(Ebook) Thermal Engineering: Engineering Thermodynamics and Heat Transfer (De Gruyter Textbook) by Qiu, Lin, Feng, Yanhui ISBN 9783111329697, 3111329690 Ebook All Chapters PDF
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Thermal
Engineering
Yanhui Feng
University of Science and Technology Beijing
30 Xueyuan Road, Haidian District
Beijing 100083, China
[email protected]
ISBN 978-3-11-132969-7
e-ISBN (E-BOOK) 978-3-11-132970-3
e-ISBN (EPUB) 978-3-11-132975-8
© 2024 China Science Publishing & Media Ltd. and Walter de Gruyter GmbH, Berlin/Boston
Cover image: Kannikaistock2499/iStock/Getty Images Plus
Typesetting: Integra Software Services Pvt. Ltd.
Printing and binding: CPI books GmbH, Leck
www.degruyter.com
Preface
To meet the needs of talent training in the new era, this textbook combines the classi-
cal content of engineering thermodynamics and heat transfer with modern research
advances, and expands the scope of knowledge about thermal engineering. We have
selected appropriate exercises, which can cultivate students’ ability to think indepen-
dently and solve problems and meet the needs of professional talent training in depth
and breadth.
The book consists of 13 chapters, which is categorized into two parts. The first
part is composed of eight chapters, that is, Chapters 1–8. Chapter 1, as an introduction,
introduces the classification and definition of different energy forms and outlines the
research content of this book. Chapter 2 elaborates some basic concepts of engineer-
ing thermodynamics, such as thermodynamic system, thermodynamic state, state pa-
rameters, and thermodynamic cycle. Chapter 3 introduces the physical essence and
mathematical expression for the first law of thermodynamics for open system and
closed system and their applications. Chapter 4 presents the properties and the ther-
mal processes of ideal gas. Chapter 5 focuses on the second law of thermodynamics,
the Carnot cycle, and the entropy. Chapter 6 elaborates the thermal process and prop-
erties of water vapor and wet air. Chapter 7 introduces the power cycle of steam and
gas and the piston internal combustion engine cycle. Chapter 8 introduces the refrig-
eration equipment and the efficiency calculation method. The second part focuses on
the heat transfer, which consists of five chapters, that is, Chapters 9–13. Chapter 9 in-
troduces the basic ways of heat transfer and important definitions. Chapter 10 elabo-
rates on the theoretical basis of heat conduction and the relevant knowledge of
steady-state heat conduction. Chapter 11 introduces the basic theory of thermal con-
vection, that is, Newton’s cooling law, and the influencing factors on heat transfer.
Chapter 12 introduces the basic concept of thermal radiation, the basic law of black-
body radiation, the emission characteristics of actual objects, atmospheric greenhouse
effect, and greenhouse effect. Chapter 13 describes the heat transfer process and heat
exchangers, as well as the enhanced and weakened heat transfer approaches.
This book is of particular use to thermodynamic engineers, mechanical engineers,
electrical engineers, and low carbon practitioners worldwide, as well as to academics
and researchers in the fields of thermal management, energy engineering, and mate-
rial science.
This book was financially supported by the textbook construction fund of the Uni-
versity of Science and Technology Beijing and the Academic Affairs Office of Univer-
sity of Science and Technology Beijing.
https://doi.org/10.1515/9783111329703-202
Acknowledgments
As the editor of this book, I am very grateful for the financial support from the plan-
ning textbook construction funds of the University of Science and Technology Beijing
(no. JC2022YB013). The authors of each chapter also provided great help. I would like
to express my sincere gratitude to the authors Yiling Liu, Xin Wang, Yijie Yang, Zhaoyi
Wang, Yuxin Ouyang, Guangpeng Feng, and Zihan Liu. In addition, I also express my
gratitude to the books cited. Most of the contents of this book are collected from vari-
ous related journals and works. Finally, I would like to thank all the readers of this
book. It is your support and affirmation that gave the motivation to publish. Owing to
the relatively short writing time, omissions and even errors in the book are inevitable.
We will listen carefully to readers’ criticisms and correction.
https://doi.org/10.1515/9783111329703-203
Contents
Preface V
Acknowledgments VII
Chapter 1
Introduction 3
1.1 Energy 3
1.2 Energy source 5
1.3 Conversion and utilization of energy 16
1.4 Research contents of fundamentals of thermal engineering 18
Exercises 19
Answers 20
Chapter 2
Basic concepts 21
2.1 Review: introduction 21
2.2 Introduction to the basic concept 21
2.3 Thermodynamic system 21
2.4 Equilibrium state and state parameters 23
2.5 Equation of state and state parameter coordinate diagram 26
2.6 Quasi-static process and reversible process 27
2.7 Work and heat 31
2.8 Summary 35
Exercises 36
Answers 37
Chapter 3
First law of thermodynamics 39
3.1 Review: basic concepts 39
3.2 Introduction to the first law of thermodynamics 39
3.3 Storage energy of thermal system 39
3.4 The essence of the first law of thermodynamics 40
3.5 The expression of the first law of thermodynamics for closed
system 41
3.6 Stable flow energy equation of open system 44
3.7 The application of stable flow energy equation 50
X Contents
3.8 Summary 57
Exercises 60
Answers 61
Chapter 4
Property and process of the ideal gas 63
4.1 Review: first law of thermodynamics 63
4.2 Introduction to property and process of the ideal gas 63
4.3 Ideal gas state equation 63
4.4 Thermal capacity, thermodynamic energy, entropy, and enthalpy of
ideal gases 65
4.5 Thermodynamics, entropy, and enthalpy of ideal gases 70
4.6 Ideal gas mixture 72
4.7 Purpose of thermal process of ideal gas 76
4.8 Summary 91
Exercises 93
Answers 94
Chapter 5
Second law of thermodynamics 99
5.1 Review: the first law of thermodynamics 99
5.2 Introduction to the second law of thermodynamics 99
5.3 The direction of spontaneous process and the expression of the
second law of thermodynamics 99
5.4 Carnot cycle and Carnot theorem 104
5.5 Entropy 111
5.6 Summary 118
Exercises 118
Answers 119
Chapter 6
Water vapor and wet air 121
6.1 Review: gaseous working medium 121
6.2 Review: water vapor 121
6.3 Water vapor generation process 121
6.4 State parameters of water vapor 126
6.5 Basic thermal process of water vapor 131
6.6 The nature of wet air 134
6.7 Summary 136
Exercises 137
Answers 137
Contents XI
Chapter 7
Steam and gas power cycles 141
7.1 Review: power cycle 141
7.2 Steam power plant cycles 141
7.3 Piston internal combustion engine cycle 151
7.4 Ideal cycle of gas turbine plant 153
7.5 Summary 156
Exercises 156
Answers 157
Chapter 8
Refrigeration equipment and cycle 161
8.1 Refrigeration 161
8.2 Air compression refrigeration cycle 161
8.3 Vapor compression refrigeration cycle 164
8.4 Absorption refrigeration cycle 166
8.5 Heat pump 168
Exercises 169
Answers 169
Chapter 9
Basic ways of heat transfer 177
9.1 Thermal conduction 178
9.2 Thermal convection 181
9.3 Thermal radiation 184
9.4 Heat transfer process 186
9.5 Summary 190
Exercises 190
Answers 191
Chapter 10
Thermal conduction 193
10.1 The theoretical basis of thermal conduction 194
10.2 Steady-state heat conduction 203
10.3 Summary 209
Exercises 209
Answers 210
XII Contents
Chapter 11
Convection heat transfer 213
11.1 Convective heat transfer 213
11.2 Newton’s cooling law 214
11.3 Influence factors on convective heat transfer 217
11.4 Summary 220
Exercises 220
Answers 222
Chapter 12
Radiative heat transfer 225
12.1 Basic concepts of thermal radiation 225
12.2 The basic law of blackbody radiation 231
12.3 Emission characteristics of actual objects 234
12.4 Atmospheric greenhouse effect and greenhouse effect 236
Exercises 238
Answers 239
Chapter 13
Heat transfer process and heat exchanger 241
13.1 Heat transfer process 241
13.2 Heat exchanger 247
13.3 Enhancing and weakening of heat transfer 256
13.4 Summary 259
Exercises 259
Answers 259
Appendix Table A1: Saturated and unsaturated vapor (by temperature) 261
Appendix Table A2: Saturated and unsaturated vapor (by pressure) 265
Appendix Table A3: Unsaturated water and superheated water vapor 269
References 277
Index 279
Part 1: Engineering thermodynamics
Chapter 1
Introduction
Energy is the engine of social development because humans need various forms of
energy in their daily lives. With the development of society, the cognition and utiliza-
tion of energy are constantly improving. With the development of science and tech-
nology, the efficiency of energy utilization has been greatly improved, and our society
has been developed into the Industry 4.0 era.
1.1 Energy
The world is made up of matter. All matter is in motion. Energy is a measure of mat-
ter in motion. All matter has energy, which means that the world would be in station-
ary state without energy, and lives would be nowhere to be found. Corresponding to
various forms of motion of matter, there are also various forms of energy, which can
be converted to each other, but the total amount remains the same. Heat energy can
be converted into electricity, which can be further converted into light energy. How-
ever, the total amount of energy is a constant.
Energy exists in numerous forms such as thermal, mechanical, kinetic, potential, elec-
trical, magnetic, and nuclear, and their sum constitutes the total energy (E) of a sys-
tem. There are six main forms of energy that are recognized and utilized nowadays:
1. Thermal energy: This is the sum of the kinetic energy of the thermal motion of
molecules and the potential energy due to the intermolecular interaction. Tem-
perature reflects the intensity of thermal motion of molecules, which means that
it is also the macroscopic reflection of substances’ thermal energy. Thermal en-
ergy is widely used by human being at early times, such as previous drilling
wood for cooking fire and the internal combustion engine now. As shown in
Fig. 1.1(a), ice will melt and become water when it absorbs thermal energy from
human hands.
2. Electric energy: This is the energy related to the movement and the accumula-
tion of electric charge. It is one of the extensively used energy forms. As shown in
Fig. 1.1(b), electric energy can turn into lighting.
3. Mechanical energy: Mechanical energy is the first recognized and utilized en-
ergy, which consists of kinetic energy and potential energy of an object such as
https://doi.org/10.1515/9783111329703-001
4 Chapter 1 Introduction
the water wheel during ancient times and the wind power engine at present. As
shown in Fig. 1.1(c), the ball’s kinetic and potential energy can convert to each
other.
4. Radiant energy: This is the energy emitted by an object in the form of electro-
magnetic waves. Radiant energy is usually converted from other forms of energy.
As shown in Fig. 1.1(d), the Sun’s radiation energy can burn through an aluminum
plate.
5. Nuclear energy: Nuclear energy refers to the energy generated by nuclear reac-
tion. It is of great importance in the future for electricity production. Fig. 1.1(e) is
a picture of a model of nuclear power plant.
6. Chemical energy: Chemical energy refers to the energy released through chemi-
cal reactions. Various fuels, including coal, gas, and oil, are common examples of
the sources of chemical energy. As shown in Fig. 1.1(f), wood contains chemical
energy, which will be released by combustion.
Thermal
Energy
a b c
Fig. 1.1: Six representative energy forms: (a) thermal energy, (b) electric energy, (c) mechanical energy,
(d) radiant energy, (e) nuclear energy, and (f) chemical energy.
Energy source refers to material resources that can provide energy directly or indirectly.
Energy source is what human society relies on for survival and development. There are
various forms of energy resources on the Earth, which are classified according to the
original source, development steps, utilization, and whether they can be recycled.
There are many classification criteria for energy source, generally including the following
ways:
According to the initial source, energy source can be produced by extraterrestrial
bodies, the Earth’s interaction with other celestial bodies and the Earth itself. Energy
produced from extraterrestrial bodies is mainly solar energy. Fossil fuels (coal, oil,
and natural gas) are essentially solar energy fixed by ancient organisms. In addition,
water energy, wind energy, and wave energy are also converted from solar energy.
Energy from the Earth’s interaction with other celestial bodies includes tidal energy.
Energy from the Earth itself includes nuclear energy and geothermal energy.
According to the socioeconomic status, it can be classified into conventional energy
and new energy. Conventional energy is the energy with long exploitation time, mature
technology, and wide usage. New energy is the energy that has not been developed and
utilized on a large scale due to immature technology and short exploitation time.
According to the development steps, it can be classified into primary energy
source and secondary energy source. Primary energy source exists in pristine form in
nature, which can be directly exploited and utilized. Secondary energy source is the
energy directly or indirectly converted from primary energy.
According to whether the energy source can be regenerated or not, it can be clas-
sified into renewable energy source and non-renewable energy source. Renewable en-
ergy source would not be significantly reduced by exploitation and have a natural
resilience. Non-renewable energy source has limited reserves, and its amount de-
creases with the development and utilization. Eventually, it will be exhausted.
6 Chapter 1 Introduction
Hydraulic
energy
Wind energy
Tidal energy
Com
bus
ion
Coal
Fis
Oil
sio
Nuclear fuel
Natural gas
n(
Solar energy
fus
(Chemical energy)
)
With the development of human society, there are five major issues of global concern:
energy, population, food, environment, and resource. Simultaneously, 3E problem is
also proposed. 3E problem refers to energy, environment, and economy. Therefore,
energy construction is one of the strategic emphases worldwide.
According to BP Statistical Yearbook of World Energy 2021 [1], COVID-19 has
exerted a huge impact on energy markets, with primary energy and carbon emissions
decreasing at the highest pace since World War II. Among this, the global primary
energy consumption has dropped by 4.5% in 2020, with oil accounting for three-
quarters roughly, which is the biggest drop since 1945. In spite of this, the demand for
renewable energy like wind energy, solar energy, and hydroelectric power continues
growing, with solar energy making history. On a country-by-country basis, the United
States, India, and Russia saw the biggest drops in energy consumption. China, with
the largest increase (2.1%), was one of the few countries whose energy demand in-
creased in last year. We will elaborate the status of world energy as follows:
1.2 Energy source 7
Carbon emission: Carbon emission due to energy use has dropped by 6.3%, which is
the lowest since 2011. In terms of primary energy, it was also the biggest drop since
the end of World War II.
Fossil oil: The largest regional oil demand reduction occurred in the United States (de-
crease by 2.3 million barrels/day (b/d)), followed by the European Union (decrease by
1.5 million b/d) and India (decrease by 480,000 b/d). In fact, China is the only country
that renders an increase in oil consumption (220,000 b/d). Global oil production has de-
creased by 6.6 million b/d, with OPEC accounting for two-thirds of the decline. Libya (de-
crease by 920,000 b/d) and Saudi Arabia (decrease by 790,000 b/d) had the largest
declines among OPEC members. Moreover, among non-OPEC members, Russia (decrease
by 1 million b/d) and the United States (down 0.6 million b/d) saw the largest declines.
Natural gas: Natural gas consumption has decreased by 81 billion cubic meters (BCM),
or 2.3%. In contrast, the proportion of natural gas in primary energy continued to
rise, reaching a record of 24.7%. Russia (decrease by 33 BCM) and the United States
(down 17 BCM) are the countries with the biggest decline in gas demand in 2020,
while China (22 BCM) and Iran (10 BCM) saw the biggest increase.
Coal: Coal consumption has decreased by 6.2 EJ, or 4.2%, with the United States (decrease
by 2.1 EJ) and India (decrease by 1.1 EJ) decreasing the most. China and Malaysia were two
notable exceptions, with coal consumption increasing by 0.5 EJ and 0.2 EJ, respectively.
Renewable energy, hydropower, and nuclear power: Renewable energy including bio-
fuels but excluding hydropower has increased by 9.7%, slower than the average of the
past decade (13.4% per year), but the increase in energy (2.9 EJ) was similar to that in
2017, 2018, and 2019. Solar power has increased by 1.3 EJ (20%), making a new record,
with wind power accounting for the largest increase in renewable energy (1.5 EJ). The
installed solar capacity has increased by 127 GW. Wind capacity has increased by 111
GW, which is almost twice of the largest increase in previous years. China had the
largest increase in renewable energy (1.0 EJ), followed by the United States (0.4 EJ).
European Union has increased by 0.7 EJ. Hydropower has increased by 1.0%, of which
China has increased the most (0.4 EJ). Nuclear power has decreased by 4.1%, with the
biggest decline in France (−0.4 EJ), the United States (−0.2 EJ), and Japan (−0.2 EJ).
Electric power: Global electricity production has dropped by 0.9%, surpassing the
0.5% decline in 2009, which is the only decrease in records since 1985. The proportion
of renewable energy generation increased from 10.3% to 11.7%. Meanwhile, the pro-
portion of coal generation has dropped by 1.3–35.1%, which is BP’s lowest record.
Important minerals: Global lithium production has dropped by 4.6% due to capacity
reduction in Australia. Cobalt production in the Democratic Republic of Congo de-
clines in 2019, but increases by 2.9% in 2020 as the country’s capacity partially re-
stores. Influenced by substantial growth in Australia and the United States, the
production of rare earth metals has increased by 23.2%.
8 Chapter 1 Introduction
Figure 1.3 illustrates the proportion of primary energy consumption for different re-
gions in the world in 2020, where China’s share is 27.2%.
6.5%
Fig. 1.3: Percentage of global primary energy consumption for different regions in year 2020.
As shown in Fig. 1.4, in 2020, energy producers overcome the negative impact of COVID-
19 and actively promote the resumption of work and production, with a total energy pro-
duction of 4.08 billion tce (tons of standard coal equivalent) and a year-on-year increase
of 2.8%. Among them, raw coal output is 3.9 billion tons, with an increase of 1.4% year
on year. Crude oil production is 19.4769 million tons, with an increase of 1.6% year
on year. Natural gas production is 192.5 billion m3, with an increase of 9.8% year on year.
Power generation is 7,779.06 billion kW · h, with an increase of 3.7% year on year.
As shown in Fig. 1.5, with the recovery of China’s economy and social order, energy
consumption has also showed a gradual recovery trend. In 2020, the total energy con-
sumption was 4.98 billion tce, with an increase of 2.2% over the previous year, among
which coal has increased by 0.6%, crude oil by 3.3%, natural gas by 7.2%, and electricity
by 3.1%.
Besides, energy production and the consumption structure continued to get im-
proved, as shown in Fig. 1.6. Driven by a series of policies and measures such as deep-
ening energy supply-side structural reform and giving priority to the development of
non-fossil energy, China’s clean energy continues to develop rapidly. The proportion
of clean energy has further increased, and the energy structure has been optimized
continuously. In the past decade, the proportion of different types of energy has dif-
ferent trends. The share of raw coal and crude oil production continues to decline,
while the share of natural gas production does not change much. The proportion of
clean electricity production, including hydropower, nuclear power, wind power, and
solar power, has increased significantly. In 2020, clean electricity production accounts
for 28.8% of the total electricity generation.
The energy consumption structure in China is shown in Fig. 1.7. Similarly, the pro-
portion of coal consumption shows a declining trend, accounting for 56.8% of the total
1.2 Energy source 9
45 10
Total energy production (Tons of standard coal)
Growth rate(%)
4
25
2
20
0
15
–2
10
5 –4
0 –6
2011 2012 2013 2014 2015 2016 2017 2018 2019 2020
60 8
Total energy consumption
7
Total energy production
50 growth rate
(Tons of standard coal)
6
Growth rate (%)
40
5
30 4
3
20
2
10
1
0 0
14
12
15
13
20
16
18
19
11
17
20
20
20
20
20
20
20
20
20
20
energy consumption in 2020, but it is still the main energy source in China in short
term. The share of clean energy consumption, including natural gas, hydropower, nu-
clear power, and wind power, in total energy consumption has increased from 13% in
2011 to 24.3% in 2020. In general, coal plays a dominant role in China’s energy struc-
ture, oil and natural gas are highly dependent on the import from foreign countries,
and the proportion of clean energy consumption increases continuously.
10
76.2 75.4 73.5 72.2 69.8 69.6 69.2 68.6 70.2 68.5 67.4 65.8 63.8 62.2 60.6 59 57.7
77.8
40 40
20 20
0 0
2011 2012 2013 2014 2015 2016 2017 2018 2019 2011 2012 2013 2014 2015 2016 2017 2018 2019
(a) (b)
Fig. 1.6: (a) Energy production structure and (b) energy consumption structure in 2011–2019.
1.2 Energy source 11
Clean energy
Fossil oil
Coal 24.3%
56.8%
18.9%
Moreover, the energy efficiency level continues to improve. In recent years, China has
made efforts to save energy and reduce carbon emissions to realize clean and efficient
use of energy. Energy consumption and carbon emissions continue to decline. Energy
imports have maintained rapid growth, especially for oil and gas resources. Renewable
energy has been developed rapidly. The total installed capacity of renewable energy
power generation in China has reached 930 million kW · h, with an increase of about
17.5% year by year and 15.7% compared to year 2011, accounting for 42.4% of the total
installed capacity. Renewable energy generation has reached 220 million kW · h, with
an increase of about 8.4% year by year, which quadruples the current growth rate of
total energy consumption.
There are many challenges and difficulties in China’s energy development. The
first is the low per capita energy resources, which is 62% of the world average level in
coal and 7% in fossil oil and natural gas. The second is that energy security is difficult
to ensure. From 1.6% in 1993 to 72% in 2019, the oil’s dependence on foreign countries
has been increasing, and the crude oil import source is still intensive. Similarly, natu-
ral gas import has increased rapidly, and the dependence on foreign countries has
reached 42.8% in 2019. Besides, the priority to set prices for oil, natural gas, and other
products is still in the control of developed countries. Although the energy import
channel has been gradually improved, there are still some risks. There is still a long
way to go forward for the development of new energy.
In order to keep sustainable development of energy construction in China, Outline of
the national medium- and long-term plan for science and technology development was is-
sued, which claims that we should adhere to the priority of energy saving and energy
consumption reduction, promote the diversification of energy structure, promote clean
and efficient utilization of coal and reduce environmental pollution, strengthen the diges-
tion, absorption, and re-innovation of imported technology of energy equipment, and
improve the technical ability of regional optimal allocation of energy. In a word, for
sustainable development of energy construction, we can find methods from reducing
expenditure, broadening sources, saving energy, and reducing emissions.
12 Chapter 1 Introduction
New energy refers to new kind of energy and new energy technology. New energy
technology is the study hot spot for engineers. Five elements of new energy technol-
ogy are:
– High efficiency: significant improvement in thermal efficiency
– Environment friendly: zero emission, no vibration, low noise technology
– Industrial scale
– Life cycle analysis of the feasibility of energy
– Economic feasibility
Some new energy technologies have been widely used in practice and achieved good
results in energy conservation and emission reduction.
According to the study in 2021 [2], a fuel cell is an energy conversion device essentially
consisting of an anode, electrolyte, and a cathode, which can directly convert chemi-
cal energy into electrical energy with higher efficiency and lower emissions.
Hydrogen is quite abundant in nature. There is no carbon dioxide or air pollu-
tants’ by-product emission but water when hydrogen is electrochemically oxidized in
a fuel cell system, making hydrogen a clean energy. Hence, hydrogen can be used in
many fields, such as transportation, power generation, and militarized equipment [3].
According to the type of electrolyte, fuel cells can be classified as alkaline fuel
cells (AFCs), proton-exchange membrane fuel cells (PEMFCs), phosphoric AFCs, molten
carbonate fuel cells, and solid oxide fuel cells. PEMFC stands out from all types of fuel
cell due to its unique advantages of rapid start-up time, wild range of operating tem-
perature (−40 to 90 °C), and high specific energy. PEMFC has PEM directly affecting its
performance, which has functions of conducting protons, separating fuel oxidizer,
and insulating protons. It provides a channel for the migration and transport of pro-
tons so that protons can pass through the membrane from the anode to the cathode
and form a circuit with the electron transfer of the external circuit to provide the ex-
ternal current. It plays a very important role in the performance of the fuel cell, and
its quality directly affects the service life of the battery [4].
Figure 1.8 depicts the working principle of a fuel cell, which occurs when oxygen
and hydrogen are used to produce water, electrical power, and heat [3, 4]. There are
various designs available for fuel cells, whose difference mainly origins from the differ-
ence in the chemical characteristics of the electrolyte [5]. It is to be noted that they all
operate with the same basic principles and generate electricity and heat through elec-
trochemical reaction.
1.2 Energy source 13
e– e– e–
Electrical Circuit
Cathode
Polymer H+ Anode
H+ Electrolyte
H2 e– H+ e– O2
Membrane
H+
H+
H+
Fuel From Air
Exhaust
According to a study in 2021 [6], the advanced coal to chemicals industry (ACCI) is an
important approach to use coal in a clean, highly efficient, and low carbon manner,
with the purpose to solve China’s coal-dominated energy structures, excessive im-
ported oil and natural gas, and strict environmental constraints. The 12th Five-Year
Plan saw constantly improved technologies and equipment. However, there are sev-
eral challenges as well, such as insufficient strategic understanding, severe external
constraints, and immature technology.
The industrialized technology routes of ACCI include preparing gas and liquid
fuels and chemicals. Generally, it uses coal as the feedstock to synthesize natural gas
and conventional oil-based products, such as gasoline, diesel, olefins, aromatics, and
ethylene glycol, which is conducted via pyrolysis, gasification [7], liquefaction, and
downstream processes, and thus partly replaces oil and natural gas. Compared with
the processes used in the traditional coal chemical industry, ACCI utilizes advanced
conversion technology and thus has long and complex processes. Figure 1.9 illustrates
that the gasification approach starts from coal gasification technology, and then uses
syngas as an intermediate product to produce methanol, Fischer–Tropsch oil (e.g.,
naphtha, gasoline, diesel oil, liquefied petroleum gas, etc.), synthetic natural gas, and
ethylene glycol. Methanol can be further converted into olefins, gasoline, and aro-
matics. The liquefaction approach refers to the direct coal liquefaction process, whose
main products are diesel and jet fuel. The pyrolysis approach is the deep processing
of coal tar produced via medium- and low-temperature pyrolysis.
14 Chapter 1 Introduction
Coal tar
Pyrolysis hydrogenation
Methanol to
gasoline
Sythetic natural
Methanation
gas
Methanol to
Olefins
olefins
Methanol to
Aromatics
aromatics
Ethylene glycol
Gasification Ethylene glycol
synthesis
According to a study in 2017 [7], photovoltaic (PV) cells, which is also known as solar
cells, are made from the same semiconductor materials used in electronics and com-
puter chips. The diversity of PV materials, different potential characteristics, and low-
cost, versatile fabrication technologies are the merits of this energy conversion sys-
tem. Solar cells are essentially composed of large-area PN junctions, which are made
of the combination of a p-type semiconductor and an n-type semiconductor to form a
junction. Asymmetric doping of the p-type and n-type semiconductor creates a poten-
tial barrier to the major charge flow between the regions. This results in a depletion
region where the flow of electrons and holes ceases in equilibrium state, and the
chemical forces of diffusion are exactly balanced by the electrostatic forces of the cre-
ated electric field. The concentration gradient provides a necessary electronic asym-
metrical condition for PV cells.
Figure 1.10 illustrates the operational principle of a solar cell [7]. When light is
illuminated onto a piece of solar cell, photons of different wavelengths hit the semi-
conductor surface. Only a fraction of photons are converted into electrical energy as
only photons with energy higher than energy band gap of the semiconductor can be
absorbed. Photon absorption leads to generation of electron–hole pair (EHP). The ma-
jority carrier concentrations (the total number of electrons in an n-type semiconduc-
1.2 Energy source 15
tor or the total number of holes in a p-type semiconductor) are not affected by contribu-
tions from the additional photons because concentrations that EHPs generate are insig-
nificant compared to the majority carrier concentrations. However, minority carrier
concentrations (the total number of electrons in a p-type semiconductor or the total
number of holes in an n-type semiconductor) are affected significantly and experience
an increase. This change upsets the equilibrium condition between the diffusion force
and electrostatic force. Electrons originated from the p region eventually diffuse into the
depletion region, where the potential energy barrier at the junction is lowered, allowing
current to flow and establish a voltage at the external terminals. Holes created in the
n-doped region travel in the opposite direction to the p-doped side. Solar cells are
based on the movement of charges in the above manner, which will finally produce
electrical current.
Metallic
Solar Radiation
Conducting Strips
(Photon-light) i
Electron Flow
Approx
Glass
Lens
V 0.58 VDC
N-type Silicon
Depletion Layer
–ve Electrons
P-type Silicon
Substrate Base
+ve Holes
ergy sources, including natural gas, biomass, wind, solar, and geothermal energy. In
addition, it can be coupled with other energy forms such as waste heat, pressure, and
gas. Because of the different energy forms, distributed energy systems differ in forms
and structures. It mainly includes cogeneration of heat and power, renewable energy,
energy storage, and fuel cell. The technical block diagram is shown in Fig. 1.11.
Steam turbine
Gas turbine
Cogeneration
Reciprocating internal combustion engine
Stirling engine
Wind energy
Distributed energy Renewable energy
Supply technology Biomass energy
Solar energy
Physical
Thermal
Fuel cells
As shown in Fig. 1.12, wind energy and hydraulic energy can turn into mechanical en-
ergy through mechanical devices, and mechanical energy can turn into electrical energy
through generators. The chemical energy in hydrogen and alcohol can be converted di-
rectly into electricity by fuel cells. Geothermal energy can be used directly for heating.
Solar energy can be converted into biomass energy and thermal energy through photo-
synthesis and solar collectors, respectively. In addition, other energies, such as chemical
energy in coal, oil, and gas and nuclear energy, are usually converted into thermal en-
ergy directly or indirectly through combustion or nuclear reactions.
According to statistics, the energy utilized by thermal energy accounts for more
than 90% of the total energy utilization in China and more than 85% for the other coun-
tries in the world. Therefore, in the process of energy conversion and utilization, ther-
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