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 WB JEE
Engineering Entrance Exam

Solved Paper 2021

Physics
Category-I (Q. Nos. 1 to 30) 5.
Carry 1 mark each and only one option is correct. 1kΩ
In case of incorrect answer or any combination of 9V
more than one answer, 1/4 mark will be deducted. 10 V

1. A spherical convex surface of power 5 D

separates object and image space of refractive What is the value of current through the
indices 1.0 and 4/3, respectively. The radius diode in the circuit given?
of curvature of the surface is (a) Zero (b) 1 mA
(a) 20 cm (b) 1 cm (c) 4 cm (d) 5 cm (c) 19 mA (d) 9 mA

2. In Young’s double slit experiment, light of 6. A

wavelength λ passes through the double slit B
and forms interference fringes on a screen 1.2
Y
m away. If the difference between 3rd order
maximum and 3rd order minimum is 0.18 cm
and the slits are 0.02 cm apart, then λ is
(a) 1200 nm (b) 450 nm For the given logic circuit, the output Y for
(c) 600 nm (d) 300 nm
inputs (A = 0, B = 1) and (A = 0, B = 0)
3. A 12.5 eV electron beam is used to bombard respectively are
gaseous hydrogen at ground state. The (a) 0, 0 (b) 0, 1
energy level upto which the hydrogen atoms (c) 1, 0 (d) 1, 1
would be excited is
7. From dimensional analysis, the Rydberg
(a) 2 (b) 3 (c) 4 (d) 1
constant can be expressed in terms of electric
4. Let r , v , E be the radius of orbit, speed of charge (e), mass (m) and Planck constant (h) as
electron and total energy of electron 1
[consider ≡ 1 unit]
respectively in H-atom. Which of the 4 πε 0
following quantities according to Bohr theory, h2 me 4
is proportional to the quantum number n? (a) (b)
r r me 2 h2
(a) vr (b) rE (c) (d) 2 4
E v me me 2
(c) 2
(d)
h h

Page 1 of 47
 8. 12. In case of projectile motion, which one of the
F 3m following figures represent variation of
m 2m
horizontal component of velocity (ux ) with
Three blocks are pushed with a force F across time t ? (Assume that air resistance is
a frictionless table as shown in figure above. negligible)
ux ux
Let N 1 be the contact force between the left
two blocks and N 2 be the contact force
between the right two blocks. Then, (a) (b)
(a) F > N1 > N2 (b) F > N2 > N1 t t
(c) F > N1 = N2 (d) F = N1 = N2 ux
ux
V K
9. (c) (d)
m m

t t
A block of mass m slides with speed v on a
frictionless table towards another stationary
block of mass m. A massless spring with 13. A uniform thin rod of length L, mass m is
spring constant k is attached to the second lying on a smooth horizontal table. A
block as shown in figure. The maximum horizontal impulse P is suddenly applied
distance, the spring gets compressed through perpendicular to the rod at one end. The
is total energy of the rod after the impulse is
m m k k P2 7 P2 13P 2 2 P2
(a) v (b) v (c) v (d) v (a) (b) (c) (d)
k 2k m 2m m 8m 2m m

10. a (in m/s2)

14. Centre of mass (CM) of three particles of
masses 1 kg, 2 kg and 3 kg lies at the point
10 (1, 2, 3) and CM of another system of
particles of 3 kg and 2 kg lies at the point
(− 1, 3 , − 2). Where should we put a particle of
5 mass 5 kg, so that the CM of entire system
lies at the CM of the first system?
x (in m) (a) (3, 1, 8) (b) (0, 0, 0)
0 20 35
(c) (1, 3, 2) (d) (− 1, 2, 3)
The acceleration versus distance graph for a
. × 10 3 kg/m 3 is dropped
15. A body of density 12
particle moving with initial velocity 5 m/s is
shown in the figure. The velocity of the from rest from a height 1 m into a liquid to
particle at x = 35 m will be density 2.4 × 10 3 kg/m 3 . Neglecting all
(a) 20.62 m/s (b) 20 m/s dissipative effects, the maximum depth to
(c) 25 m/s (d) 50 m/s which the body sinks before returning to
float on the surface is
11. A simple pendulum, consisting of a small ball (a) 0.1 m (b) 1 m (c) 0.01 m (d) 2 m
of mass m attached to a massless string
hanging vertically from the ceiling is 16. Two solid spheres S1 and S2 of same uniform
oscillating with an amplitude such that density fall from rest under gravity in a
Tmax = 2Tmin , where Tmax and Tmin are the viscous medium and after sometime, reach
maximum and minimum tension in the terminal velocities v1 and v2 , respectively. If
string, respectively. The value of maximum m v
ratio of masses 1 = 8 , then 1 will be equal to
tension Tmax in the string is m2 v2
3 mg 3 mg
(a) (b) mg (c) (d) 3 mg 1 1
2 4 (a) 2 (b) 4 (c) (d)
2 4

Page 2 of 47
17. p q  1 − 1 q 1
(a)   (b)
4 π ε0  a b 4 π ε0 a
q  1 − 1 q 1
1 (c)   (d)
p0 4 π ε0  R a 4 π ε0 R
2

3 22. Three infinite plane sheets carrying uniform

charge densities − σ, 2σ, 4 σ are placed
V
V0 2V0 parallel to XZ-plane at Y = a, 3 a , 4 a,
respectively. The electric field at the point
In the given figure, 1 represents isobaric, 2 (0, 2a, 0) is
represents isothermal and 3 represents 5σ $ 7σ $
adiabatic processes of an ideal gas. If ∆U1 , (a) j (b) − j
2 ε0 2 ε0
∆U 2 and ∆U 3 be the changes in internal σ $ 5σ $
energy in these processes respectively, then (c) j (d) j
2 ε0 − 2 ε0
(a) ∆U1 < ∆U 2 < ∆U 3 (b) ∆U1 > ∆U 3 < ∆U 2
(c) ∆U1 = ∆U 2 > ∆U 3 (d) ∆U1 > ∆U 2 > ∆U 3 23. Two point charges +q1 and + q2 are placed a
18. If pressure of real gas O 2 in a container is finite distance d apart. It is desired to put a
RT a third charge q3 in between these two charges,
given by p = − , then the mass of so that q3 is in equilibrium. This is
2 V − b 4 b2
(a) possible only, if q 3 is negative
the gas in the container is (b) possible only, if q 3 is positive
(a) 32 g (b) 16 g (c) possible irrespective of the sign of q 3
(c) 4 g (d) 64 g (d) Not possible at all
19. 300 g of water at 25°C is added to 100 g of ice 24. Y
at 0°C. The final temperature of the mixture
is
L
(a) 12.5°C (b) 0°C (c) 25°C (d) 50°C
X
EZ M O
20.

Z/a
Consider two infinitely long wires parallel to
OM Z-axis carrying same current I in the positive
z-direction. One wire passes through the
point L at coordinates (− 1, + 1) and the other
wire passes through the point M at
The variation of electric field along the Z-axis coordinates (− 1, − 1). The resultant magnetic
due to a uniformly charged circular ring of field at the origin O will be
radius a in XY -plane as shown in the figure. µ 0I $j µ 0I $j
The value of coordinate M will be (a) (b)
2 2π 2π
(a)
1
(b) 2 (c) 1 (d)
1 µ 0I $i µ 0I $i
(c) (d)
2 2 2 2π 4π
21. A metal sphere of radius R carrying charge q 25. A thin charged rod is bent into the shape of a
is surrounded by a thick concentric metal small circle of radius R, the charge per unit
shell of inner and outer radii a and b, length of the rod being λ. The circle is rotated
respectively. The net charge on the shell is about its axis with a time period T and it is
zero.The potential at the centre of the sphere, found the magnetic field at a distance d away
when the outer surface of the shell is (d >> R) from the centre and on the axis,
grounded will be

Page 3 of 47
 varies as R m / d n. The values of m and n 30. Y
respectively are
(a) m = 2, n = 2 (b) m = 2, n = 3 R
(c) m = 3, n = 2 (d) m = 3, n = 3 X

26. 1/χ
A

B The cross-section of a reflecting surface is

T represented by the equation x 2 + y 2 = R 2 as
For two types of magnetic materials A and B, shown in the figure. A ray travelling in the
variation of 1/ χ (χ : susceptibility) versus positive x-direction is directed toward
temperature T is shown in the figure. Then, positive y-direction after reflection from the
surface at point M. The coordinate of the
(a) A is diamagnetic and B is paramagnetic
point M on the reflecting surface is
(b) A is ferromagnetic and B diamagnetic
(a) 
R R 
(b)  − ,− 
R R
(c) A is paramagnetic and B is ferromagnetic , 
(d) A is paramagnetic and B is diamagnetic  2 2  2 2

(c)  −
R R 
(d) 
R R 
27. V ,  ,− 
 2 2  2 2

V0 Category-II (Q. 31 to 35)

t Carry 2 marks each and only one option is
0 T/2 T correct. In case of incorrect answer or any
The rms value of potential difference V combination of more than one answer, 1/2 mark
shown in the figure is will be deducted.
V0 V0 V0
(a) (b) V0 (c) (d) 31. For a plane electromagnetic wave, the electric
2 3 2
field is given by
28. . × 10 11 t) k$ V/m. The
E = 90 sin(0 .5 × 10 3 x + 15
corresponding magnetic field B will be
(a) B = 3 × 10−7 sin(0.5 × 103 x + 15
. × 1011t ) $i T
−7
Red Yellow Orange (b) B = 3 × 10 sin(0.5 × 10 x + 15
3
. × 1011t ) $j T
The carbon resistor with colour code is (c) B = 27 × 109 sin(0.5 × 103 x + 15. × 1011t ) $j T
shown in the figure. There is no fourth band
in the resistor. The value of the resistance is (d) B = 3 × 10−7 sin(0.5 × 103 x + 15
. × 1011t ) k$ T
(a) 24 M Ω ± 20% (b) 14 kΩ ± 5% 32. Two metal wires of identical dimensions are
(c) 24 k Ω ± 20% (d) 34 k Ω ± 10%
connected in series. If σ1 and σ 2 are the
29. L electrical conductivities of the metal wires
respectively, the effective conductivity of the
combination is
σ1σ 2 2σ1σ 2 σ + σ2
(a) σ1 + σ 2 (b) (c) (d) 1
~
V=V0 sin ωt
σ1 + σ 2 σ1 + σ 2 2 σ1σ 2

Consider a pure inductive AC circuit as 33. A uniform rod of length L pivoted at one end
shown in the figure. If the average power P is freely rotated in a horizontal plane with
consumed is P, then an angular velocity ω about a vertical axis
(a) P > 0 (b) P < 0 passing through P. If the temperature of the
(c) P = 0 (d) P is infinite system is increased by ∆T, angular velocity

Page 4 of 47
 ω (a) Magnetic field at the centre O of the circular coil
becomes . If coefficient of linear expansion M
2 due to the bar magnet is 3 .
of the rod is α(α << 1),then ∆T will be x
1
1 1 1 (b) Induced emf is proportional to 4 .
(a) (b) (c) (d) α x
α 2α 4α
(c) The magnetic moment µ due to induced current
34. An ideal gas of molar mass M is contained in in the coil is proportional to a4 .
1
a very tall vertical cylindrical column in the (d) The heat produced is proportional to 6 .
uniform gravitational field. Assuming the gas x
temperature to be T, the height at which the 37. Electric field component of an EM radiation
centre of gravity of the gas is located is varies with time as E = a (cos ω 0 t + sin ωt
(R→universal gas constant) cos ω 0 t), where a is a constant and ω = 10 15 s −1 ,
RT RT
(a)
g
(b)
Mg ω 0 = 5 × 10 15 s −1 . This radiation falls on a
(c) MgR (d) RTg metal whose stopping potential is − 2 eV.
Then, which of the following statement(s)
35. Under isothermal conditions, two soap is/are true? (h = 6 .62 × 10 −34 J-s)
bubbles of radii a and b coalesce to form a
(a) For light of frequency ω , photoelectric effect is
single bubble of radius c. If the external
not possible.
pressure is p, then surface tension of the
(b) Stopping potential versus frequency graph will
bubbles is be a straight line.
p(c 3 − a3 + b 3 ) p(c 3 − a3 − b 3 ) (c) The work function of the mutual is − 2 eV.
(a) (b)
4(a + b − c )
2 2 2
4(a2 + b 2 − c 2 ) (d) The maximum kinetic energy of the
p(c 2 + a3 − b 2 ) p(a3 + b 3 − c 3 ) photoelectrons is − 2 eV.
(c) (d)
4(a + b − c )
3 3 3
4(a2 + b 2 − c 2 ) 38. p

2p0 C
Category-III (Q. Nos. 36 to 40)
Carry 2 marks each and one or more option(s) p0 A
is/are correct. If all correct answers are not marked B
and also no incorrect answer is marked, then score
V
= 2 × number of correct answers marked ÷ actual V0 2V0
number of correct answers. If any wrong option is
marked or if any combination including a wrong Consider the p - V diagram for 1 mole of an
option is marked, the answer will be considered ideal monatomic gas shown in the figure.
wrong, but there is no negative marking for the Which of the following statement(s) is/are
same and zero marks will be awarded. true?
(a) The change in internal energy for the whole
36. process is zero.
x a (b) Heat is rejected during the process.
O (c) Change in internal energy for process A → B is
v 3
− p0 V0 .
A small bar magnet of dipole moment M is 2
moving with speed v along x-direction (d) Work done by the gas during the entire process
is 2 p0 V0 .
towards a small closed circular conducting
loop of radius a with its centre O at x = 0 (see 39. The potential energy of a particle of mass
figure). Assume x >> a and the coil has a 0.02 kg moving along X -axis is given by
resistance R. Then, which of the following V = Ax (x − 4) J, where x is in metre and A is a
statement(s) is/are true? constant. Which of the following
statement(s) is/are correct?

Page 5 of 47
 (a) The particle is acted upon by a constant A particle of mass m and charge q moving with
force. velocity v enters region-b from region-a along the
(b) The particle executes simple harmonic normal to the boundary as shown in the figure.
motion.
Region-b has a uniform magnetic field B
(c) The speed of the particle is maximum at
x = 2 m.
perpendicular to the plane of the paper. Also,
π region-b has length L.
(d) The period of oscillation of the particle is s.
5
Choose the correct statement.
b qLB
40. a (a) The particle enters region- c only if v > .
c m
× × ×
qLB
(b) The particle enters region- c only if v < .
× × × m
v
× × × (c) Path of the particle is a circle in region-b.
L (d) Time spent in region-b is independent of velocity v.

Chemistry
Category-I (Q. Nos. 41 to 70) 44. p-nitro–N, N–dimethylaniline cannot be
Carry 1 mark each and only one option is correct. represented by the resonating structures.
In case of incorrect answer or any combination of O O
⊕
more than one answer, 1/4 mark will be deducted. Me2N N Me2N N
O O
41. The exact order of boiling points of the (I) (II)
compounds n-pentane, isopentane, butanone
and 1-butanol is
⊕ ⊕ O ⊕ O
(a) n-pentane < isopentane < butanone <
Me2N N Me2N N
1-butanol O
O
(b) isopentane < n-pentane < butanone <
1-butanol (III) (IV)
(c) butanone < n -pentane < isopentane < (a) I and II (b) II and IV
1-butanol (c) I and III (d) III and IV
(d) 1-butanol < butanone < n-pentane <
isopentane 45. CO2H CH3

42. The maximum number of atoms that can be 1. H OH and HO H

in one plane in the molecule
p-nitrobenzonitrile are
CH3 COOH
(a) 6 (b) 12
(c) 13 (d) 15 CH3 CH3
43. Cyclo [18] carbon is an allotrope of carbon
with molecular formula C18 . It is a ring of 18 and
2.
carbon atoms, connected by single and triple
bonds. The total number of triple bonds NO2 NO2
present in this cyclocarbon are
(a) 9 (b) 10 H Cl H 3C Cl
3. and
(c) 12 (d) 6
CH3 Cl Cl H

Page 6 of 47
 The relationship between the pair of The compounds A and B above are
compounds shown above are respectively respectively.
(a) homomer (identical), enantiomer and Ph OMe CO2H
constitutional isomer (a) and Ph
(b) enantiomer, enantiomer and diastereomer
(c) homomer (identical), homomer (identical) and Cl
constitutional isomer Ph OMe
(d) enantiomer, homomer (identical) and (b) and PhCOCH
3
geometrical isomer
Cl
46. The exact order of acidity of the compounds OH
p-nitrophenol, acetic acid, acetylene and Ph OMe CO2H
ethanol is (c) and Ph
(a) p-nitrophenol < acetic acid < acetylene < Cl
ethanol
(b) acetic acid < p-nitrophenol < acetylene < Ph OMe CO2H
ethanol and Ph
(d)
(c) acetylene < p-nitrophenol < ethanol < acetic OMe
acid
(d) acetylene < ethanol < p-nitrophenol < acetic 49. For a spontaneous reaction at all temperatures
acid which of the following is correct?
47. NH2 H (a) Both ∆H and ∆S are positive
(b) ∆H is positive and ∆S is negative
N CO2H
1. Me (c) ∆H is negative and ∆S is positive
(d) Both ∆H and ∆S are negative
O
NH2 H 50. A given amount of Fe2+ is oxidised by x mol of
MnO −4 in acidic medium. The number of moles
N CO2H
2. Me of Cr2O72− required to oxidise the same amount
O
CH3 of Fe2+ in acidic medium is
(a) x (b) 0.83 x
H
(c) 2.0 x (d) 1.2 x
N CO2H
3. H2N 51. An element crystallises in a body centered
cubic lattice. The edge length of the unit cell is
O Me
200 pm and the density of the element is 5.0 g
H cm −3 . Calculate the number of atoms in 100 g
of this element.
N CO2H
4. H2N (a) 2.5 × 1023 (b) 2.5 × 1024
O (c) 5.0 × 10 23
(d) 5.0 × 1024

The dipeptides which may be obtained from 52. Molecular velocities of two gases at the same
the amino acids glycine and alanine are temperature (T) are u1 and u2 . Their masses are
(a) Only 1 (b) Only 2 m1 and m2 respectively. Which of the following
(c) Both 1 and 2 (d) All of them expressions is correct at temperature T?
m1 m2
48. Benzaldehyde + methanol (a) = (b) m1u1 = m2u 2
u12u 22
1. dil. HCl m1 m2
dry
→ A 2  → B (c) = (d) m1u12 = m2u 22
HCl .( CH CO) O, 3 2 u1 u2
CH 3 COONa

Page 7 of 47
53. When 20 g of naphthoic acid (C11H 8O 2) is 59. Solubility products (K sp) of the salts of types
dissolved in 50 g of benzene, a freezing point MX , MX 2 and M3 X at temperature T are
depression of 2K is observed. The van’t Hoff 4 .0 × 10 −8 , 3.2 × 10 −14 and 2.7 × 10 −15
respectively. Solubilities (in mol dm −3 ) of the
. K kg mol −1 ]
factor (i) is [K f = 172
salts at temperature T are in the order.
(a) 0.5 (b) 1.0 (c) 2.0 (d) 3.0 (a) MX > MX 2 > M 3 X (b) M 3 X > MX 2 > MX
(c) MX 2 > M 3 X > MX (d) MX > M 3 X > MX 2
54. The equilibrium constant for the reaction
N 2( g )+ O 2( g ) 2NO( g ) is 4 × 10 −4 at
c 60. The reduction potential of hydrogen half-cell
2000 K. In presence of a catalyst the will be negative if
equilibrium is attained 10 times faster. (a) p(H2 ) = 1 atm and [H+ ] = 10
. M
Therefore, the equilibrium constant, in (b) p(H2 ) =1atm and [H+ ] = 2.0 M
presence of the catalyst at 2000 K is (c) p(H2 ) =2 atm and [H+ ] = 10
. M
(d) p(H2 ) =2 atm and [H+ ] = 2.0 M
(a) 4 × 10−4 (b) 4 × 10−3
−5
(c) 4 × 10 (d) 2.5 × 10−4 61. A saturated solution of BaSO 4 at 25°C is
4 × 10 −5 M. The solubility of BaSO 4 in 0.1 M
55. Under the same reaction conditions, initial
concentration of 1.386 mol dm −3 of a Na 2SO 4 at this temperature will be
substance becomes half in 40 s and 20 s . × 10−9 M
(a) 16 . × 10−8 M
(b) 16
−6
through first-order and zero-order kinetics (c) 4 × 10 M (d) 4 × 10−4 M
k 
respectively. Ratio  1  of the rate constants 62. A solution is made by a concentrated solution
 k0 
of Co(NO 3 )2 with a concentrated solution of
for first-order (k1) and zero-order (k0) of the NaNO 2 is 50% acetic acid. A solution of a salt
reactions is containing metal M is added to the mixture,
(a) 0.5 mol −1 dm 3 (b) 0.5 mol dm −3 when a yellow precipitate is formed. Metal ‘
(c) 1.0 mol dm −3 (d) 2.0 mol −1 dm 3 M’ is
56. Which of the following solutions will have (a) magnesium (b) sodium
(c) potassium (d) zinc
highest conductivity?
(a) 0.1 M CH3COOH (b) 0.1 M NaCl 63. Extraction of a metal (M) from its sulphide
(c) 0.1 M KNO 3 (d) 0.1 M HCl ore (M2S) involves the following chemical
57. Indicate the products (X ) and (Y ) in the reactions
following reactions 2 M2S + 3O 2 Heat

→ 2 M2O + 2SO 2 ↑
Na 2S + nS( n = 1 − 8 ) → (X ) M2S + 2 M2O Heat
→ 6 M + SO 2 ↑
Na 2SO 3 + S → (Y ) (a) Zn (b) Cu (c) Fe (d) Ca
(X) (Y) 64. The white precipitate (Y ), obtained on
(a) Na 2S2O 3 Na 2S2 passing colourless and odourless gas (X )
(b) Na 2S( n + 1) Na 2S2O 3 through an ammoniacal solution of NaCl,
(c) Na 2Sn Na 2S2O 3 loses about 37% of its weight on heating and
(d) Na 2S5 Na 2S2O 4 a white residue (Z) of basic nature is left.
Identify (X ), (Y ) and (Z) from following sets.
58. 2.5 mL 0.4 M weak monoacidic base
(K b = 1 × 10 −12 at 25°C) is titrated with 2/15 M (X) (Y) (Z)
HCl in water at 25°C. The concentration of (a) N2 (NH4 )2 CO 3 NH4Cl
H + at equivalence point is (K w = 1 × 10 −14 , at (b) O2 NaNH4CO 3 NaHCO 3
25°C)
(c) CO 2 NH4HCO 3 (NH4 )2 CO 3
. × 10−13 M
(a) 37 . × 10−7 M
(b) 32
(d) CO 2 NaHCO 3 Na 2CO 3
. × 10−2 M
(c) 32 (d) 2.7 × 10−2 M

Page 8 of 47
65. Which structure has delocalised π-electrons? 1. Methoxymethyl chloride
(a) O 3 (b) CO 2. Benzyl chloride
(c) HCN (d) O 3 and HCN 3. Neopentyl chloride
66. The H 3O+ ions has the following shape 4. Propyl chloride
(a) 1 and 3 (b) 2 and 3
(a) tetrahedral (b) pyramidal
(c) 2 and 4 (d) 3 and 1
(c) triangular planar (d) “T” shaped
72. The products X and Y which are formed in
67. For the reaction 14 N(α , p) 17O, 1.16 MeV
the following sequence of reactions are
(Mass equivalent = 0 .00124 amu) of energy is respectively.
absorbed. Mass on the reactant side is
1. Zn / HCl, ∆
18.00567 amu and proton mass = 100782
. dil. HNO 3
Phenol → X 2.(CH
    → Y
amu. The atomic mass of 17O will be CO) O(1 equiv.)
3 2

(a) 17.0044 amu (b) 16.9991 amu OH OH

(c) 17.0114 amu (d) 16.9966 amu COCH3

68. A solution of NaNO 3, when treated with a (a) and

mixture of Zn dust and ‘A’ yields ammonia. ‘
A’ can be NO NH2
(a) caustic soda
(b) dilute sulphuric acid OH OCOCH3
(c) concentrated sulphuric acid
(d) sodium carbonate
(b) and
69. Indicate the number of unpaired electrons in
K 3[Fe(CN)6] and K 4[Fe(CN)6].
NO2 NH2
K 3[Fe(CN)6 ] K 4[Fe(CN)6 ]
(a) 1 0 OH OH

(b) 5 6
(c) 6 5 (c) and
(d) 0 1
NO2 NHCOCH3
70. Which of the following compounds have
magnetic moment identical with OH OH
[Cr(H 2O)6]3+ ?
(a) [Cu(H2O)6 ]2+ (b) [Mn(H2O)6 ]3+
(d) and
(c) [Fe(H2O)6 ]3+ (d) [Mn(H2O)6 ]3 +
COCH3
Category-II (Q. Nos. 71 to 75)
NO NH2
Carry 2 marks each and only one option is
correct. In case of incorrect answer or any 73. The atomic masses of helium and neon are
combination of more than one answer, 1/2 mark 4.0 and 20.0 amu respectively. The value of
will be deducted. the de-Broglie wavelength of helium gas at
− 73 °C is M times the de-Broglie wavelength
71. Among the following chlorides the of neon at 727°C. The value of M is
compounds which will be hydrolysed most (a) 5 (b) 25
easily and most slowly in aqueous NaOH 1 1
(c) (d)
solution are respectively: 5 25

Page 9 of 47
74. The mole fraction of a solute in a binary 77. The compounds X and Y are respectively
solution is 0.1 at 298 K, molarity of this 1. Mg, ether
solution is same as its molality. Density Br
2. Acetaldehyde
CH3 X
of this solution at 298 K is 2.0 g cm −3 . 3. Br2 / NaOH
The ratio of molecular weights of the 4. H2O+
solute and the solvent (Msolute / Msolvent) is 1. SOCl2
1 1 2. NH3
(a) 9 (b) (c) 4.5 (d) Y
9 4.5 3. Br2 / NaOH

75. 5.75 mg of sodium vapour is converted CH3 CH3

to sodium ion. If the ionisation energy of (a) H3C and H3C
OH NH2
sodium is 490 kJ mol −1 and atomic
weight is 23 units, the amount of energy
CH3
needed for this conversion will be (b) H3C NH2
and H3C
(a) 1.96 kJ (b) 1960 kJ O
(c) 122.5 kJ (d) 0.1225 kJ
CH3
Category-III (Q.Nos. 76 to 80) (c) H3C and H3C CONH2
OH
Carry 2 marks each and one or more
option(s) is/are correct. If all correct answers
are not marked and no incorrect answer is (d) H3C CO2H and H3C NH2
marked, then score = 2 × number of correct
answers marked ÷ actual number of correct 78. Aqueous solution of HNO 3, KOH, CH 3COOH and
answers. If any wrong option is marked or if CH 3COONa of identical concentration are
any combination including a wrong option is provided. The pair(s) of solutions which form a
marked, the answer will be considered buffer upon mixing is (are)
wrong, but there is no negative marking for (a) HNO 3 and CH3COOH
the same and zero mark will be awarded. (b) KOH and CH3COONa
(c) HNO 3 and CH3COONa
76. The product(s) in the following sequence
(d) CH3COOH and CH3COONa
of reactions will be
1. Na/NH 3 (liq.) 79. Reaction of silver nitrate solution with
ethanol, − 33° C
Me  C ≡≡ C  Me 2  → phosphorus acid produces
. dil.alkaline KMnO 4 (a) silver phosphite
Product(s) (b) phosphoric acid
Me Me (c) metallic silver
H OH H OH (d) silver phosphate
(a) (b)
H OH HO H
80. N 2H 4 and H 2O 2 show similarity in
Me Me
(a) density
Me Me (b) reducing nature
HO H HO H (c) oxidising nature
(c) H OH (d) HO H (d) hybridisation of central atoms
Me Me

Page 10 of 47
 Mathematics
Category-I (Q. Nos. 1 to 30) 6. The value of the integral
1
  x + 1 2  x − 1 2  2
1
Carry 1 marks each and only one option is 2

correct. In case of incorrect answer or any ∫   x −1  x + 1  dx is equal to

+ − 2
combination of more than one answer, 1/4 mark −1 2  
will be deducted.
(a) loge   (b) 4loge  
4 3
 3  4
 x x 2
e − x −1−  (c) 4loge   (d) loge  
4 3
1. If I = lim sin  2  , then limit  3  4
x→0  x2 
  x
  3
7. If ∫ (e x − 1)−1 dx = log e
2
then the value of x
(a) does not exist log e 2
(b) exists and equals 1 is
(c) exists and equals 0 1
1 (a) 1 (b) e 2 (c) log 4 (d)
(d) exists and equals e
2
8. The normal to a curve at P(x , y) meets the
2. Let f : R → R be such that f (0) = 0 and
X -axis at G. If the distance of G from the
| f ′ (x)| ≤ 5 for all x. Then f ()
1 is in
origin is twice the abscissa of P then the
(a) (5, 6) (b) [− 5, 5] curve is
(c) (− ∞, − 5) ∪ (5, ∞ ) (d) [− 4, 4]
(a) a parabola (b) a circle
sin 2 x
3. If ∫ dx (c) a hyperbola (d) an ellipse
(a + bcos x)2
9. The differential equation of all the ellipses
 a  centred at the origin and have axes as the
= α log e|a + bcos x| + + c,
a + bcos x 
co-ordinate axes is

(a) y2 + xy′2 − yy′ = 0
then α is equal to
(b) xyy′ ′ + xy′2 − yy′ = 0
2 2
(a) (b) (c) yy′ + xy′2 − xy′ = 0
b2 a2
2 2 (d) x2 y′ + xy′ ′ − 3 y = 0
(c) − 2
(d) − 2
b a dy d2y
where y′ ≡ , y′ ′ ≡ 2
2x dx dx
f ()t
4. Let g(x) = ∫ t
dt where x > 0 and f be
10. If x
dy
+ y=
xf (xy)
, then| f (xy)| is equal to
x
continuous function and f (2 x) = f (x), then dx f ′ (xy)
2 2
(a) g ( x) is strictly increasing function (a) ke x /2
(b) ke y /2

(b) g ( x) is strictly decreasing function x2 y2

(c) ke (d) ke
(c) g ( x) is constant function
(d) g ( x) is not derivable function 11. The straight the through the origin which
3 divides the area formed by the curves
| x − 1|
5. ∫ | x − 2| + | x − 3| dx is equal to y = 2 x − x 2 , y = 0 and x = 1 into two equal
1 halves is
4 3 (a) y = x (b) y = 2 x
(a) 1 + loge 3 (b) 1+ loge 3
3 4 3 2
(c) y = x (d) y = x
4 3
(c) 1 − loge 3 (d) 1 − loge 3 2 3
3 4

Page 11 of 47
 5
18. Consider the real valued function h : {0, 1, 2,
12. The value of ∫ max{ x 2 , 6 x − 8} dx is
0
..... 100} → R such that h(0) = 5, h(100) = 20
1
(a) 72 (b) 125 and satisfying h(p) = { h(p +1) + h(p – 1)} for
(c) 43 (d) 69 2
every p = 1, 2 ……99. Then the value of h() 1 is
13. A bulb is placed at the centre of a circular (a) 5.15 (b) 5.5
track of radius 10 m. A vertical wall is erected (c) 6 (d) 6.15
touching the track at a point P. A man is
running along the track with a speed of 10 19. If|z| = 1 and z ≠ ± 1, then all the points
m/sec. Starting from P the speed with which z
representing lie on
his shadow is running along the wall when 1 − z2
he is at an angular distance of 60° from P is
(a) a line not passing through the origin
(a) 30 m/sec (b) 40 m/sec
(b) the line y = x
(c) 60 m/sec (d) 80 m/sec
(c) the X -axis
14. Two particles A and B move from rest along a (d) the Y-axis
straight line with constant accelerations f
and f ′ respectively. If A takes m sec. more 20. Let C denote the set of all complex numbers.
than that of B and describes n units more Define A = {(z , w)| z , w ∈ C and|z| = |w|},
than that of B in acquiring the same velocity,
B = { z , w)|z , w ∈ C and z 2 = w 2 }. Then
then
(a) (f + f ′ ) m2 = ff ′ n (b) (f − ff ′ ) m2 = ff ′ n (a) A = B (b) A ⊂ B
1 1 (c) B ⊂ A (d) A ∩ B = ϕ
(c) (f ′ − f ) n = ff ′ m2 (d) (f + f ′ ) m = ff ′ n2
2 2 21. Let α , β be the roots of the equation
15. Let α , β , γ be three non-zero vectors which x 2 − 6 x − 2 = 0 with α > β. Ifa n = α n − β n for
are pairwise non-collinear. If α + 3β is a − 2a 8
n ≥ 1, then the value of 10 is
collinear with γ and β + 2 γ is collinear with α, 2a 0
then α + 3β + 6 γ is (a) 1 (b) 2
(a) γ (b) 0 (c) 3 (d) 4
(c) α + γ (d) α
22. For x ∈ R , x ≠ − 1, if
16. Let f :R → R be given by f (x) = | x 2 − 1|, x ∈ R.
(1 + x)2016 + x (1 + x)2015 + x 2 (1 + x)2014
Then 2016
(a) f has a local minimum at x = ± 1but no local + .... + x 2016 = Σ a i . x i , then a17 is equal to
i =0
maximum.
(b) f has a local minimum at x = 0 but no local 2016! 2016!
(a) (b)
minimum. 17 !1999! 16!
(c) f has a local minima at x = ± 1and a local 2017 ! 2017 !
(c) (d)
maxima at x = 0. 2000! 17 !2000!
(d) f has neither a local maxima nor a local minima
at any point. 23. Five letter words, having distinct letters, are
17. Let a , b, c be real numbers, each greater than to be constructed using the letters of the
2 3 5 word ‘EQUATION’ so that each word
1, such that log b a + log c b + log a c = 3. contains exactly three vowels and two
3 5 2
consonants. How many of them have all the
If the value of b is 9, then the value of ‘a’
vowels together?
must be
27 (a) 3600 (b) 1800
(a) 3 81 (b) (c) 18 (d) 27
2 (c) 1080 (d) 900

Page 12 of 47
24. What is the number of ways in which an 31. Let T and U be the set of all orthogonal
examiner can assign 10 marks to 4 questions, matrices of order 3 over R and the set of all
giving not less than 2 marks to any question? non-singular matrices of order 3 over R
(a) 4 (b) 6 respectively. Let A = { − 1, 0 , 1}, then
(c) 10 (d) 16 (a) there exists bijective mapping between A and T,
U.
25. The digit in the unit’s place of the number (b) there does not exist bijective mapping between
1! + 2 ! + 3 ! + .... + 99 ! is A and T, U.
(a) 3 (b) 0 (c) there exists bijective mapping between A and T
(c) 1 (d) 7 but not between A and U.
(d) there exists bijective mapping between A and U
26. If M is a 3 × 3 matrix such that (0, 1, 2) but not between A and T.
M = (1 0 0), (3, 4 5) M = (0, 1, 0), then
(6 7 8) M is equal to 32. Four persons A , B, C and D throw and
(a) (2 1 −2 ) (b) (0 0 1) unbiased die, turn by turn, in succession till
(c) (−1 2 0) (d) (9 10 8) one gets an even number and win the game.
What is the probability that A wins the game
1 0 0  if A begins?
 
27. Let A = 0 cos t sin t (a)
1
(b)
1
(c)
7
(d)
8
0 − sin t cos t
  4 2 15 15

Let λ 1 , λ 2 , λ 3 be the roots of det(A − λ I 3) = 0, 33. The mean and variance of a binomial
where I 3 denotes the identity matrix. If distribution are 4 and 2 respectively. Then
the probability of exactly two successes is
λ 1 + λ 2 + λ 3 = 2 + 1, then the set of possible
7 21 7 9
values of t, − π ≤ t < π is (a)
64
(b)
128
(c)
32
(d)
32
π
(a) a void set (b)  
4
π π
(c) − , 
π π
(d) − , 
34. Let Sn = cot −1 2 + cot −1 8 + cot −118
 4 4  3 3
+ cot −1 32 + ... to nth term. Then lim Sn is
n→ ∞
28. Let A and B two non singular skew
π π π π
symmetric matrices such that AB = BA, then (a) (b) (c) (d)
A 2 B2 (A T B)−1 (AB−1)T is equal to 3 4 6 8

(a) A 2 (b) − B2 35. If a > 0 , b > 0 then the maximum area of the
(c) − A 2
(d) AB parallelogram whose three vertices are O(0 , 0),
A(a cos θ , bsin θ) and B(a cos θ , − bsin θ) is
29. If a n(> 0) be the nth term of a G.P. then (a) ab when θ =
π
(b) 3ab when θ =
π
4 4
log a n log a n + 1 log a n + 2 π
(c) ab when θ = − (d) 2ab
log a n + 3 log a n + 4 log a n + 5 is equal to 2
log a n + 6 log a n + 7 log a n + 8 36. Let A be the fixed point (0, 4) and B be a
(a) 1 (b) 2 (c) −2 (d) 0 moving point on X -axis. Let M be the
midpoint of AB and let the perpendicular
30. Let A , B, C be three non-void subsets of set S. bisector of AB meets the Y -axis at R. The
Let (A ∩ C) ∪ (B ∩ C ′) = φ where C ′ denote the locus of the midpoint P of MR is
complement of set C in S. Then 1
(a) y + x2 = 2 (b) x2 + ( y − 2 )2 =
(a) A ∩ B = φ (b) A ∩ B ≠ φ 4
1
(c) A ∩C = A (d) A ∪C = A (c) ( y − 2 )2 − x2 = (d) x2 + y2 = 16
4

Page 13 of 47
37. A moving line intersects the lines x + y = 0 44. The locus of the centre of a variable circle
and x − y = 0 at the points A , B respectively which always touches two given circles
such that the area of the triangle with externally is
vertices (0,0 ), A and B has a constant area C. (a) an ellipse (b) a hyperbola
The locus of the mid-point AB is given by the (c) a parabola (d) a circle
equation
45. A line with positive direction cosines passes
(a) ( x2 + y2 )2 = C 2 (b) ( x2 − y2 )2 = C 2
through the point P(2 , −1, 2) and makes equal
(c) ( x + y)2 = C 2 (d) ( x − y)2 = C 2 angle with co-ordinate axes. The line meets
the plane 2 x + y + z = 9 at point Q. The length
38. The locus of the vertices of the family of of the line segment PQ equals.
parabolas 6 y = 2 a 3 x 2 + 3 a 2 x − 12 a is (a) 1 unit (b) 2 unit
105 64 (c) 3 unit (d) 2 unit
(a) xy = (b) xy =
64 105
35 16  5 x + 12 1 − x 2 
(c) xy = (d) xy = 46. For y = sin −1 
16 35  ;| x| ≤ 1, if
 13 
39. A ray of light along x + 3 y = 3 gets a(1 − x ) y 2 + bxy1 = 0 then (a , b) =
2

reflected upon reaching X -axis, the equation

(a) (2, 1) (b) (1, − 1)
of the reflected ray is
(c) (− 1, 1) (d) (1, 2)
(a) y = x + 3 (b) 3 y = x − 3
(c) y = 3 x − 3 (d) 3 y = x − 1 47. f (x) is real valued function such that
2 f (x) + 3 f (− x) = 15 − 4 x for all x ∈ R. Then
40. Two tangents to the circle x 2 + y 2 = 4 at the
f (2) =
points A and B meet at M(− 4 , 0). The area of
(a) −15 (b) 22 (c) 11 (d) 0
the quadrilateral MAOB, where O is the origin
is 48. Consider the functions f1(x) = x ,
(a) 4 3 sq units (b) 2 3 sq units f 2 (x) = 2 + log e x , x > 0 . The graphs of the
(c) 3 sq units (d) 3 3 sq units functions intersect
41. From a point (d , 0) three normals are drawn (a) once in (0, 1) but never in (1, ∞ )
(b) once in (0, 1) and once in (e 2 , ∞ )
to the parabola y = x , then
2
(c) once in (0, 1) and once in (e, e 2 )
1 1
(a) d = (b) d > (d) more than twice in (0, ∞ )
2 2
1 1 49. The equation 6 x + 8 x = 10 x has
(c) d < (d) d =
2 3
(a) no real root.
42. If from a point P(a , b, c), perpendicular PA and (b) infinitely many rational roots
PB are drawn to YZ and ZX -planes (c) exactly one real root
respectively, then the equation of the plane (d) two distinct real roots
OAB is 50. Let f : D → R where D = [ −0 , 1] ∪ [2, 4] be
(a) bcx + cay + abz = 0 (b) bcx + cay − abz = 0 defined by
(c) bcx − cay + abz = 0 (d) bcx − cay − abz = 0
 x, if x ∈[0 , 1]
43. The co-ordinate of a point on the auxiliary f (x) =  Then,
circle of the ellipse x 2 + 2 y 2 = 4  4 − x , if x ∈[2 , 4 ]
(a) Rolle’s theorem is applicable to f in D.
corresponding to the point on the ellipse
(b) Rolle’s theorem is not applicable to f in D.
whose eccentric angle is 60° will be
(c) there exists ξ ∈ D for which f′(ξ) = 0 but Rolle’s
(a) ( 3, 1) (b) (1, 3 ) theorem is not applicable.
(c) (1, 1) (d) (1, 2) (d) f is not continuous in D.

Page 14 of 47
 Category-II (Q.Nos. 51 to 65) 58. If the tangent at the point P with
Carry 2 marks each and only one option is co-ordinates (h, k) on the curve y 2 = 2 x 3 is
correct. In case of incorrect answer or any perpendicular to the straight line 4 x = 3 y,
combination of more than one answer, 1/2 mark
will be deducted. then
(a) (h, k ) = (0, 0) only
(b) (h, k ) =  , −  only
51. Let f (x) be continuous periodic function with 1 1
a+T  8 16 
period T. Let I = ∫ f (x) dx. Then (c) (h, k ) = (0, 0) or  , 
1 1
 8 16 
a
(a) I is linear function in ‘a ’ (d) no such point P exists
(b) I does not depend on ‘a’
59. The co-efficient of a 3b4c 5 in the expansion of
(c) 0 < I < a2 + 1 where I depends on ‘a’
(bc + ca + ab)6 is
(d) I is quadratic function in ‘a’
12 ! 6!
(a) (b)
e− t
1 a
et 3! 4! 5! 3!
52. If b = ∫ dt, then ∫ is
(d) 3. 
t +1 t − a −1 6! 
a −1 (c) 33 
0
 3! 3!
(a) be a (b) be − a (c) − be − a (d) − be a
60. Three unequal positive numbers a , b, c are
53. The differential of f (x) = log e (1 + e10x ) − tan −1 such that a , b, c are in G.P. while
(e 5x ) at x = 0 and for dx = 0.2 is  5c   7 b  2a 
log   , log   , log   are in A.P. Then
(a) 0.5 (b) 0.3 (c) − 02
. (d) − 0.5  2a   5c   7 b
a , b, c are the lengths of the sides of
54. Given that f :S → R is said to have a fixed
(a) an isosceles triangle
point at c of S if f (c) = c. (b) an equilateral triangle
Let f : [1, ∞) → R be defined by f (x) = 1 + x. (c) a scalene triangle
Then (d) a right-angled triangle
(a) f has no fixed point in [1, ∞ )
(b) f has unique fixed point in [1, ∞ )
61. The determinant
(c) f has to fixed points in [1, ∞ ) a2 + 10 ab ac
(d) f has infinitely many fixed points in [1, ∞ ) ab b 2 + 10 bc is
4x ac bc c 2 + 10
 3 x − 1
55. The lim   equals
x → ∞  3 x + 1 (a) divisible by 10 but not by 100
(b) divisible by 100
(a) 1 (b) 0 (c) e −8 / 3 (d) e −4 / 9 (c) not divisible by 100
(d) not divisible by 10
56. The area bounded by the parabolas
x2 62. Let R be the real line. Let the relations S and T
y = 4 x2, y = and the straight line y = 2 is
9 or R be defined by
20 2 S = {( x, y) : y = x + 1, 0 < x < 2}, T = {( x, y) : x − y is
(a) sq. unit (b) 10 5 sq. unit an integer}. Then
3
10 3 (a) both S and T are equivalence relations on R
(c) sq. unit (d) 10 2 sq. unit (b) T is an equivalence on R but S is not
7
(c) neither S nor T is an equivalence relation on R
57. If a (α × β) + b(β × γ) + c(γ × α) = o, where (d) S is an equivalence relation on R but T is not
a , b, c are non-zero scalars, then the vectors 63. The plane lx + my = 0 is rotated about its line
α , β , γ are
of intersection with the plane z = 0 through
(a) parallel (b) non-coplanar
(c) coplanar (d) mutually perpendicular an angle α. The equation changes to

Page 15 of 47
 7
(a) lx + my ± tanα l 2 + m2 = 0 7K
68. The remainder when 7 7 (22 time 7) is
(b) lx + my ± z tanα l 2 + m2 + 1 = 0 divided by 48 is
(c) lx + my ± z tanα l 2 + 1 = 0 (a) 21 (b) 7
(c) 47 (d) 1
(d) lx + my ± z tanα l + m = 02 2

69. Whichever of the following is/are correct?

64. The points of intersection of two ellipses 2
dx 1
x 2 + 2 y 2 − 6 x − 12 y + 20 = 0 and (a) To evaluate I1 = ∫4+ x 2
, it is possible to x =
t
−2
2 x 2 + y 2 − 10 x − 6 y + 15 = 0 lie on a circle. 1
The centre of the circle is (b) To evaluate I2 = ∫ ( x2 + 1) dx, it is possible to
(a) (8, 3) (b) (8, 1) 0
put x = sec t
(c)  , 3
8
(d) (3, 8) 1
3 
π
(c) To evaluate I2 = ∫ ( x2 + 1) dx, it is not possible
0
3
sin x to put x = cosec θ
65. Let I =
π
∫ x
dx . Then
(d) To evaluate I1, it is not possible to put x =
1
4
t
3 2 3 2 3
(a) ≤ I≤ (b) ≤ I≤
8 6 2π π 70. A plane meets the co-ordinate axes at the
3 2 4π points A , B, C respectively such a way that
(c) ≤ I≤ (d) π ≤ I ≤
9 16 3 the centroid of ∆ABC is (1, r , r 2 ) for some
real r. If the plane passes through the point
Category-III (Q. Nos. 66 to 75) (5, 5, − 12) then r =
3
Carry 2 marks each and one or more option(s) (a) (b) 4
2
is/are correct. If all correct answers are not 3
marked and also no incorrect answer is marked, (c) − 4 (d) −
2
then score = 2 × number of correct answers
marked ÷ actual number of correct answers. If any 71. Let P be a variable point on a circle C and Q
wrong option is marked or if any combination be a fixed point outside C. If R is the
including a wrong option is marked, the answer midpoint of the line segment PQ, then locus
will considered wrong, but there is no negative of R is
marking for the same and zero marks will be (a) a circle
awarded. (b) a circle and a pair of straight lines
(c) a rectangular hyperbola
66. If|z + i| − |z − 1| = |z| − 2 = 0 for a complex (d) a pair of straight lines
number z, then z is equal to 
(a) 2 (1 + i ) (b) 2 (1 − i )
n n n
72. lim  + +
(c) 2 (− 1 + i ) (d) 2 (− 1 − i ) n→ ∞
 (n )
3
(n + 4) 3
(n + 8)3
x 3x + 2 2 x −1
n 
67. 2 x −1 4x 3 x + 1 = 0 is true for + ..... +  is
7 x − 2 17 x + 6 12 x − 1 [ n + 4 (n −1)]3 
(a) only one value of x 5− 5 5+ 5
(a) (b)
(b) only two value of x 10 10
(c) only three values of x 2+ 3 2− 3
(c) (d)
(d) infinitely many value of x 2 2

Page 16 of 47
 0 , if − 1≤ x < 0 (a) fmin = 3 −1
 (b) fmax =
π 1
+ ln 3
73. Let f (x) = 1, if x =0 and let
6 4
2 , if 0 < x ≤1 π 1
 (c) fmin = − ln 3
x 3 4
F(x) = ∫ f ()t dt, − 1 ≤ x ≤ 1, then (d) fmax =
π
12
+ ln 5
−1
(a) F is continuous function in [− 1, 1]
75. Let f and g be periodic functions with the
(b) F is discontinuous function in [− 1, 1]
(c) F ′( x) exists at x = 0 periods T1 and T2 respectively. Then f + g is
(d) F ′( x) does not exist at x = 0 (a) periodic with period T1 + T2
(b) non-periodic
74. The greatest and least value of
(c) periodic with the period T1
1 1 
f (x) = tan −1 x − ln x on  , 3  are (d) periodic when T1 = T2
2  3 

Answers
Physics
1. (d) 2. (c) 3. (c) 4. (a) 5. (a) 6. (c) 7. (*) 8. (a) 9. (a) 10. (c)
11. (a) 12. (b) 13. (d) 14. (a) 15. (b) 16. (b) 17. (d) 18. (b) 19. (b) 20. (d)
21. (a) 22. (b) 23. (c) 24. (b) 25. (d) 26. (d) 27. (d) 28. (c) 29. (c) 30. (c)
31. (b) 32. (c) 33. (b) 34. (b) 35. (b) 36. (b,c) 37. (a,b) 38. (b,c) 39. (b,c) 40. (a,d)

Chemistry
41. (b) 42. (d) 43. (a) 44. (b) 45. (c) 46. (d) 47. (d) 48. (d) 49. (c) 50. (b)
51. (d) 52. (d) 53. (a) 54. (a) 55. (a) 56. (d) 57. (b) 58. (d) 59. (d) 60. (c)
61. (d) 62. (c) 63. (b) 64. (d) 65. (a) 66. (b) 67. (b) 68. (a) 69. (a) 70. (d)
71. (a) 72. (c) 73. (a) 74. (a) 75. (d) 76. (b,c) 77. (d) 78. (c, d) 79. (b, c) 80. (b,c,d)

Mathematics
1. (c) 2. (b) 3. (c) 4. (c) 5. (b) 6. (c) 7. (c) 8. (c) 9. (b) 10. (a)
11. (d) 12. (c) 13. (b) 14. (c) 15. (b) 16. (c) 17. (d) 18. (a) 19. (d) 20. (c)
21. (c) 22. (d) 23. (c) 24. (c) 25. (a) 26. (c) 27. (c) 28. (c) 29. (d) 30. (a)
31. (b) 32. (d) 33. (a) 34. (b) 35. (a) 36. (a) 37. (b) 38. (a) 39. (b) 40. (a)
41. (b) 42. (b) 43. (b) 44. (b) 45. (c) 46. (b) 47. (c) 48. (c) 49. (c) 50. (b)
51. (b) 52. (c) 53. (a) 54. (b) 55. (c) 56. (a) 57. (c) 58. (b) 59. (d) 60. (c)
61. (b) 62. (b) 63. (d) 64. (c) 65. (a) 66. (b, c) 67. (d) 68. (b) 69. (c,d) 70. (a,c)
71. (a) 72. (a) 73. (a, d) 74. (b, c) 75. (d)

(*) None of the option is correct.

Page 17 of 47
 Answer with Explanations
Physics
1. (d) The situation is as shown in the figure below 1 12.5
⇒ 1− =
n2 136 .
µ1 =1 µ2 = 4 125
. 1
3 ⇒ 1− = 2
136
. n
1
⇒ = 0.080
n2
⇒ n = 353
. ≈4
So, n2 = n = 4 th excited state.
Given, P = 5D
1 1 n2
∴ f = = m = 20 cm 4. (a) Radius (r) of nth orbit in H-atom = × 0.529 Å
P 5 Z
Let u = − ∞ (object distance) Speed (v) of electron in nth orbit in H-atom
= 2.19 × 106   m/s
Then, v = f (by sign convention) Z
Using formula for refraction at spherical surface,  n
µ 2 µ1 µ 2 − µ1 Energy (E) of electron in nth orbit in H-atom
− =
v u R −13.6
= eV
4 n2
−1
4 1
⇒ − = 3 [Q v = 20 cm] So, the quantity which is proportional to quantum
3 × (20) (−∞) R number n is rv.
1 1 5. (a) The net voltage in the circuit is (10 − 9) V = 1 V
⇒ =
15 3R This leads to reverse bias of diode in the circuit.
⇒ R = 5cm Hence, current through the diode will equal
to 0 mA.
2. (c) Given, D = 1.2 m, d = 0.02 cm = 0.02 × 10−2 m
According to question, 6. (c) The given logic circuit is
3Dλ 5Dλ AB
− . × 10−2
= 018 A
d 2d
B
3 × 1.2 5 × 1.2
λ −  = 0.18 × 10−2
Y
 0.02 × 10−2 2 × 0.02 × 10−2 
AB
⇒ λ3 −
5
. × 10−2 × 0.02 × 10−2
× 1.2 = 018
 2
. × 10−4 × 0.02 × 2
018 Output is written as
⇒ λ= m Y = AB + AB
1.2
When A = 0, B = 1,
⇒ λ = 0.006 × 10−4 m
then Y = 0 ⋅ 1 + 0 ⋅1
⇒ λ = 600 × 10−9 m
= 0 ⋅ 0 + 1 ⋅1
= 600nm = 0+1
3. (c) Let initially the electron in hydrogen atom be =1
in ground state, i.e. n1 = 1 and after bombarding, it When A = 0 , B = 0,
jumps to nth energy level i.e. n2 = n, then then Y = 0⋅ 0 + 0 ⋅ 0
136. . 
136 = 0 ⋅1 + 1 ⋅ 0
12 . 5 eV =  2 − 2  eV
 ()
1 n  =0+ 0=0

Page 18 of 47
7. (*) According to question, from dimensional From Newton’s equation of motion,
analysis,
N 2 = 3ma = 3m ×
F Q a = F 
 
R ∝ e ambhc 6m  6m 
⇒ R = ke ambhc F
⇒ N2 =
2
Using dimensional formula of R, e, m and h,
Hence, F > N1 > N 2.
[M 0L−1 T0 ] = [M1 / 2L3/ 2T−1 ]a[M]b[ML2T−1 ]c
9. (a) At maximum compression of spring,
1 e2 e2
{Since, F = ⋅ 2 = 2 total kinetic energy of first block = potential
4 π ε0 r r energy of spring
⇒ e 2 = Fr 2 ⇒
1 1 2
mv = kx
2

[e] = [Fr 2]1 / 2 = [MLT−2 ⋅ L2]1 / 2 = [M1 / 2L3/ 2T−1 ]} 2 2

m
⇒ [M 0L−1 T0 ] = [M a/ 2L3a/ 2T− a][M b][M cL2c T− c ] ⇒ x= ⋅v
k
a 3a
+b + c + 2c
⇒ [M 0L−1 T0 ] = [M 2 L2 T− a− c ] 10. (c) During first half of the motion (i.e. upto x = 20
a m) acceleration in increasing linearly is given by
∴ + b+ c=0 …(i) 5 x
2 a= x+5 ⇒ a= + 5
3a 20 4
+ 2c = − 1 …(ii)
2 ⇒
dv x
= + 5 Q a = dv 
 
dt 4  dt 
−a − c = 0 …(iii)
v ⋅ dv x Q dx = v ⇒ dt = dx 
On solving Eqs. (i), (ii) and (iii), we get ⇒ = +5  
a = 2, b = 1, c = − 2 dx 4  dt v
v 20
∴ R ∝ e 2mh−2 x 
2
⇒ ∫ v ⋅dv = ∫  4 + 5 ⋅ dx
e m 5 0
⇒ R∝
h2 v 2 v
 x2 
2

Hence, no option is correct. ⇒   = + 5x 

2
 5  8 0
8. (a) Given,
v2 25 400
⇒ − = + 100
5 2 8
3m
F 2m v2 25
m ⇒ = 150 + ⇒ v2 = 325
2 2
Since, the table is frictionless, hence acceleration of Now, in second half of motion, acceleration is
the whole system is given as
constant, i.e. a = 10m / s2
F F
a= = ⇒ v2 − u2 = 2as
m + 2m + 3m 6m
Free body diagram at 1st block (left most) ⇒ v ′2 − v2 = 2as (take, v = v′, u = v)
a ⇒ v ′ − 325 = 2 × 10 × (35 − 20)
2
(Q v2 = 325)
F m N1 ⇒ v′ = 625 = 25m/s
From Newton's equation of motion, 11. (a) The given situation is shown below
F − N1 = ma = m ×
F Qa = F 
 
6m  6m 
θ
5F Tmin
⇒ N1 = Tmax
6 l
O
Free body diagram of 3rd block (right most)
a h θ
F 3m v
N2 mg cosθ
mg

Page 19 of 47
 Tmin = mg cosθ …(i) Kinetic energy
mv2 =  mvCM + I CMω2 
1 2 1
Tmax − mg = …(ii)  2 
l 2
By law of conservation of energy, 1 2
1 mL2 P 2L2 × 144 
=  × m ×   + ×
P
1 × 
mgh = mv2  m 4 × m2 × L4 
2 2 12
2
1 P2
⇒ mg(l − l cosθ) = mv2 [Q h = l − l cosθ] = [1 + 3]
2 2m
2mg(l − l cosθ) = mv2 2P 2
=
m
⇒ 2mgl(1 − cosθ) = mv2 …(iii)
14. (a) Centre of mass of three particles ( i.e. 1kg, 2kg
From Eqs. (ii) and (iii), we get
and 3kg)
2mgl(1 − cosθ)
Tmax − mg = 1r1 + 2r2 + 3r3
l = [1$i + 2$j + 3k$]
6
⇒ Tmax − mg = 2mg(1 − cosθ)
 m1 r1 + m2r2 + m3r3 
⇒ 2Tmin − mg = 2mg(1 − cosθ) [QTmax = 2Tmin]
QCM = m + m + m 
⇒ 2mg cosθ − mg = 2mg(1 − cosθ) [from Eq. (i)]  1 2 3 
⇒ 2cosθ − 1 = 21
( − cosθ) where, r1 , r2 and r3 are position vector of mass 1kg
⇒ 2cosθ − 1 = 2 − 2cosθ 2kg and 3kg, respectively.
⇒ 4 cosθ = 3 Now, centre of mass of two particles ( i.e. 3kg and
3 2kg)
⇒ cosθ = 3r4 + 2r5
4 $]
= [− $i + 3$j − 2k
3 3 5
∴ Tmax = 2Tmin = 2mg cosθ = 2mg × = mg
4 2 where, r4 and r5 are position vector of mass 1 kg and
3 2 kg.
⇒ Tmax = mg Now, according to question, if 5kg mass is added to
2
whole particle system, then entire mass lies on CM
12. (b) In projectile motion, horizontal component at of first system,
velocity remains constant with time. 1r1 + 2r2 + 3r3 + 3r4 + 2r5 + 5r6 $]
= [1$i + 2$j + 3k
Hence, correct representation of graph between t 16
and ux is shown in option (b).
where, r6 is position vector of 5 kg mass.
13. (d) L
⇒ 6$i + 12$j + 18k $ − 5$i + 15$j − 10k$ + 5r
6
$
= 16$i + 32$j + 48k
P
⇒ $
5r6 = 15$i + 5$j + 40k
The given impulse acts as both linear and an $
⇒ r = 3$i + $j + 8k
6
angular impulse.
Linear impulse = P = mvCM (where, vCM = velocity Hence, position of 5 kg mass is (3, 1, 8).
of centre at mass of rod) 15. (b) Given, density of body = 1.2 × 103 kg / m 3 = ρb
L
Angular impulse = P × = I CMω Density of liquid = 24
. × 103 kg / m 3 = ρl
2
mL2 Height of fall = 1m = H
where, I CM =
12 Let the volume of the body be V.
and ω is angular velocity at rod about centre of Then, buoyant force acting on the body when it is
mass, totally immersed in liquid = (ρl Vg)
PL Weight at the body = (ρbVg)
i.e ω=
2I CM Net upward force acting on the body = (ρl − ρb)Vg

Page 20 of 47
 Net deceleration produced 17. (d) Given figure is
Net upward force p
(a) =
Mass of body
(ρl − ρb)Vg 1
(a) = p0
2
ρbV
(ρl − ρb) 3
(a) = g
ρb V
V0 2V0
Let initial velocity of the body be u, then
1 Process 1 is isobaric expansion (p = constant).
(ρbV)u2 = ρbVgH Hence, temperature of gas will increase, therefore
2
∆U1 will be positive.
⇒ u2 = 2gH
Process 2 is an isothermal process, ∆U 2 = 0
Final velocity of the body will be zero. Process 3 is an adiabatic expansion, hence
⇒ v2 − u2 = 2as temperature of gas will fall.
(ρ − ρb) g ∴ ∆U 3 = negative
⇒ (0)2 − 2gH = − 2 l ×s
ρb Therefore, ∆U1 > ∆U 2 > ∆U 3
ρb  1.2 × 103  18. (b) The van der Waals’ equation for real gas is as
⇒ s= ⋅H=  ⋅1
ρl − ρb  2.4 × 10 3
− 1.2 × 10 3
 follows
an2
=
1.2
=1 m p + 2 (V − nb) = nRT
1.2 V
where, p is the pressure, a and b are constants, V is
16. (b) Given densities of both spheres are same. Let the volume, T is the temperature and n is the
it be ρ unit and density of liquid be σ and η be its number of moles.
viscosity.
van der Waals’ equation can be rearranged as
Let radius of sphere S1 be r1 and that of sphere S2 be
nRT an2
r2 and volumes are V1 and V2 , respectively. p= − 2
Now, V − nb V
m1 m2 Dividing first part with n and the 2nd part with n2,
= (Q density is same)
V1 V2 we get
m1 m2 nRT an2
⇒ = 2
4 3 4 3 p= n − n2
πr1 πr2 V nb
3 3 − V
3 n n n2
 r1  m  8
⇒   =  1 = RT a
 2
r  m2  1 ⇒ p= − 2 …(i)
V V
r1 2 −b
⇒ = n n2
r2 1
The equation given in question is as follows
Now, terminal velocity is given by RT a
p= − …(ii)
2r 2(ρ − σ) g 2V − b 4b 2
v=
9η By comparing Eqs. (i) and (ii), we get
2r12(ρ − σ) g V
= 2V
⇒
v1
= 9η n
v2 2r22(ρ − σ) g ⇒ n=
V
=
1 1
(i.e. n = mole)
9η 2V 2 2
2 By using mole formula to determine the amount of
v1  r1 
⇒ =   = 22 = 4 O2 as follows
v2  r2  Mass
Mole = …(iii)
Molar mass

Page 21 of 47
 The molar mass of O2 is 32g/mol. Substituting in Eq. 21. (a) The given situation is shown below
(iii), we get
1 Mass +
⇒ = +
2 32g / mol b
–
⇒ Mass of O2 = 16 g –
+q +
19. (b) We know that, latent heat of fusion at ice is – r a –
79.7 cal per gram. – –
+ –
Let final temperature be T. +
P
Then, +
m1 s∆T = m2L
⇒ 300 × 1 × (25 − T) = 100 × 75 A radial electric field E exists in the region
⇒ 25 − T = 25 between the two shells due to charge on inner
shell only.
⇒ T = 0° C
Electric field at point P is calculated according to
After that total energy left, Q = 4.7 × 100 = 470 cal
Gauss’s law,
Total mass of water = 400 g q
Amount of water again converted into ice, i.e φE = E ⋅ 4 πr 2 =
ε0
Q 470
m= = q
Lice 79.7 ⇒ E= …(i)
4 π ε0 r 2
⇒ m = 59
. g
The potential at the centre of sphere,
Thus, whole mass is converted into water at 0°C and b b b q
about 5.9 g water is again converted into ice whose V = − ∫ E ⋅ dr = ∫ E ⋅ dr = ∫ dr
a a a 4 πε r 2
temperature is also 0°C. 0

After achieving the temperature of 0°C, latent heat [from Eq. (i)]
of fusion is required firstly for conversion of water q 1 1 
⇒ V=  − 
into ice, then further lowering of temperature as 4 π ε0  a b 
possible.
So, the final temperature will be 0°C. 22. (b) The given situation is shown in the figure

20. (d) The electric field along Z-axis due to uniformly X

–σ 2σ 4σ
charged circular ring of radius a in XY-plane is
given by
kqz
E= 2 2a
,0
(z + a 2)3/ 2 O 0,
Y
a P
where, q is the net charge on the ring and z is axial
distance on Z - axis from the centre of the ring. 3a
Now, at point M in the graph shown, electric field is
maximum. Z 4a
So, We have to calculate electric field at
3
kq(z 2 + a 2)3/ 2 − (z 2 + a 2)3/ 2 ⋅ 2z 2 point P (0, 2a, 0).
dE 2
= Net electric field at point P,
dZ (z 2 + a 2)
−σ $ 2σ $ 4σ $
dE E= j− j− j
For maxima, =0 2 ε0 2 ε0 2 ε0
dZ
−7σ $
3 E= j
⇒ (z 2 + a 2)3/ 2 = × 2z 2(z 2 + a 2)1 / 2 2 ε0
2
⇒ z + a = 3z 2 ⇒ 2z 2 = a 2
2 2 23. (c) The given situation is shown below
z 1 +q1 q3 +q2
⇒ =
a 2
d

Page 22 of 47
 Case 1 If charge q 3 is taken as positives. ∴ From Eq. (i), we get
In this situation, force on charge q 3 due to charges q = 2πRλ
q1 and q 2 will be repulsive and in opposite direction. Current associated,
Hence, at a certain location between + q1 and + q 2, q
I=
charge q 3 will be in equilibrium, when both T
repulsive forces will be equal in magnitude. 2πRλ
I= …(ii)
Case 2 If charge q 3 is taken as negative. T
In this situation, force on charge q 3 due to charges Magnetic field on the axis at a distance d away from
q1 and q 2 will be attractive and in opposite direction. the centre,
Hence, at a certain location between + q1 and + q 2,
µ 0 IR2
charge q 3 will be in equilibrium, when both B=
attractive forces will be equal in magnitude. 2(R + d 2)3/ 2
2

24. (b) The given situation is shown below For d >> R,

Y µ 0 IR2
B=
2(d 2)3/ 2
µ 0 IR2
L(–1,1) BL =
2d 3
2πRλ  2
µ 0 
BM
R
X  T 
O = 3
2d
M (–1,–1) µ πλ R3
= 0 . 3
T d
R3 Rm
⇒ B∝ 3 [given, B ∝ ]
Length, OL = 1 + (−1) =
2 2
2 d dn
∴ m = 3, n = 3
and OM = (−1)2 + (−1)2 = 2
26. (d) Since, susceptibility χ of diamagnetic material
QMagnetic field at point O due to wire L,
is independent of temperature.
µ I  $i + $j  Q B = µ 0 ⋅ I 
BL = 0 .   1/χ
2π 2  2   2π r 
A

Magnetic field at point O due to wire M,

B
µ I  − $i + $j 
BM = 0 .   T
2π 2  2 
1
∴Resultant magnetic field at the origin O, Hence, is also independent of temperature.
χ
B = BL + B M
Therefore, material B is diamagnetic. For
µ I  $i + $j  µ 0 I  − $i + $j  paramagnetic substance, susceptibility varies
= 0   + .  
2π 2  2  2π 2  2  inversely as temperature.
1 1
µ 0 I  $i + $j − $i + $j  i.e. χ∝ or ∝T
= χ
2 2π   T
2 
Therefore, material A is paramagnetic.
µ 0I µ I
= .( 2$j) = 0 $j
27. (d) V
2 2 2π
25. (d) Charge per unit length of the thin rod = λ
V0
If l be the length of the rod, the charge on the rod,
q = lλ …(i) t
0 T/2 T 3T
According to given situation, 2
l = 2πR

Page 23 of 47
 Rms value of potential difference is given as Here, i=r
V02 + 0 2 Since, i + r = 90°
Vrms = ⇒ i + i = 90°
2
⇒ i = 45°
V0
= i = r = 45°
2
Coordinate at point P is
28. (c) (R cosθ, Rsinθ) = (R cos135° , Rsin135°)
 −1 1 
=  R  , R  
  2  2 
−R R 
= 
Red Yellow Orange
, 
 2 2
The colours of the four bands of carbon resistors are
red, yellow, orange and no fourth band. 31. (b) For a plane electromagnetic wave, the electric
∴ Red Yellow Orange No colour field is given by
↓ ↓ ↓ ↓ $ V/m
E = 90sin(0.5 × 103 x + 1.5 × 1011 t) k
2 4 3 20% Here, E 0 = 90 V/m
∴ R = 24 × 103 Ω ± 20 % E
∴ B0 = 0
= 24kΩ ± 20% c
90
29. (c) L =
3 × 108
= 30 × 10−8 T
= 3 × 10−7 T
~
V=V0 sin ωt Since, electric field vector and magnetic field
vector, both are perpendicular to each other and
In pure inductive circuit, alternating voltage leads
π also perpendicular to direction of propagation of
angle from alternating current. electromagnetic wave. Hence,
2
π B = B0 sin(0.5 × 103 x + 1.5 × 1011 t)$jT
i.e. Phase difference, φ =
2 B = 3 × 10−7 sin(0.5 × 103 x + 1.5 × 1011 t)$jT
Average power consumed, 32. (c) Since, both wires are identical, so they have
π
P = Vrms × I rms × cos same cross-section A and same length l. Also, in
2 series combination of wires, effective resistance,
⇒ P=0 Q cos π = 0 R = R1 + R2
 2  (l + l) 1 1
⇒ = +
30. (c) The given situation is shown below σ eff A σ1 A σ 2 A
2 1 1
Y ⇒ = +
σ eff σ1 σ 2
2σ1 σ 2
r ⇒ σ eff =
i σ1 + σ 2
P R
33. (b) Initial length of rod = L
135°
X Initial angular velocity, ωi = ω
O
When rod pivoted at one end is freely rotated in
horizontal plane, then its angular momentum,
Li = I1ω1
 ML2 
Reflecting surface (x 2 + y 2 = R 2 ) Li =   ⋅ω
 3 

Page 24 of 47
 ∴Putting the value of ρ in Eq. (i), we have
∞ ( − Mgh / RT )
∫ hρ0 e
h = 0∞
dh
=
RT
− (Mgh/RT )
∫0 ρ0 e
L dh Mg

35. (b) Under isothermal conditions,

p1 V1 + p2V2 = pV
When temperature of the system is increased with
temperature ∆T, then change in length of rod ∆L is 
⇒ p −
4T  4 3  4T  4 3
 . πa +  p −  ⋅ πb
given as  a  3  b  3

=  p −
∆L = αL∆T 4T  4 3
 πc
Now, new length of the rod,  c 3
L ′ = ∆L + L = αL∆T + L = L(α∆T + 1) where, T is surface tension of soap bubble.
⇒ L ′ = L(1 + α∆T) …(i) ⇒ p[c 3 − (a 3 + b 3)] − 4T(a 2 + b 2 − c 2) = 0
Now, new angular momentum, p(c 3 − a 3 − b 3)
⇒ T=
ML ′2 ω 4(a 2 + b 2 − c 2)
L f = I 2ω2 = .
3 2
By the law of conservation of angular momentum, 36. (b,c)
M
L f = Li O
a
ML2 x
I 2ω2 = ⋅ω
3
ML ′2 ω ML2
⋅ = ⋅ω Magnetic field at the centre O of the circular coil
3 2 3
due to bar magnet (axial position)
L ′2 µ 2M
⇒ = L2 B= 0. 3
2 4π x
L2(1 + α∆T)2
⇒ = L2 [from Eq. (i)] Hence, option (a) is not true.
2 dφ d
Induced emf, e = − = − ⋅ BA
⇒ (1 + α∆T)2 = 2 dt dt
⇒ 1 + α 2∆T 2 + 2α∆T = 2 d µ 2M
= − ⋅ 0 ⋅ 3 πa 2
dt 4 π x
Since, α is very small, hence the term α 2∆T 2 may be
µ Ma 2 d 1
neglected. =− 0 ⋅
∴ 1 + 2α∆T = 2 ⇒ 2α∆T = 1 2 dt x 3
−3 dx
⇒ ∆T =
1 = − µ 0 Ma 2.  4 
2α  x  dt
3µ 0 Ma 2 dx
34. (b) As the gravitational field is uniform, therefore e= ⋅
centre of gravity and the centre of mass are at x4 dt
same location. 1
⇒ e∝ 4
∴The location of centre of mass is x
∞ Hence, option (b) is true.
∫ hdm
h= 0∞ e 3µ 0 Ma 2 dx
Induced current, I = = …(i)
∫0dm R x 4 R dt
∞ 3µ 0 Ma 2 dx 2
∴ Magnetic moment, µ = IA = πa
∫ hρdh
h = 0∞ …(i) x 4 R dt
3 π µ 0 M dx 4
∫0 ρdh ⇒ µ= (a )
x 4 R dt
But from barometric formula and gas law,
µ ∝ a4
ρ = ρ0 e − Mgh/ RT
⇒ Hence, option (c) is true.

Page 25 of 47
 Net heat produced, p
(V0 , 2p0)
H ∝ I2
2p0 C
2
H ∝  4 
1 (2V0 , p0)
⇒ [from Eq. (i)]
x  p0 A
B
1
⇒ H∝
x8 V
V0 2V0
Hence, option (d) is not true.
Heat rejected by the gas in path AB during isobaric
37. (a,b) Given, E = a(cosω0 t + sinωt + cosω0 t)
compression,
ω = 1015s−1 dQ AB = nCp ∆T
5
ω0 = 5 × 1015 s−1 = 1 ⋅ R(TB − TA) [Q n = 1]
2
Since, ω < ω0 5R  p0 V0 2p0 V0  p V
=  −  = −5 0 0
⇒ 2πν < 2πν0 2 1 × R 1 × R  2
⇒ ν < ν0 [ν0 = threshold frequency] Heat absorbed by the gas in path BC of isobaric
Hence, for light of frequency ω, process,
photoelectric effect is not possible. dQBC = nCV ∆T
3R
According to Einstein’s equation, = 1 × (TC − TB)
2
eV0 = hν − hν0
3R  2p0 V0 p0 V0  3p0 V0
eV0 = hν − φ0 =  − =
2  1 × R 1 × R 2
Hence, stopping potential versus frequency graph
will be straight line. Net heat = dQ AB + dQBC
−5p0 V0 3p V
= + 0 0 = − p0 V0
Stopping (V0) 2 2
potential
∴Heat is rejected during the process.
Change in internal energy in process A → B,
3
∆U = nCV ∆T = 1 × R(TB − TA)
2
Frequency 3R  p0 V0 2p0 V0 
=  − 
(ν 0 ) 2 1 × R 1 × R 
3
Work-function of metal surface, = − p0 V0
2
ω
φ0 = hν0 = h 0  Work done by the gas during entire process is W,
 2π  then
5 × 1015 W = W AB + WBC
= 6.62 × 10−34 ×
2π = p0 (V0 − 2V0) + 0 = − p0 V0
. × 10−19J
= 527 39. (b,c) Mass, m = 0.02 kg

. × 10
527 −19 Potential energy,
= eV U = Ax(x − 4) J
1.6 × 10−19
⇒ U = Ax 2 − 4 Ax
= 329
. eV
dV d
∴Maximum kinetic energy of photoelectron, Force, F=− = − (Ax 2 − 4 Ax)
dx dx
K max = − (eV0) = − [e(−2)] = 2eV
⇒ F = − 2Ax + 4 A …(i)
38. (b,c) Since, given p-V diagram is not a cyclic This force is dependent on x, hence particle is not
process, hence the change in internal energy for acted upon by a constant force.
the whole process is not zero.
From Eq. (i), it is clear that f ∝ − x

Page 26 of 47
 Hence, particle executes simple hormonic motion. Since, charge particle enters into magnetic field B
Speed of particle is maximum at equilibrium perpendicular to it, hence it performs a circular
position, i.e. when F = 0 path in magnetic field. Radius of circular path,
−2Ax + 4 A = 0 mv
i.e. r=
⇒ x = 2m Bq
Period of oscillation, Charge particle will enter in region c, when
m L < 2r
T = 2π …(i) mv
k ⇒ L< 2
From Eq. (i), F = −2Ax + 4 A Bq
LBq qLB
Since, value of k will be obtained in terms of A. ⇒ < v ⇒ v>
Therefore, the value of time period will be also 2m 2m
obtained in terms of A, hence option (d) is not ⇒ 
v>  
1  qLB
correct.  2 m
qLB
40. (a,d) The given situation is shown below i.e. When v > , then particle surely will inter
b m
a qLB qLB
× × × c into region c, because >
m 2m
× × ×
Hence, option (a) is correct.
× × ×
Since, charge particle enters into region c, hence
× × × path of the particle is a circle not in region b.
× × × Hence, option (c) is not correct.
× × × Time spent in region b is given as
v 2πm
× × × T= which is independent of v.
Bq
L Hence, option (d) is correct.

Chemistry
41. (b) The exact order of the boiling points of the Therefore, the maximum number of atom in one
given compound is isopentane < n-pentane plane in this case are 15.
< butanone < 1-butanol. 43. (a) The total number of triple bonds present in
The highest boiling will be of butanol because in cyclo (18) carbon are 9. Its structure is shown
butanol, molecules are associated due to extensive below:
intermolecular hydrogen bonding. C ≡≡ C — C≡≡
Now butanone has higher boiling point from —
C C—
≡≡

n-pentane and iso-pentane because butanone has

stronger dipole-dipole interaction and n-pentane C C
≡≡
—

has higher boiling point than isopentane because of C

C
—

larger surface area, due to which n-pentane has

≡≡

greater van der Waals’ force of attraction. C

C
≡≡
—

42. (d) All the atoms present in p-nitrobenzonitrile C≡ — C

are in one plane as show in the structure ≡ C
C≡≡
C
C ≡≡ C
— —
14 15
H H
13 O 5
Structure of cyclo (18) carbon
4
11
N 6 2 1 44. (b) Resonating structures II and IV of p-nitro-N,
== + 7 3 C ≡≡ N N-dimethyl aniline are incorrect. In structure II
O12 8 and IV, valencies of N are not satisfied correctly.
H 10 H9

Page 27 of 47
 All the correct resonating structures of p-nitro-N, The general formula of amino acid is
N-dimethyl aniline are as follows H 2 N  CH(R) COOH, R is CH 3 for alanine and H
+ + + for glycine. The structure are as follows
NMe2 NMe2 NMe2 NMe2 O O
 
– – H 2N  CH  C  OH + H 2N  C H  C OH →
 
CH 3 H
–
NH2 NH2
+ +
N N N+ N+
NH COOH + NH COOH +
O O– O O– O O– O O– CH3 CH3
CH3
45. (c) COOH CH3 O O
H H

H OH and HO H are monomers. N COOH N COOH

H2N HN
+ 2
CH3 COOH O Me O
When the same compound is represented in 48. (d) Benzaldehyde reacts with 2 moles of methanol
different ways, then all the representations are OMe
in presence of dry HCl to give Ph which
known as homomers of each other. on reaction with dil. HCl OMe
CH3 CH3 gives respective aldehyde and alcohol. Aldehyde
on reaction with (CH 3CO)2O,
and CH 3COONa gives COOH
are also homomers. Ph
NO2 O2N OMe dil. HCl
Dry
PhCHO + CH3OH Ph
Cl CH3 Cl Benzaldehyde HCl OMe
H
and are constitutional
H3C Cl Cl H COOH (CH3CO)2O
cis trans Ph PhCHO+2CH3OH
CH3COONa
isomers.
Constitutional isomers are the compounds that 49. (c) The free energy change of a reaction is
have the same molecular formula and different ∆G° = ∆H ° − T∆S °
connectivity. Now, a spontaneous reaction is one that releases
46. (d) The correct order of acidity of the given free energy and therefore, the sign of ∆G must be
compounds is acetylene < ethanol < negative.
p-nitrophenol < acetic acid. So, when ∆H is negative and ∆S is positive, the sign
Ethanol is stronger acid than acetylene. This is of ∆G will be negative and the reaction will be
because after the loss of acidic proton (H + ) the spontaneous at all temperature.
corresponding anion formed by ethanol is stabilised 50. (b) In acidic medium,
by the electronegative oxygen atom. Now +7
p-nitrophenol is more acidic than ethanol because Mn O−4 + 8H+ + 5e − → Mn2+ + 4H 2 O
the phenoxide ion obtained after the deprotonation and Fe 2+ → Fe 3+ + e −
is stabilised by resonance effect and also by EWG 1
effect (which is caused by NO2 group). So, number of moles of MnO−4 = moles …(i)
5
Likewise, acetic acid is more acids than all of the
given compounds as the formed carboxylate ion is Also, in acidic medium,
+6
stabilised by resonance which is due to the presence Cr2 O 27− + 14H+ + 6e − → 2Cr 3+ + 7H 2O
of electronegative oxygen atom.
and Fe2+ → Fe3+ + e −
47. (d) All the given dipeptides can be obtained from
1
the amino acids glycine and alanine. 7 =
So, number of moles of Cr2O 2− moles …(ii)
6

Page 28 of 47
 Now, from Eq. (i) For gas A,
1
moles of MnO−4 = x moles of MnO −4 u1 =
3RT
5 m1
1
∴ = x 3RT
5 u12 =
m1
5x = 1 …(iii)
u12m1
Put this value in Eq. (ii). T= …(i)
1 5x 3R
will be For gas B,
6 6
So, the number of moles of Cr2 O72− required to 3RT
u2 =
oxidise the same amount of Fe 2+ in acidic medium m2
5 3RT
is x or 0.83x. u22 =
6 m2
51. (d) Density of the element (d) = 5.0 g cm−3 u22m2
T= …(ii)
Edge length of unit cell (a) = 200 pm 3R
= 200 × 10−10 cm From Eq. (i) and (ii),
Z× M u12m1 u22m2
d= 3 =
a × NA 3R 3R
[where M = mass of element ∴ m1 u12 = m2u22
N A = Avogadro number 53. (a) ∆Tf = i × k f × m
Z = number of atoms per unit cell]
∆Tf = depression in freezing point of solvent
For body centred cubic lattice, Z = 2
i = van’t Hoff factor
2× M
5= k f = freezing point depression constant
(200 × 10−10)3 × 6.022 × 1023
m = molality
5 × (200 × 10−10)3 × 6.022 × 1023 ∆ Tf
⇒ M= i= =
2
2 m × kf  wsolute × 100 
5 × (200)3 × 1030 × 6.022 × 1023   × 1.72
=  M solute × Wsolvent 
2
2
= 12. 044 g =
 20 × 1000  × 1.72
Now, 12.044 g of element have → 6.022 × 1023  
 172 × 50 
atoms
 Msolute = M( C11 H 8 O 2) 
6.022 × 1023  
1 g will have → atoms
12. 044  = 12 × 11 + 8 × 1 + 2 × 16 
 = 172 
6.022 × 1023  
100 g will have → × 100 atoms 2
12. 044 ⇒ i= = 0.5
4
= 0.5 × 10 25
atoms or
54. (a) The presence of catalyst does not change the
= 5 × 10 atoms
24
value of equilibrium constant. It only increases
the rate of forward and backward reaction to
52. (d) Let two gases are A and B.
equal extent. So, the equilibrium constant in
u1 = molecular velocity of gas A presence of catalyst at 2000 K is same as
u2 = molecular velocity of gas B equilibrium constant in the absence of catalyst at
m1 = molecular mass of gas A 2000 K, i.e. 4 × 10−4 .
m2 = molecular mass of gas B 55. (a) For 1st order kinetic, t1 / 2 =
ln 2
= 40 …(i)
3RT k1
The root mean square velocity, urms =
M [A ]
For 2nd order kinetics, t1 / 2 = 0 = 20 …(ii)
(where, M = molecular mass, R = gas constant) 2k0

Page 29 of 47
 From Eq. (i), 0.1 × h2
= 10−2
ln 2 1−h
40 =
k1
On calculating, h = 0.27 which is significant, not
ln 2 negligible.
⇒ k1 = …(iii)
40 ∴ [H + ] = Ch = 0.1 × 0.27 = 2.7 × 10−2 M
From Eq. (ii),
[A0 ] 59. (d) For salt MX, K sp = [S] [S]
20 = …(iv)
2k0 K sp = 4 × 10−8 (given)
[A0 ] ∴ 4 × 10−8 = [S]2
k0 =
40
∴ S = 2 × 10−4
 k1  ln 2 40
Now, ratio   = × For salt MX 2, K sp =[S] [2S]2
 k0  40 [A0 ]
ln 2 0.693 . × 10−14
K sp = 32
= =
[A0 ] 1.386 mol dm −3 1/ 3
. × 10−14 
 32
−1
= 0.5 mol dm 3 [S] =  
 4 
56. (d) Among the given solutions, NaCl, KNO3 and = (8 × 10−15)1 / 3 = 2 × 10−5
HCl are strong electrolytes but conductivity also For salt MX 3, K sp = [3S]−3[S]
depends upon size of ions. Smaller the size of
ions, greater its conductance, hence greater is the K sp = 2.7 × 10−15
conductivity than larger ions. So, out of NaCl, 1/ 4
KNO3 and HCl ions, H + is the smallest and  2.7 × 10−15 
[S] =  
therefore, 0.1 M HCl will have highest  27 
conductivity.
= (10−16)1 / 4 = 10−4
57. (b) Na2 S + nS → Na2 S( n + 1) ∴Solubility of MX order is
Na2 SO3 + S → Na2 S2 O3 MX > MX 3 > MX 2
X = Na2 S( n + 1) 60. (c) Reduction hydrogen half-cell is
Y = Na2 S2 O3 H+|(xM)|Pt (H 2 ); Pressure pH 2
58. (d) Let a weak monoacidic base is BOH. BOH is
Half-cell reaction is
neutralised as follow
2H + (aq) + 2e − → H 2(g)
BOH + HCl → BCl + H 2 O
At point of equivalence, all BOH get converted into n= 2
salt and the concentration of H + ions is due to the Reaction quotient ⇒ Q =
pH 2
hydrolysis of resultant salt, BCl. [H + ]2
B+ + H 2 O q BOH + H + ° 0.0591
C(1 − h ) Ch Ch E red = E red − log Q
n
Volume of HCl used 0.0591
NV 2.5 × 2 × 15 E red = − log Q
Va = b b = = 7.5mL 2
Na 2× 5 1
Case (a), log Q = log = 0 ∴ E red = 0
Now, the concentration of salt, [BCl] 1
Conc. of base 2 × 2.5 1 1
= = = = 0.1 Case (b), log Q = log = − ve ∴ E red = + ve
Total volume 5 (7.5 + 2.5) 10 4
Ch2 K 10−14 2
Case (c), log Q = log = + ve ∴ E red = − ve
So, K h = = w = −12 = 10−2
1 − h K b 10 1
2
Ch2 Case (d), log Q = log = − ve ∴ E red = + ve
or = 10−2 4
1−h
∴E red is negative for option (c).

Page 30 of 47
61. (d) Solubility of saturated solution = Solubility Its structure is as follows:
product
∴ K sp = 4 × 10−5 (for BaSO 4 ) O+
Let the solubility of BaSO4 in 0.1 M Na2 SO4 be x.
BaSO4 c Ba2+ + SO24 − H H
x x H
Na2 SO4 c 2Na+ SO24 − Hybridisation = sp 3 and shape = pyramidal
2 × 0. 1 ( 01
( 0. 2)
.) 67. (b) Mass on the reactant side = 18.00567 amu
Mass of the proton = 1.00782 amu
∴Total (SO24−) = x + 01
.
Energy absorbed in the reaction = 116
. MeV
≈ 0.1 M = 0.00124 amu
Thus, K sp = [Ba2+ ] [SO24− ] 14
N(α, p ) 17O
4 × 10−5 = [x] (0.1) This reaction can be simplified as
−4 ∆E
∴ x = 4 × 10 14
7 N + 42α → 17
8 O + 11 H
−4
∴ Solubility = 4 × 10 M where, ∆E is the energy absorbed.
In this reaction, highly energetic alpha particle with
62. (c) The given reaction is as follows:
kinetic energy 1.16 MeV are absorbed by 14 7 N
Co(NO 3)2 + 7Na 2NO 2 + 4CH 3COOH →
nucleus to form 17 O isotope and a proton.
Na 3[Co(NO 2)6] + 3NO 2 + 2H 2O + 4CH 3COONa 8
Hence,
Sodium cobalt nitrile 1.16MeV
With the salt of potassium, sodium cobalt nitrile
14
7 N + 42α → 17
8 O + 11 H
forms insoluble double salt K 2Na[Co(NO 2)6]⋅ H 2O.
18.00567 amu 1.00782 amu
This salt is yellow coloured ppt.
According to conversation of mass-energy.
63. (b) The metal (M) is copper and the reactions are 18.00567 amu = ( 17
8 O + 1.0078 − 0.00124) amu
as follows: 17
8 O = 18.00567 − 1.0078 + 0.00124
∆
2Cu 2 S + 3O2 → 2Cu 2 O + SO2 ↑ = 16.99914 amu
∆
Cu 2 S + 2Cu 2 O → 6Cu + SO2 ↑ 68. (a) A solution of NaNO3, when treated with a
mixture of Zn dust and NaOH (caustic soda)
64. (d) When CO2 is passed through ammoniacal yields ammonia gas.
solution of NaCl, sodium bicarbonate (NaHCO3) Complete reaction is as follows
and (NH 4 Cl) are formed.
Zn + NaOH + NaNO 3 → Na 2ZnO 2 + H 2O + NH 3 ↑
NH 4OH + NaCl +CO 2 → NaHCO 3 + NH 4Cl Zinc Caustic Sodium Sodium Ammonia
( X) Ammonium metal soda nitrate zincate
Sodium
bicarbonate chloride
(Y) 69. (a) In K 3[Fe(CN)6 ]Fe present in +3 oxidation state
On further heating NaHCO3, we get Na2 CO3 . outer electronic configuration of Fe 3+ =
2NaHCO 3 → Na 2CO 3 + H 2O + CO 2 3d 4s 4p
Sodium
carbonate
(white ppt.)
( Z) As CN is a strong field ligand. So, it causes the
pairing of electrons.
65. (a) Structure of ozone (i.e. O3) has delocalised Therefore, K 3[Fe(CN)6 ] =
π-electrons. Its resonance structure are as follows: 3d 4p 4s
O⊕ O⊕ O
O O O

 128 pm
O 117°
O O
CN CN CN CN CN CN
66. (b) The structure of the hydronium ion is 2 3
pyramidal because it has three bonding pairs of d sp
electrons and one lone pair of electrons.

Page 31 of 47
 Thus, in this complex, number of unpaired electron is h
73. (a) de-Broglie wavelength, λ =
one. mv
In K 4[Fe(CN)6 ]Fe, present in +2 oxidation state λ He M Ne 20
∴ = =
outer electronic configuration of Fe 2+ λ Ne M Ne 4
3d 4s 4p
∴ λ He = 5λ Ne
74. (a) Given,
As in this case also the ligand is CN (which is a x solute = 0.1
strong field). So, it again causes the pairing of the
electron. This can be shown in following way. Molarity = Molality
K 4[Fe(CN)6 ] = Density of solution = 2g cm −3
3d 4s 4p 2 × 10−3
= kg
10−6
Thus, in this case the number of unpaired electron = 2 × 103 kg/m 3
is zero. = 2 kg/L
70. (d) When two complexes have same number of
unpaired electrons, they have same value of msolute msolute
magnetic moment. The number of unpaired Msolute Msolute
=
electrons present in[Cu(H 2 O)6 ]2+ , [Mn(H 2 O)6 ]4+ , Volume Mass of solvent (kg)
[Mn(H 2 O)6 ]3+ , [Fe(H 2 O)6 ]3+ and [Cr(H 2 O)6 ]3+ are Volume of solution = Mass of solvent (kg)
0, 3, 4, 5 and 3 respectively. Mass of solution
= Mass of solvent
Thus, the magnetic moment of [Mn(H 2 O)6 ]3+ and d
[Cr(H 2 O)6 ]3+ are identical as they have same Mass of solution
∴ =2
number of unpaired electrons (i.e., 3). Mass of solvent
Mass of solute+ Mass of solvent
71. (a) Methoxymethyl chloride (CH 3 OCH 2 Cl) ∴ =2
Mass of solvent
hydrolysed most easily and neopentyl chloride Mass of solute
[(CH 3)3 C  Cl] hydrolysed most slowly. Primary ∴ =1 …(i)
Mass of solvent
halide readily undergoes SN 2 mechanism and
ηsolute
forms intermediate whereas tertiary halides due = 0.1
to steric hinderance reacts slowly with water. ηsolute + ηsolvent
72. (c) Phenol on nitration with dil. HNO3 gives msolute
p-nitro phenol (X) which on heating with Zn/HCl, M solute
= 0.1
form p-amino phenol, which on acetylation with msolute m
+ solvent
[CH 3 (CO)2 O] gives p-hydroxy acetanilide. Reaction M solute M solvent
is as follows :
1
OH OH OH M solute {Q M solute = msolvent
= 01
.
1 1 using (i)}
+
dil.HNO3 Zn/HCl, ∆ M solute M solvent
M
(CH3CO)2O ∴ solute = 9
M solvent
NO2 NH2
( X) 75. (d) IE Na = 490 kJ/mol
OH
m (g)
ηNa = Na
M Na
. × 10−3
575
=
23
NHCOCH3 ∴ IE Na = 490 × 0.25 × 10−3
p-hydroxy acetanilide = 0.1225 kJ

Page 32 of 47
76. (b,c) Butyne (Me  C ≡≡ C  Me) on reaction with Na / NH 3(liq.) undergoes reduction to give but-2-ene which
on reaction with dil. alkaline KMnO 4 gives diol.
H H OH H H OH
Na/NH3(liq.) Dil. alk. KMnO 4
Me—C== C—Me Me—C== C—Me Me—C—C—Me + Me—C—C—Me
Ethanol, –33ºC
But-2-ene
H OH HO H
Butan-2, 3-diol

77. (d) Complete reaction is as follows :

O
OMg+Br–
Mg, ether – + CH3C—H
Br CH3 BrMg CH3 H3C—C CH3
H
4-bromotoluene

Br2/NaOH,
H3O+ SOCl2
HOOC CH3 ClOC CH3

4-methyl benzoic acid 4-methyl benzoylchloride

( X)
NH3

Br2/NaOH O
H2N CH3 C CH3
Hoffmann H2N
bromamide
(Y) degradation 4-methyl benzamide

78. (c, d)Buffer solutions are made by mixing weak acid with its salt of strong base or mixing weak base with its
salt of strong acid. It is never formed by mixing strong acid and strong base. The pair(s) of solutions which
− + − +
form a buffer upon mixing are (c) HNO3 and CH 3 COONa, (d) i.e. CH 3 COOH and CH 3 COONa.

79. (b, c) Reaction of silver nitrate solution with phosphorus acid produces phosphoric acid and metallic silver.
Complete reaction is as follows:
H 3 PO3 + AgNO3 + H 2 O −→ H 3 PO4 + Ag ↓ + 2HNO3
Phosphorus Phosphoric
acid acid

80. (b, c, d) N 2 H 4 and H 2 O2 show similarity in reducing and oxidising nature. They have same hybridisation of
central atoms i.e. sp 3. The structure of hydrazine and hydrogen peroxide as follows.
H
H H
N N O O
H
H H
Hydrazine Hydrogen peroxide
(N2H4 ) (H2O2 )

Page 33 of 47
Mathematics
 x x2  2  1
dt − ∫ 2 dt 
a
b 2  ∫ t
 e − x −1 −  =−
t 
1. (c) Given, I = lim  2
x→ 0  2 

x
 2  t− 2 + 1 
  = − 2 ∫  log() t −a + C
b  − 2 + 1
 x x2 
= − 2  log | t | +  + C
 e − x −1 −  2 a
sin 2 b  t 
 x 2  x2
  ex − x − 1 − 2  a 
  2 ∴ I=−  log | a + b cos x | + a + b cos x  + C
= lim × b2
x→ 0 x2 x2  
e − x −1 −
x
2
2 ⇒ α=−
x2 b2
x2 4. (c) Given, g(x) = ∫ f ()
2x t
dt, x > 0
ex − x − 1 −
= lim 2  0 form x t
 
x→ 0 x2 0  f (2x) d f (x) d
⇒ g′(x) = (2x) − (x)
Q lim sin x
= 1
2x dx x dx

 x→0 x  (Using Leibnitz Rule for Differentiation)
ex − 1 − 0 − x f (2x) f (x)
= lim  0 form = (2) −
  2x x
x→ 0 2x 0 
f (2x) − f (x)
ex − 1 =
= lim x
x→ 0 2 f (x) − f (x)
= (Q f (2x) = f (x))
1 ex − 1
= lim × x x
2x→0 x ⇒ g′(x) = 0
1 ex − 1 ⇒ g(x) is constant function
= lim × lim x
2 x → 0 x x→ 0
5. (b) We have,
=0
3 | x + 1|
=∫ dx
2. (b) Given, | f ′(x) |≤ 5 for all x 1| x − 2| + | x − 3|
1 1 1 2 x −1 3 x −1
⇒ ∫0 − 5dx ≤ ∫0 f ′(x)dx ≤ ∫0 5 dx = ∫1 − x + 2 − x + 3 dx + ∫2 x − 2 − x + 3 dx
⇒ − 5 ≤ f()
1 − 0≤ 5 (Q| x | = x, x ≥ 0, − x, x < 0)
⇒ − 5 ≤ f()1 ≤5 2x −1 3
=∫ dx + ∫2(x − 1)dx
⇒ 1 ∈ [− 5, 5]
f() 1 − 2x + 5

sin 2x 3
3. (c) Let I = ∫ dx 1 2− 2x + 2  x2 
(a + b cos x)2 =− ∫
2 − 2x + 5
1
dx + 
 2
− x
2
2 sin x cos x
⇒ I=∫ dx 1 2− 2x + 5 − 3
dx +  − 3 − (2 − 2)
9
2 ∫1 − 2x + 5
(a + b cos x)2 =−
2 
Put a + b cos x = t
t−a 1  2− 2x + 5 2 3 3
2  ∫1 − 2x + 5 ∫1 − 2x + 5 dx +
⇒ cos x = ⇒ − b sin x dx = dt =− dx −
b 2
t − a 1
I = − ∫  1 2
dx + log [− 2x + 5]1  +
2 3 3
2  ∫1
2
 dt =−
b  b  t2 2  2
2 t−a 3
= − 2 ∫ 2 dt = log 3 + 1
b t 4

Page 34 of 47
 1 1
= [log e t − log e (t + 1)]1t
2 
2
 
2
2
6. (c) ∫  x + 1  +  x − 1  − 2 dx  t 
t

1  x − 1   x + 1
 =  log e
− 
2  t + 1 1
1 1
 t 1
2 x + 1 x − 1  2  2 =  log e − log e 
= ∫  −   dx  t + 1 2
1  x − 1 x + 1 
−   2t
2 = log e
1
t +1
2 
4x  2t 3
∴ =
= ∫  2  dx
− 1 2t + 1 2
1 x
−
2 ⇒ 4t = 3t + 3
1 ⇒t = 3
0
 4x  4x  2
Now, ex − 1 = t
= ∫  2
− 1
 dx − ∫  2  dx
− 1 ⇒ ex − 1 = 3
1 x  0  x
−
2
1
⇒ ex = 4
0
x 2
x ⇒ x = log 4
=−4 ∫ 1 − x 2 dx + 4∫ 1 − x 2 dx 8. (c) Equation of normal
1 0
−
2 −1
1
Y − y= (X − x)
dy / dx
= 2[log(1 − x 2)]0 1 − 2 [log(1 − x 2)]02
−
2
When y = 0
G =  x + y , 0
dy
= − 2 log 1 −  − 2 log 1 − 
1 1 Then,
  dx 
4  4
3 4 According to the question,
= − 4 log = 4 log dy dy
4 3 x+ y = 2x ⇒ y = x
x dx dx
1
7. (c) Let I = ∫ e x
−1
dx ⇒ ∫ y dy = ∫ x dx
loge 2
y2 x 2 y2 − x 2
Put ex − 1 = t ⇒ ex = t + 1 ⇒ = + C ⇒ =C
2 2 2
e x dx = dt
⇒ which is hyperbola.
dt dt
⇒ dx = x = 9. (b) We know that the equation of an ellipse
e t +1
x2 y2
When x = x, t = e − 1 x whose centre is at origin is + =1
a2 b2
and when x = log e 2, t = eloge 2
−1= 2−1 =1 Differentiate both sides w.r.t x, we get
t 2x 2y dy
1 + 2 =0
I= ∫ t(t + 1) dt a2 b dx
1
2y dy 2x
1 A B ⇒ =− 2
= + b 2 dx a
t(t + 1) t t +1
y dy b2
1 = A(t + 1) + B()
t ⇒ =− 2
x dx a
t = 0, A = 1
Again differentiate both sides w.r.t x, we get
t + 1 = 0 ⇒ t = − 1, B = − 1
y d  dy  d  y
∴
1 1
= −
1   + y′   =0
x dx dx   dx  x 
t(t + 1) t t + 1
xy′ − y × 1 
y ′′ + y′ 
y
t
1 1  ⇒  =0
⇒ I = ∫ −  dt x  x2 
1
 t t + 1

Page 35 of 47
 xy′− y 
y ′′ + y′ 
y
⇒  =0 13. (b) Given, radius of circular track is 10 m.
x  x2 
⇒ xyy ′′ + x(y′)2 − yy′ = 0
y
Which is the required differential equation.

10. (a) Given, x dy + y = x f (xy) C

θ
P
dx f ′(xy) r
d f (xy)
⇒ (xy) = x
dx f ′(xy)
f ′(xy)
⇒ d(xy) = x dx
f (xy) dθ
and speed of man = 10 m/sec. i.e. v = r = 10
f ′(xy) dt
⇒ ∫ f (xy) d(xy) = ∫ x dx y
Now, tan θ =
x 2 r
⇒ log | f (xy) | = + C ⇒ y = r tan θ
2
dy dθ
x 2
⇒ = r sec2 θ ⋅
⇒ | f (xy) | = e 2 + C dt dt
dθ
x2 = sec θ ⋅ r
2

= ke 2 dt
= sec2 60° ⋅ (10)
11. (d) − y = (x − 1) − 1 2
= (2)2 × 10
y = 1 − (x − 1)2 = 40 m/sec.
Hence the required area is
1 14. (c) Let B travels x units,
1
 (x − 1)3  v = u + at
∫ [1 − (x − 1) ] dx =  x − 3 
2

0 0 According to the problem,

 (− 1)3  f ′ t = f (t + m)
= 1 − −  f′ − f m
 3  ⇒ =
f t
1 2
=1 − = 2
3 3  f 
⇒ t 2 = m2   ...(i)
Hence, y =
2
x will divide the entire area in 2 equal  f′ − f 
3 1
parts. Again, n + x = f (t + m)2
2
5
12. (c) ∫ max {x 2 , 6 x − 8} dx 1 1
⇒ n + f ′ t 2 = f (t + m)2 ...(ii)
0 2 2
2 4 5 Now from Eqs. (i) and (ii), we get
= ∫ x dx + ∫ (6 x − 8)dx + ∫ x dx
2 2
m 2( f ′ − f )
=
0 2 4
n mff ′
x 3 2
 6x  2  x3 
4 5
1
=  +  − 8x +   ⇒ ( f ′ − f)n = ff ′ m2
 3 0  2 2  3 4 2
8 125 64 15. (b) Given, α + 3 β is collinear with γ
= + [3x 2 − 8 x]42 + −
3 3 3
∴ α + 3β = λ1 γ
69
= (48 − 32 − 12 + 16) + λ α
3 ⇒ β= 1γ− ...(i)
3 3
= 20 + 23
and β + 2γ is collinear with α
= 43
∴ β + 2γ = λ 2α

Page 36 of 47
 ⇒ β = λ 2α − 2γ ...(ii) 1
⇒ a = (36) 2 = 33 = 27
From Eqs. (i) and (ii), we get
λ1 α
γ − = λ 2α − 2γ 18. (a) Given, h(p) = 1 {h(p + 1) + h(p − 1)}
3 3 2
λ for every p = 1, 2, ..., 99
α  λ 2 +  = γ  1 +
 2
1
⇒
 3  3  2h(p) = h(p + 1) + h(p − 1)
1 λ ⇒ h(p − 1), h(p), h(p + 1) are in AP.
⇒ λ 2 + = 0 and 1 + 2 = 0
3 3 Now, h(100) = 20
1 λ1 ⇒ h(0) + 99d = 20
⇒ λ 2 = − and =−2
3 3 ⇒ 5 + 99d = 20 (Qh(0) = 5)
1 15 5
⇒ λ1 = − 6 and λ 2 = − ⇒ d= =
3 99 33
α ∴ 1 = h(0) + d
From Eqs. (i) and (ii), β = − 2γ − h()
3 5
= 5+ = 5 + 0.15
 α 33
∴ α + 3β + 6γ = α + 3  − 2γ −  + 6γ
 3 =5.15
=0
19. (d) Let z = e iθ
16. (c) Given, f (x) = | x − 1 |, x ∈ R.
2
e iθ 1
Also, let w = =
The graph of f (x) is clearly, from graph. 1 − e 2iθ e − iθ − e iθ
f(x)=x2–1 1 i
= =
− 2 ⋅ i sin θ 2 sin θ
⇒ w is purely imaginary
⇒ Locus of point is Y-axis.
x=–1 x=1
20. (c) We have, z 2 = w2
⇒ z 2 − w2 = 0
f (x) has a local minima at x = ± 1 and has local
maxima at x = 0 ⇒ (z − w)(z + w) = 0
17. (d) Given, ⇒ z = w, z = − w
2 3 5 ⇒ |z|= |w|
log b a + log c b + log a c = 3
3 5 2 ∴B⊂ A
2 log a 3 log b 5 log c
⇒ + + =3 21. (c) Given, x 2 − 6 x − 2 = 0
3 log b 5 log c 2 log a
2 3 5 ⇒ x n − 2(x 2 − 6 x − 2) = 0
log b a + log c b + log a c
Since, A.M = 3 5 2 ⇒ x n − 6 x n − 1 − 2x n − 2 = 0
3
3 When, n = 10,
= =1
3 Then, x10 − 6 x 9 − 2x 8 = 0
1
⇒ x10 − 2x 8 = 6 x 9
G.M =  log b a ⋅ log c b ⋅ log a c 
2 3 5 3
and
3 5 2  Since, α and β are roots of (i).
2 log a 3 log b 5 log c
= × × =1 ∴ α10 − 2α 8 = 6α 9
3 log b 5 log c 2 log a
and β10 − 2β 8 = 6β 9
∴ A.M. = G.M
∴
2 log a
= 1 ⇒ a2 = b3 ∴ (α10 − β10) − 2(α 8 − β 8) = 6(α 9 − β 9)
3 log b

Page 37 of 47
 ⇒ a10 − 2a 8 = 6a 9 (Qa n = α n − β n ) 27. (c) Given,
a10 − 2a 8 1 0 0 
⇒ =3
2a 9 A =  0 cos t sin t 
 
 0 − sin t cos t 
22. (d) For x ∈R, x ≠ − 1
Since, det(A − λ I 3) = 0
(1 + x)2016 + x(1 + x)2015 + x 2(1 + x)2014 + K 1−λ 0 0
2016
⇒ cos t − λ =0
+ x = ∑ ai ⋅ x 0 sin t
2016 i

i=0 0 − sin t cos t − λ

Here, coefficient of x17 ⇒ (1 − λ) {(cos t − λ) 2 + (sin t)2} = 0
2015 2014
= 2016
C17 + C16 + C15 + K + 1999
C0 ⇒(1 − λ) (cos2 t + λ 2 − 2λ cos t + sin2 t) = 0
2015 2014 1999
= 2016
C1999 + C1999 + C1999 + K + C1999 ⇒ (1 − λ) (λ 2 − 2λ cos t + 1) = 0
n+1
(Q Cr + Cr − 1 =
n n
C r) ⇒ λ2 − 2λ cos t + 1 − λ3 + 2λ2 cos t − λ = 0
(2017)!
= 2017
C2000 = ⇒ − λ 3 + λ 2(1 + 2 cos t) − λ( 1 + 2 cos t ) + 1 = 0
(2000)! (2017 − 2000)!
⇒ λ3 − λ2(1 + 2 cos t) + λ(1 + 2 cos t ) − 1 = 0
2017!
= ∴ λ1 + λ 2 + λ 3 = (1 + 2 cos t )
(2000)! (17)!
⇒ 1 + 2 cos t = 2 + 1 (Given)
23. (c) Given, word “EQUATION” 1 π π
⇒ cos t = ⇒t = − ,
Here, consonants—Q, T , N 2 4 4
and Vowel—E , U , A, I , O
∴Number of word = 5C3 × 3! × 3C2 × 3!
28. (c) Given A and B be two non-singular skew
symmetric matrices.
= 10 × 6 × 3 × 6 Such that AB = BA
= 1080 ⇒ AT = − A and BT = − B ...(i)
24. (c) According to the question, Since matrices are non-singular
Consider, x1 + x 2 + x 3 + x 4 = 10, where x i ≥ 2 ∴ order of these matrices are even.
⇒(x1 − 2) + (x 2 − 2) + (x 3 − 2) + (x 4 − 2) = 2 Now, A2B2(AT B)− 1 (AB− 1)T
⇒ y1 + y2 + y3 + y4 = 2, where yi ≥ 2, = A2B2(− AB)− 1 (AB− 1)T
(where, x1 − 2 = y1 , x 2 − 2 = y2, x 3 − 2 = y3 and
x 4 − 2 = y4 ) = − A2B2(B− 1 A− 1) (BT)− 1 AT
∴Number of ways = 2 + 4 − 1 C4 − 1 = 5C3 = 10 = − A2(B2B− 1) A− 1 (− B)− 1 (− A)
= − A2B ⋅ A− 1 B− 1 A
25. (a) We have,
= − A2B(BA)− 1 A
1! + 2! + 3! + 4! + 5! + K + 99!
Since unit digit of 5!, 6!, 7!, ... 99! are zero. = − A2B(AB)− 1 A (QAB = BA)
∴1! + 2! + 3! + 4! + 5! + K + 99! −1 −1
= − A BB 2
A A
= 1 + 2 + 6 + 24 = 33 = − A2(BB− 1) (A− 1 A)
∴Unit digit = 3
= − A2
26. (c) Given,
(01 2) M = (1 0 0) ...(i) 29. (d) We have, an = ar n − 1
and (3 4 5)M = (01 0) ⇒ log a n = log(ar n − 1)
⇒ (6 810) M = (0 2 0) ...(ii) ⇒ log a n = log a + (n − 1) log r
On subtracting Eq. (i) from Eq. (ii), we get log a n log a n + 1 log a n + 2
(6 810) m − (0 1 2) M = (0 2 0) – (1 0 0) Now, log a n + 3 log a n + 4 log a n + 5
⇒ (6 7 8) M = (−1 2 0) log a n + log a n + log a n +
6 7 8

Page 38 of 47
 log a + (n − 1) log r log a + n log r 2 6
P(x = 2) = 8 C2    
1 1
∴
= log a + (n + 2) log r log a + (n + 3) log r  2  2
log a + (n + 5) + log r log a + (n + 6) log r 8
= 8 C2  
1
log a + (n + 1) log r  2
log a + (n + 4) log r 8×7 1 7
= × =
log a + (n + 7) log r 2 × 1 256 64
On applying R2 → R2 − R1 , R3 → R3 − R1 34. (b) Given,
log a + (n − 1) log r log a + n log r log a + (n + 1) log r
Sn = cot − 1 2 + cot − 1 8 + cot − 1 18
3 log r 3 log r 3 log r
+ cot − 1 32 + K to nth term.
6 log r 6 log r 6 log r
= cot − 1 2 × 12 + cot − 1 2 × 22 + cot − 1 2 × 32
= 0 (Since R2 and R3 are proportional)
+ cot − 1 2 × 42 + K
30. (a) Given, (A ∩ C) ∪ (B ∩ C ′) = φ ∴ nth term = cot − 1 2n2
⇒ A∩C=φ ...(i)
tn = tan− 1  2 
1
and B ∩ C′ = φ ...(ii) ⇒
 2n 
From Eqs. (i) and (ii), we get
 (2n + 1) − (2n − 1) 
A∩B=φ = tan− 1  
 1 + (2n + 1) (2n − 1) 
31. (b) Since, = tan− 1 (2n + 1) − tan− 1 (2n − 1)
n(A) ≠ n(T)
∴ Sn = tan− 1 (2n + 1) − tan− 1 ()
1
and n(A) ≠ n(U)
∴There does not exist bijective mapping between A and ∴ lim Sn = tan− 1 (∞) − tan− 1 ()
1
n→ ∞
T, U.
π π π
= − =
32. (d) Even numbers on die are 2, 4, 6. 2 4 4
and odd numbers on die are 1, 3, 5.
3 1 35. (a) We have vertices of parallelogram O(0, 0),
∴ P(even) = = A(a cos θ, b sin θ) and B(a cos θ, − b sin θ)
6 2
A (a cos θ,b sin θ)
3 1
and P(odd) = =
6 2
O(0,0) P
According to the question,
4 8 12
1 1 
+   × +   × +  
1 1 1 1 1
P(A(wins)) = × + K∞
2  2 2  2 2  2 2
5 9 3
B (a cos θ,–bsin θ)
1 1 
+   +   +   + K ∞
1 1
=
2  2  2  2
1 1 Here, OA = OB
2 1 16 8
= = 2 = × = ∴Area of parallelogram = 2 × area of ∆OAB
 1
4 15 2 15 15
1−  = 2 ×  × OP × AB
1
 2 16
2 
33. (a) We have, 1
= 2 × × a cos θ × 2b sin θ
Mean, np = 4 2
= 2 × ab (sin θ cos θ)
and variance, npq = 2
= ab sin 2θ
npq 2 1 π
∴ = = ∴Area will be maximum when θ = .
np 4 2 4
⇒
1 1
q = ∴ p = and n = 8 π
⇒ Maximum Area = ab when θ =
2 2 4

Page 39 of 47
36. (a) Let point B = (2p , 0) ⇒ {(β + α)2 − (β − α)2}2 = 16c 2

Y ⇒ (4h2 − 4k2)2 = 16c 2

⇒ h2 − k2 = c 2
A (0,4)
M ∴Locus of the mid point P of MR is (x 2 − y 2)2 = c 2
B
O(0,0) P
X 38. (a) Given equation of parabola
6 y = 2a 3 x 2 + 3a 2 x − 12a
R
6 y + 12a = 2a  a 2 x 2 + ax 
3
⇒
 2 
∴Coordinates of M are (p , 2) 
= 2a  a x + 2⋅ ax +  − a
2 2 3 9 9
4−0 2  4 16  8
Now, Slope of AB = =−
0 − 2p p 2
a = 2a  ax + 
105 3
p ⇒ 6y +
∴Slope MR = 8  4
2
p Let vertices are (h, k)
∴Equations of MR = y − 2 = (x − p) −3 − 35a
2 ∴ h= and k =
On putting x = 0, we get 4a 16
105
p2 p2 ∴ hk =
y − 2= − ⇒ y = 2− 64
2 2
∴locus of the vertices is
 p2 
∴Coordinates of R is  0, 2 −  105
 2 xy =
64
 p2 
 2− + 2 39. (b) Given, equation of ray of light x + 3y = 3
 p 2 
∴Coordinates of P is ,
2 2  x+ √3y =√3
 
  B
p p 2
i.e.  , 2 − 
2 4 X–axis
A
∴y = 2 − x ⇒ y + x = 2
2 2

Y B′
37. (b) x–y=0 On putting y = 0, we get x = 3
B
∴Coordinates of A are ( 3, 0)
Now, let B(0, 1) then B′ = (0, − 1)
O
X y−0 x− 3
∴Equation of AB′ is =
A 0+1 3−0
⇒ 3y = x − 3
x+y=0
Let coordinates of A are (α, − α) and coordinates of B 40. (a)
are (β, β) A
∴β + α = 2h and β − α = 2k
1
Now, Area of ∆AOB = × OA × OB M O
x2+y2=4
2 (–4,0)
1 B
= 2α 2
2β 2 = |αβ | = c
2
⇒ α 2β 2 = c 2 Given, equation of circle x 2 + y 2 = 4
⇒ 16α 2β 2 = 16c 2 Centre = (0, 0) and radius = 2

Page 40 of 47
 ∴ MA = (4)2 − (2)2 = 12 = 2 3 44. (b) According to the question, we have.
∴Area of quadrilateral MAOB
= 2 ×area of ∆MAO
C
1
= 2 × × MA × OA r r
2
=2 3×2 r1 r2
= 4 3sq. units. C2
C1
41. (b) Given, equation of parabola y = x 2

We know that for y 2 = 4ax

CC1 = r + r1
if we draw a normal from (h, 0) on it then condition
and CC2 = r + r2
for three normal is h > 2a
1 ∴ CC2 − CC1 = (r + r2) − (r + r1) = r2 − r1
∴d> ⇒ Locus of centre is Hyperbola.
2

42. (b) A 45. (c) Let direction cosines of line is (l , l , l).

∴ l2 + l2 + l2 = 1
B 1
O ⇒ 3l 2 = 1 ⇒ l =
3
According to question the coordinates of A and B are
(0, b , c) and (a , 0, c) respectively. ∴ Direction cosines of line is   1 1 1 
, , 
 3 3 3
Now, perpendicular vector OA × OB
$i $j k$ Now, equation of a line passing through P(2, − 1, 2)
x − 2 y+1 z− 2
= 0 b c = = =k … (i)
1/ 3 1/ 3 1/ 3
a 0 c
⇒ x = k + 2, y = k − 1and z = k + 2
= $i(bc − 0) − $j(0 − ac) + k$ (0 − ab) Since line (i) meets the plane
= bc$i + ac$j − abk$ 2x + y + z = 9 at Q
∴ 2(k + 2) + (k − 1) + (k + 2) = 9
∴Required equation of plane is bcx + acy − abz = 0
⇒ 2k + 4 + k − 1 + k + 2 = 9
43. (b) Given, equation of ellipse x 2 + 2y2 = 4 ⇒ 4k + 5 = 9
x2 y2 ⇒ 4k = 4 ⇒ k = 1
⇒ + =1 … (i)
4 2 ∴Coordinates of Q are (3, 0, 3)
Y ∴ PQ = (3 − 2)2 + (0 + 1)2 + (3 − 2)2
= 1+1+1= 3 units.
P (2 cos 60°
2 sin 60°)  5x + 12 1 − x 2 
60° 46. (b) Given, y = sin− 1  
X  13 
O
 5x 12 1 − x 2 
= sin− 1  + 
13 13
 
5
Now, equation of auxiliary circle is x 2 + y 2 = 4. Let sinθ1 = and cosθ2 = x
13
∴Point on the auxiliary circle with eccentric angle ∴ y = sin− 1 (sinθ1 ⋅ cosθ2 + cosθ1 ⋅ sinθ2)
60º is P(2cos 60º , 2sin 60º)
= sin− 1 {sin(θ1 + θ2)}
i.e., P(1, 3)
5
= θ1 + θ2 = sin− 1 + cos− 1 x
13

Page 41 of 47
 1 Clearly f (x) is increasing in [0, 1] and decreasing in
⇒ y1 = −
1 − x2 [2, 4]
− x ∴ f (x) is neither continuous and nor differentiable
and y2 = in D.
(1 − x ) 1 − x 2
2
∴Rolles theorem is not applicable to f in D
⇒ y2(1 − x 2) = xy1
51. (b) f (x) be a continuous periodic function with
⇒ y2(1 − x 2) − xy1 = 0 period T
∴ a = 1, b = − 1 a+ T

∴ (a , b) = (1, − 1) Given, I= ∫ f (x) dx

a
47. (c) Given, 2 f (x) + 3 f (− x) = 15 − 4 x … (i) T

On replacing x by − x in Eq. (i), we get

I= ∫ f (x) dx
0
2 f (− x) + 3 f (x) = 15 + 4 x … (ii)
Hence, I does not depend on ‘a’.
On solving Eqs. (i) and (ii), we get 1 t
f (x) = 4 x + 3 52. (c) We have, b = ∫ e dt
∴ f(2) = 4 × 2 + 3 = 11 0
t +1

e− t
a
48. (c) Given, f1 (x) = x, f2(x) = 2 + log e x Let I= ∫t − a −1
dt
Now, Let h(x) = f2(x) − f1 (x) a −1

= (2 + log e x) − x a
e − ( a + a − 1 − t)
= 2 + log e x − x
I= ∫a + a −1 − t − a −1
dt
a −1
Here, h(0+ ) < 0, h()
1 > 0, h(e) > 0 and h(e 2) < 0 and
 b b 
value of h(x) for all x ≥ e 2 is negative. Q ∫ f (x) dx =
 a
∫ f (a + b − x) dx 
∴h(x) = 0 has two roots is (0, 1) and (e , e 2) a 
a t − 2a + 1
e
49. (c) Given equation, 6x + 8x = 10x I= ∫a − 2− t
dt
x x a −1
⇒  6  +  8  =1
    put t − (a − 1) = x ⇒ dt = dx
 10   10 
x x when t = a, x = 1 and t = a − 1 ⇒ x = 0
⇒  3 +  4  = 1 1 + a − 1 − 2a + 1
    ex
 5  5 ∴ I= ∫ a − 2 − x − a + 1 dx
3 4 0
Let = sinθ ⇒ = cosθ
ex ⋅ e− a
1
5 5
∴ (sinθ)x + (cosθ)x = 1
⇒ I= ∫ − (x + 1) dx
0
it is possible only x = 2 1
ex
∴given equation has exactly one real root. ⇒ I = − e− a∫ dx
0
x +1
50. (b) We have, f : D → R where D = [0, 1] ∪ [2, 4]  1 et 
if x ∈ [0, 1] ⇒ I = − e − a(b) Q ∫ dt = b 
 x, +
f (x) =   0 t 1 
4 − x , if x ∈ [2, 4]
⇒ I = − be − a
Y
0,2 53. (a) We have,
2
f (x) = log e (1 + e10 x ) − tan− 1 (e 5x )
1 0,1
10e10 x 5e 5x
X′ X ⇒ f ′(x) = −
O (1,0) (2,0) (3,0) (4,0) 1+ e 10 x
1 + e10 x
10e10 x − 5e 5x
⇒ f ′(x) =
1 + e10 x
Y′

Page 42 of 47
 10 − 5 5 2 3/ 2 2
⇒ f ′(0) = = = 5× [y ]0
1+1 2 3
10 3/ 2
We know that, = [2 − 0]
f (x + ∆ x) − f (x) = f ′ (x) dx 3
10
5
⇒ f (x + ∆ x) − f (x) = × 0.2 [Qdx = 0.2] = ×2 2
2 3
20
⇒ ∆f (x) = 0.5 = 2sq unit.
3
54. (b) We have,
57. (c) We have,
f (x) = 1 + x
a(α × β) + b(β × γ) + c(γ + α) = 0
f (c) = 1 + c
Clearly a(α × β), (β × γ ) and (γ + α) are coplanar
⇒ c =1 + c [Q f (c) = c] vector∴α , β and γ are also coplanar
⇒ (c − 1)2 = ( c)2
58. (b) Given equation
⇒ c 2 − 2c + 1 = c y 2 = 2x 3
⇒ c 2 − 3c + 1 = 0 dy
⇒ 2y = 6x2
3± 5 dx
⇒ c=
2 dy 3x 2
⇒ =
∴ f has unique fixed point in [1, ∞] dx 4
 
4x
 dy  3h2
55. (c) Let L = lim  3x − 1  ⇒  
 dx  ( h , k)
=
k
x → ∞ 3x + 1 
 3x − 1  Slope of tangent is perpendicular to line
lim  − 1 4x
L=e
x → ∞  3x + 1  4 x = 3y
 3x − 1 − 3x − 1 
 3h2   4 
lim   4x ∴     = −1
L=e
x→∞  3x + 1   k   3
lim
− 2× 4 ⇒ 4h2 = − k …(i)
x→∞ 1
3+
L=e x and k = 2h
2 3
…(ii)
From Eqs. (i) and (ii)
L = e− 8/ 3
(4h2)2 = 2h3
2
56. (a) Given curve, y = 4 x 2, y = x and y = 2 ⇒ 16h4 = 2h3
9
1
Graph of given curve ⇒ h=
y=4x2 8
2
k = − 4 
–1 1 1
,2 2 ∴
,2
√ 2 y=2 √ 2 y=x /9  8
1 −1
(–3/√2,2)
0,2 (3/√2,2) ⇒ k=−4× =
64 64
1 − 1
∴ (h, k) =  ,  only
 8 16 

59. (d) Given, (bc + ca + ab)6

6!
General term = (bc)p (ca)q(ab)r
Area of shaded region p!q !r !
2 y 6!
= 2∫  3 y −  dy = (a)q + r (b)p + r (c)p + q
0 2  p!q !r !
0 5 y Coefficient of a 3b 4 c 5 in the expansion (bc + ca + ab)6
= 2∫ dy
2 2 ∴ q + r = 3, p + r = 4, p + q = 5

Page 43 of 47
 = 2(p + q + r) = 12 1 b2 c2
=p+ q+ r=6 = (a + b + c + 10) 1 b + 10
2 2 2 2
c2
∴p = 3, q = 2, r = 1 1 b 2
c + 10
2

= 3
6! 6! 
∴Coefficient of a 3b 4 c 5 is 
3! 21
! !  3! 3!  R2 → R2 − R1 and R3 → R3 − R1
1 b2 c 2
60. (c) Given a , b , c are in G.P and log  5c  , log  7b  . = (a + b + c + 10) 0 10
2 2 2
0
 2a   5c 
log   and A.P
2a 0 0 10
 7b 
= (a 2 + b 2 + c 2 + 10) (100)
∴b 2 = ac
QIf is divisible by 100.
2log   = log   + log  
7b 5c 2a
and
 5c   2a   7b  62. (b) We have,
2 S = {(x , y) : y = x + 1, 0 < x < 2}
49b 5c
⇒ = For reflexive (x , x) ∈ S
25c 2 7b
x = x + 1 ∉S
⇒ (7b)3 = (5c)3 ∴S is not reflexive
⇒ 7b = 5c ⇒ c =
7
b ∴S is not equivalence relation
5 T = {(x , y) : x − y is an integer}
and b 2 = ac For reflexive (x , x) ∈ T
x = x − x = 0∈R
b 2 = a  b 
7
⇒ T is reflexive
5 
For symmetric
7
⇒ b= a (x , y) = x − y is an integer
5
(y, x) = y − x is also integer
5b 7
Sides are , b, b ∴T is symmetric
7 5
For Transitive
∴ a , b , c are the length of the sides of scalene
triangle. (x , y) ∈ T, (y, z) ∈ T a⇒(x , z) ∈ T
(x , y) = x − y is an integer
61. (b) We have, (y, z) = y − z is also integer
a 2 + 10 ab ac ∴(x − y) + (y − z) = x − z is an integer
ab b 2 + 10 bc ∴ (x , z) ∈ T
ac bc c 2 + 10 Hence, T is an equivalence relation.

a(a 2 + 10) ab 2 ac 2 63. (d) Given plane,

1 P1 = lx + my = 0and P2 = z = 0
= a b 2
b(b + 0)
2
bc 2
abc Plane through common line of P1 and P2
a c 2
b c 2
c(c + 10)
2

∴ P3 = lx + my + nz = 0
Taking common a , b , c from R1 , R2 and R3 angle between P1 and P3 = α
respectively
l 2 + m2
a 2 + 10 b2 c2 ∴ cosα =
abc l + m + n2 l 2 + m2
2 2
= a2 b 2 + 10 c2
abc l 2 + m2
a2 b2 c 2 + 10 ⇒ cosα =
l + m2 + n2
2
Applying C1 → C1 + C2 + C3, we get
a 2 + b 2 + c 2 + 10 b2 c2 l 2 + m2
⇒ cos2 α =
l + m2 + n2
2
= a 2 + b 2 + c 2 + 10 b 2 + 10 c2
a + b + c + 0
2 2 2 2
c + 10
2 l 2 + m2 + n2 n2
b ⇒ sec2 α = =1 + 2
l + m
2 2
l + m2

Page 44 of 47
 ⇒ (sec2 α − 1) (l 2 + m2) = n2 |z + i |− |z − 1|= 0
⇒ n = tan α( l + m )
2 2 2 2 ⇒ |z + i |= |z − 1|
x 2 + (y + 1)2 = (x − 1)2 + y 2
= n= ± (l 2 + m2) tanα
⇒ x 2 + y 2 + 2y + 1 = x 2 − 2x + 1 + y 2
∴Equation becomes
= y=− x …(i)
lx + my ± z tanα l 2 + m2 = 0

64. (c) Given ellipse

x 2 + 2y 2 − 6 x − 12y + 20 = 0
and 2x 2 + y 2 − 10 x − 6 y + 15 = 0
The point of intersection of the given ellipse is y=–x
(x 2 + 2y 2 − 6 x − 12y + 20) +
λ(2x 2 + y 2 − 10 x − 6 y + 15) = 0
∴ | z | = 2 ⇒ x 2 + y2 = 4 …(ii)
(1 + 2λ) x 2 + (2 + λ) y 2 − (6 + 10λ) x
From Eqs. (i) and (ii)
− (12 + 6λ) y + 20 + 5λ = 0
x2 + x2 = 4
The points lie on circle
∴Equation becomes circle ⇒ 2x 2 = 4 x = ± 2
∴ 1 + 2λ = 2 + λ ⇒ λ = 1 and y=m 2
∴Equation of circle is ∴ z = x + iy
3x 2 + 3y 2 − 16 x − 18 y + 35 = 0 z=± 2m 2i

∴Centre of circle is  , 3 z=±

8 21
( m i)
3 
z= ( − i)
21
π / 3 sin x
65. (a) We have, I = ∫ dx and z= 2(− 1 + i)
π /4 x
sin x 67. (d) We have,
Let f (x) =
x x 3x + 2 2x − 1
f (x) is decreasing functions 2x − 1 4x 3x + 1 = 0
⇒ f (π / 3) < f (x) < f (π / 4) 7 x − 2 17 x + 6 12x − 1
3 3 2 2
⇒ < f (x) < R3 → R3 − 3R1 − 2R2, we get
2π π
x 3x + 2 2x − 1
3 3 π /3 2 2 π /3
2π ∫π / 4 π ∫π / 4
⇒ dx < I < dx 2x − 1 4x 3x + 1 = 0
0 0 0
3 3  π π 2 2
⇒  − <I< (π / 3 − π / 4)
2π  3 4  π ∴infinite value of x is possible.

⇒
3
<I<
2 68. (b) We have
8 6 7... 7
77 (22 time 7)
7
66. (b, c) have | z + i | − | z − 1 | = | z | − 2 ⇒ 7 77
is an odd number
| z | − 2⇒| z | = 2represent a circle. ∴ 7( 2m + 1) = 72m × 7
= (72)m × 7
= (49)m × 7
|z|=2
= (48 + 1)m × 7
= 71
( + 48k)
= 7 + (48 × 7) k
∴ remainder = 7

Page 45 of 47
 2 2 2
α β r2
⇒ Locus of R is  x −  +  y −  =
dx
69. (c, d) (a) I1 = ∫4+ x 2  2  2 4
−2

It is possible to put x = tan t Which represents a circle the locus of R is circle.

Option (a) is incorrect. 
1 72. (a) Let I = lim  n + n
+
n
n→ ∞ 3
 n (n + 4)3 (n + 8)3
(b) I 2 = ∫ x + 1 dx
2

0
n 
It is possible to put x = tan t + …+ 
∴ Option (b) is also incorrect [n + 4 (n − 1)]3 
n −1
Hence, option (c) and (d) are correct. n
⇒ I = lim
n→ ∞
∑
70. (a, c) Let equation of plane be r=0 (n + 4r)3
x y z n −1
+ + =1 1 n n
a b c ⇒ I = lim
n→ ∞ n
∑
r = 0 (n + 4r)
3

Centroid =  , , 
a b c
n −1
 3 3 3 1 1
a b c
⇒ I = lim
n→ ∞ n
∑ 3/ 2
∴ = 1, = r, = r 2 r=0 1 + 4r 
 
3 3 3  n
⇒ a = 3, b = 3r c = 3r 2 1 dx
Equation of plane be
⇒ I= ∫0 (1 + 4 x )3/ 2
x y z
+ + =1  (1 + 4 x)− 3/ 2 + 1 
1
3 3r 3r 2 ⇒ I= 
Now plane is passes through (5, 5, − 12)  4(− 3 / 2 + 1)  0
5 5 12 −1
∴ + − =1 ⇒ I= [(1 + 4 x) −1 / 2]10
3 3r 3r 2 2
⇒ 5r 2 + 5r − 12 = 3r 2 − 1 − 1/ 2
⇒ I= [5 − 1]
2
⇒ 2r 2 + 5r − 12 = 0
−1  1
⇒ 2r 2 + 8r − 3r − 12 = 0 ⇒ I= − 1
2  5 
= (2r − 3) (r + 4) = 0 − 1 1 − 5 
⇒ I= 
⇒ r = 3 / 2, − 4 2  5 
71. (a) Let the equation of circle is 5 −1 5( 5 − 1) 5 − 5
⇒ I= = =
(x − α)2 + (γ − β)2 = r 2 2 5 10 10
∴ x = α + r cosθ 0, if −1≤ x < 0
y = β + r sinθ 73. (a, d) We have, f (x) = 1, if x=0
∴ P ≡ (α + r cosθ, β + r sinθ)  2, if 0< x ≤1

θ = (a , b) x
Let R = (h, k) F(x) = ∫ f ()t dt
α + r cosθ β + r sinθ −1
∴ h= ,k =
2 2 0 1

r cosθ = 2h − α and r sinθ = 2k − β

F(x) = ∫ 0 dt + ∫ 2 dt
−1 0
∴ r 2(cos2 θ + sin2 θ) = (2h − α)2 + (2k − β)2
 0, − 1 ≤ x ≤ 0
2 2 2 F(x) = 
α β
=  h −  +  k −  =   2x , 0 < x ≤ 1
r
 2  2  2

Page 46 of 47
 Graph of i(x) is − (x − 1)2
f ′(x) =
(0,2) 2x(1 + x 2)
f ′(x) is decreasing function ∀ x > 0
1
fmax at x = and fmin at x = 3
(1,0) 3
f   = tan− 1
1 1 1 1
∴ − log
 3 3 2 3
π 1
Clearly F(x) is continuous in [− 1, 1] = + log 3
6 4
F ′(x) does not exist at x = 0 1
f( 3) = tan− 1 3 − log 3
74. (b, c) We have, 2
π 1
log x on  , 3 = − log 3
1 1
f (x) = tan− 1 −
2 
 3  3 4
π 1
1 1 ∴ fmax = + log 3
f ′(x) = − 6 4
1 + x 2 2x
π 1
fmin = − log 3
2x − 1 − x 2 3 4
f ′(x) =
2x(1 + x 2)
75. (d) We have, f and g be periodic function with
− (x 2 − 2x + 1)
f ′(x) = periods T1 and T2 respectively
2x(1 + x 2) f + g is periodic if T1 = T2

Page 47 of 47
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