0% found this document useful (0 votes)
16 views10 pages

1901 - Iit - (Ja) - Nurture - (P#1,2&3) - CT-3 - Answer Keys & HS

The document contains the answer key for the JEE (Advanced) Cumulative Test conducted on January 19, 2025, covering subjects including Physics, Chemistry, and Mathematics. Each section lists questions along with their corresponding correct answers and numerical solutions. The document serves as a reference for evaluating student performance in the test.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
0% found this document useful (0 votes)
16 views10 pages

1901 - Iit - (Ja) - Nurture - (P#1,2&3) - CT-3 - Answer Keys & HS

The document contains the answer key for the JEE (Advanced) Cumulative Test conducted on January 19, 2025, covering subjects including Physics, Chemistry, and Mathematics. Each section lists questions along with their corresponding correct answers and numerical solutions. The document serves as a reference for evaluating student performance in the test.
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

(1103CJA101001240016) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Advanced)


CUMULATIVE TEST
(Academic Session : 2024 - 2025)
19-01-2025

JEE(Main + Advanced) : Nurture (PHASE : 1,2&3)


Test Type : Unit Test # 01
ANSWER KEY PAPER-2
PHYSICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. D A A A D D
Q. 7 8 9 10 11 12
SECTION-I (ii)
A. A,C A,B,D A,C,D A,B,D A,B,D B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 9 2.38 30 2 3.5 2.00

CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. D C B A B C
Q. 7 8 9 10 11 12
SECTION-I (ii)
A. A,B,C,D A,B,C A,B,C A,B,D B,C B,D
Q. 1 2 3 4 5 6
SECTION-II
A. 9.00 5.00 6.00 7.00 6.00 8.00

MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B B D D D A
Q. 7 8 9 10 11 12
SECTION-I (ii)
A. A,D A,B,C B,C B,D B,C,D A,B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 1.00 306.00 7.00 7.00 528.00 5.00

HINT – SHEET

1103CJA101001240016 HS-1/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
PHYSICS 2. Ans ( C )
NH3 + N2H4 mixture
SECTION-I (i)
xmole ymole
4. Ans ( A ) * Sealed container volume = constant
(vr)i = 0 * At 1000 K reactions takes place
In one time period ur is O, thrice (begining, middle 2NH3(g) —→ N2(g) + 3H2(g)
and one PQ and diametucally opposite points. x
x 3x
0
2 2
N2H4(g) —→ N2(g) + 2H2(g)
y
0 y 2y
PHYSICS
* New pressure 4.8 atm
P1 P2
SECTION-II
= volume is constant
n1 T1 n2 T2
6. Ans ( 2.00 ) 0.6
(x + y) (300 K)
=
4.8
(2x + 3y) (1000 k)
F.B.D of 2 kg block 10 8 × (x + y)
=
3 2x + 3y
20x + 30y = 24x + 24y
6y = 4x
3y
x=
2
x
Mole % of NH3 = × 100
x+y
3
When 2 kg block just leaves the contact (original mixture) = × 100 = 60%
5
N=0
20 1
3. Ans ( B )
Kx + 0 = 20 ⇒ x = =m Active methylene compound.
40 2
Applying WET for the whole system 4. Ans ( A )
wg + wsf = Δ k Electron with drawing groups increase the acidity
2
1 1 1 1 of carboxylic acids by stabilizing the conjugate
⇒ 50 × – (40) [( ) − 0] = (5) [V2
2 2 2 2 base through delocalization of the negative charge
– 0] ⇒ V = 2√2 m/s by inductive and/or resonance effects.
The effect of the following groups in increasing
CHEMISTRY acidity order is
SECTION-I (i) P h < I < Br < Cℓ < F < CN < NO2 < CCℓ3 < CF3

1. Ans ( D ) Acidic strength ∝ [H + ] ∝ Ka ∝ 1


pKa

HS-2/10 1103CJA101001240016
Nurture/Phase-1,2&3/19-01-2025/Paper-2
5. Ans ( B ) 11. Ans ( B,C )
2.5 gm impure sample have BOH weak monoacidic
base
Assume moles of BOH present = a
Conc. of BOH = 10a
'X' is polar BOH + HCl → BCl + H2 O
10a 0.5 V
6. Ans ( C ) 10a – 1 × 10a 1
× 10a
Amphibole chain silicate is represented as 5 5
(Si2O5.5)x3x – or (Si4O11)x6x – 8a 2a
Basic Buffer
CHEMISTRY Salt
pH = 14 – pKb
( + log )
Base
SECTION-I (ii)
9 = 14 – pKb – log 1
7. Ans ( A,B,C,D ) pKb = 5 + 2 × 0.3 = 5.6
4
Apply mass conservation, V = 80 ml.
Kb =10 – 5.6
0.8
M = 28.75 × × 1000 = 6.25 moles/litre At equivalent point
80 × 46
M = 28.75 ×
0.8
× 1000 = 10 moles/Kg BOH + HCl → BCl + H2
50 × 46 O ∵ a = 0.5 V
0.5
XC2 H5 OH = = 0.152 a 0.5V a
0.5 + ( 50 )

Conc. BCl = a
18
23
→ Salt hydrolysis
Mass fraction of ethanol = × 100 = 0.315 0.1 + V
73 pH = 7 – pKb – 1 log C
1
8. Ans ( A,B,C ) 2 2
Cr oxidises from +3 to +6 while I reduces from +5 4.5 = 7 – × 5.6 – 1 log a
1
2 2 0.1 + V
to – 1. One I atom gains 6 electrons. 1 a
– 0.3 = log ( )

9. Ans ( A,B,C ) 1
2 0.1 + V
2log ( ) = log ( a ) = a =
1
(A) Δ SXY = SY – SX > 0 2 0.1 + V 0.1 + V 4
SY > SX ⇒ 0.5V × 4 = 0.1 + V
i.e., Y is more disordered than X V = 100 ml of HCl
(B) S is a state function, so it does not depend on 2V = 0.1 + V
type of process. V = 0.1
(C) Δ SXY = – Δ SYX Salt conc. = 0.5 × 0.1 = 0.25 M
Because S is state function 0.1 + 0.1
∴ moles of Base = 0.5 V
Δ SYX = – 10 J/K
= 0.5 × 0.1
10. Ans ( A,B,D ) = 0.05 moles
(i) I is 1° Amine and II is 2° amine so functional wt = 0.05 × 45 = 2.25
isomers. wt% = 2.25
× 100 = 90%
(ii) Both are metamers as different group around 2° 2.5
amine.
(iii) I, IV are functional isomer
(iv) I & III has difference in chain length.

1103CJA101001240016 HS-3/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
12. Ans ( B,D ) 3. Ans ( 6.00 )
HA A– + H+
t=0 0.2 – 0.1
t = eq 0.2(1 – α ) 0.2 α 0.1 + 0.2 α
[H + ][A− ] 0.2 α (0.1 + 0.2 α)
Ka = = ....(1)
[HA] 0.2 (1 − α)
(0.2α + 0.1) (0.2α)
5 × 10−2 =
0.2 (1 − α)
4 × 10−2 α2 + 2 × 10−2 α
5 × 10−2 =
0.2 (1 − α)
5 × 0.2 (1 - α ) = 4 α 2 + 2 α
1 - α = 4α2 + 2α
CHEMISTRY 4 α 2 + 2x + α - 1 = 0.
SECTION-II 4α2 + 3α - 1 = 0
1. Ans ( 9.00 ) α =
−3 ± √9 + (16)
8
2
α = = 0.25
8
[H+] = 0.2 α + 0.1
= 0.2 × 0.25 + 0.1
= 0.05 + 0.1
=0.15
by multiplying 40 answer is = 0.15 × 40 = 6
4. Ans ( 7.00 )
Aromatic ⇒ a, c, d ⇒ x = 3
Non-aromatic ⇒ b, e, g ⇒ y = 3
2. Ans ( 5.00 ) Anti-aromatic ⇒ f, h ⇒ z = 2
II, III, V, VII, VIII has presence of alpha hydrogen. ∴ x + 2y – z = 3 + 2 × 3 – 2
So, will show tautomerism. =9–2=7

HS-4/10 1103CJA101001240016
Nurture/Phase-1,2&3/19-01-2025/Paper-2
5. Ans ( 6.00 ) MATHEMATICS
SECTION-I (i)

1. Ans ( B )
(x2 + 2)2 – (a + 4) (x2 + 2) (x2 + 1) + (a + 3) (x2 +
1)2 = 0
Divide by (x2 + 1)2 :
2
x2 + 2 x2 + 2
( ) − (a + 4) ( ) +a+3=0
x2 + 1 x2 + 1
2
x +2
let 2 =t
x +1
∴ t2 – (a + 4)t + (a + 3) = 0

6. Ans ( 8.00 ) ⇒t=1;t=a+3


x2 + 2
for t = 1 : = 1 ⇒ x2 + 2 = x2 + 1
x2 +1
Not possible
x2 + 2
for t = a + 3 : =a+3
x2 + 1
⇒ x2 + 2 = x a + 3x + a + 3
2 2

x2( – a – 2) = a + 1
The following values are given in the question: a+1
x2 = ⩾ 0
μ obs = 2D, Xanti = 0.75, so Xgauche = 1 – 0.75 = 0.25 −a − 2
a+1
By using the formula ⇒ mobs = μi Xi

⩽ 0
a+2
μ obs = μ gauche × Xgauche + μ anti × Xanti
2 = μ gauche × 0.25 + 0.75 × 0
2
μ gauche = =8D
0.25 a ∈ ( – 2, – 1]

1103CJA101001240016 HS-5/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
2. Ans ( B ) 4. Ans ( D )
Equation of the line in parametric form is 3z1 + i 2z2 + 2z3
=
x y 4 4
= =r. P = point of intersection of AD & BC
1 √ 5

6 √ 6
Any point on the given line can be taken as
r √ 5
( , r) .
√ 6 √ 6
r √ 5
Now ,if r = OA then the point ( , r)
√ 6 √ 6
will also satisfy the equation x = 1.
⇒ r = √6 = OA1
3
Similarly OA2 =2 6. Hence √ AD = 1 ⇒ DP =
4
OA12 + OA22 + … … .. + OA32 + … … … ..+OAn2 9 √7 √7
BP = √1 − = ⇒ BC =
= 6 + 22 6 + 32 6+. . . . . . . . . . +n2 6
√ √ √ √ 16 4 2
1
n(n + 1)(2n + 1) area of Quad. ABCD = . AD × BC
=6 ( ) 2
6 1 √7 √7

= 2n3 + 3n2 + n = × 1 × =
2 2 4
Hence (B) is the correct answer. 5. Ans ( D )
3. Ans ( D ) Let point of intersection of tangents at A and B be
Let given curves be S = 0 & S' = 0 the point P(h,k) , then the equation of AB is
So, a circle passing through their points of xh yk
+ =1 .......(1)
intersection can be S' + λ S = 0 4 1
x2 y 2
⇒ (a' + λ a)x2 + (a' + a – b + λ b)y2 + ( λ – 1)2hxy Homogenizing the given ellipse
4
+
1
= 1 using
– 2(g' + λ g)x – 2(ƒ' + λ ƒ)y + c(1 + λ ) = 0 equation (1)
2
So, λ = 1 x2 y 2 xh yk
⇒ + =( + )
Now, required circle is 4 1 4 1
(a + a')x2 + (a + a')y2 – 2x(g + g') – 2y(ƒ + ƒ') + 2c h2 1 2hk
⇒ x2 ( − ) + y 2 (k2 − 1) + xy = 0
16 4 4
=0
h2 − 4 hk
So, point P is the center of this circle. ⇒ x2 ( 2 2
) + y (k − 1) + ( ) xy = 0
16 2
Hence, PA = PB = PC = PD = r ......(2)
Given equation of pair of straight lines
x2 + 4y2 + λ xy = 0 and above equation (2) should
represent same line. Hence
h2 − 4 k2 − 1 hk
= =
16 4 2λ
On eleminating λ , relation obtained in h and k is
h2 – 4 = 4(k2 – 1) h2 – 4k2 = 0
Thus desired locus is x2 – 4y2 = 0

HS-6/10 1103CJA101001240016
Nurture/Phase-1,2&3/19-01-2025/Paper-2
6. Ans ( A ) 9. Ans ( B,C )
Let M be 18 cos θ, 8 sin θ . As shortest
(√ √ ) |Z| = 1 ⇒ z = cos θ + i sin θ
distance lies along common normal |z2 + z – 1|2 = (cos 2 θ + cos θ – 1)2 + (sin 2 θ +
Given line will be parallel to the tangent at M sin θ )2
x cos θ y sin θ = 3 + 2 cos θ – 2 cos 2 θ – 2 cos θ
+ =1 is parallel to
√ 18 √ 8 = 3 – 2 cos 2 θ
2x – 3y + 25 = 0 ⇒ |z2 + z – 1| will be maximum if
√ 8 cos θ 2
⇒− = ⇒ tan θ = −1 cos 2 θ = – 1 and minimum when cos 2 θ = 1.
3
18 sin θ
10. Ans ( B,D )


⇒θ= ⇒ po int M is (−3, 2)
4 As tangents are perpendicular to each other and its
7 4
points of intersections P ( ,− ) lies on
5 5
directrix. AB is focal chord.
MATHEMATICS
Equation of AB is x – y = 4, as focus is ( α , β ) so
SECTION-I (ii) α−β=4 ⇒ β=α−4
7. Ans ( A,D ) Now ∠ ASP = 90°
3
An = an + bn + cn 2 4
− −α+4
−2 − α + 4 5
Bn = (An − An−1 ) − (An−1 − An−2 ) ⇒ ⋅
  2−α 7
quadratic quadratic −α
5
⇒ Bn is linear in n. 16
n
−α
2−α 5
Cn = ∑ [(Br − Br−1 ) − (Br−1 − Br−2 ) ] ⇒ ⋅ = −1
  2−α 7
r=3
const co nst
−α

5
16 7 23
=0 ⇒ −α=α− ; α=
Cn = 0 5 5 10
23 17
10
10 × 11 ⇒ Focus is ( , − )
∑ Cr + r = − (1 + 2) = 52 10 10
r=3
2 3 √2 27√2
Also, ℓ1 = AS = , ℓ2 = BS =
8. Ans ( A,B,C ) 1 1 1
10
27√2
10
27√2
Sides of rhombus are parallel to the line pair 7x2 – = +
ℓ1 ℓ2
⇒ a=
100
⇒ 4a =
25
a
8xy + y2 = 0.
So, its diagonals are parallel to the angle bisectors
x2 − y 2 xy
⇒ 2x2 – 2y2 + 3xy = 0
=
6 −4
y 2 y
⇒ 2( ) − 3 ( ) − 2 = 0
x x
y 1
⇒ = 2, − = Slope of diagonals
x 2
So, equation of diagonal can be
y – 2 = 2(x – 1) or y – 2 = − 1 (x – 1)
2
5
Hence, point P can be (0, 0) or ( 0, )
2

1103CJA101001240016 HS-7/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
11. Ans ( B,C,D ) 12. Ans ( A,B,C )
Given parabola
y = x2 + ax + 1
a 2 a2
⇒ y = (x + ) + 1 −
2 4
As no any point of the parabola lies below x axis,
a2
1− ⩾ 0 Hyperbola and ellipse will be confocal with focus
4
a2 ±2√2, 0)
∴ ⩽ 1 ⇒∴ a ∈ [−2, 2] (

4 2 √2
No. of integral values of a = 5 1 3
1 − e21 = ⇒ e1 = ⇒ e2 =
9 3 2 √2
The tangent to y = x2 + ax + 1 at (0,1) is T =0
x2 y2 8
y+1 x+0 ∴ − =1⇒A=
⇒ = x ⋅ 0 + a( ) + 1 A2 B2 3
2 2 64 9 8
2 2
⇒ y + 1 = ax + 2 ⇒ y = ax + 1 B = ( − 1) ⇒ B =
9 8 9
This is tangent to x2 + y 2 = r2 also 9x2 9y 2
− =1
1 64 8
∴ 1 2 = r 2 ( a2 + 1 ) ⇒ r 2 =
a2 + 1
1
∴ for maximum value of a, r2 =
4+1 MATHEMATICS
1
∴ r= SECTION-II
√ 5
for maximum value of radius r,
2
must be a2 1. Ans ( 1.00 )
minimum i.e. a = 0, for this ∣
∣ z12 − z22 ∣∣ = ∣∣¯z21 + ¯z22 − 2z¯1 ¯z2 ∣∣
a = slope of tangent = 0 ∣
∣z12 − z22 ∣∣ = ∣∣z12 + z22 − 2z1 z2 ∣∣
Also, area enclosed by the tangent |z1 + z2 | |z1 − z2 | = |z1 − z2 | |z1 − z2 |
y = ax + 1 with coordinate axes ⇒ |z1 + z2| = |z1 – z2|
1 ∣ 1∣ 1
= ⋅ 1 ⋅ ∣− ∣ = ⇒ z1 ⊥ z2
2 ∣ a ∣ 2 |a|
z1 π
⇒ arg( ) = 2nπ +
z2 2
π π 3π
⇒− , ,
2 2 2
minimum value of |a + b| = 1, (a = – 1 & b = 2)
∴ Minimum area (when |a| = 2)
1 1
= =
2×2 4

HS-8/10 1103CJA101001240016
Nurture/Phase-1,2&3/19-01-2025/Paper-2
2. Ans ( 306.00 ) 3. Ans ( 7.00 )
x2 y2 Area of trapezium F1MNF2
Hn ⇒ − =1
1+n 3+n 1
Δ = (MF1 + NF2 ) MN also MF1.NF2 =
b 2 3 + n √ 2n + 4 2
e = √1 +
a 2
= √1 +
1+n
=
n+1 b2 (MF1 – NF2)2 + MN2 = (F1F2)2
2n + 4 ⇒ (MF1 +
e=√
n+1 NF2)2 –
n = 48 (smallest even value for which e ∈ Q)
4MF1.NF2 +
10
e= MN2 = (F1F2)2
7
a2 = n + 1 , b2 = n + 3
= 49 = 51
2b2
1 = length of LR =
a 2Δ
2
51 ⇒( − 4b2 + MN 2 = 4a2 e2
L=2⋅ MN
)

7
102 4Δ2
1= + MN 2 = 4 (a2 e2 + b2 ) = 4 (a2 e2 + a2 − a2 e2 )
7 MN 2
21ℓ = 306 ∵ MN is chord of auxiliary circle
⇒ MN = 2√a2 − p2
4Δ2
+ 4a2 − 4p2 = 4a2
MN 2
Δ
⇒ =p
MN
Now p = distance of MN : √ 3x − 2y + 4 = 0 from
(0,0)
4 16ℓ2
⇒p= ⇒ =7
√ 7 Δ2

1103CJA101001240016 HS-9/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
4. Ans ( 7.00 ) 5. Ans ( 528.00 )
a 0 = 0, a1 = 0
an+2 = 3 an+1 – 2 an+1 : n ≥ 0
an+2 – an+1 = 2 (an+1 – an) + 1
n = 0 a2 – a1 = 2 (a1 – a0) + 1
n = 1 a3 – a2 = 2 (a2 – a1) + 1
n = 2 a4 – a3 = 2 (a3 – a2) + 1
n = n an+2 – an+1 = 2 (an+1 – an) + 1
(an+2 – a1) – 2 (an+1 – a0) – (n + 1) = 0
an+2 = 2an+1 + (n +1)
n→n–2
an – 2an – 1 = n – 1
Now a25a23 – 2a25a22 – 2a23a24+4a22a24
= (a25 – 2a24) (a23 – 2a22) = (24) (22) = 528
Let equation of transverse common tangent L with 6. Ans ( 5.00 )
positive slope is Let f(x) = px2 – qx +r
(y − 5) = 2√2 (x − 1) It has two distinct real roots lying between 0 and 1.
4 √2 f(x) can be written as, f(x) = p(x – α )(x – β ),
[As, slope ⇒ tan θ = = 2 2] √
2 where α and β are the roots of the equation.
Suppose equation of tangent L' which is parallel to
From the graph it can be observed that f(0)f (1) > 0
L is
As p, q and r are integers f(0)f(l) > 1
2 √2 x − y = λ
f(0) = p α β

2√2 (1) − 8 − λ ∣

So, ∣

=1 ∣
∣ f(l) = p(l – α )(1 – β )
∣ 8+1 √ ∣
⇒ p2( α )(l – α )( β )(1 – β ) > 1 > 0 → (1)
⇒ λ = 2√2 − 11, 2√2 − 5
Using AM ³ GM, we get
∴ Equation of L' is
1
2√2x − y + (11 − 2√2) = 0 α+1−α+β+1−β
> (αβ (1 − α) (1 − β)) 4
So, a = 2 ; b = 1; c = 11 4
AM and GM cannot be equal because the equation
a+b+c 14
gives = =7 has distinct roots
2 2
p2
> p2 (αβ (1 − α) (1 − β))
16
p2
⇒ >1
16
⇒p>4
Therefore the minimum value of p is 5.

HS-10/10 1103CJA101001240016

You might also like