Sec: JR.

IIT _*CO-SC(MODEL-B) Date: 29-12-2024

Time: 3 Hrs Max. Marks: 180
29-12-2024_JR.IIT_STAR CO-SC(MODEL-B) _JEE ADV_WAT-36_SYLLABUS
MATHEMATICS: PRESENT WEEK (80%): CIRCLE: Equation of Circles (Various forms), Secant,
Tangent, Normal, Chord of Circle, Chord of contact, Chord whose midpoint is
given
PREVIOUS WEEK (20%): 3D-GEOMETRY-II: Equation of Plane, Distance of
point from plane, angle between two planes, Image of point and line with
respect to plane
PHYSICS: PRESENT WEEK (80%): ELECTROSTATICS-IV: Conductors and their
properties, Conducting spheres, Induced charges, Energy density, Electrostatic
pressure, Self energy of bodies with spherical charge distribution.
PREVIOUS WEEK (20%): ELECTROSTATICS-III: Electric potential and
potential energy, Relation between field and potential, Conservation of energy,
Potential due to various charge distributions, Equipotential lines/surfaces,
Complete eletric dipole. (Exclude: Conductors and their properties,
Electrostatic pressure, Electrostatic self- energy)
CHEMISTRY: PRESENT WEEK (80%): ALCOHOLS :Preparation of alcohols from alkene, akyl
halides, amines, aldehydes, ketones and carboxylic acid and derivatives,
Physical propertties, reactions: esterification, dehydration, with metals,
conversion into alkyl chlorides, oxidation into aldehyde, ketones and carboxylic
acids, Lucas test, victor meyer test (Exclude:MPV reduction, exceptions of LAH
& SBH, swern oxidation) GLYCOL &GLYCEROL:Preparation, reaction with
conc. HI, PI3, HIO4, glycerol with oxalic acid, pinacol pinacolone
rearrangement
PREVIOUS WEEK (20%): ARYL HALIDES :Preparation using EAS, Sandmayer
reaction, Mechanism of SNAr reactions and EAS Reactions chlorobenzene,
Fittig, Wurtz-Fittig (Exclude:Benzyne mechanism & cine substitution)
GRIGNARD REAGENT: Preparation and properties of Grignard reagent,
preparation and properties of Grignard reagent & Organo lithium
Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :19 – 24) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 33-36) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

CHEMISTRY:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N:37 – 42) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec –III(Q.N : 51-54) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
MATHEMATICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are)
correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
a
1. If y = 2x + K is a diameter to the circle 2(x 2  y 2 )  3x  4y  1  0 and K equal to
b
then (where a, b  N, a & b are coprime number to each other)
(A) a – b = 0 (B) |a – b| = 1 (C) a + b = 3 (D) a × b = 2
(x  1)2 (y  2)2 a
2. If the equation   1 represents a circle and   (where a, b  N, a
3 4 b
& b are coprime number to each other) then
(A) a + b = 7 (B) b – a = 1 (C) 2a – b = 2 (D) a × b = 12
3. Equation of a circle concentric with the circle 2x 2  2y 2  6x  8y  1  0 and of

double its area is 4x 2  4y 2  ax  by  c  0 then

(A) a = 12 (B) b = 16 (C) c = -21 (D) a is an even number
4. The equations of the tangents to the circle x 2  y 2  6x  4y  12  0 which are

parallel to the line 4x + 3y + 5 = 0

(A) 4x + 3y - 31 = 0 (B) 4x + 3y – 9 = 0
(C) 4x + 3y + 19 = 0 (D) 4x + 3y – 10 = 0
5. Let x, y be real variable satisfying the x 2  y 2  8x  10y  40  0 .

a  max  (x  2)2  (y  3)2  and b  min  (x  2)  (y  3)  , then

2 2

(A) a + b = 18 (B) a  b  4 2

(C) a  b  4 2 (D) a.b = 73

6. Point M moved on the circle (x  4)2  (y  8)2  20 . Then it broke away from it and
moving along a tangent to the circle, cuts the x-axis at the point (-2, 0). The co-
ordinates of point on the circle at which the moving point broke away is

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
 3 46   2 44 
(A)   ,  (B)   , 
 5 5   5 5 
(C) (6,4) (D) (3, 5)

SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. The co-ordinate of the point on the circle x 2  y 2  12x  4y  30  0 , which is farthest
from the origin are (, ) then   3 = ______.

8. The equation to a circle passing through the origin and cutting of intercepts each
equal to + 5 of the axes is x 2  y 2  ax  by  c  0 then a – 2b + c = _______.

9. The circle x 2  y 2  4x  7y  12  0 cuts an intercept on y-axis is equal to ________.

10. The Cartesian equation of the curve x = 7 + 4 cos  , y = -3 + 4 sin  is
2x 2  2y 2  ax  by  c  0 then a + b + 2c = _______.

11. If the equation of chord of contact from (h, k) to x 2  y 2  2 is 2x  11y  2  0 then
h + k = ________.
12. If equation of chord of x 2  y 2  6x  10y  9  0 whose mid pt is (2, -4) is ax + by + 6
= 0 then a + b = ______.

13. If the distance between the parallel planes x + 2y – 2z + 1 = 0 and 2x + 4y – 4z + 5 =

0 is  then value of 4  ______.
x 1 y  2 z  3
14. If the image of the line   in the plane 3x – 3y + 10z – 26 = 0 is
9 1 3
x  (5 / 2) y  (1/ 2) z  2
  then b – 3c = ______.
9 b c

SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 15 to 16:
Locus of point of intersection of perpendicular tangents to a circle is called director
circle with respect to given circle.

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
15. If tangents drown from (0, 0) to circle x 2  y 2  2kx  2ry  r 2  0 are perpendicular
then
(A) k = 0 (B) r2  k 2  0 (C) k 2  r2  0 (D) none of these
16. Consider a circle c1 : x 2  y 2  4 . The locus of point of intersection of perpendicular

tangents to c1 is c2 and the locus of point of intersection of perpendicular tangents

to c2 is c3 then area of c3


(A) 4 (B)16 (C) (D) none of these
4
Paragraph for Question Nos. 17 to 18:
Let the intersecting planes be P1  0 and P2  0 then all the planes passing through

line of intersection of above planes are called family of planes with respect to above
planes and their equation can be given as P1   P2  0;   R

17. The equation of the plane which contains the line of intersection of the planes
  ˆ ˆ ˆ
r.(iˆ  2ˆj  3k)
ˆ  4  0 and r.(2i  j  k)  5  0 and which is perpendicular to the plane

r.(5iˆ  3ˆj  6k)
ˆ  8  0.

(A) 33x + 45y + 50z – 41 = 0 (B) 33x - 45y + 50z – 41 = 0

(C) 33x - 45y - 50z – 41 = 0 (D) 33x + 45y - 50z – 41 = 0
18. The equation of a plane containing the line of intersection of the planes x + y + z – 6
= 0 and 2x + 3y + 4z + 5 = 0 and passing through (1, 1, 1).

(A) 20x - 23y + 26z – 69 = 0 (B) 20x + 23y - 26z – 69 = 0

(C) 20x - 23y - 26z – 69 = 0 (D) 20x + 23y + 26z – 69 = 0

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are)
correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
19. Two concentric shells have radii R and 2R, charges q A and q B and potentials 2V

3V
and respectively. Now shell B is earthed by closing the switch S and let charges
2
on the shells changed to q A ' and q B ' . Then we have:

(A) q A /q B  1/2

(B) q A '/ q B '  1

(C) Potential of A after earthing becomes (3/2)V

(D) Potential difference between A and B after earthing becomes V/2

20. Two concentric spherical shells have charges + q and – q as shown in figure. Which
of the statement given below is/are correct :

(A) At A electric field is zero, but electric potential is non-zero

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
(B) At B electric field and electric potential both are non-zero
(C) At C electric field is zero but electric potential is non-zero
(D) At C electric field and electric potential both are zero
21. An ellipsoidal cavity is carved within a perfect conductor as shown in figure. A
positive charge q is placed at the centre of the cavity. The points A and B are on the
cavity surface as shown in the figure. Then which of the following is/are correct :

(A) Electric field near A in the cavity = Electric field near B in the cavity
(B) Charge density at A = Charge density at B
(C) Potential at A = Potential at B
(D) Total electric field flux through the surface of the cavity is q / 0

22. Two non-conducting spheres of radii R1 and R 2 carrying uniform volume charge

densities  and  respectively, are placed such that they partially overlap as
shown in the figure. At all points in the overlapping region which of the statements
is/are correct about the electric field and electric potential :

(A) The electric field is zero

(B) The electric potential is constant
(C) The electric field is constant in magnitude
(D) The electric field has same direction
23. An uncharged conducting ball B lies inside a charged conductor A as shown in
figure. B is isolated from A.

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
(A) When B touches the inner surface of A, then potential of B will change.
(B) No net charge is inside the cavity.
(C) There is an induced charge on B.
(D) Potentials of A and B are same.
24. Two conducting plates M and N, each having large surface area A (on one side), are
placed parallel to each other as shown in the figure. The plate M is given charge Q1
and N, charge Q2 ( Q1 ) . Then

(A) electric field at point A is (Q1  Q2 )/2A0 toward right

(B) electric field at point B is (Q1  Q2 )/2A0 toward right

(C) electric potential of N is greater than M

(D) all of the above

SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
25. Figure shows two conducting thin concentric shells of radii r and 3r. The outer shell
carries charge q and the inner shell is neutral. The amount of charge that flows
from the inner shell to the earth after the key K is closed is equal to (1/ n)th of the
charge on the outer shell. What is the value of n?

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
26. A small sphere of mass m = 0.5 kg carrying a positive charge q = 110 C is
connected with a light, flexible and inextensible string of length r = 60 cm and
whirled in a vertical circle. If a vertically upward electric field of strength
E  105 NC 1 exists in the space, calculate minimum velocity of sphere (in m/s)

required at highest point so that it may just complete the circle. (g  10ms 2 ) .

27. An electric field is expressed as E  2iˆ  3ˆj . Find the potential difference (VA  VB )

between two points A and B whose position vectors are given by r A  ˆi  2ˆj and

r B  2iˆ  ˆj  3kˆ . (in Volts)

28. As shown in figure, a dust particle with mass m  5.0  10 9 kg and charge

q 0  2.0nC starts from rest at point a and moves in a straight line to point b. What

is its speed v at point b? (in m/s) (round off to nearest integer)

29. A 100 eV electron is projected directly toward a large metal plate that has surface
charge density of 2.0  10 6 Cm2 . From what distance must the electron be
projected, if it is to just fail to strike that plate? (in mm)

30. A metal sphere of radius 10 cm is given a charge of 12C . The force acting on unit

area of its surface due to its own charge is _______  102 N / m2 .

31. The outward pull on a metal plate of an area 0.01m2 having a charge density of
50C / m2 is ______. (in N)

32. A cube of side 10 cm encloses a charge of 0.1C at its centre. What is number of
lines of force through each face of the cube. (round off to nearest integer)

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 33 to 34:
There are two concentric spherical shell of radii r and 2r . Initially, a charge Q is
given to the inner shell and both the switches are open

33. If switch S1 is closed and then opened, charge on the outer shell will be

(A) Q (B) Q/2 (C) -Q (D) –Q/2

34. Now, S2 is closed and opened. The charge flowing through the switch S2 in the
process is
(A) Q (B) Q/4 (C) Q/2 (D) 2Q/3
Paragraph for Question Nos. 35 to 36:
Three concentric spherical conductors A, B and C of radii R, 2R and 4R respectively.
A and C is shorted and B is uniformly charged.

35. Charge on conductor A is

(A) Q/3 (B) –Q/3 (C) 2Q/3 (D) -2Q/3
36. Potential at A is
(A) Q / 40R (B) Q /160R (C) Q /200R (D) 5Q / 480R

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
CHEMISTRY MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are)
correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
37. Which of the following reactions will yield propan-2-ol?

H CH3 MgBr
(A) H2C  CH  CH3  HOH  (B) CH3  CHO 
HOH


(i) C2H5 MgI Neutral KMnO4

(C) CH2O 
(ii)HOH
 (D) H2C  CH  CH3  

38. A compound ‘X’ undergoes reduction with LiAlH4 to yield ‘Y’. When vapours of ‘Y’ are

passed over freshly reduced copper at 300°C, ‘X’ is formed. What is ‘Y’?

(A) CH3COCH3 (B) CH3CHO (C) CH3CH2OH (D) CH3  O  CH3

39. Re agent
CH3  CH  CH  CH2   Alcohol
CH3

Which is/are true about alcohol and Reagent?

Alcohol Reagent (R)

(A) BH3 / THF,H2O2 / OH

(B) Hg(OAc)2 /NaBH4  H2O

(C) H3O

(D) None of the above

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
40. In the Victor Mayer’s test, the colours given by 1°, 2°, 3° alcohols are respectively:

(A) red (B) colourless (C) blue (D) pink

41. Consider the following reaction

C2H5OH  H2SO4  Pr oduct

Among the following, the compounds can be formed as a product under any
conditions

(A) Ethyl hydrogen sulphate (B) Ethylene

(C) Acetylene (D) Diethyl ether

42. To bring about dehydration of alcohols we can use

(A) Conc. H2SO4 (B) anhydrous Al2O3

(C) ZnO (D)CaO

SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
43. Identify numbers of alcohol those will show rearrangement during dehydration with
concentrate H2SO4 .

44. Find out number of reagents that converts 1° alcohol to aldehyde.

KMnO4 |H | , K 2Cr2O7 |Dil.H2SO4 , Ceric ammonium nitrate

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
45. Consider the given reaction and answer the following questions

How many product will be formed in given reaction (excuding stereo)

46. An unknown compound (A) (molarmass = 180) on acylation gives a product (molar
mass = 390) than find the number of hydroxyl group present in compound (A).

47. For the given reaction

the total number of possible products formed by 3° carbocation of A is

48. How many of the following compounds would give turbidity with lucas reagent
without heating

1) Benzyl alcohol 2) Allyl alcohol

3) Cyclohexanol 4) 2-methyl-2-proponol

5) Neopentanol 6) Phenol

7) O-Cresol 8) Cylopropyl methyl carbionol

9) P-Nitro benzyl alcohol

49. How many moles of Grignard reagent will be required by one mole of given
compound?

50. How many moles of HI reacts with glycerol to give 2-iodopropane.

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 51 to 52:
1, 2-diols are oxidized to ketones or aldehydes by periodic acid HIO4 . Periodic acid

reacts with diol to form a cyclic intermediate. The reaction takes place because
iodine is in a highly positive oxidation state, so it readily accepts electrons. When the
intermediate breaks down, the bond between the two carbons bonded to the OH
groups break.

51.

(A) OH (B)

OH
O O
(C) (D)

H
O

52. HOH2C
C=O
HIO4
CHOH 
(Excess)

CHOH
CH2OH
Which of the following will not form by above reaction?

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Narayana IIT Academy 29-12-2024_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-36_QP

O O
(A) (B) CH3OH (C) CO2 (D)
HCH H  C  OH
Paragraph for Question Nos. 53 to 54:
Carbon-oxygen double bond are easily reduced by NaBH4 or LiAlH4 . The actual

reducing agent in these reduction is hydride ion (H ) .

The metal-hydrogen bond in LiAlH4 is more polar than metal-hydrogen bond in NaBH4 . As a result

LiAlH4 is strong reducing agent than NaBH4 . Esters, carboxylic acids, amides cannot be reduced by

NaBH4 .

53. Find the correct product of the following reaction:

(A) (B)

(C) (D) No reaction

54.

(A) (B) (C) (D)

JR.IIT_*CO-SC Page. No. 15