We Indicate the coefficient that will be used for Cr;0,* in this reaction: qalen 0-4 Ke “4 aie Certs pony Seow yal 2 2 beHl4Hts Cr,02 —DEr3*+ THO Se ‘ ie 5 a 1 Add evening oe . 7 Ze yt 29,3 a ba > between Ait «Cr Ober CC, * Dee" THO15. Consider the following statements about chemical reactions based on Collision Theory. Which of the following statements are truc? a 1a. Heating a reaction increases the reaction rate by detreasing the energy in the collisions b. Axfy energy collision will lead to product formation (*«¢2 onenbsten * tury) Adding a catalyst lowers the activation energy of the system, allowing more collisions to have the minimum energy needed 4. The higher the temperature of a system, the less energy in collisions 4T~ TE €. NG specific orientation is needed for a reaction to be successful 16, Consider the fictional reaction A + B —» F + G which is catalyzed by reagent C. The rate of this reaction was monitored by looking at the disappearance of B under several as different experimental setups at 298 K. Find rote HAT OME TA] [6] [Cl Rate of disappearance of B| (a ]" exp 3+ 4 Experiment jaye - 900874 (M) (M) (M) (M/s) (iF) © Fo0s050e 1 0.3 0.0501 0.000101 L ae 3 be 2 04 0.0502 0.00027 Bae el. s B 0.4 0.050.05 0,0000674 a | 03 0.05005 0.000506 (Shot = Rest IS. 03 0. Ss 0.0000506 F Ros Step 1:A+C—D cater LCAITC) ~ Step2:D>E+C rater CD) mrik Steg 4 is Soak tg, then gestiBe! Step 3:E+BF+G m<=F(E]C6} zt Fote= KTAJEC] Given the previous information, which of the following situations would lead to a plausible reaction mechanism? a, Step 3 as the rate determining step. All other steps are fast steps. b. Step 3.as the rate determining step. Step 2 is a fast equilibrium step while step 1 is a fast step. c. Step 2 as the rate determining step. All other steps are fast steps. Step 1 as the rate determining step. All other steps are fast steps. . None of the above44 of [AIphas reacted yatage -Vtt ln TAle (st of ! £ : 17. A first order reaction, where [A], = 1.2 M, is 65.3 % complete in 389 s. How long does it take for the same reaction to go from 1.2 M to 88.6 % completion? Naeats 097.76 AFA Oi 4.3805 bea Aw hapa ide b. 110.48 (ATE LU that reaitad ce. 369.04 (A212 - (653. 1,2) =0.416 ‘ Q 798.10 Vn Gave) = E896) #1 U2 7 BB. ea a at EgReRe in('39) =-banmt* (Aas 1.2 C12) = OIE MI Cee qABIO S ) 18. Consider the molecule represented by the following Newman Projection: math! Isopropyl. H ve ae H isopropyl Lage | \ sg Wm \ ches: osteo enee How many stereocenters are found in this molecule? @ ba 2) 3 4 Ss geo 19. Consider the reaction of 3-bromohexane with OH" where the stereocenter exists in the "R" conformation. Which of the following statements is true? a. Inan mechanism, the bromine will leave on it's own in the first step b. ‘The hybridization ofthe oxygen atom chiyiges from one hybridization in the reactants to another hybridization in the products $3 he whole Hine ©) the alcohol product has the "S" conformation atthe stereacenter the reaction was second order 4. A 50/50% mixture of the "R" and "S” stereocenter will be found ifthe reaction follows an $2 mechanism = ©. An Syl mechanism will be a dite step process : S-bromelwvane 2G,20. Consider the ion O,* and determine which of the following statements are true: a. The bond order for this ionishO25 ay b. The electrons in the P pi orbital will be the lowest energy electrons in the ion ¢. There are no unpaired electrons in the MO diagram of this ion > 4. Allelectrons in this ion are paired © This ion will weakly interact with a magnetic field - ae Berea ai de Os has 26) -] = MN vem th go: Staats’, 8 im GOOD LUCK ON THE FINAL EVERYONE!!!