Sec: XI-IC-IIT Date : 05-02-2024

Time : 3.0 Hrs. CFTM-08 Max. Marks : 300

JEE MAIN 2022 Model

PHYSICS
+Ve –Ve Total
Section Question Type No. of Qs.
Marks Marks marks

Sec – I
Questions with Single Correct Choice 4 –1 20 80
(Q.N : 1 – 10)

Sec–II Questions with Integer

4 –1 10 20
(Q.N : 11 – 15) Answer Type (+/– Number)

Total 30 100

CHEMISTRY
+Ve –Ve Total
Section Question Type No. of Qs.
Marks Marks marks

Sec – I
Questions with Single Correct Choice 4 –1 20 80
(Q.N : 16 – 25)

Sec–II Questions with Integer

4 –1 10 20
(Q.N : 26 – 30) Answer Type (+/– Number)

Total 30 100

MATHEMATICS
+Ve –Ve No. of Total
Section Question Type
Marks Marks Qs. marks

Sec–I
Questions with Single Correct Choice 4 –1 20 80
(Q.N : 31 – 40)

Sec–II Questions with Integer

4 –1 10 20
(Q.N : 41 – 45) Answer Type (+/– Number)

Total 30 100
Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024

Exam Syllabus
40% : Cyclic process, molar heat capacity, Second law of thermodynamics, Heat engine and
refrigerator
40% : Kinematic Equations of SHM, Variation of velocity and acceleration during SHM, Dynamics
of SHM, Energy of SHM, Physical Pendulum
Physics 20% : Unit and Dimension Complete chapter Motion in straight line Complete chapter Motion in a
plane Complete chapter Laws of Motion Complete chapter Work power and Energy Complete
chapter System of Particles & Rotational Motion Complete Chapter Gravitation Complete Chapter
Mechanical properties of Fluids Complete Chapter Mechanical properties of Solids Complete
Chapter Thermal properties of matter Complete Chapter KTG Complete Chapter
40% : Isomerism: Structural- chain isomerism, positional isomerism, ring chain isomerism, functional
isomerism, metamerism, tautomerism, geometrical isomerism
40% : Alkane: preparation from alkene, alkyne, alkyl halides and carboxylic acids,
Reaction of alkanes: halogenation (excluding steriochemistry) combustion, controlled oxidation,
isomerisation, aromatization & pyrolysis.
20% : Some Basic concept in Chemistry (Complete chapter); Atomic Structure (Complete chapter);
Periodic Properties (Complete chapter); Chemical bonding and molecular structure (Complete
chapter) ; State of Matter (Complete chapter); Thermodynamics (Complete chapter); Equilibrium
CHEMISTRY (Complete chapter); Redox Reactions & (Volumetric Analysis) (Complete chapter); Hydrogen
(Complete chapter); S-block element (Complete chapter); Some p-block elements (Complete
chapter) General Organic Chemistry; Structural representation and classification of organic
compounds; Nomendature: Rules of IUPAC nomenclature of alkanes and Nomenclature of
unsaturated hydrocarbons, functional groups and polyfunctional compounds, Bicycloalkane,
spiroalkane and benzene derivatives, Electronic effects: Inductive effect, Electrometric effect,
Resonance, Hypercongugation, Aromaticity, reaction intermediates: stability of carbocation’s, free
radicals, Stability of carbanion and carbene (excludining benzyne and nitrenes), conformation in
alkane.
40% : Half angle formula, Circumcentre, incentre, Ortho centre, Centroid, Escribed circle, Regular
polygon LIMIT & DERIVATIVES(NCERT LEVEL):limit, determinate and indeterminate form, evaluation
of limit
40% : Important properties of limits, working rule for evaluation of limits of different Forms
Derivatives, derivative of standard functions, Basic rules of differentiation,
MATHEMATICS 20% : Sequence and Series Complete chapter, Trigonometric Equations Complete chapter,
Quadratic Equations Complete Chapter, Theory of Equations Complete Chapter, Binomial Theorem
Complete Chapter, Straight Line Complete chapter, Circles complete chapter, Complex numbers
complete chapter, Permutation and Combination Complete chapter, Parabola Complete Chapter,
Ellipse Complete Chapter, Hyperbola Complete Chapter
PROPERTIES OF TRANGLES: Height and Distance, Properties of triangle, sine rule and cosine rule.
Napier's analogy, projection formulae, Area of triangle in different form.

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
PHYSICS Max. Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A cyclic process ABCD is shown in the following P-V diagram. Which of the following curves
represent the same process? (Process BC and AD is isothermal)

A) B) C) D
2. An ideal heat engine has an efficiency  . The coefficient of performance of the engine when driven
backward will be:
A) 1  1/  B)  / 1    C) 1/   1 D) 1/ 1 
3. Four moles of hydrogen, 2 moles of helium and 1 mole of water vapour form an ideal gas mixture.
What is the molar specific heat at constant pressure of mixture?
16 7 23
A) R B) R C) R D) R
7 16 7
4. A refrigerator consumes an average 35 W power to operate between temperature –10°C to 25°C. If
there is no loss of energy, then how much average heat per second does it transfer?
A) 350 J/s B) 298 J/s C) 263 J/s D) 35 J/s
5. In the given elliptical P-V diagram:

A) the work done is positive B) the change in internal energy is non-zero

2 2
C) the work done =    / 4  P2  P1  V2  V1  D) the work done =   V1  V2     P1  P2 
6. The relation between the internal energy U and adiabatic constant  is: (for adiabatic process)
PV PV  PV 
A) U  B) U  C) U  D) U 
 1  1  PV

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
7. Curve which represents adiabatic and constant internal energy

A) C and D, respectively B) D and C, respectively

C) A and B, respectively D) B and A, respectively
8. A ring shaped tube contains two ideal gases with equal masses and molecular weight M1 = 32 and
M2 = 28. The gases are separated by one fixed partition and another movable stopper S which can
move freely without friction inside the ring. The angle  is

A) 182° B) 170° C) 192° D) 180°

9. The potential energy of a particle executing SHM along the x-axis is given by U  U 0  U 0 cos ax .
What is the period of oscillation?
ma U0 2 m m
A) 2 B) 2 C) D) 2
U0 ma a U0 aU 0
10. A particle executing SHM has velocities u and v and accelerations a and b in two of its positions.
Find the distance between these two positions.
u 2  v2 v2  u 2 v2  u 2 v2  u 2
A) B) C) D)
ab ab ab ab
11. A uniform semicircular ring having mass m and radius r is hanging at one of its ends freely as shown
in the given figure. The ring is slightly disturbed so that it oscillates in its own plane. The time period
of oscillation of the ring is

r r r 2r
A) 2 B) 2 1/ 2
C) 2 1/ 2
D) 2 1/ 2
 1   4   2   4
g 1  2  g 1  2  g 1  2  g 1  
          
12. A particle performs SHM of amplitude A along a straight line. When it is at distance 3 / 2A from
mean position, its kinetic energy gets increased by an amount 1 / 2 m2 A 2 due to an impulsive force.
Then its new amplitude becomes:
5 3
A) A B) A C) 2A D) 5A
2 2

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
13. A particle executes SHM with time period 8 s. Initially, it is at its mean position. The ratio of distance
travelled by it in the 1st second to that in the 2nd second is
A) 2 :1 
B) 1: 2  1  
C) 2  1 : 2  
D) 2  1 :1 
14. The time period of oscillation of a simple pendulum of length L suspended from the roof of a vehicle,
which moves without friction down an inclined plane of inclination  is given by:
L L L L
A) 2 B) 2 C) 2 D) 2
 g cos    g sin   g  g tan  
15. A wire is bent an angle θ. A rod of mass m can slide along the bended wire without friction as shown
in Fig. A soap film is maintained in the frame kept in a vertical position and the rod is in equilibrium
as shown in the figure. If rod is displaced slightly in vertical direction, then the time period of small
oscillation of the rod is

  cos   
A) 2 B) 2 C) 2 D) 2
g g g cos  g tan 
16. A body of mass m is released from a height h to a scale pan hung from a spring. The spring constant
of the spring is k, the mass of the scale pan is negligible and the body does not bounce relative to
the pan, then the amplitude of vibration is
mg 2hk mg
A) 1 B)
k mg k
mg mg 2hk mg mg 2hk
C)  1 D)  1
k k mg k k mg

17. The time period of a satellite, revolving above earth’s surface at a height equal to R will be (Given
g  2 m / s 2 , R = radius of earth)
A) 2R B) 8R C) 32R D) 4R
18. A body of mass m dropped from a height h reaches the ground with a speed of 0.8 gh . The value
of work done by the air-friction is:
A) – 0.68 mgh B) mgh C) 0.64 mgh D) 1.64 mgh
19. ˆ ˆ
A projectile is given by an initial velocity of i  2j m / s , where î is along the ground and ˆj is along
2
the vertical upward. If g = 10 m/s , the equation of its trajectory is:
A) 4y  2x  5x 2 B) 4y  2x  25x 2 C) y  x  5x 2 D) y  2x  5x 2
20. For a gas CP  CV  R in a state P and C P  C V  1.10R in a state Q. TP and TQ are the temperatures
are two different states P and Q, respectively. Then:
A) TP  TQ B) TP  TQ C) TP  0.9TQ D) TP  TQ

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer is
in the decimals, Mark the nearest Integer only. Have to Answer any 5 only out of 10 questions
and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.

21. If P-V diagram of a diatomic gas is plotted, it is a straight line passing through the origin. The molar
heat capacity of the gas in the process is nR where n is an integer. The value of n is:

22. An engine operates by taking a monatomic ideal gas through the cycle shown in the figure. The
percentage efficiency of the engine is close to ________.

23. 1 mole of rigid diatomic gas performs a work of Q/5 when heat Q is supplied to it. The molar heat
capacity of the gas during this transformation is xR/8, The value of x is ...........
[K = universal gas constant]
24. A reversible heat engine converts one-fourth of the input into work. When the temperature of the sink is
reduced by 52 K, its efficiency is doubled. The temperature in Kelvin of the source will be
25. The velocity of a particle executing SHM varies with displacement (x) as 4v 2  50  x 2 . The time
period of oscillation is x/7 s. The value of x is: (take   22 / 7 )
26. A mass 0.9 kg, attached to a horizontal spring, executes SHM with an amplitude A1. When this mass
passes through its mean position, then a smaller mass of 124 g is placed over it and both masses
A 
move together with amplitude A2. If the ratio 1 is , then the value of α will be ____ .
A2  1
27. A particle starts executing simple harmonic motion (SHM) of amplitude 'a' and total energy E. At
any instant, its kinetic energy is 3E/4 then its displacement 'y' is given by (amplitude is 4)
28. A particle of mass 1 kg is hanging from a spring of force constant 100 Nm–1. The mass is pulled
slightly downward and released so that it executes free simple harmonic motion with time period T.
The time when the kinetic energy and potential energy of the system will become equal, is T/n. The
value of n is ________.
29. A soap bubble of radius 3 cm is formed inside the another soap bubble of radius 6 cm. If the internal
pressure of the smaller bubble of radius 3 cm in the above system is equal to the internal pressure of
the another single soap bubble of radius r cm. The value of r is:
30. A car is moving on a plane inclined at 30º to the horizontal with an acceleration of 10 ms–2 parallel
to the plane upward. A bob is suspended by a string from the roof of the car. The angle in degrees
which the string makes with the vertical is______. (Take g = 10 ms–2)

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
CHEMISTRY Max. Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.

31. The compounds C2 H5OC2 H5 and CH3OCH 2CH 2CH3 are

A) Chain isomers B) Geometrical isomers
C) Metamers D) Conformational isomers
32. Which of the following is incorrect relation:

A)

B)

C)

D)
33. Which of the following cannot be written in an isomeric form?
A) CH 3  CH  OH   CH 2  CH 3 B) CH3  CHO
C) CH2  CH  Cl D) Cl  CH 2CH 2  Cl
34. Give compound shows which type of isomerism

A) Chain isomerism B) Positional isomerism

C) Metamerism D) Functional group isomerism
35. Which of the following does not show geometrical isomerism?
A) 1, 2-dichloro-1pentene B) 1, 3-dichloro-2-pentene
C) 1, 1-dichloro-1-pentene D) 1, 4-dichloro-2-pentene
36. What characteristic is the best common to both cis-2-butene and trans-2-butene?
A) Boiling point B) Dipole moment
C) Heat of hydrogenation D) Product of hydrogenation
37. Among the following the compounds having the highest enol content:
A) CH3CHO B) CH3COCH3
C) D) CH3  CO  CH 2  CO2CH3

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
38. Given interconversion takes place in

A) Acidic medium B) Basic medium C) Both D) None

39. What is the correct IUPAC name of the following compound

A) 2E, 4E, 6Z 4-methyl octa-2, 4, 6 triene B) 2E, 4Z, 6Z 5-methyl octa-2, 4, 6 triene
C) 2Z, 4Z, 6Z, 5-methyl octa-2, 4, 6 triene D) 2E, 4Z, 6E 4-methl octa-2, 4, 6 triene
40. Which of the following will show geometrically isomerism.

A) B) C) D)

41. In which of the following pairs first will have higher enol content than second:

A)

B)

C)

D)
42. Which of the following compounds can be best prepared by Wurtz-reaction?
A) Iso-butane B) n-butane C) n-pentane D) Iso-pentane
43. Ethyl iodide and n-propyl iodide are allowed to undergo Wurtz reaction. The alkane which will not
be obtained in this reaction is:
A) butane B) propane C) pentane D) hexane

44.

Above reaction is known as

A) Addition B) Substitution C) Elimination D) Rearrangement

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
45. Ethane is subjected to combustion process. During the combustion the hybrid state of carbon
changes from:
A) sp2 to sp3 B) sp 3 to sp C) sp to sp3 D) sp2 to sp 2
46.

Arrange the compounds I, II and III in decreasing order of their heats of combustion:
A) II > I > III B) I > II > III C) III > II > I D) III > I > II
47. Among the following free radical bromination reactions, select those in which 2° halide is the major
product–

A) P, Q, R, S B) P, R, U C) P, R, S, T D) P, Q, R, S, T
48. Select the chain propagation steps in the free-radical chlorination of methane.

A) 2, 3, 5 B) 1, 3, 6 C) 3, 5 D) 2, 3, 4
49.

Br• will abstract which of the hydrogen most readily?

A) a B) b C) c D) d
50. What should be the value of Kc for the reaction 2SO2 g   O2 g   2 SO3 g  , if the amount are
SO3  48g , SO2  12.8g and O2  9.6 g at equilibrium and the volume of the container is one litre?
A) 64 B) 30 C) 42 D) 8.5

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
SECTION-II
(Integer Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer is in the
decimals. Have to Answer any 5 only out of 10 questions and question will be evaluated according to the
following marking scheme:
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
51. How many benzenoid aromatic isomers shown by C7H7Cl?
52. The number of cis-trans isomer possible for the following compound

53. How many structural isomeric primary amines are possible for the formula C4H11N?
54. Double bond equivalent of cubane is

55.

Double bond equivalent (degree of Unsaturation) of (A) is:

56.

The number of possible monobromo products is (excluding stereoisomers):

57. The 1st, 2nd, and 3rd ionization enthalpies, I1 , I 2 , I3 , of four atoms with atomic number n, n+1, n + 2
and n + 3, where n < 10, are tabulated below. What is the value of n?

58. The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as its
molality. Density of this solution at 298 K is 2.0 g cm-3. The ratio of the molecular weights of the
 MWsolute 
solute and solvent,   , is
 MWsolvent 
59. 8 gm NaOH and 4.9 gm H2SO4 are present in one litre of the solution. What is its pH
60. Find out the sum of the all the Locent of the substituents?

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
MATHEMATICS Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
x
 1  2x 
61. The value of x
im   _____
 1  3x 
2 1
A) e B) C) 0 D)
3 e
f(1  cos x)  f(2)
62. f '(2) = 4 then, lim ..
x 0 tan2 x
1 1
A) -2 B) 2 C) D) 
2 2
 100 
  x k   100
im  
k 1
63. is equal to
x 1 x 1
A) 0 B) 5050 C) 4550 D) –5050
1  cos x dy
64. If y  , then equals -
1  cos x dx
1 1
A) sec2 x / 2 B) cosec2 x / 2 C) sec2 x / 2 D) cosec 2 x / 2
2 2
65. Derivative of sec x with respect to tan x is-
A) sin x B) cos x C) cosec x D) None of these
2
 x  x 1 
66. If xlim   ax  b  = 4, then

 x 1 
A) a = 1, b = 4 B) a = 1, b = –4 C) a = 2, b = –3 D) a = 2, b = 3
2024 2024
x y 
67. If log2024  2024 2024 
  where  is number of positive integral solution of x+y+z+w  400000 ,
x y 
dy
then =
dx
y y 2024y 2024y
A) B)  C) D) 
x x x x
68. For triangle whose vertices are (0, 0), (5, 12) and (16, 12) the coordinates of Incentre are (a,b) then
A) a = 4, b = 7 B) a = 11, b = –4 C) a = 7, b = 9 D) a = 21, b = 37
69. A triangle has the lines y = m1 x and y = m2 x for two of its sides, where m1, m2 are the roots of the
equation x2 + ax – 1 = 0 and the orthocentre of triangle is (  ,  ) then     15 =___
A) 30 B) 27 C) 15 D) 45
70. if (2a, 4a), (2a, 6a) and (2a + 3a , 5a) are the vertices of a three sided regular polygon then its side
is___
A) 3a B) 2a C) a D) 3a
 2x
1 , 0  x  1
71. Let f(x) =  a , if xim f(x) exists, then maximum value of a is :
1
 ax, 1  x  2
A) 1 B) –1 C) 2 D) –2

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
10
 x 3 
72. The term independent of x in the expansion of   2

is-
 3 2x 
3 5 5
A) B) C) D) None of these
2 4 2
73. Differentiation of sin  x  3 w.r.t. x is
2

A) cos  x 2  3 B) 2x cos  x 2  3 C)  x 2  3 cos  x 2  3 D) 2x cos  2x  3

74. If  and  are roots of 2x2 – 3x – 6 = 0, then the equation whose roots are  2 + 2 and  2 + 2 will
be
A) 4x2 + 49 x – 118 = 0 B) 4x2 – 49x – 118 = 0
C) 4x2 + 49 x + 118 = 0 D) 4x2 – 49x + 118 = 0
10x  2x  5 x  1
75. lim =
x 0 ncos x
A) n2n5 B) n2n5 C) 2n2n5 D) 2n2n5
2  3 cos x  sin x
76. lim =
x  / 6 (6x  )2
1
A) 1 B) 1 C) D) 1
6 36 2 9
77. The derivative of log 5 (log 7 (x) at x= e is__
1 1 1 1
A) e
B) C) D)
log(7 ) log(5e ) log(57 ) log(75 )
3 3
 1  cos 4x   x  cos ec x 
78. If lim      tan x   L
x 0
 x2   log 1  x  
d
then
dx
 cos 2  2 x   at x=L is______
A) 2 B)  C) 0 D) 2
dy
79.  
If y  sin  x   ln x 2  e2x then
dx
will be
2 2
A) cos x   2e2x B) cos x   2e2x
x x
2 2
C) cos x   2e2x D) cos x   2e2x
x x
80. Locus of centroid of the triangle whose vertices are (a cos t, a sin t), (b sin t, – b cos t) and (1, 0),
where t is a parameter, is-
A) (3x + 1)2 + (3y)2 = a2 – b2 B) (3x– 1)2 + (3y)2 = a2 – b2
2 2 2 2
C) (3x – 1) + (3y) = a + b D) (3x + 1)2 + (3y)2 = a2 + b2

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Narayana IIT/NEET Academy XI_IC_IIT_ CFTM – 08-05-02-2024
SECTION-II
(Integer Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer is in the
decimals. Have to Answer any 5 only out of 10 questions and question will be evaluated according to the
following marking scheme:
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
81. If in a  ABC, a = 6, b = 3 and cos(A–B) = 4/5, then its area________
 
tan
82. If 3 sin  =5 sin  , then 2 is equal to
 
tan
2
83. Five times the Length of the latus rectum of the parabola 25 [(x–2)2 + (y–3)2] = (3x–4y + 7)2 is_
x2 y2
84. If x + y = 2 touches the ellipse 2 + 2 =1 at a point P, then eccentric angle (in degree) of P is_
a b a b
85. If A(2, –3) and B(–2, 1) are two vertices of a triangle and third vertex moves on the line
2x + 3y = 9 and the locus of the centroid of the triangle is 2x+3y+k=0 then the value of k  1 is__
86. The incentre of the triangle formed by (0, 0), (5, 12), (16, 12) is  ,   , then   
87. Let k be an integer such that the triangle with vertices (k, –3k), (5, k) and (–k, 2) has area 28 sq. units.
Then the orthocentre of this triangle is at the point (, ) then 
d
88. let f(x)=sin(x) and g(x)=tan(x) then ( fog( x ) at x=0 is__
dx
3x2024  8x2023  7 1
89. The value of lim . =
x  x2020  4x2019  8! x 4

2 9 3
90. In a  ABC, A = , b – c = 3 3 cm and area (  ABC) = cm2. Then ‘a’ is
3 2

DETAILS OF PAPER SETTER :

BRANCH
PHYSICS CHEMISTRY MATH
DEL-MV DEL-DWA SURAT

MR MANISH KUMAR Mr. ASHISH GARG MR. ANKIT SHARMA

93197 99204 8850854709

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