1901 - Iit - (Ja) - Nurture - (P#1,2&3) - CT-3 - Answer Keys & HS
1901 - Iit - (Ja) - Nurture - (P#1,2&3) - CT-3 - Answer Keys & HS
CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. D C B A B C
Q. 7 8 9 10 11 12
SECTION-I (ii)
A. A,B,C,D A,B,C A,B,C A,B,D B,C B,D
Q. 1 2 3 4 5 6
SECTION-II
A. 9.00 5.00 6.00 7.00 6.00 8.00
MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. B B D D D A
Q. 7 8 9 10 11 12
SECTION-I (ii)
A. A,D A,B,C B,C B,D B,C,D A,B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 1.00 306.00 7.00 7.00 528.00 5.00
HINT – SHEET
1103CJA101001240016 HS-1/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
PHYSICS 2. Ans ( C )
NH3 + N2H4 mixture
SECTION-I (i)
xmole ymole
4. Ans ( A ) * Sealed container volume = constant
(vr)i = 0 * At 1000 K reactions takes place
In one time period ur is O, thrice (begining, middle 2NH3(g) —→ N2(g) + 3H2(g)
and one PQ and diametucally opposite points. x
x 3x
0
2 2
N2H4(g) —→ N2(g) + 2H2(g)
y
0 y 2y
PHYSICS
* New pressure 4.8 atm
P1 P2
SECTION-II
= volume is constant
n1 T1 n2 T2
6. Ans ( 2.00 ) 0.6
(x + y) (300 K)
=
4.8
(2x + 3y) (1000 k)
F.B.D of 2 kg block 10 8 × (x + y)
=
3 2x + 3y
20x + 30y = 24x + 24y
6y = 4x
3y
x=
2
x
Mole % of NH3 = × 100
x+y
3
When 2 kg block just leaves the contact (original mixture) = × 100 = 60%
5
N=0
20 1
3. Ans ( B )
Kx + 0 = 20 ⇒ x = =m Active methylene compound.
40 2
Applying WET for the whole system 4. Ans ( A )
wg + wsf = Δ k Electron with drawing groups increase the acidity
2
1 1 1 1 of carboxylic acids by stabilizing the conjugate
⇒ 50 × – (40) [( ) − 0] = (5) [V2
2 2 2 2 base through delocalization of the negative charge
– 0] ⇒ V = 2√2 m/s by inductive and/or resonance effects.
The effect of the following groups in increasing
CHEMISTRY acidity order is
SECTION-I (i) P h < I < Br < Cℓ < F < CN < NO2 < CCℓ3 < CF3
HS-2/10 1103CJA101001240016
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5. Ans ( B ) 11. Ans ( B,C )
2.5 gm impure sample have BOH weak monoacidic
base
Assume moles of BOH present = a
Conc. of BOH = 10a
'X' is polar BOH + HCl → BCl + H2 O
10a 0.5 V
6. Ans ( C ) 10a – 1 × 10a 1
× 10a
Amphibole chain silicate is represented as 5 5
(Si2O5.5)x3x – or (Si4O11)x6x – 8a 2a
Basic Buffer
CHEMISTRY Salt
pH = 14 – pKb
( + log )
Base
SECTION-I (ii)
9 = 14 – pKb – log 1
7. Ans ( A,B,C,D ) pKb = 5 + 2 × 0.3 = 5.6
4
Apply mass conservation, V = 80 ml.
Kb =10 – 5.6
0.8
M = 28.75 × × 1000 = 6.25 moles/litre At equivalent point
80 × 46
M = 28.75 ×
0.8
× 1000 = 10 moles/Kg BOH + HCl → BCl + H2
50 × 46 O ∵ a = 0.5 V
0.5
XC2 H5 OH = = 0.152 a 0.5V a
0.5 + ( 50 )
Conc. BCl = a
18
23
→ Salt hydrolysis
Mass fraction of ethanol = × 100 = 0.315 0.1 + V
73 pH = 7 – pKb – 1 log C
1
8. Ans ( A,B,C ) 2 2
Cr oxidises from +3 to +6 while I reduces from +5 4.5 = 7 – × 5.6 – 1 log a
1
2 2 0.1 + V
to – 1. One I atom gains 6 electrons. 1 a
– 0.3 = log ( )
9. Ans ( A,B,C ) 1
2 0.1 + V
2log ( ) = log ( a ) = a =
1
(A) Δ SXY = SY – SX > 0 2 0.1 + V 0.1 + V 4
SY > SX ⇒ 0.5V × 4 = 0.1 + V
i.e., Y is more disordered than X V = 100 ml of HCl
(B) S is a state function, so it does not depend on 2V = 0.1 + V
type of process. V = 0.1
(C) Δ SXY = – Δ SYX Salt conc. = 0.5 × 0.1 = 0.25 M
Because S is state function 0.1 + 0.1
∴ moles of Base = 0.5 V
Δ SYX = – 10 J/K
= 0.5 × 0.1
10. Ans ( A,B,D ) = 0.05 moles
(i) I is 1° Amine and II is 2° amine so functional wt = 0.05 × 45 = 2.25
isomers. wt% = 2.25
× 100 = 90%
(ii) Both are metamers as different group around 2° 2.5
amine.
(iii) I, IV are functional isomer
(iv) I & III has difference in chain length.
1103CJA101001240016 HS-3/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
12. Ans ( B,D ) 3. Ans ( 6.00 )
HA A– + H+
t=0 0.2 – 0.1
t = eq 0.2(1 – α ) 0.2 α 0.1 + 0.2 α
[H + ][A− ] 0.2 α (0.1 + 0.2 α)
Ka = = ....(1)
[HA] 0.2 (1 − α)
(0.2α + 0.1) (0.2α)
5 × 10−2 =
0.2 (1 − α)
4 × 10−2 α2 + 2 × 10−2 α
5 × 10−2 =
0.2 (1 − α)
5 × 0.2 (1 - α ) = 4 α 2 + 2 α
1 - α = 4α2 + 2α
CHEMISTRY 4 α 2 + 2x + α - 1 = 0.
SECTION-II 4α2 + 3α - 1 = 0
1. Ans ( 9.00 ) α =
−3 ± √9 + (16)
8
2
α = = 0.25
8
[H+] = 0.2 α + 0.1
= 0.2 × 0.25 + 0.1
= 0.05 + 0.1
=0.15
by multiplying 40 answer is = 0.15 × 40 = 6
4. Ans ( 7.00 )
Aromatic ⇒ a, c, d ⇒ x = 3
Non-aromatic ⇒ b, e, g ⇒ y = 3
2. Ans ( 5.00 ) Anti-aromatic ⇒ f, h ⇒ z = 2
II, III, V, VII, VIII has presence of alpha hydrogen. ∴ x + 2y – z = 3 + 2 × 3 – 2
So, will show tautomerism. =9–2=7
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5. Ans ( 6.00 ) MATHEMATICS
SECTION-I (i)
1. Ans ( B )
(x2 + 2)2 – (a + 4) (x2 + 2) (x2 + 1) + (a + 3) (x2 +
1)2 = 0
Divide by (x2 + 1)2 :
2
x2 + 2 x2 + 2
( ) − (a + 4) ( ) +a+3=0
x2 + 1 x2 + 1
2
x +2
let 2 =t
x +1
∴ t2 – (a + 4)t + (a + 3) = 0
x2( – a – 2) = a + 1
The following values are given in the question: a+1
x2 = ⩾ 0
μ obs = 2D, Xanti = 0.75, so Xgauche = 1 – 0.75 = 0.25 −a − 2
a+1
By using the formula ⇒ mobs = μi Xi
∑
⩽ 0
a+2
μ obs = μ gauche × Xgauche + μ anti × Xanti
2 = μ gauche × 0.25 + 0.75 × 0
2
μ gauche = =8D
0.25 a ∈ ( – 2, – 1]
1103CJA101001240016 HS-5/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
2. Ans ( B ) 4. Ans ( D )
Equation of the line in parametric form is 3z1 + i 2z2 + 2z3
=
x y 4 4
= =r. P = point of intersection of AD & BC
1 √ 5
√
6 √ 6
Any point on the given line can be taken as
r √ 5
( , r) .
√ 6 √ 6
r √ 5
Now ,if r = OA then the point ( , r)
√ 6 √ 6
will also satisfy the equation x = 1.
⇒ r = √6 = OA1
3
Similarly OA2 =2 6. Hence √ AD = 1 ⇒ DP =
4
OA12 + OA22 + … … .. + OA32 + … … … ..+OAn2 9 √7 √7
BP = √1 − = ⇒ BC =
= 6 + 22 6 + 32 6+. . . . . . . . . . +n2 6
√ √ √ √ 16 4 2
1
n(n + 1)(2n + 1) area of Quad. ABCD = . AD × BC
=6 ( ) 2
6 1 √7 √7
= 2n3 + 3n2 + n = × 1 × =
2 2 4
Hence (B) is the correct answer. 5. Ans ( D )
3. Ans ( D ) Let point of intersection of tangents at A and B be
Let given curves be S = 0 & S' = 0 the point P(h,k) , then the equation of AB is
So, a circle passing through their points of xh yk
+ =1 .......(1)
intersection can be S' + λ S = 0 4 1
x2 y 2
⇒ (a' + λ a)x2 + (a' + a – b + λ b)y2 + ( λ – 1)2hxy Homogenizing the given ellipse
4
+
1
= 1 using
– 2(g' + λ g)x – 2(ƒ' + λ ƒ)y + c(1 + λ ) = 0 equation (1)
2
So, λ = 1 x2 y 2 xh yk
⇒ + =( + )
Now, required circle is 4 1 4 1
(a + a')x2 + (a + a')y2 – 2x(g + g') – 2y(ƒ + ƒ') + 2c h2 1 2hk
⇒ x2 ( − ) + y 2 (k2 − 1) + xy = 0
16 4 4
=0
h2 − 4 hk
So, point P is the center of this circle. ⇒ x2 ( 2 2
) + y (k − 1) + ( ) xy = 0
16 2
Hence, PA = PB = PC = PD = r ......(2)
Given equation of pair of straight lines
x2 + 4y2 + λ xy = 0 and above equation (2) should
represent same line. Hence
h2 − 4 k2 − 1 hk
= =
16 4 2λ
On eleminating λ , relation obtained in h and k is
h2 – 4 = 4(k2 – 1) h2 – 4k2 = 0
Thus desired locus is x2 – 4y2 = 0
HS-6/10 1103CJA101001240016
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6. Ans ( A ) 9. Ans ( B,C )
Let M be 18 cos θ, 8 sin θ . As shortest
(√ √ ) |Z| = 1 ⇒ z = cos θ + i sin θ
distance lies along common normal |z2 + z – 1|2 = (cos 2 θ + cos θ – 1)2 + (sin 2 θ +
Given line will be parallel to the tangent at M sin θ )2
x cos θ y sin θ = 3 + 2 cos θ – 2 cos 2 θ – 2 cos θ
+ =1 is parallel to
√ 18 √ 8 = 3 – 2 cos 2 θ
2x – 3y + 25 = 0 ⇒ |z2 + z – 1| will be maximum if
√ 8 cos θ 2
⇒− = ⇒ tan θ = −1 cos 2 θ = – 1 and minimum when cos 2 θ = 1.
3
18 sin θ
10. Ans ( B,D )
√
3π
⇒θ= ⇒ po int M is (−3, 2)
4 As tangents are perpendicular to each other and its
7 4
points of intersections P ( ,− ) lies on
5 5
directrix. AB is focal chord.
MATHEMATICS
Equation of AB is x – y = 4, as focus is ( α , β ) so
SECTION-I (ii) α−β=4 ⇒ β=α−4
7. Ans ( A,D ) Now ∠ ASP = 90°
3
An = an + bn + cn 2 4
− −α+4
−2 − α + 4 5
Bn = (An − An−1 ) − (An−1 − An−2 ) ⇒ ⋅
2−α 7
quadratic quadratic −α
5
⇒ Bn is linear in n. 16
n
−α
2−α 5
Cn = ∑ [(Br − Br−1 ) − (Br−1 − Br−2 ) ] ⇒ ⋅ = −1
2−α 7
r=3
const co nst
−α
5
16 7 23
=0 ⇒ −α=α− ; α=
Cn = 0 5 5 10
23 17
10
10 × 11 ⇒ Focus is ( , − )
∑ Cr + r = − (1 + 2) = 52 10 10
r=3
2 3 √2 27√2
Also, ℓ1 = AS = , ℓ2 = BS =
8. Ans ( A,B,C ) 1 1 1
10
27√2
10
27√2
Sides of rhombus are parallel to the line pair 7x2 – = +
ℓ1 ℓ2
⇒ a=
100
⇒ 4a =
25
a
8xy + y2 = 0.
So, its diagonals are parallel to the angle bisectors
x2 − y 2 xy
⇒ 2x2 – 2y2 + 3xy = 0
=
6 −4
y 2 y
⇒ 2( ) − 3 ( ) − 2 = 0
x x
y 1
⇒ = 2, − = Slope of diagonals
x 2
So, equation of diagonal can be
y – 2 = 2(x – 1) or y – 2 = − 1 (x – 1)
2
5
Hence, point P can be (0, 0) or ( 0, )
2
1103CJA101001240016 HS-7/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
11. Ans ( B,C,D ) 12. Ans ( A,B,C )
Given parabola
y = x2 + ax + 1
a 2 a2
⇒ y = (x + ) + 1 −
2 4
As no any point of the parabola lies below x axis,
a2
1− ⩾ 0 Hyperbola and ellipse will be confocal with focus
4
a2 ±2√2, 0)
∴ ⩽ 1 ⇒∴ a ∈ [−2, 2] (
4 2 √2
No. of integral values of a = 5 1 3
1 − e21 = ⇒ e1 = ⇒ e2 =
9 3 2 √2
The tangent to y = x2 + ax + 1 at (0,1) is T =0
x2 y2 8
y+1 x+0 ∴ − =1⇒A=
⇒ = x ⋅ 0 + a( ) + 1 A2 B2 3
2 2 64 9 8
2 2
⇒ y + 1 = ax + 2 ⇒ y = ax + 1 B = ( − 1) ⇒ B =
9 8 9
This is tangent to x2 + y 2 = r2 also 9x2 9y 2
− =1
1 64 8
∴ 1 2 = r 2 ( a2 + 1 ) ⇒ r 2 =
a2 + 1
1
∴ for maximum value of a, r2 =
4+1 MATHEMATICS
1
∴ r= SECTION-II
√ 5
for maximum value of radius r,
2
must be a2 1. Ans ( 1.00 )
minimum i.e. a = 0, for this ∣
∣ z12 − z22 ∣∣ = ∣∣¯z21 + ¯z22 − 2z¯1 ¯z2 ∣∣
a = slope of tangent = 0 ∣
∣z12 − z22 ∣∣ = ∣∣z12 + z22 − 2z1 z2 ∣∣
Also, area enclosed by the tangent |z1 + z2 | |z1 − z2 | = |z1 − z2 | |z1 − z2 |
y = ax + 1 with coordinate axes ⇒ |z1 + z2| = |z1 – z2|
1 ∣ 1∣ 1
= ⋅ 1 ⋅ ∣− ∣ = ⇒ z1 ⊥ z2
2 ∣ a ∣ 2 |a|
z1 π
⇒ arg( ) = 2nπ +
z2 2
π π 3π
⇒− , ,
2 2 2
minimum value of |a + b| = 1, (a = – 1 & b = 2)
∴ Minimum area (when |a| = 2)
1 1
= =
2×2 4
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2. Ans ( 306.00 ) 3. Ans ( 7.00 )
x2 y2 Area of trapezium F1MNF2
Hn ⇒ − =1
1+n 3+n 1
Δ = (MF1 + NF2 ) MN also MF1.NF2 =
b 2 3 + n √ 2n + 4 2
e = √1 +
a 2
= √1 +
1+n
=
n+1 b2 (MF1 – NF2)2 + MN2 = (F1F2)2
2n + 4 ⇒ (MF1 +
e=√
n+1 NF2)2 –
n = 48 (smallest even value for which e ∈ Q)
4MF1.NF2 +
10
e= MN2 = (F1F2)2
7
a2 = n + 1 , b2 = n + 3
= 49 = 51
2b2
1 = length of LR =
a 2Δ
2
51 ⇒( − 4b2 + MN 2 = 4a2 e2
L=2⋅ MN
)
7
102 4Δ2
1= + MN 2 = 4 (a2 e2 + b2 ) = 4 (a2 e2 + a2 − a2 e2 )
7 MN 2
21ℓ = 306 ∵ MN is chord of auxiliary circle
⇒ MN = 2√a2 − p2
4Δ2
+ 4a2 − 4p2 = 4a2
MN 2
Δ
⇒ =p
MN
Now p = distance of MN : √ 3x − 2y + 4 = 0 from
(0,0)
4 16ℓ2
⇒p= ⇒ =7
√ 7 Δ2
1103CJA101001240016 HS-9/10
Target:IIT-JEE (JA)/19-01-2025/Paper-2
4. Ans ( 7.00 ) 5. Ans ( 528.00 )
a 0 = 0, a1 = 0
an+2 = 3 an+1 – 2 an+1 : n ≥ 0
an+2 – an+1 = 2 (an+1 – an) + 1
n = 0 a2 – a1 = 2 (a1 – a0) + 1
n = 1 a3 – a2 = 2 (a2 – a1) + 1
n = 2 a4 – a3 = 2 (a3 – a2) + 1
n = n an+2 – an+1 = 2 (an+1 – an) + 1
(an+2 – a1) – 2 (an+1 – a0) – (n + 1) = 0
an+2 = 2an+1 + (n +1)
n→n–2
an – 2an – 1 = n – 1
Now a25a23 – 2a25a22 – 2a23a24+4a22a24
= (a25 – 2a24) (a23 – 2a22) = (24) (22) = 528
Let equation of transverse common tangent L with 6. Ans ( 5.00 )
positive slope is Let f(x) = px2 – qx +r
(y − 5) = 2√2 (x − 1) It has two distinct real roots lying between 0 and 1.
4 √2 f(x) can be written as, f(x) = p(x – α )(x – β ),
[As, slope ⇒ tan θ = = 2 2] √
2 where α and β are the roots of the equation.
Suppose equation of tangent L' which is parallel to
From the graph it can be observed that f(0)f (1) > 0
L is
As p, q and r are integers f(0)f(l) > 1
2 √2 x − y = λ
f(0) = p α β
∣
2√2 (1) − 8 − λ ∣
So, ∣
∣
=1 ∣
∣ f(l) = p(l – α )(1 – β )
∣ 8+1 √ ∣
⇒ p2( α )(l – α )( β )(1 – β ) > 1 > 0 → (1)
⇒ λ = 2√2 − 11, 2√2 − 5
Using AM ³ GM, we get
∴ Equation of L' is
1
2√2x − y + (11 − 2√2) = 0 α+1−α+β+1−β
> (αβ (1 − α) (1 − β)) 4
So, a = 2 ; b = 1; c = 11 4
AM and GM cannot be equal because the equation
a+b+c 14
gives = =7 has distinct roots
2 2
p2
> p2 (αβ (1 − α) (1 − β))
16
p2
⇒ >1
16
⇒p>4
Therefore the minimum value of p is 5.
HS-10/10 1103CJA101001240016