XI CHEMISTRY ASSIGNMENT QUESTIONS Page 1 of 4

CHAPTER # 1
1: Define the following:
i) Stoichiometry ii) Limiting reactant iii) Avogadro’s number
iv) Molar volume v) Theoretical and actual yield vi) % yield

2: Calculate the mass and volume of N2 gas produced by heating 25g of NH3 gas at S.T.P
2NH3 = N2 + 3H2
3: Potassium chlorate is often to used generate oxygen gas in high school laboratory, if 183.7 g of KClO3 completely
burnt catalytically, what volume of oxygen gas will be obtained at 390C and 1200 torr pressure?
2KClO3 2KCl + 3O2
4: Calculate the volume of NO2 and O2 gas produced at S.T.P when a sample of 54g N2O5 is heated?
2N2O5 4NO2 + O2
5: The atomic mass of Na = 23 a.m.u
a) Calculate the mass of 2.408X1023 atoms of Na. b) Calculate the no of moles & no of atoms in 60gm.
c) Gram atomic mass of Na.
6: What is the minimum mass of Al(OH)3 that can be obtained by reacting of 13.4g of AlCl 3 with 10g of NaOH
according to the following equation. And also find the percentage yield of Al(OH)3.
AlCl3 + 3NaOH → Al(OH)3 + 3NaCl
7: Find the weight of Barium sulphate precipitated on adding a solution containing 82 gram of potassium sulphate to
a solution containing 82 gram of Barium chloride. K2SO4 + BaCl2  BaSO4 + 2KCl

CHAPTER # 2
1. Define Radioactivity. Give an account of chief types of radiations. Given out by radioactive elements.
2. What are the assumptions of Bohr’s Theory?
3. Explain rules of electronic configuration (n+l rule, Hund’s rule, Aufbau principle, pauli’s exclusion
principle.)
4. Describe Heisenberg uncertainty principle
5. Derive expression for radius, wave number and energy of hydrogen atom.
6. Write electronic configuration and number of electron, proton and neutron of the following.
a) Na (Z=11, A=23) b) Cr (Z=24, A=48) c) Cl-1 (Z=17, A=35) d) Cu (Z=29, A=58)
7. Define Quantum number and explain its types. Describe 4 quantum number needed to specify an electron
in an atom. Write all possible values l, m and s for n=2.
8. Draw the shape of orbital when the value of l=0 and l=1.
9. What are X-rays & describe the relationship between their wavelength and atomic numbers.
10. Calculate the radius of 3rd orbit of hydrogen atom using Bohr’s radius.
11. A photon of wave number 23x105m-1 is emitted when electron undergoes a transition from a higher energy
orbit to n=2. Determine the orbit from which electron fall and also the spectral lines appear in this
transition of electron. (RH= 1.09678x107 m-1)

CHAPTER # 3
1. Define sigma and pi bond with characteristics.
2. Describe VSEPRT and Hyrid orbital theory and draw the shapes of i) NH3 ii) H2O iii) BF3 iv) CH4 v) CO2
3. Describe orbital hybridization. Explain sp or sp2 hybridization with the help of example of C2H4 and C2H2
molecules.
4. Describe ionic character of covalent compound or write a note on dipole moment.
5. Define ionic and covalent bond with characters and example.
6. Describe valence bond theory or molecular bond theory.
7. Define bond energy, bond axis and bond length.

CHAPTER # 4
1.What are the postulates of Kinetic Molecular Theory of the gases.
2.Unit conversion of pressure, volume and temperature
3.Derive General gas equation and calculate value of Gas constant “R” in different units.
4.Derive ideal gas equation. OR State and explain Graham’s law and Dalton’s Law.

Q – 4) NUMERICAL

Prepared By: M.Fahad Khan

(Ph.D Chemistry)
XI CHEMISTRY ASSIGNMENT QUESTIONS Page 2 of 4

 1.40 dm3 volume of a gas measured at a temp of 27ºC and a pressure of 900 torr was found to have a mass
of gas 2.273gm Calculate the molecular mass of the gas.
 A quantity of a gas measure 500ml at 35ºC and 600mm pressure. What would be the volume of the gas at
45ºC and 800mm pressure.
 What is the density of CH4 gas at 100ºC and 3.5 atm pressure
 1100ml of CO2 at a pressure of 500 torr, 1500 ml N2 at a pressure of 400 torr and 800 ml of O2 at a pressure
of 600 torr are places together in a container of 1000 ml capacity. Find the partial pressure of each
gas.
 A gaseous mixture contains 0.2 mole of O2 and 0.3 mole of CO2. If the partial pressure of oxygen is 60 torr,
Calculate the partial pressure of CO2.
 Two moles of oxygen are kept in a vessel of 15.5 dm3 at a temperature of 37 oC, calculate the pressure
exerted by the gas if (a) gas behave as ideal gas (b) gas behave as a non ideal
(The vandar waal constant for oxygen are given as (a) 1.36 atm dm 6 mol-2 (b) 0.0318 dm3 mol-1)

CHAPTER # 5
1. Write general properties of liquid or KMT of liquid.
2. Define liquid crystals with its uses.
3. Write a short note on any one i) Viscosity ii) Surface tension iii) Vapour pressure iv) Boiling point
4. Write anomalous behavior of water.
5. Define hydrogen bond and correlate the following behavior of water with hydrogen bonding among its
molecules?
6. How the high specific heat of water effects on moderating the temperature of atmosphere?

CHAPTER # 6
1. Write difference b/w crystalline and amorphous solid.
2. Write Types of crystalline solid with characters.
3. Define crystal system and write any four cell parameter with its diagram.
4. Write a short note on isomorphism and polymorphism.

CHAPTER # 7
1. State and explain law of Mass Action.
2. Apply Le – Chatelier’s principle to Formation of NH3 by Haber;s process.
3. For the reaction PCl5 = PCl3 + Cl2
Predict the Direction when following stress are applied. a) Pressure increases b) Temperature decreases
c) More PCl5 is added d) Remove Cl2
4. What is Solubility product? Give its applications in precipitation of Sparingly soluble substances.
5. Describe the relationship between Kc and Kp. 4. Applications of Kc.
6. Lead floride (PbF2) is a high meltingwhite solid used in glass coating to reflect IR rays.
Its solubility in water at .
8-) At 444°C reaction of hydrogen and iodine is performed in a sealed 1 dm³ steel vessel.
H2 + I2 ↔ 2HI
If equilibrium mixture contains 1 mole of H2, 1 mole of I2 and 7 moles of HI.
Calculate (a) Equilibrium constant (Kc) (b) Initial concentration of H₂ and I2

9-) Lead fluoride (PbF2) is a high melting white solid used in glass coating to reflect IR rays. Its solubility
in water at 25°C is 0.58g/dm³. Calculate its Ksp
10-) . Kp for the decomposition of phosphorus pentachloride (PCI5) at 523°C is 0.82. Calculate Kc for this
reaction
PCl5 ↔ PCl3+ Cl2(g)
11-) 164.64g N2. and 518.4g O2 gases are mixed and heated at 2300°C until the equilibrium is established,
338.4g nitric acid (NO) is formed. Calculate KC
N2 + O2 ↔ 2NO

CHAPTER # 8
1-) Define pH & pOH of a solution. Also show that pH + pOH-14.
2-) Why is the aqueous solution of NH4Cl acidic and Na2CO3 alkaline.

Prepared By: M.Fahad Khan

(Ph.D Chemistry)
XI CHEMISTRY ASSIGNMENT QUESTIONS Page 3 of 4

3-) Write down conjugate base of each of the following acids

, H2SO4 , H2S , NH4+ , HCOOH
Descriptive Questions
1-) Explain Bronsted-Lowry theory of acids and bases. What is meant by conjugate acid- base pair? Give examples.
.2-) Describe Lewis theory of acids and bases. What are the advantages of this theory over Lowry Bronsted theory?
3-) What is salt hydrolysis? Classify the salts on the basis of reactivity with water.
Numerical Questions
A solution is made by dissolving 1.48g HCl in water at 25°C. If the volume of solution is 750cm³ and HCl is assumed
to be completely ionized, calculate its pH.
2. The hydroxide ion concentration in an antiseptic solution at 25°C is 3.5 x 10-4 M Calculate its pH.
3. What is the concentration Hand OH ion in an aqueous solution at pH 5.6

CHAPTER # 9
Q – 1) Define the following:
i) Order of reaction ii) Activation energy iii) Rate and Velocity of reaction iv) Rate law.
Q – 2) i) Discuss all the factors affecting rate of chemical reactions.
ii) Write a short note on catalyst.
Q – 3) Numerical
1:For the given reaction A + B  products, determine the rate law, rate constant and order of Reaction and rate
constant from the following data:
S. A (mole/dm3) B (mole/dm3) Rate mole s -1
No
1 0.1 0.1 1 x 10-3
2 0.2 0.1 4 x 10-3
3 0.1 0.3 3 x 10-3
2: Write rate expressions of following:
(1) PCl5  PCl3 + Cl2 (2) 2NO + O2  2NO2
(3) H2SeO3 + 6I- + 4H+  Se + 3I2 + 3H2O
3: (a)Rate constant for decomposition of nitrogen dioxide 2NO2  2NO + O2 is 1.8 x 10-8 dm3 mol-1 S-1 .What is
initial rate when initial concentration of NO2 is 0.50 M?
(b) What is the rate constant if the initial concentration of NO2 is doubled?

CHAPTER # 10
1. State and explain Roult’s law.
2. Write a short not on solubility.
3. Diffentiate solution, suspension and colloidal solution.
4. Define concentration of solution and describe its various units.
5. Numerical of molarity, molality, mole fraction, ppt and ppm.

CHAPTER # 11
Q – 1) Define the following term:
i) Change in enthalpy ii) Thermo chemistry iii) State
iv) Thermodynamics v) Heat of formation
Q – 2) Explain Hess’s law with its application.
1. State and explain Born Haber cycle.
2. State and explain 1st .law of thermodynamics and show that:
Qp = ΔE + PΔV = ΔH OR Qv= ΔE
3. Derive pressure – volume work on the basis of 1st law of thermodynamics.
Q – 3) Numerical
1: In a certain process 848J of heat is absorb by a system, while 394 J of work is done on the System. What is the
change in the internal energy of the process?

Prepared By: M.Fahad Khan

(Ph.D Chemistry)
XI CHEMISTRY ASSIGNMENT QUESTIONS Page 4 of 4

2: Calculate the heat of formation of CH4 from the following data.

C + 2H2 = CH4 ∆HF = ?
C + O2 = CO2 ∆H = -394 KJ/mole
H2 + ½ O2 = H2O ∆H = -286 KJ/mole
CH4 + 2O2 = CO2 + 2H2O ∆H = -890.34 KJ/mole
3- A thermochemical process is carried out at constant pressure of 8.52atm. If it absorbs 15.4KJ energy from the
surrounding due to which an expansion in the volume of 4.7dm³ is occurred. Calculate its change in internal energy.
4-) In the manufacturing of HNO3 by the Ostwald process, one of the most important exothermic reactions is the
oxidation of ammonia
4NH3(g) + 5O2 ↔ 4NO +6H2O
Determine standard heat of reaction (∆HO) from the following given data.
∆HO NH 3 =-46.19KJ/mol
∆HO of NO =90.25KI/mol
∆HO of H2O (l) =-285.8KJ/mol

5-) Draw a fully labeled Born Haber cycle for Rubidium chloride (RbCI) and determine
the lattice energy by using the following values. (all in kJ / mol ).
i I.P1ST of Rb = 403
ii Electron affinity of Cl = - 349KJ / mol
iii Cl2 = 242KJ / mol
iv Bond energy of Sublimation energy of Rb = 86.5 KJ/mol
v Heat of formation of RbCl-430.5 KJ/mol

CHAPTER # 12
1. Diffentiate reduction and oxidation process.
2. Define oxidation number with its rule and calculate the oxidation number of the following.
a. Cr in K2Cr2O7 c) S in Na2S2O3 e) Cl in HClO3
b. Mn in MnO4-1 d) O in OF2 f) C in C2H6O
3. Define electrolysis with the help of CaCl2 salt.
4. Write a short note on galvanic cell or ECS.
5. Write a short note on Electrode potential of Zn or SHE.
6. Balance the following chemical equation by ion electron method.
a. Cr2O7-2 + I2 + H+ Cr+3 + IO3-1 + H2O
b. MnO4-1 + SO3-2  Mn+2 + SO4-2 (Basic)
c. Cl2 + OH-1  Cl-1 + ClO3-1 (Basic)

Prepared By: M.Fahad Khan

(Ph.D Chemistry)