arbonate solid alhet To To ConhrcONFImaRtiMATORY

onC0,of
TESTS ) heatthe
ConhimatNO,ionof he
-Ahsence Hno Gi) ( |Ganhmatiosno, of HConhrmation S2
of n ) la)
gos
is
. +2-3 WE.
WEWE.
+ +
Salt HCL.dil. W.E.
+
WE. W.E. WE. a
or or or does the
salt solutionsolution
the issolve NO, SOg,as, H,S ) C,
gas gas gas, swialtth
HSO, Test
ofevolved few a S.E. or
CO,,,
when
few adrops acetic
drops acid
S.E. S.E. S.E.
drops +BaCl, suspension +Sod. +acetic + water-nsoluble
add not
didissolve
l. in
add add
the
salt (reddishacidified(smsrottenelslike turlnimse s dil.
tu rns
the ofH,SO,
FeSO,-Dark
of + of
solution-White nitroprusside aid HC-co, Mgso, dil. water.
in brown), water
H,so.
so salt acidified aidified HCI-Co,
of lead + potassium
turns
and treated is +KI solution-White If eggs), milky
KMnO,-Pink CdCo,-A gas the
NO,. solution+2-3
KMnO, acetate
solution-A evolves salt PeSO, turns-c0,.
brown gas dichromate
with ppt. dissoves
evolves lead
solution--Pink
dilute or which yelsolution-Black
low with
carbonate
indicated. is
solution
acetate
drops black KMn0,
colourofdissolves ppt. with soluble
sulphuric ppt. purple brisk
black--NO,. paper
colour. confirms brisk
starch of
effervescence-confirms
or C0,2- green paper
acid. colour with violet pDt. effervescence.
soluble black-.
solution--Blue evolution colouration.
is -So.
disappears. disappears. indicated.
carbonate.
of
S0,
colouration. on insoluble READY
adding

Conhrmation
(i)
NO, of Conhrmation
()
C0
()
of Conhrmation of
(i ) ()
Conhrmation ofl
() ()
ConfrmationBr
(ii) ()
of
() (1) CONFIRMATORY
ConfhrmationCl
()
TESTS
of (v) () (i) (2) () () H,Conc.
Heat STes0,t REFERENCE
() a
ANO, L, Br,
colourless, vapours gas HCl pinch
W.EMixture
. Salt Salt Ester Oxalic colourChlorine Salt shake-Orange Chlorine Salt pptCI. -. Salt solution.
confirms
solution. To To Colourless
solution + the the g as
+ solution
+
dil. test. aid solution
K,Cr,0,solid salt salt gas
FeSO,
+ CS,
inwater
water To (on turn turns gives theof
conc. H,SO, Salt CH,
test. COO the add solution vapours adding starch CHART
solution + layer. test, conc. + + odourless white salt
H,SO, acetic +Solid colour test. conc. yellow Mn0, starch
warm conc. add with
acid Salt HNO, HNO,+AgN0, Salt + and with paper a paper ppt.
salt solution conc. paper conc.
conc. Cu
+ + and H,SO, solution in
solution
CS,
conc. vinegar gas (soluble FOR
chips. add CaCl,
+
oxalic
+
AgNO,
+ H, S O, conc.
HNO, (CO,)-C,0. pellet) blue yellow H,SO,
H,SO, + layer. obtained H,SO,
2-3
solution--White
Ethyl
aci d dil. +
dil. + smel-CH,CO0. turns -I. or in QUALITATIVE
Heat-Reddish
by
drops solution--Yellow
HCI+1-2
solution-Pale heat and orange-Br.NH,OH)
alcohol, + HCl and
1 the 2-3 addAgN0,solution-A PeSO,
of +1-2 -Red
sides KMnO, acetic heat-Cl,
heat-Fruity drops vapours. solution with
mLof mLof yellow
of
brown ppt. of acid AgNO,-Ci.
the solution-Pink water, CS, ppt. carbon andlead Pass gas
tube-Dark
gas. + ppt. evolves. blackNO,. ANALYSIS
smell.
rubVinegar insoluble
Chlorine the
disulphidepartially whi te
acetate vapours ppt.
brown colour water, in soluble soluble
NH,OH. solution-yellow OF
is smell. shake-Violet chlorine + through
ring. discharged.
NH,OH.
in
NH,OH
in ACID
water, NaOH
RADICALS
() Conhrnation
()
PO
of (i ) Conhrmation )
S0
of Absence
the If noIf
heat--Yellow
Magnesia pptand.
Ammonium Matofch HCI.Barium
dil.
salt gas
match
stick chlornde
does CI,of evolved is
miture stic
test.
not Br,r,
molybdate eact when
Dip Mix
test. the the
test. with NO,, mixture
W.E.
W.E. test. fused salt CH,dil. CO0
or S.E. or H,sO, heated is
neutral mass with S.E.
+ Na,in CO,. asand
conc. dil. + wel C0:. with
S.E. sod.
HNO, nitroprusside Make HCl as conc.
Magnesia
+
BaCl, +
conc. H,SO,.
and its
boil. paste. H,SO,
solution-White
mixture-White Now solution-Purple Fuse test
add for
amm. little a SO
paste ppt. -
ppt.molybdate
and
steaks. oninsoluble PO,.
the
sol. end
in
 oConfmation
mtwater Boil Pb2 of
( (0
to white
confrms PL the Add PPt ofAdA and
bove
above parts White
prt.
second KCO, corfums KIdivide
solution
solution ppt. (PL2)
solution. :
part
solution PL the with
Yelow to
of Yellow one sohution distilled
ppt the part
to
Corfmationiniated
As
of If
(0 the (Conhmation of
Pb Confhrmgtion Cu
of
solution-Blue
(E) Yelowppt.As)
excessadd Pbdil Disove SO%ppt.-(P, KackC) II lt
Ppe.-Group
Yelow
PPt PotTelow
ppt Pot (0 group
magnesia HNO, Amm
MagnesiaYelowPp ppt solution. dil soBution
Cu2. HSo,
HN0,To
is
Aidify Add
obtzined chromate
iodide indicated.
moiybiate acetic erCeSS the isI
+ the NH,OH to and bladk absent,
mixtue Amm. test Chocolate Deep
mizture coloured alcobol one
acidabove of
is test To blue NH, If part ppt
pas
molybdate test yellow To the Add no
test. brown deep
solution OH solutionCu? white If of in
indatessecond th e
White
Yellow the O.S. athe
whiteminimum
H,S
in 0.S. Pot. blue solution
To add above gas
ppt colourAs
is ferrocyanide
ppt. solution ppt.
thsolution
e ppt. add KI ppt. through Make
part
the of sohution
isquantity
K,CrO,. solution. confrms to formed, is the
O.addS. + original formed
conc. with
0.solution
S.
add
of for READY
Confrmation ofA solution
Conhmation (Fe*)ppt.-(Pe)
DissoBve ppt.-(AIP)ofWhite
Reddish
brown sufident
test.
Lake(1) () (1) If of
() group the
ina drops
solution Perform
with sulphocyanide
colouration. To
solution. To given
colourless second one into the I lREFERENCE
time
white is
of
in partbrownppt.
two absent, aftermisture
harcoalcavitycobalt Aprussion
excess. blueWhite ppt. of
parts.
part
medium litmus Blue solution acddification
add
solution. in
ppt. in
Ablue
mass. ofblue dil solid distilled CHART
solution+ + solution addpot. HCland
(calleda ppt., dil. colour NH,C1, with
A water,
HCl+ blood ferrocyanide
suspended nitrate
lake).NHOH add orppt. dividethe 0.5 dil. in
a ml HCL dil, FOR
few test red pot.
conc. Filter. HCl
QUALITATIVE
ConhrmationMn2of Conhrmation of Ni indicated Confrmation
is If Dissolve
the
Confrmation ppt.--(Zn2)
Zn2ofFleshBlackWhite groupgroup IfHNO, or
() Confrmation purple
(i) () () Take () () Co2 ofgreenish the (i)
solution
conc.
2
inPink turning
Perform grey.
ppt. Dissolve
off beadBrown
beadin NH,OH
Perform bead.
Perform and Take
NH,OH. solution. To
solutionBluish . ) ppt.-(Mn)
whitepptToone coloured IV to
reducing
flame. H, S ,
dimethyl Co ppt. second a ppt.-(N is I I the
HCl,
bead in 0.S. aidify O. S . -Ni* Note part
present. is O.S.
is obtained part in cold
boraxbead add fAlesh reducing borax and and boraxbead indicated. of
White absent,
in glyoxime-Bright Add and the
N2 part
two of
or
oxidising NaOH with is of white Boil ANALYSIS
coloured thenmake neutralise a indicated
colour
and solution parts. Co)
and hot.
oxidising
fame. bead dil.
pindh is ppt. of through and
ppt. Label
test and add test acetic black
of solution
soluble cool.
flame ppt.
test alkaline of Co2 add in
with Br, withpotassium the the dl.
in flame with a aid and Ni2* pot. a Add original it
andwater-White
group red few th e add salt. in HCl part
dil, if ferrocyanide
colourless and the pptdrops . by salYellow
t by the If or excess. add and theof NH OF
PPPE HC,
salt adding nitrite
addng the
salt Co2+ NaOH divide OH solution BASIC
boil grey Blue ppt. salt solution tíll
of is is
it (0.S.).
smells RADICALS
(im) () Perform (ii) CO,Boioff
DissoBve Whita If
() (t) () group obtained
Brick
Crimson Light confirms
ammonium thirdthe Awhite If above of To
IfBa?*isK,Cro, To ppt. the
the both one a IV ammonía.
red green part O.S.,
fame
Ca2*. part Bappt. absent,
soution solution.
part (Ba, absent, is group in
flarne-Ca? red of
flame-Ba? test oxlate add
flame-S and
confirns of white Sr, If
of addamm. to pass Il a dil.
with the Sr* thenYellow the ppt.
solutiOn. ppt. Ca) the HC.
confirmed. a above are Sr. to above is
confirmed. part sulphate the ppt. in
O.S. H,S formed,
confirmed. absent,
of solution Confins
second solution, dil add gas.
A
the white acetic solid
then solution. Ifgroup
salt. part a
ppt. add Ba?. add acid NH, C L, ppt. is
to of IM
is
analysis brownish Pass heat. ToTestfNH
ppt.or or obtained present.
NH
Note: the () If
group
() OH
NH,' the Ifsalt Perforn
phosphate
with drops To
of
amnonia the Vis and
basic may
gas add white . (NH),CO,
of0.Sabsent
through sodium harcoal NH,OH
raicals be colouration
obtained is gas ppt.-A solution add
tested evoBves
bydroxide a test
as Nessler's pink
avity andpinch for sohution.
zero in
the NH,fis cobaltnitrate Whitexcess
e
ofMg?-.
group. mass.
beginning reagent. solution ppt-Me NH,4af
present of
2
af A
and test