13112024 PCM Test # 01

(for JEE-Mains 2025)

Time : 3 :00 Hr. Max. Marks : 300
* Each question + 4 (for correct answer) & - 1 (for wrong answer)
Each section have 20 Single choice Questions & 5 Integer Type.
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Section A
PHYSICS
R 2 – P2
Q.1 Two vectors P and Q act at a point and produce resultant R. If Q is replaced by Q acting
in the direction opposite to that of Q, the resultant :
(A) Remains the same (B) Becomes half (C) Become twice (D) None of these

Q.2 An elevator is moving upwards with constant acceleration. The

dashed curve in figure shows the position y of the ceiling of the
elevator as a function of time t. At the instant indicated by the
point P, a bolt breaks loose and drops from the ceiling. Which
of the solid curves shown best describes the position of the bolt
as a function of time ?
(A) I (B) II (C) III (D) IV
Q.3 A ball is projected from a point with velocity 10 ms–1 perpendicular to the inclined plane as
shown in figure. The range of the projectile (use g = 10 ms–2) on the inclined plane is :
10 20 40 50
(A) m (B) m (C) m (D) m
3 3 3 3
Q.4 A simple pendulum has time period T1. The point of suspension is now moved upward accord-
ing to the relation y = Kt2, (K = 1 m/s2) where 'y' is vertical displacement. The time period
T12
now becomes T2. The ratio T 2 is (use g = 10 ms–2) :
2

(A) 5/6 (B) 6/5 (C) 1 (D) 4/5

Q.5 Focal length of the plano-convex lens is 15 cm. A small object is placed at
A as shown in the figure. The plane surface is silvered. The image will form
at :
(A) 60 cm to the left of lens (B) 12 cm to the left of lens
(C) 60 cm to the right of lens (D) 30 cm to the left of lens

Q.6 Two non-conducting spheres of radii R1 and R2 and carrying uni-

form volume charge densities + and –  , respectively, are placed
such that they partially overlap as shown in the figure. At all points
in the overlapping region, check which statements are true :
(a) The electrostatic field is zero
(b) The electrostatic potential is constant
(c) The electrostatic field is constant in magnitude
(d) The electrostatic field has same direction
(A) c , d (B) b , c (C) c only (D) a , d
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Q.7 In the given circuit diagram, when the current reaches steady
state in the circuit, the charge on the capacitor of capacitance C
will be :
r
2 r
1
(A) CE (r + r ) (B) CE (r + r)
1 2 1

1 r
(C) CE (D) CE (r + r)
2

Q.8 Wires are used to form the following letters. In each case the wire used have same cross-
section area and resistivity. Length of each of straight portion of wire is same.

Which letter will show maximum resistance between P & Q.

(A) Letter A (B) Letter B (C) Letter C (D) Letter D
Q.9 If instead of mass, length and time as fundamental quantities, we choose velocity, accelera-
tion and force as fundamental quantities and express their dimensions by V, A and F respec-
tively, then the dimensions of pressure will be expressed as :
(A) [FA2V–1] (B) [F2AV–1] (C) [FA2V–4] (D) [FAV–2]
Q.10 A steel ball of mass 0.5 kg is dropped from a height of 4.05 m onto a horizontal steel slab.
The collision is elastic, and the ball rebounds to its original height. If the ball is in contact
with the slab for 0.002 sec, the average force (in newton) on the ball during the impact is 15
x × 102 N. Find x. (Take g = 10 m/s2) :
(A) 5 (B) 4 (C) 3 (D) 2

Q.11 In the arrangement shown, by what acceleration the boy must

go up so that 100 kg block remains stationary on the wedge.
The wedge is fixed and friction is absent everywhere. (Take
g = 10 m/s2) :
(A) 2 m/s2 (B) 4 m/s2
(C) 6 m/s2 (D) 8 m/s2
Q.12 Two lighter nuclei combine to form a comparatively heavier nucleus by the relation given
follows 21X + 21X = 42Y. The binding energies per nucleon 21X and 42Y are 1.1 MeV and 7.6
MeV respectively. The energy released in this process is :
(A) 26 MeV (B) 20 MeV (C) 16 MeV (D) 7.6 MeV
Q.13 Given below are two statements :
If two springs S1 and S2 of force constants k1 and k2, respectively, are stretched by the same
force, it is found that more work is done on spring S1 than on spring S2.
Statement I: If stretched by the same amount, work done on S1, will be more than that on S2.
Statement II: k1 < k2.
In the light of the above statements, choose the most appropriate answer from the options
given below :
(A) Statement I is correct but Statement II is incorrect.
(B) Statement I is incorrect but Statement II is correct.
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 (C) Both Statement I and Statement II are correct.
(D) Both Statement I and Statement II are incorrect
Q.14 A cord is used to lower vertically a block of mass M by a distance d with constant downward
g
acceleration . Work done by the cord on the block is :
4

d d d
(A) Mg (B) 3Mg (C) –3Mg (D) Mgd
4 4 4
Q.15 A ball of mass m moving with a certain velocity collides against a stationary ball of mass m.
The two balls stick together after collision. If E be the initial kinetic energy, then the loss of
kinetic energy in the collision is
(A) E (B) E/2 (C) E/3 (D) E/4
Q.16 Three bricks each of length L and mass M are arranged as shown in figure. The distance of the
centre of mass of a system from the wall is :

20 11 12 13
(A) L (B) L (C) L (D) L
3 12 5 14
Q.17 A radio–active elements emits 2  and 3  particles then mass number of daughter's element
is :
(A) Decreased by 6 (B) Decreased by 12 (C) Increased by 2 (D) Increased by 4
Q.18 In the given nuclear reaction A, B, C, D, E represents :
–
  E
92 U238   B ThA  DPaC   92 U234

(A) A=234, B=90, C=234, D=91, E=  (B) A=234, B=90, C=238, D=94, E= 
(C) A=238, B=93, C=234, D=91, E=  (D) A=234, B=90, C=234, D=93, E= 
Q.19 When an object is placed at a distance of 25 cm from a concave mirror, the magnification is
m1. The object is moved 15 cm farhter away with respect to the earlier position, and the
magnification becomes m2. If m1/m2 = 4 the focal length of the mirror is (Assume image is
real m1, m2 are numerical values)
(A) 10 cm (B) 30 cm (C) 15 cm (D) 20 cm
Q.20 A beam of convergent light converges to a point 0.5 m in front of the mirror after reflection
at a convex mirror but in the absence of the mirror the beam converges to a point 0.2 m
behind the mirror. The radius of curvature of the mirror is :
0.5m
P
I O

0.2m
(A) 20 cm (B) 50 cm (C) 66.67 cm (D) 28.57 cm

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Integer Type :
Q.21 In a Vernier callipers, each cm on the main scale is divided into 20 equal parts. If tenth vernier
scale division coincides with 9th main scale division. Then the value of Vernier constant will
be _____ × 10–2 mm.
Q.22 A pendulum inside an elevator has a time period T1 when elevator is at rest. Time period is T2
when the elevator accelerates up with acceleration a and T3 when the elevator accelerates
down with acceleration a. If T1, T2 and T3 are related as T12 (T22 + T32) = nT22T32 find the value
of n :
Q.23 A boy of mass 4 kg is standing on a piece of wood having mass 5 kg. If the coefficient of
friction between the wood and the floor is 0.5, the maximum force that the boy can exert on
the rope so that the piece of wood does not move from its place is ______ N. (Round off to
the Nearest integer) [Take g = 10 ms–2]
Q.24 A current of 2 mA was passed through an unknown resistor which dissipated a power of 4.4
W. Dissipated power when an ideal power supply of 11 V is connected across it is N × 10–5 W,
where the value of N is :
Q.25 Orange light of wavelength 6000 × 10–10 m illuminates a single slit of width 0.6 × 10–4 m. The
maximum possible number of diffraction minima produced on both sides of the central maxi-
mum is ________.

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 Section B
CHEMISTRY
Q.1 Duplet configuration is NOT found in
(A) Hydride ion (B) Hydrogen molecule (C) Lithium cation (D) Be 3+
Q.2 Molecule having an incomplete octet in the central atom is :
(A) XeF2 (B) NF3 (C) BCl3 (D) F2O
Q.3 Which of the following species are hypervalent ?
(1) ClO4– (2) BF3 (3) SO42– (4) CO32–
(A) 1, 2 , 3 (B) 1 , 3 (C) 3 , 4 (D) 1 , 2
Q.4 A gaseous mixture contains SO3 (g) and C2H6 (g) in a 16 : 15 ratio by mass. The ratio of total
number of atoms present in C2H6 (g) and SO3 (g) is :
(A) 2 : 5 (B) 1 : 5 (C) 5 : 1 (D) 5 : 2
Q.5 1.61 gm of anhydrous ZnSO4 was placed in moist air, after few days its weight was found to
be 2.87 gm. What is the molecular formula of hydrated salt ? [Zn = 65]
(A) ZnSO4 · H2O (B) ZnSO4 · 3H2O (C) ZnSO4 · 7H2O (D) ZnSO4 · 10H2O
CH2
Ph2CH – CH – CH2 –
Q.6 is prepared by Wittig reaction using compounds (A) and (B).
Ph
Me
In this reaction Ph3PO is obtained as another product.

Me – C – C – CH2CH2
O O
(A) on reaction with (C) {C21HxP} gives 1-butene.
reacts with excess (B) to give a
hydrocarbon (D). The number of benzene rings in (D) are :
x x x x
(A) (B) +1 (C) +2 (D) +3
3 3 3 3
Q.7 Ionisation enthalpy (iH1kJ mol–1) for the elements of Group 13 follows the order.
(A) B > Al > Ga > In > Tl (B) B < Al < Ga < In < Tl
(C) B < Al > Ga < In > Tl (D) B > Al < Ga > In < Tl
Q.8 The solubility of different sparingly salts are given as under :
S.No. Formula Type Solubility product
1. AB 4.0 × 10–20
2. A2B 3.2 × 10–11
3. AB3 2.7 × 10–31
The correct increasing order of solubility is :
(A) 1, 3, 2 (B) 2, 1, 3 (C) 1, 2, 3 (D) 3, 1, 2

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Q.9 Consider the following six electronic configurations (remainimg inner orbitals are com-
pletely filled) and mark the incorrect option.

I. II. III.

IV. V. VI.

(A) Stability order : II > I > IV > III

(B) Order of spin multiplicity : IV > III = I > II
(C) V does not violate all the three rules of electronic configuration
(D) If VI represents A and A+ when kept near a magnet, acts as diamagnetic substance.
Q.10 The standard enthalpies of formation of CO2(g ), H2O(l)and glucose(s) at 25°C are
–400 kJ/mol, –300 kJ/mol and –1300 kJ/mol, respectively. The standard enthalpy of com-
bustion per gram of glucose at 25°C is :
(A) + 2900 kJ (B) – 2900 kJ (C) –16.11 kJ (D) +16.11 kJ

Q.11

The bond energies (in kJ/mol) at 25°C are C – C = 346 , C – H = 413 and H – H = 437, C =
C ; 611. From the data, the value of H at 25°C for the above reaction is :
(A) –289 kJ mol–1 (B) –124 kJ mol–1 (C) 124 kJ mol–1 (D) 289 kJ mol–1
Q.12 Adipic acid on heating followed by reaction with m-CPBA gives :
(A) six memebered homocyclic ester (B) five memebered hetrocyclic ester
(C) six memebered homocyclic acid (D) five memebered hetrocyclic acid

Q.13

The reagent (X) in the above reaction is :

(A) BrCH2CH2COOH (B) (CH3CO)2O
(C) (CH3CH2CO)2O (D) (CH3CH2COO)2
Q.14 The intermediate formed in aldol reaction is :
(A) carbocation whose +ve charge is stabilised by resonance .
(B) carbocation whose +ve charge is not stabilised by resonance .
(C) carbanion whose —ve charge is stabilised by resonance .
(D) carbanion whose —ve charge is not stabilised by resonance
Q.15 Bond dissociation energy of E–H bond of the “H2E” hydrides of group 16 elements (given
below), follows order.
(A) O (B) S (C) Se (D) Te
(a) A > B > C > D (b) A > B > D > C (c) B > A > C > D (d) D > C > B > A

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Q.16 Reaction of BeO with ammonia and hydrogen fluoride gives 'A' which on thermal decompo-
sition gives BeF2 and NH4F. What is 'A' ?
(A) (NH4)2BeF4 (B) H3NBeF3 (C) (NH4)BeF3 (D) (NH4)Be2F5
Q.17 In Ideal SN2 situation the bond angle between Nu– , C and Cl– in Transition state of the reac-
tion NU Θ CH3Cl  is :
(A) 0° (B) 90° (C) 45° (D) 180°
Q.18 Increasing rate of SN1 reaction in the following compounds is

(a) (A) < (B) < (C) < (D) (b) (B) < (A) < (C) < (D)
(c) (B) < (A) < (D) < (C) (d) (A) < (B) < (D) < (C)
Q.19 A mixture of p—tolualdehyde and m—tolualdehyde undergoes self and cross con
densation in presence of aqueous ethanolic KCN gives ‘x’ no. of isomers. The no.
of isomers of C4H8 are equal to :
(A) x (B) x – 2 (C) x – 1 (D) x + 1
Q.20 Cyclohexanone oxime on treatment with conc. H2SO4 gives :
(A) Nylon—6 , 6 (B) caprolactam (C) Amyl alcohol (D) cyclohexyl amine

Integer Type :
Q.21 Bond length of A-A bond is 124 pm and bond length of B – B bond is 174 pm. Calculate the
bond length (in pm) of A-B bond in AB molecule if percent ionic character of A-B bond is
19.5%.
Q.22 0.1 mol HCl is dissolved in distilled water of volume V, then , Vlim

(pH)Solution at is equal to :

Q.23 An organic compound (A) of formula C15H32O8 on reaction with excess CH3COCl gives
C21HxOy. The value of x + y is :
Q.24 The no. of hydrogen atoms in the product obtained in the reaction

(excess)  is :
NH2 NH2

CHO

Q.25 Total number of acidic oxides among

N2O3 , NO2 , N2O , Cl2O7 , SO2 , CO , CaO , Na2O and NO is _________ .

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 Section C
MATHEMATICS
Q.1 If x  a  0 is the directrix of the parabola y 2  2 y  ax  2 then the value of a is :
(A) 2 (B) 3 (C) 4 (D) 4/3
Q.2 The locus of centroid of triangle formed by a tangent to the parabola y 2  36 x with coordi-
nate axes is :
(A) y 2  9 x (B) y 2  3x  0 (C) y 2  3x (D) y 2  9 x
Q.3 If a  0 , and the line 2bx  3cy  4d  0 passes through the points of intersection of the pa-
rabola y 2  4ax and x 2  4by then.
(A) d 2  (2b  3c) 2  0 (B) d 2  (3b  2c)2  0
(C) d 2  (2b  3c) 2  0 (D) d 2  (3b  2c) 2  0
Q.4 Number of 4 digit positive integers if the product of their digits is divisible by 3 is.
(A) 2700 (B) 5464 (C) 6628 (D) 7704
Q.5 Let the product of all the divisore of 1440 be P. If P is divisible by 24x, then maximum value
of x is :
(A) 28 (B) 30 (C) 32 (D) 36
Q.6 If the equation x 2  5  4 cos  x     2 x has at least one solution where ,    2, 5 then
the value of     equal to.
(A)  (B) 2 (C) 3 (D) 5
  3 1 3 1
Q.7 All values of x   0, 2  such that   4 2 are :
  sin x cos x
  11 3
(A) (B) (C) (D)
15 12 36 10
dy sin y  x
Q.8 The solution of the differential equation dx  sin 2 y  x cos y is

x2 x2
(A) sin y  x sin y  C (B) sin y  x sin y  C
 

2 2
x2 x2
(C) sin y  x  sin y  C (D) sin y  x  sin y  C
 

2 2
Q.9 The primitive of the D.E (2xy4ey + 2xy3 + y)dx + (x2y4ey – x2y2 – 3x)dy = 0 is :
x2 x x2 x
(A) x e   K (B) x e   K
2 y 2 y

y y3 y y3
x2 x x2 x
(C) x e   K (D) x e   K
2 y 2 y

y y3 y y3

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 x dx + y dy a2 - x2 - y 2
Q.10 The solution of the differential equation = is
x dy - y dx x2 + y 2
1 y  y
(A) x  y  a cos c  tan
2 2
 (B) x 2  y 2  a sin c  tan 1 
 x  x
 x  x
(C) x 2  y 2  a sin c  tan 1  (D) x 2  y 2  a cos c  tan 1 
 y  y

Q.11 If z1, z2 are complex numbers such that Re( z1) | z1  2 |, Re( z2 ) | z2  2 | and
arg( z1  z2 )   / 3 , then Im (z1  z2) =
(A) 2 / 3 (B) 4 / 3 (C) 2 3 (D) 3
Q.12 If z  x  iy is such that | z  4 || z  2 | , then
(A) x  0, y  0 (B) x  0, y  0
(C) x  2, y  3 (D) x  3 and y is any real number

Q.13 If x 2  x  1  0 then the value of :

2 2 2 2
 1  2 1   3 1   27 1 
 x     x  2    x  3   .....   x  27  is
 x  x   x   x 
(A) 27 (2) 18 (C) 54 (D) - 27
Q.14 If x>1, y >1, z>1 are in G.P., then logex e, logey e, logez e are in :
(A) A.P (B) H.P (C) G.P (D) A.G.P
n
1  1 1 
Q.15 If 
r 0
n
Cr
 a , then the value of    n
0  i  j n  C i
 n  is
C j 
na
(A) na (B) n2a (C) (D) none of these
2
Q.16 The greatest value of the expression P  x   1  x  1  x 1  2x  is equal to
5 2

(A) 102 (B) 108 (C) does not exist (D) none of these
n
 r n
  1
r 1
Q.17 The value of   . Cr is
r 1  r 1 
1 1 1
(A) (B) (C) (D) 0
n 1 n n 1
Q.18 Two circles passing through the points A(1, 2) and E(2, 1) touch the line 4x + 8y – 7 = 0 at B
and D. The possible coordinate of point C such that ABCD is a parallelogram is :
 15 9  1 5  5 3
(A)  ,  (B) (0, 3) (C)  ,  (D)   ,
 2 2 2 2  2 4
Q.19 In the xy–plane, the length of the shortest path from (0, 0) to (12, 16) that does not go inside
the circle (x – 6)2 + (y – 8)2 = 25 is
5
(A) 10 3 (B) 10 5 (C) 10 3  (D) 10  5
3

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Q.20 If two circles  x  1   y  3  r 2 and x 2  y2  8x  2y  8  0 intersect in two distinct
2 2

points, then
(A) 2  r  8 (B) r  2 (C) r  2 (D) r  2
Integer Type :
Q.21 log (a + c), log (a + b), log (b + c) are in A.P and a, c, b are in H.P where a, b, c > 0.
If a + b = k c/4 then the value of ‘k’ is :

 2
Q.22 If x, y  R satisfy log8 x  log 4 y  5 and log8 y  log 4 x 2
 7 then the value of
 x2  y 2 

2080
.....

4 ta tb tac

Q.23 If a,b,c,d are in A.P and  f  t  dt  32 where f  t   t  b t  c t  1 then the positive
0
tc td t b d
common difference of A.P is___ :
p
Q.24 In a triangle ABC, a : b : c = 4 : 5 : 6. The ratio of the radius of the circumcircle to that of the incircle is q then
p  q  ..... :
Q.25 21 tickets are numbered from1 to 21 serially. Three are drawn at random. The chance that the numbers on
1 
the selected tickets are in A.P is ‘P’. Then   7  = ..... where [.] is G.I.F :
P 

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