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Qpt3 Solution

The document presents a series of physics problems and their solutions, covering topics such as escape velocity, angular momentum, gravitational forces, and motion. Each problem is followed by a detailed solution that includes relevant equations and calculations. The answers are provided in a structured format, indicating the correct choice for each question.

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0% found this document useful (0 votes)
12 views20 pages

Qpt3 Solution

The document presents a series of physics problems and their solutions, covering topics such as escape velocity, angular momentum, gravitational forces, and motion. Each problem is followed by a detailed solution that includes relevant equations and calculations. The answers are provided in a structured format, indicating the correct choice for each question.

Uploaded by

shivagame334
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
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QPT-3 Solution

1. Ans: (c) h = 7R

Solution:
−−−−
The equation for escape velocity is ve = √
2GM

R
… (1)

If satellite is moving in a circular orbit then, Gravitational force = Centripetal force


2
GM m mv
2
=
R+h
(R+h)

−−−−−
GM
v = √
(R+h)

It is given that,
1
vc =
4
ve s
as
−−−−− −−−−
t

GM 1 2GM
= √
ha

√ 4 R
(R+h)

On taking square on both sides, we get,


pt
ra

GM 1 2GM
=
w

R+h 16 R
u/

GM GM
=
R+h 8R

R + h = 8R

h = 8R − R

h = 7R

2. Ans: (b)
K

Solution: According to the principle of conservation of angular momentum, I ω = constant


As I is doubled, ω becomes half
Now K.E. of rotation, K = 12 I ω2
Since I is doubled and ω is halved, K.E. will become half i.e. K

2
.

3. Ans: (a) (− R

50
,
21R

80
)

Solution: Let, M 2 = M , M 1 = 4M

R
4M (O) − M ( )
10

x cm =
4M + M

R
⇒ x cm = −
50

3R 3R
4M ( ) − M( )
8 16

ycm =
4M + M

21R
⇒ y =
cm
80
4. Ans: (a) work done by force F when the center moves a distance S is 2F S

Solution:

When the centre moves a distance S , the topmost point displaces by 2S. The work done is by the force is

W = 2F S

5. Ans: (c) 3 km s−1

Solution:
GM G 4 4
3
g = = πR ρ = πGRρ i.e. g ∝ Rρ
2 2
R R 3 3

gP √6g √6 ρE 3 gP RP ρ P
E
= = and = and =
gE 11gE 11 ρ 2 gE RE ρ
P E

RP gP ρ E √6 3

s
∴ = = ×
as
RE gE ρ P 11 2

−−−
at
∴ Escape velocity v = √ 2gR
h

− −−−−−−− −−−−−−−−−−−−
pt

vP gP RP √6 √6 3 3
∴ = √ × = √ × × =
ra

vE gE RE 11 11 2 11
w

3 3
−1
u/

∴ vP = × vE = × 11 = 3 km s
11 11

6. Ans: (c) Speed of all the particles lying on the curved surface of a cylinder whose axis coincides with the axis of rotation is same

Solution: All points in the body, in plane perpendicular to the axis of rotation revolve in connection circles. All points lying on circle of
same radius have same speed (and also same magnitude of acceleration) but different directions of velocity (also different directions of
acceleration). Hence there cannot be two points in the given plane with same velocity or with same acceleration. As mentioned above,
points lying on circle of same radius have same speed.
Angular speed of body at any instant w.r.t. any point on body is same by definition.

7. Ans: (a) If both assertion and reason are true and reason is the correct explanation of assertion.
2
mr ω L
∴ = = constant
Solution: According to Kepler's law, dA

dt
= constant As, dA

dt
=
1

2
2
r

dt
=
1

2
2
r ω 2m 2m

∴ L = constant
s
as

mg sin θ
8. Ans: (c)
at

2
h

Solution: Minimum force is required when this force is applied perpendicular to the rod balancing torque about the hinge
pt

l
mg sin θ = F l
2
ra

mg sin θ
⇒ F =
w

2
u/

2 2

9. Ans: (c) ω R

2g

Solution: The value of acceleration due to gravity at the equator is gE = g − Rω


2
and the acceleration due to gravity at a height h
above the pole is gh = (1 −
2h

R
)g. It is given that
∵ mg = mg
E h
∴ gE = gh

∴ gE = gh

2h 2hg
2
∴ g − Rω = (1 − )g = g −
R R

2 2
2hg R ω
2
∴ Rω = ∴ h =
R 2g
10. Ans: (b) −0.2 kg msec−1

dx 4
v = = = 2 m/s
dt 2

velocity between t = 0sec to t = 2sec = 2 m/s

Solution:
velocity at 2sec = 0 m/s

Impulse = change in linear momentum

−1
= m(Vf − Vi ) = 0.1(0 − 2) = −0.2kgms

2
4 √ 2 Gm
11. Ans: (c) r

Solution: Wext = ΔV × m = [Vf − V0 ]m

Gm
= [0 − 4(− )] × m
r/√2

2
4 √ 2 Gm
Wext =
r
.

12. Ans: (b) 0.2 m

Solution: Let v′ = common speed momentum conservation gives


v
′ ′
m2 v = (m1 + m2 )v ∴ v =
2

force
Acc = a =
mass

μ(m1 + m2 )g
a = −
m1 + m2 ,
2 2
a = −μg ∵ v = u + 2as

′ 2 ′ − −− −−−−− −−−−− − −1 −1
⇒ 0 = (v ) − 2μg(4) ⇒ v = √ 8μg = √8 × 0.05 × 10 ms = 2 ms

2
v − −−− v 16
′ −1
∴ v = 2v = 4 ms Also, = √ 2gH , H = = = 0.2 m
2 8g 80

13. Ans: (a) Assertion is true, reason is true; reason is a correct explanation for assertion.

Solution: For the satellite revolving around the earth, the gravitational force is balanced with centripetal force, hence even though there
is no fuel in the satellite still it revolves because of the force balance of gravitational force and centripetal force between satellite and
earth. ,

14. Ans: (b) 5 s


s

Solution: Given, MI = 2.5 kgm


−2
as

−1
W = 40 rad s
T = 10 Nm
at

As T = Iα
th

10 = 2.5α
−2
α = 4 rad s
p

Now, ω = ω 0 + αt
ra

60 = 40 + 4 × t
w

20 = 4t
t = 5 s ;

15. Ans: (a)


5a 5 b
,
12 12
Solution: If the total mass of object mass ' M ' then the mass removed part will be M

4
.

a M 3a Ma 3Mb
M⋅ − ( ) −
2 4 4 2 16 5
XCM = = = a
M 3M
12
M−
4 4

b M 3 b Mb 3Ma
M⋅ − ( ) −
5
!
2 4 4 2 10
YCM = = = b
M 3M
12
M−
4 4

16. Ans: (b) 8

3
πρGmh

Solution: As with height g varies as

and in accord with the figure h1 > h2 so W1 will be lesser than W2 and
h1 h2
W2 − W1 = mg − mg = 2mg[ − ]
2 1 R R

or W2 − W1 = 2m
GM
2
h

R
R

GM
[as g = 2
and (h1 − h2 ) = h]
R

2mhG
or W2 − W1 = 3
(
4

3
πR ρ)
3

=
8

3
πρGmh [as M =
4

3
πR ρ]
3
^

2 g
17. Ans: (a) 3

Solution:

mg − T = ma .....(1)
T ⋅ R = 1/2 mR
2 a

R
....(2)

2 g
= a
3

18. Ans: (d) If both assertion and reason are false.

Solution: First, let ius look at them as two independent statements. During collision, there is deformity of shape of balls leading to
increase in potential energy of the body, thus decreasing the kinetic energy momentarily. (Total energy remains constant, not KE) Thus,
assertion is false. Energy spent against friction should be considered when calculating total energy. Law of conservation of energy always
applies, in every case. Only note is to identify the forms of energy. Reason is also false. !

19. Ans: (a) 2.33 m s−2

Solution: Free body diagram of the cylinder w.r.t. the inclined plane. The torque about the point of contact 0.
3 a
(r = radius of circle, R = 6 m)
2 2
(mg sin θ − mrω )R = I ⋅ α = mR ×
2 R

2
3
∴ mgsin θ − mrω = ma
2
s

2 2 1 1
as

2 −2
∴ a = ( g sin θ − rω ) = [10 × − 6 × ] = 2.33 m s
3 3 2 4
t
ha
pt
ra
w
u/
s
as

20. Ans: (d) 0.9 cm right and 2.0 cm above 1 kg mass.

Solution:

Take 1 kg mass at origin

1×0+1.5×3+2.5×0
Xcm = = 0.9 cm
5
1×0+1.5×0+2.5×4
Ycm = = 2 cm
5

21. Ans: 16
as Solution: The energy corresponding to escape speed is
1 1 GM
at
E = m(2gR) = m(2 R)
2
2 2 R

1 GM GMm
= m(2 ) =
2 R R

Ve = 64 V m

4 4
3 3
⇒ πR e = × π × R m × 64
3 3

⇒ R c = 4R m

∵ ρ = ρ
c m

Me Mm
=
Ve Vm

Me Mm
⇒ =
64 V m Vm

⇒ Mc = 64Mm

Em Mm Re
So = ×
Ee Rm Me

1 1
= × 4 = ⋯ … [∵ R e = 4R m ]
64 16

E
Em =

ss
16

ta
22. Ans: 4 ha
Solution: For translation, N − fs = ma for rotation (fs − fk )R = I α and a = Rα .
pt

Solving, fk = 0.8 N; fs = 1.4 N


ra

P f
k
⇒ μ = =
w

10 2 N
u/

P 0.8
⇒ =
10 2

⇒ P = 4

23. Ans: 6

Solution:
T πab 1
t = ( + abe)
πab 4 2

1 e
t = T( + )
4 2π

1 1
t = 16( + )
4 8

t = 6 months
24. Ans: 50

Solution:
2 2
4mR 2 m R m 2
IP = [ + m(4R )] − [ + 5R ]
2 4 2 4

2 1 5
I P = mR [(2 + 4) − ( + )]
8 4

2 11 37 2
I P = mR (6 − ) = mR … (1)
8 8

2 2
4mR m R m 2
IO = ( ) − ( + R )
2 4 2 4

2 1 1 2 3 2 13
I O = mR [2 − ( + )] = mR [2 − ] = mR ( ) … (2)
8 4 8 8

IP 37/8 37
So = =
IO 13/8 13

⇒ m + n = 37 + 13 = 50

25. Ans: 35
s


Solution: Applying conservation of linear momentum at the time of the collision, or at t
as

= 1 s, m v + m(0) = 2 m(20 î + 10 ĵ )

ˆ ˆ
∴ v⃗ = 40 i + 20 j
t
ha

1 1 2
At 1sec, masses will be at height : h1 = uy t +
2
vy t
2
= (20)(1) +
2
(−10)(1) = 15 m
pt

2 2
uy (20)
After explosion other mass will further rise to a height: h2 =
2 g
=
2×10
= 20 m :
ra

uy = 20 m/s just after the collision.


/w

∴ Total height h = h1 + h2 = 35 m

26. Ans: 4

Solution:

Loss of KE = Gain in PE

1 2 R
⇒ mv = mgh( )
2 h+R

CASE I.
2gR

1

2
m(
3
) = mgh1 (
R

h1 +R
) ...(i)

4gR

1

2
m(
3
) = mgh2 (
R
) ...(ii)
h 2 +R

Solving (i)
1 h1
⇒ =
3 h 1 +R

R
⇒ h1 =
2
...(iii)
Solving (ii)
h2

2

3
=
h 2 +R
...(iv)

⇒ h2 = 2R

From (iii) and (iv)


h1 R/2
⇒ =
h2 2R

h2
= 4
h1

27. Ans: 32


L = ICM ⋅ ω + mvCM R

v 2
−1
ω = = = 0.5rads
R 4
Solution:
⃗ 2
L = mR ⋅ ω + mvCM ⋅ R

= 2 × 16 × 0.5 + 2 × 2 × 4 = 16 + 16

⃗ 2 −1
L = 32 kg m s

28. Ans: 24
−3 −1
= 20 × 10 × 300 = 6 kg m s

N = number of bullet per sec = 4

dp
Solution: Momentum of one bullet, p = mv
∴ = change of momentum per sec or force
dt

= N (p − 0) = 4 × 6 = 24 N

29. Ans: 4

Solution: Acceleration due to gravity is g =


GM
2
R
2

and if L be the angular momentum of the earth, then rotational KE =


L

where, I be the moment of inertia.
2l

So, I =
2


MR
2
(for sphere) I =
2

5
MR
2

2
5L
∴ Rotational KE =
2
4M R

Since, angular momentum remains conserved.


So, rotational KE(K) ∝ 1 2
R

∴ Both g and K are ∝ R


−2
.
Δg ΔK ΔR
∴ = = −2 ×
g K R

∴ Both g and K would decrease by


2 × 2% = 4%

30. Ans: 4

Solution:
Suppose the masses m1 and m2 are attached to the ends of a massless rod. C1 is the axis of rotation which is at a distance R from each
of the masses. ∴ the moment of inertia of the system, I = m1 R2 + m2 R2 = (m1 + m2 )R2 Now if the distance between the
2 2 2
masses is doubled, then the moment of inertia Γ = m1 (2R) + m2 (2R) = (m1 + m2 )4R Since the same torque is applied in
′ ′
τ = Iα = I α
2
both the cases, ′
Iα (m1 + m2 )R α α
⇒ α = = =
′ 2
I (m1 + m2 )4R 4

31. Ans: (a) 0. 02

2−
Solution: Ksp 1
= [Ba
2+
][SO4 ]

2+ 2−
Ksp = [Ba ][CO3 ]
2

2−
Ksp SO 4 −10
1 1×10
= 2−
= −9
= 0.02
Ksp CO 3 5×10
2

32. Ans: (c) The volume on the reaction mixture was decreased

Solution: Volume of the vessel was decreased, which led to sudden increase in [H2 ]. The reaction then moves in direction to achieve a
state of new equilibrium.
A catalyst does not affect the equilibrium concentration of reactants and products.
Increase in pressure would decrease concentration as reaction favoured forward.
P 4 ( s) will have no effect on kp and concentration of H2 ( g) ( because active mass of solid is taken to be unit)

33. Ans: (d) -48

N2 O4(g) + 3CO(g) ⟶ N2 O(g) + 3CO2( g)

Solution: ΔHreaction = ΣHeat of formation of products

−ΣHeat of formation of reactants

ΔHreaction = [ΔHf N 2 O + 3 × ΔHf CO2 ] −

[ΔHf N 2 O4 + 3 × ΔHf CO]

ΔHr = [+811 + 3(−393)] − [10 + 3(−110)]

= [811 − 1179] − [−320] = −368 + 320

= −48 kJ/mol

34. Ans: (a) 12

Solution: 40 mL of 0.1MHCl = 1000 0.1


× 40

= 0.004 mole

10 mL of 0.45MNaOH = × 10 = 0.0045 mole


0.45

1000

∴ NaOH left unused = 0.0005 mole


Volume of solution = 50 mL
0.0005
∴ Molarity of NaOH = × 1000
50

= 0.01M
− +
Or [OH ] = 10
−2
or [H ] = 10
−12
pH = 12

35. Ans: (a) a → r, s; b → p, s; c → r, s; d → q

Solution:

(a → r)

Enthalpy is a state function and this is a function of internal energy, pressure and volume.

(b → p)

Temperature is independent of bulk matter of the system.

Hence, it is an intrinsic property but it is a state variable.

(c → r)

Free energy is a state function as it depends on the state of the system as well as H,T and S.

It is also a function of U, P and V.

(d → q)

Work is a path function as the amount of work done depends upon the path undertaken.
36. Ans: (b) 11.3

Solution: pH = 2, [HCl] = 10−2 (M) & pOH = 2


−2
or [NaOH] = 10 (M)
4ml of 10 moles HCl.
−2 −5
(M)HCl ≡ 4 × 10

6ml of 10 moles NaOH


−2 −5
(M)NaOH ≡ 6 × 10

After mixing total moles of OH = moles of NaOH − moles of HCl = 6 × 10 − 4 × 10


− −5 −5

After mixing excess moles of OH = 2 × 10 Total volume = 6 + 4 = 10ml = 10 × 10 litre


− −5 −3
ss

−5
− 2×10 3 −3
[OH ] = × 10 = 2 × 10
10

or pOH = 3 − log 2
ta

= 3 − 0.3 = 2.7

or pH = 11.3
ha

37. Ans: (c) 0.7 atm

Solution: 2AB(s) ⇌ A2 ( g) + B2 ( g)

(0.5 + p )p
0 0

Kp = pA × pB
2 2

0.06 = (0.5 + p0 )p0


2
p + 0.5p0 − 0.06 = 0
0

p0 = 0.1

ptotal = pA + p = (0.5 + p ) + p
2 B 2 0 0

= 0.6 + 0.1 = 0.7 atm

38. Ans: (b) −74.8 kJ mol


−1

Solution: For reaction


CO2 (g)+2H O(l) → CH4 (g)+2O (g)
2 2
o o o
Δr H = Σ(Δf H ) − Σ(Δf H )
products reactants
o o o
= [(Δr H (CH4 ) + 2 × 0) − (Δf H (CO2 ) + 2Δf H (H2 O ))]
o
+890.3 = [Δf H (CH4 )] − [−393.5 + 2 × (−285.8)]

Δf H
o
of CH4 (g) = −74.8 kJ/mol

39. Ans: (a) 8.5 × 10−5 M

2+ 2−
Solution: Ksp (SrCrO4 ) = [Sr ][CrO
4
]

−6
2− 7×10 −5
[CrO4 ] = = 7 × 10
0.1

2+ 2−
Ksp (BaCrO 4 ) = [Ba ][CrO4 ]

2− 2−
[CrO
4
] ≈ [CrO
4
] from SrCrO4
total

2+ K sp (BaCrO4 )
[Ba ] =
2−
[CrO ]
4

−9
2+ 6×10 −4
[Ba ] = = 0.85 × 10
−5
7×0
−5
= 8.5 × 10 M

40. Ans: (a) N2 ( g) + 3H2 ( g) → 2NH3 ( g)

Solution: Entropy is the measure of randomness. As the randomness (disorder) increases, entropy increases, The order of entropy is
Solid < Liquid < Gas
prderticles (most disordered)

Thus, in reaction N2 ( g) + 3H2 ( g) → 2NH3 ( g)


Entropy decreases because number of gaseous molecules decreases.

41. Ans: (a) 0. 120

Solution: This problem is based on the concept of degree of dissociation and equilibrium constant. It is advisable to follow the given
steps to solve the question.
Write the decomposition reaction then calculaate total pressure at equilibrium in terms of degree of dissociation (α).
Then, calculate pressure of NO2 (pNO ) using value of Kp and p. 2

Then after calculate degree of dissociation (α).


Given reaction is
N2 O ⇌ 2NO2

At eqbuilibrium 1 − α 2α

Let α = degree of dissociation, p = total pressure


Total number of moles = 2α + 1 − α = 1 + α
1−α
∴ pNO = ( ) ⋅ p
2 1+α

⎡ ( ) ⎤
1−α

p
[p ] ⎣ (1+α)
⎦ 2 2
NO
2 4α p 1+α
= = 1−α
= ×
pNO 1+α (1−α) p
2
1+α

2
4α p
= 2
1−α

Putting values of Kp and p, we get


2
4α ( 2)
0.120 = 2
1−α
2

= 2
1−α
2 2
0.120 (1 − α ) = 8α

1/2
0.120
α = ( ) = 0.120
8.12

Hence, 0. 120 is the choice.

42. Ans: (b) Change in internal energy is same in all the four cases

Solution: As work done = area under p − V curve, work done is maximum in case I Change in internal energy is independent of the
path from A to B. Therefore, in all cases change in internal energy is same.

43. Ans: (d) 1 : 10

Solution: Given, that pH = 5.74, pKa = 4.74


Suppose that volume of acid solution = xL Volume of salt solution = yL

From Henderson equation,


[Salt]
pH = pKa + log
[Acid]

[CH COONa]
or, pH − pKa
3
= log
[CH3 COOH]

[CH3 COONa]
or, 5.74 − 4.74 = 1 = log
[CH3 COOH]

ss
CH3 COONa]
or = 10
[CH3 COOH] ta
x+y

[CH COOH]
1 0.1y

or
3
ha
= =
[CH3 COONa] 10 x+y
pt

Thus, x

y
=
1

10
ra

44. Ans: (d) I, II and III are the same


w
u/

Solution: As Internal energy change is a state function so it depends only on the initial and final temperature and does not depends on
the path taken.

45. Ans: (a) ClO



s

Solution: HClO4 is the strongest acid among HClO, HClO2 , HClO3 and HClO4 as more the number of oxygen atoms attached,
as

more is the acidity of the molecule order of acidity is : HClO < HClO2 < HClO3 < HClO4 So the conjugate base order will be
− − − −
just the reverse: ClO > ClO2 > ClO3 > ClO4
t
ha

46. Ans: (d) All


pt
ra

Solution: Here all the given statements are true. The entropy of isolated system with P-V work only, is always maximized at equilibrium.
It is possible for the entropy of closed system to decrease substantialy in an irreversible process. By second law of thermodynamics it can
w

be said that entropy can be created but not destroyed. ΔSsystem is zero for reversible process in an isolated system.
u/

47. Ans: (d) If both Assertion and Reason are false statements, then mark (4).

Solution: Value of equilibrium constant does not depend on concentration of reactants or products.

48. Ans: (d) 0.05M KClO4 + 0.05M HClO4

Solution: Buffer solutions can be obtained by mixing a weak acid with its salt formed with a strong base or by mixing a weak base with
its salt formed with a strong acid. As HClO4 is a strong acid, therefore equimolar mixture of HClO4 and its salt KClO4 is not a
buffer solution.

49. Ans: (d) 750 K

Solution: 1

2
X2 +
3

2
Y2 ⟶ XY3
∘ ∘ ∘
ΔSreaction = ΔSproducts − ΔSreactants
∘ ∘ 1 ∘ 3 ∘
∴ ΔSreaction = ΔSXY − ΔSX − ΔSY
3 2 2 2 2
1 3 −1
= 50 − × 60 − × 40 = −40 JK
2 2

Using equation, ΔG = ΔH − TΔS


We have, ΔH = −30 kJ, ΔS = −40 JK−1 mol
−1

and at equilibrium, ∆G = 0. Therefore,


ΔH −30×1000
T = = = 750 K
ΔS −40

50. Ans: (c)

∘ ∘
ΔH ΔS
Solution: InK = −
R
(
1

T
) +
R

At high temperature if shifted backward, it is exothermic reaction.


ΔHreac is -ve
o

Slope is +ve

51. Ans: 8

Solution: Ka (C6 H5 COOH) = 1 × 10


−4
s

pH of 0.01M C6 H5 COONa
as

2
Kw 0.01 h
Kh = =
Ka 1−h
t

−14 −2 2
ha

10 10 h
= (1 − h 1)
−4
10 1−h
− −4 −6
[OH ] = 0.01 h = 0.01 × 10 = 10
+ −8
[H ] = 10 pH = 8

52. Ans: 2
s

Δn
Solution: Kp = Kc (RT)
as

No. of gaseous No. of gaseous


t

Δn = { } − { }
ha

moles of products moles of reactants


= x
pt

x 2
Kp = Kc (RT) = Kc (RT)
ra

∴ x = 2
w

53. Ans: 1250

Solution: Cp = q/T;
Heat required = No. of moles ×Cp × T

= (144 × 25 × 10)/(14.4 × 2) = 1250 J

54. Ans: 4
[salt⌋
Solution: pOH = pKb + log
[ base ]

−10
= − log 10 + log 1 = 10; pH = 14 − 10 = 4

55. Ans: 60
50
Solution: Number of moles of CaCO3 present initially = 100
= 0.5 moles Kp of the given reaction can be written as:
PCO V
Number of moles of CO2 1.64×10
Number of moles of CaCO3 reacted =
2
Kp = P CO 2 = 1.64 atm = = = 0.2 0.2
RT 0.082×1000
0.3
moles Number of moles of CaCO3 unreacted = (0.5 − 0.2) = 0.3 moles Percentage of CaCO3 unreacted = 0.5
× 100 = 60%

56. Ans: 8
Q = 0 (∵ process is adiabatic. )

ΔU = w = −Pext ΔV
Solution:
= −1(10 − 2) atm L = −8 atm L

57. Ans: 230

Solution:

Given reaction:

3CaO + Al → Al2 O3 + 3Ca

º º
Now, Δr H° = ΣΔf H
Products
− ΣΔf H
Reactants

= [1 × (−1675) + 3 × 0] − [3 × (−635) + 2 × 0]

−1
= +230 kJ mol

58. Ans: 9
0.1
Solution: 0.1 × 1 = (1 + v) × 0.01 ⇒ 1 + v =
0.01

⇒ 1 + v = 10 ⇒ v = 10 − 1 = 9L

59. Ans: 37

Solution:

Amount of CO2 in one liter of solution = 4. 4 . = 0. 1 Mole

pH = 1/2{pKa − logC}

For a weak acid solution

pH = 1/2{6. 4 + 1} = 3. 7

60. Ans: 815

Solution: 2C(s) + H2 ( g) ⟶ C2 H2 ( g)(H − C ≡ C − H)

⇒ B ⋅ E(H2 ) + ΔB ⋅ E(H2 ) + ΔHsub (C) − B ⋅ E(C − H) × 2 + B ⋅ E(C ≡ C)ΔHrxn

⇒ 330 + 1410 − [350 × 2 + x] = 225 ⇒ x = 815

61. Ans: (b)


9!

2! 4!

C I N O R S U
Solution:
1 2 2 1 1 1 1
9!
Total number of arrangements = 2!2!
The number of ways, vowels in these words are arranged
4!
=
2!

I O U
( )
2 1 1

But the vowels are restricted to have only one arrangement i.e. IIOU
9!/2!2!
⇒ Total number of possible arrangement of the letters of the word INCURSION = =
9!

2!4!
4!/2!

62. Ans: (d) 1140

Solution:

The number of solutions (positive integer) of x + y + z = r is r−1 C 2


∴ The desired number of solutions is
20 r−1
∑ C2
r=3

2 3 4 19
C2 + C2 + C 2 + .... + C2

3 3 4 19
= ( C + C ) + C + .... + C
3 2 2 2

4 4 18 19
= C + C + ... + C + C
3 2 2 2
=
20
C3 (Adding in the same way)

20×19× 18 3
= = 1140
3 × 2

63. Ans: (c) (cot2, 0)

Solution:

cos
−1
x > cos
−1
x
2
⇒ x < x
2
&x ∈ [−1, 1]

{ ∵ cos−1 x is a decreasing function}

⇒ x(x– 1) > 0 &x ∈ [−1,1]

⇒ x ∈ (−∞, 0) ∪ [1, ∞) &x ∈ [−1, 1]

⇒ x ∈ [−1, 0) . . . . (1)

2
Now (cot−1 x) − 5cot
−1
x + 6 > 0

−1 −1
⇒ (cot x − 2)(cot x − 3) > 0

⇒ cot
−1
x < 2 or cot−1 x > 3

x > cot2 or x < cot3. . . (2)

{ ∵ cot−1 x is a decreasing function}


ss
ta
ha
pt

s
ra

as

(1) ∩ (2) ⇒ x ∈ (cot2, 0)


w

at

29
64. Ans: (b)
h

180
pt

Solution: We need 3 -digit number which is divisible by 4&5 both. i.e. their last two digits are 00, 20, 40, 60&80 Now, ending with
ra

00 are '9'. {100, 200, … … , 900} If digit repeat other than ' 0 ' then they are {220, 440, 660, 880} but 220 numbers can be
w

permuted according to the condition as {220, 202} So, there are ' 8 ' other favorable cases. If the number have no digit repeated like
320 . 320 can be permuted in 4 ways. {302, 230, 320, 203} So, such numbers are 8 × 4 × 4 = 128 Total favorable
u/

145 29
= 9 + 8 + 128 = 145 So, required prob. = =
900 180

65. Ans: (d) None of These

Solution:

Required number of triangles

= Total number of ways of choosing 3 points−Number of ways of choosing all the 3 Points from one of AB or BC or CA

a+b+c a b c
= C − ( C + C + C )
3 3 3 3
66. Ans: (a) cot−1 1

Solution:


Let Tr = ∑
r=1
cot
−1
(3r
2
− r −
1

3
) = tan
−1
( 2
3
)
9r −3r−1

(3r+1)−(3r−2)
−1
= tan ( )
1+(3r+1)(3r−2)

∞ π π π −1 −1
∑ Tr = − = = tan 1 = cot 1
r=1 2 4 4

67. Ans: (d) 91

¯¯¯¯ ¯¯¯¯¯¯¯¯¯¯¯
Solution: P(¯EE ) + P(EEEEE)
4 8
5 1 5 1 5 1
= × + ( ) × + ( ) …∞
6 6 6 6 6 6

3
5 5 30
= [1 + ( ) …] = = 0.329 = 0.33
36 6 91

68. Ans: (a) 6

Solution:

Green→ g, Blue → 3

3 g
1 C 1 ⋅ C1
=
2 (g+3)
C
2

(g+3)(g+2)
= 6g
s

2
as

2 2
9 + 5g + 6 = 12g ⇒ g − 7g + 6 = 0
at

or 6
th

g = 1
p

69. Ans: (b) 600


ra

Solution: a + c = 2b
w

So, both a and c will be even or both will be odd as their sum is even.
u/

25×24
In first 50 natural number 25 are even and 25 are odd. Required number of ways 2 C52 +
2
C52 = 2 ×
2
= 600

70. Ans: (a)


6

55

Solution: Total cases = 11!


Number of favourable cases = 2! ×
9
C4 × 4! × 6!
9
2!× C4 ×4!×6!
Hence, required probability =
11!
2!×9!×4!×6!
=
11!×5!×4!
2×6 6
= =
11×10 55

71. Ans: (a) 133320

Solution: There are 4! = 24 numbers. Each digit occurring 3! = 6 times, in the unit's, ten's, hundred's and thousand's places. We note
that (2 + 4 + 6 + 8) = 120. Thus in the over all sum there will be 120 units, 120 tens, 120 hundreds and 120 thousands.
The required sum
2 3
= 120(1 + 10 + 10 + 10 )

= 120 × 1111 = 133320

72. Ans: (a) A and B are independent

Solution: Given, P (A ∩ B) =
1

6
31
P (A ∪ B) =
45
7
and ˉ) =
P (B
10
7 3
∴ P (B) = 1 − =
10 10

Now, P (A ∪ B) = P (A) + P (B) − P (A ∩ B)


31 3 1
⇒ = P (A) + −
45 10 6
31 1 3 5
∴ P (A) = + − =
45 6 10 9

P (A∩B)
Then. P(
B
) = =
1

5
=
10
3
>
1

6
A P (A)
1

P (A∩B) 5
and A 1
6
P( ) = = 3
= >
B P (B) 9 6
3

5 3 1
and, P (A) × P (B) = 9 × 10 =
6
= P (A ∩ B)

Hence, A and B are independent.

73. Ans: (d) 256

Solution: Given, x1 . x2 . x3 . x4 = 770 = 2.5.7.11


Let positive integer x1 = 2a .5b . 7c .11d 1 1 1 1

Let positive integer x2 = 2a .5b .7c .11d 2 2 2 2

Let positive integer x3 = 2a .5b .7c .11d 3 3 3 3

Let positive integer x4 = 2a .5b .7c .11d 4 4 4 4

Now, x1 x2 x3 x4 = 2a +a +a +a .5b +b +b +b .7c +c +c +c .11d +d +d +d


1 2 3 4 1 2 3 4 1 2 3 4 1 2 3 4

As per given condition a1 + a2 + a3 + a4 = 1, which can be in 4 ways (1, 0, 0, 0), (0, 1, 0, 0)(0, 0, 1, 0) and (0, 0, 0, 1),
similarly for other powers.
Hence total number of ways = 4 × 4 × 4 × 4 = 256

74. Ans: (b) 5 − 2π

−1 −1
tan (tan(f (−5) + f (20) + cos (f (−10) + f (17))))

Solution:
−1 −1 −1 −1
= tan (tan(2 + 3 + cos (1 − 2))) = tan (tan(5 + π)) = tan (tan 5) = 5 − 2π

75. Ans: (b) 1

14

Solution:
8!
Total ways of arrangements = 2!.4!
.

w, x, y, z

Now 'S' can have places at dot's and in places of w, x, y, z we have to put 2A s, one I and one N
5
Therefore, favourable ways = C
4
× (
4!

2!
)

Hence, required probability = 5⋅4!⋅2!⋅4!

2!⋅8!
=
1

14
.
s

76. Ans: (c) 13


as

Solution: N 5 4 3
a, b ∈ l N = 10 a + 10 b + 10 a + 10 b + 10a + b
2
t

= ababab 1 < a ≤ 9 0 < b ≤ 9


ha

4 2 2 2
= (10 + 10 + 1)(10a + b) = (10 + 10 + 1)(10 − 10 + 1)(10a + b) = 3 × 37 × 13 × 7(10a + b) . . . . . . (1)
pt

then 10a + b = P 1 × P 2 p1 , p2 ∈ prime and 10 ≤ 10a + b ≤ 99


ra

a b 10a + b
w

1 0 10 = 2 × 5
u/

2 2 22 = 2 × 11

3 4 34 = 2 × 17

3 8 38 = 2 × 19

4 6 46 = 2 × 33

5 5 55 = 5 × 11

5 8 58 = 2 × 29

6 2 62 = 2 × 31

7 4 74 = 2 × 37

8 2 82 = 2 × 41

8 5 85 = 5 × 17

9 4 94 = 2 × 47

9 5 95 = 5 × 19

77. Ans: (b) 8

17

Solution:
1
P (B1 ) = = P (B2 )
2
Box B1 have 20 non-prime numbers {1, 4, 6, 8, 9, 10, 12, 14, 15, 16, 18, 20, 21, 22, 24, 25, 26, 27, 28, 30}

20
⇒ P (N P /B1 ) =
30

Box B1 have 15 non-prime numbers {32, 33, 34, 35, 36, 38, 39, 40, 42, 44, 45, 46, 48, 49, 50}

15
⇒ P (N P /B2 ) =
20

Probability of non-prime= P (N P ) .

P (N P ) = P (B1 ). P (N P /B1 ) + P (B2 ). P (N P /B2 )


ss

1 20 1 15
= ⋅ + ⋅
ta

2 30 2 20
a

1 20

8
th

2 30
P (B1 /N . P ) = 1 20 1 15
=
17
⋅ + ⋅
ap

2 30 2 20

78. Ans: (a) 23

Solution:
4 2
1008 = 2 × 3 × 7

∴ The required number of even proper divisors


= Total number of selections of atleast one 2 and any number of 3's or 7's

= 4 × (2 + 1) × (1 + 1) − 1 = 23 .
25
79. Ans: (d) 15 + 24

2 2 −1
4 −1
4
Given expression = 1 + 2 + 1 + 3 + cosec(tan + tan )
3 3
Solution:
−24 25 25
−1 −1
= 15 + cosec(π + tan ( )) = 15 + cosec(cosec ) = 15 +
7 24 24

80. Ans: (c) 14

Solution:
k 2 3 4 5 6 7 8 9 10 11 12
1 2 3 4 5 6 5 4 3 2 1
P (k)
36 36 36 36 36 36 36 36 36 36 36

k = sum on dice
Expected value = 1

36
× 4 +
2

36
× 6 +
3

36
× 8 +
4

36
× 10
5 6 5 4
+ × 12 + × 14 + × 16 + × 18
36 36 36 36
3 2 1
+ × 20 + × 22 + × 24
36 36 36
504
= = 14
36

81. Ans: 28

Solution: Let the probability of occurrence of first event A, be 'a'


i.e., P (A) = a
∴ P (not A) = 1 − a
s

And also suppose that probability of occurrence of second event B, P (B) = b ,


as

∴ P( not B) = 1 − b
at

26
Now, P (A and not B) + P ( not A and B) = 49
th

26
⇒ P (A) × P (not B) + P (not A) × P (B) =
p

49
ra

26
⇒ a × (1 − b) + (1 − a)b =
49

26
⇒ a + b − 2ab = … (i)
49
15
And P (not A and not B) =
49
15
⇒ P (not A) × P (not B) =
49

15
⇒ (1 − a) × (1 − b) =
49

15
⇒ 1 − b − a + ab =
49

34
⇒ a + b − ab = … (ii)
49
From (i) and (ii),
42
a + b = … (iii)
49

8
and ab =
49

2 2
42 42 4 × 8 196
(a − b) = (a + b) − 4ab = × − =
49 49 49 2401

14
∴ a − b = … (iv)
49
From (iii) and (iv),
s
as
4 2
a = ,b =
7 7

Hence probability of more probable of the two events


t
ha

4
=
7
pt

final answer is 49x = 28 .


ra

82. Ans: 22
w

Solution:
u/

There are three cases for this:

(a) Apples are distributed as (4, .


ss

3, 1)
ta

8 4
Therefore, total number of ways = C
4
× C
3
× 3!
ha

= 70 × 4 × 6
pt

= 1680
ra
w

(b) Apples are distributed as (4, 2, 2) .


u/

3 8 4
Therefore, total number of ways = C
2
× C
4
× C
2

= 3 × 70 × 6

= 1260

(c) Apples are distributed as (3, 3, 2) .

Therefore, total number of ways = 3


C2 ×
8
C3 ×
5
C 3 = 1680

So, total number of ways including all the cases = 1680 + 1260 + 1680

7
= 22 × P
3

Therefore, k = 22 .

83. Ans: 6

Solution: P (A ∩ B) = P (A) ⋅ P (B)


1
⇒ P (A) =
5
ˉ ˉ
P (A ∩(A∪B))
Now, P ( A∪B ) A
=
P (A∪B)
1 1
ˉ P (B)−P (A∩B) −
A 2 10 2
⇒ P( ) = 1 1 1
= 6
=
A∪B 3
+ −
5 2 10 10

ˉ
So, 9P ( A
) = 6
A∪B

84. Ans: 3
Solution:

x +
x
1
= 2 ⇒ x = 1 … . [x +
1

x
≥ 2 as equality occurs only when x = 1]

−1 π
⇒ sin x =
2

Similarly, y = −1 . . . . [y +
1

y
≤ −2 as equality occurs only when y = −1]

−1
⇒ cos y = π
−1 −1 π
sin x + cos y = + π
2

=
2
3
⇒ m = = 1.5
2

85. Ans: 192

Solution: Case-1:
Any 5 - digit number > 6000 is all 5 -digits number
Total number > 6000 using 5 -digits = 5! = 120
Case-2:
Using 4 -digits

i.e., 3 ways Total number = 3 × 4 × 3 × 2 = 72


Total ways = 120 + 72 = 192

86. Ans: 5

Solution: Total ways is 34


Now, a1 a2 = b1 b2
If,
Case (1)a1 a2 = b1 b2 = 0

If at least one of (a1 or a2 ) and (b1 or b2 ) is “0” i.e. (32 2


− 2 ) ways
Case (2) a1 a2 = b1 b2 = +1

Both a1 , a2 is + 1
or – 1
i.e. 22 ways
Case (3) a1 a2 = b1 b2 = −1

2 ways
2

Hence, required probability


2 2
(3 −2 )+4+4
33 11
= = =
4 81
3 27

87. Ans: 3
k

Solution: 24k → (2
3
× 3) Exponent of 2 in 13! [ 13
2
] + [
13
] + [2
13
] 3
= 10 Exponent of 3 in 13! [ 13
3
] + [
13
]2
= 5 So
2 2 3

(2
3
× 3) So K = 3

88. Ans: 2

Solution:

Let I be the evert that person has infected

P be the evert that test result is positive


¯
¯¯
P (I) P ( P /I)
¯¯
P (I/P̄ ) =
¯
¯¯ ¯ ¯
¯¯ ¯
P (I) P ( P /I)+P ( I ) P ( P / I )

1
P (I) = P ( Ī ) =
2

9 ¯¯ ¯ 9
P (P /I) = & P (P̄ /I ) =
10 10
1 1
×
¯¯ 2 10 1
P (I /P̄ ) = 1 1 1 9
= = 0. 1
10
× + ×
2 10 2 10

89. Ans: 2

Solution: Let t = sinx

−1
From the graphs of sin t and cos−1 t, we know that,

1
sin
−1
t ≥ cos
−1
t for t ∈ [ , 1]
√2

1
⇒ sinx ∈ [ , 1]
√2

Hence, x ∈ (
π

2
,

4
]


Maximum value is 4
= λ

So, 2λ

3
=
π

2
= 1. 57

90. Ans: 7

Solution:

Case 1

No box is empty

a + b + c + d + e = 10 a, b, c, d, e , ≥ 1

Number of solutions = 5+5−1


C5−1 =
9
C4 = 126
Case 2

Exactly 1 box is empty (5 ways)

a + b + c + d = 10 a, b, c, d , ≥ 1

Number of solutions = 6+4−1


C4−1 =
9
C3 = 84
Case 3

Exactly 2 box are empty (6 ways)

a + c + e = 10 a, c, e , ≥ 1

Number of solutions = 7+3−1


C3−1 =
9
C2 = 36

Case 4

Exactly 3 box are empty (1 way)

b + d = 10 b, d , ≥ 1

Number of solutions = 8+2−1


C2−1 =
9
C1 = 9

Therefore, total ways = 126 + 5 × 84 + 6 × 36 + 9 = 771

Now, [ 771
11
] = 70

Hence, sum of digits is 7.

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