SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 1/13

1 - IDENTIFICATION
GHS Product identifier: COLORAÇÃO MATIZADOR EXPORT. – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73
Recommended use of Cosmetic use.
the chemical:

Specific restrictions on There are not known restrictions on use.

use:
Supplier`s details: Botica Comercial Farmacêutica Ltda
Address: Av. Rui Barbosa, 4110 - Parque da Fonte, CEP: 83050-010 - São José dos Pinhais - PR -
Brasil.
Phone number: (41) 3375-7025
Emergency phone 55 41-3375-7910
number:

2 - HAZARD IDENTIFICATION
Classification of the Skin Corrosion/Irritation - Category 1B;
substance or mixture: Serious eye damage/eye irritation - Category 1;
Skin Sensitization - Category 1A;
Germ Cell Mutagenicity - Category 2;
Specific Target Organ Toxicity – Single Exposure - Category 2;
Hazardous to the Aquatic Environment - Acute Hazard - Category 1;
Hazardous to the Aquatic Environment - Chronic Hazard - Category 1.
Classification system Globally Harmonized System of Classification and Labeling of Chemicals (GHS), United Nations.
adopted:
GHS label elements, including precautionary statements
Pictograms:

Signal word: DANGER

Hazard statement(s): H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H371 May cause damage to the blood and to the central nervous system.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary PREVENTION:
statement(s): P203 Obtain, read and follow all safety instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 + P265 Wash hands thoroughly after handling. Do not touch eyes.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves, protective clothing, eye protection, face protection and hearing
protection.
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 2/13

RESPONSE TO EMERGENCY:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P302 + P361 + P354 IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse
with water for several minutes.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P354 + P338 IF IN EYES: Immediately rinse with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308 + P316 IF exposed or concerned: Get emergency medical help immediately.
P316 Get emergency medical help immediately.
P317 Get medical help.
P318 IF exposed or concerned, get medical advice.
P321 Specific treatment.
P333 + P317 If skin irritation or rash occurs: Get medical help.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.

STORAGE:
P405 Store locked up.

DISPOSITION:
P501 Dispose of contents and container in accordance with local regulations.
Other hazards which do The product has no other hazards.
not result in
classification:

3 - COMPOSITION/INFORMATION ON INGREDIENTS
MIXTURE

Components Industrial secret 1: 11.0 % (Classification: H401; H411) 1;

contributing to the Industrial secret 2: 5.0 % (Classification: H314; H318; H227; H302; H312; H332; H401; H412;
hazard: H335);
Industrial secret 3: 4.0 % (Classification: H315; H318; H303; H400; H410) 1;
Industrial secret 4: 2.5 % (Classification: H317; H315; H319; H401; H411);
Industrial secret 5: 2.0 % (Classification: H318; H303; H400; H410) 1;
Industrial secret 6: 2.0 % (Classification: H316; H319; H401; H412) 1;
Industrial secret 7: 1.5193 % (Classification: H317; H315; H318; H301; H313; H400; H412; H370;
H371);
Industrial secret 8: 1.1075 % (Classification: H317; H341; H302; H311; H332; H400; H410);
Industrial secret 9: 1.0 % (Classification: H315; H318; H303; H401; H412; H373) 1;
Industrial secret 10: 1.0 % (Classification: H316; H401; H411) 1,2;
Industrial secret 11: 0.9301 % (Classification: H317; H303; H401; H411);
Industrial secret 12: 0.8780 % (Classification: H317; H319; H301; H311; H330; H400; H410);
Industrial secret 13: 0.7200 % (Classification: H317; H318; H401; H411);
Industrial secret 14: 0.5494 % (Classification: H319; H302; H401; H411; H373);
Industrial secret 15: 0.50 % (Classification: H318; H302; H402);
Industrial secret 16: 0.4791 % (Classification: H317; H318; H301; H400);
Industrial secret 17: 0.4779 % (Classification: H317; H302; H332; H400; H410);
Industrial secret 18: 0.40 % (Classification: H318; H302);
Industrial secret 19: 0.2934 % (Classification: H400);
Industrial secret 20: 0.1974 % (Classification: H317; H319; H301; H312; H332; H400; H410; H373);
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 3/13

Industrial secret 21: 0.1657 % (Classification: H317; H318; H302; H401; H411);
Industrial secret 22: 0.10 % (Classification: H319) 1;
Industrial secret 23: 0.0520 % (Classification: H317; H319; H301) 3;
Industrial secret 24: 0.0020 % (Classification: H317; H315; H318; H302; H311; H400; H411; H335;
H371) 4.

1 It does not have a CAS number because it is a mixture not registered in the Chemical Abstract
Service database.
2 Contains ingredient classified as sensitizing.
3 The ingredient does not contribute to the hazard, but is classified as a sensitizer.
4 The hazards arising from the inhalation of this ingredient are not parameters for the classification of

the mixture, since, both the physico-chemical characteristics and the adequate understanding of
specialists, when a solid ingredient in the form of powder is diluted in a liquid mixture, it's not
biologically available to cause its harms.

4 - FIRST-AID MEASURES
Description of necessary first-aid measures
Inhalation: Remove victim to fresh air and keep in a position that does not obstruct breathing. If you feel unwell,
contact a TOXICOLOGICAL INFORMATION CENTER or a doctor. Bring this document.
Skin: Immediately remove contaminated clothing or accessories. Wash exposed skin with a sufficient
amount of water to remove product. In case of minor skin contact, avoid spreading the product on
unaffected areas. Immediately contact the TOXICOLOGICAL INFORMATION CENTER or doctor.
Bring this document.
Eye: Immediately flush eyes with sufficient amount of water, keeping eyelids open, for several minutes. If
wearing contact lenses, remove them if it is easy and rinse again. Immediately contact the
TOXICOLOGICAL INFORMATION CENTER or doctor. Bring this document.
Ingestion: Wash the victim's mouth with plenty of water. Never give anything by mouth to an unconscious
person. Immediately contact the TOXICOLOGICAL INFORMATION CENTER or doctor. Bring this
document.
Most important May cause an allergic skin reaction with pruritus and dermatitis. Causes severe skin burns with pain,
symptoms/effects, acute blistering and peeling. Causes serious eye damage with burning, tearing and pain. May cause damage
and delayed: to the blood and central nervous system.
Indication of immediate Avoid contact with the product when helping the victim. If necessary, symptomatic treatment should
medical attention and include, above all, supportive measures such as correction of hydro electrolytic and metabolic
special treatment disorders and respiratory assistance. In case of skin contact, do not rub the affected area.
needed, if necessary:

5 - FIRE-FIGHTING MEASURES
Extinguishing media: Appropriate: carbon dioxide (CO2), foam, water mist and powder.
Inappropriate: water jet directly.
Specific hazards arising Combustion of the material or its packaging can form irritating and toxic gases such as carbon
from the chemical: monoxide and dioxide.
Vapors can be denser than air and tend to accumulate in low-lying or confined areas such as storm
drains and basements. Containers may explode if heated.
Special protective Wear positive pressure self-contained breathing apparatus (SCBA) and full protective clothing.
actions for fire-fighters: Containers and tanks involved in the fire must be cooled with water mist.

6 - ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 4/13

For non-emergency Isolate the leakage from sources of ignition. Keep unauthorized persons away from the area. Stop the
personnel: leakage if it can be done without risk. Do not smoke. Do not touch damaged containers or spilled
product without appropriate clothing. Avoid exposure to the product. Stay in a safe place, with the wind
at your back. Use personal protective equipment as described in section 8.
For emergency Wear complete PPE with safety glasses, safety gloves, suitable protective clothing and closed shoes.
responders: In case of leakage, where exposure is high, it is recommended to use a suitable respiratory protection
mask.
Environmental Avoid that the spilled product reaches waterways or sewage system.
precautions:
Methods and materials Use water mist or vapor suppressing foam to reduce the dispersion of vapors. Use natural or spill
for containment and containment barriers. Collect spilled products and place them in appropriate containers. Adsorb the
cleaning up: remaining product with dry sand, earth, vermiculite, or any inert product. Place the adsorbed product
in appropriate containers and remove it to a safe place. For final disposal, proceed according to
Section 13 of this document.

7 - HANDLING AND STORAGE

Precautions for safe handling
Precautions for safe Handle in a well ventilated area or with general system of ventilation/local exhaust. Avoid vapors and
handling: mists formation. Avoid exposure to the product, since the effects may not be felt immediately. Use
personal protective equipment as described in section 8. Avoid contact with incompatible materials.
General hygiene: Wash hands and face thoroughly after handling and before eating, drinking, smoking, or using the
toilet. Contaminated clothing should be changed and washed before reuse. Remove contaminated
clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities
Technical measures for It is not expected that the product presents a fire or explosion hazard.
prevention of fire and
explosion:
Conditions for safe Store in a dry, well-ventilated place away from sunlight. Keep the container closed.
storage, including any It is not necessary addition of stabilizers and antioxidants to ensure the durability.
incompatibilities: Keep away from incompatible materials.

Packaging Similar to the original packaging.

compatibilities:
Inadequate packaging There are not known unsuitable material.
materials:

8 - EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Occupational exposure The values below apply to workplaces.
limit:
- Ethanolamine:
OSHA - PEL - TWA: 3 ppm (6 mg/m³) (See 29 CFR 1910.1000 Table Z-1) (CFR);
NIOSH - REL - TWA: 3 ppm (8 mg/m³);
NIOSH - REL - STEL: 6 ppm (15 mg/m³);
ACGIH - TLV - TWA: 3 ppm;
ACGIH - TLV - STEL: 6 ppm.
- Resorcinol:
ACGIH - TLV - TWA: 10 ppm;
ACGIH - TLV - STEL: 20 ppm.
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 5/13

- P-phenylenediamine:
OSHA - PEL - TWA: 0.1 mg/m³;
NIOSH - REL - TWA: 0.1 mg/m³;
ACGIH - TLV - TWA: 0.1 mg/m³.
- Sodium metabisulfite:
ACGIH - TLV - TWA: 5 mg/m³.
- Propan-2-ol:
OSHA - PEL - TWA: 400 ppm (980 mg/m³) (29 CFR 1910.1000 Table Z-1) (CFR);
NIOSH - REL - TWA: 400 ppm (980 mg/m³);
NIOSH - REL - STEL: 500 ppm (1225 mg/m³);
ACGIH - TLV - TWA: 200 ppm;
ACGIH - TLV - STEL: 400 ppm.
- Ethanol:
OSHA - PEL - TWA: 1000 ppm (1900 mg/m³) (29 CFR 1910.1000 Table Z-1) (CFR);
NIOSH - REL - TWA: 1000 ppm (1900 mg/m³);
ACGIH - TLV - STEL: 1000 ppm.
- Mica:
OSHA - PEL - TWA: 20 mppcf;
NIOSH - REL - TWA: 3 mg/m³ (R);
ACGIH - TLV - TWA: 0.1 mg/m³ (R).
- Isopentyl acetate:
OSHA - PEL - TWA: 100 ppm (525 mg/m³) (29 CFR 1910.1000 Table Z-1) (CFR);
NIOSH - REL - TWA: 100 ppm (525 mg/m³);
ACGIH - TLV - TWA: 50 ppm;
ACGIH - TLV - STEL: 100 ppm.
- Titanium dioxide:
OSHA - PEL - TWA: 15 mg/m³ (TD) (29 CFR 1910.1000 Table Z-1) (CFR);
NIOSH - REL - TWA: (Ca.AA);
ACGIH - TLV - TWA: 0.2 mg/m³ (NP.R); 2.5 mg/m³ (FP.R).

CFR: See mentioned item in OSHA CFR;

R: Respirable particulate matter;
Z3: See OSHA Table Z-3;
mppcf: Millions of particles per cubic foot of air, based on impinger samples counted by light-field
techniques. Conversion factors - mppcf X 35.3 = million particles per cubic meter = particles per c.c.
TD: Total dust;
Ca: Potential occupational carcinogen.
AA: See NIOSH REL Appendix A;
NP: Nanoscale particles;
FP: Finescale particles.
Biological limit: - 3-Aminophenol:
ACGIH - BEI: Determinant: Methemoglobin in blood. Sampling Time: During or end of shift. Index: 5
% of hemoglobin. Notation: B, Ns.
- Propan-2-ol:
ACGIH - BEI: Determinant: Acetone in urine. Sampling Time: End of shift at end of workweek. Index:
40 mg/L. Notation: Ns, B.

B: The determinant may be present in biological specimens collected from subjects who have not been
occupationally exposed, at a concentration which could affect the interpretation of the results. Such
background concentrations are incorporated in the BEI value;
Ns: The determinant is nonspecific, since it is also observed after exposure to other chemicals.
Other limits and values: - Ethanolamine:
IDLH (NIOSH, 2017): 30 ppm.
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 6/13

- Ethanol:
IDLH (NIOSH): 3300 ppm [10% LEL].
- Propan-2-ol:
IDLH (NIOSH, 2017): 2000 ppm [10% LEL].
- Isopentyl acetate:
IDLH (NIOSH): 1000 ppm.
- Titanium dioxide:
IDLH (NIOSH, 2010): 5000 mg/m³.
Appropriate engineering A risk assessment is recommended to define the engineering control measures necessary to
controls: eliminate or minimize the risk. These measures help to reduce exposure to the product. Maintain
atmospheric concentrations of the constituents of the material below occupational exposure limits
indicated.
Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection: Safety glasses.
Skin protection: Waterproof PVC or rubber apron and boots. waterproof gloves.

Respiratory protection: Respiratory protection with filter type NO, P3.

Thermal hazards: It does not present thermal hazards.

9 - PHYSICAL AND CHEMICAL PROPERTIES

Aspect: Liquid, cream.
Color: Not available.

Odour: Characteristic.
Melting point/freezing Not available.
point:

Boiling point or initial Not available.

boiling point and boiling
range:
Flammability: Not available.
Lower and upper Not available.
explosion
limit/flammability limit:
Flash point: Not available.

Auto-ignition Not available.

temperature:
Decomposition Not available.
temperature:

pH: 10 to 11.
Kinematic viscosity: Not available.

Solubility(ies): Water solubility not available.

Partition coeficient n- Not available.

octanol/water (log
value):
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 7/13

Vapour pressure: Not available.

Relative vapour density: Not available.
Density and/or relative Not available.
density:
Particle characteristics: Not applicable.

Other information: Not applicable.

10 - STABILITY AND REACTIVITY

Reactivity: Reactivity is not to be expected under normal conditions of temperature and pressure.
Chemical stability: Stable under normal temperature and pressure conditions.
Possibility of hazardous There are not known hazardous reactions with the material.
reactions:

Conditions to avoid: High temperatures. Contact with incompatible materials.

Incompatible material: Acetaldehyde, acetanilide, acid anhydride, acids, acrylonitrile, aldehydes, alkali, alkaline earth metals,
alkaline metals, aluminum, amines, ammonia, ammonia compounds, base, brass, chlorine, chromium
oxide, chromium trioxide, copper, ethylene oxide, halogen, halogen hydrocarbons, hydrogen chloride,
hydrogen peroxide, iron, isocyanates, methanol, nitrates, nitro compounds, nitrogen dioxide,
nitroparaffins, oxidizing agents, phosphorus trichloride, potassium permanganate, potassium tert-
butoxide, rubber, sodium dichromate, sulphur dioxide and vinyl acetate.
Hazardous No dangerous decomposition products are known.
decomposition
products:

11 - TOXICOLOGICAL INFORMATION
Acute toxicity: Product not classified as acute toxic.
ATEmix Vapours (4h): > 20 mg/L.
ATEmix Dusts and mists (4h): > 5 mg/L.
ATEmix Oral: > 5000 mg/kg.
ATEmix Dermal: > 5000 mg/kg.
Skin corrosion/irritation: Causes severe skin burns with pain, blistering and peeling.

Serious eye Causes serious eye damage with burning, tearing and pain.
damage/irritation:
Respiratory or skin May cause an allergic skin reaction with pruritus and dermatitis.
sensitization: It is not expected to cause respiratory sensitization.
Information regarding to:
- Industrial secret 8:
It caused sensitization to the skin of guinea pigs.

The ingredients 4-aminophenol, Resorcinol, 3-Aminophenol, 2-Amino-6-chloro-4-nitrophenol and 5-

Amino-o-cresol are classified as skin sensitizers and contribute to this product classification.

The ingredients 2-methylresorcinol, N,n-bis(2-hydroxyethyl)-p-phenylenediamine sulphate, 2,5-

diaminotoluene sulfate, P-phenylenediamine, 1-(2-Hydroxyethyl)-1H-pyrazol-4,5-diyldiammonium
sulfate, 1-Naphthol, 2-(2,4-diaminophenoxy)ethanol dihydrochloride and Allyl cyclohexanepropionate,
classified as skin sensitisers - category 1, are in concentrations < 1% and
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 8/13

do not contribute to this classification of the product.

Germ cell mutagenicity: Suspected of causing genetic defects.
Information regarding to:
- Industrial secret 8:
Studies have reported that the substance can cause genetic defects.
Carcinogenicity: It is not expected to be carcinogenic.
Reproductive toxicity: It is not expected to be reproductively toxic.

STOT - Single May cause damage to the blood and central nervous system.
exposure:
The ingredient Industrial secret 7, classified as specific target organ toxicant - single exposure -
category 2, is in concentration < 10% and does not contribute to this classification of the product.
STOT - Repeated It is not expected to exhibit specific target organ toxicity on repeated exposure.
exposure:

Aspiration hazard: It is not expected to present an aspiration hazard.

12 - ECOLOGICAL INFORMATION
Toxicity: Very toxic to aquatic life with long lasting effects.

Information regarding to:

- Industrial secret 2:
LC50 (Cyprinus carpio, 96 h): > 100 mg/L;
NOEC (Daphnia magna, 21d): 0.85 mg/L;
NOEC (Pseudokirchneriella subcapitata, 72h): 1 mg/L;
ErC50 (Pseudokirchneriella subcapitata, 72 h): 2.8 mg/L;
EC50 (Daphnia magna, 48 h): 65 mg/L.
- Industrial secret 4:
LC50 (Danio rerio, 96 h): > 100 mg/L;
EC50 (Daphnia magna, 48 h): 5.17 mg/L;
ErC50 (Pseudokirchneriella subcapitata, 72 h): 82.4 mg/L.
- Industrial secret 7:
ErC50 (Pseudokirchneriella subcapitata, 72 h): > 100 mg/L;
NOEC (Daphnia magna, 21 d): ≥ 0.172 mg/L;
EC50 (Daphnia magna, 48 h): 1 mg/L;
LC50 (Pimephales promelas, 96 h): 26.8 mg/L.
- Industrial secret 8:
EC50 (Daphnia magna, 48 h): 0.182 mg/L;
NOEC (Daphnia magna, 21d): 0.206 mg/L;
NOEC (Oryzias latipes, 41d): 0.28 mg/L;
LC50 (Oryzias latipes, 96 h): 0.82 mg/L.
- Industrial secret 12:
NOEC (Daphnia magna, 21 d): 0.00501 mg/L;
NOEC (Pseudokirchneriella subcapitata, 72 h): 0.008 mg/L;
EC50 (Daphnia pulex, 48 h): 0.15 mg/L;
ErC50 (Pseudokirchneriella subcapitata, 72 h): 0.27 mg/L;
LC50 (Oncorhynchus mykiss, 96 h): 3.9 mg/L.
- Industrial secret 16:
EC50 (Daphnia magna, 48 h): 0.605 mg/L;
NOEC (Raphidocelis subcapitata, 72 h): 2.49 mg/L;
LC50 (Fish, 96 h): 58.1 mg/L;
LC50 (Raphidocelis subcapitata, 72 h): 71 mg/L.
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 9/13

- Industrial secret 17:

LC50 (Danio rerio, 96 h): > 100 mg/L;
NOEC (Raphidocelis subcapitata, 72h): > 1 mg/L;
NOEC (Daphnia magna, 21d): 0.05 mg/L;
EC50 (Daphnia magna, 48 h): 0.267 mg/L;
ErC50 (Raphidocelis subcapitata, 72 h): 67.7 mg/L.
- Industrial secret 19:
LC50 (Oncorhynchus mykiss, 96 h): 0.3 mg/L.
- Industrial secret 20:
NOEC (Daphnia magna, 21 d): 0.276 mg/L;
ErC50 (Scenedesmus subspicatus, 72 h): 0.653 mg/L;
EC50 (Daphnia magna, 48 h): 0.82 mg/L;
LC50 (Danio rerio, 96 h): 1.08 mg/L.
- Industrial secret 24:
ErC50 (Raphidocelis subcapitata, 72 h): > 2.18 mg/L;
NOEC (Raphidocelis subcapitata, 72 h): 0.017 mg/L;
NOEC (Daphnia magna, 21 d): 0.25 mg/L;
LC50 (Fish, 96 h): 0.33 mg/L;
EC50 (Daphnia magna, 48 h): 2.51 mg/L.
Persistence and It is expected that the product presents persistence and it is not considered readily biodegradable.
degradability:
Information regarding to:
- Industrial secret 4:
Degradation rate: 0% in 28 days.
- Industrial secret 8:
Degradability rate: 6% in 28 days.
- Industrial secret 11:
Degradation rate: 0% in 28 days.
- Industrial secret 12:
Degradability: 28 - 30% in 28 days.
- Industrial secret 14:
Degradation rate: 14% in 28 days.
- Industrial secret 17:
Degradation rate: 0% in 28 days.
- Industrial secret 20:
Degradation rate: 17% in 28 days.
- Industrial secret 21:
Degradation rate: > 0 - < 1 % in 28 days.
Bioaccumulative Presents low bioacumulative potencial in aquatic organisms.
potential: Information regarding to:
- Industrial secret 4:
log Kow: 1.8
- Industrial secret 7:
BCF: 3.16
log Kow: 0.8
- Industrial secret 11:
log Kow: 0.53
- Industrial secret 12:
log Kow: 0.839
- Industrial secret 16:
log Kow: 1.58 (calculated)
- Industrial secret 17:
BCF: 4 to 40
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 10/13

log Kow: 0.183 (calculated)

- Industrial secret 19:
BCF: 3.2 (calculated)
log Kow: 0.79
- Industrial secret 20:
log Kow: 0.74
- Industrial secret 24:
log Kow: 2.836.
Mobility in soil: Not determined.
Other adverse effects: No other environmental effects known.

13 - DISPOSAL CONSIDERATIONS
Disposal methods
Must be disposed of as waste in compliance with local regulations. The treatment and disposal should be evaluated for each
specific product.
Keep the product remains in its original and properly closed containers. Disposal should be performed as established for the
product.

14 - TRANSPORT INFORMATION
Road: UN - United Nations: Model Regulations:
• Recommendations on the Transport of Dangerous Goods.
UN number: 1760

Proper shipping name: CORROSIVE LIQUID, N.O.S. (Ethanolamine)

Primary risk class or 8
division:
Subsidiary risk class or NA
division:
Packing group: II
Environmental hazards: The product is considered dangerous for the environment for land transport.

Railway regulations: COTIF - Convention concerning International Carriage by Rail:

• Appendix C: RID - Regulations concerning the International Carriage of Dangerous Goods
by Rail.
UN number: 1760

Proper shipping name: CORROSIVE LIQUID, N.O.S. (Ethanolamine)

Primary risk class or 8

division:
Subsidiary risk class or NA
division:
Packing group: II
Environmental hazards: The product is considered dangerous for the environment in rail transport.

Sea: IMO - International Maritime Organization:

• IMDG Code - International Maritime Dangerous Goods Code.
UN number: 1760
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 11/13

Proper shipping name: CORROSIVE LIQUID, N.O.S. (Ethanolamine)

Primary risk class or 8

division:
Subsidiary risk class or NA
division:
Packing group: II

Environmental hazards: The product is considered a marine pollutant.

EmS: F-A,S-B

Air: IATA - International Air Transport Association:

• DGR - Dangerous Goods Regulation.
UN number: 1760

Proper shipping name: CORROSIVE LIQUID, N.O.S. (Ethanolamine)

Primary risk class or 8

division:
Subsidiary risk class or NA
division:
Packing group: II

Environmental hazards: The product is considered dangerous for the environment for air transport.

Special precautions for Not applicable.

user:
Maritime transport in Consult regulations:
bulk according to IMO
instruments: • International Maritime Organization: MARPOL: Articles, protocols, annexes, unified
interpretations of the International Convention for the Prevention of Pollution from Ships, 1973, as
modified by the Protocol of 1978 relating thereto, consolidated edition. IMO, London, 2006;
• International Maritime Organization: IBC code: International code for the construction and
equipment of shipping carrying dangerous chemicals in bulk: With Standards and guidelines relevant
to the code. IMO, London, 2007.

15 - REGULATORY INFORMATION
Convention concerning Safety in the use of Chemicals at Work (Convention 170) - International Labour Organization, 1990.

16 - OTHER INFORMATION
This document was prepared based on current knowledge about the proper product handling and under normal conditions of use,
in accordance with the application specified on the packaging. Any other use of the product involving their combination with other
products, and use various forms of those indicated, are the responsibility of the user. Warns that the handling of any chemical
substance requires the prior knowledge of its hazards for the user. In the workplace it is for the user company's product promotes
training of its collaborators about the possible risks arising from exposure to the chemical.

Texts of Hazard statements (H) mentioned in section 3:

H227 Combustible liquid;
H301 Toxic if swallowed;
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 12/13

H302 Harmful if swallowed;

H303 May be harmful if swallowed;
H311 Toxic in contact with skin;
H312 Harmful in contact with skin;
H313 May be harmful in contact with skin;
H315 Causes skin irritation;
H316 Causes mild skin irritation;
H318 Causes serious eye damage;
H319 Causes serious eye irritation;
H330 Fatal if inhaled;
H332 Harmful if inhaled;
H335 May cause respiratory irritation;
H370 Causes damage to organs;
H373 May cause damage to organs through prolonged or repeated exposure;
H400 Very toxic to aquatic life;
H401 Toxic to aquatic life;
H402 Harmful to aquatic life;
H411 Toxic to aquatic life with long lasting effects;
H412 Harmful to aquatic life with long lasting effects.

Change control:

Version Manufacture date Changes

01 05/14/2024 Elaboration

Abbreviations:
ACGIH - American Conference of Governmental Industrial Hygienists;
ATEmix - Acute Toxicity Estimate of the mixture;
BCF - Bioconcentration factor;
BEI - Biological Exposure Index;
CAS - Chemical Abstracts Service;
EC - European Community;
EC50 - Effective concentration of substance that causes 50 % of the maximum response;
EEC - European Economic Community;
EPA - United States Environmental Protection Agency;
ErC50 - Effective concentration that results in a 50% reduction in the growth rate;
IARC - International Agency for Research on Cancer;
IDLH - Immediately Dangerous to Life or Health;
Kow - Octanol-water partition coefficient;
LC50 - Lethal Concentration 50%;
LEL - Lower Explosive Limit;
NIOSH - National Institute for Occupational Safety and Health;
NOEC - No Observed Effect Concentration;
OSHA - Occupational Safety & Health Administration;
PEL - Permissible Exposure Limit;
REL - Recommended Exposure Limit;
STEL - Short Term Exposure Limit;
TLV - Threshold Limit Value;
TWA - Time Weighted Average;
UN - United Nations.
Bibliographic references:
 SDS

In accordance with Globally Harmonized System of

Classification and Labelling of Chemicals (GHS)- Chapter 1.5
and Annex 4

SAFETY DATA SHEET

Product: COLORAÇÃO MATIZADOR EXPORTAÇÃO – PERFECT BLOND DARK BLONDE GOLDEN BROWN 6.73 60G

Revision: 01 Date: 05/14/2024 Pages: 13/13

ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIALS HYGIENISTS. TLVs® and BEIs®: Based on the
Documentation of the Threshold Limit Values (TLVs®) for Chemical Substances and Physical Agents & Biological Exposure
Indices (BEIs®). Cincinnati-USA, 2023.

CONCAWE - HAZARD CLASSIFICATION AND LABELLING OF PETROLEUM SUBSTANCES IN THE EUROPEAN

ECONOMIC AREA. Available at: <https://www.concawe.eu/>. Access in: May. 2024.

ECHA - EUROPEAN CHEMICAL AGENCY. Available at: < http://echa.europa.eu/web/guest >. Access in: May. 2024.

EPA - UNITED STATES ENVIRONMENTAL PROTECTION AGENCY. Available at: <https://www.epa.gov/>. Access in: May.
2024.

GESTIS - SUBSTANCE DATABASE. Available at: < http://gestis-

en.itrust.de/nxt/gateway.dll/gestis_en/000000.xml?f=templates$fn=default.htm$3.0 >. Access in: May. 2024.

GHS - GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS. 10th rev. ed. New
York and Geneva: United Nations, 2023.

HSDB - HAZARDOUS SUBSTANCES DATA BANK. Available at: http://pubchem.ncbi.nlm.nih.gov/. Access in: May. 2024.

IARC - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER. Available at:

http://monographs.iarc.fr/ENG/Classification/index.php. Access in: May. 2024.

NIOSH - NATIONAL INSTITUTE OF OCCUPATIONAL AND SAFETY. International Chemical Safety Cards. Available at:
http://www.cdc.gov/niosh/. Access in: May. 2024.

OSHA - OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION. UNITED STATES DEPARTMENT OF LABOUR. <
https://www.osha.gov/chemicaldata/search > Access in: May. 2024.

REACH - REGISTRATION, EVALUATION, AUTHORIZATION AND RESTRICTION OF CHEMICALS. Commission Regulation

(EC) No 1272/2008 of December 2008 amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorization
and Restriction of Chemicals. Available at: < http://eur-
lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2008:353:0001:1355:en:PDF >. Access in: May. 2024.