( 1) j NDT-24IBloCheml03/20IBIOt03IC-4155I 1~-20241Set-AJ

BIOLOGY
Bio#03 : PLANT KINGDOM

1. In which of the following which is set of green 1.

algae :
( 1) Ectocarpus, Dictyota, Laminaria, Sargas's um
~ .
and Fucus
(2) Chlamydomonas, Volvox, Ulothrix, Spriro!zyra
and Fucus
(3) Chlamydomonas·, Volvox, Polysiphonia, (3) ~'11~;tJ4J-11t1, cll&:11,~, tjfofJRiqiJ~lll, 4'Nl?>l~'<f ~ q;m
Porphyra and Chara ff· .
~ ~
fl-11~'.<i◄ ll~'<I ~
V \

(4) Chlamydomonas, Volvox, S p ~ :rrr.r::tlm=, cllC'C11cffi, ~VIIIYl"I"

2. Select right statement 'w.r.t ::-mT'C'T.=)cfi ~ l) ~ q;~ q;) ~ :

'
(Phaeophyceae) :
(.-J1fi1qRf 3ITTf>R) cf> ma i oW m~
bear ·two equal apical ~i,
(2) They posses chloro_phy . ~ -~ I l?>llFM~R~.:r~q>W
phycoerythrin.

centrally locat~ va:cu

(4) Asexual reproduction ·
by multiflagellated zoos
3. Cytotaxonomy is based on : i
(1) Nucleic acid ~~tR
(3) Alkaloids (4) '11~~vt4't fflRct'iT tR
4. Majority of red algae te ~ fctR aBIT ~ ~ ffl cfft ~ i?
(1) Marine and warmer areas ~~ ~ 1Tii ~ ~
(2) Marine and colder areas (2)~~~at?!Tlt
(3) Freshwater and warmer areas (3) ~ <'lei ofl ll vn;f,~~
1Jii ar,n 1t
(4) Brackish water and colder areas (4) ~"GIB~~ a),n 1t
All are economic importance of bryophytes except: 5. ~ ~ ·t1•i~fillt1~l?>l~c! ~ ~ ~ ~-
(1) Packing ma.terial (2) Fuel (1) ~ cm trct> ~ 1t (2) ~ 1t
(3) Trans shipment (4) Succession ~.-faJ'1nz;Ptw\ 1t (4) ~
). Multicellular sporophytic phase is expected in the 6. ~§q=,~~l<Glll ~vtl'!J~c:{ ~ ~ ~-'tlw1l~vf@lt'7
life cycle of :-
(I) Euglenoids (2) Green algae (1) q_•c.fl41~~ (2) ~ mm>r
(3) Diatoms (4) Bryophytes (3) ~l~~c+f -~
Which is an intermediate stage ~)c'14''11 cf 4'1"g'ffi g•'fq,)~11~ <fi ~ ~ -qcfi ~
protonema and leafy gametophyte : ~t:
(I) Spore (2) Bud (1)~
(3) Prothallus (4) Thalloid body (3)'S!T~ .•#
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8. Answer the following question (a, b, c and d) by 8. ~lf!)f<i,<!il'3llmrlil>m"§Uf.!"'lw-i)(a, b, C-em!d) ct; 10. Identify the alga shown in figure and match. 10. fm{;j~lf!)ficm;ici;)~31'1.~lf!)~~~
using the given diagram : ~~: ~~"fl~~:

3 Correct match with the given characters is

!lumber ot Stored
(a) Name of plant (a) 'ITG1< <liT 'f!1f !lame of A11ae na,ella In food 1'ameolAlpe
(b) Ploidy of plant (b) lllGlf q\) ~ 1ametea ffl'llll
(c) Plant is homosporus or heteroporus (c) tfT<:l:t 't1"1•lhi!l'1cli <u ~~"1<l'lvi1'1cli Floridean
1 Polysi phoni a Absent
(d) Which type of event is shown by this plant (d) ~ lllGlf ct; 6ffl fc!,<f ll<ffl q\) filrm ~ q\) "vl'T<fi t starch

~ ~ - ~ - - ~ - - -.......:::.~ ~ ,~ .....-.:T~ -~------,-------, 2 Porphyra

(a)

Se lagine lla Diploid

(b)

Hetero
(c) (b) (d)

~~
(cl
~-<I>[ 3 Ectocarpus

2 Salvinia Diploid Hete~ spo~

m oC ~-<I>[
~

4 Porphyra ~ ffl
~
~ d h abit
I Ori m of
2 ~
~..-«" l, ~~
~
<ffl ~ ~ "lr'IT "GIT~ t
3 Pinus Haploid Ho
~- >:
4 Riccia Haploid Ho ,,... -:, 'l ""'~
'l'ef""'1'/<l>T

u<\'l'I
11. How many organism in
consider as biological
~ ""'~ ~<111'3<Qffl Mango, Elephant, BGA, C

9. Identify the following fi I

f.M ~ (A-D_ ! f ' ~ :- Riccia, Funaria, Rhiz.obi

I
(1) Nine ( (2)U:

•
1
( I. (3) Eight (4)G'fl
~- 12. Select the correct statem <li'l~.~.fi.)~~
l find out _c orrect option
(A) (B)
(B)

/~
, •
(A)

A
I ■ (C)

B C
(D)

D
A
(C)

B C
(D)

D
fil
1 Seeds are covered in fruit wall
fij)•Male gametes
1 are motile (ii).,. ~ lJfcmra✓
Salvin ia Dictyota Se laginella Cycas
~ ~ 'ff/7llfffl' ,Ifill) Presence of vessels (iii) ~ail e l l ) ~
! Salvinia Fucus Sphagnum Ginkgo (lv)Presence of naked seeds (iv)~ ell)~
rfl{!ffr' ~ fif,rq;'r
Fun.aria Pinus ©ptions ~
Selaginella Fucus 3 rfl{!ffr' ~ 'lTq-ffl
(!) II, iii (2) i, iii, iv (2) i, Iii, iv
Ginkgo (l) i~
Sinagnum Laminari Salvi nia 4 ~ ~ ~ fif,rq;'r (3) II, iii, iv (4) ii, iv (3) ii, iii, iv ~
 • (4)

13. How many characters resemble with 13. ~ ~ ~~..),).,;ii ~ '1 ~~ ~?

siphonogamous plants ?
(i) Presence of triploid endosperm in all plants
(ii) Always heterosporous
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(i) <l"ft q1c:<ii ' l ~ ~ l l l t ~ ! "

(ii)~~~ ✓
(1) Laminaria
(2) Sphagnum
(3) Selaginella
(5)

~
(2)~
(3)~
(4)~
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(4) Salvinia
(iii) Free-living gametophytes (iii) ~ ~ ~ ,. 20. Which of the following is not correct for Pinus ? 20. ~ ~ ~ Pf"l~~o >I '1 ~ ' f l t ) ~ t?
(iv) Synergid-cells are found in female (iv) 'ff'!ffl ~~•il')iifl ~ ~ !J'.'1<1>)~'1" 'f ~
t (1) Branched stem I 1l -mfa"o i1'!I .,...
gametophyte of all siphonogamous plants ~ ~ ;;iRU r .Jef'wm;r~ Br
(2) Coralloid roots -=-
(1) i, ii, iv (1) i, ii, iv (3) Monoecious sporophyte (3) ~~~
(2) only iv (2) only iv (4) ~q.,.flijjlj<ti ~ -
(4) Heterosporous plant·
(3) i, ii (3Jj,,H
(4) only ii fionly ii 21. . 21.
14. Fusion between one large, non-motile (static) 14. -q<i; ~ 3l'f«, ~ ) 'IJGI !J~cMI ~~"R~~
female gamete and a smaller, motile male gamete ~~ ...... t
~ elm~ .. .. .'f tmlT uf@J t:
is termed ...... and it found in .... :
(1) Isogamous, Cblamydomonas
(2) Anisogamous, Fucus
(3) Oogamous, Spirogyra
(4) Oogamous, Volvox
15. Which of the following stat

-(Jzl m\~w,'ll)=_
'fffl)~t?
(1) Porphyra, Laminaria . ~ q i f ~"TIGl'f ~WJ'f
as food. I '

(2) In Rhodophyceae ~"!Jlffi;iwmficf; ~ <l1B

bear two laterally a I Choose the correct opti
(3) Sex OJ:Elll1S in bryop ~§<f>)~1<tll<1 m-H I diagram :
(4) Bryophytes usually occ ~UT<ITGR~'R'lflt\ll@tf
(1) Chara - Red algae - -~a,d~
shaded. localties. 1rc!r<'i - ~ a , b ~
(2) Volvox - Green algae - c:hlo&lp!WII
16. Five kingdom classi.ficati-~ · ........
(1) Body ofE8llisation
(3) Chlamydomonas - B ~
M -~ - ~a,c~
-~~
Cl}1<n;gphyll a,
(2) Cell structure (4) Chara - Green alga~
(3) Gross morphology ~<'161~ Chlorophyll a , b pigments ~a.b~
(4) Mode of nutrition lU'l"TllltMt
(4) . 22. Match List-I with List-II : 22. ~-1~~-II~~~~ :
17. In brown algiie food is stored as : 17. ~~>l.mr~~N<!Jt : Lfat-1 Lfat-D ~-I ~-D
(1) Laminarin or mannitol ....ff)~m~~WJ>l (A) Psilotum (I) Pteropsida (A)~ (I)~
(2) Starch (2) ~ ~ ~ >l (B) Selaginella (II) Lycopsida (B) ~(llftt."\<'11 (II) <'ll!l<illf•~H!I
(3) Floridean starch (3) ~ ffl ~ WI" >l (CJ Equisetum (Ill) Psilopsida (C) ~ (Ill) 'tll!l<'11f'lf"51
(4) Oil (4) m.tWJ>l (D) Adiantum (IV) Sphenopsida (D) ~ (IV) 'l'GI.Jl~:s,
18. Common examples of mosses is/are :- 1 8 . ~ : : ~ ~ t ~:- Choose the correct answer from the options given ~~lfll~l\'1m\\lffi~:
(1) Funaria below:
(2) Polysiphonia (2) c/f~fllll'li'if.t<11 (1) A-N, B-Ill, C-11, D-1 (1) A-N, B-111, C-11, D -1
(3) Marchantia (3)~ (2) A-III, B-11, C-1, D-N (2) A-Ill, B-11, C-1, D-IV
(4) All of the above (4)~~ (3) A-III, B-11, C-IV, D-1 ~ I , B;il, C-N, D-1
19. In which of the following the plant body is 19. f.to;r >l '1 ~ll'Jl:ll"-ll>Tl! ~ . ~ ~~ 'f ~ (4) A-I, B-11, C-N, D-111 (4) A-1, B-11, C-N, D-lll
differentiated into hold fast, stipe and lamina ? snftt?
 •
23. Given below are two statements; one is labelled
(6)

23. ~ c:'t ~ ~
!JOZ1'4"l--'°"/:IOl_,_IC-4llllll16-0240IMJ~

t : 11<1' f.l,t1,U<'l<I> "'~ (A) t ~ ~ 26. Select the incorrect match :

(7)
26'.
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1@'cl ~ <l>T 'ff<R ~ :

j
as Assertion (A) and the other is labelled as 1liR"I (R) i:
Reason (R).
Aaaertlon (A) :- The gymnosperms are i1i1A (A) :• ~ faq~.flutl':j<I> ~i I Green algae, presence of
(I) pyrenoids, starch is the reserve food 1l"""8. ~11it~.tif.m
heterosporous.
'llafl~l"'!il"RA ..,--
Reuon (R) :- Gymnosperms produce two kind of ~(R) :• ~~c:'t~l1111R~~3lf11>1
spores, mega (large) and micro (small) spores. ~mt,~~~ I
Correct answer from the options given below : ~~,m~,l.)~i3ffi'~:

~
(1) Both A and Rare true but R is not the correct (1) A 31RR ~ ~ t ~ R , A ctfl-m\'&lrolll"ffi!i - .....~(f<i','M """511.'t

--
Red algae, presence of phycoerythrin <'11<'1 ~
explanation of A
(2)
pigment
~
(2) A is true but R is false
(3J A is false but R is true
(4) Both A and R are true and R is the correct
explanation of A
Green algae, Fucoxanthin
24. Which of the following statement~ s 'it f.r"'f -q.) '$'t;mlj<ll'r,ffl ~ -m) "!t't t? cell wall with polys
(3)~
correct with respect to brown al~
(a) They are found primarily in4t'arine ,l'l!T<)'Gfill_il
(b) They show great variatio • · ~'!!Gft@mt, . . . .
(cJ They usually rep uf'R~~iIB!..mmllr . Brown algae,
nonmotile spores. zoospore
(d) Common members 16.il~ 'IRl~~.-i!Gllr:l~~'{!frl•IIT<lllffi~I, ~~~
Laminaria and . --r
(lJ a, band c
27. Find the correct stateme ~~
(2J b, cand d ...Y ,1;_; ~
".,~--,y,, --- ~ 3lR
"'"'"' 't.'"'"y"
(lJ Volvox and Fucus
(3) c andd Ulothrix: and Spirogym -0$-ootillUllh _,,-..,,ii:' "'"""'mn:= ~ t
(4) a and b (2J Red algae have a d o l~<h)~R~..,- ~~ 00 i

Btate-Dt-1 : In p u,.,!f~~,:::::=::~~:;:~;;;:;;: ~~<I .flutl':j<(f>lC: ilffl!i_ vi)

phycoeiythrin ~~~~~~ 7>l c:'I "fl'lA ~~Mt
(3) Brown algae produce
body is sporophyte w , ~ -~ ilRIT i I lateral flagella ~ ~
foot, seta and capsule. (4) Carrageen is obtained from Gelidium & ~ ~ 3lR ~ <l Ul'<'I"~ i
Statement-D : The sporophyte in mosses is more il>IA•D : 'Im ' i t ~ fo!clmctfl 3Nffl 3lfircl; ~ Graci/aria
elaborate than that in liverworts. ilRIT i I 28. Select the correct statement : is. -mi~ -ch)~-
In the light of the above statements, Choose the ~ ~ ~ ~>l. ~~~if .)-m) i3ffi' ~ : (AJ Chlamydomonas exhibits isogamy, while (Al ~~l~-,;\lfl.J1~ ~ - ~~ ~ q ; ) ~
most appropriate answer from the options given Fucus shows oogamy t1 /
1
below : (BJ Isogametes are generally similar in structure, (B) ~ ~ ffl'IT, ~ 3lR al<fim >l WW{ iM
(lJ Both statement I and statement II are function and behaviour i,,. . ,.
incorrect (CJ lsogametes differ either in structure, function (CJ ~ l l l ' f f i ~. ffl>l~~lt3ffilfF!Jm,
(2J Statement I is correct but statement II is (2J 1lieR I '11ft i tR'g ~ li l@cf i and in behaviour . t1 l'
incorrect (DJ In oogamy female gamete is smaller & motile, (DJ ~ i f ~ 'T"l<I> ~~ 31R~ilm t ~
(3J Statement I is incorrect but statement II is (3J <l>l?R I 1@cf i tR'g <l>er-1 II -m\ t while male gamete is larger and non-motile ~ ~ 31R 3ffil mffl t I 'f

~31R<1>11R II~ .it!!

correct (lJ Only A & B (2) A, B & C ~ A cf B (2) A, B cf C
(41 Both statement I and statement ll are correct (3) B, C & D (4) All (3) B, C cf Q.. (41 ~
 •
29. Read the following statement:
A Possess chlorophyll a, c carotenoids and
:xanthophylls
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29. r.t"1~~ a ~ c f i ' t ~:
A. ~ a , c ct~)R4fH't1 C f ~ ~ i

a. qj)ftrcbJAA~~~~~.)fttt
•
35, Given below is the diagram of organism. Identify
the parts labelled A, B, C and D, and select the
right option about them :-
(9)
In:n-ll4j aoc:--to3/:10jllll)t03jC-41111111----,-.Aj
35. ~ ~ 'llIT
ft1?1 ~ m;ftc1 WI ~ A, B, C
?1?.:110 ~1Wlcfi't~c!m~flltflf~-mt~
~:-
t

B. Cell wall usually covered by a gelatinous

coating of algin ffift t
C. Gametes are pyriform and bear two laterally C. ~ '1l'W'lffll ~ 311<1iR~ ~t cl!fl en t!ITTfu~
attached flagella ~t
D. Members are found primarily in marine D. ~ ~ ~ ~ " l ! P ) " ( j f f f i t
habitats
All these information are related with group "l)~~~.t~l .
(1) Phaeophyceae (2) Chlorophyceae -{1'(~ (2) <Mh)l/lili'l\l
(3) Rhodophyceae (4) Cyanophyceae (3) ~ (4) '!11<1-,)l/lil;'l\l
30. Agar-Agar, which is used in culture media due i3ffl ~ ~ ~ ~ '3ttl ~
30. 1PJR- 1P!R. ftm;i;J
; : : higl) capacity of water imbibition is o% ed.. ~e!>@T ~ (l;Rl1I ~ vlTffl t, ~ lmlJ i?

111 Laminaria 121 Porp✓ \NE ro, ~

"{3)~ ~~
" 12, QRlljflffl"
,...f<f)°®tl%<1'l ,/t
(3) Chondrus (4) Gejiai~ \ ;
31. Identify the incorrect statemctf 4 31. ~ ~~~ ? Part (Al
'lfT1l (C) ~ID)
(1) In plants, growth byfi/e1~ v ision.~ur 4l) ~ ~ ~&m~ffl~uftcr-fq;rr; ~ ~

N -~~w~~tl<li"t crnl-ift~t
Sporopbyte Stalk
continously through ouy tfi~lifc ~ ~ itRR-mfcl ~ .) mtft ffift t I 2 Capsule Foot ~ ~
(2) -ln animals, growth is JinQgy upto
~ • I
g•'l<ffl<;:Pl<;:
~~ ~
,m:-

:::_Ii~
3 Sporophyte Stalk
(3) objec~ also ~ o~ sic.groJ h (3 ~-~ qffift tI 4 Capsule Seta ~ g•'l<lil<\fil<;:
(4) In maJonty of higher ~anisms ~ an~ .i/ cbm\JJ-A'i ~~<lmwR~~tl \
~_ 36. A : Bryophytes are also call amphi ·
reproduction are inclu~ events
32. Brown algae i~ characterised)by the ~ 1';~.¥t~ fW<. ._.clft ~ ll'R!~\ilJat : · · plant kingdom. ~
(1) Phycocyarun i2J• Pbycoerytbrin~ : h l i (-ll 'l>ii!illl ~~'l 7 (2) ~ R : These plants can live~ so
on water for sexual rep~ c .
(3) ~~xanthin , Ha~ , ~ e ~~ 1..\.
79 . (4) ~
~~ ~-~ ~ ~lff"IT qi) <l'l'l'1' ~~ (1) Both (A) and (R) are ~ d (R) is
33. ArtificJ.B.l systems ga,,~qual weig~
explanation of (A) .
vegetative and sexual characteristics, this is not 'Im t I ~ "lffi" ~ '1t'I t I <fdifcl; 3ll!ffi" ........ ~ ~
ll'RT 3IIBRt.) W!lf.lc! ID "(jfffi t: (2) Both (A) and (R) are true and (R) is the not (2) A~ R ~ ~ t ~ R, A <Ill~~~
acceptable because often __ charact~t/3 are
more easily affected by environment :
correct explanation of (A) t,
. (1) vegetative (2) sexual ~ (2)~
(3) (A) is true and (R) is false
(4) (A) is false and (R) is true or false
(3)A~t~R~tl
(4)A~t~R~~~tl
(3) anatomical (4) physiological (3)~ (4) -~
37. Asexual reproduction in liverworts takes place by: 37. ~ ~ ~ uA'I ... ~ ~ i :
34. Select erroneous (incorrect) pair ? 34. ,n;ia"!Jllf<ll't~:
(1) Binary fissiQn and .budding (l)~~~~
(I) Ulothrix-Isogamous type of sexual reproduction (l)~-~~il>l~wR
(2) Zoospore and gammae (2) ~ cl!fl 1l1t ll'RT
(3) Zygospore and fragmentation (3)~~~j;ffi
(2) Eudorina- Anisogamous type of sexual (2)~-~~il>l~;;J.R
reproduction (4) Fragmentation and gammae ~~~itit~
38. In bryophytes during sexual reproduction if male 38. ~ ~ ~ ur-,.i rt; tRR ~ iR ~ ~ ~ aiTr
(3) Volvox - Oogamous type of sexual (3) ~ - ~ ~ i l > l ~ ; ; J . R
reproduction
and female sex organ are produced on different fil"f fil"f ~ 'R ~fflit !.ffl ~ ~ ~ t :
(4) Polysiphonia - Isogamous type of sexual ~M1~q;)r.t<11- ~ IT<liRil>l~wR thalli then this condition is known as :
(2) Dichogamy (2) fll~'lilli<'l4qq(1j
(1) Monoecious
reproduction
(3) Dloecious · (4) Bisexuality (4)~
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39. The branch of taxonomy which is based on 39. ~ ~ - l l l ' t ~ ' f f l f f l W ~ ~ ~ ~"tt 45. Which of the following is odd one w.r .t. bryophytes? 45. ~ : " ' "$ ~ -.t f.p;r-.j \q' 1ll'Affl ~ f!!" ! :-
cytological information like chromosome number, ~-lll'tmJ!II, ~ -~ t R ~ t : (1) Heterosporous ~.fl<iil'14i
structure and behaviour is (2) Embryo formation (2) 'll"lf.1'1fur
(1) Chemotaxonomy (l)'ffl!'IR~ (3) Gametophytic plant body (31 !J•>t<l>'lc:flle; qrc:q fflR
(2) Classical taxonomy (2) ~ ~ (4) Show oogamy (4) ~"!JT'R ~
(3) Cytotaxonomy ...13('~~ 46. Strobili or cones are found in ?· ~"lfll'f<!f'lp)ulmt :-
(4) Both (1) and (2) (4) (1) ~ (2) m;jj (1) Selaginella, Equisetum ~ -~ - q
Spirogyra differs from Fucus as the former lacks 40. ;,<jlli\t11•111i~l~\q'fivolt ~ ~ - . t ~ M t : (2) Selaginella, M.olla (21 ~~lti:i<-11, ~ - . t
(1) Chlorophyll 'a' (l)~'a'<t\) (3) Equisetum, M.olla (3)~.~-.j
(2) Flagellated male gametes (2) ~ - R ~ < t \ ) (4) Selaginella, Sphagnum (41 ~~lti:i<-11, ~ - . j
(3) Non-flagellated male gametes ~"'~ell) 47. Which of the given algae has stored food which 47. ~ l'f(l-frcffi;r-.t \q' fllf<I -frcm;r-it 1'ftuR "fflfi; <!'llliciW~e"! cf
(4) Thalloid gametophyte (4) ~ l j i f t l ~ < I I ) is very similar to amylopectin and glycogen in '<'lli!4>)\il'i Ji .......r-1 ffilRJ -it g'tm t :-
41. Select the odd one w .r. t life cycle pattern of algae. 41. ~ ' 1 6 ~ ' i f i ! i - $ f f i l j ~ m ) ~ : structure?
(1) Spirogyra (1) Chara (2) Volvox (2)~
(2) Volvox (3) Fucus (4) v('Jf~
(3) Purus 48. -.j~~~"<illftrcl;Tlj~~-<11)
(4) Chlamydomonas a cellulosic wall -usually "' -.m ~ ~ ~ ~ ~ ~
42. _15 ~ l en ~ ~ - gelatinous coating~of ·
then the number of chr <t\)ffil!ll;r;,m:-M: ' (1) Ulothrix
rhizoidal ~ and spore (2) Sargassum
(1) 30, 15, 15 (3) Polysiphonia
(2) 30, 15, 30 (4) Chlamydomonas
(3) 30, 30, 15 49.
(4) 15, 15, 30
43. Which of the following fea
all the gymnosperms? Cycas, Pinus, Ginkgo, Mus
(1) They are heterospo Ectocarpus
. (1) 3 , (215
(3) Dominant
I• u phase is · (3) 4 _ ~ .
!J•'i<l>'lc:file;. fl<ii,~file;A~~t SO. Select the correct- option. w .r .t. ploidy level of 50. ~ .lj Jli'm: ~ - ~11 ~~~~-.~
14. Read the following four statements (a-d). · 44. f.lior'!fR~(a-d)~:- __ capsule, seta and _rhlzoid.s_~tively in Funaria. lj"flt\~111T~~ :-
a . In gymnosperms, female gametophyte is a -'l'il'!tlf!Gfl<i! if 'ITc:Tj:,-'i<fflqfit«; <lfl ~ !J~.fl,iti'j<lu\ (1')12~ 2n and n -·(2) n , n and 2n ~ 2n ~ n (2)n,n-c,11T2n
represented by megasporophyll ifflT ~ ~ tI (31 2n, n and 2n (4) n, 2n and n (3) 2n, n ~ 2n (4) n , 2n ~ n
~
,,·~ t.¥' 51. f.R i't ~ ~ .. ~ ~ ~ t ?
(2) In Selaginella, the gametophytic plant body b. ~ - . t ~ ~ 1 h 1 ~ - . t 51. Which of the following ls true for bryophyta ?
poS8C88e6 rhizophore (1) Sphagnum ls used as packing material for (1) ~111T"ll'm1!~~-~ilflfllitlm'l'lfi~
(3) Origin of seed habit can be traced in Selaginella c. ~ - . t fl<ii" ~ e l l ) ~ iliT tmt ~ w~).t' , transshipment of living organism as it can ~-.j ~ \ill ffl>ffl t 1fll!fll! ~ ~ iim-.t ~ lli'I
(4) Antheridiophore and archegoniophores are d. ~ ; i ~ 3 \ ' r > { ~ ~ ~ t l hold large· quantity of oxygen ~ ~ ffl>ffl t I
present in Marchantia (2) Sex organs in liverwort are multicellular and (2) ~-.t~wl'WI il§<il'lf~all<I c t t n ~ ~
How many of the above statements are correct? ffl1ft'I i'j "" ~ ~ .it) ! : jacketless t1

~
(l)Two (3) Oemmae formation is a common mode of (3)~i'tTl'llf.l>tful~;;r-R~~~t1
(2) Three asexual reproduction in liverwort
(3) One (3)1fll! (4) In bryophyta fusion of gamete occurs inside ~ ~ - . i ~ 1111 ~ ~ ~ ~ m t 1
(4) Four (4)'!1R oogonlum
 !ld:&T·:l4f..a,-I03/:ZOflll0f03fc-411511f l6-o::l--f ~ jn:sr-24, - -103,::io1mo,oa1c-4111SJ 1 - . -1w ]
(1:3) (13)

52. ~~,m~clil~31ml:RclR<t ~~-q~ ~ 56. Consider the following statements (A-D) 56, f.R"<l>"-Ri (A-D) tR o!IR~
52. Study the following diagram carefully and identify
~<l;~~~clil'!lll'!~~~ ~>m~ (A) Heterocysts are important sites for nitrogen .(A) ~ . ~ ~ - < I ; ~ t.J-<lM "if>liR-
the correct statements for the organi!lm ' shown
-q"~~clil'qlA°~:- fixation as well as carbon dioxide fixation ~~-<l;~~!ITTlt f Y .
in diagram and select the correct option from
(B) Cell wall of diatoms is indestructible due to (B) ~ c t l t ~ ~~ ~~ ~-7';
options given below :
presence of calcium carbonate "<l>R"l ~ M ' l t 1 / '
(C) In fungi, plasmogamy always ·occurs between 1q -.i;q.,,-l\~mmm moi~ -<li'IEZ!mmt 1r
two-motile gametes
(D) Algae show isogamous, anisogamous and (D) ficm;i ~ . ~ll'l!J•'lc#I aft~310..:g''l<!\1 llil>R <Ii~
oogamous type ·o r sexual reproduction uf'Fl~t, ../
How many of the above statement (s) is/ are not '3tWffl ~ ~ ~ 'flff t ?>t"
correct?
( 1) One (1) 11<1>
(2)Two (~)~
(A) Sporophylls form distinct compact structure
known as strobilli
A ~~~~~~f.rinur~
. '
(3) Three
(4) Four _.- ~~
-=== ....J2f ffl'f
·
(B) 1b.is is a heterosporous fem <l> 1IR ~ ~ 57. Chlamydomonas and chlorell~ ~ ~ 57.e ' "~' l<I ' ( ~ ~ <Ii ~ <'llllVI 11<1> -~ -<Ii "iITTl t .
(C)Gcrmination of spore lead ~~wYlg•'lc!ilt;~G~f.!'l\ur characters of algae but RH. · er pla\cd them ~. . ~'~~~<l>< ~ ~ ~ vf'R'l ll fcl><I ~ tR
independent monoecious _.......,= · in to protista on the basis of . ~ ~? ~
'fTC:1 !J•'l<!>)t;~G.cl> ~mffl~ I
(D) The development of t he
embryos takes plac1
(1) Mode of nutrition
(2) Metabolism
'-'.;
I..J..i (2) ~ -:s:. ·
(l)tlPl"l ~

gametophyte (2) I' 1 (3) Body organization Cl:::' ~ f ~ ffiili!I

(E) It is microphyllous pl.ail: ;;,.,uu11i'll'r.m ~ll,,r ~ I ....- (4) Reproduction <( 11 (14J~ Z
(1) A, B, D and E only In Pinus needle shape 1 s, repartee!. ' 7 t js ~~~ ~~ ~ctlt Mt I l"" ~ <Iii tm:'I" <Ii
\A.if.el in~~ ~~ -ii
1
(2) A, D and E only ~~;,l'J!'-t-- ( - the significance of these life ! ?
(3) A, C, D and E only , 2ll E 1 \~

s3in
cycle?
(4) A, B, C and E only , ~E fj) (1) lt protect the plants from cattlea r-lJl'◄: -F.\.~ 111~111'1~"-..irnTt
53. How many of the followin -..,..;--------i ~ ctlt~ "<i ~ ~~~ (2) It helps to plants high wind ~ ~ !A~ll!i11ftr1' ~ -<I'll~ t
set of chromosome in cc ll ? I ~ ~ (3) Xerophytic adaptation ~~ 96; ~G ~t(
Primary protonema of~ , · __ _ 1; ~~~ltm•,fl.-as : q ; ; f l f l ~. ~
• 1'11..°<i
0
(4) More than one opti ar,r correct ~ • ~" ~ m~ t -
~ , 'ITTl-liWfilftl, ~ - l i ~ ~ 2l
4
prothallus, Gcmmae in Marchantia, Rhizome of ,
fern, Capsule wall of moss, Endosperm of Pinus, ctlt cmftlq; ~ . 1IR <Ii '1"11 ~ ~ ~ - ~
Vegetative cell of pollen grain, Leaves of fern, ~ )" YI
Cotyledons of wheat, Leaves of Funaria
(1) Eight (2) Six (3) Five (4) Seven (1) 3!lo • (2) 9: ~ (4) "fflff
54. Which of the following is correctly matched : 54. f.p;J-q "Wi-!ffl -mt~ t? 59.
.
'--~\
~~-~ - ~
59.
(1) Eudorina - Green algae - Anisogamy
1
(2) Gracillaria - Brown algae - Oogamy (2) ~ -1i<7 ficm;i - ~
(3) Spirogyra - Green algae - O_ o gamy (3 ) «:m;~)•lllj~I -:- ~ frcm;J - ~
(4) Sunflower - Angiosperm - lsogamy (4)~-~-~ I Identify the fern :- q;,t ..,;) ~ : -
55. In Cyi:ii.s, roots are associated .with,__ 55. ~>l.:'!,of _ __ cf)~ei~Mt1 I
(1) Azolla (1) ~
(1) Fungi ., (l)<ffqcf;

=:,
(2) Dryopteris (2) ~
(2) Protista (2)~ (3) Adiant um
(3) Cyanobacteria ~l<l'l)he'l~,11 (4) Salvinia
(4) Virus (4)~
 Ttflll.Hlll'tlP

•
60. Match the Column-I with Column-II :
CollllD!l-1
I. Yeast
Column-D
(a) Antibiotic
(b) Pseudomycelium
( 14)

60. ~
illm'-241•-t03/:IC>I lll0f03 Ic-41111111---.1..g
-I q;)~-11 " ~ ~ :
ili'f<PI-D
(a)~
(b)~~~
••
66- The giant Redwood tree (Sequoia) is a/ an
. (1) Angiosperm
(2) Free fem
(3) Pteridophyte
(15)
66. firoR;I ~~ ~
(1) ~
(2)~'A
Irm-:Ml--f03/::IOllll0f031c-41118I IIII-Q340:MI-A!

(::SJ Ml-s)'l>l*c
) mffl t -

II. Gelidium
III. Fucus (c) Agar-Agar III.~ (c) 3f'IR-3JllR (4) Gymnosperm
~
(d) Alginates IV. ~ (d)~ 67. The most common type of spores produced in 67. frcm;J,)~~~ "'!1T'IRllil!IR11il'f«.'I ~ ~ P.
IV. Chlorclla
m IV algae are motile, they are :
I D m IV D
(1) c d b a (1) Sporangiosporcs (2) Conidia (1) ~ (2) <li'IMm
(1) c d b a
(2) b c d a yr<'c d (3) Zoosporcs (4) Chlamydosporcs ~~ ('+J ~'ll<l-s).ivt1'1
(3) a b c d (3) a b C 68. Which of the following plant groups produce seeds 68. Pt"1~ftila ~ ~ ~ ;fi;:;r f.iflt(, 1IR<IT i ~ ~
~d a b c but not flowers? f.tflt(, orgj 1IRm !?
~d a b c
61. Cyanobacteria arc classified under the following : 61. •M-,~~~R<ll ~ f.'t9~faa '1" ~ 3icrRl ~ ~ (1) Bryophytes (2) Gymnosperms (1) lU<i)'l>l*i:;'!1 ~~
lflll t? (3) Ptcridophytes (4) Fems (3J ~~il'l>l*i:;'!1 (4) 'A

~ I 69. In which of the following is a ~lo · . . f.l"1 '1" ~ ~ ) -fr<m;i cfl't.mT i?

(1) Protista

£ ~~~
~
::;:::~ (1) Chlorella (2) · ~ ~C'i/ (2)
~
(4)Algae \\~~'- ~)~_,~ R ~~
~ 3ffil'I7 ~ < I i i ~ ~ i-
y \/
0
70.
(3) Voluox
~~l~e mismatched _ ·
(4)
~ ~ 'i'IWI
(4) ;i<11:iW'll$'ll
~ l ~ w l ' I "'

~r
62. Fusion of two motile gametes :whi~ dissimilm: 62. D
in size is termed as , <i.; .0 ~ ===
(2) '!1'1!J"tcf>cil
() O (2) Equisetwn
(3) Salvinia
l¥lJ~(a_(,
..
~
-6'ftll::....e..e:
pt!: ":i-
~q'l.ivtl'j<li
"' .Q
jqq'l-'vtl'jcf> ,,
(1) ~q'l!J''l'j!:.
(1) Oogamy (2) Isqgam-f. .J
~ r::::).f ~ ~•>tcf>cii>" (4) ~1fi>1g•>tcf>cil 0. 0 . (4) Pinl.lS fl!flrAJq!.=ffl" - ~ w l ' I --

w.:
(3) Anisogamy (4)
63. A plant shows thallus levcl< or~1-1ion. ~t 63-7-~·r1G1t~ rJ WWHl~Mci-11ffi!lt~~lmTI 71. The moss responsible for >mi~ M t?
shows rbizoids and is ha11loid. I, n ~ s watet to ==i\!mT~fft1~3fll"ll-;;ftq;f'flili~q;..)~~ (1) Riccia (2)
e m al~ e t e s uR'l~ ~ ~hm~~~-gnrci,~lMt1 (3) Marchantia ~ i"1Pr-P7
complete its life cycle bccau ~
arc motile. Identify the group, ,1° which it- bc1onga lffliWI ~ ~ { ~ "'!11W cli 3icrRl 3T1ffl i ? 72. Select the common characten ,i; (fl'lr-1) ~ 1111 'i'IWI ~ I

~) Ptcridophytcs
(2) Gymnosperms
]j ~ ~~ fll'l>i4c
79~
i ( 1) External fertilisation
(2) Diplontic life cycle pa~
(3) Gametophyte as domin~ .
(4) Gametes formed by m1'Jti
..
t
~t
'1 ~ ~ t
f.lfim m !
(3) Monocots - (3)'~
(4) Bryophytcs ~~ 73. The first terrestrial plants which possess vascular 73. ~~~~ctr-mit~ll :fi~~~ ullE'I
64. Plants of this group arc diploid and well adapted 64. ~~~,ft-E)~imffmTT~ ~-q~~ tissues i.e., xylem and phloem arc c,m~~ff?
to extreme conditions. They grow bearing ~ ~ lITTf f I~~ "'!1tR ~ ~ mll'IT {I) Bryophytes (2) Pteridophytes (1) illc,)'l>l!I~ J2t~'l>l!l<;'t1
sporophylls in comps.ct structures called cones. iArn ff~~ <mm f I ~ "'!11W ~ t- (3) Angiosperms (4) Gymnosperms (3) ~ (4) ~
The group in reference is 74. Gyµuiospcnns differ from fems in having/being ~~ll<li"R<A"fll'-ft?
(1) Monocots (I) ~ (1) Embryophytes (2) Vascular tilssues (1)~11~1f1'1>1!1~'!1~ (2 ) ~ ~ ~ ~ i·
(2) Dicots (2)~ (3) Ovule (4) Archegonia ~~~~! (4)~~t!Tlfl"v1Rft i
(3) Ptcridophytes (3) ~R-s)q,1~c;'!i 75. Gametophytes do not have an independ.; nt 75. f.1"1">!" ~ !J•'1<1>)c;fi)c: ' I i i ~ itm i ?
(4) Gymnosperms ~~ existence in
65. Protonema is 65. ~~~)- (1) Dryopteris{2) Pinl.lS (I)~ ~tmW
(1) Haploid and is found in mosses _µ-('~ ~-qf:,:r ii lITTIT vlTffl t I (3) Riccia (4) Funaria (3) ~ (4) ~
(2) Diploid and is· found in liverworts (2) ~ mTT ~ '1 IITTIT u11m t I 76. Select the orgahism which belong to the class 76. clll!<ll'l~-sl <m " ~ ~ 1111 lllR ~ I
(3) Diploid and is found in pteridophytes (3) ~ mi ~R-s'il'l>l~c ~ IIT!l1 \illffl! I Lyoopsida.
(4) Haploid and is found in pteridophytes (4) ~ "cim ~R-s'l'l>l~c ii IIT!l1 vlTffl t I (1) Adiantum (2) Selaginella (I ) ~
(3) Equisetum (4) Psilotum (3 ) ~
 0

•
77. Select the odd one w.r.t . prothallus.
(16)
In:&T-:Ml..a,-to3/llOIJIIOfOSIC--4llllll

77. ~ ~ ~ ~ ~ ' i f ! R ~ I
1~,~
•
jt4. Members of Basidiomycetes
(1) Have sex organs but lack sexual reproduction
(17)
!IIIZl'-:Mj..a.-103/:aDjmotm(c-411181 i & e - - 4 1 ~
84_ -fltf%.,),m;flte'lvt J; ~
(l) ,)~3f'T~!~~uA•Pf;J ~mm_t
:
l"

=-~~
(I) Unicellular ....fi"f~<l>q,)fl1c6'14
(2) Generally do not produce asexual spores • (2) imi: 31~f1l<1> ~-it) ffi
(2) Photosynthetic (2) U<l>li!l'dit<'l41_
(3) Are pufiballs, morels and bracket fungi· ~q,4'fot. '1)~ctl ~~"<l>lf<l>.1.
(3) Thalloid gametophyte (3) ~~ (4) 'lffi'f "<l>Tll' -it)~ '(
(4) Do not produce fruiting bodies
(4) Free living (4) ~
85. Mycelium is aseptate and coenocytic in . 85. ~ ~ 1 ! T m -;;n'<'ll !?
78. Double fertilisation includes triple fusion and 78. ~ ~ ~ ~ " ! f ' l < l > ~ ~ - g ) m t _ f.19
(1) Phycomycetes (2) Ascomycetes t/>ljj4>)iii:;-flte'lvt (2) \lffi•MRte'lvt
syngamy is seen in 1' ~~'!Im '"1m t?
(3) Deutcromycetes (4) Basidiomycetes (3) <il£~'<)'11!;Rte'lvt (4) •fltf%41'11!lRte'lvt
(1) Mosses (1) 'ITT'!
86: ;frot ~ l't<m.•1 {'ff14'1)-~R <11) ~ "ii; mfl cii ~ ~
(2) Flowering plants ~ "<l1G'! 86. Besides_paddy field (cyanobacteria) are also found
inside vegetative part of: <l>iftlll;1fT1!~~>fi-qrq;;m1\~
(3) Ferns (3) ~
(l)Equisetum (2)Psilotum (l)~ (2)~
(4) Gymnosperms (4) ~
79. Io angiosperms, embryo sac has egg apparatus 79. ,>t1<!<1.f!Rit<1)~'!l"lilTT'l,)~~itffit ~11lfi~ (3) Pinus (4) Cycas (3) ll1!;0ffl ~
which includes one egg cell and ~ ~ .............. mc1t t~ I 87. Read the following five statements (A to E) and 87. · P!"'1~1'&<1"<1>tF!(A-E)~3flHl"ifi"fltt~cm;nfctcl;c;q
s _. - .h- -
select the option with all correct atatcmen..t;;!.
(1) One synergid cell .-llllili.....---l (1) 11lfi~"<l>)ftrq,r
(2) Two antipodal cells ~ ~~
(A) Mosses and Lichens are the ~ -.,r.i ~ '
tR
. m
1l"AA ~ ~
(3) Two synergid cells ~~~ tD colonise a bare rock

(4) One antipodal cell 'f:iJ€,; "<l>)ftrq,r (B) Selaginella is a homospor

· (CJ Coralloid roots in Cycas
~R>!llcllid!
VAMmJt

m ~;
~- ;frq;f<lili
G<mT t·

4~ -
80. Edocxupus and Polysipho . 1ii9_A \
(1) Haplontic and diplonticJlife
(2) Haplontic and haplo~ i~ t1
<l'-11~;:;frq;f'i'fw
:~w (DJ Main plant body in bryo g>iliffl'il;t'i~fflt. ~ ~R>!lt/>l!;c
·"ir-i1!1'1'l!f>fi~ t /
g•iictll'i~'i~'R~
. respectively § t _..,....
(3) Diplontic life cycle <( ~ gametophytcs are priieut'lwitbll
- ( ;;fr1R <!iii located on sporophyt
(4) Haplo-diplontic life cy ,
1 (l)A,DandE
81. All of the following as" " m wer•'@ft ffl'ffi1!~~iml"!J"Rmt? (2)8,C~E
fragmentation, except ___ _J/ (3)A,CandD (4)B, C~D
( 1) ProtDnema of mosses
(2) Filamentous algae
(3) FilamentDus fungi
(4) Unicellular organis
1 ,..._-== ""'fi...,;;;;; \2 ~ ~...r
::---......;;.i;..;..--~ : " f f i ' 4
ll're);ffirr

(4) \l<l>4>)1l1<t\'14 ~
I 88. In bryophytes and p
male gametes require
(1) Insect
(2) Birds :r
~-N~~~~~~

82. Mark the incorrect option regarding the scientific 82. 3IT'f ~ ~ "'IJ1I ~ ffl'il 1' ~ <l>I 'fflR ~ I (3) Water
(4)Wind (4)~
name of mango. I •

(1) Mangifero represents the genus while indica (1) ~ <m q;) c:-ffi ~ ~ 11lfi fcWI ~ !
t 89. Which of the following statements is con-eet ? 89. Pi'-l~!'&e, i!~crl'r.ml1tltR d!?
is a particular species
(1) Horsetails are gymnospemis (1) ~31'lllle,'1-Al ~ y
(2) Stems are usually unbranched in both Cycas (2) ~atR~l'!"'fl-1>1=1~-u,-e,q-1cR~~~
(2) It is in Latin language
andCedrus
(3) It is binomial name
(3) Selaginella is heterosporous, while Salvinia (3) ft/J/f}/¼,lqif> F<l•1'1'1"11".Jif> q1~t. ~ ~~
(4) It should be underlined whether handwritten
is homosporous ~im;ntf
or printed
83. Which of the following is commonly called sac
(4) Ovules are not enclosed by ovary wall in % ,jj'il'l(1(tfttql ii~~~ fflT ~ 'llff
gymnosperms g)ffh.,....
fungi? 90. Floridean starch has structure similar to: 90. 4vMl~4., ~<lfl ffi'il'll ~ ~ ~ t?
(I) Muror
(2) aaviceps
(3) Rhuopus
Z~
(3)~
(1) Mannltol and algln
(2) Laminarin and cellulose
~ (l)~al'N~
(2J~atR~
(3) Starch and cellulose (3J~afR~
(4) Agaricus (4) ~
(4) Amylopectip and glyco~en ~ ' 11il<'<i~Fcle., atR ~
 g
c-c- c - c- c- C
~ Ir --1a.-f03!C-4llllll 16-GQ40:Mt~ (iusT44t..a.••-/2Dla.-,mtC-411111!1& .oa40MI~
+ _ 0 (181 !JOZT44!BlaCllaD-,-
- (19)

7=0r L 5_ In which ofthe following reactions alkyne is not formed 1 5 _ f.l'-flf"fl~~lf~"'liff~ i l

~ - c.- c - CHEMISTRY
0~ ~
Chcm#03: HYDROCARBON
I. ~
BP
, NaNH,,
..) .)
ll,) ;rI , ,
,j
Br
·-
Zn dµ1!4 i. ~
Br
NaNH,, II.
Br

~
Br
Zn du st ,-

Br
.IV !r 1. ale. KOH

1. Toe product for the following reactions are

m.~ NaNH,, . / l
Br
2 . NaNH, ,
, (.., Br
Br I (:'(,....-
(1) only I (2) Both I and m
1 olrKnU ~ CH,-b- CH,- CH,~c.KOH► X
CH,-C-CH,-CH,-===-X ✓ (.
(3J Both m& IV (4J Both I and n
1 c,-l 1 I
H o~ H
6. Winch of the i>llowing hydroautxna ~ be chosen
H H as a reactant to .irepare hr:mn-3-ooe by the hydration
CH•- c
1 cH-cH, 1.o, , Y+Z c1-1,-b-cH•CH, 1.o,
2.H,0/Zn
►
Y+Z 1. ~ 2.~
I - 2.H,0/Zn
CH, 3.~ 4.
(Y) (Z)
(]Q (Y) CH,-C!!!!C-,CH, 1. H,/Pd-Ba H, 1. H,/Pd-BaSO, rl1
CH3CH2CHO CH3C"2CHO 7.
(11 (CH3bC•Cf¼ CH3C"2 2. Br,/CC 2. Br,/CCI.
CH3CHO CH3 COOH
(21 Cf¼-Cf¼ CH3 C Identify structure of -<1>'1~1
HCOOH
(31 CH3--CH•CH--CH3 CH., CH,1~--COOH (1) CH,-C ~ C-CH.,
I I
Br Br ·
CH,--yH--CH5' HCHO
Br
CH, .
I
2. The compounds CH3 CH•C H3 cl-err C~3 CH2 CH•CH2 (2) CH,- C - CH., - CH., 01_s -cA-f - ~-W~
I 1 q,,
CH3CI½CH-CI½ ' ' I CI <el
Br
(1) are geometrical isomer i
(3) CH,- CH, - CH - CH._
(2) are structural ieomera t
I
(31 exist together in d mt Br
(41 contains same num -sp2 m-~ ~ ffl i I (4) CH,-CH-CH-C ,-CH -CH,
carbon bonds I I I
3. ~~~~~~~~t, Br Br Br Br
3. Which compound bum with sooty flame
(11 Saturated hydrocarbons 111~~ - D 8.CH,-0-CH•CH-O ...l::W.c+ Major Product ~- CH,-O-tH•CH-0..lmt . ~~
(2) Alicyclic hydrocarbons (2) '1~t11gtfflct> ~
(3) Aromatic hydrocarbons ~~ (I) Br-CH,0-ctt • C H - 0 (1) B ~ H ~ C H • C H - 0 .-f Q•
(4) Alkane and alkene (4}~~~

4. ~ + X. ~Addition product 4. ~+x,.£fh.~~ ~l CH,-Q-ctt-ctt.-Q ~.-Q-ctt-CH.,-0

I I
Which of the following is incorrect statement for \3lRt1m ~ " $ ~ r.i..,~~~ ti "fl lll"RflT ~,rom Br Br
the above reaction. ii
(1) ~ lf ~ ~ ~ lf ~ ~ 3lltl'f 1lrT (3) CH,-0-CH.,-CH-o (3) CH,-0-CH.,-CH-O
(1) Reaction involves cyclic halonium ion aa
. I I
intermediate "&!It I Br Br
(2) Reaction involves carbanion intermediate ~~ lf ~ ~ ~ -.'1 <1>1ihll0111M 1'J1l "&II t I
(3) Reaction involves anti addition (31 ~ lf "llfmtrtT ~ t I ., (41 c t t , - Q - c t t - c H - Q (4) CH, - 0 - ' CH-CH-0
.::1 - I I - - I I -
(4) Chiral atom is present in addition product (4) ~~~~lR1lJVJ~t,-
~ - C-1-\ ~tJi 9-
~ -
or- cp, .,_
' Br Br Br Br

Cl
 @ ,:201
•
_,.__/IIOla-afOOl~ll!SI l ~ _ _.
jmr-::1141..a-,f03/1101Cbomf031c-411111l l~l11otf} (:21) 1
&'/ ~ c,. ... ~ l,
• ii, C~,-CH,-C = C H ~ I CH,-CH.,-C:5CH~ 0!.- \. ;<
KMnO m ~ ~ m ~ 1 l i f ~ l R ~ " 1 ~
(2) CH,-CH=CH-CH, ~~i_►
9. Which molecule will give following compound when 9. 4 - Br,
heated with acidic solution of KMn04 Pi"'l~~d~~- (2) CH,-CH=CH-CH, CCI/ cJI
2Bl'.
eel• 2Br
eel•
~-o-f< )

HO
~OH
<r1 fl HO~OH
(31 cH;:;;;CH

(4) CH,-CH=CH,~
(31 CH:aCH
(4) CH,-CHaCH,...!!!!!+
~::,·· 1 ~.,.
,-.
0,3"
c'(•'!)
0 0
0 0 CH,-CH=CH-CH., CBr, • (X}l.alc.KOH• M CH -CH=CH-CH ~ ( X } l .alc.KOH► M

(l)fp (2)f!;;
14, Cl, 2.NaNH., 14. , , cci. 2 .NaNH,

(l)fp (2)1:p Identify product (Y)

(1) Cis - 2 - butene (2) Trans . 2 _ B.utene
~(Y)cli)~
(l) Cis _ 2 _ butene (2) Trans . 2 - Butene
~ Butyne
(3) 8:>- (4)0 (3)8:>- (4)0 15,
(3) Propan-2-amine (4) 2 . Butyne
Read the following statements.
L Halogen in aryl halide is o-, p directing and
activating in nature
15.
(3) Propan-2-amine
Pt"'!~~" ~ ci;) tra'I -
I. ~ ~ -1j ~ o-, p - ~ elm ~fll;« 0 icf>~
~ < I i i ~ ~ I"'(' -. - -
10. Which p,:oduct is produced when sodium salt 10. ~~'if'@ltulil~~m~~ 11. Benzene forms triozonide which indicates the II. ~ ~ iRTclT t vfl aR ~ ~ ~
ofbutanoic acid is heated with soda-lime. ·, q;)~m~1Tif1R6tl o>i,,_u,,_p•tJc... .
()I presence of three double bonds ,c==: c:-mm t I ..,.,.-
(!) I"' member of homologous series ot · E ~
;Ii)

"°~~
(2) 2rd member of homologous ~
.(3) 3nl member of homologousJ '""es
''
o
e

'
0 11~
( I
~~~11>1~~
" JJMt<lil ~~
Cmll<l
~~ JJMt11>1~~ - J
III. Benzene reacts with C~ in preec':;,eef t-~lft:
to form hexachloro~b enzen
Choose the correct option
\ , \\ '-'
rrn~;U<lim<ll'l~ii C~
'- ""- ~~t 1/ -

"'-''°
<)_
.2-,:,.,i:i ,1;- · . :m') ~ < l i l ' ~ <IRI
~ JJMt 11>1 <lg'f ~

L 'l~~w V
(4) 4 th member of homologo'}s
(1) All statements are corr ~ ~t
11. Which of the following corDP.P } Na m ~ M f f l 4 , 5 - ~ (2) Only two statements ~ t ~~ i:\....;iR~ t
,/ Na to fonn 4,5 - diethyloc ~ ··•ii'<~"'.t:#-~ J' (3) Only one statement i1 ~ t l[<l>_iwi
' \ \ll) t
~
3)~
(!) CH,-CH.,~H-CH., -CH,;:-:-1,'lr (4) All statements are inco~ ~
CH.,
I r
I .
16. V ~;•) Product \\ . l
If the following-prO!!_ucts ~ "
) -~
obtained &om
~~~ /J
. ..,,._..,..,,""' ~
fl ~ ~~~'llltcfr.,;uufl~
·
CH, ' - - ~-• CH,
the above reaction then i~ tifrtbe.I>r.i\c!l 'tlil ~~~ ilffi vfl ~~~ii iRffl
(2) CH,-CH-CH.,- Br
I
Br which is produced in maximlQ,~~ A ~
CR, (l)UBr ~ % f) ·--..··"-Bri '2l(XBr
I I
CH,
(3) CH,-CH.,-CH.,-CH-CH,
-....:t::=f=~~_,~ CR,
~H,-CH.,-CH.,-CH-CH,
I
(3) P (4) ()<Br (3) P . ~Br
I
Br
(4) CH,-CH,-CH.,-CH-CH.,-CH.,
I
Br
(4) ·CH,.:....CH,-CH,-CH-CH.,-CH,
I
17. In the given reaction identify (X).
0~ (Y) Zn/H,,O• (X)

(1) T(iqzonide ·: ·. (2) GJ.yoxal

17.
o~
<!'i'!l~>i (X) cl'>T~ I
~ (Y) Zn/H,,O• (X)
~~
Br . Br (1)
Statement-I Wurtz reaction is best niethod to 12. ~-I~ffl~~~~~~tl r (3) Oxalic acid ·· (4) Ethyleneglycol (3) ~~ · (4) 'l~~.,,,,m1<t>'f('!
J,2- 18. In electrophillc aromatic substitution reaction, 18· ~ ~ ~ ~ ~ i ! - O C H3 ~
prepare methane
~-D ~ ~ ~ m-nFI 3R¥1~ the -OCH group is ortho and para directing 3111n {'Ill! tm ~ ffl t ~ ~ -
Statement-I neo-Hexane forms three different
structural isomers of monochloroderivatives
(!) Statement I is incorrect but statement ll is true
(2) Both statement I and statement II are true
~~<A@!

(1) <l'>tRI Tf<fflt~~II m)t1

(2) ~ ~ I ~ llJtR II ~ i
t If

I
/(
j_.{~;f[
I tJ
because it
3

(1) decreases electron density at meta position

(2) increases electron density at meta position
(l)
-,c,
-~ ==-==-
~ •=m '" ~"'"x'., """" ~
12 ) 1)cr ~ lR ~ ~ ~ t
"~""
4
to
_P
(3) Both statement I and statement II are false ~ <l'>tR I ~ <litR II 111.ffl ! I £. (3) increases electron density at ortho & para ~~ tm ~ ~ ~ ~ ~ t
(4) Statement I is correct but statement II is false (4) cl>'RI ~t~<litRII 111.fflt I positions
13. Which of the following reactions produces 13. ~ , ) " ' ~ 3iMm ~ll-!llli~<iilli,s 111'1 f.Pnul ~ (4) decreases electron density at ortho & para
gemdihalide. t1 positions
 (:3:ZI lmr~,---,~,a-fOIIC--411111116-4':141D 41a.t-Aj jn#441--,oa1211-lc-41111111 ~ 1 ~
~
• (231
. 51 6\§'.••", L\- ,,= ...
21.
<>-I
In the following sequence of reactions how many
~ .:, (ZI · •~ 24 _ r.t9~1bic1 ..,f>lfll';m 31:Jll"" >'t m<l'IG (Z) >l 'W" ft.a-"~
(~~,.. .
• ,oc1a.tim:e
' "I . 19 (Xl+O, (a<,ooo . ~Mn wYI > atoms in product (Z) are sp2 hybridised -
19. (X) + o;. -"":-" n >(YI ..,...,, ,(ZI . (A • IS .
(X) <Iii f.lmvt ~- -
"
$)
•
~ ~ jl"Rl -mm t
/
(XI .,. •;;;; .,., £::;.~~ ►(Z)
sp2~t1 ,;;-,
i.:.J 0 c..-c,>1r
-11 .--
obtained by Wurtz reaction of chloromethane
clit ~ \il) ~-n\l ! I
1 (Y)
(X) ••• ':°'..:: ,,,.. ► (Y) ~:;: ►(Z) o
Identify the statement which is not true
(11 Com~und (ZI can be prepared by Kolbe's 7-
~ (ZI 1!ilf.lmvt~~3!'l"Elc'l
.'I~
\il@1
t (X) is an alkyne with lowest molecular mass
(I) 13 (2) 12
(X)ll'l'~~~~t
ft'l3 (2)12
electrolysis (3) 14 (4) 11
(21 Compound (ZI is found in coal mines and
121 ~ IZI ~~ m-il-li ~ ~ ~ ~ tR 2s.
(3) 14 (4) 11

-qrm;;mrrt I _.,..
Consider the following reactions • 25. f.19~fbi11 ~ tR~<rm-
marshy places 3 / (A)C,H.+CH,=CH-Cl ~ ►,C,H5 -CH=CH, . (A) C,H,, + CH, = CH - cr ~ c . H . - CH = CH,
(31 ~(Z)-lia~illl~ sp -s3iflr<mtR.'l-mmt
(31 a bond in compound (ZI is formed by sp3-s
overlapping
~ (ZI -Ii H-C-H "iiil' clituT "S@l 109°28'
---
t~
(B) C,H, + CH, - CH, - CH, - Cl~C,H. -CH -CH,
I
CH,
(Bl c,1-1. + cH, - cH, - ctt, - a ~ c.Hs - TH - cH,
CH,

20.
(41 H-C-H bond angle in compound (ZI is 109°28'
CH - CH = CH, + HB~ ,.,,_.,. ,(Al 20.
(41

CH, - CH= CH2 + HBr ~ >(A)

(Cl c,tt.No, + ctt,c1-1,ct ~c,1-1. -©-- ~o, (C) c.H,NO,+CH,CH,Cl ~ ,c,H,, --@-No,
3
Major ~ Which of the above reactions are possible : ~ ,'t.) ~ ~ t I
Choose the correct option for the above reaction ~ ~ < i i ~ -m'I ~ <Iii 'tllR cfRi - (1) (A) and (B) (2) (A) and (C) .Pf!AI -am (B) (2) (A) -ntfl (C)
(1) Compound (A) is formed by stable ~ ~ 1) ~ (A) llilf.lmvt~~i!-mmt (3) (Bl (41 (A),(B) I (41 (A),(B) cMT (CJ

(2) Compound (A) is formed bY. tlec~ \lf r" 26. Identify most suitable ~ ~~~ ~ ~ ~
4 · 111T f.liltn, ~Jl~f-w)g) "!1111 eRT -mm t
~~:,.:H,CH•~;~ ~H•1:;:~C~CHO
addition \,.\ \ "'l
(3) Compound (A) is Mar "ll'li)ve additi.on ~ ~
product _ ~ ~~t ._,._.._...,,....~
Compound (A) is t
(4) -1'"'- ~ "
21.
addition
Which of the following
i~,;.;...a.i;_:
;J; .
' ""=~--(~ ~ "!Jiffl'l,<'l<lim>TeRJ"S@lt
<11111<1>~-w't<lc~'TI!'t~
(3) H2/Pd-C,Quinoline ~ ,
(41 H2/Ni, 6.
· line Cu/523K, 100 atm

-
• KMnO4 (s) •
(j)
--f,.,. __....:::,-::.-
undergo Friedel - Craft r (),'l. Which of the followin ffl'q-fl-~ ~ -q ~ -nff
- COOH . OCH,
contributor to the resonan ' Ii tm--'lllf~<l>-i•I ~ i I
1116"' 1210 -.ii- ~ ~-~-i;;;~•al (;)[() ~ 4
1 1 6 ---- tolulene undergo para ni ~ = ~Ir - --

91 ::~,:::i...~ $0(4¢i.
CH, CH, CH, CH, CH,
:]~t~~~ ~ ~ <ii:)1r$'1g<'!-1TqRt I
(I)¢
22. Compare rate of electrG
substitution (EASI
ONa NHCOG ONa
-~ !.J{
0)
9
J~(3) 1

0 0
NRCOCH, .

0
NH,

(I) (II) (III) (IV) 0 (II

~ill
0 0 (II)

> II > IV
(III) 0 (IV) 0 ,' ' . I NO, NO, r
~ Chlorination of propane gives four
,
28.
NO,
m'RC6 •R•M\4'1<1>~•1 - d l l R ~ ~ m'<I ~!I .r-A
NO, NO, NO,

(1) I > III > Il > IV (21 I > Ill > IV > II (2) I > III > IV > II . dichloroproducts. One of them exhibit optical if 11'1' ll<l>1ftrcl; ~ -s1,:f~tcn>fflT i I-sl:;<l\.•/N'Nlc<ll~ (ufl
(3) Ill > II > I-> IV (4) Ill > I > IV > Il (3) III > 11 > I > IV (4) III > I > IV > II isomerism. How many trichloroproducts ~ ~ ~ "ffll;cfl i) ~ ~ S:lii!4\.ithhlc<ll~
~ 'tl~fq<lcl'ilfi cm~) "!IT'a ~ vii ~ i)D
o IKMn2·:~ : 23. 0 IKM'f·~~Olf':c<J ~"-~ . ...@'
(excluding stereoisormesl can be obtain from the
dichloroproduct (that can show optical isomerism) c..-Fo/
23.
H,O, 273K
DQ
KMnO Olf' (Y)
KMnO
H,O, 273K
-m'I~clit ~ -
(Y) •
( I c, ~
\/- O'-f (1) Four
(31 One
(21 Two
(4) Three
(1) llR
~ (3) 11'1)
~
(41 6\;f
c.
6
Identify correct statement
, (II Both compound (X) and compound (Y) arc diols g("~(X)cl'-ll~Mzyn~t , 29. In which of the following compounds electrophilic ~ f.19>l.1111\'r-m ~ >l JD 111T ~~"<IT'! 'llct>~r.,qffq,
(2) Compound (XI is dicarboxylic acid and (2) ~ (X) 6l~cbli0~~<1>-ll'<'lt~~ (Y} ~ addition of HI takes place according t o f.llR~~g)mt 1 - - ~- .
compound (Y) is dial t Markovnikove's rule - ; - -_ ~ L
(3) Compound (XI is dicarboxylic acid and (31 ~ (X)_6i~<l>li0~~<1> ~t~ ~(Y) ~ '.' (II CH3--.CH":'CH-CH3 (21 Ph-CH•CH2 (11 CH 3-CH•CH-CH~_;H•C""
compound (Y) is diol t ' e i- - -e 2
-pl CH2•CH2 (41 H,N-CH•CH, C) (31 CH2•CH2 (4) H,N-CH•CH,
(41 ~ (X) ~ ~ (Y) <:r-l'f 'lli!<l>liO~~<I> 3!'vl 8
(4) Both compound (X) and compound M are ('I I
dicarboxylic acids (- C -
r
C • C'\
I
(' - C-C c.-c- c... c.-cI - c..
I ,.,
c----c c,.-c. 1
c::.1 C!:(
I
CI
I
e/ c.'. y c. i- C \
'f '-- C l
 -,,i,oia.-t031c-41sa116-02-:IOkl llot~ !Nm•:Ml--,o:Jf3Dla.m,-IC-4111Bl l
(2 41 §-,---- (25)

, . Which of the following ~ves alkynide with

30. f.i""1~f?Jic1 i1 ~ 11\"r-raT ~ ~ ,1 ~ ~ "ffl¥.I ~Br
sodi~ in liquid ammonia
(1) CH2=CH2
(2) CH3-CH2-CH3
~t,q>l!j"tl,-s '1"tT<ll t I
(1) CH2 •CH2
(2) CH3-CH2-CH3
(l)X, 1!"";,) ~Be ~& (l)x
~r

(3) CH3-C• C-CH3

....@rCH3-C a <;:-:C_!!J

31.
(4) CH3-C" CH
CH.+CJ,-!!!.-+?
For the above reaction which statement is not
31.
(4) CH3-C" CH
CH4 + Cl 2 -!?!.-+?
i3tM1R! ~ ~ ~ ~ m ~ ~ ~ t I
(3) ¢., ~~( 4
1~ f u ~ f u (J)¢B, ~B,(◄)f P-B,
correct
(1) It is substitution reaction (1) ~ ~ ~ ' ! I .
36.
~
V ,,rJ
2HBr Na
ROOR, (x) dry ether' (y) . . 36.
f"7r'l
V ;I 2HBr Na
ROOR > (x ) dry ether
>IYJ ~
l)' Q {
(2) It's initial step is Cl-Cl heterolytic bond ~ ~ ~ W 1 ' ! 1 1 G ' 1 Ci-Cl ~~~'SRI!
cleavage t How many 3° carbon atoms are in'product (y) ~ (y) -q 1W'~ 3 ° ~ ~ t I
(3) It gives ethane as a biproduct . (3) ~~~~,'j~~t (1) 3 (2) 1 (2)1
(4) It is a chain reaction _....._....,....,_;;;;:: ~~t (3) 2 (4) zero (41~

0--1-00 . ~ 00 -iL%)
H(a)
32· 2 HH(b)

Identify reagent (A) A) " ~1Wi!Rclm I 37. ~ +Br-to

(1) Cone. H SO4 (2) . H(d) H(c)

2
~ S 4 (2) Ale. KOH
·~~ ~~~
tiR11~.m:-~""61l1iT'fl~Wfl!>~

33.
(3) NaNH2

0 C:C- C:C
~~~~~
,~..._~,--,·~.,..,,

z.>- (.\
\

f;::C
-0 (4) t-BuOK
Na/NH,(Q
f\d:!...
(xi hydrogen most readily
(1) a (2
~
(2) b

~
What is (x)

(1)~(2)
G}» C4o/) 38.
(3) C •

Match the columns - I

Column· I
(4
-11 ~ ~ ~ :
cf;@11'-U
(Reaction)
(41~ (A) CH3-Cff,-CH2-CI ---+ CH3 ~ .;:.......=-~ (I) Cu/ 523K/ I00 attn
(3)~1
(B) (CH:,)3 CH ---+ (CH:,)3 C~H (Il) Zn / H•
(C) CH4 +02 --;--+ CH3 OH (Ill) KMn04
() , / Cone. r,so,, ? 34.
+- Cone. H.SO,, ?
6.
(1) A - II B - III C- I =11... B-m C-1
34. ~ (2) A - II B- I
C, - III (2) A -II B-1 ~I
OH OH
(3) A - I B - III
C - lI (3) A - I B - ill C - II
End product of the above reaction is fflqc1'~11il 3!f.irl~t I
(4) A - lII B - II (4) A - . m

(l)o6- 12,ro
C- I B - II C- I

(1)00- 45a 39. Auertion : Alkanes

can have infinite number 39. ~ : C - C ~ ~ ~ ~ ~ q,ffll'J ~ -q ~

(3,ro (4)ccr
fflitlVl~t ,

(3)ro (4,ccr
of conformations by rotation around C - C single
bond
Reaaoan : Rotation around C - C aingle bond is ~ : C - C ~ ~ 1 1 i l ~ ~: 'j<ltl1m11~ ,..-
completely free
(1) Both (Al and (R) are true and (R) is the correct ~Rc:);il~t?l'-ITR, A 11iT~'«letl<1>~01 ~I
~
~M':/.r
~ ~~
explanation of (Al ,
35. ~ l{•Jor
Anby. PcBr,
Identify (X) and (Y) respectively :
35. ~M':lor
Anby. FeBr,
ililm: (X) o~ (Y) WI 1IWffl I Cvl (2) Both (Al and (R) are true and (R) is the not ·
correct explanation of (Al
(3) (Al is true and (RI ia false
(4) (Al is false and (RI is true or false
(2) A ITtlT R ~ ~ t ~ R, A 1liT ~ '«ltic!'\<1>~01
t,
'( 3)A~i?l'-ITR~t l
(4)A~t~R~3ltfcll~t l
-mf
 \
er
'
c..- c.-c...

•
40.

KOH in ethanol
(IJ CH3 CH2CH2CH2Br
(261
!mr44i--/:IOIClloa-lC Allllll l6-0NCIMla.t..ij

Arrange the following alkyl halides in decreasing 40. ~ ii KOH~ ~!3..-~ot)_q;r ~~~ ~
order of the rate of l}-elimination reaction with ~ii f.'1"1~faa ~~~~CIR I

(I) CH3CH2 CH2CH2Br

(27)

CH, ,
c-(1"
'cu,
-/'J/Ola-fmJCAJ.8811.__-J~

H .

/CH,
J

\ c;. -
c.-

(II) CH3 CH(Br)CH2 CH3 (II) CH3CH(Br)CH2CH3 · (4) .,.,c-c,

(III) (CH:J3CBr (III) (CH3)aCBr CH,-' 'H
(IV) 9l2 • CH - CH(Br)CH3 ff,/Ni►
(IV) CH2 • CH - CH(Br)CH3
~IV>III>II>I
44. 4-Isopeopyl-6-methyl hept-3-ene
A
? 44. 4-3111it1'iw) ftl<'t -6-~l'f H,/Ni►
A
?
(1) IV > ill > II > I (2) III > IV > II > I (2)III>IV>Il>I
The IUPAC name of the product ls ~<IITIUPAC'IA! I
(3)I>II>ill>IV (4)I>IV>II>III (3) I > II > III > IV (4) l > IV > II > III
(1) 2-methyl-5-isopropylheptane
(l!_)-~-5-311!iffl>t)f<l<'I ~
41. Ffiedel - Craft acylation can be used to obtain 41. f.'1"1~fat1 lj~~~<mm«!~ct ;~ ~~ . (2) 4-Isopropyl-2-methyl heptane
, which of the following_ compound.
...,12) 4-31Uit1Mftl<'l-2-~~
(3) 4-IsopropyJ...6...methyl heptane (3) 4-3111iffl>t'lf<l<'l-6-~~
NO,

(2)$
NO, H,C CH, (4) 2,5 - dimethyl - 4 - propy1 beJ1ane
H,xCH, (4) 2,5 - ~ - 4 - ~~

(l) Y. 45· NPh dil.H.so.,A (Major)- Themajoq:rcxf~ · A./Ph dil.H,.so,,A (Major) • ~~t
(2) 0 .....- - ~ - ~ O OH CH, t _ r '1
CH.. COCH, I
~CH-CH-CH,
I
fH; ~
(l)V . (2) CHr-C-CH,-Ph

(4)$
COOH

(3)$
CH,
I
OH
OH
t
COCH, COCH, ~C--CH,-CH,
bH,
42. 'Ibe l:illawing compound
reaction
~~~_;fl~t,
---- 46. Which of the following co
optically inactive compo
hydrogenation
H,-Ph(4l .l...vJ.
~ l!liff)ut4"1ct>~"i
t, ---:S y~--
'ff

H Me

(1)~

(3)*
1110+c1~ An

(2) 0 + ~Cl.:.-=:::...=~
H Me
( 4 ) ~•: (..YM:
~ T ,,-- (4) ~
Ale. KOH 4 7 . Which of the following reagent is used for
(31 A ' 47. f . R i l ~ ~ ~ l l i l ~ ~ ~ - . j ·
Br- unsaturation test in organic compounds
~,l;~fflfflt r - ~
~ H./~
(1) Tollen's reagent (2) Baeyer's reagent
(1)~~ ~3@BL
141 V ·Quinoline' (3) Schifl's base (4) Soda lime
(3)ftr1'>SRlll (4) ~ ~
43. Which ex the following hydrocarbon has the zero 48. ~ B r Dry~er•(Ml
dipole JDllll]eflt. 48. ).__,, Br Ory~ftiei' (M)

CH,'-. /H 'I
Identify compound (M)
(1) 2, 4 - dimethylhexane
~ (M) ell) ~ I r-
C. - c.. - C.-
~
c:::-c -c.
(1) .,.,c - c, _ 111 2, 4 _ ~ w m
H ,r "(.;ff,-CH, (2) 3 , 4 - dimethylhexane
(2)3, 4 - ~ ~
(3) 2, 5 - _4imethylhexane
CH,, /CH, (4) 2, 3 - dlmethylhexane
~5-~~
121 H / c - c,H 1412,3-~wm
•49. Friedel-Craft reaction is type of
(1) Nucleophilic substitution reaction
(28)

(2) Electrophilic aromatic substitution reaction

(3) Acid - base reaction
49. fim.;r-~~lfilW!iRtl
(1) ~~~~
~~~'1~€1 ~~ ~ 3lfllfil;m
(3) 31-r;_;f-e!R ~
-
55_ In the
.
.
free radical
. halogenation of meth
chain propagation step is :

(1) C'2~2CI
ane,
(29)

55.

{I)
jnsr441-.a.-to.1~la...tmlc-4111511_._I~
--'-'---'

C'2 ~ 2 C l
......,.__..,.__
.,..., " ' ~ ~~1v14'1<t><"i ~ 'i<ll<ili ~-qc:- i;

/
,.
:

(2) CH. + c 1 - cH3 + HCI

(4) Nucleophilic addition reaction (4) " ! l f i 1 < 1 ; ~ ~ ~ ..)2fcH, +c1-cH. + Hc1
~ ~
(31 cH. +cI - c H3CJ+H
H. SO. H, +? (3) CH, +c1-cH, CI + H
50. LJ "', Lindlar Catalys? ? L} "'' ~dlar Catalyst (4) CH, +CI-CH,Cl
(4) CH3 +c1-cH.Cl )4
Product of the above reaction will be ~ ~ l f i l ~ m'T1 I 56. Among the following reactions select th .

~
56. F-i"1~fad < i ~ \ f f i ~ l f i l ~ ~ ~
w hic h 2° halide 1s
· the major product.
· ose m
~i, .
(I}~

(3}~
(2}ifA-

(4)0- (3) ~ .
(2}~

. (4}~
I. ·.6. !3r~ hv I. 6 Br,/ hv

~ t type of reaction can not 1.;::J:¥,jft;rfac! ~~~~"'itl~~tl II. ~ / Br,/ hv ~ Br,/hv

7 fpllowing compound
III.A:,_.,.,~ ~
0-CH•CH, CH,
N. l .&· HBr
HBr

~ PeroxideJ rde)

(I} Free radical substitu ·

(2) Electrophilic addition f ./
- 57.
(1) II
(3) I, III, N
(
(
Which one of the folio ·
(2) II & IV
(4) Il, 111 & IV y
~~~~~
(3) Nu\:leophilic substitutio •~ I rt· one isomer upon mono ffl'!llfiir:jt-lTS<~r:ui~ ~ "l1<f> ~ ~ i I
(4) Electrophilic aromatic~ s aromatic substitution
~ctl't~~~-.t; .
52. Which of the following se_~j c

(2)$
CH, CH,
required for the preparatio
(l}~CH,
(I) CH,-COOK , electro! si
6H,-COOK ·
, Zn Cl .
' CH,
(2) C 2 H 5CI , Zn/HCI

(3)0 (4)e:
COOH , NaOH CH, c~
(3)0- ~
(3) CH3 C~COOH , NaOH 3 2 CH,
(4) CH3 CH2 CI, Mg
(4) CH3 C~CI, Mg
3RR arraif<lq;~lifl~"<ti ~ lfil ~clfffll! I
53. The intermolecular force that determine the 53. - \
CH, CH,
relative boiling points of alkanes
(1) Hydrogen bonding 58. Statement -I Alkene + H., ~ 1 Alkane Both 58. ~ - I ' l ~ + H, ~ ' I ~
(2) Vander waal's force Pt and Pd catalyse the above reaction at room
temperature
Pt ""'11 N_;wn ~ .ti ffl"II t i . ~ ~ cJ>1 ~
(3) Dipole-Dipole attraction <f>fflff,,,,...--
Statement -D Benzene losses it's aromaticity after
(4) Ionic bond ~-D ~~~,m;-~~ ~~Vt~c11e11
54. Aqueous solution containing sodium 54. add!~on reaction so benzene does not undergo
addition reaction easily « r ~ t ~ ~ ~ ~ ~ ~ -rt't ~
propanoa'.te and sodium ethanoate on t1
electrolysis yields. (1) Statement I is incorrect but statement TI is true ( 1} llit.-l I ~ t ~fllr.n1v..1 II "flt) t I
(1) Only propane (2) Both statement I and statement II are true ~~I ~ lPf'i' II "flt) ff I
(2) Only pentane (3) Both statement I and statement II are' false (3 ) ~ 1/itA I fllJT <1iiR II ~ tI
(3) Mixture of propane, ethane and butane (4) Statement I la correct but statement II is false (4) 1/itRI " f l t ) t ~ llitRII ~t I
(4) Mixture of methane and propane
 c~c-c_c__
t
c--c.-c-
rI
C.

jmT-:Mi..-l03/111DICIMml03IC41SS(1&.m --laot-Aj
=
--
(31)
• (30) , . Highest boiling point is expected
Compound JX! on reaction with 0 3 followed by
~ (X) 3ITGIT'f. Zn/H O <fi "ffltl ~~ <fi--!K_ . for· 63. ~~~~~t,
~ <fi ~ q ' I ~ ~ 31'1-. 2-~R'I~~ ~ t I
59. 59. (1) 2,2-dimethyl propane (2 ) 2 -meth
(3) 2-methylbutane (1) 2,2-dimethyl ~ e (2) 2 - m e t h y l ~
Zn/H 2 0 gives acetaldehyde and 2-methyl H ylpel).tane
propanal as products. The compound (X) is ~___o;qt o- .
141 exane . (3) 2-methylbutane ~exane ~ '1
~H3--CIH--CHiCH--CH3 64. CaC2 2. Fe-:t':
1
heat ~A so,+Conc.Hz90, ➔B
64. CaC2 1
► B 'Q
(1) CH3--CH--CH=CH--CH3 2 . Fe Z£bmr ) t ~ £ C.SO;+ Ounc.H;aS9,
Identify incorrect statement
I ~ ,i;wr <11'1 ~ <l'Rl -
CH3 CH 3 (1) Compound (A) contains 14n+2 ),r e·
(1) ~ (A) >l (4n+2),i e·i ./
(2) Compound (B) is benzene sulPh oruc
(2) CH3 --CH2--C=CH-CH3 (2) CH3--CH 2--C=CH--CH3 . acid (2)~(8)~~-t ~
I· 1' (3) Com~und (A) is formed by cyclic ,._~
4) SO ff · •
_
po•.,....,usation (3) ~
(A) cm f.t'ltor .'il~hl ◄1;i:1<Gi<l>~or -.;RT llTffl t /
CH3 CH3 ( - 3 activates the benzen . _JM/403 H, ~ ~ ~ ~ ~ ,t;) ~ clR
(3) CH3 --CH 2--CH--CH=CH 2 electrophile e nng .towards
(3) CH3--Cff,--CH--CH=CH 2 ~t
I ~C:CH ·

(J (. . ;. ,-
I CH ~C:CH
CH 3 3
.y _., (.)\ 65. V ....2lm4(x). What is (x) 65. V ....2lm41x> - (x)~t
(4) CH3--CH--CH=CH2 I
(4) CH3--CH--CH-CH 2 Br Br
I
I ~i-\ I

o"'-/
CH c.. _,.()1) ~CH,--CH-Br CH,-CH-Br -~C-CH,
3
(l)v Br (2) ) ~ I Br -...,ft!V -~
Br
w gso. > ~ - '3<'llG (

Identify correct product °' ~ . H,SO, (4)

(4)y
l""'l(C • CH,
~
(1) v0
(2
~
__ ~
OH Br

.Z ~u 66. Match the column.

oA o

(A)o
Column-I ColUDID • D

f~~~~~q
(3) (4 ··-,:·· 0

61. An organic compound (X)

dilute ff,S0 containin""'",_,;....;.;i,. g,, · ffi'<I>~
(&
~~~
4

CaHo <ffl'
)
<l:J
t
I ffl ~ , t ; ) ~ qffi1T

4
a compound (Y). Com~nd ,"'(Y)~ " ' ;o }1' (}6
9~ Ai& ~~ ~~,ftfTr<l;Ml!l'<IID<ll~I~
~~
(B)~ 11~~

(C)6
obtained from a reactioN~ nzene wl.Th~ ~ "" <fi mill~ 111't
chloride in presence of Anhy. AJCl . Identify
3
correct answer from the following options.
~ , i ) > f l ~ M ilill!l'<lf<vtll;;;ji<l<l><fltl
f.'l+.t Fc,i f&a 1' -ff ~ i3"ffi WI ,w.f <IR
Ill Can form glyoxal as a (C)6 llJ ~ ,ff

x-0"
(D)o-
Ci=CH Ci=CH
~ 0'CH,-CH,
(D)o-
(2 ) y =©"CH,-CH, (1) X = 0 ' product on ozonQ\ysis
(1) (2) y
0 0 .

,.-:::y-C• C-CH, r,;:y8, II . IV Aromatic nature

IV~~
(3)X=V
(4) Y - t...:::) Cl (3) x=0'CiiiC-CH, .)'Jf¥=0'c'CI
(1) A- Ill, IV B- I, lll, IV (1) A- III, IV B - I, Ill, IV I"
62. Statement-I Trans-2-butene has less boiling il>f-A-1 s;Rl-2-~ W I ~ fffil-2-¢,1-ff ~~I C - 1, II D - I, II,lll C -1, ll
62. D - I, 11,IIJ
point than cis-2-butene (2) A - Ill, IV 8-1 ~ - J D . IV B -1
Statement-II 2-Butene has more
C - I, II D - 1, Ill C - I, II- D - I, Ill
hyperconjugation structures than propene (3) A - I, III, IV B - I, II (3) A - I, !!1.!Y B-1,11
(1) Statement I and II are correct
(2) Statement I and II are incorrect
C - I, II, IV
(4) A- I
D - 1,11
B - lll
C - I , II, IV
(4) A- I
r D - 1,11
l"
B-111
(3) Only statement II is correct C - II 0-IV C - 11 D-IV
(4) Only statement I is correct
 -----zrn:cr:rrfRP'JC '7lEvrapGGW

(33) !nn441_,.il03~1Cllomil03 1C4Ullll 16-03--I~

. . (l)A - 1 B - II C - IIl _D - IV (1) A - I B - fl C - III D - IV
67. Which of the following is used for the following (2) A - JI B - IV C-I D - III (2) A-JL B-IV C - I D - ill
conversion (3) A - II B - III C - IV D-I ~ I I B - III C - IV D - I

c5-c o CO,K
c5-c oCO,K
~
(4) A - IV B - III
0
Conc. HNO,
72- ~ Cone. H,so! Major1>roduct
C - II D-I
.
(4) A .:-iv B - III C - II D - I

(1) NaOH + CaO

(1) NaOH + eao Me H
~0.~3Jlltre'I

~~
(2) J-1,0 , electrolysis 0
(3) Zn - Hg/HCI O NO, ~ N O,
(3) Zn - Hg/HCI
NO~
(4) HI + Red P
(4) H1 +Red P (1)
(2) ~ .
(1)~- ~ H
HgSO, k Me H
~ dil.H
.n, ..,..,
2s0: ~
68 HgSO, ·•H
: ,- ~ J . .e dil.H,sO: etone · e
Which of the following ketone can not be ~ ~ . ) f.l"'1foif&o '1 .t ~ ~ "fiff ~ 0 "

(~~~ ~
0
obtained by the above reaction. ~ __,,_ _ . .A-,;::=:t.:::::
·
~
(4)
(1) CH,ii'fH~ H,
OCH,
(2) CH,-CH,
g
H-CH,
/
(2) CH,-CH,-C-CH,-CH,
V
(3)~
O,N Me ~
O~ e ~
CH,
(3) CH,- 6H - -0(4) ~ g:q -0---tfl CH~~
./
-o·;. 73. The major product of the fo>l#wibN ~

Br~Br
. :;,;
,.cf;§=<'... - ;,s<l
'~''
~

r
,
..,;r~~t1

•
Br Na/ dryether >
l'J.
H

JIJ· An unknown compound (A)IJ

6
of Br /CC1 and is oxidised~ by
!;!:l_; ~.w,,-.~ ) C6H 12 , Br2 /CCl4 11il~<lffill
, ,HRT~~<l>lii~foi qi (1)0 (2)6
~ afi~~~;;nmt I (A) q\) m<RT ~
2 4
optically active carboxyJ a 1
structure of (A)
~
\\
~
l)
•

(3)6
~
70.
(1)

.;--y"
(3)
How many different i
(4)
n
(2)

(C.,H 0 ) (excluding ste ·somer)

14 2
·~ ~ ~~ ; ; ;

;,,;;,;::-....,_
,
~
1"<R~~WI~
~ ~~
7 14 2
H 0 )
.

-=~~
~1,.j;, 0
(2)

~
74. CH,-CH• C H , ~ CI.
N1,~ h

How many structural i

decarboxylation give 3-' e~ lpentane ~ ~~t

product
✓
(1) 4 (2) 7 (1) 4 - (2) 7 c.-c.- .f- u- c......- (P) -~
(3) 5 (4) 8 (3) 5 (4) 8 C.
(1) 4 (2) 3 (3) 2 (4) 5 (1)4 (2)3 ~ (4) 5
71. Match the column-I with column-II. 71. ~ - I <fl;~ ~-II WI f;n;m/- 75. Identify non-benzenoid aromatic compound : 75. ~ ~ ~ - q \ ) ~cr;'<'i :
c,- c
Column-1 (R.eacdon)
A. CH -C ,. C-CH3 ➔ cis-2-butene
3
8. CH3 -C = C-CH 3 ➔ Trans - 2 - butene
-~ - I ( ~ )
A. CH,- C•C - CH, ➔~-2-~
B. CH,-C•C-CH, ➔~ -2- ~
- c - c- c
'
c., 11100' ._ (2)6 (l)~
~
. ,,,.....,,)L
~,u
C. CH3-CH-CH-CH3 ➔ 2 .- ~
C. CH3-CH-CH-CH 3 ➔ 2 - Butene

Br Br
I I Br Br
I I
D. CH3-CH- CH-CH3 ➔ 2 - ~
(3)0
r·
(4)0
D. CH -CH-CH-CH3 ➔ 2 - Butyne
3
I I 76· Which of the following gives ele c t rophilic
I I Br Br
Br Br aromatic substitution at meta position
-~._;r,i-n ( ~ )
Col11Dlll-Il (Reaeent) (1) Anisole (2) Benzaldehyde
(I) alk. KOH, NaNH2 / 6. (II) H, / Pd - C, Quinoline
(I) alk. KOH, NaNH2 / 6. (II) H, / Pd - C, Quinoline (3) Toluene (4) Chlorobe112ene
(III) Na/liq. NH3 (IV) Zn dust
(III) Na/liq . NH3 (JV) Zn dust
 j,o:rr-lM(aloCl,omf03/:IClla-,,f03 (C-4111SI 11>-m-:ac>lMI - ~
(35)
(34)
f.l"'lfZ.l~<i i't ~ ~ ~ 11 ~ <t; ~11 ~
(1) Only JI ..,{1fW<fR JI
77. In which of the following reactions free radical
11.
~-..mit1
(2) Only I and III
(3) I,JI and III
(2) ~ I mil III
(3) I ,11~ III ~->I ( ~
-- ~
is formed as an intermediate

(1) 0+ CI,Anhy.FeCI,► 111 0+ c1,WW·FeCI-. (4) I and JI

CH,=CU Cone. H,S0, (4) I elm II ~ ~
~ ~i : ~ ~
· • ., Cold -. P product is • CH,•C Cone. H,S0, 0-f=c>i
~ O O K + H20 """""'""'-- 84 84
(2) Cff,COOK + H,0 de<tn>\r- ➔ (1). Ethylalochol (2) Ethylhydrog .
(3) O• Br,cci., •
(3), Ethane
,. ·
· · (4)' Ethyne
ensulphat
"
~=~""=
Cold p
·- -~ lt!Y_
O• Br, e (1) Q~tilQc;,,Mltil _;;.,r~i«<""'"5''~' -, '--

~ ~
(3) CCI. 3
. 85. Identify correct statement . 11
(4)O+Hl- (4)O+HI-
~ , Product ~ )
I. At ·high temperature an~/ 85. -ml~ i f \ ) ~ <fRT :
(4)

~
78. CH, + o, or pressure in the I
, . presence of nickel catalyst h drog . · '\'l'ii:!ffllf<lm/ 'll!Gfil'Rf.lq;;;i~<
78. CH, + o, _.._ Product ~~'!m<ll"G~~ ..:. .•
be,nzen~, gives cyclohexane
' Y enation of ..o 0=="~... ~
11>1 t:1,;iiili.iHl<i>~ 1~li\<MIS<ffl'l i' 1.......- -- -
tl'l~-ij~
Identify product in the above reaction
(1) ~ (2) CO2 + H 2

~"~ ='" i\<"cfs;N>liitil "' 3ITili1fUl "' tl't'<".!]!li@{iitl3

(-1) CO (2) CO2 + H 2 ,
2 ---@JC(s) (4) C2H 50H JI. ·Attack
-• , , of electrophile
m the ,ormation
to be
of areniumnzcne
.
.
. nng .results JI· i;;fA = 4 • _,_ _,_ ""
(3) C(s) (4) ½H50H
79. tR:-2~ ~ btR:-2-!;L 10
f.tR:>t ~~mm i' ~ ~ ' f l~
~
79. Pent-2-yne ~ Trans-pent-2-ene of the carbon is sp3 hybricli e- ~
t - F
What is (A)
(1) "2/Ni, t,.
(2) "2/lindlar'S catalyst
III. In case of nitratio
. olooUOpruld• ao; n ~ U'Cf'. ,.,., •.,...,.,,.
---..,m mt1~-~~- ao; ""'~
(2) (4) H2 /Pd-C
(3) Na/NH3(~ (4) -~~ffli'l~i'I (1) Only I & JI 2
( ) '>•-'JlliZ",.___ " ~ (2) ~ I om JII

~ om
80. Which of the following is
hydroc:8rl>On :
1. <;H50H and Zn II.
---
n. C6H5C00Na ~ Na0H/CaO
86.
(3) Only JI & III

~
. ~ + B r CCI
,-==-+A
Major"
(::::1
(4~ l U,& l:

<(
6...:;;_
, 1

~:jor·
rr-1
Ill
(A) ~i
Alp3/Crp3
ru.~and

~ ~
(2)Wil'RII
o:xBr L Br
(1) Only I (4) Il ~ llI
(3) !,IT & Ill
(1) ""*Br (2)
~ - - &,,....l..!D' Br
....._;:;._-.:; (2)~
Br 1
2.~
8 I. .)-..._,.,,Br •
\ -1---=-
The above reaction is call
(1) Dehalogenation
~Br
(3)V-¼
tl 1. :
.....t lr
I '- ~ Br7
I • ~ (4)
~
Br

~
Br Br Br
(3) Dehydrogenation

82. ~
co,K
+ 1-i:o electrolysis•Pruduct 82.
~
co,K
+ H,0 electrolysis•Pruduct 00·: 87, In the given reaction (f-Br 1. ale.KOH
(x) 2 . HBr,R,O, (y) 87.
< f t ~ ~ ,'j 0 - B r 1. ale.KOH
(x) 2 . HBr,R,O,) (y)

~,K The product (y) i's

~ ,K ~~cITT~m<lfG< fql~-
What will be the major product of the above
reaction (l) o:D . AO)
(l) Positional isomer of (x)
(2) Identical of (x)
(3) Chain isomer of (x)
if
1210)
11100 (3)(10 (4)(0
(4) GeoII!etrical isomer of (x)
Which of the following can be used as the halide
(4)(0
(3)00 83. m'!lli'l<lfl~'IIM : component of Friedel Craft reaction.
83. Identify correct order : (I) CH3-CH3 > CH~•CH2> @[ ;: ::,]'° (!) Chlorobenzene

(I) CH -CH3 > CH2 ~CH2 >

3 @ ~~J (II) CH.CH > CH2 •CH2 > CH3-CH3( ~ '1111 E.N.rr" (2) Bromobenzene (2) ..).,)~-v?f'l

(Il) Cffi!CH > C"2•CH2 > C"3-CH3(E.N. of carbon] (Ill) CH3- ~ C H3 > CH,-C■CH > CH•.Q!i
(3) Chloroethene (3t~
(4) lsopropyl chloride (4 ) ->llii;ii~ulf?tc;i ~
(Ill) CH - c .. c-CH 3 > CH 3-Ca CH > CH•CH , ~ 'lmffll] '(
3
[Acidic strength]
f

(36) IKE&T-:14 IIHoCbemf03/~ ICbemf03 IC--4158 I 16-0'.3-2m41 Set-Aj .

89. General combustion reaction for~ ny 89. ~ ~ &l~'fl~<Pl4'1 $ ~ ~ ~ at~fsli41 Pts.:i.~ c1
hydrocarbon may be given by the following ~itll4Ptcfi t14'1qj~Oj aRT ~ '11T ~ t:
chem.icaJ:equation : CxHy + (A) 0 2 ~ x CO2 + (B) H 2 0
C~y + (A) 0 2 ~ x CO 2 + (B) H 2 0 mfi~ct>T~:
Identify correct option :

" (1) A= y
4 -,. (1) A= y
4
~
(2) A= x + y (2) A= x + y

(3) B =y ~Y .
2 2
(4) B ,; x + y (4i B=x+ y
4 4
90. .-CH3 - C = CJ::! 1f~ )A 90. CH3 -C=CH Ti~ >A
- - -What- is (A)
_ Clf:t, / H
(1) Br/C = c, Br

Clf:t, / Br
= c,
Br
(2) Br/C H
H
CH3 , /Br . Br
(3) /c = c'" (3-)~ I! }, Br
H 'Br
CH3 , / H C ,3, ·. H
(4)
H
/c = c, Br
(4 . ..
Br
 ~
[ Tes t Code I I Date : 7
.
4 1 55
-
I
i
ANSWER-KEY OF BioC 11err1TS#03 / 2 (J (SI~T-P~) 16 Fe b . 2024 '
t ,..., (f~t~~- ~~~
Lld;;Jj~s:: ., .r. ~ .;!!;,'.ii,.i •,·• :-.1, i"11.J¢.'AH
1. •t 2. J 3. 2 4. 9. 2 10. ➔
l 5. .:.~ 4 6. 7. 2 8. I
1 1. ' ') 12. 4 1. 3. 4 1 4. .~ 1 9. 1 20. ').
15. f )
✓- 16. 3 17. l .1 8. I
21. ~, 22. ,1 23. 4 24. ...,
1 29. 1 30. -I
' ) 25. ')
,) 26 . J 27. 2 2 8.
,
3 1.. -l 32 . J 33. 1 34. - j. 35. 37. 4 3 8. ~!9 ' J 40. /.
,, 4 36. l ' J
41. ,) 42. ) 4 3. 4 44 . l 45. 4 4 8. '.j 49. '3 5 0.
1 tJ6. 1 47.
r· , ...,
52. 1 53. 2 59. i 60 . ~
,) .1. .
" 54. l 55. J 56. J 57. J 5 8. ';
61. -1 62. J 63 . 4 ,· 69.
~
7 0. /.
64. -J. 65. l 66. CI 67. J 68. /
, )
., l.1 ..., .3 80 .
... .
r-
72 . 73. ·-
) 7,:1..- . .) 75. ) 76 . .)
77 . I 78 . 79 .
8l . -t 82. ,:j 83 . 2 84-. )
85. ! 86. -1 87 . l 88 . '
8 9. -~ 90. ·t
-¾f:• .]~ . r,~m r•L«....:".'.4-J.,;.g "~ t l
,. . ~-r_~tf"f i x}J,,d L" ·-~ ~ ~ ~ ~1i):-~:L
l, " "
.,
t -) . ~- I lU.
r· ••,
c;
• I :.::::. - }
3. .' t"'t. )
'-'· --+ I 7. ·t .:.., . ' ,
11. .:.j 12. ) 13 . 1 14. -+ p-
..) .
--,·
16. -+ 17. 2 18 . l. 9. l 20. ~}
') '
L l. 22 . 1 23.
....,
,) 24 . ....,
) 25 . .--,) 26. ) 27. '2 '.2 8. ~9 . ). 30. ·t
I
...,
~) t. /. 3 2. ) 33 . 3 34 . 4 35. ~) 36. ] 37. 4 3 8. l ~l 9 . J 40 .
,1 ! . l~2. J 43. J 4 -1 . ? 45. I 1 16. ....,
) 47. '2 4 8. '1 9 2 SU .
~,- . 52. :) 53 . _,: S 1. .\ ,-,-
\.) , ) ~ ?, 5-6. l 57. 2 ::; d . ~: 9. l 60 . 'l'
61. 62. ] 63. rI 6 4-. :~ 65 . '.2 66. .?. 67. 2 <.>8 . G9 . >
) 70.
71.
.,
.. 72. L 73 . :3 74 . 1 75. 2 76. ')
- 77. '2 7 8. 79. -~ 80. ....
' '
H 1. '1
82 . 2 83 . 1 84-. 2 85 . 4 86. 1 87. 1 .S 8 . -1
I
~~9 . J 90 . ')
_., -·· - " -·~- -- -- -- -
_._ u • ,, ... .. " ~ ·... 1... ·l'lliidmm.mira,f~ Jliiiniilwmmlififil11ffllWWWamc,_ fffl1i&s&m;t;:,11r,mrnn" ,~