Safety Data Sheet
Endura Fungicide
Revision date : 2022/09/22 Page: 1/12
Version: 8.0 (30278695/SDS_CPA_US/EN)
1. Identification
Product identifier used on the label
Endura Fungicide
Recommended use of the chemical and restriction on use
Recommended use*: crop protection product, fungicide
* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or
implied, including by incorporation into or reference in the seller's sales agreement.
Details of the supplier of the safety data sheet
Company:
BASF CORPORATION
100 Park Avenue
Florham Park, NJ 07932, USA
Telephone: +1 973 245-6000
Emergency telephone number
24 Hour Emergency Response Information
CHEMTREC: 1-800-424-9300
BASF HOTLINE: 1-800-832-HELP (4357)
Other means of identification
Substance number: 134581
Registration number: EPA Registration number: 7969-197
Molecular formula: C18 H12 Cl2 N2 O
Synonyms: boscalid
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Classification of the product
Combustible Dust Combustible Dust (1) Combustible Dust
Safety Data Sheet
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Version: 8.0 (30278695/SDS_CPA_US/EN)
Label elements
Signal Word:
Warning
Hazard Statement:
May form combustible dust concentration in air.
3. Composition / Information on Ingredients
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
boscalid (ISO); 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)-nicotinamide
CAS Number: 188425-85-6
Content (W/W): 70.0 %
Synonym: 3-pyridinecarboxamide,2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)
Kaolin
CAS Number: 1332-58-7
Content (W/W): 1.0 - 5.0%
Synonym: No data available.
4. First-Aid Measures
Description of first aid measures
General advice:
Remove contaminated clothing. Show container, label and/or safety data sheet to physician. If
person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-
mouth if possible.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. If not breathing, give artificial
respiration.
If on skin:
Remove contaminated clothing. Rinse skin immediately with plenty of water for 15 - 20 minutes.
Seek medical attention.
If in eyes:
Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses,
if present, after first 5 minutes, then continue rinsing. Seek medical attention.
If swallowed:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor. Never induce vomiting or give anything
by mouth if the victim is unconscious or having convulsions.
Most important symptoms and effects, both acute and delayed
Symptoms: (Further) symptoms and / or effects are not known so far
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Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Symptomatic treatment (decontamination, vital functions).
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
foam, dry powder, carbon dioxide, water spray
Special hazards arising from the substance or mixture
Hazards during fire-fighting:
carbon monoxide, carbon dioxide, Hydrogen chloride, nitrogen oxides, organochloric compounds
The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters
Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
Further information:
Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not
allow to enter drains or waterways.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Take appropriate protective measures. Clear area. Shut off source of leak only under safe
conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear
suitable personal protective clothing and equipment.
Environmental precautions
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
Contain contaminated water/firefighting water.
Methods and material for containment and cleaning up
Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or
disposal in a licensed facility. Spilled substance/product should be recovered and applied according
to label rates whenever possible. If application of spilled substance/product is not possible, then
spills should be contained, solidified, and placed in suitable containers for disposal. After
decontamination, spill area can be washed with water. Collect wash water for approved disposal.
7. Handling and Storage
Precautions for safe handling
RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND
PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product
Label and Directions for Use attached to the product for Agricultural Use Requirements in
accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate
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ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep
away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the
effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not
open until ready to use. Once container is opened, content should be used as soon as possible.
Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and spills. Do not
return residues to the storage containers. Follow label warnings even after container is emptied. The
substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact
with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of
dusts/mists/vapours. Wear suitable personal protective clothing and equipment.
Protection against fire and explosion:
The relevant fire protection measures should be noted. Fire extinguishers should be kept handy.
Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear.
Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to
national electric code. Ground all transfer equipment properly to prevent electrostatic discharge.
Electrostatic discharge may cause ignition.
Dust explosion class: Dust explosion class 2 (Kst-value 200 up to 300 bar m s-1).
Conditions for safe storage, including any incompatibilities
Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from
textiles and similar materials.
Further information on storage conditions: Keep only in the original container in a cool, dry, well-
ventilated place away from ignition sources, heat or flame. Protect containers from physical damage.
Protect against contamination. The authority permits and storage regulations must be observed.
Protect from temperatures above: 104 °F
Changes in the properties of the product may occur if substance/product is stored above indicated
temperature for extended periods of time.
8. Exposure Controls/Personal Protection
Users of a pesticidal product should refer to the product label for personal protective
equipment requirements.
Components with occupational exposure limits
Kaolin ACGIH, US: TWA value 2 mg/m3 Respirable fraction ; The
value is for particulate matter containing no
asbestos and <1% crystalline silica.
OSHA Z1: PEL 5 mg/m3 Respirable fraction ;
OSHA Z1: PEL 15 mg/m3 Total dust ;
Personal protective equipment
RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING
WORKERS:
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent)
TC23C Chemical/Mechanical type filter system to remove a combination of particles, gas and
vapours. For situations where the airborne concentrations may exceed the level for which an air
purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or
Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing
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apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape
provisions.
Hand protection:
Chemical resistant protective gloves, Protective glove selection must be based on the user's
assessment of the workplace hazards.
Eye protection:
Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if
splashing hazard exists.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. head protection,
apron, protective boots, chemical-protection suit.
General safety and hygiene measures:
Wear long sleeved work shirt and long work pants in addition to other stated personal protective
equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance
with good industrial hygiene and safety practice. Personal protective equipment should be
decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if
necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing
separately. Hands and/or face should be washed before breaks and at the end of the shift. No
eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and
animal feeding stuffs.
9. Physical and Chemical Properties
Form: granules
Odour: odourless
Odour threshold: Not determined due to potential health hazard by inhalation.
Colour: beige
pH value: approx. 4.5 - 6.5
( 10 g/l, 20 °C)
Melting point: > 20 °C
Boiling point: The substance / product
decomposes therefore not
determined.
Flash point: not applicable
Flammability: Based on the structure or composition
there is no indication of flammability
Lower explosion limit: As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit: As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Vapour pressure: negligible
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Density: approx. 12.4931 Lb/USg
( 68 °F)
Vapour density: not applicable
Partitioning coefficient n- not applicable
octanol/water (log Pow):
Self-ignition not self-igniting
temperature:
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Viscosity, dynamic: not applicable, the product is a solid
Solubility in water: dispersible
Molar mass: 343.21 g/mol
Evaporation rate: not applicable
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Oxidizing properties:
Not an oxidizer.
Dust explosivity characteristics:
Kst: 265 m.bar/s
Pmax = 7.2 BARA
Dust explosion class:
Dust explosion class 2 (Kst-value 200 up to 300 bar m s-1) (St 2)
Minimum ignition energy:
36 - 45 mJ
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
The product is chemically stable.
Hazardous polymerization will not occur. No hazardous reactions if stored and handled as
prescribed/indicated.
Conditions to avoid
Limiting oxygen concentration: 10.5 volume %
Avoid all sources of ignition: heat, sparks, open flame. This product may form an explosive mixture if:
1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is
above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded.
Incompatible materials
strong oxidizing agents, strong bases, strong acids
Hazardous decomposition products
Decomposition products:
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Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated., Prolonged thermal loading can result in products of degradation being given
off.
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: Moderately toxic after single ingestion. Slightly toxic after short-term
skin contact. Slightly toxic after short-term inhalation.
Oral
Type of value: LD50
Species: rat (male/female)
Value: > 2,000 mg/kg (OECD Guideline 423)
No mortality was observed.
Inhalation
Type of value: LC50
Species: rat (male/female)
Value: > 5.4 mg/l (OECD Guideline 403)
Exposure time: 4 h
Dermal
Type of value: LD50
Species: rat (male/female)
Value: > 2,000 mg/kg (OECD Guideline 402)
No mortality was observed.
Assessment other acute effects
Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.
The product has not been tested. The statement has been derived from the properties of the
individual components.
Irritation / corrosion
Assessment of irritating effects: May cause slight irritation to the skin. May cause moderate but
temporary irritation to the eyes.
Skin
Species: rabbit
Result: non-irritant
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Version: 8.0 (30278695/SDS_CPA_US/EN)
Eye
Species: rabbit
Result: Slightly irritating.
Method: OECD Guideline 405
Sensitization
Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. Some
individuals may develop an allergic dermatitis.
Chronic Toxicity/Effects
Repeated dose toxicity
Assessment of repeated dose toxicity: The product has not been tested. The statement has been
derived from the properties of the individual components.
Information on: boscalid (ISO); 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)-nicotinamide
Assessment of repeated dose toxicity: Based on available data, the classification criteria are not met.
Information on: Kaolin
Assessment of repeated dose toxicity: Repeated inhalative uptake of particles/dust reaching the
alveoli may cause damage to the lungs.
----------------------------------
Genetic toxicity
Assessment of mutagenicity: The product has not been tested. The statement has been derived from
the properties of the individual components. Mutagenicity tests revealed no genotoxic potential.
Carcinogenicity
Assessment of carcinogenicity: The product has not been tested. The statement has been derived
from the properties of the individual components.
Information on: boscalid (ISO); 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)-nicotinamide
Assessment of carcinogenicity: In long-term studies in rats the substance induced thyroid tumors.
The effect is caused by an animal specific mechanism that has no human counter part. In long-term
studies in mice in which the substance was given by feed, a carcinogenic effect was not observed.
Information on: Kaolin
Assessment of carcinogenicity: Based on available data, the classification criteria are not met.
The American Conference of Governmental Industrial Hygienists (ACGIH) has classified this
substance as Group A4 - Not classifiable as human carcinogen.
----------------------------------
Reproductive toxicity
Assessment of reproduction toxicity: The product has not been tested. The statement has been
derived from the properties of the individual components. The results of animal studies gave no
indication of a fertility impairing effect.
Teratogenicity
Assessment of teratogenicity: The product has not been tested. The statement has been derived
from the properties of the individual components. Animal studies gave no indication of a
developmental toxic effect at doses that were not toxic to the parental animals.
Medical conditions aggravated by overexposure
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Individuals with allergic history or pre-existing dermatitis should use extra precautions when handling
this product.
12. Ecological Information
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms.
Toxicity to fish
LC50 (96 h) 420 mg/l, Cyprinus carpio
Aquatic invertebrates
EC50 (48 h) > 1,000 mg/l, Daphnia magna
Aquatic plants
EC50 (72 h) 150 mg/l, Pseudokirchneriella subcapitata
No observed effect concentration (72 h) 32 mg/l, Pseudokirchneriella subcapitata
Assessment of terrestrial toxicity
With high probability not acutely harmful to terrestrial organisms.
Other terrestrial non-mammals
Information on: boscalid (ISO); 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)-nicotinamide
----------------------------------
Bioaccumulative potential
Bioaccumulation potential
Information on: boscalid (ISO); 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)-nicotinamide
Bioconcentration factor: 57 - 70 (28 d), Oncorhynchus mykiss
Does not accumulate in organisms.
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Mobility in soil
Assessment transport between environmental compartments
The product has not been tested. The statement has been derived from the properties of the
individual components.
Information on: boscalid (ISO); 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)-nicotinamide
Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
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Additional information
Safety Data Sheet
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Version: 8.0 (30278695/SDS_CPA_US/EN)
Other ecotoxicological advice:
The ecological data given are those of the active ingredient. Do not release untreated into natural
waters.
13. Disposal considerations
Waste disposal of substance:
Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a
violation of federal law. If pesticide wastes cannot be disposed of according to label instructions,
contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative
at the nearest EPA Regional Office for guidance.
Container disposal:
Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations.
Consult state or local disposal authorities for approved alternative procedures such as container
recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used
containers.
RCRA:
This product is not regulated by RCRA.
14. Transport Information
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory Information
Federal Regulations
Registration status:
Crop Protection TSCA, US released / exempt
Chemical TSCA, US blocked / not listed
EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicable
for this product.
State regulations
State RTK CAS Number Chemical name
PA 7783-20-2 Ammonium sulphate
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1332-58-7 Kaolin
MA 7783-20-2 Ammonium sulphate
1332-58-7 Kaolin
NJ 7783-20-2 Ammonium sulphate
1332-58-7 Kaolin
Safe Drinking Water & Toxic Enforcement Act, CA Prop. 65:
BASF Risk Assessment, CA Prop. 65:
Based on an evaluation of the product's composition and the use(s), this product does not require a
California Proposition 65 Warning.
HMIS III rating
Health: 3 Flammability: 1 Physical hazard: 0
Labeling requirements under FIFRA
This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ from
the classification criteria and hazard information required for safety data sheets, and workplace
labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide
label.
WARNING:
Causes substantial but temporary eye injury.
HARMFUL IN CONTACT WITH SKIN.
HARMFUL IF SWALLOWED.
MAY CAUSE ALLERGIC SKIN REACTION.
KEEP OUT OF REACH OF CHILDREN.
KEEP OUT OF REACH OF DOMESTIC ANIMALS.
Avoid contact with the skin, eyes and clothing.
16. Other Information
SDS Prepared by:
BASF NA Product Regulations
SDS Prepared on: 2022/09/22
We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED
HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT
PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR
TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE
Safety Data Sheet
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Version: 8.0 (30278695/SDS_CPA_US/EN)
MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED
WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED
A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY
UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION
GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET
