Sec: JR_IIT*CO-SC(MODEL-B) Date: 08-12-2024

Time: 3 Hrs CTM-23 Max. Marks: 300

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. A point charge q=100 C is located in the XY-plane at the point with position vector
r0  2iˆ  3jˆ  kˆ . What is he electric field vector (in kN/C) at the point with position

vector r  8iˆ  5ˆj  kˆ ?

a) 4.2iˆ  5.6ˆj b) 6iˆ  8ˆj c) 54iˆ  72ˆj d) 5.4iˆ  7.2ˆj
2. An infinite number of electric charges each equal to 5nC (magnitude) are placed along
X-axis at x=1 cm, x=2 cm, x=4 cm, x =8 cm and so on. In the set up , if the successive
charges have opposite sign, then electric field at x=0 is
a) 12 104 N / C b) 24 10 4 N / C c) 36 10 4 N / C d) 48 10 4 N / C
3. Two charges q1 and q 2 are kept on X-axis and electric field at different points an X-
axis is plotted against X. Choose correct statement about nature and magnitude of q1
and q 2 .

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 a) q1  ve, q 2  ve;| q1 || q 2 | b) q1  ve,q 2  ve;| q1 || q 2 |
c) q1  ve,q 2  ve;| q1 || q 2 | d) q1  ve, q 2  ve;| q1 || q 2 |
4. Two spheres each having the charge +Q are suspended by insulating threads of length
L from a hook. This arrangement is taken in space, where there is no gravitationect,
then the angle between the two suspensial effons and the tension in each will be
1 Q2 1 Q2 1 Q2 1 Q2
a) 1800 , b) 900 , c) 1800 , d) 1800 ,
40  2L  2 40 L2 4 0 2L2 40 L2

5. ABC is a right –angled triangle. Point charges q1 , q 2 and q 3 are at A, B and C ,

respectively. The force on q 3 is F as shown. Then

q1 1  tan 2  q 1  cot 2 
a)  b) 1  c) q1  q 2 d)None of these
q 2 sin   cos  q 2 sin   cos 

6. Two identical charged spheres are suspended by strings of equal lengths. The strings
an angle of 300 with each other. When suspended in a liquid of density 2.7 g cm 3 , the
angle remains the same of density of the material of the sphere is 3.6 g cm 3 , the
dielectric constant of the liquid is
a)1 b)4 c)3 d)2
7. The charges per unit length of the four quadrant of the ring is 2, 2,  , and  ,
respectively. The electric field at the centre is

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   2
a)  î b) ĵ c) î d) None of these
2 0 R 2 0 R 4 0 R

8. Two concentric rings, one of radius R and total charge +Q and the second of radius 2R
and total charge - 8Q , lie in XY-plane (i.e., Z=0 plane). The common centre of rings
lies at origin and the common axis coincides with Z –axis. The charge is uniformly
distributed on both rings. At what distance from origin is the net electric field on Z-
axis zero?

a) 2R b) 2 2R c) 2R d) 3R
9. Three charged rods of length L each are made of insulating material and form an
equilateral triangle. They have linear charge densities of  ,  and -  as shown in
figure. Find the magnitude of electric field intensity at the centroid O of the triangle.

3 3 3 3 3
a) b) c) d)
2 0 L  0 L 2 0 L  0 L

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10. A particle of mass m, charge –Q is constrained to move along the axis of a ring of
radius a. The ring carries a uniform charge density +  along its circumference.
Initially , the particle lies in the plane of the ring a point, where no net force acts on it.
The period of oscillation of the particle when it is displaced slightly its equilibrium
position is
0 ma 2 20 ma 2 40 ma 2 0 ma 2
a) 4 b) 2 c) 2 d) 2
Q Q Q 2 Q

11. n identical point charges are kept symmetrically on the periphery of the circle
x 2  y2  R 2 in XY-plane. The resultant electric field at (0,0, R) is E1 and at (0, 0, 2R) is

E 2 , the ratio of E1 / E 2 is

5 5 5 5 2
a) b) c)2 d)
4 2 2 2 2

12. In a horizontal uniform electric field, a small charged block of charge q is gently
released on the top of a fixed spherical dome. The block slides down the dome without
friction and breaks away from the surface of the dome at the angular position
3
  sin 1   from vertical. The ratio of the force of gravity acting on the block to force
5

of its interaction with the field is

a)2.5 b)4 c)4.5 d)5

13. Two small equally charged spheres, each of mass m, are suspended from the same
point by silk threads of length l. the distance between the spheres x<<l. Find the rate
dq
with which the charge leaks off each sphere. If they approach each other with
dt
a
velocity varying as v  , where a is a constant.
x

3a 20 mg 2a 2 0mg 3a 40 mg 2a 4 0mg

a) b) c) d)
2 l 3 l 2 l 3 l

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14. A non –conducting disc of mass =2 kg, total charges = +1C uniformly distributed, is
placed on a rough horizontal non-conducting surface with its cross-section in vertical
plane as shown. A uniform horizontal electric field E is now switched ON. The
maximum magnitude of electric field E , so that the disk rolls purely is ( Take ,g =10
ms 2 )

a)10 N/C b)12 N/C c)15 N/C d)20 N/C

15. Two identical charged particles of charge a are placed symmetrically on both the sides.
On the axis of a uniformly charged ring of radius a with linear charge density  as
shown I the figure. The distance of the charge particle from centre of ring is l.
Calculate tension in the due to presence to the charged particles.

qa 2 qa 2 2qa 2 qa 2

a) 3/2
b) 3/2
c) 3/2
d) 3/2
 0  a 2  12  2 0  a 2  12   0  a 2  12  4 0  a 2  12 

16. three infinitely long. Straight thin rods each carrying charge density +  and mass per
unit length m are equally spaced as shown in figure. The middle rod is this placed
through a very small distance x in the plane of figure while the other two rods held
fixed. Find the frequency of small oscillations.

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 1 2 1 2 1 2 2 1 2
b) c) d)
2 0 md 2 2 2 0 md 2 2 0 md 2 2 40 md 2

17. The electric field vector at point P(a, a, a) due to three uniformly charged infinite wires
1, 2 and 3 with uniform charge density  each kept along the X, Y and Z-axes
respectively , as shown in figure is

 ˆ ˆ ˆ  ˆ ˆ ˆ  2 ˆ ˆ ˆ
a) 
3 0 a
i  j k  b) 
2 0 a
i  j k  c)
2 2 a
 ˆi  ˆj  kˆ  d) 
 0 a
i  j k 
0

18. A proton and an electron are placed in a uniform electric field.

a)The electric forces acting on them will be equal
b)The magnitudes of the force will be equal
c)Their acceleration will be equal
d)The magnitudes of acceleration will be equal
19. Two spherical conductors B and C having equal radii and carrying equal charges repel
each other with a force F, when kept apart at some distance. A third spherical
conductor A having same radius as that of B but uncharged, is brought in contact with
B, then brought in contact with C and finally removed away from both. The new force
of repulsion between B and C is
F 3F F 3F
a) b) c) d)
4 4 8 8
20. The number of electrons that should be removed from a coin of mass 1.6 g, so that it
may float in electric field intensity 109 N/C directed upwards is
a) 9.8 10 7 b) 9.8  105 c) 9.8  103 d) 9.8 10 2

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 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10
questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

21. In a 2-D region of xy-space, a uniform electric field exists, given by :

 
E   2V / m  3iˆ  4ˆj . A charged particle of mass 10 2 g and charge 10 5 C is fired from

the origin with initial velocity 20 m/s, directed along the negative y-direction. Find the
minimum speed (in m/s) of the particle during is subsequent motion. Neglect
gravity._____________.
22. A rod of mass m (uniformly distributed) and length l is hinged about point O in a
uniform vertical electric field as shown. Linear charge density of rod varies with x as
nmg
   0 x. Electric field for which rod remain horizontal is . Find value of
2 0 l2

n.____________.

23. A ball of mass m with a charge q can rotate in a vertical plane at the end of a string of
length l=10 cm in a uniform electrostatic field whose lines of force are directed
upwards. What horizontal velocity (in m/s) must be imparted to the ball in the upper
position, so that the tension in the string in the lower position of the ball is 15 times the
weight of the ball?( Given , qE  3mg and g  10m / s 2 ) ____________.

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24. Two identical charge, 5C each , are certain distance apart in the air. The largest
charge to be transferred from one charge to another , so that their interaction force
decreases 5 times when held at the same separation in a liquid of dielectric constant 2
is n C . Find n._____________.
25. Find the magnitude of uniform electric field E in N/C (direction shown in figure ), if
an electron entering with velocity 100 m/s making 300 comes out making 600 (see
m
figure ), after a time numerically equal to of electron._____________.
e

CHEMISTRY Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

26. Correct name of the following compound is

A) 1  Bromo  3  nitrobenzene B) 3  bromo aniline

C) 1  Nitro  3  bromobenzene D) 1  Nitro  4  bromobenzene

27. Which of the following compound does not undergo Friedel Craft reaction ?

A) B)

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 C) D)

28. Least reactive compound towards electrophilic aromatic substitution reaction

A) B) C) D)

29. Which of the following is unstable at room temperature?

A) B) C) D)

30.

Compound (P) can be

A) B) C) D)

31.

For above conversion electrophile and obtained from suitable reagent which
are

electrophile ( X  ) electrophile ( Y  )

A) Conc.HNO3 / Conc.H 2 SO4   600 C  Cl2 / hv

B) Cl2 / Fe Conc.HNO3 / Conc.H 2 SO4   600 C 

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 C) Conc.HNO3 / Conc.H 2 SO4   600 C  Cl2 / Fe

Conc.HNO3 / Conc.H 2 SO4   600 C 

D) Cl2 / hv

Polymerisation
32. CH 3  C  CH   X X may be
 major 

A) B) C) D) Both (B) and ( C )

33. Most reactive compound towards electrophilic aromatic substitution is

A) B) C) D)

34. Which is the correct order for following group as activator towards electrophilic
aromatic chemistry?

A) 2 > 1 > 3 B) 1 > 2 > 3 C) 1 < 2 < 3 D) 2 < 1 < 3

35.

B in the above reaction is

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 A) B) C) D)

36. For electrophilic aromatic substitution.

The correct order towards electrophilic aromatic substitution is

A)  iii    ii    i    iv  B)  iii    iv    i    ii 

C)  iv    iii    ii    i  D)  i    ii    iii    iv 

37. When benzene is treated with conc.HNO3 and conc.H 2 SO4 to produce C6 H 5  NO2 . Here
HNO3 acts as

A) Reducing agent B) Catalyst C) Base D) Acid

38. The compound X in the reaction:

A) B) C) D)

39. Statement-1 : Benzene does not decolourise Br2  water

Statement-2 : Benzene is a planar molecule.
A) Statement-1 is True, Statement-2 is True;
Statement-2 is a correct explanation for Statement-1
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 B) Statement-1 is True, Statement-2 is True;
Statement-2 is NOT a correct explanation for Statement-1

C) Statement-1 is True, Statement-2 is False

D) Statement-1 is False, Statement-2 is True

40. Statement-1: CH 3 group attached to the benzene directs electrophile to ortho and
para position. And
Statement-2 : Methyl on benzene shows +R effect.

A) Statement-1 is True, Statement-2 is True;

Statement-2 is a correct explanation for Statement-1

B) Statement-1 is True, Statement-2 is True;

Statement-2 is NOT a correct explanation for Statement-1
C) Statement-1 is True, Statement-2 is False
D) Statement-1 is False, Statement-2 is True
41. Gammexane can be produced by

A) B)

C) D)

42. Which is the correct sequence for following conversion?

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 A) B)

Conc. CH3COCl N2H4/OH-

H2SO4 AlC3
C) D)

43. Friedel-Crafts alkylation is an example of

A) Electrophilic addition reaction B) Nuclephilic substitution reaction

C) Nucleophilic addition reaction D) Electrophilic substitution reaction.

44. Select the correct statement with respect to reaction:

A) Degree of unsaturation of one of the products is same as that of reactant benzene.

B) Degree of unsaturation of one of the products obtained is one.

C) Benzene hexachloride (BHC) is obtained as one of the products.

D) Above reaction is example of addition reaction.

45. Correct order of rate of nitration using mixture of conc.HNO3 and H 2 SO4 is

A) C6 H 6  C6 D6  C6T6 B) C6 D6  C6T6  C6 H 6

C) C6T6  C6 H 6  C6 D6 D) C6T6  C6 H 6  C6 D6

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10
questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

46. Of the following compounds, find out number of conjugated unsaturated hydrocarbon
those can show Diels alder reactions
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 , ,
47. Examine the structural formulae shown below and find out how many compounds
will show oxidation reaction with acidic kmno4 to give benzoic acid derivatives?

, ,
48. Identify number of substitutions those are deactivating but ortho and para directing
O
||
CHO , OCH 3 ,  C  NH 2 , OH ,

49. Total number of “Pi” bonds present in Naphthalene

50. At which position, electrophile is more likely to attach in electrophilic substitution of
the following compound?

MATHS Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and
(4) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

   
51.   
Let a  2iˆ  ˆj  kˆ, b  a   iˆ  ˆj   iˆ  iˆ . Then the square of the projection of a on b is

1) 2 2) 1/3 3) 1/5 4) 2/3

        
52.   
Let a  4iˆ  ˆj  kˆ, b  11iˆ  ˆj  kˆ and c be a vector such that a  b  c  c  2a  3b . 
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    2
If  2a  3b  .c  1670 , then c is equal to

1) 1609 2) 1618 3) 1627 4) 1600

  
53. Let three vectors a   iˆ  4 ˆj  2kˆ, b  5iˆ  3 ˆj  4kˆ, c  xiˆ  yiˆ  zkˆ from a triangle such that
   2
c  a  b and the area of the triangle is 5 6 . If  is a positive real number, then c is

1) 10 2) 14 3) 12 4) 16
   
54. Let OA  2a,OB  6a  5b and OC  3b , where O is the origin. If the area of the
 
parallelogram with adjacent sides OA and OC is 15 sq. units, then the area (in sq. units)
of the quadrilateral OABC is equal to
1) 35 2) 32 3) 40 4) 38
55. If A 1, 1, 2  , B  5, 7, 6  , C  3, 4, 10  and D  1, 4, 2  are the vertices of a quadrilateral
ABCD, then its area is
1) 12 29 2) 24 7 3) 48 7 4) 24 29
  
56. Let a  2iˆ  5 ˆj  kˆ, b  2iˆ  2 ˆj  2kˆ and c be three vectors such
      
      
that c  iˆ  a  b  iˆ  a  c  iˆ , a.c  29 . Then c. 2iˆ  ˆj  kˆ is equal to

1) 10 2) 12 3) 15 4) 5
       2
57. Let a and b be two vectors such that b  1 and b  a  2 . Then b  a  b is equal to  
1) 3 2) 5 3) 1 4) 4
58. Let PQR be a triangle. The points A, B and C are on the sides QR, RP and PQ
QA RB PC 1 Area  PQR 
respectively such that    . Then is equal to
AR BP CQ 2 Area  ABC 

1) 4 2) 3 3) 2 4) 5/2
         
59. Let u  iˆ  ˆj  2kˆ, v  2iˆ  ˆj  kˆ, v.w  2 and v  w  u   v . Then u.w is equal to
3 2
1) 1 2) 2 3) 4) 
2 3
    
60. If a  2, b  5 and a  b  8 , then a.b is equal to

1) 3 2) 5 3) 6 4) 4

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   
61. Let the vectors a, b, c represent three conterminous edges of a parallelepiped of volume
V. then the volume of the parallelepiped, whose coterminous edges are represented by
     
a, b  c and a  2b  3c is equal to

1) 6V 2) V 3) 2 V 4) 3 V
    
62. If four distinct points with position vectors a, b, c and d and  abc  are coplanar, then is
equal to
      
1) dca   bd a   cdb  2) adb   dca   dbc 
       
3)  dba    acd    dbc  4) bcd    d ca    dba 
        
63. Let three vectors a, b and c be such that a  b  c, b  c  a and a  2 . Then which one of
the following is NOT true?
     
1)  abc    cab   8 2) Projection of a on b  c is 2  
  2      
3) 3a  b  2c  51    
4) a  b  c  b  c  0
     
64. Let a  iˆ  ˆj  kˆ, a.b  1 and a  b  iˆ  ˆj . Then a  6b is equal to


1) 3 iˆ  ˆj  kˆ  
2) 3 iˆ  ˆj  kˆ  
3) 3 iˆ  ˆj  kˆ  
4) 3 iˆ  ˆj  kˆ 
     
65. Let a  5iˆ  ˆj  3kˆ, b  iˆ  2 ˆj  4kˆ and c      
a  b  iˆ  iˆ  iˆ . Then c. iˆ  ˆj  kˆ is equal to 
1) -12 2) -10 3) -13 4) -15
        
66. Consider three vectors a, b, c . Let a  2, b  3 and a  b  c . If   0,  is the angle
 3
   2
between the vectors b and c , then minimum value of 27 c  a is equal to
1) 110 2) 124 3) 105 4) 121
67. Let A(2, 3, 5) and C(-3, 4, -2) be opposite vertices of a parallelogram ABCD. If the

diagonal BD  iˆ  2 ˆj  3kˆ then the area of the parallelogram is equal to
1 1 1 1
1) 410 474 2) 3) 586 4) 306
2 2 2 2
68. The distance of the line 2 x  3 y  4 from the point (1, 1) in the direction of the
line x  y  1is
1
1) 2 2) 5 2 3) 4) 2 2
2

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69. The complete set of values of ‘x’ for which the
 x4 
function g  x   2 f    f  6  x  x  R
4

2
 

is decreasing. It is given that f ''  x   0x  R

1)   2, 2  2)  ,  2    2,  

3)   2, 0    2,   4)  ,  2    0, 2 

70. Let f : R  R defined by f  x   x 3  3x  1 and g is the inverse of f then the value of

g "  5 is equal to:

1 1 1
1) 2) 3) 4) None of these
6 36 216

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the
Answer in the decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10
questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

   

71. Let O be an interior point of  ABC such that OA  2OB  3OC  0 , then the ratio of the
area of  ABC to the area of  AOC is
        
72. Let a and b be two vectors such that a =1, b  4 , and a.b  2 . If c  2a  b  3b and the  
 
angle between b and c is  , then 192 sin2  is equal to
  2  2  2
73.    
If a  2iˆ  ˆj  2kˆ , then the value of iˆ  a  iˆ  ˆj  a  ˆj  kˆ  a  kˆ   is equal to
   
74. Let v   iˆ  2 ˆj  3kˆ, w  2 iˆ  ˆj  kˆ and u be a vector such that u    0 . If the minimum
 m  2
value of the scalar triple product uvw  is - 3401, and u.iˆ  where m and n are co-
n
prime natural numbers, then m + n is equal to ______.
75. Let  and  be the roots of a quadratic equation 4 x 2   5 p  1 x  5 p  0 . If   1   then
find the integral value of p.

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