ection I: Multiple Choice
S
For questions 1-5, determine if the following statements areA) TrueorB) False.
1. The equilibrium constant increases if the concentration of one of the reactants is
increased.
2. At chemical equilibrium, Keq is always equal to 1.
3. An increase in pressure with no change in volume causes the reaction to shift right.
N2( g) + 3 Br2(l) ⇌ 2 NBr3 (s)
4. In an exothermic reaction, heating the reaction causes it to shift left.
5. The correct chemical name for ZnO is zinc II oxide.
6. For this unbalanced reaction, 59.78 g of Glucose is used. Calculate the percent yield if the
reaction goes to completion with an excess of Oxygen if 32.6 mL of water is recovered,
with no water present initially. Keep three significant figures for your answer.
C6H
12O6 + O2 → CO2 + H2O
a. 90.9 %
b. 91%
c. 18.3%
d. 0.18%
7. In which direction will this reaction proceed if there are 0.5M of N2, 3.0M of H2, and
0.73M of NH3 given that the Keq for this reactionis 2.
N2 + 3 H2 ↔ 2NH3
a. Towards the products
b. Towards the reactants
c. No shift, the system will remain at those concentrations in equilibrium.
d. Answer cannot be determined without additional information
8. Given this titration curve, what is Keq?
a . 1 * 107
b. 1 * 10-7
c. 1 * 10-8
d. 1 * 108
9. What type is the following reaction?
NaI → Na+ + I-
a. Decomposition Reaction
b. Single Replacement Reaction
c. Double Replacement Reaction
d. Synthesis Reaction
10.What are the respective integer coefficients for the following chemical reaction.
C7H
6O2 + O2 → CO2 + H2O
A. 1, 7.5, 7, 3
B. 1, 7, 7, 3
C. 4, 30, 14, 5
D. 2, 15, 14, 6
11.What description belowbestfits the term of solubility?
a. The amount of solvent that can be dissolved in a given volume of solute
b. The ability for a substance to undergo a displacement reaction in a given solution
c. The amount of a solvent that is lost when a compound breaks apart
d. The ability for a substance to be dissolved in a given solvent
12.Determine the net ionic equation for the chemical reaction between magnesium
phosphate and water to produce magnesium chloride and phosphoric acid.
Mg3(PO4) 2 (s) + 6 HCl (aq) → 3 MgCl2( aq) +2 H3PO4(aq)
a. Mg3(PO4)2 (s) + 6 H+( aq) → 3 Mg2+(aq) +2 H3PO4( aq)
b. Mg3(PO4)2 (s) + 6 H+( aq) + 6 Cl- (aq) → 3 Mg2+(aq)+2 H3P O4(aq)
c. Mg3(PO4)2 (s) + 6 H (aq) + 6 Cl (aq) → 3 Mg (aq)+ 6 H (aq) +2 PO43 -(aq)
+ - 2+ +
d. Mg3(PO4)2 (s) → 3 Mg2+(aq) + 2 PO43-(aq)
Using the reaction below, determine if the following scenarios would shift the chemical reaction
a) left, b) right or c) have no effect for questions 13-15.
NH4Cl (s) ⇌ NH3 (g) + HCl (g) ΔH° = 176 KJ/mol
13.Increasing the volume
14.Removing NH3
15.Increasing the temperature
16.Bromothymol blue is an acid and base indicator with a pKa of 6.8. At around what pH
will bromothymol blue undergo a color change during an acid and base titration?
a. 2
b. 5
c. 7
d. 9
17.In which substance does phosphorus have the lowest oxidation state?
a. PF3
b. H3PO4
c. Ca3P2
d. PO43 -
18.Given the following reaction, identify the reducing and oxidizing agent, respectively.
8 NH3(g) + 6 NO2 → 7 N2(g) + 12 H2O (l)
a. NH3 ; NO2
b. NO2 ; NH3
c. NH3 ; N2
d. NO2 ; N2
19.When carbon dioxide is bubbled through distilled water at 25 degrees Celsius, which of
the following is most likely to occur?
a. Solid carbon will precipitate
b. The water will boil
c. The pH of the solution will decrease
d. Methane gas will be produced
20.Which of the following statements is true?
a. Keq is independent of the starting concentration ofthe reactants and products
b. Keq only changes with temperature
c. Keq is dependent on the final concentration of thereactants and products
d. None of the above statement is true
21.Given the following equilibrium reaction, determine the equilibrium concentration of
PCl3 if the initial concentration of PCl5 is 1.00M and the Keq is 1.20.
PCl5(g) ⇌ PCl3(g) + Cl2( g)
a. 0.987 M
b. 0.789 M
c. 1.013 M
d. 0.927 M
22.In a titration experiment, it was determined that a 80.0 mL sample of HNO3 required 94.0
mL of 0.90 M NaOH to reach the equivalence point. Calculate the molarity of HNO3.
a. 0.77 M
b. 1.06 M
c. 0.83 M
d. 1.33 M
23.Which titration curve corresponds to an initial pH of 9.9 and an equivalence point at pH =
3.7?
a. A strong base to which a weak acid is added
b. A weak acid to which a weak base is added
c. A strong base to which a strong acid is added
d. A weak base to which a strong acid is added
24.Which of the following is a characteristic associated with base?
a. React with metal to produce hydrogen gas
b. Donate an unshared electron pair
c. It always contain an hydroxide ion
d. Formed by reacting a nonmetal oxide and water
25.A 1.3 M solution of the weak acid HCN has a pH of 4.56, what is its acid dissociation
constant?
a. 2.75E-5
b. 7.50E-10
c. 5.83E-10
d. 5.38E-5
26.If 48.6 grams of magnesium are placed in a container with 72 grams of oxygen gas, what
is the mass of MgO(s) produced?
Mg(s) + O2(g)→ MgO(s)
a. 80.6 g
b. 181.35 g
c. 90.7 g
d. 85.2 g
Consider the equilibrium reaction below for questions 27-28.
2 HX (g) ⇌ H2 (g) + X2 (g)
27.Suppose a 5.70 mol sample of HX is placed in a 1.00 L vessel at 481°C, and the reaction
reaches an equilibrium where HX decomposes to form 0.451 mol H2 and 0.451 mol X2.
Determine the equilibrium constant for this reaction at the given temperature.
a. 113
b. 160
c. 135
d. The answer cannot be determined without knowing the concentration of HX
28.Consider the reaction below. The initial concentration of HX gas is 0.75 M and the
equilibrium concentration of X gas is 0.300 M. What would be the equilibrium
concentration of HX gas?
a. 0.85 M
b. 0.30 M
c. 0.15 M
d. 0.75M
Use the following to answer questions 29-34.
or the following reaction, write how each change will affect the indicated quantity, assuming a
F
container of fixed size unless specified otherwise. Write A (increase), B (decrease), or C (no
change). For a chemical added, write how it would respond AFTER the addition.
X2 (g) + M2(g) ⇌ 2XM(g) ΔHº = -516.8 kJ/mol
2 9.How would M2 change if the pressure is increased andvolume decreased?
30.How would M2change when some HBr is added?
31.How would X2 change when some of it is removed?
32.How would the K value change when some X2 was added?
33.How would the K value change when the temperature is increased?
34.How would XM change when some of it is removed?
