—

A B B M E A S U R E M E N T & A N A LY T I C S | U S E R G U I D E | I M/A X 4 P H R E V. P

AX416, AX436, AX460, AX466 and AX468

Single and dual input analyzers for pH/Redox (ORP)

Measurement made easy

AX400 series
For more information
pH/Redox (ORP)
analyzers
Further publications are available for free download
from:
www.abb.com/analytical

or by scanning this code:

Search for or click on

Data Sheet DS/AX4PH-EN

AX460, AX466 and AX416
Single and dual input analyzers for pH/Redox (ORP)

User Guide Supplement | PID control IM/AX4PID

AX460
Single input pH/Redox (ORP) analyzer

User Guide Supplement | PROFIBUS® IM/AX4/PBS

AX400 series
Single and dual input analyzers
Electrical safety Health and safety
This equipment complies with the requirements of CEI/IEC To ensure that our products are safe and without risk to health,
61010-1:2001-2 ‘Safety Requirements for Electrical Equipment the following points must be noted:
for Measurement, Control and Laboratory Use’. If the • The relevant sections of these instructions must be read
equipment is used in a manner NOT specified by the Company, carefully before proceeding.
the protection provided by the equipment may be impaired. • Warning labels on containers and packages must be
observed.
• Installation, operation, maintenance and servicing must
Symbols only be carried out by suitably trained personnel and in
accordance with the information given.
One or more of the following symbols may appear on the • Normal safety precautions must be taken to avoid the
equipment labelling: possibility of an accident occurring when operating in
conditions of high pressure and/or temperature.
• Chemicals must be stored away from heat, protected from
Warning – refer to the manual for instructions
temperature extremes and powders kept dry. Normal safe
handling procedures must be used.
• When disposing of chemicals ensure that no two chemicals
Caution – risk of electric shock
are mixed.

Safety advice concerning the use of the equipment described in

Protective earth (ground) terminal
this manual or any relevant hazard data sheets (where
applicable) may be obtained from the Company address on the
back cover, together with servicing and spares information.
Earth (ground) terminal

Direct current supply only

Alternating current supply

Both direct and alternating current supply

The equipment is protected through double

insulation

Information in this manual is intended only to assist our

customers in the efficient operation of our equipment. Use of
this manual for any other purpose is specifically prohibited and
its contents are not to be reproduced in full or part without
prior approval of the Technical Publications Department.
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 Contents

Contents
1 Introduction ..................................................................... 2 6 Installation .................................................................... 44
1.1 System Description .................................................. 2 6.1 Siting Requirements .............................................. 44
1.2 PID Control .............................................................. 2 6.2 Mounting ............................................................... 45
1.3 AX400 Series Analyzer Options ................................ 2 6.2.1 Wall-/Pipe-mount Analyzers ....................... 45
6.2.2 Panel-mount Analyzers ............................... 46
2 Operation ......................................................................... 3 6.3 Connections, General ............................................ 47
6.3.1 Relay Contact Protection
2.1 Powering Up the Analyzer ........................................ 3
and Interference Suppression ..................... 48
2.2 Displays and Controls .............................................. 3
6.3.2 Cable Entry Knockouts,
2.2.1 Membrane Key Functions ............................. 3
Wall-/Pipe-mount Analyzer ......................... 49
2.3 Operating Page ........................................................ 6
6.4 Wall-/Pipe-mount Analyzer Connections ................ 50
2.3.1 Single Input pH ............................................. 6
6.4.1 Access to Terminals ................................... 50
2.3.2 Dual Input pH ............................................... 7
6.4.2 Connections ............................................... 51
2.3.3 Single Input Redox (ORP) ............................. 8
6.5 Panel-mount Analyzer Connections ....................... 52
2.3.4 Dual Input Redox (ORP) ................................ 9
6.5.1 Access to Terminals ................................... 52
2.3.5 Dual Input pH and Redox (ORP) ................. 10
6.5.2 Connections ............................................... 53
2.3.6 Wash Function ............................................ 11
6.6 pH Sensor Systems Connections ......................... 54
6.6.1 Standard ph Systems Connection – 2867,
3 Operator Views .............................................................. 12 AP100, AP300, 7650/60, TB5, Non-ABB ... 54
3.1 View Set Points ...................................................... 12 6.6.2 Differential ph Systems Connections –
3.2 View Outputs ......................................................... 14 Capable of Providing Sensor Diagnostics
3.3 View Hardware ....................................................... 14 (AP200, TBX5) ........................................... 55
3.4 View Software ........................................................ 15
3.5 View Logbook ........................................................ 16 7 Calibration ..................................................................... 56
3.6 View Clock ............................................................. 18
7.1 Equipment Required .............................................. 56
7.2 Preparation ............................................................ 56
4 Setup ............................................................................. 19 7.3 Factory Settings .................................................... 57
4.1 Sensor Calibration .................................................. 19
4.1.1 Set Buffer Type (pH Only) ........................... 19 8 Simple Fault Finding ..................................................... 62
4.1.2 Set Up User Defined Buffers (pH Only) ........ 21
8.1 Error Messages ..................................................... 62
4.1.3 Adjust Offset (Redox/ORP Only) .................. 22
8.2 Calibration Fail Message or No
4.1.4 Automatic, Single- and
Response to pH/Redox Changes .......................... 62
Two-Point Calibration (pH Only) .................. 23
8.3 Checking the Temperature Input ............................ 63
4.1.5 Manual, Single- and
Two-Point Calibration (pH Only) .................. 25
4.1.6 Grab Calibration (pH Only) .......................... 27 9 Specification ................................................................. 64

5 Programming ................................................................. 28 Appendix A – Buffer Solutions ......................................... 67

5.1 Security Code ........................................................ 28
5.2 Configure Display ................................................... 29
5.3 Configure Sensors ................................................. 30
5.4 Configure Diagnostics ............................................ 33
5.5 Configure Alarms ................................................... 34
5.5.1 Wash Cycle Configuration
(Applicable Only to Alarm 3) ........................ 36
5.6 Configure Outputs .................................................. 38
5.7 Configure Clock ..................................................... 40
5.8 Configure Security .................................................. 41
5.9 Configure Logbook ................................................ 41
5.10 Test Outputs and Maintenance .............................. 42

IM/AX4PH Rev. P 1
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 1 Introduction

1 Introduction All models incorporate a wash facility for system cleaning; the
Alarm 3 relay can be configured to control the wash system
1.1 System Description either automatically or manually. The relay can be programmed
The AX460 single input and AX466 dual input pH/Redox (ORP) to deliver either a continuous or pulsed signal to control an
analyzers and associated electrode systems have been external power supply to a solenoid or pump and the frequency,
designed for continuous monitoring and control of pH and duration and recovery time for the wash cycle are also
Redox (ORP). The electrode system can be standardized to the programmable. During a wash cycle, the analog output value is
analyzer using the built-in calibration facility and a single point held in its pre-cycle condition.
buffering facility provides easy re-calibration after initial Analyzer operation and programming are performed using five
standardization. tactile membrane keys on the front panel. Programmed
The analyzer is available in wall-/pipe-mount or panel-mount functions are protected from unauthorized alteration by a
versions with either one or two programmable, pH or Redox four-digit security code.
(ORP) input channels, each with its own associated temperature
input channel. When making temperature compensated 1.2 PID Control
measurements, the sample temperature is sensed by a The AX460 single input pH analyzer incorporates Proportional
resistance thermometer (Pt100, Pt1000 or Balco 3K) mounted Integral Derivative (PID) control as standard. Refer to the
in the electrode system. PID Control Supplementary User Guide, IM/AX4PID for a full
description and instructions on how to configure and operate
The analyzer can be configured for, and connected to, either a PID control.
standard pH input (single, high impedance input >1013 ) or
differential pH input (dual, high impedance inputs, both >1013 ). 1.3 AX400 Series Analyzer Options
Differential pH input is designed for use with pH electrode Table 1.1 shows the range of configurations that are possible for
systems that incorporate a solution earth (ground) rod. The the AX400 Series analyzers. The analyzer detects the type of
measuring electrode and reference electrode signals are input board fitted for each input automatically and displays only
measured separately using two, high impedance amplifiers and the operating and programming frames applicable to that input
compared with the solution earth (ground) potential. The board type. If no input board is fitted for a second input
difference between the results is the value used for the pH (Sensor B), Sensor B frames are not displayed.
measurement.

Model Analyzer Description Sensor A Sensor B

AX410 Single Input 2-Electrode Conductivity (0 to 10,000 µS/cm) 2-Electrode Conductivity –

AX411 Dual Input 2-Electrode Conductivity (0 to 10,000 µS/cm) 2-Electrode Conductivity 2-Electrode Conductivity

AX413 Dual Input 2-Electrode Conductivity and 4-Electrode Conductivity 2-Electrode Conductivity 4-Electrode Conductivity

AX416 Dual Input 2-Electrode Conductivity and pH/Redox (ORP) 2-Electrode Conductivity pH/Redox (ORP)

AX418 Dual Input 2-Electrode Conductivity and Dissolved Oxygen 2-Electrode Conductivity Dissolved Oxygen

AX430 Single Input 4-Electrode Conductivity (0 to 2,000 mS/cm) 4-Electrode Conductivity –

AX433 Dual Input 4-Electrode Conductivity (0 to 2,000 mS/cm) 4-Electrode Conductivity 4-Electrode Conductivity

AX436 Dual Input 4-Electrode Conductivity and pH/Redox (ORP) 4-Electrode Conductivity pH/Redox (ORP)

AX438 Dual Input 4-Electrode Conductivity and Dissolved Oxygen 4-Electrode Conductivity Dissolved Oxygen

AX450 Single Input 2-Electrode Conductivity (USP) 2-Electrode Conductivity –

AX455 Dual Input 2-Electrode Conductivity (USP) 2-Electrode Conductivity 2-Electrode Conductivity

AX456 Dual Input 2-Electrode Conductivity (USP) and pH/Redox (ORP) 2-Electrode Conductivity pH/Redox (ORP)

AX460 Single Input pH/Redox (ORP) pH/Redox (ORP) –

AX466 Dual Input pH/Redox (ORP) pH/Redox (ORP) pH/Redox (ORP)

AX468 Dual Input pH/Redox (ORP) and Dissolved Oxygen pH/Redox (ORP) Dissolved Oxygen

AX480 Single Input Dissolved Oxygen Dissolved Oxygen –

AX488 Dual Input Dissolved Oxygen Dissolved Oxygen Dissolved Oxygen

Table 1.1 AX400 Series Analyzer Options

2 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2 Operation 2.2.1 Membrane Key Functions

2.1 Powering Up the Analyzer Menu 1

Warning. Ensure all connections are made correctly, Advance to
especially to the earth stud – see Section 6.3, page 47. next menu

Menu 2
1. Ensure the input sensors are connected correctly.
A – Moving Between Menus
2. Switch on the power supply to the analyzer. A start-up
screen is displayed while internal checks are performed,
then the Operating Page (Section 2.3) is displayed as the Advance to
pH or Redox (ORP) monitoring operation starts. next page

2.2 Displays and Controls Page 1 Page 2

The display comprises two rows of 41/2 digit, 7-segment digital Frame 1 or Frame 1
displays, that show the actual values of the measured Frame 2 Frame 2
parameters and alarm set points, and a 6-character dot matrix Frame 3 Frame 3
For majority
display showing the associated units. The lower display line is a Frame 4
of Frames
16-character dot matrix display showing operating and
programming information. B – Advancing to Next Page

Page X
Display Frame 1
Lines
Advance to
0.00 pH Units
next Frame
Lower
Display Line 0.00pH Frame 2
Frame 3
Monitoring pH
Frame 4
Alarm C – Moving Between Frames
LEDs

Parameter Value Adjust

Membrane Keys
Menu Key
New value is
Sidescroll Key stored automatically
Downscroll Key
Up Key D – Adjusting and Storing a Parameter Value
Down Key

Parameter X
Fig. 2.1 Location of Controls and Displays Y Select
Z

New value is
automatically stored

E – Selecting and Storing a Parameter Choice

Fig. 2.2 Membrane Key Functions

IM/AX4PH Rev. P 3
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

Use the Menu Key

Use the Sidescroll Key to scroll through the Pages within each Menu
to scroll through
the Menus

Section 2.3, Page 6 Section 3.1, Page 12 Section 3.2, Page 14 Section 3.3, Page 14 Section 3.4, Page 15 Section 3.5, Page 16 Section 3.6, Page 18
OPERATING PAGE VIEW SETPOINTS VIEW OUTPUTS VIEW HARDWARE VIEW SOFTWARE VIEW LOGBOOK VIEW CLOCK
A1: Setpoint Analog Output 1 Sensor A Module AX400/2000 Issue Alarms Date 01:01:03
A2: Setpoint Analog Output 2 Sensor B Module Errors Time 12:00
Use the Downscroll
Key to scroll through A3: Setpoint Analog Output 3 Option Board Power
the Frames Cals
A4: Setpoint Analog Output 4
within each Page
A5: Setpoint

Section 4.1, Page 19

SENSOR CAL. Cal. User Code Set Auto Buffers Sensor Cal. A Sensor Cal. B
Buffer Type A: Buffer Method B: Buffer Method

Set Buffer 1 A: Immerse Buf.1 B: Immerse Buf.1

Set Buffer 2 #### 100% #### #### 100% ####

A: Enter Point 1 A: Cal. Buffer 1 B: Cal. Buffer 1

A: Enter Point 2 A: Immerse Buf.2 B: Immerse Buf.2

A: Enter Point 3 #### 100% #### #### 100% ####
A: Enter Point 4 A: Cal. Buffer 2 B: Cal. Buffer 2
A: Enter Point 5 A: Calibration B: Calibration
B: Enter Point 1 A: Slope & Check B: Slope & Check
B: Enter Point 2
B: Enter Point 3
Note. Sensor calibration parameters shown above
B: Enter Point 4 are for Automatic, 2-point calibration only. For other
Section 5.1, Page 28 B: Enter Point 5 calibration options, refer to Section 4.1.
SECURITY CODE

Section 5.2, Page 29

CONFIG. DISPLAY Set Language Set Temp. Units Set Backlight
English Temp. Units LED Backlight

Section 5.3, Page 30

CONFIG.SENSORS Config. Sensor A Config. Sensor B

A: Probe Type B: Probe Type

A: Diff. Input B: Diff. Input

A: Electrode B: Electrode
A: Temp. Comp B: Temp. Comp
A: Temp. Sensor B: Temp. Sensor

* A:
A: Enable Cals
Preset Temp.
B: Enable Cals
B: Preset Temp.
*
A: Sample Comp. B: Sample Comp.
A: Sample Coeff. B: Sample Coeff.
A: Set Min Slope B: Set Min Slope

* Displayed only if Probe Type is set to Redox or ORP

Section 5.4, Page 33 Key
CONFIG.DIAGS Config. Sensor A Config. Sensor B
Available only if option board fitted and
A: pH Glass B: pH Glass analog features enabled – see Section 7.3
A: Ref. Checking B: Ref. Checking
To CONFIG. ALARMS A: Ref. Alarm B: Ref. Alarm Dual input analyzer only
(see Fig. 2.4)

Fig. 2.3 Overall Programming Chart

4 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

Use the Menu Key

to scroll through Use the Sidescroll Key to scroll through the Pages within each Menu
the Menus

Section 5.5, Page 34

CONFIG.ALARMS Config. Alarm 1 Config. Alarm 2 Config. Alarm 3 Config. Alarm 4 Config. Alarm 5
A1: Type A2: Type A3: Type A4: Type A5: Type

*
A1: Assign A2: Assign A3: Assign A4: Assign A5: Assign
Use the Downscroll
Key to scroll through A1: Failsafe A2: Failsafe A3: Failsafe Wash Mode A4: Failsafe A5: Failsafe
the Frames A1: Action A2: Action A3: Action Wash Frequency A4: Action A5: Action
within each Page
A1: Setpoint A2: Setpoint A3: Setpoint Wash Duration A4: Setpoint A5: Setpoint
A1: Hysteresis A2: Hysteresis A3: Hysteresis Recovery Period A4: Hysteresis A5: Hysteresis

A1: Delay A2: Delay A3: Delay A4: Delay A5: Delay
* toApplicable
Alarm 3
only

Section 5.6, Page 38

CONFIG.OUTPUTS Config. Output 1 Config. Output 2 Config. Output 3 Config. Output 4
AO1: Assign AO2: Assign AO3: Assign AO4: Assign
AO1: Range AO2: Range AO3: Range AO4: Range
AO1: Span Value AO2: Span Value AO3: Span Value AO4: Span Value

AO1: Zero Value AO2: Zero Value AO3: Zero Value AO4: Zero Value
AO1: Default AO2: Default AO3: Default AO4: Default

AO1: Default Val AO2: Default Val AO3: Default Val AO4: Default Val

Section 5.7, Page 40

CONFIG.CLOCK Set Clock?
Format dd/mm/yy
Date 01:01:02

Time 12:00
Press To Set Press To Abort

Displayed only if option board fitted and serial communications feature enabled (Section 7.3) –
CONFIG.SERIAL
see Supplementary Manual Profibus® Datalink Description (IM/AX4/PBS)

CONFIG. CONTROL Single Input Analyzer Only — see Supplementary Manual PID Control (IM/AX4PID)

Section 5.8, Page 41

CONFIG.SECURITY Alter Sec.Code
Alter Cal.Code
Key
Available only if option board fitted and
Section 5.9, Page 41
analog features enabled – see Section 7.3
CONFIG.LOGBOOK Logbook

Section 5.10, Page 42

TEST/MAINTENANCE Test Outputs Maintenance Load/Save Config

Test Output 1 Hold Outputs Factory Config.

Test Output 2 Automatic Time User Config.

Test Output 3 Press To Set Press To Abort

Test Output 4
To FACTORY SETTINGS
(see Section 7.3, Page 57)

Fig. 2.4 Overall Programming Chart (Continued)

IM/AX4PH Rev. P 5
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2.3 Operating Page

2.3.1 Single Input pH

Measured Values
7.00 pH pH.

24.4 Deg.C Temperature.

Monitoring pH

Measured Millivolts
Millivolts.

404 mV
Millivolts

% Slope and pH Check Value

100.0 % % slope value.

7.00 pH A value between the programmed minimum % slope value (see Set Min Slope – see
Section 5.3, page 30) and 105% is displayed. If the value is outside these limits, check
A: Slope & Check the electrode system.
pH check value (zero point).
Displayed as an additional indication of pH electrode system condition; 7 pH is the
optimum value for glass electrodes and 0 ph for Antimony electrodes.

VIEW SETPOINTS See Section 3.1, page 12.

SENSOR CAL. See Section 4.1, page 19.
Wash Function A3: Type set to Wash (Section 5.5) – see Section 2.3.6, page 11.
Monitoring pH A3: Type not set to Wash (Section 5.5) – return to top of page.

6 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2.3.2 Dual Input pH

Measured pH
7.00 pH Sensor A.

7.00 pH Sensor B.

Monitoring pH

Measured Temperature
25.6 Deg.C
Sensor A.

24.4 Deg.C Sensor B.

Temperature

404 mV
Measured Millivolts
Sensor A.
-256 mV Sensor B.
Millivolts

% Slope and pH Check Value – Sensor A

100.0 % % slope value.

7.00 pH A value between the programmed minimum % slope value (see Set Min Slope – see
Section 5.3, page 30) and 105 % is displayed. If the value is outside these limits, check
A: Slope & Check the electrode system.
pH check value (zero point).
Displayed as an additional indication of pH electrode system condition; 7 ph being the
optimum value for glass electrodes and 0 ph for Antimony electrodes.

100.0 %
% Slope and pH Check Value – Sensor B
% slope value.
7.00 pH pH check value (zero point).
See Sensor A above.

B: Slope & Check

VIEW SETPOINTS See Section 3.1, page 12.

SENSOR CAL. See Section 4.1, page 19.
Wash Function A3: Type set to Wash (Section 5.5) – see Section 2.3.6, page 11.
Monitoring pH A3: Type not set to Wash (Section 5.5) – return to top of page.

IM/AX4PH Rev. P 7
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2.3.3 Single Input Redox (ORP)

Measured Values
404mV Millivolts.

25.6Deg.C Temperature.

Redox (ORP)

Offset – Sensor A
Displays the offset value for the sensor set in A: Adjust Offset – see Section 4.1.3,

0mV page 22.

A: mV Offset

VIEW SETPOINTS See Section 3.1, page 12.

SENSOR CAL. See Section 4.1, page 19.
Wash Function A3: Type set to Wash (Section 5.5) – see Section 2.3.6, page 11.
Redox (ORP) A3: Type not set to Wash (Section 5.5) – return to top of page.

8 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2.3.4 Dual Input Redox (ORP)

Measured Millivolts
404mV Sensor A.

-256mV Sensor B.
Note. If Probe Type for both Sensor A and Sensor B is set to ORP (Section 5.3), the
Dual Redox
lower display line shows Dual ORP.

Sample Temperature

25.6Deg.C Sensor A.

24.4Deg.C Sensor B.
Note. The measured temperature is displayed only if Temp. Sensor is not set to None –
Temperature see Section 5.3, page 30.

Offset – Sensor A
Displays the offset value for Sensor A set in A: Adjust Offset – see Section 4.1.3,
0mV page 22.

A: mV Offset

Offset – Sensor B
Displays the offset value for Sensor B set in B: Adjust Offset – see Section 4.1.3,

0mV page 22.

B: mV Offset

VIEW SETPOINTS See Section 3.1, page 12.

SENSOR CAL. See Section 4.1, page 19.
Wash Function A3: Type set to Wash (Section 5.5) – see Section 2.3.6, page 11.
Dual Redox A3: Type not set to Wash (Section 5.5) – return to top of page.

IM/AX4PH Rev. P 9
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2.3.5 Dual Input pH and Redox (ORP)

Measured pH and Millivolts
7.00 pH Sensor A.

-256 mV Sensor B.
Note. The Probe Type for Sensors A and B can be set to any combination of pH, Redox
pH/Redox (ORP)
or ORP – see Section 5.3, page 30. The display indications change depending on
Probe Type settings, e.g. if Sensor A is set to Redox and Sensor B to pH, the lower
display shows Redox (ORP)/pH.

Measured Temperature
25.6 Deg.C Sensor A.

24.4 Deg.C Sensor B.

Temperature Note. The measured temperature is displayed only if Temp. Sensor is not set to None –
see Section 5.3, page 30.

404 mV
Measured Millivolts
Sensor A.
-256 mV Sensor B.
Millivolts

Offset – Sensor B
Displays the offset value for Sensor B set in B: Adjust Offset – see Section 4.1.3,
page 22.
0 mV
B: mV Offset

100.0 %
% Slope and pH Check Value – Sensor A
% slope value.
7.00 pH A value between the programmed minimum % slope value (see Set Min Slope –
A: Slope & Check Section 5.3) and 105 % is displayed. If the value is outside these limits, check the
electrode system.
pH check value (zero value).
Displayed as an additional indication of pH electrode system condition; 7 ph is the
optimum value for glass electrodes and 0 ph for Antimony electrodes.
VIEW SETPOINTS See Section 3.1, page 12.
SENSOR CAL. See Section 4.1, page 19.
Wash Function A3: Type set to Wash (Section 5.5) – see Section 2.3.6, page 11.
pH/Redox (ORP) A3: Type not set to Wash (Section 5.5) – return to top of page.

10 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 2 Operation

2.3.6 Wash Function

Note. The Wash function is available only if A3: Type is set to Wash – see Section 5.5, page 34.

Wash Function
Manual
On Off – Wash function off. Lower display line of Operating Page shows WASH
----- Off
On
INHIBITED.
– Wash function controlled automatically. Lower display line of Operating
Wash Function Page shows WASH IN PROGRESS.
Manual – Enables wash function to be initiated manually – see below.
Note. Set Wash Function to Off before removing the sensor from the process.
VIEW SETPOINTS See Section 3.1, page 12.
Probe Type set to pH (for either sensor if dual input analyzer) – see Section 5.3,
page 30.
SENSOR CAL. See Section 4.1, page 19.
Probe Type set to Redox or ORP (for both sensors in any combination if dual input
analyzer) – see Section 5.3, page 30.
SENSOR CAL. Enable Cals set to Yes (Section 5.3) – see Section 4.1, page 19.
Security Code Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

Press To Wash Wash Function set to Manual – see below.

Monitoring pH

Redox (ORP)
Wash Function not set to Manual. The display returns to the top of the Operating
Dual Redox
Page.
pH/Redox (ORP)

Press to Wash (Manual Wash only)

Press to Wash and Press to Abort are shown alternately on the lower

-----
display line.

Press To Wash
Press To Abort

WASH IN PROGRESS Press the key to initiate the wash cycle. The display returns to the top of the
Operating Page and the lower display line shows WASH IN PROGRESS until the wash
cycle is completed. The Wash Function selection reverts to the one that was set before
Manual was selected.
Monitoring pH

Redox (ORP) Press the key to abort the wash cycle. The display returns to the top of the
Dual Redox Operating Page.
pH/Redox (ORP)

IM/AX4PH Rev. P 11
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

3 Operator Views
3.1 View Set Points

Note. The parameter names and units of measurement displayed in the View Set Points page depend on the Probe Type settings
for Sensors A and B – see Section 5.3, page 30. Those shown below are given as examples only.

View Set Points

This page shows alarm set points. The value of each of the set points is shown,

-----
together with the name of the parameter it is assigned to.
Alarm assignments, set point values and relay/LED actions are programmable – see
VIEW SETPOINTS Section 5.4, page 33.

Sensor A (pH), Alarm 1 Set Point

Sen.A

8.30pH
A1: Setpoint

Sensor A (Temperature), Alarm 2 Set Point

Temp.A

35.0Deg.C
A2: Setpoint

Sensor B (pH), Alarm 3 Set Point – Dual input analyzers only

Sen.B

6.80pH
A3: Setpoint

Sensor B (Temperature), Alarm 4 Set Point – Dual input analyzers only

Temp.B
Note. Alarm 4 available only if option board fitted and analog features enabled – see
55.0Deg.C Section 7.3, page 57.

A4: Setpoint

Alarm 5 Set Point

Note. Alarm 5 available only if option board fitted and analog features enabled – see

-----Off Section 7.3, page 57.

A5: Setpoint

VIEW SETPOINTS
VIEW OUTPUTS See Section 3.2, page 14.

SENSOR CAL.

Security Code
See Note on next page.
CONFIG. DISPLAY

12 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

Note. The menu displayed when pressing the key from the Operator View pages depends on analyzer configuration, i.e.:
Single Input Analyzers
SENSOR CAL. Probe Type set to pH
or
Probe Type set to Redox or ORP and Enable Cals set to Yes (Section 5.3) – see Section 4.1, page 19.
Security Code Probe Type set to Redox or ORP and Enable Cals set to No (Section 5.3) and Alter Sec. Code not set to zero
(Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Probe Type set to Redox or ORP and Enable Cals set to No (Section 5.3) and Alter Sec. Code set to zero
(Section 5.8) – see Section 5.2, page 29.
Dual Input Analyzers
SENSOR CAL. Probe Type for either sensor set to pH
or
Probe Type for both sensors set to Redox or ORP and Enable Cals for either sensor set to Yes (Section 5.3) –
see Section 4.1, page 19.
Security Code Probe Type for both sensors set to Redox or ORP and Enable Cals for both sensors set to No (Section 5.3) and
Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Probe Type for both sensors set to Redox or ORP and Enable Cals for both sensors set to No (Section 5.3) and
Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

IM/AX4PH Rev. P 13
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

3.2 View Outputs

Theoretical Analog Output
There are up to four analog outputs, each showing information for one sensor.

----- Note. Analog outputs 3 and 4 available only if option board fitted and analog features
enabled – see Section 7.3, page 57.
VIEW OUTPUTS

12.00mA Live current output value being retransmitted.

50.0% Current output shown as a percentage of full scale for the output range set in CONFIG.
OUPUTS – see Section 5.6, page 38.
Analog Output 1

VIEW HARDWARE See Section 3.3, below.

SENSOR CAL.

Security Code
See Note on Page 13.
CONFIG. DISPLAY

Analog Output 2
Advance to analog output 2 (and outputs 3 and 4 if option board fitted and analog
features enabled – see Section 7.3, page 57).

3.3 View Hardware

-----
VIEW HARDWARE

Sensor A Module
Shows the type of input board fitted to the analyzer for the Sensor A input.

----- pH
Sensor A Module

Sensor B Module – Dual input analyzers only

Shows the type of input board fitted to the analyzer for the Sensor B input.

----- pH
Sensor B Module

Option Board
Analog
Note. Displayed only if the option board is fitted.
----- Pb Dp Displays the optional features enabled in the Factory Settings page – see Section 7.3,
Option Board page 57.

VIEW HARDWARE VIEW SOFTWARE See Section 3.4, page 15.

SENSOR CAL.

Security Code
See Note on Page 13.
CONFIG. DISPLAY

14 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

3.4 View Software

-----
VIEW SOFTWARE

Issue
Shows the version number of the operating software.
1.00
AX400/2000 Issue

VIEW SOFTWARE VIEW LOGBOOK Option board fitted and analog features enabled (Section 7.3) and Logbook set to On
(Section 5.9) – see Section 3.5, page 16.

Monitoring pH

Redox (ORP)

Dual Redox
Operating Page (option board not fitted) – see Section 2.3, page 6.
pH/Redox (ORP)

SENSOR CAL.

Security Code See Note on Page 13.

CONFIG. DISPLAY

IM/AX4PH Rev. P 15
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

3.5 View Logbook

Note. The View Logbook function is available only if the option board is fitted and analog features enabled (see Section 7.3,
page 57) and Logbook is set to On (see Section 5.9, page 41).

The logbook stores data entries for alarm events, sensor errors, power failures and pH
calibration information.

-----
VIEW LOGBOOK

Cals View Logbook

Power
Errors Use the and keys to access the Alarms logbook.

----- Alarms Note. If no entries are stored in the Alarms logbook, the display shows No More
Entries.
VIEW LOGBOOK

1 A1
Alarms
The Alarms logbook contains up to 10 entries (entry 1 is the most recent), each
-----On comprising an alarm number, alarm state (On or Off) and the date/time of the
occurrence.
11:09:02 12:34

VIEW CLOCK Option board fitted and analog features enabled (Section 7.3) – see Section 3.6,
page 18.

SENSOR CAL.

Security Code
See Note on Page 13.
CONFIG. DISPLAY

2 A1 Advance to entries 2 to 10.

Note. If no more entries are stored, the display shows No More Entries.

Alarms View Logbook

Cals
Power Use the and keys to access the Errors logbook.
----- Errors Note. If no entries are stored in the Errors logbook, the display shows No More Entries.
VIEW LOGBOOK

1 Sen.A Errors
The Errors logbook contains up to 5 entries (entry 1 is the most recent), each
-----Pt100 comprising the sensor letter, error number and the date/time of the occurrence.
11:09:02 12:34

VIEW CLOCK Option board fitted and analog features enabled (Section 7.3) – see Section 3.6,
page 18.
SENSOR CAL.

Security Code
See Note on Page 13.
CONFIG. DISPLAY

2 Sen.A Advance to entries 2 to 5.

Note. If no more entries are stored, the display shows No More Entries.

16 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

View Logbook
Errors
Alarms Use the and keys to access the Power logbook.
Cals
----- Power Note. If no entries are stored in the Power logbook, the display shows No More Entries.
VIEW LOGBOOK

Power
1 The Power logbook contains up to 2 entries (entry 1 is the most recent), each

-----Off comprising the power state (On or Off) and the date/time of the occurrence.

11:09:02 12:34

VIEW CLOCK
Option board fitted and analog features enabled (Section 7.3) – see Section 3.6,
page 18.
SENSOR CAL.

Security Code
See Note on Page 13.
CONFIG. DISPLAY

2 Advance to entry 2.
Note. If no more entries are stored, the display shows No More Entries.

Power View Logbook

Errors Use the and keys to access the Cals logbook.
Alarms
----- Cals Note. If no entries are stored in the Cals logbook, the display shows No More Entries.
VIEW LOGBOOK

1 Sen.A
Calibration
The Cals logbook contains up to 5 entries (entry 1 is the most recent), each comprising
-----Passed 2 frames. Frame 1 contains the entry number, sensor letter and the calibration pass/fail
indication.
Calibration
Frame 2 contains the % slope value, the pH check value and the date/time of the

100.0 %
occurrence.

7.00 pH
11:09:02 12:34

VIEW CLOCK Option board fitted and analog features enabled (Section 7.3) – see Section 3.6,
page 18.

SENSOR CAL.

Security Code See Note on Page 13.

CONFIG. DISPLAY

2 Sen.A Advance to entries 2 to 5.

Note. If no more entries are stored, the display shows No More Entries.

IM/AX4PH Rev. P 17
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 3 Operator Views

3.6 View Clock

Note. The View Clock function is available only if the option board is fitted and analog features enabled – see Section 7.3,
page 57.

-----
VIEW CLOCK

Date
Shows the current date.

-----
Date 01:02:04

Time
Shows the current time.

-----
Time 12:00

Monitoring pH

Redox (ORP)
Operating Page – see Section 2.3, page 6.
Dual Redox
VIEW CLOCK pH/Redox (ORP)

SENSOR CAL.

Security Code See Note on Page 13.

CONFIG. DISPLAY

18 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

4 Setup
4.1 Sensor Calibration

Note. If Probe Type for either sensor (Sensor A only if single input) is set to Redox or ORP, the sensor can be calibrated only if
Enable Cals. for that sensor is set to Yes – see Section 5.3, page 30.

Sensor Calibration

-----
SENSOR CAL.
Sensor Calibration Security Code
Note. This frame is displayed only if Alter Cal. Code is not set to zero – see Section

0000 5.8, page 41.

Enter the required code number (between 0000 and 19999) to access the sensor
Cal. User Code
calibration pages. If an incorrect value is entered, access to the calibration pages is
prevented and the display reverts to the SENSOR CAL. menu.

Set Auto Buffers

Probe Type set to pH (for either sensor if dual input analyzer – see Section 5.3,
page 30) – continued below.

Sensor Cal. A
Probe Type set to Redox or ORP (for both sensors if dual input analyzer – see Section
5.3, page 30) – continued on page 22.

4.1.1 Set Buffer Type (pH Only)

Set Auto Buffers

-----
Set Auto Buffers

Sensor Cal. A Continued on Page 22.

SECURITY CODE Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

Buffer Type Continued below.

User
TECH.
MERCK Buffer Type
DIN
NIST Select the relevant type of buffer solution (see Appendix A):
----- ABB ABB
NIST
– ABB supplied buffer solution.
Buffer Type – NIST buffer solution.
DIN – DIN 19266 buffer solution.
MERCK – MERCK buffer solution
TECH – US Technical buffer solution
User – Buffer solution with a user defined pH value – see Section 4.1.2,
page 21.

Set Buffer 1 Buffer Type not set to User – continued on next page.
A: Enter Point 1 Buffer Type set to User – see Section 4.1.2, page 21.

IM/AX4PH Rev. P 19
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

Set Buffer 1
Set the pH value of the buffer 1 solution – see Appendix A for pH tables.

----- 4.O1pH
Set Buffer 1

Set Buffer 2
Set the pH value of the buffer 2 solution.

-----9.18pH Note. The solution selected for buffer 2 must be at least 2 ph greater than that
selected for buffer 1, e.g. if buffer 1 is set to 7 pH, buffer 2 must be set to at least 9 pH.
Set Buffer 2

Set Auto Buffers

20 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

4.1.2 Set Up User Defined Buffers (pH Only)

Buffer Type
set to User
(see Section 4.1.1)

15.0 Deg.C
Solution A: Enter point 1 (to 5)
Deg.C and Adjust are shown alternately on the upper display line. Using the and
0.00 pH keys, adjust the temperature reading (in 5 º increments) to the first of the
temperatures on the pH/temperature curve.
A: Enter point 1

15.0 Deg.C
3.99 pH
pH and Adjust are shown alternately on the center display line. Using the and
keys, adjust the pH reading (in 0.01 ph increments) to the pH reading that corresponds
A: Enter point 1 to the temperature reading entered above.

Notes.
1) For accurate calibration, it is important to repeat the above for buffer solution A at all
35.0 Deg.C 5 points along the pH/temperature curve.

4.02 pH 2) The displayed temperature value increases automatically by 5 ºC from the value set
for the previous point. The setting may be increased but not decreased.
A: Enter point 5

Solution B: Enter point 1 (to 5)

15.0 Deg.C Solution B set up is identical to solution A set up.

3.99 pH
B: Enter point 1

35.0 Deg.C Note. For accurate calibration, it is important to repeat the above for buffer solution B
at all 5 points along the pH/temperature curve.
4.02 pH The analyzer calculates the pH/temperature relationship from the data entered.
B: Enter point 5

Set Auto Buffers

Sensor Cal. A See Section 4.1.3 page 22.

SECURITY CODE Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

IM/AX4PH Rev. P 21
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

4.1.3 Adjust Offset (Redox/ORP Only)

Calibrate Sensor A

-----
Sensor Cal. A

Sensor Cal. B Sensor B (dual input analyzers only) calibration is identical to Sensor A calibration.

SENSOR CAL. Probe Type for Sensor B (dual input analyzers only) set to Redox or ORP and Enable
Cals. set to No (Section 5.3) – return to top of page.
SECURITY CODE Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.
A: Adjust Offset Probe Type set to Redox or ORP (Section 5.3) – continued below.
A: Buffer Method Probe Type set to pH (Section 5.3) – see Section 4.1.1, page 19.

Adjust Offset (ORP/Redox probes only)

0mV
mV and Adjust are shown alternately on the upper display line. Use the and

407mV keys to adjust the upper display line to the required offset value for the process.
The offset value is adjustable between –240 and +240 mV.
A: Adjust Offset

Sensor B (dual input analyzers only) calibration is identical to Sensor A calibration.

Sensor Cal. A Sensor Cal. B

Probe Type for Sensor B (dual input analyzers only) set to Redox or ORP and Enable
SENSOR CAL.
Cals. set to No (Section 5.3) – return to top of page.

Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
SECURITY CODE
Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.
CONFIG. DISPLAY

22 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

4.1.4 Automatic, Single- and Two-Point Calibration (pH Only)

Sensor A: Buffer Method (pH probes only)

Auto Select the type of automatic calibration required:

-----1-Pt Auto 1-Pt –

Auto 2-Pt –
Automatic, single-point calibration
Automatic, two-point calibration
A: Buffer Method

4.00pH
Calibrate Buffer (Single-Point Calibration) or Calibrate Buffer 1(Two-Point Calibration)
Immerse Sensor A in the buffer solution.

25.0Deg.C
A: Immerse Buf.1
Press the key to initiate calibration.
Note. To abort calibration, press the key again at any time before calibration is
complete – see below.

175mV The center display line shows the measured sensor output in millivolts.

#### 100% #### As calibration proceeds, a progress indicator appears in the lower display line. When
the measured sensor output stabilizes, the lower display line shows
##### 100 % #####.

4.01pH
The display then changes for 2 seconds to show the temperature-corrected buffer
value in the upper display line, then advances automatically to the next frame.

A: Cal. Buffer 1

A: Immerse Buf.2 Two-point calibration selected – continued on next page.

A: Calibration Single-point calibration selected – continued on next page.

Abort Calibration
Select Yes or No.

-----Yes
A: Abort Cal.
A: SENSOR CAL. Yes selected – return to the main menu.
A: Immerse Buf.2 No selected – calibration continues.

Calibration
Min. Max. Explanation Action
Message

Calibration
40 to 70 % 105 % The new calibration coefficients are accepted None
Passed

Calibration The electrode pair are becoming fatigued

60 to 90 % 60 to 90 % The new calibration coefficients are accepted
Low Slope – replacement is recommended

Calibration The new calibration coefficients are ignored and the Check buffer values and repeat buffering.
0% 40 to 70 %
Failed last known valid calibration coefficients are used If the fault persists, replace the electrodes

Table 4.1 Calibration Messages

IM/AX4PH Rev. P 23
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

A: Buffer Method
set to Auto 2-Pt

9.18pH Calibrate Buffer 2 (Two-Point Calibration only)

Immerse Sensor A in the second buffer solution.
20.0Deg.C
A: Immerse Buf.2
Press the key to initiate calibration.
Note. To abort calibration, press the key again at any time before calibration is
complete – see previous page.

128mV
The center display line shows the measured sensor output in millivolts.
As calibration proceeds, a progress indicator appears in the lower display line. When
#### 100% #### the measured sensor output stabilizes, the lower display line shows
##### 100 % #####.

4.01pH
The display then changes for 2 seconds to show the temperature-corrected buffer
value in the upper display line, then advances automatically to the next frame.

A: Cal. Buffer 2

A: Buffer Method
set to Auto 1-Pt
Calibration Message
See Table 4.1 for details of calibration messages.
-----Passed
A: Calibration

100.0% Slope Value

% slope value.
7.00pH A value between the programmed minimum % slope value (see Set Min Slope in the
CONFIG. SENSORS page – Section 5.3) and 105 % is displayed. If the value is outside
A: Slope & Check these limits, check the electrode system.

Sensor Cal. A
pH check value.
Displayed as an additional indication of electrode system condition; 7 ph is the
optimum value for glass electrodes and 0 ph for Antimony electrodes.

Sensor Cal. B Sensor B (dual input analyzers only) calibration is identical to Sensor A calibration.
SENSOR CAL. Probe Type for Sensor B (dual input analyzers only) set to Redox or ORP and Enable
Cals. set to No (Section 5.3) – return to top of page.
SECURITY CODE Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

24 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

4.1.5 Manual, Single- and Two-Point Calibration (pH Only)

Sensor A: Buffer Method (pH probes only)

Man Select the type of manual calibration required:

-----1-Pt Man 1-Pt

Man 2-Pt
–
–
Manual, single-point calibration
Manual, two-point calibration
A: Buffer Method

Set Buffer Temperature

Deg.C (or Deg.F) and Adjust are shown alternately on the center display line. Use the

20.0Deg.C and keys to adjust the displayed temperature value to the required buffer
temperature (–20 to150 ºC or –4 to 302 ºF).
A:Set Buf. Temp. Note. If A: Buffer Method is set to Man 2-Pt, the temperature selected is used for both
buffers.

4.00pH
Calibrate Buffer (Single-Point Calibration) or Calibrate Buffer 1(Two-Point Calibration)
Immerse Sensor A in the buffer solution.
25.0Deg.C pH and Adjust are shown alternately on the upper display line. Use the and
keys to set the displayed pH value to the temperature-corrected pH value of the
A: Immerse Buf.1
chosen solution (see the data sheet provided with the solution).
Press the key to initiate calibration.
Note. To abort calibration, press the key again at any time before calibration is

4.01pH
complete – see below.
Measured pH value from the last successful calibration.

175mV Measured sensor output in millivolts.

Press button
when stable

4.01pH When the measured sensor output stabilizes, press the

calibration.
key to accept the

Cal. Accepted is shown for 2 seconds to confirm that the calibration has been
A: Cal. Accepted
accepted, the display then advances automatically to the next frame.

4.01pH The display then changes for 2 seconds to show the temperature-corrected buffer
value in the upper display line, then advances automatically to the next frame.

A: Cal. Buffer 1

A: Immerse Buf.2 Two-point calibration selected – continued on next page.

A: Calibration Single-point calibration selected – continued on next page.

Abort Calibration
Select Yes or No.

-----Yes
A: Abort Cal.
A: SENSOR CAL. Yes selected – return to the main menu.
A: Immerse Buf.2 No selected – calibration continues.

IM/AX4PH Rev. P 25
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

A: Buffer Method
set to Man 2-Pt

9.18pH Calibrate Buffer 2 (Two-Point Calibration only)

Immerse Sensor A in the second buffer solution.
20.0Deg.C pH and Adjust are shown alternately on the upper display line. Use the and
A: Immerse Buf.2 keys to set the displayed pH value to the temperature-corrected pH value of the
chosen solution (see the data sheet provided with the solution).
Press the key to initiate calibration.
Note. To abort calibration, press the key again at any time before calibration is

9.22pH
complete – see previous page.
Measured pH value from the last successful calibration.
105mV Measured sensor output in millivolts.
Press button When the measured sensor output stabilizes, press the key to accept the
when stable calibration.

9.22pH
Cal. Accepted is shown for 2 seconds to confirm that the calibration has been
A: Cal. Accepted
accepted, the display then advances automatically to the next frame.

9.22pH The display then changes for 2 seconds to show the temperature-corrected buffer
value in the upper display line, then advances automatically to the next frame.

A: Cal. Buffer 2

A: Buffer Method
set to Man 1-Pt
Calibration Message
See Table 4.1 for details of calibration messages.

-----Passed
A: Calibration

100.0%
Slope Value
% slope value.

7.00pH A value between the programmed minimum % slope value (see Set Min Slope –
Section 5.3) and 105 % is displayed. If the value is outside these limits, check the
A: Slope & Check electrode system.
pH check value.
Sensor Cal. A
Displayed as an additional indication of electrode system condition; 7 ph is the
optimum value for glass electrodes and 0 ph for Antimony electrodes.

Sensor Cal. B Sensor B calibration (dual input analyzers only) is identical to Sensor A calibration.
SENSOR CAL. Probe Type for Sensor B (dual input analyzers only) set to Redox or ORP and Enable
Cals. set to No (Section 5.3) – return to top of page.
SECURITY CODE Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

26 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 4 Setup

4.1.6 Grab Calibration (pH Only)

Sensor A: Buffer Method (pH probes only)

Select Grab calibration method.

-----Grab
A: Buffer Method

9.18pH
Adjust Value
ph and Adjust are shown alternately on the upper display line. The displayed pH value

25.0Deg.C is the reading sampled by the analyzer as this frame is selected and is held until the
display is advanced to the next frame. Use the and keys to adjust the
A: Adjust Value displayed value (in 0.01 pH increments) to match the pH value of the measured grab
sample.
Notes.
 If the displayed value is adjusted by more than ±3pH, WARNING - OFFSET is
shown on the lower display line. If the measured grab sample value is correct
and the analyzer reading has not been over-adjusted, clean the electrode, check
the sensor connections and try again.
 If the displayed value is adjusted by ±5pH, OUT OF RANGE is shown on the
lower display line, indicating that maximum adjustment has been reached.
Further adjustment is not possible.

100.0%
Slope Value
% slope value.

7.00pH The value generated during the last valid two-point calibration, between the
programmed minimum % slope value (see Set Min Slope – Section 5.3) and 105 %, is
A: Slope & Check displayed.
pH check value.
Sensor Cal. A
The value generated during the last valid two-point calibration, adjusted by the value
applied in Adjust Value (above), is displayed.
Note. The pH check value is reset to the previous, valid check value if a single- or
two-point calibration is carried out after a grab calibration.

Sensor Cal. B Sensor B calibration (dual input analyzers only) is identical to Sensor A calibration.
SENSOR CAL. Probe Type for Sensor B (dual input analyzers only) set to Redox or ORP and Enable
Cals. set to No (Section 5.3) – return to top of page.
SECURITY CODE Alter Sec. Code not set to zero (Section 5.8) – see Section 5.1, page 28.
CONFIG. DISPLAY Alter Sec. Code set to zero (Section 5.8) – see Section 5.2, page 29.

IM/AX4PH Rev. P 27
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5 Programming
5.1 Security Code
Note. This frame is displayed only if Alter Sec. Code is not set to zero – see Section
5.8, page 41.

0000 Enter the required code number (between 0000 and 19999), to gain access to the
configuration pages. If an incorrect value is entered, access to the configuration pages
SECURITY CODE is prevented and the display reverts to the Operating Page – see Section 2.3, page 6.

CONFIG. DISPLAY See Section 5.2, page 29.

28 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.2 Configure Display

-----
CONFIG. DISPLAY
Set Language
Sets the language to be used on all displays.

-----
Set Language

Language Page
Use the and keys to select the required language.
-----
English
Deutsch
Francais
Espanol
Italiano

Set Language

Set Temperature Units

-----
Set Temp. Units

Temperature Units
Use the and keys to select the sample temperature display units.
Deg. F
----- Deg. C
Off
Temp. Units

Set Temp. Units

Set Up Display Backlight

-----
Set Backlight

Backlight
Use the and keys to select the required backlight option:
Auto.
----- On Auto. – Backlight comes on at each button press and switches off one
minute after the last button press.
LED Backlight On – Backlight is always on.
CONFIG. DISPLAY Return to main menu.
Set Backlight
CONFIG. SENSORS See Section 5.3, page 30.

IM/AX4PH Rev. P 29
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.3 Configure Sensors

-----
CONFIG. SENSORS

Configure Sensor A

-----
Config. Sensor A

Config. Sensor B Sensor B configuration (dual input analyzers only) is identical to Sensor A
configuration.

Probe Type
ORP
Redox Select the required probe type.

----- pH ORP
Redox
–
–
Millivolt display
Millivolt display
A: Probe Type
pH – pH display

Differential Input

Yes Yes – Select if electrode system is equipped with a solution earth (ground)
----- No
No –
rod and sensor diagnostics are required – see Section 5.4, page 33.
Select if electrode system is not equipped with a solution earth
A: Diff. Input
(ground) rod or sensor diagnostics are not required.
Note. Ensure the electrode system is connected correctly for the type of input
selected (Standard or Differential) – see Fig. 6.9 (wall-/pipe-mount analyzers) or
Fig. 6.11 (panel-mount analyzers).

A: Temp. Sensor Probe Type set to Redox or ORP – continued below.

A: Electrode Probe Type set to pH – continued on next page.

A: Probe Type
set to Redox/ORP
None Temperature Sensor
3K Bal
Pt1000 Select the type of temperature sensor used: Pt100, Pt1000, Balco 3K or None.

----- Pt100
A: Temp. Sensor

Enable Calibration
Select Yes to enable sensor calibration.
Yes
----- No Select No to disable sensor calibration and all associated frames.
A: Enable Cals

Config. Sensor A CONFIG. SENSORS Return to main menu.

CONFIG. ALARMS See Section 5.4, page 33.

30 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

A: Probe Type
set to pH
pH Electrode Type

Antim. Select the type of pH electrode used, Glass or Antimony.

----- Glass
A: Electrode

Temperature Compensation

Manual Select Auto to enable the analyzer to compensate automatically for fluctuations in

----- Auto sample temperature.

A: Temp. Comp.

Manual
Auto

Temperature Sensor (Automatic Temperature Compensation only)

3K Bal Select the type of temperature sensor used: Pt100, Pt1000 or Balco 3K.
Pt1000
----- Pt100
A: Temp. Sensor

A: Sample Comp. continued on next page.

Preset Temperature (Manual Temperature Compensation only)

Enter the temperature of the sample within the range –10.0 to 120.0 ºC.
25.0 Deg.C
A: Preset Temp.

A: Set Min Slope continued on next page.

IM/AX4PH Rev. P 31
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

Solution Temperature Compensation

Yes Select Yes to enable compensation for solution temperature effects referenced to

----- No 25 ºC.

A: Sample Comp.

No
Yes

Sample Coefficient
If Sample Comp. is set to Yes, enter the temperature coefficient of the sample, in pH/ºC,
-0.035 pH/°C within the range 0.020 to –0.050 (in –0.001 increments). For ammonia and sodium
hydroxide dosed boilers the value is typically –0.035 (this depends on the individual
A: Sample Coeff. boiler chemistry). The exact value for a particular sample needs to be determined by
laboratory analysis.

pH Calibration Minimum Slope Value

60.0%
Set the required pH calibration minimum slope value, in %, within the range 60.0 to
90.0 (in 0.1 increments). The calibration fail limit is set automatically to 20 % below the
minimum slope setting – see Table 4.1.
A: Set Min Slope

Config. Sensor A
Config. Sensor B Sensor B (dual input analyzers only) configuration is identical to Sensor A
configuration.
CONFIG. DIAGS see Section 5.4, page 33

32 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.4 Configure Diagnostics

Note. The Configure Diagnostics function is applicable only if Diff. Input for Sensor A and/or Sensor B is set to Yes – see Section
5.3, page 30.

-----
CONFIG. DIAGS

Configure Sensor A

-----
Config. Sensor A

Config. Sensor B Sensor B configuration (dual input analyzers only) is identical to Sensor A
configuration.

pH Glass Check
Set to On to enable the impedance of the glass electrode circuit to be monitored in
Off
----- On
order to provide low glass impedance and out-of-sample/broken cable warnings.
Note. This frame is displayed only if A: Probe Type is set to pH and A: Electrode is set
A: pH Glass to Glass – see Section 5.3, page 30.

Reference Electrode Check

Off Set to On to enable the condition of the reference electrode to be monitored in order to

----- On provide:
– an indication of when sensor cleaning or replacement is required
A: Ref. Checking
– out-of-sample/broken cable warnings

Config. Sensor A Config. Sensor B Sensor B (dual input analyzers only) configuration is identical to Sensor A
configuration.
Off
On CONFIG. ALARMS See section 5.5, page 34.

Reference Alarm
Set the impedance value above which the reference alarm is activated.
50kOhm
A: Ref. Alarm

Config. Sensor A
Config. Sensor B Sensor B (dual input analyzers only) configuration is identical to Sensor A
configuration.
CONFIG. ALARMS See section 5.5, page 34.

IM/AX4PH Rev. P 33
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.5 Configure Alarms

-----
CONFIG. ALARMS

Configure Alarm 1

-----
Config. Alarm 1
Config. Alarm 2 Alarms 2 and 3 configuration (and Alarms 4 and 5 if option board fitted and analog
features enabled – see Section 7.3, page 57) is identical to Alarm 1 configuration.
Alarm 3 can also be configured as a Wash alarm if A3: Type is set to Wash – see
following frame.

Wash Alarm 1 Type

Status Select the type of alarm required:
Alarm
----- Off Off – The alarm is disabled, the alarm LED is off and the relay is
de-energized at all times.
A1: Type
Alarm – The analyzer is configured using the Assign frame (following) to
generate an alarm in response to a specified high or low pH, Redox
(ORP) or process temperature sensor reading.
Status – An alarm is generated if either a power failure or a condition that
causes any of the error messages in Table 8.1 (page 62) to be
displayed occurs.
Wash – Alarm 3 is configured to control the wash sequence.
Note. The Wash alarm type can be assigned only to Alarm 3 and is displayed only
when the lower display line shows A3: Type.

Config. Alarm 1 A1: Type set to Off or Status.

A1: Assign A1: Type set to Alarm – continued below.
Wash Mode A3: Type set to Wash – see Section 5.5.1, page 36.

A-B Alarm 1 Assign

Temp.B
Sen.B Select the alarm assignment required:
Temp.A
----- Sen.A Sen.A
Sen.B
– The analyzer activates an alarm if the pH or Redox (ORP) value of the
process fluid measured by the selected sensor exceeds or drops
A1: Assign below the value set in the Alarm 1 Set Point parameter, depending on
the type of Alarm 1 Action selected – see next page.
Temp.A – The analyzer activates an alarm if the temperature of the process fluid
Temp.B measured by the selected sensor exceeds or drops below the value
set in the Alarm 1 Set Point parameter, depending on the type of
Alarm h1 Action selected – see next page.
A-B – The analyzer activates an alarm if the difference between the Sensor A
and Sensor B readings exceeds or drops below the value set in the
Alarm 1 Set Point parameter, depending on the type of Alarm 1 Action
selected – see next page.
Note. The Sen.B, Temp.B and A-B alarm assignment types are applicable only to dual
input analyzers and A-B is displayed only when Probe Type for each sensor is set to pH
– see Section 5.3, page 30.

A1: Failsafe Continued on next page.

34 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

Alarm 1 Failsafe
Select Yes to enable failsafe action, otherwise select No.
Yes
----- No See also Fig. 5.2 to Fig. 5.6 (page 37).
A1: Failsafe

Alarm 1 Action
High Select the alarm action required, High or Low.
-----Low See also Fig. 5.2 to Fig. 5.6 (page 37).
A1: Action

A-B
mV Alarm 1 Set Point
Deg.C
Deg.F The Alarm 1 Set Point can be set within the following ranges:
100.0 pH pH
mV
–
–
–2.00 to 16.00 pH
–1200 to 1200 mV
A1: Setpoint
Deg.C – –10.0 to 150.0
Deg.F – –14.0 to 302.0
A-B – 0.00 to 14.00 pH
Set to the value required.

Alarm 1 Hysteresis
A differential set point can be defined between 0 and 5 % of the alarm set point value.
0.0
% Set the required hysteresis in 0.1 % increments.
See also Fig. 5.2 to Fig. 5.6 (page 37).
A1: Hysteresis

Alarm 1 Delay
If an alarm condition occurs, the activation of the relays and LEDs can be delayed for a
0Secs specified time period. If the alarm clears within the period, the alarm is not activated.
A1: Delay Set the required delay, in the range 0 to 60 seconds in 1 second increments.
See also Fig. 5.2 to Fig. 5.6 (page 37).

Config. Alarm 2 Alarms 2 and 3 configuration (and Alarms 4 and 5 if option board fitted and analog
Config. Alarm 1 features enabled – see Section 7.3, page 57) is identical to Alarm 1 configuration.
CONFIG. OUTPUTS See Section 5.6, page 38.

IM/AX4PH Rev. P 35
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.5.1 Wash Cycle Configuration (Applicable Only to Alarm 3)

A3: Type
set to Wash
Wash Mode

Cont. Select the wash mode required.

----- Pulsed Cont.
Pulsed
–
–
(continuous) the relay remains energized for the wash duration
the relay is switched on and off every second for the duration of the
Wash Mode
wash, – see Fig. 5.1.

Wash Frequency

Hours Set the wash frequency required.

15 Mins Wash frequency is set in 15 minute increments between 15 and 45 minutes, then in 1
hour increments between 1 and 24 hours.
Wash Frequency

Wash Duration

Mins Set the wash duration required.

15 Secs Wash duration is set in 15 second increments between 15 and 45 seconds, then in 1
minute increments between 1 and 10 minutes.
Wash Duration

Recovery Period
Set the recovery period required, between 0.5 and 5.0 minutes in 0.5 minute
1.0 Mins increments.

Recovery Period

Config. Alarm 4 Option board fitted and analog features enabled (see Section 7.3, page 57) – Alarm 4
Config. Alarm 3
configuration is identical to Alarm 1.
CONFIG. OUTPUTS Option board not fitted or option board fitted and analog features disabled (see
Section 7.3, page 57) – see Section 5.6, page 38.

Frequency

Wash Duration Recovery Period

Continuous
t

1s 1s
Pulsed
t

Fig. 5.1 Pulsed and Continuous Wash Cycles

36 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

Note. The following examples illustrate High Alarm Actions, i.e. the alarm is activated when the process variable exceeds the
defined set point. Low Alarm Actions are the same, except the alarm is activated when the process variable drops below the
defined set point.

Process Variable Process Variable

High Set Point High Set Point

Relay Energized,
LED Off Relay Energized, LED On

Relay De-energized,
Relay De-energized, LED On LED Off

Fig. 5.2 High Failsafe Alarm without Hysteresis and Delay Fig. 5.5 High Non-Failsafe Alarm without Delay and Hysteresis

Process Variable Process Variable

High Set Point High Set Point

Hysteresis

Relay Energized, Relay Energized,

LED Off LED Off

Delay
Relay De-energized, LED On Relay De-energized, LED On

Fig. 5.3 High Failsafe Alarm with Hysteresis but no Delay Fig. 5.6 High Failsafe Alarm with Delay but no Hysteresis

Process Variable

High Set Point

Hysteresis

Relay Energized,
LED Off

Delay
Relay De-energized, LED On

Fig. 5.4 High Failsafe Alarm with Hysteresis and Delay

IM/AX4PH Rev. P 37
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.6 Configure Outputs

-----
CONFIG. OUTPUTS
Configure Output 1

-----
Config. Output 1

Config. Output 2
Output 2 configuration (and Outputs 3 and 4 if option board fitted and analog features
enabled – see Section 7.3, page 57) is identical to Output 1 configuration.

A-B Assign
Temp.B
Sen.B Select the sensor and analog output required:
Temp.A
----- Sen.A Sen.A
Sen.B
– pH/Redox (ORP)/mV for the selected sensor.
AO1: Assign
Temp.A
– Temperature for the selected sensor.
Temp.B
A-B – Difference between the Sensor A and Sensor B readings.
Note. Sen.B, Temp.B and A-B are applicable only to dual input analyzers.

Range
4-20mA
0-20mA Select the analog output current range for the selected output.
----- 0-10mA
AO1: Range

7.00pH
Span Value
pH (or mV or Deg.C or Deg.F or A-B) and Adjust are shown alternately on the upper

0.00pH display line. Use the

span value.
and keys to adjust the displayed reading to the required

AO1: Span Value

Note. The minimum and maximum span values are determined by the Zero Value
setting (see next page) plus the minimum differential, e.g. to set Span Value to 0.00 pH,
first set Zero Value to –2.00 pH.
pH – 0.00 to 16.00 pH (minimum differential, 2.00 pH)
Redox/ORP – –1100 to 1200 mV (minimum differential, 100 mV)
Temperature – Deg. C 0.0 to 150.0 (minimum differential, 10 ºC)
Deg. F 32.0 to 302.0 (minimum differential,18 ºF)
A-B – 0.00 to 14.00 pH (minimum differential, 2.00 pH)
Note. A-B is applicable only to dual input analyzers.

AO1: Zero Value Continued on next page.

38 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

7.00pH Zero Value

pH (or mV or Deg.C or Deg.F or A-B) and Adjust are shown alternately on the center

0.0pH display line. Use the

zero value:
and keys to adjust the displayed reading to the required
AO1: Zero Value
Note. The zero value setting plus the minimum differential determines the minimum
and maximum values for the span setting, e.g. to set a span value of –1100 mV, first
set the zero value to –1200 mV.
pH – –2.00 to 14.00 pH (minimum differential, 2.00 pH)
ORP/Redox – –1200 to 1100 mV (minimum differential, 100 mV)
Temperature – Deg. C –10.0 to 140.0 (minimum differential, 10 ºC)
Deg. F 14.0 to 284.0 (minimum differential, 18 ºF)
A-B – –2.00 to 12.00 pH (minimum differential, 2.00 pH)
Note. A-B is applicable only to dual input analyzers.

Default Output
Hold
On Select the system reaction to failure:
----- Off
mA Hold
On
–
–
Hold the analog output at the value prior to the failure.
Stop on failure. This drives the analog output to the level set in
AO1: Default
the Default Val frame below.
Config. Output 1
Off – Ignore failure and continue operation.
Off
or
Hold
On

Default Value
The level to which the analog output is driven if a failure occurs.
12.00mA Set the value between 0.00 and 22.00 mA
AO1: Default Val

Config. Output 2 Output 2 configuration (and Outputs 3 and 4 if option board fitted and analog features
Config. Output 1 enabled – see Section 7.3, page 57) is identical to Output 1 configuration.
CONFIG. CLOCK Option board fitted and analog features enabled (see Section 7.3, page 57) – see
Section 5.7, page 40.
CONFIG. SERIAL
Option board fitted and Serial Communications feature enabled (see Section 7.3,
page 57) – see Supplementary Manual Profibus® Datalink Description (IM/AX4/PBS).
CONFIG. CONTROL
Single input analyzer and option board not fitted – see PID Control Supplement
(IM/AX4PID).
CONFIG. SECURITY
Dual input analyzer and option board not fitted – see Section 5.8, page 41.

IM/AX4PH Rev. P 39
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.7 Configure Clock

Note. The Configure Clock function is available only if the option board is fitted and analog features enabled – see Section 7.3,
page 57.

-----
CONFIG. CLOCK
Set Clock
Set the system clock.

-----
Set Clock?

CONFIG. CLOCK
Return to main menu.

CONFIG. SERIAL
Option board fitted and Serial Communications feature enabled (see Section 7.3,
page 57) – see Supplementary Manual Profibus® Datalink Description (IM/AX4/PBS).
CONFIG. CONTROL
Single input analyzer and option board not fitted – see PID Control Supplement
(IM/AX4PID).
CONFIG. SECURITY Dual input analyzer and option board not fitted – see Section 5.8, page 41.

Date Format
Select the required date format.

-----
mm:dd:yy
Format dd:mm:yy

Date
Set Set the date in the format selected above.

-----Day Press
Use the
to move between the day, month and year fields.
and keys to adjust each field.
Date 01:01:01

Time
Set
Set the time in the format hh:mm.
----- Hours Press to move between hours and minute fields.
Time 12:00 Use the and keys to adjust each field.

----- Press to Set and Press to Abort are shown alternately on the lower display line.
Press To Set
Press To Abort Press the appropriate key to set the clock or abort the changes.

Set Clock?

40 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.8 Configure Security

-----
CONFIG. SECURITY
Alter Security Code
Set the security code to a value between 0000 and 19999.
0000
Alter Sec. Code

Alter Calibration Code

Set the sensor calibration access code to a value between 0000 and 19999.
0000
Alter Cal. Code

Alter Sec. Code CONFIG. SECURITY Return to main menu.

CONFIG. LOGBOOK Option board fitted and analog features enabled (see Section 7.3, page 57) – see
Section 5.9, page 41.

5.9 Configure Logbook

Note. The Configure Logbook function is available only if the option board is fitted and analog features enabled – see Section
7.3, page 57.

-----
CONFIG. LOGBOOK
Configure Logbook
Off Use the and keys to set the logbook On or Off.
-----On If Off is selected, all data entries in the logbook are cleared.
Logbook

CONFIG. LOGBOOK Return to main menu.

TEST/MAINTENANCE See Section 5.10, page 42.

IM/AX4PH Rev. P 41
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

5.10 Test Outputs and Maintenance

-----
TEST/MAINTENANCE
Test Outputs
Displays the output test details for the analog outputs.

----- Note. Outputs 3 and 4 are available only if the option board is fitted and analog
features enabled – see Section 7.3, page 57.
Test Outputs
Test Output 1 frame only is shown; the format of frames for the remaining outputs is
identical.

Maintenance See below.

4.00mA
Test Output 1
The theoretical output current value.

20.0% Output current as a percentage of the full range current.

Test Output 1 Use the and keys to adjust the displayed theoretical output current value to
give the output required.
FACTORY SETTINGS See Section 7.3, page 57.
Test Output 2 Test remaining outputs.

Maintenance

-----
Maintenance

Hold Outputs
Auto. Enables the relay action and analog outputs to be maintained.
On
----- Off Auto. – Changes in relay action and analog outputs are inhibited during sensor
calibration.
Hold Outputs
On – Changes in relay action and analog outputs are inhibited.
Off – Changes in relay action and analog outputs are not inhibited.
Note. The LEDs flash while the analyzer is in 'Hold' mode.

Load/Save Config Continued on next page.

FACTORY SETTINGS See Section 7.3, page 57.
Maintenance Hold Outputs set to Off or On – return to main menu.
Automatic Time Hold Outputs set to Auto. – continued on next page.

42 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 5 Programming

Hold Outputs
set to Auto.

1Hrs
Automatic Time
If required, set a time period between 1 and 6 hours, in 30 minute increments, for

30Mins which the outputs are held when Hold Outputs is set to Auto.
At the default setting of Off, changes in relay action and analog outputs are inhibited
Automatic Time
during sensor calibration and released automatically at the end of the procedure.
If a time is set, changes in relay action and analog outputs are inhibited during sensor
calibration, but if the calibration is not completed within the set time, the calibration is
aborted, the display returns to the Operating Page and CAL. ABORTED is displayed.

Maintenance
Load/Save Config Continued below.
FACTORY SETTINGS See Section 7.3, page 57.

Load/Save Configuration
Select whether a configuration is to be loaded or saved.
Yes
----- No Note. If No is selected, pressing the key has no effect.

Load/Save Config

Return to main menu.

Yes TEST/MAINTENANCE

FACTORY SETTINGS See Section 7.3, page 57.

Load User/Factory Configuration

Load Note. Applicable only if Load/Save Config is set to Yes.

----- Save Factory Config. – resets all the parameters in the Configuration Pages to
the Company Standard.
User Config.
Factory Config. Save User Config. – saves the current configuration into memory.
Load User Config. – reads the saved user configuration into memory.

User Config. and Factory Config. are displayed alternately if a User Configuration has
been saved previously. Use the and keys to make the required selection.

-----
Press To Set. Press to Set and Press to Abort are shown alternately on the lower display line.
Press To Abort
Press the appropriate key to load/save the configuration or abort the changes.

TEST/MAINTENANCE

IM/AX4PH Rev. P 43
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6 Installation
6.1 Siting Requirements

Note.
 Mount in a location free from excessive vibration, and
where the temperature and humidity specification will
not be exceeded.
 Mount away from harmful vapors and/or dripping
fluids and ensure that it is suitably protected from
direct sunlight, rain, snow and hail.
 Where possible, mount the analyzer at eye level to
allow an unrestricted view of the front panel displays
and controls.

Maximum Distance
Sensor
100m (275 ft)

A – Maximum Distance Between Analyzer and Sensor

55°C
(131°F)
Max.
–20°C
(–4°F)
Min.

B – Within Temperature Limits

IP65*

C – Within Environmental Limits

* Refer to Specification, page 64

Fig. 6.1 Siting Requirements

44 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.2 Mounting
6.2.1 Wall-/Pipe-mount Analyzers

Dimensions in mm (in.) Fixing Centers 94 (3.7)

210 (8.23)
192 (7.56)
R1
0(
0.4 96 (3.76)
)
Fixing Centers

150 (5.9)
175 (6.9)

192 (7.56)
6)
.2
(0
50
6.
Ø
25

Fig. 6.2 Overall Dimensions

61 (23/8) OD
Position 'U' bolts on pipe 1
Vertical or
Drill suitable Horizontal
2 holes Position plate over 'U' bolts 2 Post

1
Mark fixing centers
(see Fig. 6.2)
3
Secure plate
3
Secure instrument to
wall using 4 Secure transmitter to mounting plate
suitable fixings
A – Wall-mounting B – Pipe-mounting

Fig. 6.3 Wall-/Pipe-mounting

IM/AX4PH Rev. P 45
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.2.2 Panel-mount Analyzers

Dimensions in mm (in.)
25 92 +0.8
–0 (3.62 +0.03
–0 )
96 (3.78) 137.50 (5.41) (0.98)

91.60 (3.6)
96 (3.78)

92 +0.8
–0
Panel Cut-out (3.62 +0.03 )
–0

5.40 (0.2)

Fig. 6.4 Overall Dimensions

Cut a hole in the panel (see Fig. 6.4 for dimensions).

1
Instruments may be close stacked to DIN 43835

Remove the panel clamp and

anchors from the instrument case 3

Insert the instrument

4 into the panel cut-out

Loosen the
retaining screw on 2
each panel clamp

5 Refit the panel clamps to the case, ensuring that the

panel clamp anchors are located correctly in their slots

6 Secure the analyzer by tightening the panel clamp

retaining screws (see Note below)

Fig. 6.5 Panel-mounting

Note. The clamp must fit flat on the analyzer casing. The clamp uses a torque limiter, so it is not possible to over-tighten the
securing screws.

46 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.3 Connections, General

Warning.
 The instrument is not fitted with a switch therefore a disconnecting device such as a switch or circuit breaker conforming to
local safety standards must be fitted to the final installation. It must be fitted in close proximity to the instrument within easy
reach of the operator and must be marked clearly as the disconnection device for the instrument.
 Remove all power from supply, relay and any powered control circuits and high common mode voltages before accessing
or making any connections.
 The power supply earth (ground) must be connected to reduce the effects of RFI interference and ensure the correct
operation of the power supply interference filter.
 The power supply earth (ground) must be connected to the earth (ground) stud on the analyzer case – see Fig. 6.8
(wall-/pipe-mount analyzers) or Fig. 6.10 (panel-mount analyzers).
 Use cable appropriate for the load currents. The terminals accept cables from 20 to 14 AWG (0.5 to 2.5mm2) UL Category
AVLV2.
 The instrument conforms to Mains Power Input Insulation Category III. All other inputs and outputs conform to Category II.
 All connections to secondary circuits must have basic insulation.
 After installation, there must be no access to live parts, e.g. terminals.
 Terminals for external circuits are for use only with equipment with no accessible live parts.
 The relay contacts are voltage-free and must be appropriately connected in series with the power supply and the
alarm/control device which they are to actuate. Ensure that the contact rating is not exceeded. Refer also to Section 6.3.1
for relay contact protection details when the relays are to be used for switching loads.
 Do not exceed the maximum load specification for the selected analog output range.
The analog output is isolated, therefore the –ve terminal must be connected to earth (ground) if connecting to the isolated
input of another device.
 If the instrument is used in a manner not specified by the Company, the protection provided by the equipment may be
impaired.
 All equipment connected to the instrument's terminals must comply with local safety standards (IEC 60950, EN61010-1).

USA and Canada Only

 The supplied cable glands are provided for the connection of signal input and ethernet communication wiring ONLY.
 The supplied cable glands and use of cable / flexible cord for connection of the mains power source to the mains input and
relay contact output terminals is not permitted in the USA or Canada.
 For connection to mains (mains input and relay contact outputs), use only suitably rated field wiring insulated copper
conductors rated min. 300 V, 14 AWG 90C. Route wires through suitably flexible conduits and fittings.

Note.
 An earthing (grounding) – stud terminal is fitted to the analyzer case for bus-bar earth (ground) connection – see Fig. 6.8
(wall-/pipe-mount analyzers) or Fig. 6.10 (panel-mount analyzers).
 Always route signal output/sensor cell cable leads and mains-carrying/relay cables separately, ideally in earthed (grounded)
metal conduit. Use twisted pair output leads or screened cable with the screen connected to the case earth (ground) stud.
Ensure that the cables enter the analyzer through the glands nearest the appropriate screw terminals and are short and
direct. Do not tuck excess cable into the terminal compartment.
 Ensure that the IP65 rating is not compromised when using cable glands, conduit fittings and blanking plugs/bungs (M20
holes). The M20 glands accept cable of between 5 and 9mm (0.2 and 0.35 in.) diameter.

IM/AX4PH Rev. P 47
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.3.1 Relay Contact Protection and Interference Suppression

If the relays are used to switch loads on and off, the relay contacts can become eroded due to arcing. Arcing also generates radio
frequency interference (RFI) which can result in analyzer malfunctions and incorrect readings. To minimize the effects of RFI, arc
suppression components are required; resistor/capacitor networks for AC applications or diodes for DC applications. These
components must be connected across the load – see Fig. 6.6.
For AC applications the value of the resistor/capacitor network depends on the load current and inductance that is switched. Initially,
fit a 100R/0.022 µF RC suppressor unit (part no. B9303) as shown in Fig. 6.6A. If the analyzer malfunctions (locks up, display goes
blank, resets etc.) the value of the RC network is too low for suppression and an alternative value must be used. If the correct value
cannot be obtained, contact the manufacturer of the switched device for details on the RC unit required.
For DC applications fit a diode as shown in Fig. 6.6B. For general applications use an IN5406 type (600 V peak inverse voltage at
3 A).

Note. For reliable switching the minimum voltage must be greater than 12V and the minimum current greater than 100mA.

NC C NO Relay Contacts NC C NO Relay Contacts

Diode

R C

Load Load
External L N External + –
AC Supply DC Supply

A – AC Applications B – DC Applications

Fig. 6.6 Relay Contact Protection

48 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.3.2 Cable Entry Knockouts, Wall-/Pipe-mount Analyzer

The analyzer is supplied with 7 cable glands, one fitted and six to be fitted, as required, by the user – see Fig. 6.7.

Release the four captive

1
screws and remove
the terminal cover plate

Factory-fitted cable gland Cable entry knockouts

Place the blade of a small, flat bladed screwdriver

2
into the knockout groove and tap the
screwdriver smartly to remove the knockout
Secure the cable (see Note below)
gland with the nut 6

Note. When removing knockouts, take

great care not to damage wiring and
components within the analyzer.

Smooth the edges of the hole

3
with a small round or half-round file

4 Fit an 'O' ring seal to the the cable gland

5 Insert the cable gland into the hole in the analyzer case from the outside.
Tighten the gland to a torque of 3.75 Nm (33 lbf. in.)

Fig. 6.7 Cable Entry Knockouts, Wall-/Pipe-mount Analyzer

Note. The cable glands must be tightened to a torque of 3.75 Nm (33 lbf. in.)

IM/AX4PH Rev. P 49
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.4 Wall-/Pipe-mount Analyzer Connections

6.4.1 Access to Terminals

Release the four captive

screws and remove
the terminal cover plate

Terminal Block C
(Option Board)

Case Earth
(Ground) Stud Terminal Block A Terminal Block B

Fig. 6.8 Access to Terminals, Wall-/Pipe-mount Analyzer

Note. When refitting the terminal cover plate, tighten the captive screws to a torque of 0.40 Nm (3.5 lbf. in.)

50 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.4.2 Connections

Earth (Ground) Terminal Block C (Option Board)

Stud on Case
(see Fig. 6.8)

Analog Output 3

Analog Output 4
refer to IM/PROBUS
PROFIBUS DP
connections –
Terminal Block B

Relay 4

Relay 5
Temperature Compensator Temperature Compensator
Not used
Not used

Not used Connections Connections

Third Lead

Third Lead
NO

C12 NO
NC

C11 NC

Common

Common
C14 —

C16 —
C

C10 C

C13 +

C15 +
C1
C2
C3
C4
C5
C6
C7
C8
C9

TC

TC
** L
** N
** E
A4
A5
A6
A7
A8
A9
A10
A11
A12
A13
A14
A15
A16
B16
B15
B14
B13
B12
B11
B10
B9
B8
B7
B6
B5
B4
B3
B2
B1
*
C
NC
NO
C
NC
NO
C
NC
NO
+
—
+
—
Connect supply earth (ground) to stud on case

Refer to Section 6.6 for pH Sensor System

Neutral

Connection Details
Line

Relay 3 (see Note below)

Relay 1

Relay 2

Analog Output 1

Analog Output 2
100 to 240 V AC
+

–
12 to 30V DC

Terminal Block A
Power Supplies

Before making any electrical connections,

see Warnings on page 47

* 250 mA Type T fues (mains AC) or

2 A Type T fuse (DC)

** Ensure polarity is correct before

switching power supply on.

Fig. 6.9 Connections, Wall-/Pipe-mount Analyzer

Note.
 Relay 3 can be configured to control the wash facility – see Section 5.4, page 33.
 Tighten the terminal screws to a torque of 0.60 Nm (5.3 lbf. in.).

IM/AX4PH Rev. P 51
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.5 Panel-mount Analyzer Connections

6.5.1 Access to Terminals

Terminal Block A

Case Earth (Ground) Stud

Terminal Block C
(Option Board) Terminal Block B

Fig. 6.10 Access to Terminals, Panel-mount Analyzers

52 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.5.2 Connections

Terminal block A Terminal Block C Terminal Block B

(Option Board)
* + 12
L** Line Power C1 Not Used Common B1
100 to 240 V AC to
N ** Neutral Supplies C2 Not Used Third Lead B2
– 30V DC
E ** Connect supply earth (ground) to stud on case C3 PROFIBUS DP TC B3
A4 C C4 connections – Temperature Compensator
B4
Connections
refer to IM/PROBUS
A5 NC Relay 1 C5 B5
A6 NO C6 Not Used B6
A7 C C7 C B7
A8 NC Relay 2 C8 NC Relay 4 B8
A9 NO C9 NO Common B9
A10 C C10 C Third Lead B10
A11 NC Relay 3 (see NNNN below) C11 NC Relay 5 TC B11
A12 NO C12 NO Temperature Compensator B12
Connections
A13 + C13 + B13
Analog Output 1 Analog Output 3
A14 — C14 — B14
A15 + C15 + B15
Analog Output 2 Analog Output 4
A16 — C16 — B16

Earth (Ground)
Stud on Case
(see Fig. 6.10)

Before making any electrical connections,

see Warnings on page 47

* 250 mA Type T fues (mains AC) or Refer to Section 6.6 for pH Sensor System
2 A Type T fuse (DC) Connection Details

** Ensure polarity is correct before

switching power supply on.

Fig. 6.11 Connections, Panel-mount Analyzers

Note.
 Relay 3 can be configured to control the wash facility – see Section 5.4, page 33.
 Tighten the terminal screws to a torque of 0.60 Nm (5.3 lbf. in.).

IM/AX4PH Rev. P 53
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.6 pH Sensor Systems Connections

6.6.1 Standard ph Systems Connection – 2867, AP100, AP300, 7650/60, TB5, Non-ABB
When connecting one of these pH systems to the AX400 transmitter, ensure the differential input switch for the relevant sensor
is OFF.

Terminal Block B Function 2867 AP100 AP300

Sensor B Sensor A Color Color Color

Temperature Compensator (if fitted) Common –

B1 B9 Not Used Red White
see also Note 1below

B2 B10 Temperature Compensator (if fitted) 3rd Lead Not Used Red Grey

B3 B11 Temperature Compensator (if fitted) Not Used White Red

B4 B12 Not Used Not Used Not Used Not Used

B5 B13 Not Used Not Used Not Used Not Used

B6 B14 Reference Electrode Black Black Black

B7 B15 Screen/Shield (if fitted) Not Used Not Used Not Used

B8 B16 Glass/Metal Electrode Clear Clear Blue

Table 6.1 Standard ph Systems Connection – 2867, AP100, AP300

Terminal Block B Function *7650/60 TB5 Non-ABB

Sensor B Sensor A Color Color

Temperature Compensator (if fitted) Common –

B1 B9 Red White
see also Note 1below

B2 B10 Temperature Compensator (if fitted) 3rd Lead Red Link to White
Connect as per
B3 B11 Temperature Compensator (if fitted) White Red function –
refer to
B4 B12 Not Used Not Used Not Used (non-ABB)
B5 B13 Not Used Not Used Not Used sensor system
manual for cable
B6 B14 Reference Electrode Black Black colors

B7 B15 Screen/Shield (if fitted) Yellow Not Used

B8 B16 Glass/Metal Electrode Clear Blue

*See Note 2

Table 6.2 Standard ph Systems Connection – 7650/60, TB5, Non-ABB

Note.
1. If the sensor is fitted with a 2-wire PT100, Pt1000 or 3K Balco temperature compensator, link terminals B9 and B10 (and
B1 and B2 if dual input analyzer).
2. Discard large green wire as not required with this transmitter.
3. Redox systems are not temperature compensated so do not have temperature sensors. To remove temperature error
messages, set Temperature Sensor to NONE. If a temperature sensor is used for a separate temperature display, set
Temperature Sensor to the correct type – see Section 5.3, page 30.

54 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 6 Installation

6.6.2 Differential ph Systems Connections – Capable of Providing Sensor Diagnostics (AP200, TBX5)
When connecting one of these pH systems to the AX400 transmitter, ensure the differential input switch for the relevant sensor is ON.
See Section 5.4, page 33 for sensor diagnostics configuration. If diagnostics are not required leave them switched off.

Terminal Block B Function AP200 *TBX5

Sensor B Sensor A Color Color

Temperature Compensator (if fitted) Common –

B1 B9 Grey White
see also Note 1below

B2 B10 Temperature Compensator (if fitted) 3rd Lead White Link to White

B3 B11 Temperature Compensator (if fitted) Green Red

B4 B12 Reference Blue Black

B5 B13 Not Used Not Used Not Used

B6 B14 Solution Earth (Ground Rod) Green/Yellow Green

B7 B15 Screen/Shield (if fitted) Red Yellow

B8 B16 Glass/Metal Electrode Clear Blue

Table 6.3 Differential ph Systems Connection – AP200, TBX5

*In normal operation do not connect the heavy green wire. If noisy readings are obtained, connect the wire to the earth stud.

Note.
1. If the sensor is fitted with a 2-wire PT100, Pt1000 or 3K Balco temperature compensator, link terminals B9 and B10 (and
B1 and B2 if dual input analyzer.).
2. Redox systems are not temperature compensated so do not have temperature sensors. To remove temperature error
messages, set Temperature Sensor to NONE. If a temperature sensor is used for a separate temperature display, set
Temperature Sensor to the correct type – see Section 5.3, page 30.

IM/AX4PH Rev. P 55
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 7 Calibration

7 Calibration
Note.
 The analyzer is calibrated by the Company prior to dispatch and the Factory Settings pages are protected by an access
code.
 Routine recalibration is not necessary – high stability components are used in the analyzer's input circuitry and, once
calibrated, the Analog-to-Digital converter chip self-compensates for zero and span drift. It is therefore unlikely that the
calibration will change over time.
 Do Not attempt recalibration without first contacting ABB.
 Do Not attempt recalibration unless the input board has been replaced or the Factory Calibration tampered with.
 Prior to attempting recalibration, test the analyzer's accuracy using suitably calibrated test equipment – see Section 7.1,
page 56 and see Section 7.2, page 56.

7.1 Equipment Required

1. Millivolt source (pH or Redox input simulator): –1000 to 1000 mV.
2. Decade resistance box (Pt100/Pt1000 temperature input simulator): 0 to 10 k (in increments of 0.01 ), accuracy ±0.1 %.
3. Digital milliammeter (current output measurement): 0 to 20 mA.

Note. Resistance boxes have an inherent residual resistance that may range from a few m up to 1 . This value must be taken
into account when simulating input levels, as should the overall tolerance of the resistors within the boxes.

7.2 Preparation
1. Switch off the supply and disconnect the conductivity cell(s), temperature compensator(s) and current output(s) from the
analyzer's terminal blocks.
2. Sensor A – Fig. 7.1:
a. Link terminals B9 and B10.
b. Connect the millivolt source to terminals B14 (–ve) and B16 (+ve) to simulate the pH or Redox input. Connect the millivolt
source earth to the Case Earth (Ground) Stud – see Fig. 6.8 (wall-/pipe-mount analyzer) or Fig. 6.10 (panel-mount analyzer).
c. Connect the 0 to 10 k decade resistance box to terminals B9 and B11 to simulate the Pt100/Pt1000/Balco 3K.
Sensor B (dual input analyzers only) – Fig. 7.1:
a. Link terminals B1 and B2.
b. Connect the millivolt source to terminals B6 (–ve) and B8 (+ve) to simulate the pH or Redox input. Connect the millivolt source
earth to the Case Earth (Ground) Stud – see Fig. 6.8 or (wall-/pipe-mount analyzer) or Fig. 6.10 (panel-mount analyzer).
c. Connect the 0 to 10 k decade resistance box to terminals B1 and B3 to simulate the Pt100/Pt1000/Balco 3K.
3. Connect the milliammeter to the analog output terminals.
4. Switch on the supply and allow ten minutes for the circuits to stabilize.
5. Select the FACTORY SETTINGS page and carry out Section 7.3.

Terminal link

Sensor A Terminal Numbers B9 B10 B11 B12 B13 B14 B15 B16

Sensor B Terminal Numbers B1 B2 B3 B4 B5 B6 B7 B8

–ve +ve
Temperature pH/Redox
Simulator Input Simulator

Fig. 7.1 Analyzer Terminal Links and Decade Resistance Box Connections

56 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 7 Calibration

7.3 Factory Settings

Use the Sidescroll Key to scroll through the Pages within each Menu

Section 7.3, Page 58

FACTORY SETTINGS Factory Set Code Cal. Sensor A Cal. Sensor B Cal. Output 1
A:mV Zero (-1V) B:mV Zero (-1V) O1: Adjust 4mA
Use the Menu A:mV Span (+1V) B:mV Span (+1V) O1: Adjust 20mA
Key to scroll
through Use the Downscroll A:T.Zero (100R) B:T.Zero (100R)
the Menus Key to scroll through
A:T.Span (150R) B:T.Span (150R)
the Frames
within each Page A:T.Zero (1K0) B:T.Zero (1K0)

A:T.Span (1K5) B:T.Span (1K5)

To OPERATING PAGE
A:T.Zero (2K0) B:T.Zero (2K0)
A:T.Span (5K0) B:T.Span (5K0)

Cal. Output 2 Cal. Output 3 Cal. Output 4 Option Board Alter Fact.Code

O2: Adjust 4mA O3: Adjust 4mA O4: Adjust 4mA

O2: Adjust 20mA O3: Adjust 20mA O4: Adjust 20mA Note. The Option Board page is
displayed only if the option board is fitted.

Key
Available only if the Option Board is fitted
and Analog features enabled – see page 61

Dual input analyzer only

Fig. 7.2 Overall Factory Settings Chart

IM/AX4PH Rev. P 57
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 7 Calibration

-----
FACTORY SETTINGS
Factory Settings Access Code
Enter the required code number (between 0000 and 19999) to gain access to the

0000 factory settings. If an incorrect value is entered, access to subsequent frames is

prevented and the display reverts to the top of the page.
Factory Set Code

Calibrate Sensor A
Note. The values in the display lines for sensor calibration are shown only as

----- examples – the actual values obtained will differ.

Cal. Sensor A

Cal. Sensor B Sensor B calibration (dual input analyzers only) is identical to Sensor A calibration.

Cal. Output 1 Single input analyzers only – see page 61.

Monitoring pH

Monitoring Redox

Dual Redox Operating Page – see Section 2.3, page 6.

pH/Redox

Calibrate Input for Sensor A ?

If calibration is required select Yes otherwise select No.
Yes
----- No Note. To abort calibration, press the
complete – see next page.
key again at any time before calibration is
Calibrate I/P ?
No
Yes

-1000 mV Millivolt Zero

Set the millivolt source to –1000 mV.
-1000 Calib The display advances automatically to the next step once a stable and valid value is
A:mV Zero (-1V) recorded.
Note. The upper 6-segment display shows the measured input voltage. Once the
signal is within range the lower 6-segment display shows the same value and Calib is
displayed to indicate that calibration is in progress.

1000 mV
Millivolt Span
Set the millivolt source to +1000 mV.

1000 Calib The display advances automatically to the next step once a stable and valid value is
recorded.
A:mV Span (+1V)

100.0 Ohms
Temperature Zero (100R)
Set the temperature simulator to 100 
100.0 Calib The display advances automatically to the next step once a stable and valid value is
recorded.
A:T.Zero (100R)

A: T.Zero (1K0) Continued on next page.

58 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 7 Calibration

150.0 Ohms
Temperature Span (150R)
Set the temperature simulator to 150 

150.0 Calib The display advances automatically to the next step once a stable and valid value is
recorded.
A:T.Span (150R)

1000 Ohms
Temperature Zero (1k0)
Set the temperature simulator to 1000 
1000 Calib The display advances automatically to the next step once a stable and valid value is
A:T.Zero (1K0) recorded.

1500
Temperature Span (1k5)
Ohms Set the temperature simulator to 1500 

1500 Calib The display advances automatically to the next step once a stable and valid value is
recorded.
A:T.Span (1K5)

2000 Ohms
Temperature Zero (2k0)
Set the temperature simulator to 2000 

2000 Calib The display advances automatically to the next step once a stable and valid value is
recorded.
A:T.Zero (2K0)

5000 Ohms Temperature Span (5k0)

Set the temperature simulator to 5000 
5000 Calib
A:T.Span (5K0)
The display returns automatically to Cal. Sensor A once a stable and valid value is
Cal. Sensor A recorded.

Abort Calibration

No Select Yes or No
----- Yes
A: Abort Cal.
Yes selected:

A:T.Zero (100R) – before completion of A:mV Span (+1V) frame – calibration advances to A:T.Zero
(100R) and continues.
CAL. SENSOR A – after completion of A:mV Span (+1V) frame – the display returns to the Calibrate
Sensor A page.

No selected – calibration continues from the point at which the key was
pressed.

IM/AX4PH Rev. P 59
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 7 Calibration

Calibrate Output 1
Note. When adjusting the 4 and 20 mA outputs, the display reading is unimportant

-----
and is used only to indicate that the output is changing when the and keys
are pressed.
Cal. Output 1

Cal. Output 2 See below.

Adjust 4mA
Use the and keys to set the milliammeter reading to 4 mA.
16000 Note. The analog output range selected in Configure Outputs (Section 5.6) does not
affect the reading.
O1: Adjust 4mA

Adjust 20mA
Use the and keys to set the milliammeter reading to 20 mA.
7200 Note. The analog output range selected in Configure Outputs (Section 5.6) does not
affect the reading.
O1: Adjust 20mA

Cal. Output 1 Cal. Output 2 See below.

Monitoring pH

Redox (ORP)

Dual Redox Operating Page – see Section 2.3, page 6.

pH/Redox (ORP)

Calibrate Output 2
Note. Output 2 calibration is identical to Output 1 calibration.

-----
Cal. Output 2

Cal. Output 3 Option board fitted and analog features enabled – continued on next page.
Option Board Option board fitted, additional features disabled – continued on next page.
Alter Fact. Code Option board not fitted – continued on next page.

7200
O1: Adjust 20mA

Cal. Output 3 Option board fitted and analog features enabled – continued on next page.
Cal. Output 2
Option Board Option board fitted, additional features disabled – continued on next page.
Alter Fact. Code Option board not fitted – continued on next page.
Monitoring pH

Redox (ORP)

Dual Redox Operating Page – see Section 2.3, page 6.

pH/Redox (ORP)

60 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 7 Calibration

Option Board
Fitted and Analog
Features Enabled
Calibrate Output 3
Note.
-----  Output 3 (and Output 4) calibration is applicable only if the Option board is fitted
and analog features enabled – see below.
Cal. Output 3
 Output 3 calibration is identical to Output 2 calibration.

Calibrate Output 4
Note. Output 4 calibration is identical to Output 3 calibration.

-----
Cal. Output 4

Option Board
Fitted, Additional
Features Disabled
Configure Option Board
Analog
Note.

----- Pb Dp  This frame is displayed only if an option board is fitted.

Option Board  The software detects if an option board is fitted but cannot detect the additional
features available.
 If an option board is fitted, the correct selection must be made below to enable
use of the available features. If an incorrect selection is made, the software
menus and frames associated with that option are displayed in the Operating
and Configuration pages but the features do not work.
Use the and keys to enable the features for the type of option(s) fitted:
Analog – Analog features enabled (comprising two additional
analog outputs, two additional alarm relays, clock and
logbook facility).
Pb Dp – Profibus-DP digital communications features enabled.
Option Board Analog + Pb Dp – Both analog and Profibus-DP features enabled.
Not Fitted

Alter Factory Code

Set the factory settings access code to a value between 0000 and 19999.

0000
Alter Fact. Code

FACTORY SETTINGS Return to main menu.

Monitoring pH

Redox (ORP)

Dual Redox
Operating Page – see Section 2.3, page 6.
pH/Redox (ORP)

IM/AX4PH Rev. P 61
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 8 Simple Fault Finding

8 Simple Fault Finding 8.2 Calibration Fail Message or No Response to

pH/Redox Changes
8.1 Error Messages The majority of problems are associated with the electrodes and
If erroneous or unexpected results are obtained, the fault may cabling. Replace the electrodes as an initial check – refer to the
be indicated in the Operating Page by an error message – see appropriate instruction manual. It is also important that all
Table 8.1. However, some faults may cause problems with program parameters have been entered correctly and have not
analyzer calibration or give discrepancies when compared with been altered inadvertently – see Section 7, page 56.
independent laboratory measurements. If the above checks do not resolve the fault:
Error Message Possible Cause 1. Check that the analyzer responds to a millivolt input.
Connect a pH simulator, such as Model 2410, to the
A: FAULTY Pt100 Temperature compensator/associated transmitter input; +ve to glass and –ve to reference – see
A: FAULTY Pt1000 connections for Sensor A are either open
Section 6.4, page 50 or 6.5. Select the CONFIG. SENSORS
A: FAULTY BALCO circuit or short circuit.
page and set the Probe Type to Redox or ORP. Check that
B: FAULTY Pt100 Temperature compensator/associated the analyzer displays the correct values as set on the
B: FAULTY Pt1000 connections for Sensor B are either open simulator.
B: FAULTY BALCO circuit or short circuit.

Although the calibration has not failed, the Note. A normal laboratory mV source is not suitable
A: CAL LOW SLOPE electrode pair associated with the sensor for use as a pH simulator.
B: CAL LOW SLOPE indicated is becoming fatigued and
replacement is recommended.
Failure to respond to the input indicates a fault with the
The calibration of the sensor indicated has analyzer which must be returned to the Company for
A: PH CAL FAILED failed. Check buffer values and repeat repair. Correct response, but with incorrect readings,
B: PH CAL FAILED buffering. If the fault persists, replace the usually indicates a calibration problem. Recalibrate the
electrodes. analyzer as detailed in Section 7.
Wash Function is set to Off. Set Wash 2. Use the pH simulator to carry out an impedance check on
WASH INHIBITED
Function to On – see Section 2.3.3, page 8. the analyzer, i.e. glass to reference, glass to earth and
A: OUT OF SAMPLE 1. The sensor indicated is not fully immersed reference to earth – refer to simulator manual.
A: BROKEN CABLE in sample. If the analyzer fails this test, check for moisture within the
(alternating display) transmitter and in particular the terminal compartment. It is
2.The cable associated with the sensor
B: OUT OF SAMPLE
indicated may be damaged. vital that all evidence of moisture is removed with the use
B: BROKEN CABLE
(alternating display)
of a hot air drier.
3. Reconnect the electrode cable and connect the simulator
A: BROKEN CABLE The cable associated with the sensor
B: BROKEN CABLE indicated may be damaged.
to the electrode end of the cable. Repeat the procedures
1) and 2) above. If the analyzer fails test 2), check for
A: LOW GLASS IMP.
1. The glass electrode associated with the moisture around the connections and check that the
sensor indicated may be broken. insulation on the inner co-axial conductor is clean and that
A: BROKEN CABLE
(alternating display) 2.The cable associated with the sensor the graphite layer has been removed.
B: LOW GLASS IMP. indicated may be damaged.
B: BROKEN CABLE
3.The connections associated with the
(alternating display)
sensor indicated may be faulty.

The reference electrode associated with the

A: CHECK REF.
sensor indicated may need cleaning or the
B: CHECK REF.
sensor may need replacing.

Table 8.1 Error Messages

62 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 8 Simple Fault Finding

8.3 Checking the Temperature Input

Check the analyzer responds to a temperature input.
Disconnect the Pt100/Pt1000/Balco 3K leads and connect a
suitable resistance box directly to the analyzer inputs – see
Section 6.4, page 50 (wall-/pipe-mount analyzer) or see Section
6.5, page 52 (panel-mount analyzer). Check the analyzer
displays the correct values as set on the resistance box – see
Table 8.2.
Incorrect readings usually indicate an electrical calibration
problem. Re-calibrate the analyzer as detailed in Section 7.

Temperature Input Resistance ()

ºC ºF Pt100 Pt1000 Balco 3K
0 32 100.00 1000.0 2663
10 50 103.90 1039.0 2798
20 68 107.79 1077.9 2933
25 77 109.73 1097.3 3000
30 86 111.67 1116.7 3068
40 104 115.54 1155.4 3203
50 122 119.40 1194.0 3338
60 140 123.24 1232.4 3473
70 158 127.07 1270.7 3608
80 176 130.89 1308.9 3743
90 194 134.70 1347.0 3878
100 212 138.50 1385.0 4013
130.5 267 150.00 1500.0 4424

Table 8.2 Temperature Readings for Resistance Inputs

IM/AX4PH Rev. P 63
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 9 Specification

9 Specification
pH/Redox (ORP) – AX460 and AX466 Conductivity – AX416 Only
Inputs Range
One or two* pH or mV inputs and solution earth Programmable 0 to 0.5 to 0 to 10,000 µS/cm
One or two* temperature sensors (with various cell constants)
Enables connection to glass or enamel pH and reference sensors and Minimum span
Redox (ORP) sensors 10 x cell constant
*AX466 only Maximum span
Input resistance 10,000 x cell constant
Glass >1 x 1013 Units of measure
Reference 1 x 10 
13 µS/cm, µS/m, mS/cm, mS/m, M-cm and TDS

Range Accuracy
–2 to 16 ph or –1200 to +1200 mV Better than ±0.01 % of span (0 to 100 µS/cm)

Minimum span Better than ±1 % of reading (10,1000 µS/cm)

Any 2 ph span or 100 mV Operating temperature range
Resolution –10 to 200 °C (14 to 392 °F)
0.01 pH Temperature compensation
Accuracy –10 to 200 °C (14 to 392 °F)
0.01 pH Temperature coefficient
Temperature compensation modes Programmable 0 to 5 %/°C and fixed temperature compensation
curves (programmable) for acids, neutral salts and ammonia
Automatic or manual Nernstian compensation
Temperature sensor
Range –10 to 200 °C (14 to 392 °F)
Programmable Pt100 or Pt1000
Process solution compensation with configurable coefficient
Reference Temperature
Range –10 to 200 °C (14 to 392 °F)
25 °C (77 °F)
adjustable –0.05 to +0.02 %/°C (–0.02 to +0.009 %/°F)
Temperature sensor
Programmable Pt100, Pt1000 or Balco 3 k Display
Type
Dual 5-digit, 7-segment backlit LCD
Calibration Ranges Information
Check value (zero point) 16-character, single line dot-matrix
0 to 14 pH
Energy-saving function
Slope Backlit LCD configurable as ON or Auto-Off after 60 s
Between 40 and 105 % (low limit user-configurable)
Logbook*
Electronic record of major process events and calibration data
Electrode Calibration Modes Real-time clock*
Calibration with auto-stability checking Records time for logbook and auto-manual functions
Automatic 1 or 2 point calibration selectable from: *Available if option board is fitted
ABB
DIN
Merck
NIST
US Tech
2 x user-defined buffer tables for manual entry,
2-point calibration or single-point process calibration

64 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 9 Specification

Relay Outputs – On/Off Control Function – AX460 Only

Number of relays Controller Type
Three supplied as standard or five with option board fitted P, PI, PID (configurable)
Number of set points Control Outputs
Three supplied as standard or five with option board fitted Output
Set point adjustment Can be assigned a maximum of two relays, two analog outputs, or
Configurable as normal or failsafe high/low or diagnostic alert one of each
Hysteresis of reading Analog
Programmable 0 to 5 % in 0.1 % increments Current output control (0 to 100 %)
Delay Time proportioning cycle time
Programmable 0 to 60 s in 1 s intervals 1.0 to 300.0 s, programmable in increments of 0.1 s
Relay contacts Pulse frequency
Single-pole changeover 1 to 120 pulses per minute, programmable in increments of 1 pulse
per minute
Rating 5 A, 115/230 V AC, 5 A DC
Controller action
Insulation
Reverse, direct or bi-directional (programmable)
2 kV RMS contacts to earth/ground
Proportional band
0.1 to 999.9 %, programmable in increments of 0.1 %
Analog Outputs Integral action time (Integral reset)
Number of current outputs (fully isolated) 1 to 7200 s, programmable in increments of 1 s (0 = Off)
Two supplied as standard or four with option board fitted Derivative
Output ranges 0.1 to 999.9s programmable in increments of 0.1s, available only for
0 to 10 mA, 0 to 20 mA or 4 to 20 mA single set point control
Analog output programmable to any value between 0 and 22 mA to Auto/Manual
indicate system failure User-programmable
Accuracy
±0.25 % FSD, ±0.5 % of reading (whichever is the greater)
Access to Functions
Resolution
Direct keypad access
0.1 % at 10mA, 0.05 % at 20 mA
Measurement, maintenance, configuration, diagnostics and service
Maximum load resistance functions
750 at 20 mA
Performed without external equipment or internal jumpers
Configuration
Can be assigned to either measured variable or either sample
temperature Sensor Cleaning Function
Configurable cleaning action relay contact
Continuous
Digital Communications
Pulse in 1 s on and off times
Communications
Profibus-DP (with option board fitted) Frequency
5 minutes to 24 hours, programmable in 15 minute increments up to
1 hour then in 1 hour increments for 1 to 24 hours
Duration
15 s to 10 minutes, programmable in 15 s increments up to 1 minute
then in 1 minute increments up to 10 minutes
Recovery period
30 s to 5 minutes, programmable in 30 s increments

IM/AX4PH Rev. P 65
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 9 Specification

Mechanical Data Environmental Data

Wall-/Pipe-mount versions Operating temperature limits
IP65 (not evaluated under UL certification) –20 to 55 °C (–4 to 131 °F)
Dimensions 192 mm high x 230 mm wide x 94 mm deep Storage temperature limits
(7.56 in. high x 9.06 in. wide x 3.7 in. deep) –25 to 75 °C (–13 to 167 °F)
Weight 1 kg (2.2 lb) Operating humidity limits
Panel-mount versions Up to 95 %RH non condensing
IP65 (front only)
Dimensions 96mm x 96mm x 162mm deep EMC
(3.78 in. x 3.78 in. x 6.38 in. deep)
Emissions and immunity
Weight 0.6kg (1.32 lb) Meets requirements of:
Cable Entry Types EN61326 (for an industrial environment)
Standard 5 or 7 x M20 cable glands EN50081-2
North American 1
7 x knockouts suitable for /2 in. Hubble gland EN50082-2

Approvals, Certification and Safety

Power Supply Safety approval
Voltage requirements UL
100 to 240 V AC 50/60 Hz
CE Mark
(90 V Min. to 264 V Max. AC)
Covers EMC & LV Directives (including latest version EN 61010)
12 to 30 V DC
General safety
Power consumption
EN61010-1
10 W
Overvoltage Class II on inputs and outputs
Insulation
Pollution category 2
Mains to earth (line to ground) 2 kV RMS

Languages
Languages configurable:
English
French
German
Italian
Spanish

DS/AX4PH–EN Rev. K

66 IM/AX4PH Rev. P
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 Appendix A – Buffer Solutions

Appendix A – Buffer Solutions Temp DIN 19266 Buffers

The pH value of buffer solutions is influenced considerably by ºC ºF 1.68 pH 4.01 pH 6.86 pH 9.18 pH
temperature variations. Thus, when significant temperature 0 32 1.666 4.003 6.984 9.464
fluctuations occur, it is general practice to correct automatically 5 41 1.668 3.999 6.951 9.395
the measured, prevailing pH to the value that would apply if the
10 50 1.670 3.998 6.923 9.332
solution temperature were 25 ºC (77 ºF), the internationally
accepted standard. 15 59 1.672 3.999 6.900 9.276

Tables A1 to A5 include the pH values for ABB, DIN, Merck, 20 68 1.675 4.002 6.881 9.225
NIST, and US Technical buffer solutions. Standards are for 4, 7 25 77 1.679 4.008 6.865 9.180
and 9 pH values, from 0 to 95 ºC (32 to 203 ºF). 30 86 1.683 4.015 6.853 9.139

Temp ABB Buffers 35 95 1.688 4.024 6.844 9.102

ºC ºF 4.01 pH 7 pH 9.18 pH 40 104 1.694 4.035 6.838 9.068

0 32 4.000 7.110 9.475 45 113 1.700 4.047 6.834 9.038

5 41 3.998 9.409 50 122 1.707 4.060 6.833 9.011

10 50 3.997 7.060 9.347 55 131 1.715 4.075 6.834 8.985

15 59 3.998 9.288 60 140 1.723 4.091 6.836 8.962

20 68 4.001 7.010 9.233 65 149

25 77 4.005 7.000 9.182 70 158 1.743 4.126 6.845 8.921

30 86 4.011 6.980 9.134 75 167

35 95 4.018 9.091 80 176 1.766 4.164 6.859 8.885

40 104 4.027 6.970 9.051 85 185

45 113 4.038 9.015 90 194 1.792 4.205 6.877 8.850

50 122 4.050 6.970 8.983 95 203 1.806 4.227 6.886 8.833

55 131 4.064 8.956 Table A.2 DIN Buffer Solutions

60 140 4.080 6.970 8.932
65 149 4.097 8.913 Temp Merck Buffers
70 158 4.116 6.990 8.898 ºC ºF 4 pH 7 pH 9 pH 10 pH
75 167 4.137 8.888 0 32 4.05 7.13 9.24 10.26
80 176 4.159 7.030 8.882 5 41 4.04 7.07 9.16 10.17
85 185 4.183 8.880 10 50 4.02 7.05 9.11 10.11
90 194 4.208 7.080 8.884 15 59 4.01 7.02 9.05 10.05
95 203 4.235 8.892 20 68 4.00 7.00 9.00 10.00
Table A.1 ABB Buffer Solutions 25 77 4.01 6.98 8.95 8.95
30 86 4.01 6.98 8.91 9.89
35 95 4.01 6.96 8.88 9.84
40 104 4.01 6.95 8.85 9.82
45 113 4.01 6.95 8.82
50 122 4.00 6.95 8.79 9.74
55 131 4.00 6.95 8.76
60 140 4.00 6.96 8.73 9.67
65 149 4.00 6.96 8.72
70 158 4.00 6.96 8.70 9.62
75 167 4.00 6.96 8.68
80 176 4.00 6.97 8.66 9.55
85 185 4.00 6.98 8.65
90 194 4.00 7.00 8.64 9.49
95 203 4.00 7.02 8.64 8.833

Table A.3 Merck Buffer Solutions

IM/AX4PH Rev. P 67
Single and dual input analyzers for pH/Redox (ORP)
AX416, AX436, AX460, AX466 & AX468 Appendix A – Buffer Solutions

Temp NIST Buffers Temp US Technical Buffers

ºC ºF 4.01 pH 6.86 pH 9.18 pH ºC ºF 4.01 pH 7 pH 10.01 pH
0 32 4.003 6.982 9.460 0 32 4.000 7.118 10.317
5 41 3.998 6.949 9.392 5 41 3.998 7.087 10.245
10 50 3.996 6.921 9.331 10 50 3.997 7.059 10.179
15 59 3.996 6.898 9.276 15 59 3.998 7.036 10.118
20 68 3.999 6.878 9.227 20 68 4.001 7.016 10.062
25 77 4.004 6.863 9.183 25 77 4.005 7.000 10.012
30 86 4.011 6.851 9.143 30 86 4.011 6.987 9.966
35 95 4.020 6.842 9.107 35 95 4.018 6.977 9.925
40 104 4.030 6.836 9.074 40 104 4.027 6.970 9.889
45 113 4.042 6.832 9.044 45 113 4.038 6.965 9.857
50 122 4.055 6.831 9.017 50 122 4.050 6.964 9.828
55 131 4.070 55 131 4.064 6.965
60 140 4.085 60 140 4.080 6.968
65 149 65 149 4.097 6.974
70 158 4.120 70 158 4.116 6.982
75 167 75 167 4.137 6.992
80 176 4.160 80 176 4.159 7.004
85 185 85 185 4.183 7.018
90 194 4.190 90 194 4.208 7.034
95 203 4.210 95 203 4.235 7.052

Table A.4 NIST Buffer Solutions Table A.5 US Technical Buffer Solutions

68 IM/AX4PH Rev. P
Acknowledgments
PROFIBUS is a registered trademark of PROFIBUS and
PROFINET International (PI).

Sales Service
—
ABB Limited
Measurement & Analytics
Oldends Lane
Stonehouse
Gloucestershire
GL10 3TA
UK
Tel: +44 (0)1453 826 661
Fax: +44 (0)1453 829 671
Email: [email protected]

ABB Inc.
Measurement & Analytics
125 E County Line Road
Warminster
PA 18974
USA
Tel: +1 215 674 6000
Fax: +1 215 674 7183

abb.com/analytical

—
We reserve the right to make technical changes or modify the contents of this document
12.2018

without prior notice. With regard to purchase orders, the agreed particulars shall prevail.
ABB does not accept any responsibility whatsoever for potential errors or possible lack of
information in this document.
IM/AX4PH Rev. P

We reserve all rights in this document and in the subject matter and illustrations contained
therein. Any reproduction, disclosure to third parties or utilization of its contents – in
whole or in parts – is forbidden without prior written consent of ABB.

© ABB 2018