CHAPTER 5

[SECTON- A]
 Answer following questions in short. (Each question carries one mark)
1. What is state function? Give its example.
2. No work is done on the system, but q amount of heat is taken out from the system and given to the surroundings.
What type of wall does the system have?
3. What are Extensive properties?
4. Which type of relation is correct for the following reaction, N 2 (g) + 3 H2 (g)  2NH3 (g)
(a) ∆H = ∆U (b) ∆H > ∆U (c) ∆H < ∆U (d) ∆H ≠ ∆U
5. State the third law of Thermodynamics.
6. In process, 501 J of heat is absorbed by the system and 294 J of work is done by the system. What is the change in
internal energy for the process?
7. Which of the following condition is correct for an isothermal reaction?
(a) ∆T = 0 (b) ∆P = 0 (c) q = 0 (d) w = 0
8. State Hess's law of heat of summation.
9. At 298K temperature ice kept in open container is spontaneously melted into liquid water. Then what will be the
value of its equilibrium constant?
10. Define Standard Formation Enthalpy.
11. Given 2 H2 (g) + O2 (g)  2 H20 (I); ∆r H® = —571.66 KJ/mol calculate standard formation enthalpy of water.
12. For an Isolated system ∆U = 0, what will be ∆S?
13. In a process, 200 J of heat is absorbed by system and 150 J of work is done by the system. What is the change in
internal energy for the process?
14. Is volume extensive property or intensive property?
15. At constant pressure, whatever heat change in chemical reaction is equal to ∆H or ∆U
16.What is the sign of Combustion Enthalpy of chemical reaction
(a) +Ve (b) -Ve (c) Zero (d) None
17. For which one Std. Formation Enthalpy is none zero?
a) F2 (g) (b) Cl2 (g) (c) Br2 (g) (d) H2 (l)
18. For the process of crystallization of liquid to solid ∆S will be (a) Increased (b) decreased (c) No Charge (d) Not
defined
19. Sign of ∆H® and ∆H for the reaction that spontaneous at all temperature? (a) - , + (b) -, - (c) + , - (d) + , +

[SECTION - B]
 Answer the following questions in brief. (Each question is of two marks)
1. What is Enthalpy? Derive equation for the determination of Enthalpy change.
2. Find out the value of equilibrium constant for the following reaction at 298 K.
2NH3 (g) + CO2 (g)  NH2CONH2 (aq) + H2O (l)
Standard Gibbs energy change, ∆rG° at the given temperature is -13.6 KJ/mol.
3. Given: N2 (g) + 3H2 (g)  2 NH3 (g) ∆iH° = -92.4 KJ/mol. What is the standard enthalpy of formation of ammonia gas?
4. If water vapour is assumed to be a perfect gas, molar enthalpy change for vaporisation of 1 mol of water at 1 bar
and 100°C is 41 kJ/mol. Calculate the internal energy change when 1 mol of water is vaporised at 1 bar pressure
and 100°C.
5. Define system and explain it’s type.
6. Predict in which of the following entropy increases / decreases.
(i) Cl2 (g)  2Cl (g)
(ii) CaCO3 (s)  CaO (s) + CO2 (g)
7. Calculate the number of KJ of heat necessary to raise the temperature of 60.g of aluminium from 35°C. to 55°C
Molar heat capacity of Al is 24 J mol/K.
8. Enthalpy of combustion of carbon to CO2 is -393.5 KJ/mol. Calculate the heat released upon formation of 35.2 g of
CO2 from carbon and oxygen gas.
9. Calculate ∆rG° for conversion of oxygen to ozone, 3/2 02 (g)  03 (g) at 298 K. if kp = 2.47 x 10 -29
10. Find out the value of equilibrium constant for the following constant for the following reactions at 298K.
2NH3 (g) + C02 (g)  2 NH2CONH2 (g) + H20 (l)
standard Gibbs energy change ∆rG° at the given temperature is -13.6 KJ/mol
 [SECTIOIN - C]
 Answer the following questions in detail. (Each question is of three marks)
1. For Ideal gas derive relation between Cp and Cv.
2. At 60°C, dinitrogen tetroxide is 50 percent dissociated. Calculate the standard free energy change at this
temperature and at one atmosphere.
3. What is called process? Explain its different types.
4. For reaction at 298 k temperature, 2A + B — C, ∆H = 400 KJ/mol and ∆S = 0.2 KJ/ K mol. At what temperature will
the reaction become spontaneous considering AH and AS to be constant over the temperature range?
5. Calculate the standard enthalpy of formation of CH3OH (l) from the following data.
CH3OH (l) + 3/2 O2 (g)  CO2 (g) + 2H20 (l): ∆rH° = -726 KJ/mol
C (graphite) + O2 (g)  CO2 (g): ∆cH° = -393 KJ/mol
H2 (g) + 1/2 O2 (g)  H20 (l): ∆fH° = -286 KJ/mol
6. For the reaction, 2A(g) + B(g)  2 D(g) ∆U® = -10.5 kj and ∆S® = —44.1 J/k. Calculate ∆G® for the reaction and
Predict how the reaction may occur spontaneously.
7. Calculate the enthalpy change on Freezing of 1.0 mol of water at 10 C to- 10°C
∆ fuss H = 6.03 kJ/mol, Cp H20 (l) = 75.3 J/mol K, Cp H20 (l) = 36.8 J/mol K.

[SECTIOIN - D]
 Answer the following questions as per the instructions given. (Five marks each)
1. Explain: Born Haber cycle.
2. Explain Hess’s law of constant Heat Summation with example.
3. Define (i) Enthalpy of Atomization (ii) Bond Enthalpy (iii) Latice Enthalpy (iv) Standard enthalpy of formation.
4. The combustion of one mole before takes place at 298K and | atm. After combustion CO2 (g) and H20 (l) are
produced and 3267 KJ of heat is liberated. Calculate ArH® of benzene.
∆f H° of CO2 (g) and H20 (l) are -393. 5 KJm/ol and -285.83 KJ/mol resportively.
5. Calculate the enthalpy change for the process CCl4 (g)  C g) + 4Cl (g). Calculate bond enthalpy of C-Cl in CCl4 (g)
∆Vap H° (ccl4) = 30.5 KJ/mol, ∆f H° (ccl4) = - 135.5 KJ/mol, ∆f H® (c)=715 kJ/mol, ∆a H® (C12) = 242 KJ/m