VELAMMAL IIT & NEET ACADEMY

XII IIT GT-15 DATE: 13.01.25

KEY SHEET
MATHEMATICS
1) 2 2) 1 3) 1 4) 1 5) 1
6) 1 7) 1 8) 2 9) 3 10) 2
11) 1 12) 3 13) 4 14) 2 15) 2
16) 3 17) 4 18) 4 19) 4 20) 1
21) 3 22) 5 23) 81 24) 12 25) 193

PHYSICS
26) 1 27) 4 28) 2 29) 2 30) 2
31) 2 32) 3 33) 4 34) 1 35) 3
36) 3 37) 2 38) 1 39) 1 40) 2
41) 1 42) 3 43) 4 44) 1 45) 4
46) 3 47) 20 48) 3 49) 2 50) 9

CHEMISTRY
51) 1 52) 3 53) 2 54) 3 55) 3
56) 2 57) 4 58) 1 59) 1 60) 1
61) 4 62) 4 63) 1 64) 2 65) 1
66) 1 67) 3 68) 1 69) 3 70) 3
71) 0 72) 6 73) 2 74) 4 75) 7
 SOLUTIONS
MATHEMATICS
1. n  A  B  C   16  22  6  5  14  K  2  40  47  K  K  7
 Number of students who study English and Mathematics but not economics=5
n  A   16 n  B   22

5
2
K 14

n  C   26

sin x cos x tan x cot x

2. f  x    
1  cos 2 x 1  sin 2 x sec2 x  1 cos ec 2 x  1
 4, x 1st quadrant
 nd
sin x cos x tan x cot x 2, x 2 quadrant
     f  x max  4
sin x cos x tan x cot x  0, x 3rd quadrant
 th
2, x 4 quadrant
 z  11  z  11
3. log 
2
  0  1
z  2 z  1 
2 2
 z  2 z 1
2
 z  2 z  1  z  11
  z  5 z  2   0  z  5  z  2  0 
4. Let root of x 2  6 x  a  0 are  ,4  4  a
x 2  cx  6  0 are  ,3  3 ,   6  a  8
 x 2  6 x  8  0  x 2  cx  6  0
11
Has a root common  c  5 or c 
2
Integral roots are 2, 4 and 2, 3. Common root is 2
5. ABC is a right angled triangle at B and midpoint of hypotenuse AC is the circumcentre
Circumcentre of ABC is S  0,0 

6. Now
 x 2 x3   x 2 x3   x3 
a 1  x    .......    1  x    ......     x   .......   sin x  xx  R 
2! 3! 2! 3! 3!
lim   
3
  
x  x
Constant terms should be zero      0
Coefficient of x should be zero        0
        
x3      x 4    
Coefficient of x 2 should be zero lim 
3! 3! 3!   3! 3! 3!   2
3
x 0 x 3
    
   0, 2/3 Now    1,   1,   2
 
2 2 6 6 6
7. We arrange the letters of OUGHT in alphabetical order as G, H, O, T, U
In dictionary words starting with
G 4!
H 4!
O 4!
TG 3!
TH 3!
TOG 2!
TOH 2!
TOUGH  1!
Total = 89

dy 2 x  y  2 x dy 2y 1 2y   2y
 dy   2 x dx
x x
8.  y
  2 y
 y
dy  2 dx  y
dx 2 dx 2 2 1 2 1


y
log 2  1  
2x 
 c; y  0   1  0 
1
cc
1
log 2 log 2 log 2 log 2

log 2 y  1  2x

log 2

1
log 2 log 2
 
 log 2 y  1  2 x  1

 
If x  1 than log 2 y  1  2  1  1  2 y  1  e  2 y  e  1  y  log 2  e  1
 y 1  log 2  e  1
9.
p
m4 m  5, 2 
c  3, 2 

2 x  3 y  12, 3x  2 y  5 , 13 x  39  x  3, y  2
Centre  C   5, 2  , radius  r  25  4  13  16  4 , CM  20 , CP  6 .
10. As standard deviation is independent of change of origin
 It remains same  S .D  2
x 1 2  y z  3 x  4 y 1 z
11. Given the lines   and   intersect
2 3  5 2 
So, point on first line 1,2,3 and point on second line  4,1,0 
Vector joining both points is 3iˆ  ˆj  3kˆ
Now vector along first line is 2iˆ  3 ˆj   kˆ
Also vector along second line is 5iˆ  2 ˆj   kˆ
 2 3 
Now these three vectors must be coplanar  5 2  0
3 1 3
 2  6     315  3    11  0     3
n
 2a1   n  1 d1  5n  3
12. Given 2 
n
 2a2   n  1 d2  3n  4
2
a  3d1 38
For n  7, 1 
a2  3d 2 25
13. Equation of directrix is x  0............1
Equation of the tangent at vertex is x  4........... 2 
(2) is equidistant from (1) and latus rectum
 equation of latusrectum is x  8
14. By given condition, a2  a1  a3  a2  .......  a2025  a2024  1
 a a   a a  a a 
 tan 1  2 1   tan 1  3 2   .....  tan 1  2025 2024 
 1  a1a2   1  a2a3   1  a2024 a2025 
 tan 1 a2  tan 1 a1    tan 1 a3  tan 1 a2   .......   tan 1 a2025  tan 1 a2024 
     

 tan 1 a2025  tan 1 a1  tan 1  2025  
4
2  a b x
15. y Tan 1  Tan 
a 2  b2  ab 2
dy 2 1 x 1 a b
 sec2 .
dx a 2  b 2 1  a  b Tan 2 x  2 2 ab
 ab 2
dy 1

dx  a
x
2
16. a  b, a  b are mutually perpendicular   a  b  . a  b   0  a2  b 2  0
2 2
 iˆ   ˆj  3kˆ  3iˆ  ˆj  2kˆ  0  1   2  9  9  1  4   2  4    2    0 

cos 
a.b

 
iˆ  2 ˆj  3kˆ . 3iˆ  ˆj  2kˆ


3 26

5
ab iˆ  2 ˆj  3kˆ 3iˆ  ˆj  2kˆ 1  4  9 9  1  4 14

14cos  5  14cos   25 .
2

17. E1   4,1 ,  4,2  ,  4,3 ,  4,4  ,  4,5  ,  4,6 
 E2  1,2  ,  2,2  ,  3,2  ,  4,2  ,  5,2  ,  6,2 
E3  1,2 , 1,4  , 1,6  ,  2,1 ,  2,3 ,  2,5 ,  3,2  ,  3,4  ,  3,6  ,  4,1 ,  4,3 ,  4,5 ,  5,2  ,  5,4  ,  5,6  ,  6,1 ,  6,3 ,  6,5
1 1 1
P  E1   ; P  E2   ; P  E3  
6 6 2
1 1 1
P  E1  E2   , P  E2  E3   , P  E1  E3  
36 12 12
And P  E1  E2  E3   0  P  E1  .P  E2  .P  E3 
1 1 1
 0  . .  E1, E2 , E3 are not independent.
6 6 2
2 5
12 9 12 9  6
2 x  5x 2 x  5 x x 3
x
18.  dx   dx   dx
 
3 3 3
1 x  x 5
15  1 1   1 1 
x  5  2  1  5  2  1
x x  x x 
1 1 dt 1 1 x10
Put 2  5  1  t    3  2  c   c  c
 
2 2
x x t 2t  1 1  2 1 x  x 3 5
2  5  2  1
x x 
ml
m  10; r  2; l  2 ; 6
r
x  10 
19. Given f  x   x 2  9, g  x   a  f  g 10    f    f 10   109
x9  10  9 
18
b  g  f  3   g  9  9   g 18    2
9
x2 y 2 2 107 2  2 4 8 107  16
E:   1; e2  1   ;   ; 8e 2   2   8
109 2 109 109 109 109 109 109
20. a. A  2  2 A1  23 / A  4

b. adj  adj  2 A    2 A  212 A  212 / 212  1

4 4

c.  A  B   A2  B 2
2
 AB  BA  O
 AB   BA   BA   AB  AB  0  B 0
d. Product ABC is not defined.
x2 y 2
21. Tangent to the curve   1 is
9 4
y 2  mx  a 2 m 2  b 2 , y  mx  9m 2  4
31
And equation of tangent to the curve x 2  y 2  is
4
y  mx  a 1  m 2 , y  mx 
31
4

1  m2 
 31 31 2 5 2 15
For common tangent 9m 2  4   m  m   m2  3
4 4 4 4
2 2
22. Here   0 and 1   2   3  0  k  1,2 then A  B  1  4  5
  
23. f is continuous at x   lim f  x   lim f  x   f  
2 x  / 2  x  /2  2
tan 8 x
b
 8  tan 7 x
 lim 1  cot x  a
tan x
 lim    a 8
x  /2   7  x  /2 
b b
0 lim 1 cot x  1 tan x lim
8 x  /2  a x  / 2  a  a  8  a  8  1, eb / a  1
    e  a  8  1  e
7
 a  9, b  0,  a 2  b 2  81  0  81
tan x
e e x 1
 1,   lim 1  sin x  2
cot x
24.   lim  e1/ 2
x 0  tan x  x x0

The equation having roots 1,  

e is x 2  1  e x  e  0
It is given as ax 2  bx  e  0
a b 1
By comparing we get   a  1, b  1  e
1  1 e 1 
 
12log e  a  b   12log e 1  1  e  6 . 
25. P  X  0   P  X  1  P  X  2   P  X  3  P  X  4 
10 9 8 2 7 3 6 4
1 1 1 1 1 1 1  1   1  193
   10 C1     10 C2     10 C3     10 C4      9
2 2 2 2 2 2 2 2 2 2
 PHYSICS
KQ
26. V
R
27. C  C1  C2  C3
28. Since the balancing length is at the midpoint, each wire has a resistance equal to the
known resistance value R . When they are in series, if  is the balancing length
measured
from the left, we have resistance R in the left gap and 2R in the right gap.
R 
Thus 
2 R 100  
   33.3 cm
29.   B
    3 2  8sin 30 
   24 V
From Fleming’s Right Hand Rule, the induced current in the rod PQ is directed from Q
to B, thus giving an equivalent emf replacement of the motional emf as
I   24V
P Q  P Q
So, P is at a higher potential.
30. At resonant frequency
X L  XC
 Z  R (minimum)
31. Work done by friction on inclined plane will be negative
W  Fs cos   ve, if   900 .
 
32. 0  Pgun  Pbullet
Or Pgun  Pbullet
2
K gun Pgun / 2mgun mbullet
 2
 .
K bullet Pbullet / 2mbullet mgun
33. Total distance moved by the bodies,
x1  x2  12 R  3R  9 R ………….. (i)
Also, Mx1  5Mx2 ………… (ii)
After solving above equations, we get
x1  7.5R
x2  1.5R
2 2
 Heat  ML T
34. iii.  H       L2T 2
 Mass  M
 Heat  ML2T 2
iv.  s       L2T 2 K 1
 Mass  Temperature  MK
35. Resultant force
 1
36. MVe2
2
4S
37. EXCESS PRESSURE =
R

38. l decreases as the block moves up.

39. Isothermal process
40. Adiabatic process
41. Heat and work depends on the path taken to reach a specific value. Hence, heat and work
are path functions.
1 1 1
42. The formula connecting u , v and f for a spherical mirror   is valid only for
u v f
mirrors of small apertures where the size of aperture is very small as compared to the
radius of curvature of the mirror. Laws of mirror are valid for plane as well as large
spherical surfaces. The laws of reflection are valid when ever the light is reflected.
43.
1
 
K .E  k A2  d 2 and P.E  kd 2
2
1
2
At mean position d  0 . At extreme position d  A .
 v 
44. Let f1 be the frequency heard by wall, f1    f0
 v  vc 
Here, v  Velocity of sound,
vc  Velocity of Car,
f 0  actual frequency of car horn
Let f 2 be the frequency heard by driver after reflection from wall.
 v  vc   v  vc 
f2    f1    f0
 v   v  vc 
 345  vc  12 345  vc
 480    440  
 345  vc 11 345  vc
 vc  54 km / hr
45. Given : v paritcle  4velectron and  particle  2electron
h
Using  
p
 P  constant
  particle  p particle  electron  pelectron
  particle  m particle  v particle
 electron  melectron  velectron
m v
 m particle v particle  electron electron
2
melectron
 m particle 
8
46. Both the diodes are reverse biased, so, there is no flow of current through 5 and 20
resistances. Now, two resistors of 10 and two resistors of 5 are in series.
Hence, current I through the network  0.3A .
47. Applying Kirchhoff’s Junction Law at E current in wire DE is 8 A from D to E. Now
further applying Junction Law at D. The current in 3 resistance will be 3A towards D.

  I  I  I
48.
2R
 
B  0 iˆ  0  ˆj  0  kˆ
2R 2R
   
 0 I
 B 3
2R
49. weight = buoyant force
I 1
50. We have given, 1   I 2  4 I1
I2 4

 
2
I max  I1  I 2  9 I1

 
2
I min I1  I 2  I1
 CHEMISTRY
51. Theory based
52. 10 alkyl halides more reactive towards S N 2 reaction.
OH

53.
54.
O
alc.NH 3
CH 3  CH  CH 2  CH 2  C  Cl
CH 3
CH 3 O
NaOH , Br2
(Hoffmann CH 3  CH  CH 2  CH 2  C  NH 2
degradation)

NaNO2 , HCl
CH 3  CH  CH 2  CH 2  NH 2

CH 3

CH 3  CH  CH 2  CH 2  N 2Cl

CH 3 H 2O

CH 3  CH  CH 2  CH 2  OH

CH 3
(Major product)

55. Check balanced reaction given

56.
95
57. Mass of pure CaCO3  200   190kg
100

CaCO3   CaO  CO2
100g 56
56
1g
100
56
190 kg  190kg  106.4 kg
100
58. 2-methyl-5-oxo hexanoic acid
59. If both Assertion and Reason are true Reason is the correct explanation of Assertion
60. Conceptual
61. Kolbe’s reaction
62. Depression in freezing point, T f  iK f m . The value of van’t Hoff factor (i) is minimum
for the glucose, which is a non-electrolyte. Hence, aqueous solution of glucose has
highest freezing point.
z2
63. En, z  13.6  eV
n2
64. C=4, Si=6

3
65. i ) Co  en 3  ; O. I (only)

ii ) Co  NH 3 4 Cl2  ; G. I (only)

iii ) Cr  gly 3  ; both O. I and G. I

iv) Co  NH 3  Cl3  ; G. I (fac and mer)

66. i ) Ni 2 ; d 8 ; SFL; C.No  4; square planar
ii ) Ni 2 ; d 8 ;WFL; C.No  4;Tetrahedral
iii ) Ni 0 ;4 s 2 3d 8 ; SFL; C .No  4;Tetrahedral
iv)Co 2 ;3d 7 ;WFL; C.No  4;Tetrahedral
FeSO4  NH 4 2 SO4 .6 H 2O (Mohr’s salt)
67.
68.  i  B  Ga  Al  In  Tl : Atomic radius
 ii Tl : more stablein  1due to I.P.E
69. NH 3  PH 3  AsH 3  SbH 3 : Lemis basicstructure
70. i ) F2 to I 2 ; SRP values decreases
ii ) Cl  F  Br  I ; electron affinity
iii ) Cl2  Br2  F2  I 2 ; BDE
71. 0
72.
2   1  1  x  4   2   0
x  6
73. X = 3, Y = 2, Z = 3
74. I, II, III, IV compounds gives iodoform text.
75. 50   H  NH 4OH  57