Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS&ALL_BT’S JEE-ADVANCE-2021-P1 Date: 26-04-2023
Time: 09.00Am to 12.00Pm GTA-18 Max. Marks: 180
26-04-2023_Sr.Super60_ NUCLEUS & ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Syllabus

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

JEE-ADVANCE-2021-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 5 – 10) +2 0 6 12
Value Answer Type
Questions with Multiple Correct Choice
Sec – III(Q.N : 11 – 16) +4 -2 6 24
with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 17 – 19) +4 0 3 12
Value Type
Total 19 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 20 – 23) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 24 – 29) +2 0 6 12
Value Answer Type
Questions with Multiple Correct
Sec – III(Q.N : 30 – 35) +4 -2 6 24
Choice with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 36– 38) +4 0 3 12
Value Type
Total 19 60

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 39 – 42) Questions with Single Correct Choice +3 -1 4 12
Paragraph Questions with Numerical
Sec – II(Q.N : 43 – 48) +2 0 6 12
Value Answer Type
Questions with Multiple Correct
Sec – III(Q.N : 49 – 54) +4 -2 6 24
Choice with partial mark
Questions with Non-negative Integer
Sec – IV(Q.N : 55 – 57) +4 0 3 12
Value Type
Total 19 60

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 2

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
PHYSICS Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 4 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases. Section 1 (Max Marks: 12)
 Section 1 contains Four questions
 Each Question has Four Options and Only One of these four will be the correct answer.
 For each question, choose the option corresponding to the correct answer
 The Marking scheme to evaluate Answer to each question will be :
 Full Marks: +3 (If the answer is correct)
 Zero Marks: 0 (If the question is unanswered)
 Negative Marks: -1 (In all other cases)
1. A system consist of block of mass m, rod of length  and mass 2m connected with the
help of string, which passes through an ideal pulley is released from rest as shown in the

figure. Tension in the rod at a distance from the upper end of the rod is
3

2mg 4mg 8mg 2mg

A) B) C) D)
9 9 9 3
2. Consider a conducting sphere having net charge zero and a positive point charge Q is
placed as shown in figure. Choose the option correctly representing the direction of
electric field at point A (just outside the sphere) due to induced charges on sphere.

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 3

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

A) B)

C) D)
 x
3. Resistivity of wire AB is given by   0 1   where  AB    and x is measured from
 
2
end B. If balancing length is from end A, find x.
3

4R 5R 3R 3R
A) B) C) D)
5 4 4 5
4. To study the performance of a race car, a high speed motion picture camera is positioned
at point A. The camera is mounted on a mechanism which permits it to record the motion
of the car as the car travels on straightway BC. The speed of the car in terms of b,  , and
d
is given by :
dt

d d d d
A) b cos 2  B) b sin 2  C) b sec 2  D) b co sec 2 
dt dt dt dt
Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 4

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
SECTION 2
 This section contains THREE (03) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen virtual
numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases

Question Stem for Question Nos. 5 and 6

Question Stem
A ray of light travelling in air is incident at nearly grazing incidence on a large rectangular
slab of transparent medium having thickness 16 m. Treating the point of incidence as the
origin and the refractive index of medium varies with thickness as a function of y (in
3
metre),   y   y 2  1 . If equation of the path of ray is x  KY 1/k and ray emerges out
of the slab at x  x0 , then

5. Value of k is _______.
6. Value of x0 _______m.
Question Stem for Question Nos. 7 and 8
Question Stem
RLC circuit can be taken similar to damped oscillation, the equation
q dq d 2q dx d 2x 1
R L  E is similar to Kx  b  m  F where K is analogus to , b
C dt dt 2 dt dt 2 C
to R and m to L. A constant DC excitation is switched on at t = 0

7. If L = 1 mH and C  10F then find value of R for which circuit is critically damped?
8. If R  10, L  1mH and C  10F , then find time in (m sec), at which current is 0 for
first time after switching the circuit  t  0 
Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 5

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

Question Stem for Question Nos. 9 and 10

Question Stem
A point charge q is placed at the centre of one of the faces of cuboid PQRS as shown in
   
the figure. If  E . d s is electric flux through area ds. If value of  E . d s over the surface
q   Nq
QRUT is and value of  E . d s over the surface PQRS is , then
k 0 0

9. Value of k is _______.
10. Value of N _______.
SECTION 3
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
 Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
 Zero Marks: 0 If unanswered;
 Negative Marks: -2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
11. The length of sonometer wire between two fixed ends is 100 cm. Three bridges be placed
so as to divide the wire into four segments whose fundamental frequencies are in the ratio
of 1 : 2 : 3 : 4 from the left end. Then which of the following is/are correct.
A) The position of the first bridge from the left fixed end is 48 cm.
B) The position of the 2nd bridge from the right fixed end is 28 cm.
C) The position of the 3rd bridge from the left fixed end is 88 cm.
D) The separation between the first bridge and the 3rd bridge is 40 cm.

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 6

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
12. Two surface OABC and OCDE lies in the plane of xy and yz as shown in the figure. A
charged particle ‘q’ lies in the space at a point P, if

A) Coordinates of ‘P’ is  a  r , a  r , r  and a  r , then flux passing through

7q
surface OABC is .
240
B) Coordinates of ‘P’ is  a  r , a  r , r  and a  r , then flux passing through
q
surface OCDE is .
240
C) Coordinates of ‘P’ is  a  r , a  r , r  and a  r , then flux passing through
q
surface OABC is .
240
D) Coordinates of ‘P’ is  a  r , a  r , r  and a  r , then flux passing through
q
surface OCDE is .
240
13. U –  (U  Internal energy of the gas and   density of the gas) plot of an ideal mono–
atomic gas undergoing a cyclic process is shown in the figure. A  B is part of a
rectangular hyperbola. Then which of the following graphs in options below correspond to
the process given in adjacent diagram ?

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 7

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

A) B)

C) D)
14. A uniform rod of mass ‘m’ and length ‘  ’ is held horizontally by two vertical strings ‘A’
and ‘B’ of negligible mass and a small block of mass ‘m’ is also placed on the top of the
rod as shown in the figure. Then which of the following is/are correct.

4
A) The tension in the string ‘A’ immediately after the string ‘B’ is cut, it mg .
7
2
B) The tension in the sting ‘A’ immediately after the string ‘B’ is cut, is mg .
7
C) The acceleration of centre of mass of the rod immediately after the string ‘B’ is cut, is
3
g.
7
D) The acceleration of centre of mass of the rod and the block immediately after the string
5
‘B’ is cut, is g.
7
Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 8

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
15. A small charged particle ‘q’ lies at the centre of two concentric conducting hollow spheres
of inner radii R and 5R and outer radii 3R and 7R respectively. Then which of the
following is/are correct.

kq 2
A) The energy stored in the space between 3R to 5R (cavity) is .
15R
kq 2
B) The energy stored in the space between 3R to 5R (cavity) is .
30 R
C) The amount of work has to be performed to slowly transfer the charge ‘q’ from center
29 kq 2
through the orifice to infinity is .
210 R
D) The amount of work has to be performed to slowly transfer the charge ‘q’ from center
38 kq 2
through the orifice to infinity is .
105 R
16. A source ‘S’ of sound wave of fixed frequency ‘f’ and an observer ‘O’ are located in air
initially at the space point A and B, a fixed distance apart. State in which of the following
cases, the observer will not see any Doppler effect and will receive the same frequency ‘f’
as produced by the source.
A) Both the source ‘S’ and observer ‘O’ remains stationary but wind blows with constant
speed in arbitrary direction.
B) The observer ‘O’ remains stationary but the source ‘S’ moves parallel to and in the
same direction and with the same speed as wind.
C) The source ‘S’ remains stationary but the observer ‘O’ and the wind have same speed
away from the source.
D) The source ‘S’ and the observer ‘O’ move directly against the wind but both with the
same speed.
Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 9

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
SECTION 4
 This section contains THREE (03) question.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct integer is entered;
 Zero Marks : 0 In all other cases.
17. A ring of mass m and radius r and made of an insulating material carries uniformly
distributed charge. Initially it rests on a frictionless horizontal tabletop with its plane
vertical. The charge on the ring so that it starts rolling on entering completely into the
N mv0
region of the magnetic field is , then find the value of ‘N’.
rB

18. A composite object is formed by combining a uniform rod of circular cross–section with
thermal conductivity k and a frustum of same length with thermal conductivity 2k as
Nk
shown in the figure. The equivalent thermal conductivity of the object is given as ,
5
find ‘N’.

19. Consider the circuit shown in figure. With switch S1 closed and the other two switches
open, the circuit has a time constant 0.05 sec. With switch S2 closed and the other two
switches open, the circuit has a time constant 2 sec. With switch S3 closed and the other
two switches open, the circuit oscillates with a period T. Find T/5 (in sec).
(Take  2  10 ),

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 10

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

CHEMISTRY Max. Marks: 60

SECTION 1
 This section contains Four (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +3 If ONLY the correct option is chosen;
 Zero Marks : 0 If the none of the options is chosen (i.e. the question is unanswered);
 Negative Marks : -1 In all other cases.

20. Electron in Li 2 ion having magnitude of potential energy P, was provided with sufficient
energy so that it jumps to higher energy level with kinetic energy Y. If it has probability
of emitting Electromagnetic radiations of six different wavelengths while de-excitation
between these two energy levels, then what is the correct relationship between P and Y?
Here n is the orbit number of higher energy state.
P 3 2Y 3 P 3 P 3
A) 1 B) 1 C) 1 D) 1
Y n P n Y n Y n
21.
O

HNO
3


 Major product is :
H

O
O
NO2

NO2
A) B)
O O
NO2

NO2

C) D)
22. Product obtained in the given reaction is:
OH
H+
C  C  CH 


Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 11

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

A) Ph Ph B) Ph  CH  C  CH  Ph
O
O

C) Ph  C  CH  CH  Ph D) Ph Ph
2 2 2
23. The oxidizing power of  CrO4  , MnO4  and  FeO4  follows the order.
2 2 2 2 2 2
A)  CrO4    MnO4    FeO4  B)  FeO4    MnO4    CrO4 
2 2 2 2 2 2
C)  MnO4    FeO4    CrO4  D)  CrO4    FeO4    MnO4 
SECTION 2
 This section contains THREE (03) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks : 0 In all other cases.

Question Stem for Question Nos. 24 and 25

Question Stem
Consider the reaction (at 300K) whose free energy of reaction is expressed as

0
GRe action  GRe
 C   0 at non equilibrium state. Forward reaction
action  RTl n
 A B 
being spontaneous, the net rate of reaction (observed rate) is defined as r1  r2 where r1
and r2 are rate of forward and backward reaction at the given instant defined by the
r
values obs  0.5 , [A] = 0.5 M, [B] = 1 M, [C] = 2 M.
r1
Hint: Law of mass action is known to be applicable for the given stoichiometry R=8.30 J/mol K,
ln2=0.7.
24. What is the equilibrium constant at 300K?

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 12

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
25. What is the absolute free energy of reaction (KJ/mol), for a given stoichiometry, when
concentrations of all species are taken as 1 M at 300K? (Round of to nearest integer)
Question Stem for Question Nos. 26 and 27
Question Stem
An organic compound ‘A’  C9 H 8O2  does not decolorizes bromine water and evolves no
gas with CH 3MgBr , but gives orange precipitate with 2, 4 – dinitro phenyl hydrazine. ‘A’
on refluxing with dil. H 2 SO4 produces B  C9 H10O3  which forms salt with NaOH and on
treatment with CH 3COC yields C13 H14O5 . B is a non–resolvable compound which on
heating with N 2 H 4 / NaOH yields ‘C’  C9 H12O2  . ‘C’ on dehydrating with conc.
H 3 PO4 yields ‘D’  C9 H10O  as major product. ‘D’ on ozonolysis following by work–up
with  CH 3  S yields ‘E’  C7 H 6O2  which can also be obtained by the action of phenol
2
with alkaline solution of chloroform followed by acidification of product.
26. What will be the molecular mass of the product obtained after acidic hydrolysis of the
compound C13 H14O5 formed in above passage (ignore AcOH)?
27. What will be the degree of unsaturation of the compound obtained after treating ‘E’ with
Tollen’s reagent followed by acidification?
Question Stem for Question Nos. 28 and 29
Question Stem
H 2O aq. alkali
X + Y + Z P + Q X + Y

heating HCl

R + Z white dense fumes

CH3MgBr/aq.Q

S + other products

(P can be used in the preparation of pastries and as firextinguisher)

28. Number of water molecules present in the crystalline compound of R is
29. Number of pi-bonds present in the organic compound ‘S’ of the above reaction scheme.

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 13

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
SECTION 3
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +4 If only (all) the correct option(s) is (are) chosen;
 Partial Marks: +3 If all the four options are correct but ONLY three options are chosen,
 Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
 Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
 Zero Marks: 0 If unanswered;
 Negative Marks: -2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
30. Choose the correct reason (s) for acquiring stability by lyophobic colloidal particles.
A) Preferential adsorption of specific ions on their surface from the colloidal system.
B) Preferential adsorption of molecules of dispersion medium on their surface from the
colloidal system.
C) Attraction between different colloidal particles having opposite charges on their
surface.
D) Potential difference between the fixed layer and the diffused layer of opposite charges
around the colloidal particles.
31. Atoms of element B (as anions) form hexagonal close packing (hcp) lattice and atoms of
element A (as cations) occupy 2/3rd of tetrahedral voids. If atoms of element B (as anions
of same charge as hcp lattice) forms cubic close packing (ccp) and atoms of element A (as
cations) occupy octahedral voids, then,
A) Total number of voids unoccupied per unit-cell must be same in both crystal structures.
B) Total number of tetrahedral voids occupied in hcp is same as that of octahedral voids
occupied in ccp.
C) Radii of cations of element A is same in both the crystal structures.
D) Average oxidation state of metal ion is different in hcp and ccp.
32. Select the wrong IUPAC name(s) :
A) 2–hydroxyhexen–4–one B) 2,3–dimethylcyclohexene
C) hept–1–en–6–yn–5–ol D) 1,3–diethoxypropan–1–one
33. Glucose and cane sugar can be distinguished by :
A) iodine solution B) Fehling’s solution
C) Molisch test D) Tollen’s reagent

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 14

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
34. Hydrometallurgy is used for extraction of noble metals like silver and gold, which of the
following steps/observations takes place?
A) Leaching B) Reduction
C) Displacement reaction D) Complex formation
35. The melting point of lithium metal is 454 K, and that of sodium is 371 K. Which of the
following statements can explain this difference in their melting points?
A) Metallic bonding in lithium is stronger than metallic bonding in sodium.
B) The delocalized electrons are more strongly attracted to the metal cation of lithium.
C) The lithium cations have a greater charge density than sodium cation.
D) Li  cations are smaller than Na  cations.
SECTION 4
 This section contains THREE (03) question.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct integer is entered;
 Zero Marks : 0 In all other cases.

36. The Cell Ag  s  Ag 2 SO4  s  Hg 2 SO4  aq, sat  Hg 2 SO4  s  Hg l  Pt has emf of 0.140V at

298K and 1 bar. Close to 298 K emf varies with temperature by 1.39  104VK 1 . How
much heat (by magnitude) is absorbed by cell if it discharges isothermally and reversibly
to deposit one gram equivalent of copper from its aqueous solution in units of kJ?
(1F=96500C). Report the value to nearest integer.
37. How many of the given compounds shows both geometrical and optical isomerism with
all the stereo isomers being optically active?
OH OH OH OH
i) ii) iii) iv)
OH OH

v) vi) vii) viii) CH 3  CH  C  CH 2

ix) x)
HO
38. Number of S-S linkages present in the ion of tetrathionate.
Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 15

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

MATHEMATICS Max. Marks: 60

SECTION 1
 This section contains Four (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +3 If ONLY the correct option is chosen;
 Zero Marks : 0 If the none of the options is chosen (i.e. the question is unanswered);
 Negative Marks : -1 In all other cases.

39. Let f  x  e
e x
sgn x and g  x  ee x
sgn x 
 , x  R where { } and [ ] denotes the

fractional and integral part functions, respectively. Also h  x   log e  f  x    loge  g  x  

then for real x, h(x) is

A) An odd function B) An even function
C) Neither odd nor an even function D) Both odd as well as even function
40. In the equation A + B + C + D + E = FG, where FG is the two digit number whose value
is 10F + G and letters, A, B, C, D, E, F and G each represents different digits and FG is as
large as possible.
If a five digit number is made using the digits A, B, C, D, E without repetition then
2
A) The probability that the number is divisible by 11 is
5
1
B) The probability that the number is divisible by 11 is
5
1
C) The probability that the number is divisible by 4 is
4
3
D) The probability that the number is divisible by 4 is
10


41. Let    sin 2k  6 
k 1

Let g :  0,1  R be the function defined by g  x  2 x  2  

 1 x

Then, which of the following statements is/are NOT CORRECT?

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 16

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P

A) The minimum value of g  x is 27/6

B) The maximum value of g  x is 1  21/3

C) The function g  x attains its maximum at more than one point

D) The function g  x attains its minimum at more than one point

1
1 x
x
42. The value of lim    by  a 1  y   dy  where b  a .
x0  
0
1 1
b a b  bb 
1  b  b a b  b  b a
A)   B) C)   D) e  
e a a  a a
 aa   aa 

SECTION 2
 This section contains THREE (03) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the on-screen
virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks: 0 In all other cases.

Question Stem for Question Nos. 43 and 44

Question Stem
Let f : R  R such that f /  0  1 and

f  x  2 y   f  x   f  2 y   e x  2 y  x  2 y   x . e x  2 y e 2 y  4 xy for all x, y  R then

43. The value of f  2  2e 2 is

44. The value of f /  3  4e3 is

Question Stem for Question Nos. 45 and 46

Question Stem
Let L1 and L2 be the lines x  2 y  z  3  0  3 x  y  2 z  1 and
2 x  2 y  3z  2  0  x  y  z  1 .
Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 17

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
45. Square of the distance of the origin from the point of intersection of L1 and L2 is
1
46. The distance of the origin from the plane through the lines is units then a + b is
a b
equal to ______ (given b is prime)
Question Stem for Question Nos. 47 and 48
Question Stem
An equation of the form 2m log a f  x  loga g  x  , a  0, a  1, m  N is equivalent to the
2m
system f  x  , g  x  0 and  f  x    g  x .

47. Number of values of x satisfying the equation

l og x 2  l og 2 x 2  l og 4 x 2 is_________
48. Number of values of x satisfying the equation

l og
 x  6
3  x 2  1  l og
 2 x  5 x
2  x 2  1 is_________

SECTION 3
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen,
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct:
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
 Zero Marks : 0 If unanswered;
 Negative Marks: -2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to the correct answer, then
Choosing ONLY (A), (B) and (D) will get +4 marks;
Choosing ONLY (A), will get +1 mark;
Choosing ONLY (B), will get +1 mark;
Choosing ONLY (D), will get +1 mark;
Choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
Choosing any other option(s) will get -2 marks.
49. A differentiable function f : R  R satisfies the functional equation

f  x . f  y   f  x  y   e x f  y   e y f  x   xy x, y  R . If f '0  0 and f 0  0 ,

then which of the following statements is/are correct?

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 18

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
f  x 1
A) lim
2

x 0 x 2
x2
B)   f 't   f t  dt  0 x  1
x
C) F  x2   F  x1  x2  x1 ,where F  x  f ' x  f  x 
D) There exists at least two horizontal tangents to the curve y  f  x  in 1,1 .
50. Which is / are CORRECT ?
A) Let the mean and variance of four numbers 3, 7, x and y  x  y  be 5 and 10
respectively. Then the mean of four numbers 3  2 x,7  2 y, x  y and x  y is 10
B) Let in a series of 2n observations, half of them are equal to a and remaining half are
equal to  a . Also by adding a constant b to each of these observations, the mean and
standard deviation of new set becomes 5 and 20, respectively. Then the value of
a 2  b 2 is equal to 425
C) Consider a set of 3n numbers having variance 4. In this set, the mean of first 2n
numbers is 6 and the mean of the remaining n numbers is 3. A new set is constructed by
adding 1 into each of first 2n numbers, and subtracting 1 from each of the remaining n
numbers. If the variance of the new set is k, then 9k is equal to 68
D) Consider three observations a, b and c such that b = a + c. If the standard deviation of

a  2, b  2, c  2 is d, then b 2  3 a 2  c 2  9d 2
100 k 1
k 1
51. If I    dx , then
k 1 k
x  x  1
50 50
A) I  log e 101 B) I  log e 101 C) I D) I 
51 51
52. The number of ordered triplets of sets (A, B, C) such that:
A) A,B,C  1,2,3,.....,8 .
B) A  B  B  C  C  A  2 .
C) A  B  C  4 .
(Here, S denotes the number of elements in the set S).
A) 45300 B) 45360 C) 42840 D) 5040

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 19

@bohring_bot
 Sri Chaitanya IIT Academy 26-04-2023_Sr.Super60_NUCLEUS&ALL_BT’S_Jee-Adv(2021-P1)_GTA-18_Q.P
53. From the set of n number 1,3,5......, 2n 1 five consecutive numbers are removed and the
393
mean of remaining numbers is . Choose the correct option(s).
5
A) The value of n is 80.
B) The value of n is 75.
C) The mean of removed number is 101.
D) The mean of removed number is 99.
54. If the graphs of the functions y = lnx and y = ax intersect at exactly two points, then a
must be lying in
A) (1, e) B) (1/e, 1) C) (0, 1/e) D) (0, 1/2)
SECTION 4
 This section contains THREE (03) question.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer the using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks : +4 If ONLY the correct integer is entered;
 Zero Marks : 0 In all other cases.

55. Let A   aij  be a real matrix of order 33 , such that ai1  ai 2  ai 3  2 , for
 
R
i  1, 2,3 . Then, the sum of all the entries of the matrix A3 is equal to R then 
3
56. The number of real solutions of the equation
   i 
    i  
1  i 1 x     x 
 x  x       cos     x  
1 i
sin
i1 i1
2  2  i1 2 i1 

lying in the interval 0,2 is _____.

  
(Here, the inverse trigonometric function sin1 x and cos1 x assume values in  , 
 2 2 
and  0,  , respectively.)
  
57. A, B, C, D are four points in the space and satisfy AB  3, BC  7, CD  11 and
  
DA  9 . Then AC . BD has value __________

Sec: Sr.Super60_ NUCLEUS&ALL_BT’S Space for rough work Page 20

@bohring_bot